JP2011168459A - Cement firing method and firing device - Google Patents

Cement firing method and firing device Download PDF

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JP2011168459A
JP2011168459A JP2010035518A JP2010035518A JP2011168459A JP 2011168459 A JP2011168459 A JP 2011168459A JP 2010035518 A JP2010035518 A JP 2010035518A JP 2010035518 A JP2010035518 A JP 2010035518A JP 2011168459 A JP2011168459 A JP 2011168459A
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cement
fluidized bed
limestone
circulating fluidized
bed furnace
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JP5348790B2 (en
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Kensaburo Kondo
健三朗 近藤
Shinichiro Saito
紳一郎 齋藤
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Taiheiyo Cement Corp
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    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
    • C04B7/44—Burning; Melting
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B7/00—Hydraulic cements
    • C04B7/36—Manufacture of hydraulic cements in general
    • C04B7/43—Heat treatment, e.g. precalcining, burning, melting; Cooling
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00—Technologies relating to the processing of minerals
    • Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
    • Y02P40/18—Carbon capture and storage [CCS]

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  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Treating Waste Gases (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To efficiently recover or store carbon dioxide included in an exhausted gas from a cement firing apparatus while receiving various recycled resources. <P>SOLUTION: The cement firing device 1 includes: a circulating fluidized bed 31 of thermally decomposing limestone while heating the same; a preheater 21 of heating a cement raw material other than the limestone; and a cement kiln 23 of firing the heated cement raw material. In the circulation fluidized bed, the limestone is thermally decomposed into quicklime, and is utilized for the firing of cement, and simultaneously generated carbon dioxide having high purity is recovered and stored. The device can include: a crusher 32 of crushing the quicklime and coal ash from the circulation fluidized bed; and a chlorine bypass system of removing chlorine concentrated at the lowest part of the preheater. The raw material other than the limestone can be heated, e.g., by a shaft furnace or the like other than the preheater. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、セメント焼成方法及び焼成装置に関し、特に、セメント焼成装置から排出される排ガス中の炭酸ガスを効率よく回収するセメント焼成方法等に関する。   The present invention relates to a cement firing method and a firing apparatus, and more particularly to a cement firing method and the like that efficiently recovers carbon dioxide in exhaust gas discharged from a cement firing apparatus.

セメント焼成装置からは、燃料の石炭の燃焼と、原料の石灰石の分解に伴いセメント１トンあたり７００ｋｇ以上の炭酸ガス（ＣＯ2）が排出される。炭酸ガスは地球温暖化の原因となるため、そのまま大気に排出するのは好ましくなく、上記炭酸ガスの回収又は貯留が求められていた。 From the cement firing device, 700 kg or more of carbon dioxide (CO 2 ) is discharged per ton of cement with combustion of fuel coal and decomposition of raw material limestone. Since carbon dioxide causes global warming, it is not preferable to discharge it to the atmosphere as it is, and it has been demanded to collect or store the carbon dioxide.

そこで、特許文献１には、酸素燃焼微粉炭セメントクリンカ焼成プロセスを利用し、プレヒータからの排ガスを冷却し、冷却した排ガス中の水蒸気を取り除き、除湿された排ガスの一部から炭酸ガスを液化して取り除くセメント焼成設備の炭酸ガス回収方法等が開示されている。   Therefore, Patent Document 1 uses an oxygen combustion pulverized coal cement clinker firing process to cool the exhaust gas from the preheater, remove water vapor in the cooled exhaust gas, and liquefy carbon dioxide from a part of the dehumidified exhaust gas. A method for recovering carbon dioxide gas from a cement firing facility that is removed in the past is disclosed.

特許第４３５０７６５号公報Japanese Patent No. 4350765

しかし、近年の社会的要請に沿って、セメント工場では様々なリサイクル資源を受け入れ、セメント焼成装置において原燃料として利用しているため、プレヒータからの排ガス中に、炭酸ガス以外の成分が増加し、特許文献１に記載の技術を採用しても、この炭酸ガス以外の成分が炭酸ガスの回収又は貯留を妨げていた。   However, in line with recent social demands, cement factories accept various recycling resources and use them as raw fuel in cement firing equipment, so the components other than carbon dioxide in the exhaust gas from the preheater increase, Even when the technique described in Patent Document 1 is adopted, components other than the carbon dioxide gas have prevented the recovery or storage of the carbon dioxide gas.

そこで、本発明は、上記問題点に鑑みてなされたものであって、セメント焼成装置において多種多様なリサイクル資源を受け入れても、セメント焼成装置からの排ガス中に含まれる炭酸ガスを効率よく回収又は貯留することが可能なセメント焼成方法等を提供することを目的とする。   Therefore, the present invention has been made in view of the above-mentioned problems, and even if a wide variety of recycled resources are accepted in the cement firing device, the carbon dioxide contained in the exhaust gas from the cement firing device can be efficiently recovered or It aims at providing the cement baking method etc. which can be stored.

上記目的を達成するため、本発明は、セメント焼成方法であって、循環流動層炉において、石灰石を昇温して熱分解させ、該循環流動層炉以外の装置において、石灰石以外のセメント原料を昇温し、セメントキルンにおいて、前記熱分解により生じた生石灰と、前記昇温されたセメント原料とを焼成することを特徴とする。   In order to achieve the above object, the present invention is a cement firing method, wherein a limestone is heated and pyrolyzed in a circulating fluidized bed furnace, and a cement raw material other than limestone is used in an apparatus other than the circulating fluidized bed furnace. The temperature is raised, and the quick lime generated by the thermal decomposition and the heated cement raw material are fired in the cement kiln.

そして、本発明によれば、循環流動層炉において石灰石を熱分解して生石灰としてセメント焼成に利用し、同時に純度の高い炭酸ガスを生成することができ、セメントキルンで多種多様なリサイクル資源を原燃料として利用しながら、炭酸ガスの処理を容易にすることができる。   According to the present invention, limestone is thermally decomposed in a circulating fluidized bed furnace and used as quick lime for cement firing, and at the same time, high-purity carbon dioxide gas can be generated. Carbon dioxide gas can be easily treated while being used as a fuel.

上記セメント焼成方法において、プレヒータ付きセメントキルンの該プレヒータにおいて、前記石灰石以外のセメント原料を昇温し、該セメントキルンにおいて、該昇温されたセメント原料と、前記熱分解により生じた生石灰とを焼成することができる。   In the cement firing method, the cement raw material other than the limestone is heated in the preheater of the cement kiln with a preheater, and the heated cement raw material and the quick lime generated by the thermal decomposition are fired in the cement kiln. can do.

また、上記セメント焼成方法において、前記循環流動層炉の排ガスから炭酸ガスを回収又は貯留することができる。   Moreover, in the said cement baking method, a carbon dioxide gas can be collect | recovered or stored from the waste gas of the said circulating fluidized bed furnace.

さらに、上記セメント焼成方法において、前記熱分解により生じた生石灰及び石炭灰分を破砕して得られた破砕物を前記セメントキルンに供給し、前記プレヒータの最下部に濃縮した塩素を除去することができる。   Furthermore, in the cement firing method, the crushed material obtained by crushing quick lime and coal ash generated by the thermal decomposition can be supplied to the cement kiln, and the concentrated chlorine at the lowermost part of the preheater can be removed. .

前記循環流動層炉以外の装置で昇温されるセメント原料に、前記循環流動層炉に供給される石灰石以外の石灰石を含めるようにしてもよい。   You may make it include the limestone other than the limestone supplied to the said circulating fluidized bed furnace in the cement raw material heated up with apparatuses other than the said circulating fluidized bed furnace.

また、本発明は、セメント焼成装置であって、石灰石を昇温して熱分解させる循環流動層炉と、石灰石以外のセメント原料を昇温する、前記循環流動層炉以外の装置と、前記熱分解により生じた生石灰と、前記昇温されたセメント原料とを焼成するセメントキルンとを備えることを特徴とする。本発明によれば、上記発明と同様に、セメントキルンで多種多様なリサイクル資源を原燃料として利用しながら、純度の高い炭酸ガスを生成し、炭酸ガスの処理を容易にすることができる。   Further, the present invention is a cement firing device, a circulating fluidized bed furnace for heating and thermally decomposing limestone, an apparatus other than the circulating fluidized bed furnace for heating a cement raw material other than limestone, and the heat It comprises a quick kiln generated by decomposition and a cement kiln that fires the heated cement raw material. According to the present invention, similarly to the above-described invention, a carbon dioxide gas with high purity can be generated and a carbon dioxide gas can be easily treated while using a wide variety of recycled resources as a raw fuel in a cement kiln.

前記セメント焼成装置において、前記循環流動層炉以外の装置を、前記セメントキルンに付設されたプレヒータとすることができる。   In the cement baking apparatus, an apparatus other than the circulating fluidized bed furnace may be a preheater attached to the cement kiln.

前記セメント焼成装置において、前記循環流動層炉の排ガスから炭酸ガスを回収する炭酸ガス回収装置、又は前記循環流動層炉の排ガスからの炭酸ガスを貯留する炭酸ガス貯留装置を設けることができ、発生した純度の高い炭酸ガスを回収又は貯留することができる。   In the cement firing device, a carbon dioxide gas recovery device that recovers carbon dioxide gas from the exhaust gas of the circulating fluidized bed furnace, or a carbon dioxide gas storage device that stores carbon dioxide gas from the exhaust gas of the circulating fluidized bed furnace can be provided and generated The high purity carbon dioxide gas can be recovered or stored.

前記セメント焼成装置において、前記循環流動層炉からの生石灰及び石炭灰分を破砕する破砕装置と、該破砕装置からの破砕物を前記セメントキルンに供給する供給装置と、前記プレヒータの最下部に濃縮した塩素を除去する塩素バイパスシステムとを設けることができる。   In the cement baking apparatus, a crushing apparatus that crushes quick lime and coal ash from the circulating fluidized bed furnace, a supply apparatus that supplies the crushed material from the crushing apparatus to the cement kiln, and the bottom of the preheater. And a chlorine bypass system for removing chlorine.

以上のように、本発明によれば、セメント焼成装置において多種多様なリサイクル資源を受け入れても、セメント焼成装置からの排ガス中に含まれる炭酸ガスを効率よく回収又は貯留することができる。   As described above, according to the present invention, the carbon dioxide contained in the exhaust gas from the cement firing device can be efficiently recovered or stored even when a wide variety of recycled resources are accepted in the cement firing device.

本発明にかかるセメント焼成装置の一実施の形態を示すフローチャートである。It is a flowchart which shows one Embodiment of the cement baking apparatus concerning this invention.

次に、本発明を実施するための形態について、図面を参照しながら詳細に説明する。   Next, an embodiment for carrying out the present invention will be described in detail with reference to the drawings.

図１は、本発明にかかるセメント焼成装置の一実施形態を示し、このセメント焼成装置１は、大別して、セメント焼成部２と、石灰石加熱部３と、熱回収部４と、炭酸ガス回収・貯留部５とで構成される。   FIG. 1 shows an embodiment of a cement firing apparatus according to the present invention. This cement firing apparatus 1 is roughly divided into a cement firing part 2, a limestone heating part 3, a heat recovery part 4, a carbon dioxide recovery / It is comprised with the storage part 5. FIG.

セメント焼成部２は、サイクロン２１Ａ〜２１Ｄと、仮焼炉２１Ｅとを備えたプレヒータ２１と、セメントキルン２３と、クリンカクーラ２４と、抽気プローブ２５と、バッグフィルタ２６等で構成され、抽気プローブ２５及びバッグフィルタ２６は、塩素バイパスシステムの一部を構成する。これらの装置は、通常のセメント焼成装置に備えられるものであり、詳細な説明を省略する。   The cement firing unit 2 includes a preheater 21 including cyclones 21A to 21D and a calcining furnace 21E, a cement kiln 23, a clinker cooler 24, an extraction probe 25, a bag filter 26, and the like. And the bag filter 26 comprises a part of chlorine bypass system. These apparatuses are provided in a normal cement baking apparatus, and detailed description thereof is omitted.

石灰石加熱部３は、石灰石を昇温して熱分解させる循環流動層炉３１と、熱分解されて得られた生石灰等を破砕するロールクラッシャ３２等で構成される。   The limestone heating unit 3 includes a circulating fluidized bed furnace 31 that heats and decomposes limestone, and a roll crusher 32 that crushes quick lime obtained by thermal decomposition.

熱回収部４は、プレヒータ２１からの排ガスＧ１から廃熱を回収する廃熱ボイラー４１と、循環流動層炉３１からの排ガスＧ３から熱を回収する蒸気ボイラー４２と、両ボイラー４１、４２からの蒸気を利用して発電する発電機４３とで構成される。   The heat recovery unit 4 includes a waste heat boiler 41 that recovers waste heat from the exhaust gas G 1 from the preheater 21, a steam boiler 42 that recovers heat from the exhaust gas G 3 from the circulating fluidized bed furnace 31, and the boilers 41 and 42. And a generator 43 that generates power using steam.

炭酸ガス回収・貯留部５は、蒸気ボイラー４２からの排ガスを冷却するなどの前処理を行う前処理装置５１と、前処理後の排ガスに吸収液を添加するなどして炭酸ガスを分離回収するＣＣＳ装置５２とで構成される。尚、ＣＣＳ装置としては、関西電力株式会社製の排煙脱炭プラント等を用いることができる。   The carbon dioxide gas recovery / storage unit 5 separates and recovers the carbon dioxide gas by adding a pretreatment device 51 that performs pretreatment such as cooling the exhaust gas from the steam boiler 42 and the pretreated exhaust gas. And a CCS device 52. As the CCS device, a flue gas decarburization plant manufactured by Kansai Electric Power Co., Inc. can be used.

次に、本発明にかかるセメント焼成装置１の動作について、図１を参照しながら詳細に説明する。   Next, operation | movement of the cement baking apparatus 1 concerning this invention is demonstrated in detail, referring FIG.

まず、石灰石加熱部３の循環流動層炉３１で燃料として微粉炭を燃焼させ、石灰石（ＣａＣＯ3）を投入して昇温し、ＣａＣＯ3を生石灰（ＣａＯ）と炭酸ガス（ＣＯ2）に熱分解させる。次に、熱分解した生石灰、及び微粉炭燃焼により生じた石炭灰分をロールクラッシャ３２により破砕し、破砕物をセメントキルン２３に供給する。循環流動層炉３１の下部に堆積する残渣は、適宜排出して処理する。 First, pulverized coal is burned as fuel in the circulating fluidized bed furnace 31 of the limestone heating unit 3, limestone (CaCO 3 ) is charged and the temperature is increased, and CaCO 3 is heated to quick lime (CaO) and carbon dioxide (CO 2 ). Decompose. Next, pyrolyzed quicklime and coal ash generated by pulverized coal combustion are crushed by a roll crusher 32, and the crushed material is supplied to the cement kiln 23. The residue deposited in the lower part of the circulating fluidized bed furnace 31 is appropriately discharged and processed.

循環流動層炉３１で生成された排ガスＧ３は、上述のように、ＣａＣＯ3の熱分解により生じたＣＯ2と、微粉炭の燃焼ガスのみを含有し、リサイクル資源の昇温や燃焼によって生じたガスを含んでいないため、後段の炭酸ガス回収・貯留部５において効率よく炭酸ガスを回収、貯留することができる。 As described above, the exhaust gas G3 generated in the circulating fluidized bed furnace 31 contains only CO 2 generated by the thermal decomposition of CaCO 3 and the combustion gas of pulverized coal, and is generated by the temperature increase or combustion of the recycled resources. Since no gas is contained, the carbon dioxide gas can be efficiently recovered and stored in the subsequent carbon dioxide gas recovery / storage unit 5.

セメント焼成部２において、石灰石以外のセメント原料、すなわち、粘土、珪石、鉄滓、鋳物砂、スラグ、アルミナスラッジ、廃棄物等をプレヒータ２１に投入して予熱した後、これらを仮焼炉２１Ｅで仮焼し、セメントキルン２３に供給する。そして、セメントキルン２３で、仮焼された石灰石以外の原料と、上記石灰石加熱部３のロールクラッシャ３２で破砕された生石灰とを焼成し、セメントクリンカを生成する。   In the cement firing part 2, cement raw materials other than limestone, that is, clay, silica stone, iron slag, foundry sand, slag, alumina sludge, waste, and the like are put into the preheater 21 and preheated, and then these are calcined in the calcining furnace 21E. Calcination and supply to cement kiln 23. And in the cement kiln 23, raw materials other than the calcined limestone and quick lime crushed by the roll crusher 32 of the limestone heating unit 3 are fired to produce a cement clinker.

また、プレヒータ２１の最下部に設けられたプローブ２５により、セメントキルン排ガスの一部Ｇ５を抽気してバッグフィルタ２６に供給し、排ガスの一部Ｇ５に含まれる塩素を含む微粉（塩素バイパスダスト）Ｆを集塵する。微粉（塩素バイパスダスト）Ｆを除去した後の排ガスＧ６は、循環流動層炉３１に戻すことができる。   Further, a part of the cement kiln exhaust gas G5 is extracted by the probe 25 provided at the lowermost part of the preheater 21 and supplied to the bag filter 26, and fine powder (chlorine bypass dust) containing chlorine contained in the exhaust gas part G5. Collect F. The exhaust gas G6 after removing the fine powder (chlorine bypass dust) F can be returned to the circulating fluidized bed furnace 31.

次に、熱回収部４において、廃熱ボイラー４１によってプレヒータ２１からの排ガスＧ１の廃熱を回収し、また、蒸気ボイラー４２によって、循環流動層炉３１からの排ガスＧ３の廃熱を回収する。両ボイラー４１、４２で発生した水蒸気を発電機４３に供給し、この水蒸気を利用してタービンを回し、発電する。   Next, in the heat recovery unit 4, the waste heat of the exhaust gas G1 from the preheater 21 is recovered by the waste heat boiler 41, and the waste heat of the exhaust gas G3 from the circulating fluidized bed furnace 31 is recovered by the steam boiler 42. Steam generated in both boilers 41 and 42 is supplied to a generator 43, and the turbine is rotated using this steam to generate electricity.

炭酸ガス回収・貯留部５の前処理装置５１において、蒸気ボイラー４２からの排ガスＧ４を冷却するなどの前処理を行った後、ＣＣＳ装置５２において、Ｎ2、Ｏ2、ＣＯ2及びＨ2Ｏを含む排ガスＧ４に、アルカノールアミン（Ｒ−ＮＨ2）を吸収液として添加し、下式に示すような化学反応を生じさせることにより、排ガスＧ４から炭酸ガス（ＣＯ2）を回収又は貯留することができる。 After the pretreatment such as cooling the exhaust gas G4 from the steam boiler 42 in the pretreatment device 51 of the carbon dioxide gas recovery / storage unit 5, the CCS device 52 performs N 2 , O 2 , CO 2 and H 2 O. The carbon dioxide (CO 2 ) is recovered or stored from the exhaust gas G4 by adding alkanolamine (R—NH 2 ) as an absorption liquid to the exhaust gas G4 containing, and causing a chemical reaction as shown in the following formula: Can do.

Ｒ-ＮＨ2＋Ｈ2Ｏ＋ＣＯ2⇔Ｒ-ＮＨ3ＨＣＯ3
２Ｒ-ＮＨ2＋ＣＯ2⇔Ｒ-ＮＨＣＯＯＮＨ3Ｒ R-NH 2 + H 2 O + CO 2 ⇔R-NH 3 HCO 3
2R-NH 2 + CO 2 ⇔R-NHCOONH 3 R

尚、炭酸ガス回収・貯留部５の前処理装置５１において、活性炭吸着塔等を設けることで、排ガスＧ４に含まれる酸性ガスの他、ＤＸＮｓやＰＣＢ等の残留性有機汚染物質（ＰＯＰｓ）や、水銀（Ｈｇ）を回収・除去することができる。   In addition, in the pretreatment device 51 of the carbon dioxide gas recovery / storage unit 5, by providing an activated carbon adsorption tower or the like, in addition to the acidic gas contained in the exhaust gas G4, residual organic pollutants (POPs) such as DXNs and PCB, Mercury (Hg) can be recovered and removed.

また、上記実施の形態においては、セメント焼成部２のプレヒータ２１には、石灰石以外の原料を投入したが、循環流動層炉３１に投入した以外の石灰石の一部をプレヒータ２１に投入することもできる。   In the above embodiment, the preheater 21 of the cement firing unit 2 is charged with raw materials other than limestone. However, a part of limestone other than that charged into the circulating fluidized bed furnace 31 may be charged into the preheater 21. it can.

さらに、上記実施の形態においては、石灰石以外の原料をプレヒータ２１において昇温したが、シャフト炉等を用いて昇温することもできる。   Furthermore, in the said embodiment, although raw material other than limestone was heated up in the preheater 21, it can also be heated up using a shaft furnace etc.

１ セメント焼成装置
２ セメント焼成部
２１ プレヒータ
２１Ａ〜２１Ｄ サイクロン
２１Ｅ 仮焼炉
２３ セメントキルン
２４ クリンカクーラ
２５ 抽気プローブ
２６ バッグフィルタ
３ 石灰石加熱部
３１ 循環流動層炉
３２ ロールクラッシャ
４ 熱回収部
４１ 廃熱ボイラー
４２ 蒸気ボイラー
４３ 発電機
５ 炭酸ガス回収・貯留部
５１ 前処理装置
５２ ＣＣＳ装置
Ｆ 微粉
Ｇ１〜Ｇ６ 排ガス DESCRIPTION OF SYMBOLS 1 Cement baking apparatus 2 Cement baking part 21 Preheater 21A-21D Cyclone 21E Calcining furnace 23 Cement kiln 24 Clinker cooler 25 Extraction probe 26 Bag filter 3 Limestone heating part 31 Circulating fluidized bed furnace 32 Roll crusher 4 Heat recovery part 41 Waste heat boiler 42 Steam boiler 43 Generator 5 Carbon dioxide recovery / storage unit 51 Pretreatment device 52 CCS device F Fine powder G1 to G6 Exhaust gas

Claims (9)

循環流動層炉において、石灰石を昇温して熱分解させ、
該循環流動層炉以外の装置において、石灰石以外のセメント原料を昇温し、
セメントキルンにおいて、前記熱分解により生じた生石灰と、前記昇温されたセメント原料とを焼成することを特徴とするセメント焼成方法。 In a circulating fluidized bed furnace, the limestone is heated and pyrolyzed,
In an apparatus other than the circulating fluidized bed furnace, the temperature of the cement raw material other than limestone is raised,
In the cement kiln, the quick lime produced | generated by the said thermal decomposition and the said cement raw material heated up are baked, The cement baking method characterized by the above-mentioned. プレヒータ付きセメントキルンの該プレヒータにおいて、前記石灰石以外のセメント原料を昇温し、該セメントキルンにおいて、該昇温されたセメント原料と、前記熱分解により生じた生石灰とを焼成することを特徴とする請求項１に記載のセメント焼成方法。   In the preheater of the cement kiln with a preheater, the cement raw material other than the limestone is heated, and the heated cement raw material and the quick lime generated by the thermal decomposition are fired in the cement kiln. The cement baking method according to claim 1. 前記循環流動層炉の排ガスから炭酸ガスを回収又は貯留することを特徴とする請求項１又は２に記載のセメント焼成方法。   The cement firing method according to claim 1 or 2, wherein carbon dioxide gas is recovered or stored from the exhaust gas of the circulating fluidized bed furnace. 前記熱分解により生じた生石灰及び石炭灰分を破砕して得られた破砕物を前記セメントキルンに供給し、
前記プレヒータの最下部に濃縮した塩素を除去することを特徴とする請求項２又は３に記載のセメント焼成方法。 Supplying the cement kiln with crushed material obtained by crushing quick lime and coal ash generated by the pyrolysis,
The cement baking method according to claim 2 or 3, wherein chlorine concentrated at a lowermost portion of the preheater is removed. 前記循環流動層炉以外の装置において昇温されるセメント原料は、前記循環流動層炉に供給される石灰石以外の石灰石を含むことを特徴とする請求項１乃至４のいずれかに記載のセメント焼成方法。   The cement raw material according to any one of claims 1 to 4, wherein the cement raw material heated in an apparatus other than the circulating fluidized bed furnace includes limestone other than limestone supplied to the circulating fluidized bed furnace. Method. 石灰石を昇温して熱分解させる循環流動層炉と、
石灰石以外のセメント原料を昇温する、前記循環流動層炉以外の装置と、
前記熱分解により生じた生石灰と、前記昇温されたセメント原料とを焼成するセメントキルンとを備えることを特徴とするセメント焼成装置。 A circulating fluidized bed furnace that heats and decomposes limestone;
An apparatus other than the circulating fluidized bed furnace for heating the cement raw material other than limestone,
A cement baking apparatus comprising a quick kiln generated by the thermal decomposition and a cement kiln for baking the heated cement raw material. 前記循環流動層炉以外の装置は、前記セメントキルンに付設されたプレヒータであることを特徴とする請求項６に記載のセメント焼成装置。   7. The cement firing apparatus according to claim 6, wherein the apparatus other than the circulating fluidized bed furnace is a preheater attached to the cement kiln. 前記循環流動層炉の排ガスから炭酸ガスを回収する炭酸ガス回収装置、又は前記循環流動層炉の排ガスからの炭酸ガスを貯留する炭酸ガス貯留装置を備えることを特徴とする請求項６又は７に記載のセメント焼成装置。   The carbon dioxide gas recovery device which collects carbon dioxide gas from the exhaust gas of the circulating fluidized bed furnace or the carbon dioxide gas storage device which stores the carbon dioxide gas from the exhaust gas of the circulating fluidized bed furnace is provided. The cement baking apparatus as described. 前記循環流動層炉からの生石灰及び石炭灰分を破砕する破砕装置と、
該破砕装置からの破砕物を前記セメントキルンに供給する供給装置と、
前記プレヒータの最下部に濃縮した塩素を除去する塩素バイパスシステムとを備えることを特徴とする請求項７又は８に記載のセメント焼成装置。 A crushing device for crushing quick lime and coal ash from the circulating fluidized bed furnace;
A supply device for supplying crushed material from the crushing device to the cement kiln;
The cement baking apparatus according to claim 7, further comprising a chlorine bypass system that removes concentrated chlorine at a lowermost portion of the preheater.
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JP2010509166A (en) * 2006-11-09 2010-03-25 レール・リキード−ソシエテ・アノニム・プール・レテュード・エ・レクスプロワタシオン・デ・プロセデ・ジョルジュ・クロード Method for producing clinker with controlled CO2 release

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013180949A (en) * 2012-02-29 2013-09-12 Citic Heavy Industries Co Ltd Quicklime firing system with calcining furnace and production method using the system
JP2015527286A (en) * 2012-07-04 2015-09-17 ティッセンクルップ インダストリアル ソリューションズ アクツィエンゲゼルシャフトＴｈｙｓｓｅｎＫｒｕｐｐ Ｉｎｄｕｓｔｒｉａｌ Ｓｏｌｕｔｉｏｎｓ ＡＧ Method and system for producing cement clinker from cement raw material
JP2019055903A (en) * 2017-09-22 2019-04-11 太平洋セメント株式会社 Firing apparatus of ecological cement
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