JP2011145404A - Method of manufacturing electrophotographic photoreceptor - Google Patents

Method of manufacturing electrophotographic photoreceptor Download PDF

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JP2011145404A
JP2011145404A JP2010005213A JP2010005213A JP2011145404A JP 2011145404 A JP2011145404 A JP 2011145404A JP 2010005213 A JP2010005213 A JP 2010005213A JP 2010005213 A JP2010005213 A JP 2010005213A JP 2011145404 A JP2011145404 A JP 2011145404A
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brush
conductive support
photosensitive layer
layer coating
ring
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JP5509860B2 (en
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Fumitaka Minegishi
史隆 嶺岸
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Mitsubishi Chemical Corp
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Mitsubishi Chemical Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of manufacturing an electrophotographic photoreceptor suppressing another failure while achieving a sampling purpose in a process of sampling, with a brush, photosensitive layer coating liquid adhering to an end of a conductive support. <P>SOLUTION: The method is provided for manufacturing the electrophotographic photoreceptor by applying the photosensitive layer coating liquid to the conductive support and drying it. The method includes the process of sampling, with the brush, the photosensitive layer coating liquid adhering to an end of a conductive support outer peripheral surface after applying the photosensitive layer coating liquid. The brush includes a cylindrical ring with a length T(mm), and a brush bristle group consisting of a plurality of brush bristles that are erected from the inner peripheral surface of the ring and have a length L(mm) and a diameter d(mm). When it is assumed that the thickness of the axial direction of the ring of the brush bristle group is t(mm), sectional secondary moment of the brush bristles is I(mm<SP>4</SP>), modulus of longitudinal elasticity of the brush bristles is E(kg/mm<SP>2</SP>), the contact width of the brush bristles with the outer peripheral surface of the conductive support is y(mm), and the degree of density of the brush bristle group is σ, a predetermined relationship is established. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、電子写真感光体の製造方法に関し、詳しくは、導電性支持体端部に付着した感光層塗布液の除去を適切におこなうことができる電子写真感光体の製造方法に関する。   The present invention relates to a method for producing an electrophotographic photosensitive member, and more particularly, to a method for producing an electrophotographic photosensitive member capable of appropriately removing a photosensitive layer coating solution adhering to an end portion of a conductive support.

電子写真感光体は、導電性を有する支持体(導電性支持体)の表面に感光層が設けられて形成される。すなわち、その製造においては導電性支持体の表面になんらかの方法により感光層となるべき感光層塗布液を塗布する。かかる塗布の方法の1つとして、感光層塗布液中に導電性支持体を浸漬し、その後これを引き上げて取り出すいわゆる浸漬塗布法が知られている。当該塗布に次いで感光層塗布液が付着した導電性支持体を乾燥させる。かかる方法によれば、塗布が容易であるとともに、感光層の均一性が良好な電子写真感光体を得ることができる。   The electrophotographic photosensitive member is formed by providing a photosensitive layer on the surface of a conductive support (conductive support). That is, in the production, a photosensitive layer coating solution to be a photosensitive layer is applied to the surface of the conductive support by some method. As one of such coating methods, a so-called dip coating method is known in which a conductive support is dipped in a photosensitive layer coating solution, which is then pulled out. Following the coating, the conductive support to which the photosensitive layer coating solution is adhered is dried. According to this method, it is possible to obtain an electrophotographic photosensitive member that is easy to apply and has good uniformity of the photosensitive layer.

ここで、電子写真感光体の両端部は、他と電気的に接続させたり、他の部材を取り付けたりする必要があることから、上記した感光層が形成されない方が好ましいことがある。上記した浸漬塗布法によれば、導電性支持体の一端(上端)側に感光層を形成しないことは、ここを浸漬しなければよいので可能である。ところが、導電性支持体の他端(下端)側にはどうしても感光層塗布液が付着する。   Here, since both ends of the electrophotographic photosensitive member need to be electrically connected to other parts or attached with other members, it may be preferable that the above-described photosensitive layer is not formed. According to the dip coating method described above, it is possible not to form the photosensitive layer on one end (upper end) side of the conductive support because it is not necessary to immerse the photosensitive layer. However, the photosensitive layer coating solution inevitably adheres to the other end (lower end) side of the conductive support.

そこで、浸漬塗布法で導電性支持体に感光層塗布液を付着させたときには、浸漬塗布の後に、導電性支持体の少なくとも一方の端部から感光層塗布液を除去する工程が必要である。かかる除去手段として、感光層塗布液を除去すべき導電性支持体の端部にブラシを配置して拭き取ることが特許文献1に開示されている。これによれば、導電性支持体端部に付着した感光層塗布液を拭き取って除去することが可能であるとされている。   Therefore, when the photosensitive layer coating solution is adhered to the conductive support by the dip coating method, a step of removing the photosensitive layer coating solution from at least one end of the conductive support is necessary after the dip coating. As such a removing means, Patent Document 1 discloses that a brush is disposed on an end portion of a conductive support from which a photosensitive layer coating solution is to be removed. According to this, it is supposed that the photosensitive layer coating solution adhering to the end portion of the conductive support can be wiped off and removed.

特許第3845465号公報Japanese Patent No. 3845465

上記したようなブラシは導電性支持体に直接接触して感光層塗布液を拭き取るので、導電性支持体に傷をつけることや、摩耗によりブラシ自体の損耗が激しいことが不具合の原因の1つとなっていた。一方、このような不具合を回避するために例えばブラシのコシを弱くしすぎれば、本来の目的である感光層塗布液の拭き取りが適切に行われなくなる。   Since the brush as described above directly contacts the conductive support and wipes off the photosensitive layer coating solution, one of the causes of the trouble is that the conductive support is scratched or the wear of the brush itself is severely worn. It was. On the other hand, if, for example, the stiffness of the brush is made too weak in order to avoid such a problem, the photosensitive layer coating solution, which is the original purpose, cannot be properly wiped off.

また、上記したブラシのコシに関連した事項の他、異物の混入や導電性支持体との接触強さ等の問題もあり、どのようなブラシによれば、不具合を低減させて拭き取り工程をおこなうことができるかについての判断が困難であった。   Moreover, in addition to the above-mentioned matters related to the stiffness of the brush, there are also problems such as contamination of foreign matters and contact strength with the conductive support. With any brush, the wiping process is performed with reduced defects. It was difficult to judge whether it was possible.

そこで、本発明は上記問題点に鑑み、導電性支持体の端部に付着した感光層塗布液をブラシにより拭き取る工程において、拭き取りの目的を達しつつ、他の不具合を抑制することが可能な電子写真感光体の製造方法を提供することを課題とする。   Accordingly, in view of the above problems, the present invention provides an electronic device capable of suppressing other problems while achieving the purpose of wiping in the step of wiping the photosensitive layer coating solution adhering to the end of the conductive support with a brush. It is an object of the present invention to provide a method for producing a photographic photoreceptor.

以下、本発明について説明する。ここではわかりやすさのため括弧書きにて図面の参照符号を付すが、本発明はこれに限定されるものではない。   The present invention will be described below. Here, for ease of understanding, reference numerals of the drawings are given in parentheses, but the present invention is not limited to this.

請求項1に記載の発明は、円筒状の導電性支持体(1)に感光層塗布液を塗布、乾燥させて電子写真感光体を製造する方法であって、導電性支持体に感光層塗布液を塗布した後、導電性支持体の外周面の端部に付着した感光層塗布液をブラシ(40)で拭き取る工程(S2)を有し、ブラシは、長さT(mm)の円筒状であるリング(41)と、該リングの内周面からリングの中心軸に向かうように立設した長さL(mm)、直径d(mm)の複数のブラシ毛(42a、42a、…)からなるブラシ毛群(42)と、を備え、ブラシ毛群の、リングの軸線に平行な方向の厚さをt(mm)、ブラシ毛の断面二次モーメントI(mm)を、

Figure 2011145404
とし、ブラシ毛の縦弾性係数をE(kg/mm)、及びブラシ毛と導電性支持体の外周面との接触代をy(mm)、ブラシ毛群の密集度を、
Figure 2011145404
で表わすと、
Figure 2011145404
が成立することを特徴とする電子写真感光体の製造方法である。 The invention according to claim 1 is a method for producing an electrophotographic photosensitive member by applying a photosensitive layer coating solution to a cylindrical conductive support (1) and drying it, and applying the photosensitive layer to the conductive support. After applying the solution, the photosensitive layer coating solution adhering to the end of the outer peripheral surface of the conductive support has a step (S2) of wiping with a brush (40), and the brush has a cylindrical shape with a length T (mm). And a plurality of bristles (42a, 42a,...) Having a length L (mm) and a diameter d (mm) erected from the inner peripheral surface of the ring toward the center axis of the ring A bristle group (42) comprising: a thickness of the bristle group in a direction parallel to the axis of the ring t (mm), and a cross-sectional secondary moment I (mm 4 ) of the bristle,
Figure 2011145404
And the longitudinal elastic modulus of the bristle is E (kg / mm 2 ), the contact margin between the bristle and the outer peripheral surface of the conductive support is y (mm), and the density of the bristle group is
Figure 2011145404
In terms of
Figure 2011145404
Is a method for producing an electrophotographic photosensitive member.

請求項2に記載の発明は、円筒状の導電性支持体(1)に感光層塗布液を塗布、乾燥させて電子写真感光体を製造する方法であって、導電性支持体に感光層塗布液を塗布した後、導電性支持体の外周面の端部に付着した感光層塗布液をブラシ(40)で拭き取る工程を有し、ブラシは、長さT(mm)の円筒状であるリング(41)と、該リングの内周面からリングの中心軸に向かうように立設した長さL(mm)、直径d(mm)の複数のブラシ毛からなるブラシ毛群と、を備え、ブラシ毛群の、リングの軸線に平行な方向の厚さをt(mm)、ブラシ毛の断面二次モーメントI(mm)を、

Figure 2011145404
とし、ブラシ毛の縦弾性係数をE(kg/mm)、及びブラシ毛と導電性支持体の外周面との接触代をy(mm)、ブラシ毛群の密集度を、
Figure 2011145404
で表わすと、
Figure 2011145404
が成立することを特徴とする電子写真感光体の製造方法である。 The invention according to claim 2 is a method for producing an electrophotographic photosensitive member by applying and drying a photosensitive layer coating solution on a cylindrical conductive support (1), and applying the photosensitive layer to the conductive support. A step of wiping off the photosensitive layer coating solution adhering to the end of the outer peripheral surface of the conductive support with a brush (40) after applying the solution, and the brush is a cylindrical ring having a length T (mm) (41), and a bristle group consisting of a plurality of brush bristles having a length L (mm) and a diameter d (mm) erected from the inner peripheral surface of the ring toward the central axis of the ring, The thickness of the bristle group in the direction parallel to the axis of the ring is t (mm), and the cross-sectional secondary moment I (mm 4 ) of the bristle is
Figure 2011145404
And the longitudinal elastic modulus of the bristle is E (kg / mm 2 ), the contact margin between the bristle and the outer peripheral surface of the conductive support is y (mm), and the density of the bristle group is
Figure 2011145404
In terms of
Figure 2011145404
Is a method for producing an electrophotographic photosensitive member.

本発明によれば、導電性支持体の端部拭き取りに際し、感光体塗布液を適切に除去しつつ、導電性支持体への傷つきが抑制され、ブラシ毛の寿命向上、及びブラシ毛群の洗浄後の異物残留も抑制することが可能となる。   According to the present invention, at the time of wiping the edge of the conductive support, the photosensitive coating solution is appropriately removed, while damage to the conductive support is suppressed, the life of the brush hair is improved, and the brush hair group is washed. It is also possible to suppress the remaining foreign matter.

1つの実施形態に係る電子写真感光体の製造方法に含まれる工程S0を説明するフロー図である。It is a flowchart explaining process S0 included in the manufacturing method of the electrophotographic photoreceptor which concerns on one embodiment. 導電性支持体、及び搬送装置を説明する図である。It is a figure explaining an electroconductive support body and a conveying apparatus. 導電性支持体が搬送装置のピッカーに保持されている姿勢を説明する図である。It is a figure explaining the attitude | position where the electroconductive support body is hold | maintained at the picker of a conveying apparatus. 浸漬塗布工程を説明する図である。It is a figure explaining a dip coating process. 端部拭き取り装置を説明する図である。It is a figure explaining an edge part wiping apparatus. ブラシを表わした図である。It is a figure showing a brush. 関係式を説明するための図である。It is a figure for demonstrating a relational expression. 関係式を説明するための他の図である。It is another figure for demonstrating a relational expression.

本発明の上記した作用及び利得は、次に説明する発明を実施するための形態から明らかにされる。以下本発明を図面に示す実施形態に基づき説明する。ただし本発明はこれら実施形態に限定されるものではない。   The above-described operation and gain of the present invention will be clarified from embodiments for carrying out the invention described below. Hereinafter, the present invention will be described based on embodiments shown in the drawings. However, the present invention is not limited to these embodiments.

図1は、1つの実施形態に係る電子写真感光体の製造方法に含まれる工程S0を説明するフロー図である。工程S0は、浸漬塗布工程S1、端部拭き取り工程S2、及び表面乾燥工程S3、を含んでいる。工程S0の前後には通常の製造方法と同様の各工程が配置されている。例えば工程S0の前には導電性支持体の洗浄・乾燥工程(図1に破線で表した。)等を有し、工程S0の後には積み下ろしや荷詰めの工程等が含まれる。   FIG. 1 is a flowchart for explaining step S0 included in the method of manufacturing an electrophotographic photosensitive member according to one embodiment. Step S0 includes a dip coating step S1, an edge wiping step S2, and a surface drying step S3. Before and after step S0, the same steps as those in the normal manufacturing method are arranged. For example, before the step S0, there is a cleaning / drying step (shown by a broken line in FIG. 1) of the conductive support, and after the step S0, a loading and unloading step and the like are included.

工程S0の説明の前に、該工程S0に供給される導電性支持体1及びその搬送手段10について説明する。図2、図3に説明図を示した。図2は、導電性支持体1、1、…が搬送手段10に保持されている場面を表しており、図3は、具体的にどのように保持されているかを説明する図である。図3では分かり易さのため、導電性支持体1の内側を透視して表している。   Prior to the description of step S0, the conductive support 1 supplied to the step S0 and its transport means 10 will be described. 2 and 3 are explanatory diagrams. FIG. 2 shows a scene where the conductive supports 1, 1,... Are held by the conveying means 10, and FIG. 3 is a diagram for explaining how the conductive supports 1, 1,. In FIG. 3, the inside of the conductive support 1 is seen through for easy understanding.

本実施形態の導電性支持体1は円筒状であり、電子写真感光体として機能するに際し、円筒軸の軸心を中心に回転することにより媒体に連続して画像等を転写させることができる。従って可能な限り偏心がなく、振れが小さく、真直度が良好な方がよい。導電性支持体1の外径、及び長さはこれが適用される画像形成装置の仕様に見合った適切なものとされるが、通常、導電性支持体1の外径は2cm〜20cm、長さは21cm〜100cmの範囲であることが多い。   The conductive support 1 of the present embodiment has a cylindrical shape, and when functioning as an electrophotographic photosensitive member, an image or the like can be continuously transferred to a medium by rotating around the axis of the cylindrical shaft. Therefore, it is better that there is as little eccentricity as possible, the deflection is small, and the straightness is good. The outer diameter and length of the conductive support 1 are appropriate for the specifications of the image forming apparatus to which the conductive support 1 is applied. Usually, the outer diameter of the conductive support 1 is 2 cm to 20 cm and the length is long. Is often in the range of 21 cm to 100 cm.

導電性支持体1の材質は特に限定されるものではないが、導電性を有することが必要とされることから、アルミニウム、ニッケル、黄銅、ステンレス鋼等の金属材料、又はこれらの金属箔のラミネート物、蒸着物を挙げることができる。また、その他、表面にアルミニウム、銅、パラジウム、酸化すず、酸化インジウム等の導電性層を設けたポリエチレンテレフタレート、ポリプロピレン、ナイロン、ポリスチレン、フェノール樹脂などの高分子材料、及びそれらの高分子にカーボンブラックなどを混合させ導電性を持たせたものでもよい。さらには、硬質紙等のその他の材料を円筒状に成形し、金属粉末、カーボンブラック、ヨウ化銅、高分子電解質等の導電性物質を適当なバインダーとともに塗布して導電処理したもの、又は酸化すず、酸化インジウム等の導電性金属酸化物で導電処理したプラスチックドラム等を挙げることもできる。   Although the material of the electroconductive support body 1 is not specifically limited, Since it is required to have electroconductivity, metal materials, such as aluminum, nickel, brass, stainless steel, or the lamination of these metal foils And deposits. In addition, polymer materials such as polyethylene terephthalate, polypropylene, nylon, polystyrene, and phenolic resin with conductive layers such as aluminum, copper, palladium, tin oxide, and indium oxide provided on the surface, and carbon black for these polymers It is also possible to mix them with conductivity. Furthermore, other materials such as hard paper are formed into a cylindrical shape, and a conductive material such as metal powder, carbon black, copper iodide, and polymer electrolyte is applied together with a suitable binder to conduct a conductive treatment, or oxidized. Examples thereof include a plastic drum subjected to conductive treatment with a conductive metal oxide such as tin oxide.

搬送装置10は、導電性支持体1を保持するとともに、その移動・搬送をする装置である。搬送装置10は、図2からわかるように、昇降及び水平方向に移動可能であるアーム11と、該アーム11の先端に設けられた板状の基体12を具備している。また基体12の下面からは複数のピッカー13、13、…が下方に延在するように設けられている。   The conveyance device 10 is a device that holds the conductive support 1 and moves and conveys the conductive support 1. As can be seen from FIG. 2, the transfer device 10 includes an arm 11 that can move up and down and move in the horizontal direction, and a plate-like substrate 12 provided at the tip of the arm 11. Also, a plurality of pickers 13, 13,... Are provided so as to extend downward from the lower surface of the base 12.

ピッカー13は、図3からわかるように、軸14を備え、該軸14の外周面には空気の流入及び流出により膨張及び収縮する2つの風船体15、16が具備されている。また、軸14の先端には、先端が細く形成されているガイド部材17が設けられている。   As can be seen from FIG. 3, the picker 13 includes a shaft 14, and two balloon bodies 15 and 16 that expand and contract by air inflow and outflow are provided on the outer peripheral surface of the shaft 14. In addition, a guide member 17 having a thin tip is provided at the tip of the shaft 14.

図3に示したように、軸14が導電性支持体1の内側に挿入され、風船体15、16が膨張することにより該導電性支持体1が保持される。軸14が導電性支持体1の内側に挿入される際には該挿入を妨害しないように風船体15、16は収縮している。このとき、楔状であるガイド部材17の補助により円滑に挿入が行われる。   As shown in FIG. 3, the shaft 14 is inserted inside the conductive support 1, and the balloon supports 15 and 16 are expanded to hold the conductive support 1. When the shaft 14 is inserted into the inside of the conductive support 1, the balloon bodies 15 and 16 are contracted so as not to disturb the insertion. At this time, the insertion is performed smoothly with the aid of the wedge-shaped guide member 17.

ピッカー13、13、…に保持された導電性支持体1、1、…はアーム11の昇降及び移動・回動により搬送される。   The conductive supports 1, 1,... Held by the pickers 13, 13,.

図1に戻って工程S0の各工程について説明する。
浸漬塗布工程S1は、導電性支持体1を感光層塗布液が溜められた浸漬装置20に浸漬して感光層塗布液を導電性支持体1に塗布する工程である。図4に説明図を示した。上記したように搬送装置10に保持された導電性支持体1、1、…が、該搬送装置10により浸漬装置20の真上まで搬送され、図4に矢印Aで示したように降下して浸漬され、その後、引き上げられる。これにより、導電性支持体1の外表面に感光層塗布液が塗布される。
Returning to FIG. 1, each step of step S0 will be described.
The dip coating step S1 is a step of immersing the conductive support 1 in a dipping device 20 in which a photosensitive layer coating solution is stored to apply the photosensitive layer coating solution to the conductive support 1. FIG. 4 shows an explanatory diagram. As described above, the conductive supports 1, 1,... Held by the transport apparatus 10 are transported by the transport apparatus 10 to just above the immersion apparatus 20, and descend as shown by an arrow A in FIG. Soaked and then pulled up. Thereby, the photosensitive layer coating solution is applied to the outer surface of the conductive support 1.

上記した浸漬塗布工程S1の説明から明らかなように、導電性支持体1はその下端部から浸漬されるので、少なくとも導電性支持体1の下端部には感光層塗布液が付着している。
また、当該浸漬塗布工程S1では、一回の塗布とは限らず、必要とされる複数の層がある場合には、必要な複数の層が形成されるまで、繰り返して塗布してもよい。
As is clear from the description of the dip coating step S1 described above, the conductive support 1 is immersed from the lower end thereof, and therefore the photosensitive layer coating solution is attached to at least the lower end of the conductive support 1.
Moreover, in the said dip coating process S1, not only one application | coating but when there exist a some required layer, you may apply repeatedly until a required some layer is formed.

ここで用いられる浸漬装置20は公知のものを適用することができる。例えば浸漬装置20は、感光層塗布液が貯溜され、導電性支持体1が浸漬される部位である浸漬槽と、感光層塗布液を循環させる循環機構とを備える。浸漬槽に貯溜された感光層塗布液は、塗布液供給口から浸漬槽に供給され、その上部からオーバーフローする。オーバーフローした感光層塗布液はトレイで受け止められて塗布液タンクに送られる。塗布液タンクでは、感光層塗布液の調整が行わると共に攪拌され、その後、供給ポンプにより再び浸漬層に送られる。   A known device can be used as the immersion device 20 used here. For example, the dipping device 20 includes a dipping tank that is a part where the photosensitive layer coating solution is stored and the conductive support 1 is dipped, and a circulation mechanism that circulates the photosensitive layer coating solution. The photosensitive layer coating solution stored in the immersion tank is supplied from the coating solution supply port to the immersion tank and overflows from the upper part thereof. The overflowed photosensitive layer coating solution is received by the tray and sent to the coating solution tank. In the coating solution tank, the photosensitive layer coating solution is adjusted and stirred, and then sent again to the immersion layer by a supply pump.

感光層塗布液は、電荷発生物質、電荷輸送物質、結着樹脂及び塗布溶媒を混合して形成される。ここで、電荷発生物質、結着樹脂及び塗布溶媒からなる電荷発生層用の塗布液と、電荷輸送物質、結剤樹脂及び塗布溶媒からなる電荷輸送層用の塗布液とは別々に混合してなる。   The photosensitive layer coating solution is formed by mixing a charge generation material, a charge transport material, a binder resin, and a coating solvent. Here, the charge generation layer coating solution composed of the charge generation material, the binder resin and the coating solvent and the charge transport layer coating solution composed of the charge transport material, the binder resin and the coating solvent are mixed separately. Become.

電荷発生物質としては、スーダンレッド、ダイアンブルー、ジエナスグリーンB等のアゾ顔料、ジスアゾ顔料、アルゴールイエロー、ピレンキノン等のキノン顔料、キノシアニン顔料、ペリレン顔料、インジゴ顔料、インドフアーストオレンジトナー等のビスベンゾイミダゾール顔料、銅フタロシアニン等のフタロシアニン顔料、キナクリドン顔料、ピリリウム塩、アズレニウム塩が挙げられる。   Examples of charge generating materials include azo pigments such as Sudan Red, Diane Blue, and Dienas Green B, quinone pigments such as disazo pigments, algor yellow, and pyrenequinone, quinocyanine pigments, perylene pigments, indigo pigments, and bis such as Indian First Orange toner. Examples thereof include benzimidazole pigments, phthalocyanine pigments such as copper phthalocyanine, quinacridone pigments, pyrylium salts, and azulenium salts.

電荷輸送物質としては、主鎖または側鎖にアントラセン、ピレン、フエナントレン、コロネン等の多芳香族化合物またはインドール、カルバゾール、オキサゾール、イソオキサゾール、チアゾール、イミダゾール、ピラゾール、オキサジアゾール、ピラゾリン、チアジアゾール、トリアゾール等の含窒素環式化合物の骨格を有する化合物、その他、ヒドラゾン化合物など正孔輸送物質が挙げられる。   Charge transport materials include polyaromatic compounds such as anthracene, pyrene, phenanthrene and coronene in the main chain or side chain or indole, carbazole, oxazole, isoxazole, thiazole, imidazole, pyrazole, oxadiazole, pyrazoline, thiadiazole, triazole Examples thereof include compounds having a skeleton of a nitrogen-containing cyclic compound such as, and hole transport materials such as hydrazone compounds.

感光塗膜を形成するための結着樹脂としては、ポリカーボネート、ポリアリレート、ポリスチレン、ポリメタクリル酸エステル類、スチレン−メタクリル酸メチルコポリマー、ポリエステル、スチレン−アクリロニトリルコポリマー、ポリサルホン等、ポリ酢酸ビニル、ポリアクリロニトリル、ポリビニルブチラール、ポリビニルピロリドン、メチルセルロース、ヒドロキシメチルセルロース、セルロースエステル類などが挙げられる。   Examples of the binder resin for forming the photosensitive coating film include polycarbonate, polyarylate, polystyrene, polymethacrylic acid esters, styrene-methyl methacrylate copolymer, polyester, styrene-acrylonitrile copolymer, polysulfone, etc., polyvinyl acetate, polyacrylonitrile. , Polyvinyl butyral, polyvinyl pyrrolidone, methyl cellulose, hydroxymethyl cellulose, cellulose esters and the like.

溶媒としては、揮発性が高く、かつ、その蒸気の密度が空気よりも大きい溶剤が好適に用いられ、例えば、n−ブチルアミン、ジエチルアミン、エチレンジアミン、イソプロパノールアミン、トリエタノールアミン、N,N−ジメチルホルムアミド、アセトン、メチルエチルケトン、シクロヘキサノン、ベンゼン、4−メトキシ−4−メチルペンタノン−2、ジメトキシメタン、ジメトキシエタン、2,4−ペンタジオン、アニソール、3−オキソブタン酸メチル、モノクロルベンゼン、トルエン、キシレン、クロロホルム、1,2−ジクロロエタン、ジクロロメタン、テトラヒドロフラン、ジオキサン、メタノール、エタノール、イソプロパノール、酢酸エチル、酢酸ブチル、ジメチルスルホキシド、メチルセルソルブ、エチルセルソルブ、メチルセルソルブアセテート等が挙げられる。   As the solvent, a solvent having high volatility and a vapor density higher than that of air is preferably used. For example, n-butylamine, diethylamine, ethylenediamine, isopropanolamine, triethanolamine, N, N-dimethylformamide , Acetone, methyl ethyl ketone, cyclohexanone, benzene, 4-methoxy-4-methylpentanone-2, dimethoxymethane, dimethoxyethane, 2,4-pentadione, anisole, methyl 3-oxobutanoate, monochlorobenzene, toluene, xylene, chloroform, 1,2-dichloroethane, dichloromethane, tetrahydrofuran, dioxane, methanol, ethanol, isopropanol, ethyl acetate, butyl acetate, dimethyl sulfoxide, methyl cellosolve, ethyl cellosolve Methyl cellosolve acetate, and the like.

感光層塗布液中の各成分の濃度は、公知の方法に従って適宜選択される。そして、固形分の濃度は、主として、形成すべき層の膜厚に応じて決定されるが、単層型電子写真感光体を製造する際の塗布液の場合および積層型電子写真感光体を製造する際の電荷輸送層用の感光層塗布液の場合には、40質量%以下、好ましくは10質量%〜35質量%に調整される。また、これらの塗布液の場合、その粘度は、50cps〜300cps、好ましくは70cps〜250cps、乾燥膜厚は、15μm〜40μmとするのがよい。   The concentration of each component in the photosensitive layer coating solution is appropriately selected according to a known method. The concentration of the solid content is mainly determined according to the film thickness of the layer to be formed. In the case of a coating solution for producing a single-layer type electrophotographic photosensitive member, a laminated type electrophotographic photosensitive member is produced. In the case of the photosensitive layer coating solution for the charge transport layer, the amount is adjusted to 40% by mass or less, preferably 10% to 35% by mass. In the case of these coating solutions, the viscosity is 50 cps to 300 cps, preferably 70 cps to 250 cps, and the dry film thickness is 15 μm to 40 μm.

図1に戻って端部拭き取り工程S2について説明する。端部拭き取り工程S2は、上記浸漬塗布工程S1で塗布された感光層塗布液のうち導電性支持体1の端部に付着した感光層塗布液を拭き取る工程である。図5に説明図を示した。   Returning to FIG. 1, the edge wiping step S2 will be described. The edge wiping step S2 is a step of wiping off the photosensitive layer coating solution adhering to the end of the conductive support 1 from the photosensitive layer coating solution applied in the dip coating step S1. FIG. 5 shows an explanatory diagram.

端部拭き取り工程S2では、図5からわかるように、端部拭き取り装置30に導電性支持体1の端部を挿入し、ここに備えられるブラシ40により当該端部の感光層塗布液を除去する。   In the end wiping step S2, as can be seen from FIG. 5, the end of the conductive support 1 is inserted into the end wiping device 30, and the photosensitive layer coating solution at the end is removed by the brush 40 provided therein. .

端部拭き取り装置30は、基台31を備え、該基台31の上面にガイド32が立設されている。また基台31の上面には、導電性支持体1の端部形状に合わせて溝33が形成されており、その内側にブラシ40が配置されている。すなわち、感光層塗布液が塗布された導電性支持体1は、その筒状である内側にガイド32を挿入することにより、導電性支持体1の位置決めが行われ、端部が溝33内に入り、ブラシ40の回転により端部の感光層塗布液を拭き取ることができる。
ここで、拭き取り装置30は、導電性支持体1が差し込まれるに先立って、拭き取り液槽中に浸漬され、該液中で回転しながらブラシ40が洗浄されつつ、該ブラシ40が拭き取り液を含んだ状態とされている。
The end wiping device 30 includes a base 31, and a guide 32 is erected on the upper surface of the base 31. A groove 33 is formed on the upper surface of the base 31 according to the shape of the end of the conductive support 1, and the brush 40 is disposed on the inside thereof. That is, the conductive support 1 coated with the photosensitive layer coating solution is positioned by inserting the guide 32 inside the cylindrical inside thereof, and the end portion is in the groove 33. Then, the photosensitive layer coating solution at the end can be wiped off by the rotation of the brush 40.
Here, the wiping device 30 is immersed in a wiping liquid tank before the conductive support 1 is inserted, and the brush 40 contains the wiping liquid while being cleaned in the liquid while rotating in the liquid. It is supposed to be in a state.

以下、ブラシ40についてさらに詳しく説明する。図6にブラシ40を示した。図6(a)は、ブラシ40の斜視図、図6(b)は、ブラシ40の平面図、図6(c)は、図6(b)のVIc-VIc断面図である。ただし、図6(c)では、見易さのため、図6(b)に比べて拡大して示している。
ブラシ40は、長さTの円筒状であるリング41、及びリング41の内周面からリング41のリング中心軸に向かって延在する複数のブラシ毛42a、42a、…(図6(c)参照)から構成されるブラシ毛群42を備えている。図では、一本一本の各ブラシ毛42a、42a、…を表すことはできないので、ブラシ毛群42として示す。
Hereinafter, the brush 40 will be described in more detail. FIG. 6 shows the brush 40. 6A is a perspective view of the brush 40, FIG. 6B is a plan view of the brush 40, and FIG. 6C is a sectional view taken along VIc-VIc in FIG. 6B. However, in FIG. 6C, it is shown in an enlarged manner as compared with FIG.
The brush 40 has a cylindrical ring 41 having a length T, and a plurality of brush bristles 42a, 42a extending from the inner peripheral surface of the ring 41 toward the ring central axis of the ring 41 (FIG. 6C). The brush bristle group 42 is configured. In the figure, each brush hair 42a, 42a,... Cannot be represented one by one, and is shown as a brush hair group 42.

リング41は、長さTを有する円筒状の部材である。リング41の材質は特に限定されるものではないが、所定の剛性、強度を有していることが好ましいことから金属であることが好ましい。その中でも防錆性、洗浄性の観点からステンレス鋼であることがさらに好ましい。   The ring 41 is a cylindrical member having a length T. The material of the ring 41 is not particularly limited, but is preferably a metal because it preferably has predetermined rigidity and strength. Among these, stainless steel is more preferable from the viewpoint of rust prevention and cleanability.

ブラシ毛群42は、リング41の内周面から該リング41の中心軸に向けて設けられた長さL、線径d(図7参照)であるブラシ毛42a、42a、…の集合である。ブラシ毛42a、42a、…の長さLは、リング41の内側半径より短いので、図6(a)、図6(b)からわかるように、ブラシ毛群42もリング状となる。また、図6(c)に表れるように、ブラシ毛群42の厚さ(リング41の軸線に平行である方向の長さ)はtである。
ブラシ毛42a、42a、…は後述する式(1)を満たすことができる材料であれば特に限定されるものではないが、洗浄性や導電性支持体1へ傷を付け難いとの観点から、樹脂性であることが好ましい。その中でも入手し易さや性能の観点からナイロン、ポリブチレンテレフタレート(PBT)、ポリプロピレン等を用いることができる。
The bristle group 42 is a set of brush bristles 42a, 42a,... Having a length L and a wire diameter d (see FIG. 7) provided from the inner peripheral surface of the ring 41 toward the central axis of the ring 41. . Since the length L of the brush hairs 42a, 42a,... Is shorter than the inner radius of the ring 41, the brush hair group 42 also has a ring shape as can be seen from FIGS. 6 (a) and 6 (b). As shown in FIG. 6C, the thickness of the bristle group 42 (the length in the direction parallel to the axis of the ring 41) is t.
The brush hairs 42a, 42a,... Are not particularly limited as long as the material can satisfy the formula (1) described later, but from the viewpoint that it is difficult to damage the cleaning property and the conductive support 1, It is preferable that it is resinous. Among these, nylon, polybutylene terephthalate (PBT), polypropylene and the like can be used from the viewpoint of availability and performance.

さらにブラシ40は、拭き取られる導電性感光体1との関係で次の式(1)を満たす。   Further, the brush 40 satisfies the following expression (1) in relation to the conductive photoreceptor 1 to be wiped off.

Figure 2011145404
Figure 2011145404

ここで、Eはブラシ毛42aの縦弾性係数(kg/mm)、Iはブラシ毛42aの断面二次モーメント(mm)、σはt/Tで表わされるブラシ毛群42の密集度(tは上記したブラシ毛群42の厚さ(mm)、Tは上記したリング41の長さ(mm)である。)、Lは上記したブラシ毛群42の長さ(mm)、yはブラシ毛群42と導電性感光体外周面との接触代(mm)を表わす。さらに詳しく、断面二次モーメントI(mm)と、接触代y(mm)について説明する。 Here, E is the longitudinal elastic modulus (kg / mm 2 ) of the bristle 42a, I is the cross-sectional secondary moment (mm 4 ) of the bristle 42a, and σ is the density of the bristle group 42 expressed by t / T ( t is the thickness (mm) of the brush bristle group 42, T is the length (mm) of the ring 41, L is the length (mm) of the brush bristle group 42, and y is the brush. The contact allowance (mm) between the bristle group 42 and the outer peripheral surface of the conductive photoconductor is shown. More specifically, the cross-sectional secondary moment I (mm 4 ) and the contact allowance y (mm) will be described.

断面二次モーメントI(mm)は、上記したリング41の長さT(mm)と、ブラシ毛42aの線径d(mm)を用いて、式(2)により求められる。図7に説明図を示した。 The cross-sectional secondary moment I (mm 4 ) is obtained by the equation (2) using the length T (mm) of the ring 41 and the wire diameter d (mm) of the brush bristles 42a. FIG. 7 is an explanatory diagram.

Figure 2011145404
Figure 2011145404

図6(c)に相当する図である図7(a)に示したように、リングの内面の全長(すなわち長さT)に亘ってブラシ毛群が配置されていると仮定する(T=t)。このとき、図7(b)の斜視図で示したように、リングの長さTに沿ったブラシ毛1列に注目する。導電性支持体をブラシの内側に差し込み、ブラシを回転させたときの該ブラシの変形を考える(図8(a)参照)と、当該ブラシ毛1列を1つの単位とし、図7(b)にBで示した方向からみた断面の断面二次モーメントを考慮することがよい。従って、図7(c)で示した矩形断面の断面二次モーメントが式(2)により表される。   As shown in FIG. 7A, which is a view corresponding to FIG. 6C, it is assumed that the bristle group is arranged over the entire length (ie, length T) of the inner surface of the ring (T = t). At this time, as shown in the perspective view of FIG. 7B, attention is paid to one row of brush hairs along the length T of the ring. Considering the deformation of the brush when the conductive support is inserted inside the brush and the brush is rotated (see FIG. 8A), one row of the bristle is taken as one unit, and FIG. It is preferable to consider the cross-sectional second moment of the cross section viewed from the direction indicated by B in FIG. Therefore, the cross-sectional second moment of the rectangular cross section shown in FIG. 7C is expressed by the equation (2).

一方、接触代y(mm)は、図8に説明図を示した。ブラシ40はその性質上、図8(a)に示したように、導電性支持体1をブラシ40の内側に差し込み、該ブラシ40を回転させると、ブラシ毛42a、42a、…の先端が導電性支持体1の表面に接触する。yはその接触する量を表わしている。具体的には図8(b)からわかるように、ブラシ毛42aの長さL(mm)から、リング41の内面と導電性支持体1の外面との距離(図8(b)のx(mm))を引いた大きさがy(mm)となる。   On the other hand, the contact allowance y (mm) is shown in FIG. Because of the nature of the brush 40, as shown in FIG. 8A, when the conductive support 1 is inserted inside the brush 40 and the brush 40 is rotated, the tips of the brush hairs 42a, 42a,. The surface of the conductive support 1 is contacted. y represents the amount of contact. Specifically, as can be seen from FIG. 8B, from the length L (mm) of the brush bristles 42a, the distance between the inner surface of the ring 41 and the outer surface of the conductive support 1 (x ( The size obtained by subtracting mm)) is y (mm).

次に、上記式(1)に含まれる次式(3)の導出について説明する。   Next, derivation of the following equation (3) included in the above equation (1) will be described.

Figure 2011145404
Figure 2011145404

式(3)は、ブラシ毛にかかる荷重を求めることにより導出できる。詳しくは次の通りである。図8(b)に示したように、導電性支持体1をブラシ40の内側に差し込み、該ブラシ40を回転させたときのたわみν(mm)は、ここにかかる荷重をw(kg)とすると、断面二次モーメントを用いて、式(4)で表すことができる。   Equation (3) can be derived by determining the load on the brush hair. Details are as follows. As shown in FIG. 8B, the deflection ν (mm) when the conductive support 1 is inserted into the brush 40 and the brush 40 is rotated is expressed as w (kg). Then, it can represent by Formula (4) using a cross-sectional secondary moment.

Figure 2011145404
Figure 2011145404

一方、図8(b)からたわみν(mm)は概ね式(5)で表すことができる。   On the other hand, from FIG. 8B, the deflection ν (mm) can be approximately expressed by the equation (5).

Figure 2011145404
Figure 2011145404

式(4)、式(5)から荷重w(kg)を求めると式(6)を得る。   When the load w (kg) is obtained from the equations (4) and (5), the equation (6) is obtained.

Figure 2011145404
Figure 2011145404

ここで、断面二次モーメントI(mm)は上記のようにT=tとして算出しているので、実際のブラシ毛の密集度を反映するために、σ(=t/T)を乗じて上記式(3)を導くことができる。 Here, since the cross-sectional secondary moment I (mm 4 ) is calculated as T = t as described above, it is multiplied by σ (= t / T) in order to reflect the actual density of the bristle. The above formula (3) can be derived.

そして、式(1)からわかるように、式(3)の下限を2×10−4(kg)、上限を4×10−4(kg)とするものである。好ましくは下限は2.5×10−4(kg)、上限は3.5×10−4(kg)である。 As can be seen from the equation (1), the lower limit of the equation (3) is 2 × 10 −4 (kg), and the upper limit is 4 × 10 −4 (kg). Preferably, the lower limit is 2.5 × 10 −4 (kg), and the upper limit is 3.5 × 10 −4 (kg).

以上のような条件を具備する端部拭き取り工程S2によれば、導電性支持体1の端部拭き取りに際し、感光体塗布液を適切に除去しつつ、導電性支持体1への傷つきを抑制し、ブラシ毛42a、42a、…の寿命向上、及びブラシ群42の洗浄後の異物残留も抑制することが可能となる。   According to the edge wiping step S2 having the above-described conditions, when wiping the edge of the conductive support 1, the photosensitive support liquid is appropriately removed and the damage to the conductive support 1 is suppressed. It is possible to improve the life of the brush bristles 42a, 42a,... And to prevent residual foreign matter after the brush group 42 is cleaned.

図1に戻って表面乾燥工程S3について説明する。表面乾燥工程S3は、導電性支持体1、1、…の表面に塗布された感光層塗布液を乾燥させる工程である。表面乾燥工程S3では、必要かつ充分な乾燥が行われるように乾燥の温度と時間を調整すると良い。乾燥時温度としては通常、100℃〜250℃、好ましくは110℃〜170℃、さらに好ましくは120℃〜140℃の範囲である。ここで乾燥時の温度とは塗布された感光体の乾燥時の表面温度をいう。低沸点の溶剤の沸点との温度差が小さければ乾燥には比較的長時間を要するが、感光層中の有効成分が分解・変質する恐れが小さい。乾燥条件としては1段階で乾燥させる他、例えば2段階で乾燥させる方法もとることができる。この場合、1段目の乾燥温度は50℃〜150℃、好ましくは70℃〜120℃、2段目の乾燥温度は1段目より高い温度で通常、100℃〜250℃、好ましくは110℃〜170℃、さらに好ましくは120℃〜140℃であって必要かつ充分な乾燥が行われるように乾燥時間を調整すると良い。2段乾燥などの乾燥温度を途中で変更する場合は、乾燥中の最高温度を基準として、該最高温度より沸点の高い溶剤と低い溶剤を選択する。
乾燥手段としては、熱風乾燥器、蒸気乾燥器、赤外線乾燥器及び遠赤外線乾燥器等を用いることができる。
Returning to FIG. 1, the surface drying step S3 will be described. The surface drying step S3 is a step of drying the photosensitive layer coating solution coated on the surfaces of the conductive supports 1, 1,. In the surface drying step S3, the drying temperature and time may be adjusted so that necessary and sufficient drying is performed. The drying temperature is usually 100 ° C to 250 ° C, preferably 110 ° C to 170 ° C, more preferably 120 ° C to 140 ° C. Here, the temperature during drying refers to the surface temperature during drying of the coated photoreceptor. If the temperature difference from the boiling point of the low-boiling solvent is small, drying takes a relatively long time, but there is little possibility that the active components in the photosensitive layer will be decomposed or altered. As drying conditions, in addition to drying in one stage, for example, a method of drying in two stages can be used. In this case, the drying temperature of the first stage is 50 ° C. to 150 ° C., preferably 70 ° C. to 120 ° C., and the drying temperature of the second stage is higher than the first stage, usually 100 ° C. to 250 ° C., preferably 110 ° C. It is preferable to adjust the drying time so that necessary and sufficient drying is performed at ˜170 ° C., more preferably at 120 ° C. to 140 ° C. When changing the drying temperature, such as two-stage drying, on the basis of the maximum temperature during drying, a solvent having a higher boiling point and a lower solvent than the maximum temperature are selected.
As a drying means, a hot air dryer, a steam dryer, an infrared dryer, a far infrared dryer, or the like can be used.

以下、実施例を示して本発明をさらに詳しく説明する。実施例では、式(3)に含まれる条件を変更し、式(3)を計算し、式(1)が成立するかについて判断するとともに、その条件で、導電性支持体の端部拭き取りをおこなった結果を調べた。表1に条件、及び結果を示した。表1で「式(1)の成立判断」では、式(1)が成立する場合を「○」とし、成立しない場合を「×」とした。また、「拭き取り状況」は、端部拭き取り後の導電性支持体の表面を目視し、表面の傷、及び拭き取り残しが全く観察されなかった場合を「◎」、表面に傷がなく、殆どの感光層塗布液が拭き取られていた場合を「○」、表面に傷があるか又は許容範囲を超える拭き残しがあった場合を「×」とした。   Hereinafter, the present invention will be described in more detail with reference to examples. In the embodiment, the condition included in the expression (3) is changed, the expression (3) is calculated, and it is determined whether the expression (1) is satisfied, and the end wiping of the conductive support is performed under the condition. We investigated the results. Table 1 shows the conditions and results. In Table 1, “Establishment of Formula (1)” is defined as “◯” when Formula (1) is met, and “X” when not established. In addition, the “wiping status” is “◎” when the surface of the conductive support after wiping the edge was visually observed and no scratches on the surface and no wiping residue were observed. The case where the photosensitive layer coating solution was wiped off was indicated as “◯”, and the case where there was a scratch on the surface or there was a remaining wiping exceeding the allowable range was indicated as “X”.

Figure 2011145404
Figure 2011145404

表1からわかるように、式(1)が成立する条件では拭き取り状況も良好であり、式(1)が成立しない条件では拭き取りの結果に問題がある結果となった。その中でも、2.5×10−4(kg)以上、3.5×10−4(kg)以下では特に良好であった。 As can be seen from Table 1, the wiping condition is also good under the condition where the expression (1) is satisfied, and the wiping result is problematic under the condition where the expression (1) is not satisfied. Among them, it was particularly good at 2.5 × 10 −4 (kg) or more and 3.5 × 10 −4 (kg) or less.

以上、現時点において実践的であり、かつ好ましいと思われる実施形態に関連して本発明を説明したが、本発明は、本願明細書中に開示された実施形態に限定されるものではなく、特許請求の範囲及び明細書全体から読み取れる発明の要旨あるいは思想に反しない範囲で適宜変更可能であり、そのような変更を伴う電子写真感光体の製造方法もまた本発明の技術的範囲に包含されるものとして理解されなければならない。   Although the present invention has been described with reference to embodiments that are presently practical and preferred, the present invention is not limited to the embodiments disclosed herein, Changes can be made as appropriate without departing from the spirit or concept of the invention that can be read from the claims and the entire specification, and a method of manufacturing an electrophotographic photosensitive member involving such changes is also included in the technical scope of the present invention. It must be understood as a thing.

1 導電性支持体
10 搬送装置
11 アーム
12 基体
13 ピッカー
14 軸
15、16 風船体
17 ガイド部材
20 浸漬塗布装置
30 端部拭き取り装置
31 基台
32 ガイド
33 溝
40 ブラシ
41 リング
42 ブラシ毛群
42a ブラシ毛
DESCRIPTION OF SYMBOLS 1 Conductive support body 10 Conveyance apparatus 11 Arm 12 Base body 13 Picker 14 Shaft 15 and 16 Balloon body 17 Guide member 20 Immersion coating apparatus 30 End wiping apparatus 31 Base 32 Guide 33 Groove 40 Brush 41 Ring 42 Brush hair group 42a Brush hair

Claims (2)

円筒状の導電性支持体に感光層塗布液を塗布、乾燥させて電子写真感光体を製造する方法であって、
前記導電性支持体に前記感光層塗布液を塗布した後、前記導電性支持体の外周面の端部に付着した前記感光層塗布液をブラシで拭き取る工程を有し、
前記ブラシは、長さT(mm)の円筒状であるリングと、該リングの内周面からリングの中心軸に向かうように立設した長さL(mm)、直径d(mm)の複数のブラシ毛からなるブラシ毛群と、を備え、
前記ブラシ毛群の、前記リングの軸線に平行な方向の厚さをt(mm)、前記ブラシ毛の断面二次モーメントI(mm)を、
Figure 2011145404
とし、前記ブラシ毛の縦弾性係数をE(kg/mm)、及び前記ブラシ毛と前記導電性支持体の外周面との接触代をy(mm)、前記ブラシ毛群の密集度を、
Figure 2011145404
で表わすと、
Figure 2011145404
が成立することを特徴とする電子写真感光体の製造方法。
A method for producing an electrophotographic photosensitive member by applying a photosensitive layer coating solution to a cylindrical conductive support and drying it,
After applying the photosensitive layer coating solution to the conductive support, the step of wiping the photosensitive layer coating solution adhering to the end of the outer peripheral surface of the conductive support with a brush,
The brush is a cylindrical ring having a length T (mm), and a plurality of lengths L (mm) and diameters d (mm) erected from the inner peripheral surface of the ring toward the center axis of the ring. A group of brush bristles made up of
The thickness of the bristle group in the direction parallel to the axis of the ring is t (mm), and the cross-sectional secondary moment I (mm 4 ) of the bristle is
Figure 2011145404
And the longitudinal elastic modulus of the bristle is E (kg / mm 2 ), the contact margin between the bristle and the outer peripheral surface of the conductive support is y (mm), and the density of the bristle group is
Figure 2011145404
In terms of
Figure 2011145404
A method for producing an electrophotographic photosensitive member, wherein:
円筒状の導電性支持体に感光層塗布液を塗布、乾燥させて電子写真感光体を製造する方法であって、
前記導電性支持体に前記感光層塗布液を塗布した後、前記導電性支持体の外周面の端部に付着した前記感光層塗布液をブラシで拭き取る工程を有し、
前記ブラシは、長さT(mm)の円筒状であるリングと、該リングの内周面からリングの中心軸に向かうように立設した長さL(mm)、直径d(mm)の複数のブラシ毛からなるブラシ毛群と、を備え、
前記ブラシ毛群の、前記リングの軸線に平行な方向の厚さをt(mm)、前記ブラシ毛の断面二次モーメントI(mm)を、
Figure 2011145404
とし、前記ブラシ毛の縦弾性係数をE(kg/mm)、及び前記ブラシ毛と前記導電性支持体の外周面との接触代をy(mm)、前記ブラシ毛群の密集度を、
Figure 2011145404
で表わすと、
Figure 2011145404
が成立することを特徴とする電子写真感光体の製造方法。
A method for producing an electrophotographic photosensitive member by applying a photosensitive layer coating solution to a cylindrical conductive support and drying it,
After applying the photosensitive layer coating solution to the conductive support, the step of wiping the photosensitive layer coating solution adhering to the end of the outer peripheral surface of the conductive support with a brush,
The brush is a cylindrical ring having a length T (mm), and a plurality of lengths L (mm) and diameters d (mm) erected from the inner peripheral surface of the ring toward the center axis of the ring. A group of brush bristles made up of
The thickness of the bristle group in the direction parallel to the axis of the ring is t (mm), and the cross-sectional secondary moment I (mm 4 ) of the bristle is
Figure 2011145404
And the longitudinal elastic modulus of the bristle is E (kg / mm 2 ), the contact margin between the bristle and the outer peripheral surface of the conductive support is y (mm), and the density of the bristle group is
Figure 2011145404
In terms of
Figure 2011145404
A method for producing an electrophotographic photosensitive member, wherein:
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6097361A (en) * 1983-11-01 1985-05-31 Canon Inc Apparatus for producing electrophotographic sensitive body
JPH09152725A (en) * 1995-11-29 1997-06-10 Mitsubishi Chem Corp Film remover for manufacturing electrophotographic photoreceptor
JP2004295062A (en) * 2002-05-10 2004-10-21 Ricoh Co Ltd Method and apparatus for washing substrate for electrophotographic photoreceptor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6097361A (en) * 1983-11-01 1985-05-31 Canon Inc Apparatus for producing electrophotographic sensitive body
JPH09152725A (en) * 1995-11-29 1997-06-10 Mitsubishi Chem Corp Film remover for manufacturing electrophotographic photoreceptor
JP2004295062A (en) * 2002-05-10 2004-10-21 Ricoh Co Ltd Method and apparatus for washing substrate for electrophotographic photoreceptor

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