JP2011131117A - Microbubble concentrator, microbubble generating apparatus, method of concentrating microbubble and method of generating microbubble - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To obtain a liquid in which microbubbles of desired diameters are concentrated. <P>SOLUTION: A microbubble generating apparatus includes a microbubble generator 2 generating a bubble liquid containing bubbles of various diameters including microbubbles and a microbubble concentrator 3 to which the bubble liquid is supplied. The microbubble concentrator 3 includes a primary concentrator 6 removing a bubble liquid containing large-diameter bubbles from the bubble liquid containing bubbles of various diameters including microbubbles and a secondary concentrator 7 causing the bubble liquid passing through the primary concentrator 6 to flow through a spiral passage 5 and taking out a bubble liquid which passes through the outer portion of the spiral passage 5 in the radial direction. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a microbubble concentrating device for concentrating microbubbles having a desired diameter from a bubble liquid containing bubbles having various diameters including microbubbles, a microbubble generating device using the concentrating device, and a concentration method and generation thereof. Regarding the method.

  A microbubble is a fine bubble of several μm to several tens of μm (or several hundred μm), has a large bubble surface area per unit volume, and a small buoyancy, so it has excellent followability to flow and adsorbs fine dust. It has excellent physical and chemical properties such as being able to float on the water surface and increasing the amount of dissolved oxygen in fresh water or seawater. For this reason, it has been successful in aquaculture of seafood such as oysters and scallops, applied to environmental fields such as sewage treatment and removal of microorganisms, manufacture of clean water and ozone water, cleaning of semiconductors, reducing ship resistance Applications are expected in a wide range such as application to biotechnology, biotechnology and medical field.

As an apparatus for generating the microbubbles, for example, there are methods described in Patent Documents 1 to 3.
The apparatus described in Patent Document 1 includes a container body having a bottomed cylindrical space, a pressurized liquid inlet opening in a tangential direction in a part of the inner wall circumferential surface of the space, and the cylindrical space. It is a swirl type fine bubble generator composed of a gas introduction hole opened at the bottom and a swirl gas-liquid mixture outlet opened at the tip of the cylindrical space.

  An apparatus described in Patent Document 2 includes a liquid introduction unit that introduces a liquid, a gas introduction unit that mixes a gas into the introduced liquid, a microbubble generation unit that generates a large number of microbubbles from the mixed gas, and a generation And the liquid contains a surfactant, while suppressing the coalescence of a large number of microbubbles generated in the microbubble generator by the action of the surfactant. This is a venturi-type microbubble generator that discharges the microbubbles.

  In the apparatus described in Patent Document 3, water pumped up by a pressure pump or the like is placed in a tank for pressurization, and this oxygen is dissolved in water in a pressurized state by supplying pressurized oxygen into the tank. This is an apparatus by a pressurized oxygen dissolution method in which the dissolved oxygen is made into fine bubbles by releasing water into the atmosphere, and the oxygen in the bubbles is dissolved in water by suspending the fine bubbles in water.

International Publication No. 00/69550 Pamphlet Japanese Patent Laid-Open No. 2003-230824 JP-A-11-207162

As described above, many methods for generating microbubbles are known, but the diameter distribution of bubbles is wide, for example, about 5 to 50 μm in the swivel type, about 50 to 300 μm in the Venturi type, and nanobubbles and millibubbles. In many cases. A method for obtaining only microbubbles having a desired diameter from these bubbles is not known.
Since microbubbles have a significant surface potential with the same polarity, they do not fuse with each other due to electrical repulsion, but large bubbles are unfavorable because they have a surface potential of zero and come into contact with microbubbles and absorb. . Nanobubbles are said to be significantly different in nature from microbubbles and are not suitable for use utilizing the characteristics of microbubbles.

The range of microbubbles is said to be about 10 to 100 μm in diameter, but large microbubbles have a feature of long life, but the bubble internal pressure is small. On the other hand, small microbubbles have a short life but high internal pressure and a large self-pressurizing effect. Therefore, if microbubbles having a desired diameter are obtained according to the application, the effect is remarkably improved.
Therefore, a method / apparatus for obtaining microbubbles, particularly liquids enriched with microbubbles having a desired diameter, from a liquid containing bubbles having a diameter distribution wider than that of microbubbles is desired. Moreover, since the lifetime from the generation of microbubbles until the diameter is reduced and disappears is said to be several minutes at the longest, the operation needs to be completed within a few seconds.

  The present invention has been made in view of such circumstances, and an object thereof is to obtain a liquid in which microbubbles having a desired diameter are concentrated.

  As a result of studying the fact that the moving speed of the bubble when the buoyancy and the centrifugal force or the gravity are balanced is proportional to the square of the diameter of the bubble according to the Stokes formula, It has been found that a device for obtaining microbubbles of a typical gas-liquid combination can be manufactured industrially as follows and can be operated under practical conditions.

That is, the microbubble concentrating device of the present invention has a spiral flow path for circulating bubble liquid containing bubbles of various diameters including microbubbles, and a predetermined radial direction in the flow path at the outlet of the spiral flow path. It has the extraction flow path which branches from a position and fractionates the said bubble liquid, It is characterized by the above-mentioned.
Further, the microbubble concentration method distributes bubble liquid containing bubbles of various diameters including microbubbles to the spiral flow path, and removes a part of the bubble liquid from a predetermined position in the radial direction of the spiral flow path. It is characterized by sorting.

  When a liquid containing bubbles with a diameter distribution including microbubbles is flowed in a field where gravity force or centrifugal force is dominant, the bubbles with large diameter move relatively large along the force balance direction. Bubbles have a relatively small moving speed, so that the bubbles are distributed from a large diameter to a small diameter as time passes. Therefore, the bubble liquid is collected at a position where microbubbles having a desired diameter are accumulated.

In the microbubble concentrator of the present invention, the predetermined position in the radial direction may be an intermediate position excluding the inner part and the outer part in the radial direction in the flow path.
A bubble liquid in which microbubbles having an intermediate diameter are concentrated except for microbubbles with a large diameter and microbubbles with a small diameter by separating from an intermediate position excluding the inside and outside in the radial direction of the spiral channel. Can be obtained.

The microbubble concentrator of the present invention includes a primary concentrator that removes bubble liquid containing large diameter bubbles from bubble liquid containing bubbles of various diameters including microbubbles, and a bubble liquid that passes through the primary concentrator. And a secondary concentrator for separating the bubble liquid passing through the radially outer portion of the spiral flow path.
Since large bubbles such as millibubbles come into contact with microbubbles and are absorbed and absorbed, first the large diameter bubbles are preferentially removed from the bubble liquid by the primary concentrator, and then the desired diameter is obtained in the secondary concentrator. The bubble liquid in which microbubbles are concentrated is collected.

In the microbubble concentrator of the present invention, the primary concentrator has a first spiral channel through which bubble liquid flows, and a radially outer portion in the channel at the outlet of the first spiral channel. In communication with the secondary concentrator.
The primary concentrator has a gas-liquid separation tank that regulates the liquid level with a liquid-repellent porous membrane and allows large-sized bubbles floating on the liquid surface to escape from the liquid-repellent porous membrane to the outside air. A flow path between the bottom of the tank and the liquid repellent porous membrane may communicate with the secondary concentrator.

The microbubble concentrating device of the present invention includes the microbubble concentrating device and a microbubble generating device that generates bubble liquid containing bubbles having various diameters including microbubbles and supplies the microbubble concentrating device to the microbubble concentrating device. A generation device is configured.
Further, the microbubble generating method of the present invention generates a bubble liquid containing bubbles having various diameters including microbubbles, and then circulates the bubble liquid through the spiral flow path, so that the radial direction of the spiral flow path A part of the bubble liquid is dispensed from a predetermined position.

  Furthermore, in the microbubble generating apparatus of the present invention, a raw material of the microbubble generating apparatus is recovered between the microbubble concentrating apparatus and the microbubble generating apparatus by collecting bubble liquid that has not been separated by the microbubble concentrating apparatus. It is preferable that a recovery flow path as a part of is provided. This is to use the bubble liquid efficiently.

  ADVANTAGE OF THE INVENTION According to this invention, the bubble liquid in which the microbubble of a desired diameter was concentrated with the spiral flow path from the bubble liquid containing the bubble of various diameters containing a microbubble can be fractionated.

BRIEF DESCRIPTION OF THE DRAWINGS It is a schematic block diagram which shows 1st Embodiment of the microbubble production | generation apparatus which concerns on this invention. It is an arrow line view which follows the AA line of FIG. It is sectional drawing of the spiral flow path of FIG. It is a schematic block diagram which shows 2nd Embodiment of the microbubble production | generation apparatus which concerns on this invention. It is an arrow line view which follows the BB line of FIG. It is a schematic block diagram which shows 3rd Embodiment of the microbubble production | generation apparatus which concerns on this invention. It is sectional drawing which follows the CC line of FIG.

Embodiments of a microbubble generating apparatus according to the present invention will be described below with reference to the drawings.
FIG. 1 to FIG. 3 show a first embodiment of the microbubble generator of this embodiment. The microbubble generator 1 of this embodiment includes a microbubble generator 2 and a generator as shown in FIG. The microbubble concentrator 3 concentrates the bubble liquid containing the microbubbles into the bubble liquid containing microbubbles having a desired diameter.

The microbubble generator 2 includes the above-described swirling microbubble generator, venturi tube microbubble generator, pressure dissolution type, static mixer type, ejector type, pore type, rotary type, ultrasonic type, steam Various types currently known, such as a condensation type and an electrolysis type, can be applied. Among them, the Venturi tube type and the pressure dissolution type are preferable because a high void ratio can be obtained even if the bubble diameter distribution range is wide.
The microbubble concentrating device 3 is provided so that spiral channels 4 and 5 having two different types of diameters are continuous, and includes a primary concentrator 6 having a large-diameter spiral channel 4 and a small-diameter spiral channel. The secondary concentrator 7 has a flow path 5.

The primary concentrator 6 has a spiral channel 4 having a start end 4a connected to the microbubble generator 2 and a terminal end separated into a position half the length of the channel in the longitudinal direction (spiral radial direction). A plate 8 is provided, and the flow path is bifurcated into an inner part and an outer part in the radial direction of the spiral by the separation plate 8, and the spiral channel 5 in the secondary concentrator 7 is divided into the outer half channel. The start end is connected.
In the example shown in FIGS. 1 and 2, the spiral flow path 5 of the secondary concentrator 7 is disposed at the radially inner position of the spiral flow path 4 of the primary concentrator 6, and both spiral flow paths 4, 5 are arranged. It is connected so that it may be folded at the connection part.

  And in the terminal part of the secondary concentrator 7, the separating plate 9 along the extension direction of a flow path as shown in FIG. 2 is provided in the position of the length of the longitudinal direction (radial direction of a spiral), The inside of the flow path is bifurcated into a spiral radial inner portion and an outer portion by the separation plate 9, and a bubble liquid extraction port 10 is formed in the inner half of the flow channel. The extraction flow path 11 corresponding to the application is connected.

  On the other hand, the flow path of the inner half of the spiral branched at the terminal end of the primary concentrator 6 and the flow path of the outer half of the spiral branched at the terminal end of the secondary concentrator 7 are the discharge ports 12 and 13, The recovery channels 14 and 15 are connected to each other, and the bubble liquid is recovered in the microbubble generator 2 and reused as a part of the raw material.

  In the microbubble generator 1 configured as described above, the microbubble generator 2 generates bubble liquid containing bubbles having various diameters including microbubbles, and the bubble liquid is converted into the primary concentrator 6 of the concentrator 3. To supply. In the primary concentrator 6, centrifugal force acts when the bubble liquid flows through the spiral flow path 4. According to the Stokes' formula, bubbles having a large moving speed along the force balance direction are relatively Since the large and small-sized bubbles are relatively small, the larger-sized bubbles move inwardly in the radial direction of the spiral while flowing through the spiral flow path 4. For this reason, bubbles are distributed from those having a large diameter to those having a small diameter from the inside to the outside in the radial direction of the spiral.

  Then, at the end of the spiral flow path 4 of the primary concentrator 6, the separation plate 8 separates the radially inner portion and the outer portion of the flow path, and only the bubble liquid that passes through the outer portion is the secondary concentrator. 7 is sent. Accordingly, the bubble liquid containing relatively small-diameter bubbles collected outside the spiral in the spiral flow path 4 of the primary concentrator 6 is sent to the secondary concentrator 7 and relatively collected inside the spiral in the radial direction. Bubble liquid containing large-diameter bubbles is returned to the microbubble generator 2 from the discharge port 12 through the recovery flow path 14.

  In the secondary concentrator 7, while the bubble liquid sent from the primary concentrator 6 flows through the spiral flow path 5, as in the case of the primary concentrator 6, large bubbles are generated along the radial direction of the spiral. The bubbles are distributed from those having a diameter toward those having a smaller diameter, and bubbles having a relatively large diameter gather on the radially inner side and bubbles having a relatively small diameter gather on the radially outer side.

  Then, at the end portion of the secondary concentrator 7, a bubble liquid containing relatively large-sized bubbles that are separated into a radially inner portion and an outer portion in the flow path by the separation plate 9 and pass through the inner portion. Only to the extraction channel 11 used for the intended application. Therefore, a bubble liquid containing small diameter bubbles is removed by removing the large diameter bubbles in the primary concentrator 6, and the smaller diameter bubbles are removed from the bubble liquid in the secondary concentrator 7, thereby generating a microbubble generator. Among the bubbles having various diameters generated in 2, the bubble liquid containing bubbles having a substantially intermediate diameter is collected. In addition, the bubble liquid containing relatively small-sized bubbles collected outside the spiral in the secondary concentrator 7 is returned from the discharge port 13 to the microbubble generator 2 through the recovery flow path 15.

  In this way, the bubble liquid generated by the microbubble generator 2 is circulated through the two concentrators 6 and 7, so that the bubble liquid containing bubbles having various diameters including microbubbles can be changed from a large diameter bubble and a small diameter. It is possible to remove the bubble liquid containing the bubbles and collect only the bubble liquid containing the bubbles having an intermediate diameter and provide it for the intended use. In this case, among the bubbles of various diameters generated in the microbubble generator 2, the large diameter bubbles come into contact with the microbubbles and are absorbed and absorbed, so by separating and removing the large diameter bubbles first, The disappearance of the microbubbles can be prevented, and the microbubbles can be sorted reliably and efficiently.

  By the way, the turbulence of the flow generated in the spiral flow paths 4 and 5 is harmful to the selection of bubbles. One of the causes of this flow disturbance is that the centrifugal force varies depending on the distance from the center of the helix. Therefore, when the axial direction of the helix is taken as the transverse direction, the vertical dimension of the channel cross section is 1 / h of the helix radius. It is preferable to make it 10 or less. Another cause of the disturbance of the flow is that the inner surface of the flow path is uneven or rough, resulting in flow resistance. Therefore, the inner surfaces of the spiral flow paths 4 and 5 can be smooth and mirror-finished. preferable. The third cause is unavoidable turbulence that occurs in the vicinity of the vertical side wall of the flow path. In order to reduce this effect, the aspect ratio of the cross-section of the spiral flow paths 4 and 5 is set to 1/5 or less. The flat cross-sectional shape shown in FIG.

  As an example of specific dimensions, in the microbubble concentrator 3 of the first embodiment, the spiral flow path 4 of the primary concentrator 6 has a spiral radius of, for example, 10 cm, and the cross section of the flow path is in the horizontal direction. It has a rectangular cross section with a length of 3 cm (spiral length direction) and a length of 0.5 cm in the vertical direction (radial direction of the spiral), and has a total length of 5 turns. And in the terminal part of the spiral flow path 4, the separation plate 8 is provided at a position half the length in the longitudinal direction (position of 0.25 cm).

  In the secondary concentrator 7, the spiral flow path 5 has a spiral radius of, for example, 5 cm, and the cross section of the flow path has a length of 2 cm in the horizontal direction (helical length direction) and a vertical direction (spiral). (Radial direction) is a rectangular cross section having a length of 0.4 cm, and has a total length of 52 turns, and the end of the secondary concentrator 7 has a half of its longitudinal length. The separation plate 9 is provided at the position (position of 0.2 cm).

  4 and 5 show a second embodiment of the present invention. In the microbubble generating device 21 of this embodiment, the primary concentrator 23 of the microbubble concentrating device 22 is not a spiral flow channel as in the first embodiment, but a gas-liquid separation tank 25 by a liquid repellent porous membrane 24. Used. The microbubble generator 2 is the same as that of the first embodiment, and other parts common to the first embodiment are denoted by the same reference numerals and the description thereof is simplified.

  In this second embodiment, the primary concentrator 23 has a liquid repellent porous membrane 24 in a tank 25 having a flat bottom surface 25a with a certain slight gap between the flat bottom surface 25a. A flat flow path 26 is formed between the liquid-repellent porous film 24 and the bottom surface 25 a of the tank 25. As the liquid repellent porous film 24, for example, a fluororesin porous hydrophobic film is used.

  The flow path 26 between the liquid repellent porous film 24 and the bottom surface 25a of the tank 25 has a length of 42 cm, a width of 20 cm, and a height of 0.5 cm, for example. The microbubble generator 2 is connected to one end 25 b of the gas-liquid separation tank 25 so as to communicate with the flow path 26, and the start end of the spiral flow path 5 of the secondary concentrator 7 is connected to the terminal end. ing. Although this secondary concentrator 7 has a slight difference in dimensions and the like, since it has substantially the same structure as the secondary concentrator 7 of the first embodiment, the same reference numerals are used.

In the secondary concentrator 7, the spiral flow path 5 has a spiral radius of, for example, 5 cm, and the cross section of the flow path has a length in the horizontal direction (helical length direction) of 2.5 cm and a vertical direction ( The length of the spiral (in the radial direction) is a rectangular cross section of 0.5 cm, and has a total length of 16 turns. The end portion of the secondary concentrator 7 is provided with a separation plate 9 extending along the direction of the flow path at a position half the length in the longitudinal direction (position of 0.25 cm). Is bifurcated into an inner portion and an outer portion in the radial direction of the spiral, and a bubble liquid outlet 10 is formed in the inner half of the flow path.
A bubble gas discharge port 27 that has passed through the liquid repellent porous membrane 24 is formed in the upper portion of the tank 25 of the primary concentrator 23, and together with the discharge port 13 at the end of the secondary concentrator 7, the microbubble generator 2 Are connected by recovery pipes 14 and 15.

  The microbubble generating device 21 of the second embodiment is configured such that bubble liquid containing bubbles having various diameters including the microbubbles generated by the microbubble generating device 2 flows through the flow path 26 of the primary concentrator 23. The large diameter bubbles pass through the liquid-repellent porous membrane 24 and are discharged to the bubble gas discharge port 27. The bubble liquid from which the large diameter bubbles have been removed flows through the secondary concentrator 7, and at the end portion thereof. The bubble liquid containing relatively small diameter bubbles is collected in the recovery pipe 15, and only the bubble liquid containing relatively large diameter bubbles is taken out to the outlet 10.

  6 and 7 show a third embodiment of the present invention. The microbubble generating device 31 of the third embodiment is different from the microbubble generating device 2 similar to that of each of the above embodiments, and the microbubble consisting of one spiral channel 32, unlike those of each of the above embodiments. And a concentrating device 33.

  In the microbubble concentrator 33, the spiral flow path 32 has a spiral radius of, for example, 7 cm, and the cross section of the flow path has a length of 4 cm in the horizontal direction (helical length direction) and a vertical direction (the spiral radius). (Direction) is a rectangular cross section having a length of 0.8 cm, and has a total length of 20 turns. Then, the microbubble generator 2 is connected to the start end portion 32a of the spiral flow path 32, and the end portion is divided into two pieces as shown in FIG. The separation plates 34 and 35 are provided, and the inside of the flow path is branched into three parts of an inner part, an intermediate part, and an outer part of the spiral, and the intermediate part serves as an extraction port 36, and an extraction flow path corresponding to the intended use 11, the inner part and the outer part serve as discharge ports 37 and 38, and are connected to the microbubble generator 2 by a recovery channel 39.

  The microbubble generator 31 of the third embodiment selects and extracts microbubbles having an intermediate diameter from a state in which bubbles are distributed from a large diameter to a small diameter in the spiral flow path 32 of the microbubble concentrator 33. Compared to those of the first embodiment and the second embodiment, the entire apparatus can be compactly accommodated.

  As an example of the microbubble concentrating device 3 in the first embodiment, a spiral flow path 4 of a primary concentrator 6 for separating and removing large-sized bubbles is passed through a spiral radius of 10 cm, a length of 0.5 cm, and a width of 3 cm. 5 sections are formed in the section of the road, the starting end 4a is used as an inlet for the stock solution containing microbubbles, and at the terminal section, the section of the channel is divided into 0.25 cm in the vertical direction by a separating plate, and the outer channel is formed. The inner channel is connected to the start end of the spiral channel 5 in the secondary concentrator 7 for separating and removing small-diameter bubbles, and the inner channel serves as a discharge port 12 for removing liquid containing large-diameter bubbles. The spiral flow path 5 of the secondary concentrator 7 has a spiral radius of 5 cm, a vertical length of 0.4 cm, and a horizontal cross section of 2 cm, and has 52 turns. At the end of the spiral channel 5, the separator 9 separates the longitudinal channel by 0.2 cm, the inner channel is the outlet 10 for the microbubble-containing product liquid, and the outer channel is a bubble containing small-sized bubbles. The liquid outlet 13 is used.

  When pure water containing air bubbles having a diameter of 1 to 100 μm is passed through the microbubble concentrating device 3 at 30 l / min, bubbles having a diameter of 20 μm or more are contained from the bubble liquid discharge port 12 containing large bubbles. Bubble liquid is collected, bubble liquid containing bubbles having a diameter of 5 μm or less is collected from the bubble liquid discharge port 13 containing small bubbles, and microbubbles having a diameter of 5 to 20 μm are concentrated from the product liquid outlet 10. Microbubble water can be obtained. The total transit time of bubble water is about 6 seconds.

  As an example of the microbubble concentrator 22 in the second embodiment, a gas-liquid separation tank 25 of a primary concentrator 23 for separating and removing large-sized bubbles is 20 cm wide, 42 cm long, and has a height of 0. Formed as a tank 25 with a water-repellent porous membrane 24 stretched at a distance of 5 cm, one end portion 25b of the gas-liquid separation tank 25 leading to the flow path 26 serves as an inlet for a stock solution containing microbubbles, and a small diameter bubble is formed at the other end. It connects with the starting end part of the spiral flow path 5 of the secondary concentrator 7 for separating and removing. The spiral flow path 5 has a flow path cross section of a spiral radius of 5 cm, a vertical length of 0.5 cm, and a horizontal width of 2.5 cm. The end of the spiral channel 5 is partitioned by a separation plate 9 in a longitudinal direction of 0.25 cm, the inner channel is an extraction port 10 for a microbubble-containing product liquid, and the outer channel is a bubble containing small-sized bubbles. The liquid outlet 13 is used.

  When pure water containing air bubbles having a diameter of 5 to 300 μm is passed through the microbubble concentrator 22 at 30 l / min, the bubbles having a diameter of 100 μm or more are separated into the gas phase through the water-repellent porous membrane 24, A bubble liquid containing bubbles having a diameter of 10 μm or less is collected from the discharge port 13 of the sub-concentrator 7, and microbubble water in which microbubbles having a diameter of 10 to 100 μm are concentrated can be obtained from the product liquid outlet 10. . The total transit time of bubble water is about 2 seconds.

  As an example of the microbubble concentrating device 33 in the third embodiment, the spiral flow path 32 for separating and removing large and small bubbles has a spiral radius of 7 cm, a vertical length of 0.8 cm, and a horizontal cross section of the horizontal 4 cm. The separation plate 34, 35 is disposed so that the starting end portion 32a serves as an inlet for the stock solution, and the flow passage section is vertically partitioned at the positions of 0.2 cm and 0.6 cm from the outer periphery at the end portion, respectively. The inner channel is a bubble liquid outlet 37 containing large-sized bubbles, the outer channel is a bubble liquid outlet 37 containing small-sized bubbles, and the central channel is used for the product liquid of the microbubble-containing liquid. The extraction port 36 is used.

When pure water containing air bubbles having a diameter of 1 to 50 μm is passed through the microbubble concentrator 33 at a rate of 60 l / min, bubbles containing bubbles having a diameter of 15 μm or more are discharged from the discharge port 37 for liquid containing large bubbles. The liquid is collected, the bubble liquid containing bubbles of 10 μm or less in diameter is collected from the liquid discharge port 38 containing small-sized bubbles, and the microbubbles having a diameter of 10 to 15 μm are concentrated from the product liquid outlet 36. Bubble water can be obtained. The total transit time of bubble water is about 3 seconds.
In the above three examples, the same result can be obtained when ozone is used as the constituent gas of the bubbles.

  In addition, this invention is not limited to the said embodiment, A various change can be added in the range which does not deviate from the meaning of this invention.

  The present invention is based on the surface potential of microbubbles, cleaning of various materials by adhesion of fats and oils and suspended substances in liquid, purification of liquids, promotion of growth of seafood by air or oxygen microbubbles, by ozone microbubbles Sterilization of sludge, sludge decomposition, surface oxidation treatment of materials, peening of metal materials using impact force when crushing microbubbles, low pipe friction resistance using reduction of surface tension and viscosity of microbubble water It can be used to generate microbubbles for purposes such as reducing resistance during water supply and ship navigation, and ultrasound contrast agents.

DESCRIPTION OF SYMBOLS 1 Microbubble generator 2 Microbubble generator 3 Microbubble concentrator 4,5 Spiral flow path 6 Primary concentrator 7 Secondary concentrator 8,9 Separation plate 10 Extraction port 11 Extraction piping 12, 13 Discharge ports 14,15 Recovery pipe 21 Micro bubble generating device 22 Micro bubble concentrating device 23 Primary concentrator 24 Liquid repellent porous membrane 25 Gas-liquid separation tank 25a Bottom surface 26 Channel 27 Discharge port 31 Micro bubble generating device 32 Spiral channel 33 Micro bubble concentrating device 34, 35 Separation plate 36 Extraction port 37, 38 Discharge port 39 Recovery piping

Claims (9)

  A spiral flow path for circulating bubble liquid containing bubbles of various diameters including microbubbles, and a part of the bubble liquid branched from a predetermined radial position in the flow path at the outlet of the spiral flow path A microbubble concentrating device comprising an extraction flow path for separating the liquid.   2. The microbubble concentrating device according to claim 1, wherein the predetermined position in the radial direction is an intermediate position excluding an inner portion and an outer portion in the radial direction in the flow path.   A primary concentrator that removes bubble liquid containing large-diameter bubbles from bubble liquid containing bubbles of various diameters including microbubbles, and a bubble liquid passing through the primary concentrator is circulated through the spiral flow path to form a spiral. A microbubble concentrating device comprising a secondary concentrator for fractionating bubble liquid that passes through a radially outer portion of the channel.   The primary concentrator has a first spiral channel through which bubble liquid flows, and a radially outer portion in the channel at the outlet of the first spiral channel communicates with the secondary concentrator. The microbubble concentrator according to claim 3, wherein   The primary concentrator has a gas-liquid separation tank that regulates the liquid level with a liquid-repellent porous membrane and allows large-sized bubbles floating on the liquid surface to escape from the liquid-repellent porous film to the outside air. The microbubble concentrating device according to claim 3, wherein a flow path between a bottom surface and the liquid repellent porous membrane communicates with the secondary concentrator.   A microbubble concentrating device according to any one of claims 1 to 5, a microbubble generating device that generates bubble liquid containing bubbles having various diameters including microbubbles and supplies the bubble liquid to the microbubble concentrating device. A microbubble generating device comprising:   A recovery channel is provided between the microbubble concentrator and the microbubble generator to recover the bubble liquid that has not been separated by the microbubble concentrator and use it as a part of the raw material of the microbubble generator. The microbubble generator according to claim 6, wherein   After generating bubble liquid containing bubbles of various diameters including microbubbles, the bubble liquid is circulated through the spiral flow path, and a part of the bubble liquid is removed from a predetermined position in the radial direction of the spiral flow path. A method for concentrating microbubbles, comprising sorting.   After generating bubble liquid containing bubbles of various diameters including microbubbles, the bubble liquid is circulated through the spiral flow path, and a part of the bubble liquid is removed from a predetermined position in the radial direction of the spiral flow path. A microbubble generating method characterized by sorting.

Images