JP2011123977A - Magnetic recording medium and magnetic recording and reproducing device - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a magnetic recording medium which has an orientation control layer having a dome-shaped convex part formed on the tops of columnar crystals, and which provides sufficiently high recording properties (OW) suitable for high-density recording. <P>SOLUTION: The magnetic recording medium is obtained by laminating on a nonmagnetic substrate at least: a soft magnetic underlayer; an orientation control layer 3 which controls the orientation of the layer right above the same; a vertical magnetic layer 4 including an axis of easy magnetization vertically oriented mainly to the nonmagnetic substrate. The orientation control layer 3 contains an Ru alloy layer containing magnetic material and having 50 emu/cc or more saturated magnetization. The vertical magnetic layer 4 contains the columnar crystals S3 consecutive in the thickness direction as well as the crystal grains constituting the orientation control layer 3. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a magnetic recording medium and a magnetic recording / reproducing apparatus.

  A hard disk drive (HDD), which is a kind of magnetic recording / reproducing apparatus, has an increasing recording density of 50% or more per year and is said to continue to increase in the future. Accordingly, development of a magnetic head and a magnetic recording medium suitable for increasing the recording density has been advanced.

  A magnetic recording / reproducing apparatus currently on the market is equipped with a so-called perpendicular magnetic recording medium in which an easy axis of magnetization in a magnetic film is oriented vertically. Even when the recording density of the perpendicular magnetic recording medium is increased, the influence of the demagnetizing field in the boundary region between the recording bits is small and a clear bit boundary is formed, so that an increase in noise can be suppressed. In addition, the perpendicular magnetic recording medium has excellent thermal fluctuation characteristics because it requires only a small reduction in the recording bit volume accompanying an increase in recording density.

  In order to meet the demand for higher recording density of magnetic recording media, it has been studied to use a single-pole head having excellent writing ability for the perpendicular magnetic layer. Specifically, by providing a layer made of a soft magnetic material called a backing layer between a perpendicular magnetic layer that is a recording layer and a nonmagnetic substrate, a magnetic flux between a single-pole head and a magnetic recording medium is provided. There has been proposed a magnetic recording medium with improved efficiency of entering and exiting.

  In addition, in order to improve the recording / reproducing characteristics and thermal fluctuation characteristics of the perpendicular magnetic recording medium, an orientation control layer is used to form a multi-layered magnetic layer, and the crystal grains of each magnetic layer are formed into continuous columnar crystals. It has been proposed to improve the vertical alignment of the magnetic layer (see Patent Document 1).

  It has been proposed to use Ru as the orientation control layer (see Patent Document 2). In addition, since Ru has a dome-shaped convex portion formed at the top of the columnar crystal, crystal grains such as a magnetic layer are grown on the convex portion, and the separation structure of the grown crystal particles is promoted. It is known to have an effect of isolating crystal grains and growing magnetic grains in a columnar shape (see Patent Document 3).

  Patent Document 4 discloses that in a perpendicular magnetic recording medium in which a perpendicular recording layer is formed on a substrate via a soft magnetic underlayer and a nonmagnetic intermediate layer, the nonmagnetic intermediate layer has Ru, Ru, Co, Fe, A layer containing one or more elements selected from Cr, B, and Mo, and the soft magnetic underlayer contains Ta in the FeCo alloy and further contains 5 at% or more of B, and is used for perpendicular recording. A perpendicular magnetic recording medium whose layer is an alloy mainly composed of CoCrPt is described.

JP 2004-310910 A Japanese Patent Laid-Open No. 7-244831 JP 2007-272990 A JP 2009-70444 A

  However, when Ru is used as the orientation control layer to form a dome-shaped convex portion at the top of the columnar crystal, the orientation control layer needs to be thickened to about 10 to 20 nm, and is closer to the substrate than the orientation control layer. The recording distance between the soft magnetic underlayer and the magnetic head placed on the magnetic head increases, and the magnetic coupling between the soft magnetic underlayer and the magnetic head becomes weak. Therefore, sufficiently high recording characteristics suitable for high-density recording (OW ) May not be obtained. Therefore, it is possible to provide a magnetic recording medium having an orientation control layer having a dome-shaped convex portion formed on the top of a columnar crystal and having sufficiently high recording characteristics (OW) suitable for high-density recording. Is required.

The present invention has been proposed in view of the above circumstances, and has an orientation control layer in which a dome-shaped projection is formed on the top of a columnar crystal, and crystal grains constituting the perpendicular magnetic layer have an orientation control layer. It is an object of the present invention to provide a magnetic recording medium that can include columnar crystals that are continuous in the thickness direction together with the constituting crystal grains, and that has sufficiently high recording characteristics (OW) suitable for high-density recording.
Another object of the present invention is to provide a magnetic recording / reproducing apparatus including a highly reliable magnetic recording medium including the magnetic recording medium of the present invention.

  In order to solve the above-mentioned problems, the present inventor has intensively studied materials for the orientation control layer. As a result, the orientation control layer includes a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more, and crystal grains constituting the perpendicular magnetic layer continue in the thickness direction together with crystal grains constituting the orientation control layer. It has been found that by including columnar crystals, a magnetic recording medium capable of obtaining a signal / noise ratio (S / N ratio), recording characteristics (OW), and thermal fluctuation characteristics suitable for high-density recording can be realized.

The present invention provides the following means.
(1) On a nonmagnetic substrate, a soft magnetic underlayer, an orientation control layer for controlling the orientation of the layer immediately above, and a perpendicular magnetic layer having an easy axis of magnetization oriented perpendicularly to the nonmagnetic substrate And the orientation control layer includes a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more, and the perpendicular magnetic layer is the orientation recording layer. A magnetic recording medium comprising columnar crystals continuous in the thickness direction together with crystal grains constituting a control layer.
(2) The orientation control layer includes a first orientation control layer disposed on the soft magnetic underlayer side and a second orientation control layer disposed on the perpendicular magnetic layer side of the first orientation control layer. The first orientation control layer includes a crystal serving as a nucleus of a columnar crystal, the second orientation control layer is continuous with the crystal serving as a nucleus in the thickness direction, and a dome-shaped convex portion is formed at the top. (1) The columnar crystal is formed, and one or both of the first orientation control layer and the second orientation control layer includes the Ru alloy layer. Magnetic recording medium.
(3) The magnetic recording medium according to (1) or (2), wherein the magnetic material is Co or Fe.
(4) The Ru alloy layer contains Co in a range of 66 at% to 80 at% and has a saturation magnetization in a range of 50 emu / cc to 700 emu / cc and / or Fe of 73 at%. The FeRu alloy layer, which is contained in a range of ˜80 at% and has a saturation magnetization in a range of 50 emu / cc to 500 emu / cc, is characterized in that it is any one of (1) to (3) Magnetic recording medium.
(5) A magnetic recording / reproducing apparatus comprising: the magnetic recording medium according to any one of (1) to (4); and a magnetic head for recording / reproducing information with respect to the magnetic recording medium.

In the magnetic recording medium of the present invention, since the perpendicular magnetic layer contains columnar crystals that are continuous in the thickness direction together with the crystal grains constituting the orientation control layer, the perpendicular magnetic layer has excellent perpendicular orientation. In the magnetic recording medium of the present invention, since the orientation control layer includes a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more, the orientation control layer exhibits magnetism. Therefore, in the magnetic recording medium of the present invention, in order to obtain a perpendicular magnetic layer containing columnar crystals continuous in the thickness direction together with crystal grains constituting the orientation control layer, the thickness of the orientation control layer is increased, and the soft magnetic underlayer and Even when the distance to the magnetic head is increased, sufficiently high recording characteristics (OW) suitable for high-density recording can be obtained.
That is, the magnetic recording medium of the present invention has a perpendicular magnetic layer containing columnar crystals continuous in the thickness direction together with crystal grains constituting the orientation control layer without adversely affecting recording characteristics (OW), A magnetic recording medium having a signal / noise ratio (S / N ratio), recording characteristics (OW), and thermal fluctuation characteristics suitable for density recording can be realized.

  The magnetic recording / reproducing apparatus of the present invention comprises the magnetic recording medium of the present invention and a magnetic head for recording / reproducing information with respect to the magnetic recording medium. Therefore, the signal / noise ratio suitable for high-density recording is provided. (S / N ratio), recording characteristics (OW), and excellent magnetic recording medium provided with thermal fluctuation characteristics.

FIG. 1 shows an example of the magnetic recording medium of the present invention. FIG. 2 is an enlarged schematic view for explaining the laminated structure of the orientation control layer and the perpendicular magnetic layer, and is a cross-sectional view showing a state in which the columnar crystals of each layer grow perpendicular to the substrate surface. FIG. 3 is an enlarged cross-sectional view showing a laminated structure of a magnetic layer and a nonmagnetic layer constituting the perpendicular magnetic layer. FIG. 4 shows an example of the magnetic recording / reproducing apparatus of the present invention.

  Hereinafter, a method for manufacturing a magnetic recording medium and a magnetic recording / reproducing apparatus according to the present invention will be described in detail with reference to the drawings. In addition, in the drawings used in the following description, in order to make the features easy to understand, there are cases where the portions that become the features are enlarged for the sake of convenience, and the dimensional ratios of the respective components are not always the same as the actual ones. Absent.

(Magnetic recording medium)
In the present invention, a soft magnetic underlayer, an orientation control layer for controlling the orientation of a layer immediately above the nonmagnetic substrate, and a perpendicular magnetic material whose easy axis of magnetization is oriented perpendicularly to the nonmagnetic substrate. The magnetic recording medium is formed by laminating at least layers.
FIG. 1 shows an example of the magnetic recording medium of the present invention. Hereinafter, the magnetic recording medium shown in FIG. 1 will be described as an example of the magnetic recording medium of the present invention. The magnetic recording medium shown in FIG. 1 includes a soft magnetic underlayer 2, an orientation control layer 3, a nonmagnetic underlayer 8, a perpendicular magnetic layer 4, a protective layer 5, and a lubricating layer on a nonmagnetic substrate 1. 6 are sequentially stacked. Among these, the soft magnetic underlayer 2 and the orientation control layer 3 constitute an underlayer.

"Non-magnetic substrate"
As the nonmagnetic substrate 1, a metal substrate made of a metal material such as aluminum or an aluminum alloy may be used, or a nonmetal substrate made of a nonmetal material such as glass, ceramic, silicon, silicon carbide, or carbon is used. Also good. Further, as the nonmagnetic substrate 1, a substrate in which a NiP layer or a NiP alloy layer is formed on the surface of the metal substrate or the nonmetal substrate by using, for example, a plating method or a sputtering method may be used.

  As the glass substrate, for example, amorphous glass or crystallized glass can be used, and as the amorphous glass, for example, general-purpose soda lime glass or aluminosilicate glass can be used. In addition, as the crystallized glass, for example, lithium-based crystallized glass can be used. As the ceramic substrate, for example, general-purpose aluminum oxide, a sintered body mainly composed of aluminum nitride, silicon nitride, or the like, or a fiber reinforced material thereof can be used.

  The nonmagnetic substrate 1 preferably has an average surface roughness (Ra) of 2 nm (20 mm) or less, preferably 1 nm or less from the viewpoint of being suitable for high recording density recording with a magnetic head flying low. Further, the surface waviness (Wa) of the surface is preferably 0.3 nm or less (more preferably 0.25 nm or less) from the viewpoint of being suitable for high recording density recording with the magnetic head flying low. Further, it is possible to use a magnetic head having a surface average roughness (Ra) of 10 nm or less (more preferably 9.5 nm or less) of at least one of the chamfered portion and the side surface portion of the end chamfer portion. Preferred for. In addition, microwaviness (Wa) can be measured as surface average roughness in a measuring range of 80 μm, for example, using a surface roughness measuring device P-12 (manufactured by KLM-Tencor).

  Further, when the nonmagnetic substrate 1 is in contact with the soft magnetic underlayer 2 mainly composed of Co or Fe, there is a possibility that the corrosion progresses due to the adsorption gas on the surface, the influence of moisture, the diffusion of the substrate components, and the like. is there. In this case, it is preferable to provide an adhesion layer between the nonmagnetic substrate 1 and the soft magnetic underlayer 2, thereby suppressing these. In addition, as a material of the adhesion layer, for example, Cr, Cr alloy, Ti, Ti alloy, or the like can be selected as appropriate. The thickness of the adhesion layer is preferably 2 nm (30 mm) or more. The adhesion layer can be formed using a sputtering method or the like.

"Soft magnetic underlayer"
A soft magnetic underlayer 2 is formed on the nonmagnetic substrate. The method for forming the soft magnetic underlayer 2 is not particularly limited, and for example, a sputtering method can be used.
The soft magnetic underlayer 2 increases the component of the magnetic flux generated from the magnetic head in the direction perpendicular to the substrate surface, and further strengthens the direction of magnetization of the perpendicular magnetic layer 4 on which information is recorded to be perpendicular to the nonmagnetic substrate 1. It is provided to fix in any direction. This effect becomes more conspicuous particularly when a single pole head for perpendicular recording is used as a magnetic head for recording and reproduction.

  As the soft magnetic underlayer 2, for example, a soft magnetic material containing Fe, Ni, Co, or the like can be used. Specific examples of soft magnetic materials include CoFe alloys (CoFeTaZr, CoFeZrNb, etc.), FeCo alloys (FeCo, FeCoV, etc.), FeNi alloys (FeNi, FeNiMo, FeNiCr, FeNiSi, etc.), FeAl alloys (FeAl, etc.). FeAlSi, FeAlSiCr, FeAlSiTiRu, FeAlO, etc.), FeCr alloys (FeCr, FeCrTi, FeCrCu, etc.), FeTa alloys (FeTa, FeTaC, FeTaN, etc.), FeMg alloys (FeMgO, etc.), FeZr alloys (FeZrN, etc.) , FeC alloys, FeN alloys, FeSi alloys, FeP alloys, FeNb alloys, FeHf alloys, FeB alloys and the like.

  Further, the soft magnetic underlayer 2 has a microcrystalline structure such as FeAlO, FeMgO, FeTaN, FeZrN, etc. containing Fe of 60 at% (atomic%) or more, or a granular structure in which fine crystal particles are dispersed in a matrix. Materials can be used.

  In addition, as the soft magnetic underlayer 2, a Co alloy containing 80 at% or more of Co, containing at least one of Zr, Nb, Ta, Cr, Mo and the like and having an amorphous structure can be used. . Specific examples of the specific material include CoZr, CoZrNb, CoZrTa, CoZrCr, and CoZrMo-based alloys.

The coercive force Hc of the soft magnetic underlayer 2 is preferably 100 (Oe) or less (preferably 20 (Oe) or less). 1 Oe is 79 A / m. If the coercive force Hc of the soft magnetic underlayer 2 exceeds the above range, the soft magnetic characteristics are insufficient, and the reproduced waveform becomes a waveform having distortion from a so-called rectangular wave, which is not preferable.
The saturation magnetic flux density Bs of the soft magnetic underlayer 2 is preferably 0.6 T or more (preferably 1 T or more). If the Bs of the soft magnetic underlayer 2 is less than the above range, it is not preferable because the reproduced waveform changes from a so-called rectangular wave to a distorted waveform.
The product Bs · t (T · nm) of the saturation magnetic flux density Bs (T) of the soft magnetic underlayer 2 and the layer thickness t (nm) of the soft magnetic underlayer 2 is 15 (T · nm) or more (preferably Is preferably 25 (T · nm) or more. If the Bs · t of the soft magnetic underlayer 2 is less than the above range, the reproduced waveform will be distorted and the OW (OverWrite) characteristic (recording characteristic) will be deteriorated.

  The soft magnetic underlayer 2 is preferably composed of two soft magnetic films, and a Ru film is preferably provided between the two soft magnetic films. By adjusting the film thickness of the Ru film in the range of 0.4 to 1.0 nm or 1.6 to 2.6 nm, the two-layer soft magnetic film can have an AFC structure. When the soft magnetic underlayer 2 adopts such an AFC structure, so-called spike noise can be suppressed.

  The material constituting the magnetic underlayer 2 is preferably partially or completely oxidized on the outermost surface (surface on the orientation control layer 3 side) of the soft magnetic underlayer 2. For example, the material constituting the soft magnetic underlayer 2 is partially oxidized on the surface of the soft magnetic underlayer 2 (surface on the orientation control layer 3 side) and its vicinity, or an oxide of the above material is formed. Are preferably arranged. As a result, the magnetic fluctuation of the surface of the soft magnetic underlayer 2 can be suppressed, the noise caused by the magnetic fluctuation can be reduced, and the recording / reproducing characteristics of the magnetic recording medium can be improved.

`` Orientation control layer ''
An orientation control layer 3 is formed on the soft magnetic underlayer 2. The orientation control layer 3 is to refine the crystal grains of the perpendicular magnetic layer 4 and improve the recording / reproducing characteristics. As shown in FIG. 1, the orientation control layer 3 of the present embodiment is arranged on the first orientation control layer 3a arranged on the soft magnetic underlayer 2 side and on the perpendicular magnetic layer 4 side of the first orientation control layer 3a. And a second orientation control layer 3b.

The first orientation control layer 3 a is for increasing the nucleation density of the orientation control layer 3, and includes a crystal serving as a columnar crystal nucleus constituting the orientation control layer 3. In the first orientation control layer 3a of the present embodiment, as shown in FIG. 2, a dome-shaped convex portion is formed on the top of the columnar crystal S1 formed by growing a crystal serving as a nucleus.
The layer thickness of the first orientation control layer 3a is preferably 3 nm or more. If the layer thickness of the first orientation control layer 3a is less than the above range, the orientation of the perpendicular magnetic layer 4 is enhanced, and the effect of miniaturizing the magnetic particles 42 constituting the perpendicular magnetic layer 4 becomes insufficient, and a good S / N ratio may not be obtained.

  The first orientation control layer 3a is made of a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more. When the saturation magnetization of the Ru alloy layer constituting the first orientation control layer 3a is less than the above range, and the second orientation control layer 3b is not composed of a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more. Since the orientation control layer does not exhibit magnetism, sufficiently high recording characteristics (OW) suitable for high-density recording cannot be obtained unless the orientation control layer 3 is sufficiently thin.

  The Ru alloy layer included in the first orientation control layer 3a preferably contains Co or Fe as a magnetic material, and the Ru alloy layer is preferably a CoRu alloy layer or a FeRu alloy layer. When the magnetic material contained in the Ru alloy layer is Co, the content of Co contained in the Ru alloy layer is preferably 66 at% or more. When the magnetic material contained in the Ru alloy layer is Fe, the content of Fe contained in the Ru alloy layer is preferably 73 at% or more. By setting the content of Co or Fe contained in the Ru alloy layer to the above value or more, a Ru alloy layer exhibiting sufficient magnetism can be obtained, and a Ru alloy layer having a saturation magnetization of 50 emu / cc or more. Can do.

Table 1 shows theoretical values of saturation magnetization (Ms) of Co, CoRu alloy, FeRu alloy, and Fe. As shown in Table 1, when the content of Co contained in the Ru alloy is 66 at% or more and the content of Fe is 73 at% or more, the saturation magnetization (Ms) is 50 emu / cc or more.
Further, as shown in Table 1, when the Co content in the Ru alloy is 80 at% or less, the saturation magnetization (Ms) is 700 emu / cc or less. As shown in Table 1, when the content of Fe contained in the Ru alloy is 80 at% or less, the saturation magnetization (Ms) is 500 emu / cc or less.

  When the Ru alloy layer is a CoRu alloy layer, it is preferable that Co is contained in the range of 66 at% to 80 at% and the saturation magnetization is in the range of 50 emu / cc to 700 emu / cc. Further, when the Ru alloy layer is an FeRu alloy layer, it is preferable that Fe is contained in the range of 73 at% to 80 at% and the saturation magnetization is in the range of 50 emu / cc to 500 emu / cc.

When the content of Co contained in the CoRu alloy layer or the content of Fe contained in the FeRu alloy layer exceeds 80 at%, the orientation control layer 3 has a dome-shaped projection formed on the top of the columnar crystal. The effect of miniaturizing the magnetic particles 42 constituting the perpendicular magnetic layer 4 becomes insufficient, the crystal orientation of the perpendicular magnetic layer is deteriorated, and a good S / N ratio may not be obtained.
Further, when the saturation magnetization of the CoRu alloy layer and / or the FeRu alloy layer exceeds the above range, the Co content contained in the CoRu alloy layer and / or the Fe content contained in the FeRu alloy layer is within the above range. Since it will exceed, it is not preferable.

The first orientation control layer 3a is preferably formed by a sputtering method within a sputtering gas pressure range of 0.5 Pa to 5 Pa. By setting the sputtering gas pressure of the first orientation control layer 3a within the above range, the first orientation control layer 3a including a crystal serving as a nucleus of a columnar crystal constituting the orientation control layer 3 can be easily obtained.
When the sputtering gas pressure of the first orientation control layer 3a is less than the above range, the orientation of the film to be formed is lowered, and the effect of miniaturizing the magnetic particles 42 constituting the perpendicular magnetic layer 4 becomes insufficient. When the sputtering gas pressure of the first orientation control layer 3a exceeds the above range, the crystallinity of the film to be formed is lowered, the film hardness is lowered, and the reliability of the magnetic recording medium is lowered.

  As shown in FIG. 2, the second orientation control layer 3b is continuous in the thickness direction with a crystal serving as a nucleus of the columnar crystal S1 included in the first orientation control layer 3a, and a dome-like convex portion is formed at the top. Columnar crystals S2 are included. In the present embodiment, the second orientation control layer 3b is grown on the projections of the columnar crystals S1 formed by growing crystals serving as nuclei contained in the first orientation control layer 3a. It consists of columnar crystals S2 continuous in the thickness direction together with the constituting crystal grains.

  The layer thickness of the second orientation control layer 3b is preferably 6 nm or more. When the layer thickness of the second orientation control layer 3b is less than the above range, the orientation of the perpendicular magnetic layer 4 is improved, and the effect of miniaturizing the magnetic particles 42 constituting the perpendicular magnetic layer 4 becomes insufficient, and a good S / N ratio may not be obtained.

  The second orientation control layer 3b is made of a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more. When the saturation magnetization of the Ru alloy layer constituting the second orientation control layer 3b is less than the above range, and the first orientation control layer 3a is not composed of a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more. Since the orientation control layer does not exhibit magnetism, sufficiently high recording characteristics (OW) suitable for high-density recording cannot be obtained unless the orientation control layer 3 is sufficiently thin.

As the Ru alloy layer included in the second orientation control layer 3b, the same Ru alloy layer as included in the first orientation control layer 3a can be used.
Note that the Ru alloy layer included in the second orientation control layer 3b may be made of the same material as the Ru alloy layer included in the first orientation control layer 3a, or may be made of a different material. Good. Specifically, for example, one of the first orientation control layer 3a and the second orientation control layer 3b may be a CoRu alloy layer and the other may be a FeRu alloy layer.

The second alignment control layer 3a is preferably formed by a sputtering method at a pressure higher than that of the first alignment control layer 3a and within a range of sputtering gas pressure of 5 Pa to 18 Pa. By setting the sputtering gas pressure of the second orientation control layer 3b within the above range, the crystal which is the nucleus of the columnar crystal S1 contained in the first orientation control layer 3a can be easily continuous in the thickness direction, and the dome-like protrusion can be formed on the top. Thus, the second orientation control layer 3b including the columnar crystal S2 in which the portion is formed is obtained.
When the sputtering gas pressure of the second orientation control layer 3b is less than the above range, the crystal grains of the perpendicular magnetic layer 4 grown on the orientation control layer 3 are separated, and the magnetic particles of the perpendicular magnetic layer are refined. A sufficient effect cannot be obtained, and a good S / N ratio and thermal fluctuation characteristics cannot be obtained. If the sputtering gas pressure of the second orientation control layer 3b exceeds the above range, the hardness of the second orientation control layer 3b becomes insufficient.

In the present embodiment, both the first orientation control layer 3a and the second orientation control layer 3b are made of a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more. One of the control layer 3a and the second orientation control layer 3b may be the Ru alloy layer. Moreover, in this embodiment, although the case where the orientation control layer 3 consists of two layers of the 1st orientation control layer 3a and the 2nd orientation control layer 3b was mentioned as an example, the orientation control layer 3 is from 1 layer. Or one of the first orientation control layer 3a and the second orientation control layer 3b or three or more layers in which both are composed of a plurality of layers.
When the orientation control layer 3 is composed of one layer, the orientation control layer 3 is composed of a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more. Further, when the orientation control layer 3 is composed of a plurality of layers, it is sufficient that at least one Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more is included. For example, a Ru alloy such as a Ru layer may be included. A layer other than the layer may be included.

Here, in the magnetic recording medium of this embodiment, the relationship between the crystal grains constituting the orientation control layer and the magnetic grains constituting the perpendicular magnetic layer will be described with reference to the drawings.
FIG. 2 is an enlarged schematic view for explaining the laminated structure of the orientation control layer and the perpendicular magnetic layer, and is a cross-sectional view showing a state in which the columnar crystals of each layer grow perpendicular to the substrate surface. In FIG. 2, the description of members other than the first orientation control layer, the second orientation control layer, and the perpendicular magnetic layer constituting the orientation control layer is omitted.

  As shown in FIG. 2, an uneven surface S1a is formed on the first orientation control layer 3a, with the top of the columnar crystals S1 constituting the first orientation control layer 3a having a dome-like convexity. On the uneven surface S1a of the first orientation control layer 3a, crystal grains constituting the second orientation control layer 3b grow in the thickness direction from the uneven surface S1a as columnar crystals S2. On the second orientation control layer 3b, an uneven surface S2a is formed with the top of the columnar crystal S2 constituting the second orientation control layer 3b having a dome-like projection. Then, on the columnar crystals S2 constituting the second orientation control layer 3b, the crystal grains of the perpendicular magnetic layer 4 become columnar crystals S3 and grow in the thickness direction. In the present embodiment, the crystal grains of the perpendicular magnetic layer 4 are grown on the dome-shaped protrusions of the second orientation control layer 3b, whereby the separation of the grown crystal grains of the perpendicular magnetic layer 4 is promoted. Crystal grains of the magnetic layer 4 are isolated and grown in a columnar shape.

  Thus, in the magnetic recording medium of the present embodiment, the columnar crystal S2 of the second orientation control layer 3b and the columnar crystal S3 of the perpendicular magnetic layer 4 are continuously formed on the columnar crystal S1 of the first orientation control layer 3a. Epitaxially grown as crystals. In the present embodiment, as shown in FIG. 1, the perpendicular magnetic layer 4 is multilayered. Crystal grains constituting each layer of the multilayered perpendicular magnetic layer 4 form a continuous columnar crystal from the orientation control layer 3 to the uppermost perpendicular magnetic layer, and repeat epitaxial growth. Therefore, in this embodiment, the crystal grains constituting the first orientation control layer 3a are refined, and the columnar crystals S1 are densified, so that the second orientation grows in a columnar shape in the thickness direction from the top of the columnar crystals S1. The columnar crystals S2 of the control layer 3b and the columnar crystals S3 of the multilayered perpendicular magnetic layer 4 are also densified.

"Nonmagnetic underlayer"
In the magnetic recording medium of this embodiment, a nonmagnetic underlayer 8 is provided between the orientation control layer 3 and the perpendicular magnetic layer 4. A nonmagnetic underlayer 8 is preferably provided between the orientation control layer 3 and the perpendicular magnetic layer 4, but the nonmagnetic underlayer 8 may not be provided. In the initial part of the perpendicular magnetic layer 4 immediately above the orientation control layer 3, disorder of crystal growth is likely to occur, which causes noise. By providing the nonmagnetic underlayer 8, noise can be suppressed.
The nonmagnetic underlayer 8 is a columnar crystal that is continuous with the columnar crystals S1 and S2 of the first alignment control layer 3a and the second alignment control layer 3b of the alignment control layer 3, and is a second alignment control layer of the alignment control layer 3. Epitaxially grown on 3b.

The nonmagnetic underlayer 8 is preferably made of a material containing Cr and an oxide. The Cr content is preferably 25 at% (atomic%) or more and 50 at% or less. As the oxide, for example, oxides such as Cr, Si, Ta, Al, Ti, Mg, and Co are preferably used, and among them, TiO ₂ , Cr ₂ O ₃ , SiO _{2, and the} like are preferably used. it can. The content of the oxide is preferably 3 mol% or more and 18 mol% or less with respect to the total amount of mol calculated as one compound, for example, an alloy such as Co, Cr, and Pt constituting the magnetic particles.

The nonmagnetic underlayer 8 is preferably made of a complex oxide to which two or more kinds of oxides are added. Among these, Cr ₂ O ₃ —SiO ₂ , Cr ₂ O ₃ —TiO ₂ , Cr ₂ O ₃ —SiO ₂ —TiO _{2 and the} like can be preferably used. Furthermore, CoCr—SiO ₂ , CoCr—TiO ₂ , CoCr—Cr ₂ O ₃ —SiO ₂ , CoCr—TiO ₂ —Cr ₂ O ₃ , CoCr—Cr ₂ O ₃ —TiO ₂ —SiO ₂ or the like is preferably used. Can do. Further, Pt may be added from the viewpoint of crystal growth.

  The thickness of the nonmagnetic underlayer 8 is preferably 0.2 nm or more and 3 nm or less. If the thickness of the nonmagnetic underlayer 8 exceeds 3 nm, Hc and Hn decrease, which is not preferable.

"Perpendicular magnetic layer"
A perpendicular magnetic layer 4 is formed on the nonmagnetic underlayer 8. As shown in FIG. 1, the perpendicular magnetic layer 4 includes three layers from the nonmagnetic substrate 1 side: a lower magnetic layer 4a, an intermediate magnetic layer 4b, and an upper magnetic layer 4c. In the magnetic recording medium of the present embodiment, the lower nonmagnetic layer 7a is included between the magnetic layer 4a and the magnetic layer 4b, and the upper nonmagnetic layer 7b is included between the magnetic layer 4b and the magnetic layer 4c. The magnetic layers 4a to 4c and the nonmagnetic layers 7a and 7b are alternately stacked.

  The crystal grains constituting each of the magnetic layers 4a to 4c and the nonmagnetic layers 7a and 7b are nonmagnetic as columnar crystals that are continuous with the columnar crystals of the first orientation control layer 3a and the second orientation control layer 3b of the orientation control layer 3. Epitaxially grown on the underlayer 8.

FIG. 3 is an enlarged cross-sectional view showing a laminated structure of a magnetic layer and a nonmagnetic layer constituting the perpendicular magnetic layer. As shown in FIG. 3, the magnetic layer 4 a constituting the perpendicular magnetic layer 4 is a magnetic layer having a granular structure, and includes magnetic particles (crystal particles having magnetism) 42 containing Co, Cr, and Pt, and an oxide 41. It is preferable that it contains.
As the oxide 41, for example, an oxide such as Cr, Si, Ta, Al, Ti, Mg, and Co is preferably used. Among _{them, TiO 2, Cr 2 O 3} , SiO ₂ or the like can be suitably used. The magnetic layer 4a is preferably made of a complex oxide to which two or more kinds of oxides are added. Among these, Cr ₂ O ₃ —SiO ₂ , Cr ₂ O ₃ —TiO ₂ , Cr ₂ O ₃ —SiO ₂ —TiO _{2 and the} like can be preferably used.

  The magnetic particles 42 are preferably dispersed in the magnetic layer 4a. The magnetic particles 42 preferably have a columnar structure that vertically penetrates the magnetic layers 4a and 4b and further the magnetic layer 4c. By having such a structure, the orientation and crystallinity of the magnetic layer 4a are improved, and as a result, a signal / noise ratio (S / N ratio) suitable for high-density recording can be obtained.

  In order to obtain the perpendicular magnetic layer 4 having the magnetic particles 42 having the columnar structure, the content of the oxide 41 contained in the magnetic layer 4a and the film formation conditions of the magnetic layer 4a are important. The content of the oxide 41 contained in the magnetic layer 4a is 3 mol% or more and 18 mol% or less with respect to the total mol amount calculated by using, for example, an alloy such as Co, Cr, and Pt constituting the magnetic particle 42 as one compound. It is preferable that it is 6 mol% or more and 13 mol% or less.

  The above range is preferable as the content of the oxide 41 in the magnetic layer 4a. When the magnetic layer 4a is formed, the oxide 41 is precipitated around the magnetic particles 42, and the magnetic particles 42 are isolated and refined. This is because it becomes possible. On the other hand, when the content of the oxide 41 exceeds the above range, the oxide 41 remains in the magnetic particles 42, and the orientation and crystallinity of the magnetic particles 42 are impaired. This is not preferable because the product 41 is deposited and the columnar structure in which the magnetic particles 42 penetrate the magnetic layers 4a to 4c vertically is not formed. In addition, when the content of the oxide 41 is less than the above range, separation and refinement of the magnetic particles 42 are insufficient, resulting in an increase in noise during recording and reproduction, and a signal / This is not preferable because the noise ratio (S / N ratio) cannot be obtained.

  The content of Cr in the magnetic layer 4a is preferably 4 at% or more and 19 at% or less (more preferably 6 at% or more and 17 at% or less). When the content of Cr in the magnetic layer 4a is in the above range, the magnetic anisotropy constant Ku of the magnetic particles 42 is not lowered too much, and high magnetization is maintained, resulting in recording / reproduction characteristics suitable for high-density recording. Sufficient thermal fluctuation characteristics can be obtained.

  On the other hand, when the content of Cr in the magnetic layer 4a exceeds the above range, the magnetic anisotropy constant Ku of the magnetic particles 42 decreases, so that the thermal fluctuation characteristics deteriorate, and the crystal of the magnetic particles 42 Deterioration in orientation and orientation is undesirable because recording / reproduction characteristics deteriorate as a result. In addition, when the Cr content is less than the above range, the magnetic anisotropy constant Ku of the magnetic particles 42 is high, so that the magnetic head is sufficient for recording data because the perpendicular coercive force is too high. The recording characteristics (OW) are unsuitable for high-density recording as a result.

  The content of Pt in the magnetic layer 4a is preferably 8 at% or more and 20 at% or less. If the Pt content is less than 8 at%, the magnetic anisotropy constant Ku necessary for the perpendicular magnetic layer 4 to obtain thermal fluctuation characteristics suitable for high-density recording cannot be obtained, which is not preferable. When the content of Pt exceeds 20 at%, stacking faults are generated inside the magnetic particles 42, and as a result, the magnetic anisotropy constant Ku is lowered. In addition, when the Pt content exceeds the above range, an fcc structure layer is formed in the magnetic particles 42, and the crystallinity and orientation may be impaired. Therefore, in order to obtain thermal fluctuation characteristics and recording / reproduction characteristics suitable for high-density recording, it is preferable to set the Pt content in the magnetic layer 4a within the above range.

  In addition to Co, Cr, and Pt, the magnetic particles 42 of the magnetic layer 4a include one or more elements selected from B, Ta, Mo, Cu, Nd, W, Nb, Sm, Tb, Ru, and Re. May be included. By including the above elements, the miniaturization of the magnetic particles 42 can be promoted or the crystallinity and orientation can be improved, and recording / reproduction characteristics and thermal fluctuation characteristics suitable for higher density recording can be obtained.

  The total content of Co, Cr, and Pt contained in the magnetic particles 42 is preferably 8 at% or less. If the total content of the above elements exceeds 8 at%, a phase other than the hcp phase is formed in the magnetic particles 42, so that the crystallinity and orientation of the magnetic particles 42 are disturbed, and as a result suitable for high-density recording. Recording / reproducing characteristics and thermal fluctuation characteristics cannot be obtained, which is not preferable.

As a material suitable for the magnetic layer 4a, for example, 90 (Co14Cr18Pt) -10 (SiO ₂ ) {Cr content 14at%, Pt content 18at%, molar concentration calculated as one compound with magnetic particles composed of the remaining Co. Is 90 mol%, the oxide composition of SiO ₂ is 10 mol%}, 92 (Co10Cr16Pt) -8 (SiO ₂ ), 94 (Co8Cr14Pt4Nb) -6 (Cr ₂ O ₃ ), and (CoCrPt)-(Ta ₂ O _{5), (CoCrPt) - (} Cr 2 O 3) - (TiO 2), (CoCrPt) - (Cr 2 O 3) - (SiO 2), (CoCrPt) - (Cr 2 O 3) - (SiO 2) _{- (TiO 2), (CoCrPtMo} ) - (TiO), (CoCrPtW) - (TiO 2), (CoCrPtB) - (Al 2 O ₃ ), (CoCrPtTaNd) — (MgO), (CoCrPtBCu) — (Y ₂ O ₃ ), (CoCrPtRu) — (SiO ₂ ), and the like.

As shown in FIG. 3, similarly to the magnetic layer 4a, the magnetic layer 4b constituting the perpendicular magnetic layer 4 is a magnetic layer having a granular structure, and magnetic particles containing Co, Cr, and Pt (crystal grains having magnetism). 42 and the oxide 41 are preferably included.
The oxide 41 is preferably an oxide of Cr, Si, Ta, Al, Ti, Mg, and Co. Among these, TiO ₂ , Cr ₂ O ₃ , and SiO ₂ can be preferably used as the oxide 41. The oxide 41 constituting the magnetic layer 4b is preferably a composite oxide composed of two or more kinds of oxides. Among these, a composite oxide composed of Cr ₂ O ₃ —SiO ₂ , Cr ₂ O ₃ —TiO ₂ , Cr ₂ O ₃ —SiO ₂ —TiO _2, or the like can be preferably used as the oxide 41.

  The magnetic particles 42 constituting the magnetic layer 4b are preferably dispersed in the magnetic layer 4b. The magnetic particles 42 preferably form a columnar structure that vertically penetrates the magnetic layers 4a and 4b and further the magnetic layer 4c. By forming such a structure, the orientation and crystallinity of the magnetic particles 42 of the magnetic layer 4b are improved, and as a result, a signal / noise ratio (S / N ratio) suitable for high-density recording can be obtained.

  The content of the oxide 41 in the magnetic layer 4b is preferably 3 mol% or more and 18 mol% or less, more preferably, with respect to the total amount of compounds such as Co, Cr, Pt, etc. constituting the magnetic particles 42. It is 6 mol% or more and 13 mol% or less. The reason why the above range is preferable as the content of the oxide 41 in the magnetic layer 4 b is the same as the content of the oxide 41 in the magnetic layer 4 a constituting the perpendicular magnetic layer 4.

  The content of Cr in the magnetic layer 4b is preferably 4 at% or more and 18 at% or less (more preferably 8 at% or more and 15 at% or less). The reason why the Cr content is in the above range is that the magnetic anisotropy constant Ku of the magnetic particles 42 is not lowered too much, and high magnetization is maintained. As a result, recording / reproduction characteristics suitable for high-density recording and sufficient heat This is because fluctuation characteristics can be obtained.

  On the other hand, when the content of Cr in the magnetic layer 4b exceeds the above range, the magnetic anisotropy constant Ku of the magnetic particles 42 decreases, so that the thermal fluctuation characteristics deteriorate, and the crystal of the magnetic particles 42 Deterioration in orientation and orientation is undesirable because recording / reproduction characteristics deteriorate as a result. In addition, when the Cr content is less than the above range, the magnetic anisotropy constant Ku of the magnetic particles 42 is high, so that the magnetic head is sufficient for recording data because the perpendicular coercive force is too high. The recording characteristics (OW) are unsuitable for high-density recording as a result.

  The Pt content in the magnetic layer 4b is preferably 10 at% or more and 22 at% or less. If the Pt content is less than 10 at%, the magnetic anisotropy constant Ku necessary for the perpendicular magnetic layer 4 to obtain thermal fluctuation characteristics suitable for high-density recording cannot be obtained. When the content of Pt exceeds 22 at%, stacking faults are generated inside the magnetic particles 42, and as a result, the magnetic anisotropy constant Ku is lowered. In addition, when the Pt content exceeds the above range, an fcc structure layer is formed in the magnetic particles 42, and the crystallinity and orientation may be impaired. Therefore, in order to obtain thermal fluctuation characteristics and recording / reproduction characteristics suitable for high-density recording, the Pt content in the magnetic layer 4b is preferably set in the above range.

In addition to Co, Cr and Pt, the magnetic particles 42 of the magnetic layer 4b include B, Ta, Mo, Cu, Nd, W, Nb, Sm, Tb, Ru, One or more elements selected from Re may be contained. By including the above elements, the miniaturization of the magnetic particles 42 can be promoted or the crystallinity and orientation can be improved, and recording / reproduction characteristics and thermal fluctuation characteristics suitable for higher density recording can be obtained.
Further, the total content of Co, Cr, Pt and other elements described above contained in the magnetic particles 42 of the magnetic layer 4b may be 8 at% or less for the same reason as the magnetic particles 42 of the magnetic layer 4a. preferable.

  As shown in FIG. 3, the magnetic layer 4 c constituting the perpendicular magnetic layer 4 preferably includes magnetic particles (magnetic crystal particles) 42 containing Co and Cr, and does not include the oxide 41. . The magnetic particles 42 in the magnetic layer 4c are preferably grown epitaxially in a columnar shape from the magnetic particles 42 in the magnetic layer 4a. In this case, the magnetic particles 42 of the magnetic layers 4a to 4c are preferably epitaxially grown in a columnar shape in a one-to-one correspondence in each layer. Further, since the magnetic particles 42 of the magnetic layer 4b are epitaxially grown from the magnetic particles 42 in the magnetic layer 4a, the magnetic particles 42 of the magnetic layer 4b are miniaturized and the crystallinity and orientation are further improved. .

  The content of Cr in the magnetic layer 4c is preferably 10 at% or more and 24 at% or less. By setting the Cr content in the above range, it is possible to sufficiently ensure output during data reproduction and to obtain better thermal fluctuation characteristics. On the other hand, when the content of Cr exceeds the above range, the magnetization of the magnetic layer 4c becomes too small, which is not preferable. When the Cr content is less than the above range, the magnetic particles 42 are not sufficiently separated and refined, noise during recording / reproduction increases, and a signal / noise ratio (S) suitable for high-density recording (S / N ratio) is not obtained.

  Further, when the magnetic particles 42 constituting the magnetic layer 4c are a material containing Pt in addition to Co and Cr, the content of Pt in the magnetic layer 4c is preferably 8 at% or more and 20 at% or less. . When the Pt content is in the above range, a sufficient coercive force suitable for high recording density can be obtained, and a high reproduction output during recording / reproduction can be maintained, resulting in recording / reproduction characteristics suitable for high-density recording. And thermal fluctuation characteristics are obtained. On the other hand, if the content of Pt in the magnetic layer 4c exceeds the above range, an fcc-structured phase is formed in the magnetic layer 4c, and crystallinity and orientation may be impaired. Further, when the Pt content is less than the above range, it is not preferable because the magnetic anisotropy constant Ku for obtaining thermal fluctuation characteristics suitable for high density recording cannot be obtained.

  The magnetic particles 42 constituting the magnetic layer 4c are non-granular magnetic layers, and besides Co, Cr, Pt, B, Ta, Mo, Cu, Nd, W, Nb, Sm, Tb, Ru, Re , One or more elements selected from Mn can be included. By including the above elements, it is possible to promote miniaturization of the magnetic particles 42 or improve crystallinity and orientation, and to obtain recording / reproducing characteristics and thermal fluctuation characteristics suitable for higher density recording.

  Further, the total content of Co, Cr, Pt and other elements described above contained in the magnetic particles 42 of the magnetic layer 4c is preferably 16 at% or less. When the total content of the above elements exceeds 16 at%, a phase other than the hcp phase is formed in the magnetic particles 42, so that the crystallinity and orientation of the magnetic particles 42 are disturbed, and as a result suitable for high-density recording. Recording / reproduction characteristics and thermal fluctuation characteristics cannot be obtained, which is not preferable.

  Examples of suitable materials for the magnetic layer 4c include CoCrPt and CoCrPtB. As the CoCrPtB system, the total content of Cr and B is preferably 18 at% or more and 28 at% or less.

  Suitable materials for the magnetic layer 4c include, for example, Co14-24Cr8-22Pt {Cr content 14-24at%, Pt content 8-22at%, balance Co} in CoCrPt series, Co10-24Cr8 ~ in CoCrPtB series. 22Pt0-16B {Cr content: 10-24at%, Pt content: 8-22at%, B content: 0-16at%, balance Co} is preferable. As other systems, in CoCrPtTa system, Co10-24Cr8-22Pt1-5Ta {Cr content 10-24at%, Pt content 8-22at%, Ta content 1-5at%, balance Co}, CoCrPtTaB system, In addition to Co10-24Cr8-22Pt1-5Ta1-10B {Cr content 10-24 at%, Pt content 8-22 at%, Ta content 1-5 at%, B content 1-10 at%, balance Co}, Examples of the material include CoCrPtBNd, CoCrPtTaNd, CoCrPtNb, CoCrPtBW, CoCrPtMo, CoCrPtCuRu, and CoCrPtRe.

The perpendicular coercive force (Hc) of the perpendicular magnetic layer 4 is preferably 3000 [Oe] or more. When the coercive force is less than 3000 [Oe], the recording / reproducing characteristics, particularly the frequency characteristics, are deteriorated, and the thermal fluctuation characteristics are also deteriorated, which is not preferable as a high-density recording medium.
The reverse magnetic domain nucleation magnetic field (-Hn) of the perpendicular magnetic layer 4 is preferably 1500 [Oe] or more. When the reverse domain nucleation magnetic field (-Hn) is less than 1500 [Oe], the thermal fluctuation resistance is poor, which is not preferable.

The average particle size of the magnetic particles 42 constituting the perpendicular magnetic layer 4 is preferably 3 to 12 nm. The average particle diameter of the magnetic particles 42 can be obtained, for example, by observing the perpendicular magnetic layer 4 with a TEM (transmission electron microscope) and image-processing the observed image.
The thickness of the perpendicular magnetic layer 4 is preferably 5 to 20 nm. If the thickness of the perpendicular magnetic layer 4 is less than the above, sufficient reproduction output cannot be obtained, and the thermal fluctuation characteristics also deteriorate. On the other hand, if the thickness of the perpendicular magnetic layer 4 exceeds the above range, the magnetic particles 42 in the perpendicular magnetic layer 4 are enlarged, increasing noise during recording and reproduction, and a signal / noise ratio (S / N ratio). And recording / reproducing characteristics represented by recording characteristics (OW) are not preferable.

  In the present invention, among the plurality of magnetic layers 4a, 4b, 4c constituting the perpendicular magnetic layer 4, the magnetic layer 4a on the nonmagnetic substrate 1 side is a magnetic layer having a granular structure, and the magnetic layer 4c on the protective layer 5 side is A magnetic layer having a non-granular structure containing no oxide is preferable. With this configuration, it is possible to more easily control and adjust each characteristic such as the thermal fluctuation characteristic, recording characteristic (OW), and S / N ratio of the magnetic recording medium.

  In the present invention, the perpendicular magnetic layer 4 can be composed of four or more magnetic layers. For example, in addition to the magnetic layers 4a and 4b, a magnetic layer having a granular structure may be formed, and a magnetic layer 4c containing no oxide may be provided on the three magnetic layers having the granular structure. However, the magnetic layer 4c not containing an oxide may have a two-layer structure provided on the magnetic layers 4a and 4b.

In the present invention, it is preferable to provide a nonmagnetic layer 7 (indicated by reference numerals 7a and 7b in FIGS. 1 and 3) between a plurality of magnetic layers constituting the perpendicular magnetic layer 4. By providing the nonmagnetic layer 7 with an appropriate thickness, magnetization reversal of individual films can be facilitated, and dispersion of magnetization reversal of the entire magnetic particles can be reduced. As a result, the S / N ratio can be further improved.
The thickness of the nonmagnetic layer 7 is a range in which the magnetostatic coupling of each layer constituting the perpendicular magnetic layer 4 is not completely cut, specifically 0.1 nm or more and 2 nm or less (more preferably 0.1 or more and 0.8 nm or less). It is preferable that

  When the three or more magnetic layers 4a, 4b, and 4c of the present invention are ferromagnetically coupled (ferro coupling, hereinafter referred to as FC) and magnetostatic coupling is completely broken, MH Since the loop becomes a loop that inverts in two stages, it can be easily discriminated. When this two-stage loop occurs, it means that the magnetic grains do not reverse all at once with respect to the magnetic field from the magnetic head, and as a result, the S / N ratio at the time of reproduction is significantly deteriorated and the resolution is lowered. Therefore, it is not preferable.

  When Ru or a Ru alloy is used as the nonmagnetic layer 7, AFC occurs in the range of 0.6 nm to 1.2 nm. In the present invention, it is essential that the magnetic layers 4a, 4b, 4c, not AFC, are magnetostatically coupled by FC.

As the nonmagnetic layer 7 provided between the magnetic layers 4a, 4b and 4c constituting the perpendicular magnetic layer 4, it is preferable to use a material having an hcp structure. Specifically, for example, Ru, Ru alloy, CoCr alloy, CoCrX ₁ alloy _{(X 1} is, Pt, Ta, Zr, Re , Ru, Cu, Nb, Ni, Mn, Ge, Si, O, N, W , Mo, Ti, V, Zr and B represent at least one element or two or more elements).

When a CoCr-based alloy is used as the nonmagnetic layer 7 provided between the magnetic layers 4a, 4b, and 4c constituting the perpendicular magnetic layer 4, the Co content is preferably in the range of 30 to 80 at%. This is because within this range, the coupling between the magnetic layers can be adjusted to be small.
Further, when an alloy having an hcp structure is used as the nonmagnetic layer 7 provided between the magnetic layers 4a, 4b, and 4c, for example, an alloy such as Ru, Re, Ti, Y, Hf, and Zn can also be used.

Further, as the nonmagnetic layer 7 provided between the magnetic layers 4a, 4b, and 4c constituting the perpendicular magnetic layer 4, a metal or alloy having another structure within a range that does not impair the crystallinity and orientation of the upper and lower magnetic layers. Etc. can also be used. Specifically, for example, Pd, Pt, Cu, Ag, Au, Ir, Mo, W, Ta, Nb, V, Bi, Sn, Si, Al, C, B, Cr, or an alloy thereof is used. it can. In particular, as a Cr alloy, CrX ₂ (X ₂ represents at least one element selected from Ti, W, Mo, Nb, Ta, Si, Al, B, C, and Zr. ) And the like can be preferably used. The Cr content in the Cr alloy is preferably 60 at% or more.

The nonmagnetic layer 7 provided between the magnetic layers 4a, 4b and 4c constituting the perpendicular magnetic layer 4 has a structure in which metal particles of the above alloy are dispersed in an oxide, metal nitride, or metal carbide. It is preferable to use it. Further, it is more preferable that the metal particles have a columnar structure penetrating the nonmagnetic layer 7 vertically. In order to obtain such a structure, it is preferable to use an alloy material containing an oxide, a metal nitride, or a metal carbide. Specifically, as the oxide, for example, SiO ₂ , Al ₂ O ₃ , Ta ₂ O ₅ , Cr ₂ O ₃ , MgO, Y ₂ O ₃ , TiO _2, etc. As the metal nitride, for example, AlN, Si For example, TaC, BC, SiC, or the like can be used as the metal carbide such as ₃ N ₄ , TaN, or CrN. Furthermore, for example, CoCr—SiO ₂ , CoCr—TiO ₂ , CoCr—Cr ₂ O ₃ , CoCrPt—Ta ₂ O ₅ , Ru—SiO ₂ , Ru—Si ₃ N ₄ , Pd—TaC, and the like can be used.

  The content of oxide, metal nitride, or metal carbide in the nonmagnetic layer 7 provided between the magnetic layers 4a, 4b, and 4c constituting the perpendicular magnetic layer 4 is determined by the crystal growth and crystal orientation of the perpendicular magnetic film 4. It is preferable that the content is not impaired, and it is preferably 4 mol% or more and 30 mol% or less with respect to the alloy constituting the nonmagnetic layer 7.

  When the content of oxide, metal nitride, or metal carbide in the nonmagnetic layer 7 exceeds the above range, oxide, metal nitride, or metal carbide remains in the metal particles of the alloy, and the metal particles In addition to impairing crystallinity and orientation, oxides, metal nitrides, or metal carbides are also deposited on the top and bottom of the metal particles, making it difficult for the metal particles to have a columnar structure that vertically penetrates the nonmagnetic layer 7. This is not preferable because the crystallinity and orientation of the magnetic layer formed on the magnetic layer 7 may be impaired. On the other hand, when the content of the oxide, metal nitride, or metal carbide in the nonmagnetic layer 7 is less than the above range, the effect of adding the oxide, metal nitride, or metal carbide cannot be obtained. Therefore, it is not preferable.

"Protective layer"
A protective layer 5 is formed on the perpendicular magnetic layer 4. The protective layer 5 prevents corrosion of the perpendicular magnetic layer 4 and prevents damage to the medium surface when the magnetic head comes into contact with the magnetic recording medium. As the protective layer 5, a conventionally known material can be used. For example, a material containing C, SiO ₂ , or ZrO ₂ can be used. The thickness of the protective layer 5 is preferably 1 to 10 nm from the viewpoint of high recording density because the distance between the magnetic head and the magnetic recording medium can be reduced. The protective layer 5 is formed using, for example, a CVD (chemical vapor deposition) method.

"Lubrication layer"
A lubricating layer 6 is formed on the protective layer 5. For the lubricating layer 6, it is preferable to use a lubricant such as perfluoropolyether, fluorinated alcohol, fluorinated carboxylic acid, or the like. The lubricating layer 6 is formed using, for example, a dipping method.

  In the magnetic recording medium of the present embodiment, the perpendicular magnetic layer 4 includes columnar crystals that are continuous in the thickness direction together with the crystal grains constituting the orientation control layer 3, so that the perpendicular magnetic layer 4 has excellent perpendicular orientation. Become. In the magnetic recording medium of this embodiment, since the orientation control layer 3 includes a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more, the orientation control layer 3 exhibits magnetism. Therefore, the magnetic recording medium of the present embodiment increases the thickness of the orientation control layer 3 in order to obtain the perpendicular magnetic layer 3 including columnar crystals continuous in the thickness direction together with the crystal grains constituting the orientation control layer 3. Even when the recording distance between the magnetic underlayer 2 and the magnetic head is increased, the magnetic recording medium has sufficiently high recording characteristics (OW) suitable for high-density recording. As a result, according to the magnetic recording medium of this embodiment, a magnetic recording medium having a signal / noise ratio (S / N ratio), recording characteristics (OW), and thermal fluctuation characteristics suitable for high-density recording can be realized.

In the magnetic recording medium of this embodiment, the orientation control layer 3 is disposed on the first orientation control layer 3a disposed on the soft magnetic underlayer 2 side, and on the perpendicular magnetic layer 4 side of the first orientation control layer 3a. The second orientation control layer 3b, and the first orientation control layer 3a includes a crystal serving as a nucleus of a columnar crystal,
The second orientation control layer 3b includes a columnar crystal that is continuous in the thickness direction with a crystal serving as a nucleus and has a dome-like convex portion formed at the top, and includes a first orientation control layer 3a and a second orientation control layer. Since both 3b include a Ru alloy layer, the orientation control layer 3 and the perpendicular magnetic layer 4 can be miniaturized and have high recording characteristics (OW) suitable for higher density recording.

(Magnetic recording / reproducing device)
FIG. 4 shows an example of a magnetic recording / reproducing apparatus to which the present invention is applied.
This magnetic recording / reproducing apparatus includes a magnetic recording medium 50 having the configuration shown in FIG. 1, a medium driving unit 51 that rotationally drives the magnetic recording medium 50, a magnetic head 52 that records and reproduces information on the magnetic recording medium 50, and A head driving unit 53 that moves the magnetic head 52 relative to the magnetic recording medium 50 and a recording / reproducing signal processing system 54 are provided.

  The recording / reproduction signal processing system 54 can process data input from the outside and send a recording signal to the magnetic head 52, process a reproduction signal from the magnetic head 52, and send the data to the outside. . As the magnetic head 52 used in the magnetic recording / reproducing apparatus to which the present invention is applied, a magnetic head having a GMR element utilizing a giant magnetoresistive effect (GMR) as a reproducing element and suitable for higher recording density is used. it can.

  The magnetic recording / reproducing apparatus shown in FIG. 4 includes the magnetic recording medium 50 shown in FIG. 1 as an example of the magnetic recording medium of the present invention, and a magnetic head 52 that records and reproduces information on the magnetic recording medium 50. Therefore, the magnetic recording medium is provided with a magnetic recording medium capable of obtaining a signal / noise ratio (S / N ratio), recording characteristics (OW), and thermal fluctuation characteristics suitable for high-density recording.

Hereinafter, the effects of the present invention will be made clearer by examples. In addition, this invention is not limited to a following example, In the range which does not change the summary, it can change suitably and can implement.
(Experimental Examples 1-30)
Magnetic recording media of Experimental Examples 1 to 30 were manufactured and evaluated by the manufacturing method described below.

First, a cleaned glass substrate (manufactured by Konica Minolta, 2.5 inch outer diameter) is housed in a film forming chamber of a DC magnetron sputtering apparatus (C-3040, manufactured by Anelva), and the ultimate vacuum is 1 × 10 ^−3. After evacuating the film formation chamber to ⁵ Pa, an adhesion layer having a thickness of 10 nm was formed on the glass substrate using a Cr target.
On the adhesion layer thus obtained, a target of 70Co-20Fe-5Zr-5Ta {Fe content 20at%, Zr content 5at%, Ta content 5at%, balance Co} is used at 100 ° C or lower. A soft magnetic layer with a layer thickness of 25 nm is formed at a substrate temperature of, and a Ru layer is formed thereon with a layer thickness of 0.7 nm, and a soft magnetic layer of 70Co-20Fe-5Zr-5Ta is formed with a layer thickness of 25 nm. This was formed into a soft magnetic underlayer.

Next, an orientation control layer was formed on the soft magnetic underlayer.
First, an orientation control layer having the composition and layer thickness shown in Tables 2 and 3 was formed on the soft magnetic underlayer at the sputtering gas pressure (gas pressure) shown in Tables 2 and 3.

Thereafter, a perpendicular magnetic layer was formed on the orientation control layer.
First, 91 (Co15Cr16Pt) -6 (SiO ₂ ) -3 (TiO ₂ ) {Cr content of 15 at%, Pt content of 18 at%, the remaining Co is 91 mol%, and the oxidation is made of SiO ₂ on the orientation control layer. A magnetic layer having a composition of 6 mol% of an oxide, 3 mol% of an oxide composed of Cr ₂ O ₃ and 3 mol% of an oxide composed of TiO ₂ is formed with a sputtering gas pressure of 2 Pa and a layer thickness of 9 nm.

Next, a nonmagnetic layer made of 88 (Co30Cr) -12 (TiO ₂ ) was formed on the magnetic layer with a layer thickness of 0.3 nm.
Next, a magnetic layer made of 92 (Co11Cr18Pt) -5 (SiO ₂ ) -3 (TiO ₂ ) was formed on the nonmagnetic layer with a sputtering gas pressure of 2 Pa and a layer thickness of 6 nm.

Next, a nonmagnetic layer made of Ru was formed with a layer thickness of 0.3 nm on the magnetic layer.
Next, on the nonmagnetic layer, a magnetic layer having a sputtering gas pressure of 0.6 Pa using a target composed of 63Co20Cr14Pt3B {Cr content 20at%, Pt content 14at%, B content 3at%, balance Co}. Was deposited with a layer thickness of 7 nm.

  Next, a protective layer having a thickness of 3.0 nm was formed by a CVD method, and then a lubricating layer made of perfluoropolyether was formed by a dipping method to produce magnetic recording media of Experimental Examples 1 to 30.

In order to investigate the orientation (Δθ50) of the CoRu alloy layer, FeRu alloy layer, and Ru layer constituting the orientation control layer of the magnetic recording media of Experimental Examples 1 to 17 obtained in this way, X-ray spectroscopic analysis was performed. (XRD) was performed, and the half width (FWHM) of the rocking curves of Ru (0002) and Co (0002) were measured. The results are shown in Table 2.
As shown in Table 2, the orientation (Δθ50) of the CoRu alloy layer and the FeRu alloy layer is larger than that of the Ru layer not containing Fe or Co, but even if it contains 80 at% of Fe or Co. It was confirmed that the decrease in orientation was in the range of 0.38 to 0.63 ° and was as small as about 0.5 °.

  In addition, with respect to the magnetic recording media of Experimental Examples 18 to 30 obtained in this way, a signal / noise ratio (S / N ratio) as a recording / reproducing characteristic using a read / write analyzer RWA1632 and a spin stand S1701MP manufactured by GUZIK. ), Recording characteristics (OW), and thermal fluctuation characteristics. The results are shown in Table 4.

As the magnetic head, a head using a single pole magnetic pole on the writing side and a TMR element on the reading side was used.
The signal / noise ratio (S / N ratio) was measured at a recording density of 750 kFCI.
Regarding the recording characteristics (OW), first, a 750 kFCI signal was written, then a 100 kFCI signal was overwritten, a high frequency component was taken out by a frequency filter, and the data writing ability was evaluated by the residual ratio.

Regarding thermal fluctuation characteristics, after writing at a recording density of 50 kFCI under the condition of 70 ° C., the output attenuation rate (%) with respect to the playback output 1 second after writing is calculated using the following (Formula 1). did.
(So-S) × 100 / (So) (Formula 1)
In (Equation 1), So represents a reproduction output when one second has elapsed after writing, and S represents a reproduction output after 10,000 seconds.

  Further, the coercive force (Hc) of the magnetic recording media of Experimental Examples 18 to 30 was measured. The results are shown in Table 4.

As shown in Table 3 and Table 4, the orientation control layer is made of a Ru alloy having a Co magnetization of 66 at% or more or a Fe content of 73 at% and a saturation magnetization (Ms) of 50 emu / cc or more. In the magnetic recording media of Experimental Examples 19 to 30, which are examples of the above, the results of the recording characteristics (OW) are higher than those of Experimental Example 18 in which the alignment control layer as a comparative example is composed only of Ru layers having the same layer thickness. I was able to confirm.
Further, as shown in Tables 3 and 4, it was confirmed that all of the magnetic recording media of Experimental Examples 19 to 30 were comparable to Experimental Example 18 in the S / N ratio, thermal fluctuation, and Hc results.

DESCRIPTION OF SYMBOLS 1 ... Nonmagnetic board | substrate, 2 ... Soft magnetic underlayer, 3 ... Orientation control layer, 3a ... 1st orientation control layer, 3b ... 2nd orientation control layer, 4 ... Perpendicular magnetic layer, 4a ... Lower magnetic layer, 4b ... Middle magnetic layer, 4c ... upper magnetic layer, 5 ... protective layer, 6 ... lubricating layer, 7 ... nonmagnetic layer, 7a ... lower nonmagnetic layer, 7b ... upper nonmagnetic layer, 8 ... nonmagnetic underlayer 15 ... oxide, S1, S2, S3 ... columnar crystal, S1a ... uneven surface, 41 ... oxide, 42 ... magnetic particle, 50 ... magnetic recording medium, 51 ... medium drive unit, 52 ... magnetic head, 53 ... head Drive unit 54... Recording / reproduction signal processing system.

Claims (5)

On the nonmagnetic substrate, a soft magnetic underlayer, an orientation control layer for controlling the orientation of the layer immediately above, and a perpendicular magnetic layer having an easy axis of magnetization oriented perpendicularly to the nonmagnetic substrate, A magnetic recording medium comprising at least laminated layers,
The orientation control layer includes a Ru alloy layer containing a magnetic material and having a saturation magnetization of 50 emu / cc or more,
The magnetic recording medium, wherein the perpendicular magnetic layer includes columnar crystals continuous in a thickness direction together with crystal grains constituting the orientation control layer. The orientation control layer comprises a first orientation control layer disposed on the soft magnetic underlayer side and a second orientation control layer disposed on the perpendicular magnetic layer side of the first orientation control layer;
The first orientation control layer includes a crystal serving as a nucleus of a columnar crystal, the second orientation control layer is continuous with the crystal serving as a nucleus in the thickness direction, and a dome-shaped convex portion is formed at the top. Containing the columnar crystals formed,
2. The magnetic recording medium according to claim 1, wherein one or both of the first orientation control layer and the second orientation control layer includes the Ru alloy layer.   The magnetic recording medium according to claim 1, wherein the magnetic material is Co or Fe.   The Ru alloy layer contains Co in a range of 66 at% to 80 at% and has a saturation magnetization in a range of 50 emu / cc to 700 emu / cc and / or Fe of 73 at% to 80 at% 4. The magnetic recording medium according to claim 1, comprising a FeRu alloy layer having a saturation magnetization in the range of 50 emu / cc to 500 emu / cc. . The magnetic recording medium according to any one of claims 1 to 4,
A magnetic recording / reproducing apparatus comprising: a magnetic head for recording / reproducing information with respect to the magnetic recording medium.

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