JP2011079780A - Powder cosmetic - Google Patents

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JP2011079780A
JP2011079780A JP2009233953A JP2009233953A JP2011079780A JP 2011079780 A JP2011079780 A JP 2011079780A JP 2009233953 A JP2009233953 A JP 2009233953A JP 2009233953 A JP2009233953 A JP 2009233953A JP 2011079780 A JP2011079780 A JP 2011079780A
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powder
sodium chloride
cosmetics
effect
cosmetic
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JP5592095B2 (en
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Sosei Oka
宗清 岡
Hiroshi Asano
浩志 浅野
Kunihiro Miyamoto
國寛 宮本
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Nippon Menard Cosmetic Co Ltd
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Nippon Menard Cosmetic Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To solve the problem that although it is hardly necessary to consider the contamination of powder cosmetics with microorganisms in an unused state, the contamination by mixing with water and from the hands, a cosmetic powder puff, the air and the like has to be considered after starting the use and due to this, an aseptic is incorporated in consideration of antibacterial properties even in these powder cosmetics but sufficient antibacterial activity cannot be obtained with these powder cosmetics. <P>SOLUTION: A powder cosmetic contains sodium chloride as an essential component. The amount of the sodium chloride incorporated is not particularly limited and normally the sodium chloride may be incorporated in an amount of 0.001-1 wt.%. A preferred amount is 0.01-0.5 wt.%. With amounts of 0.001 wt.% or less the effect is sometimes not sufficient and with amounts of 1 wt.% or more there is no increase in the effect, and such amounts are uneconomical. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、粉体化粧料に関する。具体的には、塩化ナトリウムを用いた抗菌性に優れた粉体化粧料に関する。   The present invention relates to a powder cosmetic. Specifically, the present invention relates to a powder cosmetic excellent in antibacterial properties using sodium chloride.

従来より、化粧品として石けんや化粧水、乳液、クリームなどの基礎化粧品、おしろい、ファンデーション、口紅、頬紅、アイライナーなどのメイクアップ化粧品、香水類、シャンプー、リンス、ヘアカラーなどの頭髪用化粧品などが上市されている。   Conventionally, cosmetics include basic cosmetics such as soap, lotion, milky lotion, cream, makeup cosmetics such as funny, foundation, lipstick, blusher, and eyeliner, and cosmetics for hair such as perfumes, shampoos, rinses, and hair colors. It is on the market.

これらの化粧品は、かびや細菌などが生育しやすい栄養分を多く含んでおり、使用を重ねている間に化粧料中にこれらの微生物が混入し、繁殖する可能性が高い。特に化粧水や乳液、クリームなどの化粧品は水や油分を大量に含み、微生物が非常に繁殖しやすい条件下にある。従ってこれらの化粧品では、使用中に外部からかびや細菌が混入しても繁殖しないよう防腐剤を配合して品質の劣化を防止している。   These cosmetics contain a large amount of nutrients in which fungi, bacteria, etc. are likely to grow, and there is a high possibility that these microorganisms will be mixed in the cosmetics and propagate during repeated use. In particular, cosmetics such as lotion, milky lotion, and cream contain a large amount of water and oil, and are under conditions that allow microorganisms to grow very easily. Therefore, in these cosmetics, preservatives are blended to prevent deterioration of quality so that they do not propagate even if mold or bacteria are mixed from the outside during use.

これらの化粧品に用いられる公知の防腐剤としては、サリチル酸塩やパラオキシ安息香酸エステル類のフェノール類、ソルビン酸、デヒドロ酢酸、ビサボロール等の抗菌性精油が挙げられる。   Known antiseptics used in these cosmetics include antimicrobial essential oils such as salicylates and phenols of paraoxybenzoates, sorbic acid, dehydroacetic acid, bisabolol and the like.

しかし、適切な抗菌効果を保持させんとして、防腐剤を多量に配合したり、防腐効果の異なる数種の防腐剤を選択して配合する方法が用いられている。   However, in order to maintain an appropriate antibacterial effect, a method of blending a large amount of preservatives or selecting and blending several kinds of preservatives having different antiseptic effects is used.

一方、上記した化粧品中には、おしろいやベビーパウダー、パウダーファンデーション、アイシャドウなど粉体を主体とした粉体化粧料も存在する。これらの粉体化粧料の基材には、一般的にタルクやマイカ、セリサイト、酸化亜鉛などの各種無機、有機粉体が使用される。そして、これらの基材に酸化チタンや黄酸化鉄やベンガラなどの顔料、あるいはアラントインクロルヒドロキシアルミニウムやフェノールスルホン酸亜鉛等の収れん剤その他、必要に応じて油脂などの油分等が配合される。   On the other hand, among the cosmetics described above, there are also powder cosmetics mainly composed of powder such as funny, baby powder, powder foundation, and eye shadow. As the base material for these powder cosmetics, various inorganic and organic powders such as talc, mica, sericite, and zinc oxide are generally used. These base materials are blended with pigments such as titanium oxide, yellow iron oxide, and bengara, astringents such as allantochlorohydroxyaluminum and zinc phenolsulfonate, and oils such as fats and oils as necessary.

通常これらの粉体化粧料においては、処方上水やアルコールを含むものではなく、未使用の状態では微生物の汚染を考慮する必要性は少ないが、使用開始後には水が混入したり、手や化粧パフ及び大気中等からの汚染を考慮する必要がある。このため、これらの粉体化粧料においても抗菌性を考慮して防腐剤が配合されている。   Normally, these powder cosmetics do not contain water or alcohol in the formulation, and there is little need to consider microbial contamination when not in use. It is necessary to consider contamination from cosmetic puffs and air. For this reason, antiseptic | preservative is mix | blended also in these powder cosmetics in consideration of antibacterial property.

しかしながら、これらの粉体化粧料では十分な抗菌活性が得られなかった。これは次の理由によるものと推測される。すなわち、粉体化粧料は化粧水や乳液、クリーム、シャンプー、リンスなどと異なり、油分が配合されるものの、その特性上、水やアルコールが殆ど配合されることがない。このため、粉体化粧料中に防腐剤を配合したとしても、粉体化粧料中で防腐剤が凝集すると共に不均一に分散して存在する。また、上記粉体化粧料中には水分が少なくその効果を十分に発揮できないとも考えられる。   However, sufficient antibacterial activity was not obtained with these powder cosmetics. This is presumed to be due to the following reason. That is, unlike cosmetic lotions, milky lotions, creams, shampoos, rinses, etc., powder cosmetics contain oil, but due to their characteristics, water and alcohol are hardly added. For this reason, even if a preservative is blended in the powder cosmetic, the preservative aggregates and is unevenly dispersed in the powder cosmetic. In addition, it is considered that the powder cosmetics have a small amount of moisture and cannot fully exhibit their effects.

ところで塩化ナトリウムは従来W/O乳化組成物の使用性改善の目的に配合されたり(特許文献1)、収斂剤として配合されたり(特許文献2)、粉末状マッサージ料において物理的洗浄効果やマッサージ効果を期待して配合されたり(特許文献3)、枠練り石鹸で透明性向上の目的で配合されていた(特許文献4)。しかし抗菌を目的に塩化ナトリウムを配合するという思想は全くなかった。   By the way, sodium chloride is conventionally blended for the purpose of improving the usability of the W / O emulsion composition (Patent Document 1) or blended as an astringent (Patent Document 2). It was blended with the expectation of an effect (Patent Document 3), and blended for the purpose of improving transparency with a frame kneaded soap (Patent Document 4). However, there was no idea of adding sodium chloride for antibacterial purposes.

特開平11−106310号公報JP 11-106310 A 特開平10−330240号公報Japanese Patent Laid-Open No. 10-330240 特開平10−330241号公報Japanese Patent Laid-Open No. 10-330241 特開2004−256805号公報JP 2004-256805 A

本発明は上記従来技術の問題点に鑑みてなされたものであって、安全性に優れた塩化ナトリウムからなる粉末を用いて、かび、酵母、大腸菌や緑膿菌等の微生物に対して、十分に発育抑制効果を有する抗菌性を持った粉体化粧料を提供することにある。   The present invention has been made in view of the above-mentioned problems of the prior art, and is sufficient for microorganisms such as fungi, yeast, Escherichia coli and Pseudomonas aeruginosa using a powder made of sodium chloride having excellent safety. Another object of the present invention is to provide an antibacterial powder cosmetic having a growth inhibitory effect.

そこで、上記問題点を解決すべく本発明者らは鋭意検討を重ねた結果、塩化ナトリウムを必須成分として配合することによって、著しい抗菌効果、防腐効果を向上させることを見い出し、本発明を完成するに至った。   Therefore, as a result of intensive investigations to solve the above problems, the present inventors have found that by adding sodium chloride as an essential component, a remarkable antibacterial effect and antiseptic effect are improved, and the present invention is completed. It came to.

本発明に係る粉体化粧料は、塩化ナトリウムを必須成分として含有することを特徴としている。本発明においては塩化ナトリウムの配合量は特に限定されないが通常0.001〜1重量%配合するのがよい。好ましくは0.01〜0.5重量%である。0.001重量%以下では効果が十分ではない場合があり、また1重量%以上では効果の増強がなく非経済的である。   The powder cosmetic according to the present invention is characterized by containing sodium chloride as an essential component. In this invention, the compounding quantity of sodium chloride is although it does not specifically limit, Usually, 0.001-1 weight% is good to mix | blend. Preferably it is 0.01 to 0.5 weight%. If it is 0.001% by weight or less, the effect may not be sufficient, and if it is 1% by weight or more, the effect is not enhanced and it is uneconomical.

本発明に用いる塩化ナトリウム粉体化粧料の粒子径は特に限定されず、そのものを配合してもいいが、好ましくは10μm以下である。10μm以上では使用感に影響がある場合があるからである。   The particle diameter of the sodium chloride powder cosmetic used in the present invention is not particularly limited, and may be blended, but is preferably 10 μm or less. This is because the feeling of use may be affected when the thickness is 10 μm or more.

塩化ナトリウムの微細化の方法は特に限定されないが、ボールミル、アトマイザー、ミキサー、ライカイ機等で微粉化してもいい。   The method for refining sodium chloride is not particularly limited, but it may be finely pulverized with a ball mill, an atomizer, a mixer, a likai machine or the like.

本発明においては他の防腐剤が無くても塩化ナトリウムのみで十分な効果を奏するが、他の防腐剤と併用しても良い。   In the present invention, sodium chloride alone provides a sufficient effect even without other preservatives, but may be used in combination with other preservatives.

本発明によれば高い抗菌効果を奏する粉体化粧料を得ることができる。   According to the present invention, a powder cosmetic that exhibits a high antibacterial effect can be obtained.

本発明における粉体化粧料は、上記したように、タルクやマイカ、セリサイト、酸化亜鉛などの粉体を主成分とするものであって、粉末状若しくはプレスなどによって成形された固形状の化粧品をいい、水やアルコールなどに溶解した液状物や粘性を有する剤型を除くものである。例えば、白粉類やファンデーション類、頬紅類、アイシャドウ類に代表される。より具体的には、白粉類として粉白粉、固形白粉、紙白粉、さらには、ベビーパウダー、タルカムパウダーが挙げられる。また、ファンデーション類としていわゆるパウダリータイプ、両用タイプ、ケーキタイプが挙げられる。頬紅類としては固形頬紅、アイシャドウ類としては固形粉末状のアイシャドウが挙げられる。さらに、これらの分類には含まれないが、例えばビタミンCやその誘導体を主成分とし、用時水やアルコールに溶解して用いられるような粉末状、固形状の化粧品についても適用されるものである。 As described above, the powder cosmetic in the present invention is mainly composed of powders such as talc, mica, sericite, and zinc oxide, and is a solid cosmetic that is formed by powder or pressing. It excludes liquid substances and viscous dosage forms dissolved in water or alcohol. Examples thereof include white powders, foundations, blushers, and eye shadows. More specifically, examples of white powder include powdered white powder, solid white powder, paper white powder, and baby powder and talcum powder. Examples of foundations include so-called powdery type, amphibious type, and cake type. Examples of blushers include solid blushers, and examples of eye shadows include solid powder eye shadows. Furthermore, although not included in these classifications, for example, it is also applicable to powdered and solid cosmetics which are mainly composed of vitamin C and its derivatives and dissolved in water or alcohol for use. is there.

本発明に用いられる塩化ナトリウムは、粉体化粧料の構成成分として使用されるが、その他の構成成分は従来の構成成分と何ら変わりなく用いることができる。例えば、各種の無機粉末、例えばタルク、カオリン、シリカ、雲母、セリサイト、炭酸カルシウム、炭酸マグネシウム、ケイ酸アルミニウム、ケイ酸カルシウム、ケイ酸マグネシウム、硫酸バリウム、リン酸カルシウムなどが、また、各種の有機粉末、例えばナイロン粉末、ポリエチレン粉末、ポリスチレン粉末、ポリメタクリル酸メチル粉末、ポリフッ化エチレン粉末、セルロース粉末などが、その他無機顔料、有機顔料などの粉末成分が用いられる。これら以外にも必要に応じて、各種の油性成分や界面活性剤などを用いることができる。さらに、従来から汎用されているパラオキシ安息香酸エステルなどのような各種合成抗菌剤あるいは天然抗菌剤と併用しても差し支えないものであるが、本発明においてはこれらの抗菌剤を用いることなく抗菌作用を得ることができる。   Sodium chloride used in the present invention is used as a constituent of powder cosmetics, but other constituents can be used without any difference from conventional constituents. For example, various inorganic powders such as talc, kaolin, silica, mica, sericite, calcium carbonate, magnesium carbonate, aluminum silicate, calcium silicate, magnesium silicate, barium sulfate, calcium phosphate, and various organic powders For example, nylon powder, polyethylene powder, polystyrene powder, polymethyl methacrylate powder, polyfluorinated ethylene powder, cellulose powder, and other powder components such as inorganic pigments and organic pigments are used. In addition to these, various oil components and surfactants can be used as necessary. Furthermore, it can be used in combination with various synthetic antibacterial agents such as paraoxybenzoate esters that have been widely used in the past or natural antibacterial agents. Can be obtained.

以上説明したように本発明は、塩化ナトリウムからなる粉末を配合することによって、従来では不十分であった粉体化粧料における抗菌効果を向上させるものである。   As described above, the present invention improves the antibacterial effect in powder cosmetics, which has heretofore been insufficient, by blending powder made of sodium chloride.

このように本発明においては、塩化ナトリウムを配合して粉体化粧料の抗菌性、保存性を向上させるものであって、通常の混合処理を行えば足りるものである。   As described above, in the present invention, sodium chloride is added to improve the antibacterial properties and preservability of the powder cosmetic, and it is sufficient to perform normal mixing treatment.

次に、本発明について以下の実施例に基づいてさらに詳細に説明する。なお、本発明は以下の実施例に限られないのはいうまでもない。また、以下の説明において「%」は、「重量%」を意味する。   Next, the present invention will be described in more detail based on the following examples. Needless to say, the present invention is not limited to the following examples. In the following description, “%” means “% by weight”.

実施例1(抗菌性試験)
試料30gに菌液を接種後、混釈法により菌数の変化を調べた。尚接種菌はカビ、酵母、バクテリアを用いて、4週間経過時までの菌数変化により防腐力を評価し、得られた結果を以下の4段階の基準に分類した。尚以下の分類のうち◎ないし○のものを合格と判定した。
Example 1 (Antimicrobial test)
After inoculating the bacterial solution in 30 g of the sample, the change in the number of bacteria was examined by the pour method. As the inoculum, fungi, yeast and bacteria were used, and the antiseptic power was evaluated based on the change in the number of bacteria until the lapse of 4 weeks, and the obtained results were classified into the following four criteria. Of the following classifications, ◎ or ○ were judged as acceptable.

◎:早急に効果が認められる。
○:徐々に効果が認められる。
△:ほとんど効果が認められない。
×:全く効果が認められない。
A: An effect is recognized immediately.
○: The effect is gradually recognized.
Δ: Almost no effect is recognized.
X: An effect is not recognized at all.

下記表1、表2において示した処方の本発明の粉体化粧料の一態様としてのおしろい、固形おしろい及びその比較例について上記防腐力判定試験を行い、その結果を記載した。なお、これらのおしろい、固形おしろいの製造方法は、一般的に用いられている方法に従った。   The above-mentioned antiseptic ability judgment test was conducted on the powdery cosmetics of the present invention having the formulations shown in Tables 1 and 2 below, the solid powder and the comparative examples thereof, and the results were described. In addition, the manufacturing method of these funny and solid surprises followed the method generally used.

実施例2(粉おしろい)
成分名 配合量(%)
タルク 75.9
マイカ 10.0
セリサイト 10.0
二酸化チタン 3.0
塩化ナトリウム (平均粒子径3μm) 0.1
計 100.0
Example 2 (powdered)
Ingredient name Compounding amount (%)
Talc 75.9
Mica 10.0
Sericite 10.0
Titanium dioxide 3.0
Sodium chloride (average particle size 3 μm) 0.1
Total 100.0

実施例3(固形おしろい)
成分名 配合量(%)
タルク 68.6
マイカ 10.0
セリサイト 10.0
二酸化チタン 3.0
スクワラン 5.0
パラオキシ安息香酸ブチル 0.1
塩化ナトリウム (平均粒子径5μm) 0.1
計 100.0
Example 3 (Solid white)
Ingredient name Compounding amount (%)
Talc 68.6
Mica 10.0
Sericite 10.0
Titanium dioxide 3.0
Squalane 5.0
Butyl paraoxybenzoate 0.1
Sodium chloride (average particle size 5 μm) 0.1
Total 100.0

実施例4(ベビーパウダー)
成分名 配合量(%)
タルク 96.7
酸化亜鉛 3.0
塩化ナトリウム (平均粒子径1μm) 0.3
計 100.0
Example 4 (baby powder)
Ingredient name Compounding amount (%)
Talc 96.7
Zinc oxide 3.0
Sodium chloride (average particle size 1 μm) 0.3
Total 100.0

実施例5(パウダーファンデーション)
成分名 配合量(%)
タルク 15.0
マイカ 30.0
セリサイト 18.2
ナイロンパウダー 10.0
二酸化チタン 16.0
ベンガラ 0.5
黄酸化鉄 1.0
黒酸化鉄 0.2
スクワラン 5.0
ラノリン 1.0
ミリスチン酸オクチルドデシル 2.0
モノオレイン酸ソルビタン 1.0
塩化ナトリウム (平均粒子径3μm) 0.01
パラオキシ安息香酸メチル 0.09
計 100.0
Example 5 (powder foundation)
Ingredient name Compounding amount (%)
Talc 15.0
Mica 30.0
Sericite 18.2
Nylon powder 10.0
Titanium dioxide 16.0
Bengala 0.5
Yellow iron oxide 1.0
Black iron oxide 0.2
Squalane 5.0
Lanolin 1.0
Octyldodecyl myristate 2.0
Sorbitan monooleate 1.0
Sodium chloride (average particle size 3μm) 0.01
Methyl paraoxybenzoate 0.09
Total 100.0

実施例6(両用ファンデーション)
成分名 配合量(%)
シリコーン処理タルク 22.0
シリコーン処理マイカ 44.9
ナイロンパウダー 5.0
シリコーン処理微粒子二酸化チタン 5.0
シリコーン処理二酸化チタン 10.0
シリコーン処理ベンガラ 0.5
シリコーン処理黄酸化鉄 1.0
シリコーン処理黒酸化鉄 0.2
スクワラン 4.0
固形パラフィン 0.5
ジメチルポリシロキサン 4.0
パラメトキシケイ皮酸オクチル 2.0
塩化ナトリウム (平均粒子径10μm) 0.9
計 100.0
Example 6 (both-use foundation)
Ingredient name Compounding amount (%)
Silicone-treated talc 22.0
Silicone-treated mica 44.9
Nylon powder 5.0
Silicone-treated fine particle titanium dioxide 5.0
Silicone-treated titanium dioxide 10.0
Silicone treated bengara 0.5
Silicone-treated yellow iron oxide 1.0
Silicone-treated black iron oxide 0.2
Squalane 4.0
Solid paraffin 0.5
Dimethylpolysiloxane 4.0
Octyl paramethoxycinnamate 2.0
Sodium chloride (average particle size 10μm) 0.9
Total 100.0

実施例7(ケーキファンデーション)
成分名 配合量(%)
タルク 27.8
マイカ 24.43
セリサイト 10.0
二酸化チタン 10.0
酸化亜鉛 5.0
ベンガラ 0.5
黄酸化鉄 1.0
黒酸化鉄 0.2
スクワラン 10.0
イソステアリン酸 3.0
ミリスチン酸オクチルドデシル 4.0
モノオレイン酸ソルビタン 3.0
パラメトキシケイ皮酸オクチル 1.0
パラオキシ安息香酸メチル 0.02
塩化ナトリウム (平均粒子径3μm) 0.05
計 100.0
Example 7 (cake foundation)
Ingredient name Compounding amount (%)
Talc 27.8
Mica 24.43
Sericite 10.0
Titanium dioxide 10.0
Zinc oxide 5.0
Bengala 0.5
Yellow iron oxide 1.0
Black iron oxide 0.2
Squalane 10.0
Isostearic acid 3.0
Octyldodecyl myristate 4.0
Sorbitan monooleate 3.0
Octyl paramethoxycinnamate 1.0
Methyl paraoxybenzoate 0.02
Sodium chloride (average particle size 3μm) 0.05
Total 100.0

実施例8(頬紅)
成分名 配合量(%)
マイカ 23.0
セリサイト 71.6
ベンガラ 0.05
黒酸化鉄 0.05
赤色223号 0.1
流動パラフィン 5.0
塩化ナトリウム (平均粒子径5μm) 0.2
計100.0
Example 8 (blusher)
Ingredient name Compounding amount (%)
Mica 23.0
Sericite 71.6
Bengala 0.05
Black iron oxide 0.05
Red 223 0.1
Liquid paraffin 5.0
Sodium chloride (average particle size 5 μm) 0.2
Total 100.0

実施例9(アイシャドウ)
成分名 配合量(%)
マイカ 34.55
セリサイト 45.9
群青 2.0
二酸化チタン 0.05
黒酸化鉄 0.5
雲母チタン 10.0
流動パラフィン 5.0
セスキオレイン酸ソルビタン 1.0
塩化ナトリウム (平均粒子径10μm) 1.0
計 100.0
Example 9 (Eyeshadow)
Ingredient name Compounding amount (%)
Mica 34.55
Sericite 45.9
Ultramarine 2.0
Titanium dioxide 0.05
Black iron oxide 0.5
Mica titanium 10.0
Liquid paraffin 5.0
Sorbitan sesquioleate 1.0
Sodium chloride (average particle size 10 μm) 1.0
Total 100.0

本発明によれば、塩化ナトリウムを有効成分として配合することにより、抗菌性を十分に発揮させることができる。この結果、開封後の腐敗、かびの生育を抑えることができ、粉末化粧品の保存性を向上できる。なお実施例2から実施例9においても良好な抗菌効果を得た。
According to the present invention, antibacterial properties can be sufficiently exhibited by blending sodium chloride as an active ingredient. As a result, rot and mold growth after opening can be suppressed, and the preservability of the powder cosmetic can be improved. In Examples 2 to 9, good antibacterial effect was obtained.

Claims (4)

塩化ナトリウムからなる粉末を必須成分として含有することを特徴とする抗菌性粉体化粧料。   An antibacterial powder cosmetic comprising a powder comprising sodium chloride as an essential component. 前記塩化ナトリウムからなる粉末を0.001〜1重量%含有することを特徴とする請求項1記載の抗菌性粉体化粧料。   The antibacterial powder cosmetic according to claim 1, wherein the powder comprises sodium chloride in an amount of 0.001 to 1% by weight. 前記塩化ナトリウムからなる粉末を0.01〜0.5重量%含有することを特徴とする請求項1記載の抗菌性粉体化粧料。   The antibacterial powder cosmetic according to claim 1, wherein the powder comprises sodium chloride in an amount of 0.01 to 0.5% by weight. 前記塩化ナトリウムの平均粒径が10μm以下であることを特徴とする請求項1または請求項3記載の抗菌性粉体化粧料。
The antibacterial powder cosmetic according to claim 1 or 3, wherein the sodium chloride has an average particle size of 10 µm or less.
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JP2011195485A (en) * 2010-03-18 2011-10-06 Nippon Menaade Keshohin Kk Solid powder cosmetic
JP2012246247A (en) * 2011-05-27 2012-12-13 Nippon Menaade Keshohin Kk Powder cosmetic
JP2015110529A (en) * 2013-12-06 2015-06-18 ロレアル Powdery cosmetic composition
JP2016132653A (en) * 2015-01-22 2016-07-25 日本メナード化粧品株式会社 Wet solid powder cosmetics
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