JP2011062126A - Sour taste substance-containing processed meat food - Google Patents

Sour taste substance-containing processed meat food Download PDF

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JP2011062126A
JP2011062126A JP2009214853A JP2009214853A JP2011062126A JP 2011062126 A JP2011062126 A JP 2011062126A JP 2009214853 A JP2009214853 A JP 2009214853A JP 2009214853 A JP2009214853 A JP 2009214853A JP 2011062126 A JP2011062126 A JP 2011062126A
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starch
meat
processed
processed meat
food
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Takeshi Takano
剛 高野
Toshiyuki Nakagawa
俊之 中川
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Prima Meat Packers Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for producing a sour taste substance-containing processed meat food, by which the new sour taste substance-containing processed meat food having an improved texture can profitably be produced without causing the obstruction of binding due to the compounding of the sour taste substance and without separating water, and to provide the new sour taste substance-containing processed meat food. <P>SOLUTION: There are provided the method for producing the sour taste substance-containing processed meat food, characterized by stirring a sour taste substance and starch until to give a uniform mixture, heating the mixture to form an acidic starch curd, finely cutting the starch curd to form granules, adding the granules to a processed meat food, and then stirring the mixture to produce the sour taste substance-containing processed meat food in which the granular acidic gel-like substance is dispersed in the processed meat food; and the new sour taste substance-containing processed meat food obtained by the production method. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は、酸味物質入り食肉加工食品やその製造方法に関し、より詳しくは、酸味物質を含有する澱粉カードの粒状物を食肉加工食品に混合撹拌して、前記粒状物が分散状に配合されている酸味物質入り食肉加工食品及びその製造方法に関する。   More specifically, the present invention relates to a processed processed meat product containing sour substances and a method for producing the same. More specifically, the granular product of starch curd containing sour substances is mixed and stirred in the processed processed meat product, and the granular products are mixed in a dispersed state. The present invention relates to processed meat processed food containing sour substances and a method for producing the same.

蓄肉や魚肉等を原料とするソーセージ類においては、風味、食感、健康志向等の点から従来のソーセージ類に種々改良がなされており、近年、味に関しては、酸味等の風味の付加、香味の改良、また、健康志向に関しては低脂肪ソーセージ等の需要が高くなっている。酸味等の風味の付加に際し、ソーセージ等の非単一肉塊の食肉製品に、該肉以外の原料のpHが酸性の材料を用いる場合は、肉の結着性が低下するため、製品の食感が落ち、離水が生じる等の悪影響が大きかった。そのため、酢やレモンのようにpH2〜3の低pHの原料をソーセージに使用する場合は添加量を微量にせざるを得なかった。酸味を出すために例えば1重量%の酢酸を添加した場合は、肉の結着力が殆どなくなり、肉自身の水分でさえも保水することができなくなり、製品は離水した状態となる。また、肉製品特有の弾力性もなくなり、食感ももろくなる。   Sausages made from raw meat, fish, etc. have been improved from conventional sausages in terms of flavor, texture, health-consciousness, etc. In recent years, with regard to taste, the addition of flavors such as sourness, flavor There is a growing demand for low-fat sausages, etc., regarding improvement of health and health orientation. When adding a flavor such as sourness to a non-single meat lump meat product such as sausage, if the raw material other than the meat has an acidic pH, the binding property of the meat will decrease, so The negative effects such as the feeling of falling and the occurrence of water separation were great. Therefore, when using a low pH raw material of pH 2-3 like sausage like vinegar or lemon, the addition amount had to be made very small. When, for example, 1% by weight of acetic acid is added to bring out a sour taste, the binding power of the meat is almost lost, and even the moisture of the meat itself cannot be retained, and the product is in a water-removed state. Also, the elasticity unique to meat products is lost, and the texture becomes brittle.

従来技術として、1)澱粉、植物性蛋白などの結着材の使用量を増やす方法、2)添加水の使用を少なくする方法、3)リン酸塩に代表されるアルカリ性の食品添加物でpH調整をする方法、4)酸性原料をゼラチンやプルランなどを原料としたカプセル状の中に閉じ込めて使用する方法等が対応策として知られている。しかし、製品のおいしさへの影響として上記1)では製品の食感が粉っぽくなり、2)では製品の食感が硬くなる。製造上の課題として上記3)では酸味の低下と安定的なpH調整をする難しさがあり、4)ではカプセルを作製するための特殊な設備が必要である上に、カプセルの直径が大きい場合、もしくはカプセルの皮膜厚が薄い場合はソーセージの混合工程でカプセルの破壊や加熱処理で熱によるカプセルの破壊が懸念される。いずれの対策も商品のおいしさという観点、もしくは製造課題やコストの面から満足のいく結着阻害対策ではなかった。   As conventional technologies, 1) a method of increasing the amount of binders such as starch and vegetable protein, 2) a method of reducing the use of added water, and 3) an alkaline food additive typified by phosphate, pH. As a countermeasure, 4) a method of adjusting, and 4) a method of confining an acidic raw material in a capsule shape made of gelatin, pullulan or the like as a raw material are known. However, as an influence on the taste of the product, the texture of the product becomes powdery in the above 1), and the texture of the product becomes hard in 2). In the case of 3), there is a difficulty in adjusting the acidity and stable pH adjustment in the above 3). In 4), special equipment for producing capsules is required, and the capsule has a large diameter. Alternatively, when the capsule film is thin, there is a concern that the capsule may be destroyed in the sausage mixing process or the capsule may be destroyed by heat in the heat treatment. None of the measures was a satisfactory binding inhibition measure from the viewpoint of the deliciousness of the product, or from the viewpoints of manufacturing issues and costs.

従来技術に関し、特許文献等をみると、疎水性物質からなる外皮により酸性物質を被覆した酸性マイクロカプセルを練り製品に配合すること(例えば、特許文献1、特許文献2参照)が知られている。   Regarding the prior art, it is known from the patent documents and the like to mix acidic microcapsules coated with an acidic substance with a skin made of a hydrophobic substance into a kneaded product (for example, see Patent Documents 1 and 2).

また、酸味食品を練り製品に配合する製法としては、水産練り製品の製造工程中に、酸味食品(梅肉をその代表として、マヨネーズ、各種ドレッシング、またレモン、オレンジが例示)及びトランスグルタミナーゼを添加使用する酸味食品入り水産練り製品の製造法(例えば、特許文献3参照)や、調味成分(例えば、マヨネーズ味、カレー味、チリソース味、チーズ味、ワサビ味等)を、SFI値が10℃で80以下、20℃で60以上、30℃で40以下、40℃で15以下である油脂中に分散させて固形のチップ乃至スライス状物とし、これを水分60〜90%の練肉生地と混合し、加熱ゲル化する練り製品の製造法(例えば、特許文献4参照)が知られている。   In addition, as a method of blending sour foods into kneaded products, sour foods (plum meat as a representative example, mayonnaise, various dressings, lemon and orange are exemplified) and transglutaminase are added and used during the production process of fishery kneaded products. A method for producing a sour-tasting marine product (for example, see Patent Document 3) and a seasoning component (for example, mayonnaise flavor, curry flavor, chili flavor, cheese flavor, wasabi flavor, etc.) at an SFI value of 10 ° C., 80 or less, Disperse in a fat and oil of 60 or more at 20 ° C., 40 or less at 30 ° C. and 15 or less at 40 ° C. to form solid chips or slices, which are mixed with a dough of 60 to 90% moisture and heated A manufacturing method of a kneaded product that gels (for example, see Patent Document 4) is known.

さらに、高粘度ゾル又は硬いゲルを形成できる原料と他の食材とを混合し、加熱又は加熱せずに混合・膨潤させて食品に混合した食品混合物(例えば、特許文献5参照)や、酸添加が可能な、ガラクトキシログルカンとキサンタンガムを含有するゲル化状組成物を食品に配合し、耐酸性を有し、弾力がある食品の製造法(例えば、特許文献6参照)が知られている。   Furthermore, a raw material capable of forming a high-viscosity sol or hard gel and other foods are mixed, mixed or swollen without heating or heating and mixed with food (for example, see Patent Document 5), acid addition There is known a method for producing an elastic food product comprising a gelled composition containing galactoxyloglucan and xanthan gum, which has a resistance to acid, and having elasticity (for example, see Patent Document 6).

一方、酸性食品を固形化する技術として、ゼラチンとくず粉とを配合した水溶液と、卵黄とサラダオイルと醸造酢を主成分とするマヨネーズ主体とを練合した固形状マヨネーズの製造法(例えば、特許文献7参照)や、油脂と乳化力及び熱凝固性を有する蛋白とを含有する酸性乳化食品を加熱凝固してなる固形マヨネーズ(例えば、特許文献8参照)や、食用植物油脂、卵、食酢、調味料、増粘剤、安定剤及び香辛料を主原料とした乳化物を含む固形状マヨネーズ様食品の製造において、当該乳化物中に加熱型生澱粉を添加し、乳化物を容器に密閉充填した後、これを静置加熱して固化させる固形状マヨネーズ様食品の製造方法(例えば、特許文献9参照)が知られている。   On the other hand, as a technique for solidifying acidic foods, a method for producing solid mayonnaise by kneading an aqueous solution containing gelatin and waste powder and a main mayonnaise mainly composed of egg yolk, salad oil and brewed vinegar (for example, patents) Reference 7), solid mayonnaise (see, for example, Patent Document 8) obtained by heating and coagulating an acidic emulsified food containing fat and oil and a protein having emulsifying power and heat coagulation property, edible vegetable oil, egg, vinegar, In the production of a solid mayonnaise-like food containing an emulsion mainly composed of seasonings, thickeners, stabilizers and spices, heated raw starch was added to the emulsion, and the emulsion was hermetically filled in a container. Then, the manufacturing method (for example, refer patent document 9) of the solid-state mayonnaise-like foodstuff which makes this stand still and heat and solidifies is known.

しかしながら、酸味物質と澱粉を均一になるまで撹拌した後加熱して得られる澱粉カードの粒状物を食肉加工食品に混合撹拌して、前記粒状物を分散状に配合した酸味物質入り食肉加工食品及びかかる食肉加工食品の製造方法は知られていない。   However, the starch curd granules obtained by stirring and heating the sour substance and starch until uniform are mixed and stirred in the processed meat food, and the processed meat-containing food containing the sour substance in which the granules are blended in a dispersed state, and A method for producing such processed meat food is not known.

特開平2−245148号公報JP-A-2-245148 特開2000−4841号公報JP 2000-4841 A 特開平11−332520号公報JP-A-11-332520 特開平9−47259号公報JP 9-47259 A 特開平8−168349号公報JP-A-8-168349 特開2006−262897号公報JP 2006-262897 A 特公昭61−48903号公報Japanese Examined Patent Publication No. 61-48903 特開昭61−135566号公報Japanese Patent Laid-Open No. 61-135666 特開2003−310206号公報JP 2003-310206 A

pHの低い酸味物質を、挽き肉等を用いる食肉練り製品に配合すると、練り製品の練り生地のpH低下による結着阻害を起こすことが通常である。本発明の課題は、このような酸味物質の配合によっても、結着阻害をおこすことなく、また、離水が発生せず、食感の向上した新規な酸味物質入り食肉加工食品を経済的に製造する方法及び新規な酸味物質入り食肉加工食品を提供することにある。   When a sour substance having a low pH is blended in a meat paste product using ground meat or the like, binding inhibition due to a decrease in pH of the kneaded dough of the paste product is usually caused. An object of the present invention is to economically produce a processed processed meat product containing a sour substance that does not inhibit binding, does not cause water separation, and has an improved texture even when such a sour substance is blended. And a novel processed meat food containing sour substances.

本発明者らは、ソーセージ等の練り製品に風味、食感等に変化をもたせるため、特に日本的な伝統味である酸味を付与しても、通常の練り製品と同様の食感等を有する練り製品を得るべく鋭意研究した。その結果、pHの低い原料をソーセージ生地等に配合して結着阻害が起こる時は、pHの低い原料が肉に接する面積が大きい場合であり、したがって、出来るだけその面積を減らすことで結着阻害を防ぐことができることが分かった。そのため、pHの低い原料と組み合わせて使用する他の原料としては、結着阻害を起こさない、かつ、味に影響のない原料であることが必要であり、pHの低い原料と組み合わせて使用して、ある程度の大きさで局在化させて分散することにより、練り製品内で肉との接触面積を減らし、肉の結着を防止することが出来ることを突き止めた。前記の条件を満たす種々の原料、例えば可食性の高分子物質等について、その適否を繰り返し、実験した結果、澱粉含有溶液を用いて加熱し酸味物質を澱粉によるゲルでまとめて(このゲルを澱粉カードという)、ソーセージ中に分散した結果、pHの低い原料が肉粒子間に拡散しないために肉の結着阻害を起こさず、食感も弾力性を有するものであることが認められ、本発明を完成するに至った。   In order to change the flavor, texture, etc. of the kneaded product such as sausage, the present inventors have a kneaded product having the same texture, etc. as a normal kneaded product even if it is given a sour taste, which is a traditional Japanese taste. I studied hard to get it. As a result, when the inhibition of binding occurs when ingredients with low pH are mixed with sausage dough, etc., the area where the ingredients with low pH come into contact with the meat is large, and therefore binding is achieved by reducing the area as much as possible. It has been found that inhibition can be prevented. Therefore, the other raw materials used in combination with the raw material having a low pH must be a raw material that does not inhibit binding and does not affect the taste, and is used in combination with a raw material having a low pH. It has been found that by localizing and dispersing in a certain size, the contact area with meat in the kneaded product can be reduced, and the binding of meat can be prevented. Various raw materials satisfying the above conditions, such as edible polymer substances, were repeatedly tested for suitability, and as a result of experimentation, the starch-containing solution was heated and the sour substances were collected into a starch gel (this gel was converted into starch Curd), as a result of being dispersed in the sausage, it is recognized that the raw material having a low pH does not diffuse between the meat particles, so that the binding of meat is not inhibited, and the texture is also elastic. It came to complete.

すなわち本発明は、(1)酸味物質と澱粉とを均一になるまで撹拌した後に加熱して得られる澱粉カードを粒状物とし、該粒状物を食肉加工食品に添加し、撹拌することにより、粒状の酸性ゲル状物を食肉加工食品に分散してなることを特徴とする酸味物質入り食肉加工食品や、(2)澱粉カードが、最大応力4g/cm以上であることを特徴とする上記(1)記載の酸味物質入り食肉加工食品や、(3)粒状物が、粒径2mm以上であることを特徴とする上記(1)又は(2)記載の酸味物質入り食肉加工食品や、(4)澱粉カードが、L−アスコルビン酸ナトリウムを0.2重量%以上含有することを特徴とする上記(1)〜(3)いずれか記載の酸味物質入り食肉加工食品や、(5)澱粉カードのpHが2.8〜5.0であることを特徴とする上記(1)〜(4)のいずれか記載の酸味物質入り食肉加工食品や、(6)酸味物質が、酢酸、クエン酸、フマル酸、乳酸、リンゴ酸、酒石酸、グルコノデルタラクトン、フィチン酸、リン酸及びそれらの塩のうち少なくとも1以上を含むことを特徴とする上記(1)〜(5)いずれか記載の酸味物質入り食肉加工食品や、(7)澱粉が、タピオカ澱粉であることを特徴とする上記(1)〜(6)いずれか記載の酸味物質入り食肉加工食品に関する。 That is, the present invention is (1) a starch card obtained by stirring the sour substance and starch until uniform and then heating to form granules, adding the granules to the processed meat food, and stirring, (1) The above-mentioned (2) starch curd having a maximum stress of 4 g / cm 2 or more. (1) The sour substance-containing meat processed food according to (1), (3) The granular product has a particle size of 2 mm or more, (1) or (2) the sour substance-containing meat processed food or (4 The starch curd contains 0.2% by weight or more of sodium L-ascorbate, and the processed meat-containing food with a sour substance according to any one of (1) to (3) above, or (5) that the pH is 2.8-5.0. Processed meat processed foods containing sour substances according to any one of (1) to (4) above, and (6) sour substances are acetic acid, citric acid, fumaric acid, lactic acid, malic acid, tartaric acid, glucono delta lactone In addition, at least one or more of phytic acid, phosphoric acid, and salts thereof, wherein the processed processed meat-containing food according to any one of (1) to (5) above and (7) starch is tapioca starch It is related with the processed meat food containing an acidity substance in any one of said (1)-(6) characterized by being.

また本発明は、(8)食肉加工食品が、挽き肉を使用した食品であることを特徴とする上記(1)〜(7)いずれか記載の食肉加工食品や、(9)挽き肉を使用した食品が、ソーセージであることを特徴とする上記(8)記載の食肉加工食品に関する。   In addition, the present invention provides (8) the processed meat product according to any one of (1) to (7) above, wherein the processed meat product is a food product using minced meat, and (9) a food product using minced meat Is a sausage, The meat processed food of the said (8) description characterized by the above-mentioned.

さらに本発明は、(10)酸味物質と澱粉とを均一になるまで撹拌した後に加熱して酸性の澱粉カードを形成し、前記澱粉カードを細切りして粒状物にし、該粒状物を食肉加工食品に添加し、撹拌して粒状の酸性ゲル状物を食肉加工食品に分散することを特徴とする酸味物質入り食肉加工食品の製造方法や、(11)澱粉カードが、最大応力4g/cm以上であることを特徴とする上記(10)記載の酸味物質入り食肉加工食品の製造方法に関する。 The present invention further comprises (10) stirring the sour substance and starch until uniform and then heating to form an acidic starch card, chopping the starch card into granules, and converting the granules into processed meat products And (11) the starch card has a maximum stress of 4 g / cm 2 or more. It is related with the manufacturing method of the meat processed food containing a sour substance as described in said (10) characterized by the above-mentioned.

本発明によると、酸味物質を添加しても、従来のように生地のpHが低下して結着阻害を起こすことがなく、また、離水の発生がない酸味物質入り食肉加工食品を得ることができる。さらに、澱粉カードを使用して局在的に不均一な分散をさせ、食したときに味が強く感じられ、新鮮なソーセージの食感を有する練り製品を得ることができ、しかも、酸味物質をカプセルにより被覆する等の複雑な工程を要せず、経済的に酸味物質入り食肉加工食品を製造することができる。   According to the present invention, even when sour substances are added, the pH of the dough does not decrease and binding inhibition does not occur as in the conventional case, and a processed meat-containing food with sour substances that does not cause water separation can be obtained. it can. Furthermore, the starch card can be used to disperse locally and unevenly to obtain a kneaded product that has a strong taste when eaten and has a fresh sausage texture. Therefore, it is possible to economically produce a processed meat-containing food containing a sour substance without requiring a complicated process such as coating.

熱処理歩留(%)について、食酢の濃度と添加方法がソーセージに与える影響を示す。About heat processing yield (%), the influence which the density | concentration of vinegar and the addition method have on sausage is shown. 最大応力(g/cm)について、食酢の濃度と添加方法がソーセージに与える影響を示す。About the maximum stress (g / cm < 2 >), the influence which the density | concentration of vinegar and the addition method have on a sausage is shown. 官能評価点数(硬さ)について、食酢の濃度と添加方法がソーセージに与える影響を示す。About sensory evaluation score (hardness), the influence which the density | concentration of vinegar and the addition method have on a sausage is shown. 熱処理歩留(%)について、カード中の澱粉濃度がソーセージに与える影響を示す。The heat treatment yield (%) shows the effect of starch concentration in the curd on the sausage. 最大応力(g/cm)について、カード中の澱粉濃度がソーセージに与える影響を示す。About the maximum stress (g / cm < 2 >), the influence which the starch density | concentration in a curd has on a sausage is shown. 官能評価点数(硬さ)について、カード中の澱粉濃度がソーセージに与える影響を示す。About the sensory evaluation score (hardness), the influence which the starch concentration in a card | curd has on a sausage is shown. 澱粉カード中の澱粉濃度(%)が澱粉カードの最大応力、ソーセージの最大応力及びソーセージの熱処理歩留に与える影響を示す。The influence which the starch concentration (%) in a starch curd has on the maximum stress of a starch card | curd, the maximum stress of a sausage, and the heat treatment yield of a sausage is shown. 澱粉カードにACSを添加した場合のシトラス及び香辛料由来成分解析結果を示す。The citrus and spice origin component analysis result at the time of adding ACS to a starch card | curd is shown.

酸味物質入り食肉加工食品としては、酸味物質と澱粉とを均一になるまで撹拌して得られる液状物を加熱して酸性の澱粉カードを形成し、前記澱粉カードを粒状物とし、該粒状物を食肉加工食品に添加し、撹拌することにより、粒状の酸性ゲル状物を食肉加工食品に分散してなるものであれば何ら限定されるものではない。また、酸味物質入り食肉加工食品の製造方法としては、酸味物質と澱粉とを均一になるまで撹拌して得られる溶液を加熱して酸性の澱粉カードを形成し、前記澱粉カードを細切りして粒状物にし、該粒状物を食肉加工食品に添加し、撹拌して粒状の酸性ゲル状物を食肉加工食品に分散する方法であれば、特に制限されるものではない。   As processed meat foods containing sour substances, a liquid product obtained by stirring the sour substance and starch until uniform is heated to form an acidic starch card, the starch card is made into granules, and the granules are If it adds to a processed meat food and stirs and disperse | distributes a granular acidic gel-like thing to a processed meat food, it will not be limited at all. Moreover, as a method for producing processed meat products containing sour substances, an acidic starch card is formed by heating a solution obtained by stirring the sour substance and starch until uniform, and the starch card is chopped into granules. It is not particularly limited as long as it is a method in which the granular product is added to the processed meat food and stirred to disperse the granular acidic gel in the processed meat food.

本発明の「澱粉カード」は、酸味物質と澱粉とを均一になるまで混合撹拌した後に加熱して得られる、酸性の原料を澱粉によるゲルでまとめたものであり、澱粉カードを粒状物として成形する上で、またかかる粒状物をソーセージ等の食肉加工品中に局在化(不均一分散)させる上で、澱粉カードの硬さ(最大応力)は重要である。澱粉カードは、最大応力が4g/cm以上、好ましくは5g/cm以上であり、例えば4〜27g/cm、特に5〜27g/cmを好適に例示することができる。最大応力が4g/cmより少ないと食酢のソーセージへの熱処理歩留と硬さの悪影響を防ぎきれないが、澱粉カードの最大応力が4g/cm以上であると食酢のソーセージへの熱処理歩留と硬さの悪影響を妨げることができる。なお、ここで熱処理歩留とは、熱処理後のケーシング内部のジュースと分離したゼラチンの、総重量に対する割合をいう。澱粉として、タピオカ澱粉を用いる場合、澱粉濃度が16〜32重量%で最大応力4〜27g/cmを達成することができる。 The “starch card” of the present invention is obtained by mixing and stirring sour substances and starch until they are uniform and then heating, and collecting the acidic raw materials with starch gel, and forming the starch card as a granular material. In addition, the hardness (maximum stress) of the starch curd is important in localizing (non-uniformly dispersing) such granular materials in processed meat products such as sausages. The starch card has a maximum stress of 4 g / cm 2 or more, preferably 5 g / cm 2 or more. For example, 4 to 27 g / cm 2 , particularly 5 to 27 g / cm 2 can be suitably exemplified. If the maximum stress is less than 4 g / cm 2, the adverse effects of vinegar sausage on heat treatment yield and hardness cannot be prevented, but if the maximum stress of starch curd is 4 g / cm 2 or more, vinegar sausage heat treatment step It can prevent the bad influence of the retention and hardness. Here, the heat treatment yield means the ratio of the gelatin separated from the juice inside the casing after the heat treatment to the total weight. When tapioca starch is used as the starch, a maximum stress of 4 to 27 g / cm 2 can be achieved at a starch concentration of 16 to 32% by weight.

酸味物質としては、酢酸、クエン酸、フマル酸、乳酸、リンゴ酸、酒石酸、グルコノデルタラクトン、フィチン酸、リン酸及びそれらの塩、並びに、これらの酸(塩)の含有物のうち少なくとも1以上を含み、目的とする酸風味が、マヨネーズ風味、ケチャップ風味(トマト風味)、ジャン風味、レモン風味とするような場合、固形マヨネーズ、トマトペースト、レモン果汁、中華ジャンなど適宜添加し、或いは、併用することができる。これら酸性物質の添加量は、その種類や期待する呈味(嗜好)にもよるが、澱粉カードのpHが2.8〜5が好ましく、pH2.9〜4がより好ましく、pH3〜3.5が特に好ましい。   As the sour substance, at least one of acetic acid, citric acid, fumaric acid, lactic acid, malic acid, tartaric acid, glucono delta lactone, phytic acid, phosphoric acid and salts thereof, and contents of these acids (salts) Including the above, when the target acid flavor is mayonnaise flavor, ketchup flavor (tomato flavor), jean flavor, lemon flavor, solid mayonnaise, tomato paste, lemon juice, Chinese jean or the like, or Can be used together. The addition amount of these acidic substances depends on the type and expected taste (preference), but the pH of the starch card is preferably 2.8 to 5, more preferably 2.9 to 4, and pH 3 to 3.5. Is particularly preferred.

澱粉カードに用いる澱粉としては、タピオカ澱粉、小麦澱粉、米澱粉、馬鈴薯澱粉、甘藷澱粉、ウルチ種コーンスターチ、ハイアミロースコーンスターチ、ワキシーコーンスターチ、サゴ澱粉、緑豆澱粉から選ばれる少なくとも1種を用いることができ、好ましくはタピオカ澱粉を挙げることができる。   As the starch used in the starch card, at least one selected from tapioca starch, wheat starch, rice starch, potato starch, sweet potato starch, urch corn starch, high amylose corn starch, waxy corn starch, sago starch and mung bean starch can be used. Preferably, tapioca starch can be mentioned.

酸性の澱粉カードの粒状物の粒径としては、粒径2mm以上であることが好ましい。粒径2mmより小さいと、ソーセージ肉の接触面積が大きくなり結着阻害を引き起こす可能性がある。例えば、粒径として、2〜4mm、2〜5mm、2〜6mmを挙げることができ、より具体的には、これらの範囲内で粒径が分散していても、あるいは一定値に集中していてもよい。また、粒径が6mmを超えると、異なる食感の食肉製品となる。
また、酸性の澱粉カードの粒状物は、食肉加工食品中に、例えば、2〜20重量%、3〜15重量%、4〜10重量%、5〜7重量%など適宜含有せしめることができるが、食肉加工食品中への澱粉の許容配合量を考慮すると、澱粉配合量が30重量%の澱粉カードの場合、5〜7重量%が好ましい。
The particle size of the acidic starch card is preferably 2 mm or more. When the particle size is smaller than 2 mm, the contact area of the sausage meat becomes large, which may cause binding inhibition. For example, examples of the particle diameter include 2 to 4 mm, 2 to 5 mm, and 2 to 6 mm. More specifically, even if the particle diameter is dispersed within these ranges, the particle diameter is concentrated to a certain value. May be. Moreover, when a particle size exceeds 6 mm, it will become a meat product of a different texture.
Moreover, the granular material of an acidic starch card | curd can be suitably contained, for example in 2-20 weight%, 3-15 weight%, 4-10 weight%, 5-7 weight%, etc. in meat processed food. In consideration of the allowable blending amount of starch in processed meat foods, 5-7% by weight is preferable in the case of a starch card having a starch blending amount of 30% by weight.

澱粉カードにL−アスコルビン酸ナトリウムを添加することが好ましく、これによって、澱粉カードの加熱による風味の劣化を低減することができる。澱粉カード中にL−アスコルビン酸ナトリウムが0.2重量%以上、例えば0.3〜0.4重量%以上、より好ましくは0.5重量%以上、特に好ましくは1.0重量%以上となるように添加するとより効果がある。   It is preferable to add sodium L-ascorbate to the starch curd, whereby the deterioration of flavor due to heating of the starch curd can be reduced. In the starch curd, sodium L-ascorbate is 0.2% by weight or more, for example, 0.3 to 0.4% by weight or more, more preferably 0.5% by weight or more, and particularly preferably 1.0% by weight or more. It is more effective when added in this manner.

食肉加工食品は、挽肉を使用した食肉加工品であり、例えば、ソーセージ、ナゲット、ハンバーグ、つくね、焼売等を挙げることができる。   Processed meat products are processed meat products using minced meat, and examples include sausages, nuggets, hamburgers, grilled meats, and grilled foods.

試験1[食酢の濃度と添加方法がソーセージの硬さに与える影響]
食酢などの酸性原料をソーセージへ直接添加すると、pHが低下し、肉の保水性・結着性が低下する。そこで、酸性原料を澱粉でカードにして、肉中に局在する不均一な分散をさせることによって、ソーセージの食感にどのような影響を与えるかを確認するため、対照区として「食酢を直接にソーセージへ均一に添加する区」、比較区として「食酢を澱粉カードにしてソーセージへ局在化させて添加する区」とし、ベース配合として、オールポークソーセージを用いた。一般的なソーセージの配合で評価するために、ブランクの配合をJAS上級(基準;澱粉3%以下)に近い配合にし、試験でさらに澱粉が加わっても、JAS標準(基準:澱粉5%以下)相当の配合になるように行った。
Test 1 [Effects of vinegar concentration and addition method on sausage hardness]
When an acidic raw material such as vinegar is added directly to sausage, the pH is lowered and the water retention and binding properties of the meat are lowered. Therefore, in order to confirm the effect on the texture of sausage by using non-uniform dispersion localized in the meat by curding the acidic raw material with starch, as a control plot, `` Vinegar directly The group was uniformly added to the sausage, and the comparative group was a group where vinegar was added to the sausage as a starch curd, and all pork sausage was used as the base formulation. In order to evaluate with a general sausage composition, the composition of the blank is made close to JAS high grade (standard: starch 3% or less), and even if starch is added in the test, JAS standard (standard: starch 5% or less) It went so that it might become a considerable composition.

評価項目(測定項目)は、1.食酢溶液と澱粉カードのpH測定、2.ソーセージの熱処理歩留測定(熱処理後のケーシング内部のジュースと分離したゼラチンの総重量に対する割合)、3.ソーセージの物性評価、4.ソーセージの官能評価である。   Evaluation items (measurement items) are: 1. pH measurement of vinegar solution and starch curd, 2. Heat treatment yield measurement of sausage (ratio to the total weight of gelatin separated from juice inside casing after heat treatment), 3. Physical property evaluation of sausage This is a sensory evaluation of sausages.

[澱粉カード、その粒状物の作製方法]
原料として、澱粉、食酢及び添加水を配合通りに計量した後、これら原料を撹拌して混合した。混合物を非通気性ケーシングに充填し、90℃で、20分間蒸気加熱し、その後急冷を行い、品温10℃以下になるまで冷却した。冷却後非通気性ケーシングを取り除き、ダイス状にカットし、カットした澱粉カードをソーセージへ所定の添加量とするように計量した。
[Production method of starch card and its granule]
As raw materials, starch, vinegar and added water were weighed as blended, and then these raw materials were stirred and mixed. The mixture was filled in a non-breathable casing, steam-heated at 90 ° C. for 20 minutes, then rapidly cooled, and cooled to a product temperature of 10 ° C. or lower. After cooling, the non-breathable casing was removed, cut into dice, and the cut starch curd was weighed to a predetermined amount added to the sausage.

[ソーセージの作製方法]
原料肉(豚ウデ肉、豚脂)を3cm位の大きさにナイフでカットし、下記[表1]の原料肉を配合とおりに計量し、計量した原料を混合し、5ミリサイズにグラインドした。ミキサーにグラインドした原料肉、塩漬剤、添加水を順次投入した。添加水には、氷水を使用した。十分に混合した後、一晩、冷蔵庫に静置した。塩漬肉にブランク配合用の澱粉と添加水を添加して脱気混合(4分間)した。下記[表2]のとおり、対照区はブランク配合肉に食酢溶液及び対になる試験区の澱粉カード中と同量の澱粉を粉体で添加した。ミキサーで脱気(2分)混合し、オイルスタッファーで非通気性ケーシングに充填した。結紮後、角形リテイナーに型詰めし、その後78℃でボイルした。中心品温72℃まで約2.5時間要した。その後氷水に漬け、冷蔵庫で一晩静置した後、熱処理歩留まり測定のため、レテイナーを外し、表面の水分を拭き取り、ケーシング付きの原木総重量を測定した。ケーシングを剥がし、水分やゼリーを拭き取った後、ケーシング重量を測定した。裸になった原木の表面を拭き、ゼリー等を除去後、原木重量を測定した。その後、スライサーで15mm厚にスライスした。レオメーターによる物性測定、検食による官能評価、澱粉カードのpH測定を行った。なお、表1,2における「%」は、重量%を意味する。
[Sausage production method]
Raw material meat (pork edible meat, pork fat) was cut to a size of about 3cm with a knife, the raw material meat of the following [Table 1] was weighed as blended, the weighed raw materials were mixed and grinded to 5 mm size . Raw material meat, salting agent and added water were added to the mixer in order. Ice water was used as the added water. After mixing well, it was left in the refrigerator overnight. Starch for starch blending and added water were added to the salted meat and deaerated and mixed (4 minutes). As shown in [Table 2] below, in the control group, the same amount of starch as in the starch card of the vinegar solution and the paired test group was added to the blank blended meat as powder. The mixture was degassed (2 minutes) with a mixer and filled into a non-breathable casing with an oil stuffer. After ligation, it was packed in a square retainer and then boiled at 78 ° C. It took about 2.5 hours to reach a core temperature of 72 ° C. Then, after immersing in ice water and allowing to stand overnight in a refrigerator, the retainer was removed, the surface moisture was wiped off, and the total weight of the log with casing was measured for heat treatment yield measurement. After removing the casing and wiping off moisture and jelly, the casing weight was measured. The surface of the bare wood that had been bare was wiped, the jelly and the like were removed, and the weight of the wood was measured. Then, it sliced to 15 mm thickness with the slicer. The physical properties were measured with a rheometer, the sensory evaluation was conducted by food inspection, and the pH of the starch card was measured. In Tables 1 and 2, “%” means% by weight.

試験1[食酢濃度及び添加方法がソーセージの硬さに与える影響]の結果
食酢濃度をソーセージ中に表2に示す0%、1%、2%、3%、4%となるように、それぞれを直接添加するのと澱粉カードで添加する、添加方法の違いによるソーセージへの影響についてその結果を表3に示す。また、表3の熱処理歩留の結果を図1に、表3の物性評価については図2に、官能評価については図3にそれぞれ示す。官能評価では、ブランクと硬さの比較を6名で、非常に硬い:+3、硬い:+2、やや硬い:+1、ブランクと同等:0、やや軟らかい:−1、軟らかい:−2、非常に軟らかい:−3という評価で行った。
Results of Test 1 [Effects of vinegar concentration and addition method on sausage hardness] Each of the vinegar concentrations was 0%, 1%, 2%, 3%, 4% as shown in Table 2 in the sausage. The results are shown in Table 3 for the effect on sausage due to the difference in the addition method, which is directly added and added with starch curd. The results of the heat treatment yield in Table 3 are shown in FIG. 1, the physical property evaluation in Table 3 is shown in FIG. 2, and the sensory evaluation is shown in FIG. In the sensory evaluation, the blank and hardness were compared by 6 people, very hard: +3, hard: +2, slightly hard: +1, equivalent to blank: 0, slightly soft: -1, soft: -2, very soft : The evaluation was −3.

表3に示されるように、食酢を、3%以上の濃度で生地に直接添加すると熱処理歩留がブランクに比べて顕著に低下した。これは、熱処理歩留に悪影響があったことを示すものである。また、物性評価においては、図2で明らかなように、食酢1%を生地に直接添加するとソーセージの最大応力がブランクに比べてやや低下し、食酢2%以上添加すると最大応力は顕著に低下し、ソーセージの物性に影響があった。これに対し、食酢を澱粉カードにして添加するとソーセージの最大応力はブランクとほぼ同等となり、ソーセージの物性に殆ど影響がなかった。さらに、図3に示すように、官能評価では、食酢1%を生地に直接添加するとソーセージの硬さがブランクに比べてやや軟らかくなり、食酢2%を添加すると硬さは明らかに軟らかくなり、3%添加以上では非常に軟らかくなり、ソーセージの硬さに影響があった。これに対し、食酢を澱粉カードにして添加するとソーセージの硬さはブランクとほぼ同等になり、ソーセージの物性に殆ど影響がなかった。   As shown in Table 3, when vinegar was added directly to the dough at a concentration of 3% or more, the heat treatment yield was significantly reduced compared to the blank. This indicates that the heat treatment yield was adversely affected. In addition, in the physical property evaluation, as clearly shown in FIG. 2, when 1% vinegar is added directly to the dough, the maximum stress of sausage is slightly lower than that of the blank, and when 2% or more of vinegar is added, the maximum stress is significantly reduced. The physical properties of sausages were affected. In contrast, when vinegar was added as starch curd, the maximum stress of the sausage became almost the same as that of the blank, and the physical properties of the sausage were hardly affected. Furthermore, as shown in FIG. 3, in sensory evaluation, when 1% vinegar is added directly to the dough, the sausage hardness is slightly softer than that of the blank, and when 2% vinegar is added, the hardness is clearly soft. % Addition or more became very soft and had an effect on sausage hardness. On the other hand, when vinegar was added as starch curd, the hardness of the sausage became almost the same as that of the blank, and the physical properties of the sausage were hardly affected.

試験2[澱粉カード中の澱粉濃度がソーセージの硬さに与える影響]
澱粉カードの硬さが柔らかいとソーセージの混合工程で、澱粉がペースト様に潰れ練り込まれる。澱粉カードはソーセージ中に均一分散されてしまい、配合肉中への粒状に局在化させた分散ができない。そこで、澱粉カードが均一分散されない適度な硬さを得るため、以下の実験をした。澱粉カードは、前記試験1と同様の方法で、ソーセージは、前記表1の配合を有するものを用い、前記試験1と同様の方法で試作し、下記表4の配合割合で作製した。表4に示すとおり、澱粉カード中の澱粉濃度を12.0%〜32.0%の間で、2%ずつ濃度を高くした。
Test 2 [Effect of starch concentration in starch curd on sausage hardness]
If the starch curd is soft, starch is crushed and kneaded in a paste-like manner during the sausage mixing process. The starch curd is uniformly dispersed in the sausage and cannot be dispersed locally in the blended meat. Therefore, the following experiment was carried out in order to obtain an appropriate hardness in which the starch card is not uniformly dispersed. The starch card was prepared in the same manner as in Test 1, and the sausage was prepared in the same manner as in Test 1 using the one having the composition in Table 1. The sausage was prepared in the proportion shown in Table 4 below. As shown in Table 4, the starch concentration in the starch card was increased by 2% between 12.0% and 32.0%.

試験2[カード中の澱粉濃度がソーセージの硬さに与える影響]の結果
酢酸含量52.5%の澱粉カード中の澱粉濃度を12.0%〜32.0%の間で、2%ずつ濃度を高くし、ソーセージの熱処理歩留、澱粉カードとソーセージの物性評価、及びソーセージの官能評価を行った。ソーセージ中の澱粉カード含有量を5.71%とし、ソーセージの官能評価については、前記試験1と同様に行った。すなわち、ソーセージ中には3.0%の食酢、及び、0.686〜1.828%の澱粉が含まれた11試料を対象とした。
これらの結果を表5に示す。また、表5の熱処理歩留の結果を図4に、表5の物性評価については図5に、官能評価については図6に示す。官能評価では、ブランクと硬さの比較を6名で、非常に硬い:+3、硬い:+2、やや硬い:+1、ブランクと同等:0、やや軟らかい:−1、軟らかい:−2、非常に軟らかい:−3という評価で行った。
Test 2 [Effect of starch concentration in curd on hardness of sausage] Starch concentration in starch curd with acetic acid content of 52.5% is between 12.0% and 32.0% by 2% concentration The sausage heat treatment yield, the physical properties of the starch curd and sausage, and the sensory evaluation of the sausage were performed. The starch card content in the sausage was 5.71%, and the sensory evaluation of the sausage was performed in the same manner as in the test 1 described above. That is, 11 samples containing 3.0% vinegar and 0.686 to 1.828% starch were included in the sausage.
These results are shown in Table 5. The results of the heat treatment yield in Table 5 are shown in FIG. 4, the physical property evaluation in Table 5 is shown in FIG. 5, and the sensory evaluation is shown in FIG. In the sensory evaluation, the blank and hardness were compared by 6 people, very hard: +3, hard: +2, slightly hard: +1, equivalent to blank: 0, slightly soft: -1, soft: -2, very soft : The evaluation was −3.

表5に示すデータ及び図4から、澱粉カード中の澱粉濃度が14%以下では熱処理歩留がブランクに比べて低下し、16%以上ではブランクと同等であった。これに対し、澱粉カード中の澱粉濃度が16%以上では熱処理歩留に影響がなかった。また、物性評価においては、図5で明らかなように、澱粉カード中の澱粉濃度が16%以上でソーセージの最大応力がブランクとほぼ同等であった。つまり、澱粉カード中の澱粉濃度が16%以上でソーセージの物性に殆ど影響がなかった。一方で、澱粉カード中の澱粉濃度が14%以下ではソーセージの最大応力は低下し、ソーセージの物性に大きな影響があった。さらに、図6に示すように、官能評価では、澱粉カード中の澱粉濃度が16%以上でソーセージの硬さがブランクに比べてほぼ同等であった。特に澱粉カード中の澱粉濃度が18%から20%では最もブランクに近い硬さであった。つまり、澱粉カード中の澱粉濃度が16%以上でソーセージの食感に殆ど影響はなかった。一方で、澱粉カード中の澱粉濃度が14%以下ではソーセージの硬さは軟らかくなり、ソーセージの食感に大きな影響があった。   From the data shown in Table 5 and FIG. 4, when the starch concentration in the starch card was 14% or less, the heat treatment yield decreased as compared to the blank, and when it was 16% or more, it was equivalent to the blank. On the other hand, when the starch concentration in the starch card was 16% or more, the heat treatment yield was not affected. Moreover, in the physical property evaluation, as is clear from FIG. 5, the starch concentration in the starch card was 16% or more, and the maximum stress of the sausage was almost equal to that of the blank. That is, when the starch concentration in the starch card was 16% or more, the physical properties of the sausage were hardly affected. On the other hand, when the starch concentration in the starch card was 14% or less, the maximum stress of the sausage was lowered, and the physical properties of the sausage were greatly affected. Furthermore, as shown in FIG. 6, in sensory evaluation, the starch concentration in a starch card | curd was 16% or more, and the hardness of the sausage was substantially equivalent compared with the blank. In particular, when the starch concentration in the starch card was 18% to 20%, the hardness was closest to that of the blank. That is, when the starch concentration in the starch card was 16% or more, the texture of the sausage was hardly affected. On the other hand, when the starch concentration in the starch card is 14% or less, the hardness of the sausage becomes soft, which greatly affects the texture of the sausage.

表5に示す澱粉カード中の澱粉濃度別の、カードの最大応力、ソーセージの評価(熱処理歩留、最大応力)データを図7に示す。表5と図7から、澱粉カードの最大応力が2.938g/cm以下では食酢のソーセージへの熱処理歩留と硬さの悪影響を防ぎきれないが、澱粉カードの最大応力が、4.045g/cm以上ならば食酢のソーセージへの熱処理歩留と硬さの悪影響を防ぐことができた。これより、本発明の用いる澱粉カードの好ましい物性として、澱粉カードが、最大応力4g/cm以上である、とする理由である。 FIG. 7 shows the maximum card stress and sausage evaluation (heat treatment yield, maximum stress) data for each starch concentration in the starch card shown in Table 5. From Table 5 and FIG. 7, when the maximum stress of the starch curd is not more than 2.938 g / cm 2 , the heat treatment yield and hardness of the vinegar sausage cannot be prevented, but the maximum stress of the starch curd is 4.045 g. / Cm 2 or more could prevent adverse effects of heat treatment yield and hardness of vinegar sausage. From this, the preferable physical property of the starch card used in the present invention is that the starch card has a maximum stress of 4 g / cm 2 or more.

試験3[食酢添加による澱粉カードのpH]
澱粉カード中の澱粉の配合量を一定(30%)にして、食酢の量(0〜70%)を変えた澱粉カードのpH値を測定し、ソーセージ中にはこの澱粉カードを5.71%添加して、試験を行った。食酢濃度がpH値の関連を調べた。澱粉カード中の澱粉、食酢、水の配合比率、ソーセージ中の澱粉、食酢、水の配合比率、及び澱粉カードに用いるそれぞれの食酢溶液のpH及び澱粉カードのpHを表6に示す。澱粉カード中に食酢を17.5〜70.0%配合した場合の澱粉カードのpHは3.07〜2.91であった。
Test 3 [pH of starch curd by addition of vinegar]
Measure the pH value of the starch curd with the amount of starch in the starch curd constant (30%) and change the amount of vinegar (0-70%). In the sausage, this starch curd is 5.71% Added and tested. The relationship between vinegar concentration and pH value was examined. Table 6 shows the blending ratio of starch, vinegar and water in the starch card, the blending ratio of starch, vinegar and water in the sausage, and the pH of each vinegar solution used for the starch card and the pH of the starch card. The pH of the starch card | curd at the time of mix | blending 17.5-70.0% of vinegar in a starch card | curd was 3.07-2.91.

試験4[熱処理による澱粉カード中の調味料の風味劣化防止策]
澱粉カードに付与した風味は澱粉カードを作製するときの加熱及びソーセージ製造の熱処理工程による加熱により、風味の変化や減少が起こる。そこで、種々の食品添加剤を検討した結果、L−アスコルビン酸ナトリウム(ACS)の添加が風味の減少改善効果に役立つものと考え、前記ACSの澱粉カードへの添加量を検討した。表7に示すように、ACSの添加量を0.1%、0.2%、0.3%、0.4%、0.5%、1.0%の6種とした。澱粉カードとしては、表7に示す配合及び表8に示す方法で、塩ダレ風味澱粉カードを作製した。香気成分解析は、下記の分析用澱粉カード試作方法の過程で、加熱前、1回目の加熱及び2回目の加熱後の澱粉カードをサンプルとして解析を行った。
Test 4 [Prevention of flavor deterioration of seasoning in starch card by heat treatment]
The flavor imparted to the starch curd changes or decreases in flavor due to the heating during the production of the starch curd and the heat treatment in the production of sausage. Therefore, as a result of examining various food additives, it was considered that the addition of sodium L-ascorbate (ACS) was useful for the effect of improving the flavor reduction, and the amount of ACS added to the starch curd was examined. As shown in Table 7, the amount of ACS added was six types of 0.1%, 0.2%, 0.3%, 0.4%, 0.5%, and 1.0%. As the starch card, a salty-flavored starch card was prepared by the formulation shown in Table 7 and the method shown in Table 8. The aroma component analysis was performed in the course of the following analytical starch card trial production method, and the starch card after the first heating and the second heating before the heating was analyzed as a sample.

試験4[熱処理による澱粉カード中の調味料の風味劣化防止策]の結果
香気成分分析としては、シトラス及び香辛料由来香気成分(limonene、linalool、beta-caryophyllene)の解析を以下の分析法を採用して行った。
ダイナミックヘッドスペース法:
・試料20gを香気捕集用三角フラスコにセットする。
・恒温槽・試料温度30℃に安定させた後、高純度窒素ガスで香気を捕集管に導入する。
・高純度窒素ガス流量:20ml/min for 60min=total 1200ml at 30℃
・香気捕集管はTENAX TNを使用した。
GC/MC 分析条件
・香気を捕集した捕集管に内部標準物質として0.1%benzyl alcohol 1μLを添加した。
・GERSTEL社TDS(熱脱着装置)にてAgilent社GC/MCに導入
・GERSTEL社TDS(熱脱着装置)条件
キャリアーガス:高純度ヘリウムガス 21psi
熱脱着温度:210℃
CIS4:−150℃→210℃
CTS2:−150℃→210℃
・Agilent GC/MC 測定条件
カラム:J&W DB-WAX 60m×0.32mm I.d.×0.25μm
キャリアーガス:高純度ヘリウムガス 21psi at 40℃ 定流量
昇温条件:40℃(hold 2.5min)→5℃/min→210℃(hold)
分析時間:75min
EI 測定:マスレンジ20〜350
Result of Test 4 [Measures to prevent flavor deterioration of seasoning in starch card by heat treatment] For fragrance component analysis, the following analysis methods were used for analysis of citrus and spice-derived fragrance components (limonene, linalool, beta-caryophyllene) I went.
Dynamic headspace method:
-Set 20g of sample in the Erlenmeyer flask for aroma collection.
・ Constant temperature bath ・ After stabilizing the sample temperature to 30 ° C., introduce the aroma into the collection tube with high purity nitrogen gas.
・ High purity nitrogen gas flow rate: 20ml / min for 60min = total 1200ml at 30 ℃
・ A TENAX TN was used as the aroma collection tube.
GC / MC analysis conditions-1 μL of 0.1% benzyl alcohol was added as an internal standard substance to the collection tube where aroma was collected.
-Introduced into Agilent GC / MC with GERSTEL TDS (thermal desorption device)-GERSTEL TDS (thermal desorption device) conditions
Carrier gas: High purity helium gas 21psi
Thermal desorption temperature: 210 ° C
CIS4: -150 ° C → 210 ° C
CTS2: -150 ° C → 210 ° C
・ Agilent GC / MC measurement conditions
Column: J & W DB-WAX 60m × 0.32mm Id × 0.25μm
Carrier gas: High purity helium gas 21 psi at 40 ° C constant flow rate
Temperature rise condition: 40 ℃ (hold 2.5min) → 5 ℃ / min → 210 ℃ (hold)
Analysis time: 75min
EI measurement: Mass range 20 to 350

前記分析法により解析した結果を図8に示す。図8におけるAREA数値は0.1%benzyl alcohol 1μl(内部標準物質)を1E+09にしたものである。図8より、澱粉カード中にASCを0.1%になるように添加してもASC添加なしとほぼ同じ結果であり、香気成分の減少を防ぐことができなかったが、0.2%以上となるように添加すると、香気成分の減少が添加量に依存して改善された。例えば、ASCを0.5%添加すると2回目の加熱による香気成分の減少が大幅に改善された。同様にASCを1.0%添加すると1回目、2回目の加熱による香気成分の減少が未加熱とほぼ同等になり、加熱による香気成分の減少を防ぐことができた。これより、ASCを澱粉カード中に0.5%以上添加すると効果があることが分かった。   The results of analysis by the above analysis method are shown in FIG. The AREA value in FIG. 8 is obtained by changing 1 μl of 0.1% benzyl alcohol (internal standard substance) to 1E + 09. From FIG. 8, even if ASC was added to the starch card so as to be 0.1%, the result was almost the same as the case where ASC was not added. When it was added, the reduction of the aroma component was improved depending on the amount added. For example, when 0.5% of ASC was added, the reduction of aroma components by the second heating was greatly improved. Similarly, when 1.0% of ASC was added, the reduction of the fragrance component by the first and second heating became almost the same as that of unheated, and the reduction of the fragrance component by heating could be prevented. From this, it was found that adding 0.5% or more of ASC to the starch card is effective.

以下、実施例を示すが、本発明は実施例に何ら限定されるものではない。   Hereinafter, although an Example is shown, this invention is not limited to an Example at all.

1)澱粉カードの製造
食酢3.00kg、水1.57kg及びタピオカ澱粉1.14kgを混合撹拌し、非通気性ケーシングに充填し、前記ケーシングされた澱粉含有液状物を90℃、20分間蒸気加熱した。急冷後、品温10℃以下になるまで冷却した。冷却後、非通気性ケーシングを取り除き、加熱により形成された澱粉カードをダイサーで粒径2mm以上となるようにカットした。
2)ソーセージの製造
豚肉62.0kg、豚脂肪11.0kg、水13.24kgを混合し、ミキサーに投入して、5mmサイズにグラインドした。さらに、食塩1.61kg、亜硝酸ナトリウム0.01kg、リン酸塩0.20kg、アスコルビン酸ナトリウム0.03kg、香辛料0.2kgを添加して混合した。次いで、前記1)で製造した粒状の澱粉カード5.71kgを添加して、ミキシングを行った。ミキシング中に脱気した。ソーセージ生地中に粒子状のカードが分散した状態であった。酸味入り澱粉粒子が分散されているソーセージ生地を充填機でケーシングに充填し、60℃、30分加熱した。加熱後急冷し、品温10℃以下になるまで冷却して、酸味物質入りソーセージを得た。
1) Manufacture of starch curd 3.00 kg of vinegar, 1.57 kg of water and 1.14 kg of tapioca starch are mixed and stirred, filled into a non-breathable casing, and the starch-containing liquid material in the casing is steam-heated at 90 ° C. for 20 minutes. did. After quenching, the product was cooled to a product temperature of 10 ° C. or lower. After cooling, the non-breathable casing was removed, and the starch card formed by heating was cut with a dicer so as to have a particle size of 2 mm or more.
2) Manufacture of sausage 62.0 kg of pork, 11.0 kg of pork fat, and 13.24 kg of water were mixed, put into a mixer, and ground to 5 mm size. Further, 1.61 kg of sodium chloride, 0.01 kg of sodium nitrite, 0.20 kg of phosphate, 0.03 kg of sodium ascorbate, and 0.2 kg of spice were added and mixed. Next, 5.71 kg of the granular starch card produced in 1) was added and mixed. Degassed during mixing. The particulate curd was dispersed in the sausage dough. The sausage dough in which sour-containing starch particles were dispersed was filled into a casing with a filling machine and heated at 60 ° C. for 30 minutes. After heating, it was cooled rapidly and cooled to a product temperature of 10 ° C. or lower to obtain a sausage containing a sour substance.

実施例1の澱粉カードの製造法として、原料として、タピオカ澱粉1.54kg、レモン果汁0.80kg、ホワイトペパー0.01kg、L−アスコルビン酸ナトリウム0.03kg、精製塩0.07kg、水飴1.25kg、酵母エキス0.11kg、グルタミン酸ナトリウム0.02kg、水1.87kgを用いる以外は、実施例1と同様の方法で澱粉カードの粒状物を作製した。該粒状物を実施例1のソーセージの製造に同様に用いて、酸味物質入りソーセージを製造した。   As a method for producing the starch card of Example 1, tapioca starch 1.54 kg, lemon juice 0.80 kg, white pepper 0.01 kg, sodium L-ascorbate 0.03 kg, purified salt 0.07 kg, starch syrup 1. Granules of starch curd were produced in the same manner as in Example 1 except that 25 kg, yeast extract 0.11 kg, sodium glutamate 0.02 kg, and water 1.87 kg were used. The granular material was used in the same manner for the production of the sausage of Example 1 to produce a sausage containing a sour substance.

Claims (11)

酸味物質と澱粉とを均一になるまで撹拌した後に加熱して得られる澱粉カードを粒状物とし、該粒状物を食肉加工食品に添加し、撹拌することにより、粒状の酸性ゲル状物を食肉加工食品に分散してなることを特徴とする酸味物質入り食肉加工食品。 The starch curd obtained by stirring the sour substance and starch until uniform and then heating is made into granules, and the granules are added to the meat processed food and stirred to process the granular acidic gel. Processed meat-containing food containing sour substances, characterized by being dispersed in food. 澱粉カードが、最大応力4g/cm以上であることを特徴とする請求項1記載の酸味物質入り食肉加工食品。 The processed starch-containing meat processed food according to claim 1, wherein the starch card has a maximum stress of 4 g / cm 2 or more. 粒状物が、粒径2mm以上であることを特徴とする請求項1又は2記載の酸味物質入り食肉加工食品。 3. The processed meat-containing food product according to claim 1 or 2, wherein the granular material has a particle size of 2 mm or more. 澱粉カードが、L−アスコルビン酸ナトリウムを0.2重量%以上含有することを特徴とする請求項1〜3のいずれか記載の酸味物質入り食肉加工食品。 The starch curd contains 0.2% by weight or more of sodium L-ascorbate, sour-processed meat processed food according to any one of claims 1 to 3. 澱粉カードのpHが2.8〜5.0であることを特徴とする請求項1〜4のいずれか記載の酸味物質入り食肉加工食品。 The pH of the starch card | curd is 2.8-5.0, The processed meat foodstuff containing the sour substance in any one of Claims 1-4 characterized by the above-mentioned. 酸味物質が、酢酸、クエン酸、フマル酸、乳酸、リンゴ酸、酒石酸、グルコノデルタラクトン、フィチン酸、リン酸及びそれらの塩のうち少なくとも1以上を含むことを特徴とする請求項1〜5のいずれか記載の酸味物質入り食肉加工食品。 The sour substance includes at least one of acetic acid, citric acid, fumaric acid, lactic acid, malic acid, tartaric acid, glucono delta lactone, phytic acid, phosphoric acid and salts thereof. Processed meat containing sour substances according to any of the above. 澱粉が、タピオカ澱粉であることを特徴とする請求項1〜6のいずれか記載の酸味物質入り食肉加工食品。 The processed starch-containing meat processed food according to any one of claims 1 to 6, wherein the starch is tapioca starch. 食肉加工食品が、挽き肉を使用した食品であることを特徴とする請求項1〜7のいずれか記載の食肉加工食品。 The processed meat product according to any one of claims 1 to 7, wherein the processed meat product is a food product using minced meat. 挽き肉を使用した食品が、ソーセージであることを特徴とする請求項8記載の食肉加工食品。 The processed meat product according to claim 8, wherein the food product using minced meat is sausage. 酸味物質と澱粉とを均一になるまで撹拌した後に加熱して酸性の澱粉カードを形成し、前記澱粉カードを細切りして粒状物にし、該粒状物を食肉加工食品に添加し、撹拌して粒状の酸性ゲル状物を食肉加工食品に分散することを特徴とする酸味物質入り食肉加工食品の製造方法。 After stirring until the sour substance and starch become uniform, an acidic starch curd is formed by heating, and the starch curd is chopped into granules, and the granules are added to the processed meat food and stirred to form granules. A method for producing a processed meat product containing a sour substance, characterized in that an acidic gel-like product is dispersed in a processed meat product. 澱粉カードが、最大応力4g/cm以上であることを特徴とする請求項10記載の酸味物質入り食肉加工食品の製造方法。 Starch card method according to claim 10 acidulant containing processed meat food according to, characterized in that the maximum stress 4g / cm 2 or more.
JP2009214853A 2009-09-16 2009-09-16 Sour taste substance-containing processed meat food Pending JP2011062126A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020000001A (en) * 2018-06-25 2020-01-09 味の素株式会社 Production method of animal meat paste product using enzyme

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2020000001A (en) * 2018-06-25 2020-01-09 味の素株式会社 Production method of animal meat paste product using enzyme
JP7209481B2 (en) 2018-06-25 2023-01-20 味の素株式会社 Process for producing meat paste product using enzyme

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