JP2011056797A - Method of forming prepreg thin film by joining in-mold injection - Google Patents

Method of forming prepreg thin film by joining in-mold injection Download PDF

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JP2011056797A
JP2011056797A JP2009209237A JP2009209237A JP2011056797A JP 2011056797 A JP2011056797 A JP 2011056797A JP 2009209237 A JP2009209237 A JP 2009209237A JP 2009209237 A JP2009209237 A JP 2009209237A JP 2011056797 A JP2011056797 A JP 2011056797A
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mold
injection
thin film
prepreg
resin
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Shui-Yuan Ma
水源 馬
Ling-Ling Cheng
玲玲 鄭
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ZUIKO ZAIRYO KOFUN YUGENKOSHI
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ZUIKO ZAIRYO KOFUN YUGENKOSHI
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method of forming a prepreg thin film by joining in-mold injection. <P>SOLUTION: In the method of forming the prepreg thin film by joining in-mold injection, an injection product having an appearance of a pattern or color of the natural or chemical fiber is formed by selecting natural or chemical fiber, applying the solvent-type or hot-melt-type prepreg treatment thereto by using a first thermoplastic resin to form the prepreg thin film, covering the upper surface and the lower surface of the prepreg thin film with a mold releasing film, cutting them to form a resin film, further applying the heating/pressing curing treatment thereto to form a cured resin film, successively applying the heating/pressing treatment thereto in a mold for molding the resin to form a resin film foamed case, placing the resin film foamed case in the mold for injection molding, applying the in-mold injection treatment thereto by utilizing a second thermoplastic resin to form an injection component in the mold for the injection molding by the second thermoplastic resin, and simultaneously completely joining the injection component with the resin film foamed case. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

本発明は一種の型内射出を結合させたプリプレグ薄膜の製造方法に係り、特に、任意の天然或いは化学繊維に対して、第1熱可塑性樹脂で溶剤式或いはホットメルト式プリプレグ処理を行ない、プリプレグ薄膜を形成し、続いて加熱加圧処理して可塑性と天然或いは化学繊維の紋様、色を具えた精美な樹脂フィルムを形成し、さらに、成形用型内で加熱加圧成形し、さらに、射出成形用型内に置いて第2熱可塑性樹脂を射出成形し、天然或いは化学繊維の紋様、色が被覆された外観を有すると共に必要な構造を具えた射出成形製品を得る方法に関する。   The present invention relates to a method of manufacturing a prepreg thin film combined with a kind of in-mold injection, and in particular, a prepreg treatment is performed on any natural or chemical fiber with a first thermoplastic resin using a solvent type or hot melt type prepreg treatment. A thin film is formed, followed by heat and pressure treatment to form an exquisite resin film with plasticity, natural or chemical fiber patterns and colors, and then heat and pressure molding in a mold, and injection. The present invention relates to a method for injection molding a second thermoplastic resin by placing in a mold and obtaining an injection molded product having a natural or chemical fiber pattern and color coated appearance and having a necessary structure.

家電用品、情報テクノロジー製品或いは交通工具は、いずれもプラスチック製外殻を有し、プラスチック製外殻に対する高い要求は一般的である。精美で、多様化及びカスタマイズされたプラスチック製外殻に対する市場の要求の高まりに応え、型内加飾(IMD)、型内転写(IMR)等の外殻パターン化技術が発展した。   Home appliances, information technology products or traffic tools all have a plastic outer shell, and a high demand for the plastic outer shell is common. In response to the growing market demand for diversified and customized plastic shells, outer shell patterning technologies such as in-mold decoration (IMD) and in-mold transfer (IMR) have been developed.

外殻の外観、質感に更に多くの変化を求める市場の要求に対し、現行のフィルム上へのインク印刷では既に市場の要求を満足させられなくなっている。本発明は、一種の、多種類の質感変化と異なるパターンを提供でき、並びに、異なるプラスチック部品を結合させられる製造方法を提供し、現在周知の技術の問題を解決する。   In contrast to the market demand for further changes in the appearance and texture of the outer shell, the current ink printing on the film cannot satisfy the market demand. The present invention provides a manufacturing method that can provide a kind of pattern different from many kinds of texture changes and that can combine different plastic parts, and solves the problems of the currently known technology.

本発明は一種の型内射出を結合させたプリプレグ薄膜の製造方法を提供し、それは、天然或いは化学繊維の材料を選択し、第1熱可塑性樹脂を用いて溶剤式或いはホットメルト式プリプレグ処理を行ない、プリプレグ薄膜を形成し、離型膜で該プリプレグ薄膜の上表面と下表面をそれぞれ被覆し、裁断して樹脂フィルムとなし、さらに加熱加圧熟成処理して熟成樹脂フィルムを形成し、続いて樹脂成形用型内で、加熱加圧処理し、樹脂フィルム発泡ケースを形成する。該樹脂フィルム発泡ケースを射出成形用型内に置き、第2熱可塑性樹脂を利用して型内射出処理し、該第2熱可塑性樹脂により該射出成形用型内で射出部材を形成し、並びに樹脂フィルム発泡ケースと完全に接合させ、射出製品を形成する。   The present invention provides a method of manufacturing a prepreg thin film combined with a kind of in-mold injection, which includes selecting a natural or chemical fiber material and performing a solvent type or hot melt type prepreg treatment using a first thermoplastic resin. And forming a prepreg thin film, covering each of the upper and lower surfaces of the prepreg thin film with a release film, cutting to form a resin film, and further heat and pressure aging to form an aged resin film, Then, heat and pressure treatment is performed in a resin molding die to form a resin film foam case. The resin film foam case is placed in an injection mold, an in-mold injection treatment is performed using a second thermoplastic resin, an injection member is formed in the injection mold using the second thermoplastic resin, and Fully bonded with resin film foam case to form injection product.

本発明により、天然或いは化学繊維の紋様、模様や色の外観を有する射出製品を形成できる。   According to the present invention, an injection product having a natural, chemical fiber pattern, pattern or color appearance can be formed.

本発明の型内射出を結合させたプリプレグ薄膜の製造方法のフローチャートである。It is a flowchart of the manufacturing method of the prepreg thin film which combined in-mold injection of the present invention. 本発明の射出製品の表示図である。It is a display figure of the injection product of this invention.

図1の本発明の型内射出を結合させたプリプレグ薄膜の製造方法のフローチャートを参照されたい。本発明の製造方法は、まず、ステップS100で開始し、続いてステップS200に進み、プリプレグ処理を行う材料を選択する。該材料は天然或いは化学繊維、例えば各種の色や模様を有する、なせん布、素生地、不織布、薄木皮、薄竹皮、皮革等の連続性を有する天然或いは化学繊維とされる。   Please refer to the flowchart of the manufacturing method of the prepreg thin film combined with the in-mold injection of the present invention in FIG. The manufacturing method of the present invention starts at step S100 and then proceeds to step S200 to select a material to be subjected to prepreg processing. The material is a natural or chemical fiber, for example, a natural or chemical fiber having various continuity such as a non-woven fabric, an unwoven fabric, a non-woven fabric, a thin bark, a thin bamboo skin or leather having various colors and patterns.

続いて、ステップS300に進み、第1熱可塑性樹脂を利用し、ステップS200で選択した材料に対して、溶剤式或いはホットメルト式プリプレグ処理を行ない、プリプレグ薄膜を形成し、すなわち、第1熱可塑性樹脂を均一に該材料にコーティングし、第1熱可塑性樹脂で該材料を被覆し、表面加熱乾燥後に離型膜でプリプレグ薄膜の上表面と下表面をそれぞれ被覆し、さらに裁断して一定面積寸法の片状の天然或いは化学繊維を有する樹脂フィルムを形成する。   Then, it progresses to step S300, performs a solvent type or hot-melt type prepreg process with respect to the material selected by step S200 using a 1st thermoplastic resin, and forms a prepreg thin film, ie, 1st thermoplasticity Resin is uniformly coated on the material, and the material is coated with the first thermoplastic resin. After the surface is heated and dried, the upper surface and the lower surface of the prepreg thin film are coated with a release film, and further cut to a constant area size. A resin film having natural flakes or chemical fibers is formed.

該第1熱可塑性樹脂はポリメチルメタクリレート(PMMA)、ポリエチルイミド(PEI)、ポリウレタン(PU)、熱可塑性ポリウレタン(TPU)、ポリエチルサルホン(PES)、ポリフェニレンエーテル(PPE)、ポリスチレン(PS)、或いは、ポリエーテルエーテルケトン(PEEK)とされ得る。   The first thermoplastic resin is polymethyl methacrylate (PMMA), polyethylimide (PEI), polyurethane (PU), thermoplastic polyurethane (TPU), polyethylsulfone (PES), polyphenylene ether (PPE), polystyrene (PS). Or polyetheretherketone (PEEK).

続いて、ステップS400に進み、樹脂フィルムを加熱加圧熟成処理し、熟成樹脂フィルムを形成し、該熟成樹脂フィルムの含有する樹脂分布は均一で、厚さは一致し、表面は滑らかで樹脂に覆われ、且つ高い光沢を有して透明であり、天然或いは化学繊維の紋様或いは模様或いは色を有する。該加熱加圧熟成処理の温度は摂氏50度から180度とし、圧力は1平方センチメートル当たり2kgから20kgとし、10分から40分間維持し、続いてステップS500に進む。   Subsequently, the process proceeds to step S400, the resin film is heat-pressed and aged to form an aged resin film, the resin distribution contained in the aged resin film is uniform, the thickness is equal, the surface is smooth, and the resin is smoothed. It is covered and transparent with high gloss and has a pattern or pattern or color of natural or chemical fiber. The temperature of the heat and pressure aging treatment is set to 50 to 180 degrees Celsius, the pressure is set to 2 to 20 kg per square centimeter, maintained for 10 to 40 minutes, and then the process proceeds to Step S500.

ステップS500で、熟成樹脂フィルムを成形用型内に入れて加熱加圧処理し、摂氏120度から200度に加熱し、成形用型内圧力を1平方センチメートル当たり2kgから20kgとし、成形用型内の真空度を50%から85%とし、樹脂フィルム発泡ケースを形成する。   In step S500, the aged resin film is placed in a mold and heated and pressurized, heated to 120 to 200 degrees Celsius, and the pressure in the mold is changed from 2 kg to 20 kg per square centimeter. The degree of vacuum is 50% to 85%, and a resin film foam case is formed.

続いてステップS600に進み、樹脂フィルム発泡ケースを射出成形用型内に置き、第2熱可塑性樹脂を利用して型内射出処理を行ない、第2熱可塑性樹脂に射出成形用型内で射出部材を形成させ、該射出部材は、必要な突起、溝、リブ及び必要な肉厚を有し、且つ該射出部材と樹脂フィルム発泡ケースは完全に接合され、射出製品が形成され、ステップS700で本発明の製造方法のフローを終了する。   Subsequently, the process proceeds to step S600, where the resin film foam case is placed in an injection mold, an in-mold injection process is performed using the second thermoplastic resin, and an injection member is injected into the second thermoplastic resin in the injection mold. The injection member has the necessary protrusions, grooves, ribs and the necessary thickness, and the injection member and the resin film foam case are completely joined to form an injection product. The flow of the manufacturing method of the invention is terminated.

第2熱可塑性樹脂はアクリロニトリル・ブタジエンスチレン共重合体(ABS)、ポリカーボネート/アクリロニトリル・ブタジエンスチレン共重合体(PC/ABS)、ポリカーボネート(PC)、ポリメチルメタクリレート(PMMA)、ポリスチレン(PS)、ポリプロピレン(PP)、ポリエチレンテレフタレート(PET)、ポリオキシメチレン(POM)、ポリアミド(PA)のいずれかとされる。   The second thermoplastic resin is acrylonitrile / butadiene styrene copolymer (ABS), polycarbonate / acrylonitrile / butadiene styrene copolymer (PC / ABS), polycarbonate (PC), polymethyl methacrylate (PMMA), polystyrene (PS), polypropylene. (PP), polyethylene terephthalate (PET), polyoxymethylene (POM), or polyamide (PA).

ステップS200において、更に選択した材料に対して定型処理を行なってもよく、例えば、カレンダー処理を行ない、該材料を定型し、変形しにくい特性を具備させて、後続のプリプレグ処理に有利として、生産速度をアップする。   In step S200, the selected material may be subjected to a standard process, for example, a calendar process is performed, the material is standardized, and the material is not easily deformed. Increase speed.

このほか、ステップS500で、成形用型内での加熱加圧処理の前に、熟成樹脂フィルムに対して裁断し、射出成形用型よりやや大きいサイズとし、且つ予熱処理し、例えば該成形用型の温度より摂氏10度から30度低い温度に加熱する。   In addition, in step S500, before the heat and pressure treatment in the molding die, the aged resin film is cut to a size slightly larger than the injection molding die and preheated, for example, the molding die. Heat to a temperature 10 to 30 degrees Celsius lower than the temperature of.

ステップS600において、型内射出処理の前に、先に樹脂フィルム発泡ケースに対してトリミングとパンチホール加工の少なくともいずれかを行ってもよい。そのうち、加工設備としてウォーターナイフ、CNC或いはパンチプレスを使用でき、これにより後続射出製品の外観品質を高め、毛羽或いはバリの発生をなくす。   In step S600, before the in-mold injection process, at least one of trimming and punch hole processing may be performed on the resin film foam case first. Among them, water knife, CNC or punch press can be used as processing equipment, thereby improving the appearance quality of subsequent injection products and eliminating the occurrence of fluff or burrs.

更に本発明の特徴をご理解いただくため、図2の本発明の射出製品表示図をご参照されたい。図2に示されるように、射出製品10は樹脂フィルム発泡ケース20と射出部材30を形成する。そのうち、樹脂フィルム発泡ケース20は外框状を呈し、射出部材30は内張状を呈し、且つ樹脂フィルム発泡ケース20と射出部材30は完全に接合されて射出製品10を形成している。注意すべきことは、上述の実施例は本発明の特徴を説明しやすくするために例示されたものに過ぎず、異なる形状及び組合せ設計の樹脂フィルム発泡ケース20と射出部材30はいずれも本発明の範囲内に属するということである。   For further understanding of the features of the present invention, please refer to the injection product display diagram of the present invention in FIG. As shown in FIG. 2, the injection product 10 forms a resin film foam case 20 and an injection member 30. Among them, the resin film foam case 20 has an outer casing shape, the injection member 30 has a lining shape, and the resin film foam case 20 and the injection member 30 are completely joined to form the injection product 10. It should be noted that the above-described embodiments are merely illustrated to facilitate the explanation of the features of the present invention, and the resin film foam case 20 and the injection member 30 having different shapes and combinations are both included in the present invention. It belongs to the range.

以上の記述は本発明の好ましい実施例を説明するためのものであり、本発明に対して如何なる形式上の制限を意図したものではなく、ゆえに、同じ発明の精神の下で、本発明に関して行う任意の修飾、変更は、いずれも本発明の保護を意図する範疇に属する。   The above description is for the purpose of illustrating a preferred embodiment of the invention and is not intended to be limiting in any form to the invention, and is therefore directed to the invention in the spirit of the same invention. Any modification and change belong to the category intended to protect the present invention.

10 射出製品 20 樹脂フィルム発泡ケース 30 射出部材 10 Injection product 20 Resin film foam case 30 Injection member

Claims (9)

型内射出を結合させたプリプレグ薄膜の製造方法において、
ステップS100で、開始し、
ステップS200で、プリプレグ処理を行う材料を選択し、該材料は天然或いは化学繊維とし、
ステップS300で、第1熱可塑性樹脂を利用し、選択した該材料に対してプリプレグ処理し、該第1熱可塑性樹脂を溶剤式或いはホットメルト式で該材料中に含浸させ、該第1熱可塑性樹脂に該材料を被覆させ、プリプレグ薄膜を形成し、並びに離型膜で該プリプレグ薄膜の上表面と下表面をそれぞれ被覆し、更に裁断して一定寸法の片状の天然或いは化学繊維含有の樹脂フィルムとなし、
ステップS400で、該樹脂フィルムを加熱加圧熟成処理し、熟成樹脂フィルムを形成し、
ステップS500で、該熟成樹脂フィルムを成形用型内で加熱加圧処理し、樹脂フィルム発泡ケースを形成し、
ステップS600で、該樹脂フィルム発泡ケースを射出成形用型内に置き、第2熱可塑性樹脂を利用して型内射出処理を行ない、該第2熱可塑性樹脂に該射出成形用型内で射出部材を形成させ、該射出部材は必要形状を具え、並びに該樹脂フィルム発泡ケースと完全に接合し、射出製品を形成し、
ステップS700で、終了し、
以上のステップを包含したことを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。
In the method of manufacturing a prepreg thin film combined with in-mold injection,
In step S100, start
In step S200, a material for prepreg processing is selected, and the material is natural or chemical fiber.
In step S300, the first thermoplastic resin is used to prepreg the selected material, the first thermoplastic resin is impregnated in the solvent type or hot melt type, and the first thermoplastic resin is impregnated. The resin is coated with the material, a prepreg thin film is formed, and the upper surface and the lower surface of the prepreg thin film are respectively coated with a release film, and further cut into a piece of natural or chemical fiber-containing resin. Without film,
In step S400, the resin film is subjected to heat and pressure aging treatment to form an aging resin film,
In step S500, the aged resin film is heated and pressurized in a molding die to form a resin film foam case,
In step S600, the resin film foam case is placed in an injection mold, an in-mold injection process is performed using the second thermoplastic resin, and the second thermoplastic resin is injected into the injection mold in the injection mold. The injection member has the necessary shape, and is completely joined to the resin film foam case to form an injection product,
In step S700, the process ends,
The manufacturing method of the prepreg thin film which combined the injection in the type | mold characterized by including the above step.
請求項1記載の型内射出を結合させたプリプレグ薄膜の製造方法において、ステップS200でさらに、選択した該材料に対して定型処理を行なって、該材料を定型し、変形しにくい特性を具備させ、後続のプリプレグ処理に有利として生産速度をアップすることを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   The method for manufacturing a prepreg thin film combined with in-mold injection according to claim 1, further comprising performing a standard processing on the selected material in step S200 to form the material and have a property of being difficult to deform. A method for producing a prepreg thin film combined with in-mold injection, wherein the production speed is increased in favor of subsequent prepreg processing. 請求項2記載の型内射出を結合させたプリプレグ薄膜の製造方法において、該定型処理をカレンダー処理とすることを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   3. The method for manufacturing a prepreg thin film combined with in-mold injection, according to claim 2, wherein the standard processing is a calendar process. 請求項1記載の型内射出を結合させたプリプレグ薄膜の製造方法において、ステップS300の該第1熱可塑性樹脂を、ポリメチルメタクリレート(PMMA)、ポリエチルイミド(PEI)、ポリウレタン(PU)、熱可塑性ポリウレタン(TPU)、ポリエチルサルホン(PES)、ポリフェニレンエーテル(PPE)、ポリスチレン(PS)、ポリエーテルエーテルケトン(PEEK)のいずれかとすることを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   The method for producing a prepreg thin film combined with in-mold injection according to claim 1, wherein the first thermoplastic resin in step S300 is polymethyl methacrylate (PMMA), polyethylimide (PEI), polyurethane (PU), heat Prepreg combined with in-mold injection, characterized in that it is one of plastic polyurethane (TPU), polyethylsulfone (PES), polyphenylene ether (PPE), polystyrene (PS), or polyetheretherketone (PEEK) Thin film manufacturing method. 請求項1記載の型内射出を結合させたプリプレグ薄膜の製造方法において、ステップS400の該加熱加圧熟成処理は、摂氏50度から180度の温度で、圧力は1平方センチメートル当たり2から20kgで、10分から40分間維持して行うことを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   The method for producing a prepreg thin film combined with in-mold injection according to claim 1, wherein the heat and pressure aging treatment in step S400 is performed at a temperature of 50 to 180 degrees Celsius and a pressure of 2 to 20 kg per square centimeter, A method for producing a prepreg thin film combined with in-mold injection, wherein the method is performed for 10 to 40 minutes. 請求項1記載の型内射出を結合させたプリプレグ薄膜の製造方法において、ステップS500の該加熱加圧処理では、摂氏120度から200度に加熱し、成形用型内圧力を1平方センチメートル当たり2kgから20kgに増し、成形用型内の真空度を50%から85%とすることを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   2. The method for producing a prepreg thin film combined with in-mold injection according to claim 1, wherein in the heating and pressurizing treatment in step S500, heating is performed from 120 degrees Celsius to 200 degrees Celsius, and the molding mold internal pressure is increased from 2 kg per square centimeter. A method for producing a prepreg thin film combined with in-mold injection, characterized in that the amount of vacuum in the mold is increased from 20% to 85%. 請求項1記載の型内射出を結合させたプリプレグ薄膜の製造方法において、ステップS500中、該成形用型内で加熱加圧処理する前に、該熟成樹脂フィルムを裁断し、該射出成形用型よりやや大きなサイズとなし、且つ予熱処理して温度を該成形用型の温度より摂氏10度から30度低い温度とすることを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   2. The method for producing a prepreg thin film combined with in-mold injection according to claim 1, wherein the aged resin film is cut before heating and pressurizing in the molding mold in step S500, and the injection molding mold is used. A method for producing a prepreg thin film combined with in-mold injection, characterized in that it has a slightly larger size and is preheated to a temperature of 10 to 30 degrees Celsius lower than the temperature of the mold. 請求項1記載の型内射出を結合させたプリプレグ薄膜の製造方法において、ステップS600の該第2熱可塑性樹脂は、アクリロニトリル・ブタジエンスチレン共重合体(ABS)、ポリカーボネート/アクリロニトリル・ブタジエンスチレン共重合体(PC/ABS)、ポリカーボネート(PC)、ポリメチルメタクリレート(PMMA)、ポリスチレン(PS)、ポリプロピレン(PP)、ポリエチレンテレフタレート(PET)、ポリオキシメチレン(POM)、ポリアミド(PA)のいずれかとすることを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   2. The method for producing a prepreg thin film combined with in-mold injection according to claim 1, wherein the second thermoplastic resin in step S600 is an acrylonitrile / butadiene styrene copolymer (ABS) or a polycarbonate / acrylonitrile / butadiene styrene copolymer. (PC / ABS), polycarbonate (PC), polymethyl methacrylate (PMMA), polystyrene (PS), polypropylene (PP), polyethylene terephthalate (PET), polyoxymethylene (POM), polyamide (PA) A method for producing a prepreg thin film combined with in-mold injection. 請求項1記載の型内射出を結合させたプリプレグ薄膜の製造方法において、ステップS600中、射出成形用型内で射出処理する前に、該樹脂フィルム発泡ケースにトリミングとパンチホール加工の少なくともいずれかを行うことで、後続射出製品に毛羽或いはバリが発生しないようにすることを特徴とする、型内射出を結合させたプリプレグ薄膜の製造方法。   2. The method for producing a prepreg thin film combined with in-mold injection according to claim 1, wherein at least one of trimming and punch hole processing is performed on the resin film foam case before injection processing in the injection mold in step S600. A method for producing a prepreg thin film combined with in-mold injection, wherein fuzz or burrs are not generated in the subsequent injection product by performing
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CN103587032A (en) * 2012-08-15 2014-02-19 汉达精密电子(昆山)有限公司 Glass surface treatment method and product thereof
CN103587031A (en) * 2012-08-14 2014-02-19 汉达精密电子(昆山)有限公司 Notebook computer keyboard molding method and product thereof
CN106363876A (en) * 2016-09-28 2017-02-01 东莞福嵘鞋材有限公司 Injection mold of PU decorative wallboard and manufacturing method of injection mold
JPWO2015029453A1 (en) * 2013-08-30 2017-03-02 Art&Tech株式会社 Textile-like in-mold sheet, method for producing the same, preform molded product, textile-like resin molded product, and method for producing the same

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103587031A (en) * 2012-08-14 2014-02-19 汉达精密电子(昆山)有限公司 Notebook computer keyboard molding method and product thereof
CN103587032A (en) * 2012-08-15 2014-02-19 汉达精密电子(昆山)有限公司 Glass surface treatment method and product thereof
JPWO2015029453A1 (en) * 2013-08-30 2017-03-02 Art&Tech株式会社 Textile-like in-mold sheet, method for producing the same, preform molded product, textile-like resin molded product, and method for producing the same
US11000980B2 (en) 2013-08-30 2021-05-11 Art & Tech Co., Ltd. Textile-like in-mold sheet, production method of the same, preform molded body, textile-like resin molded body, and production method of the same
CN106363876A (en) * 2016-09-28 2017-02-01 东莞福嵘鞋材有限公司 Injection mold of PU decorative wallboard and manufacturing method of injection mold

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