JP2011020986A - Method for diluting aqueous or stabilized solution of chlorine dioxide with strongly alkaline natural water and the aqueous or stabilized solution of chlorine dioxide obtained by the method - Google Patents
Method for diluting aqueous or stabilized solution of chlorine dioxide with strongly alkaline natural water and the aqueous or stabilized solution of chlorine dioxide obtained by the method Download PDFInfo
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本発明は、ＰＨ（水素イオン濃度）１０内外の強アルカリ性である二酸化塩素若しくは安定化二酸化塩素の設定濃度（ＰＰＭ）液を、同等のＰＨ１０内外の強アルカリ性である強アルカリ性天然水によって希釈することにより、ＰＨ移動を無くし若しくは僅少にして、ＰＨ移動に伴う酸性化による塩素臭の発生を無くし若しくは僅少にしたことを特徴とする、二酸化塩素水溶液若しくは安定化二酸化塩素液を強アルカリ性天然水で希釈する方法、及び、該方法で希釈した二酸化塩素水溶液若しくは安定化二酸化塩素液に係り、両者を攪拌混合できる設備装置があれば、従来のような特別の設備装置不要で、何所でも安全かつ極めて容易に、設定濃度（ＰＰＭ）に希釈した二酸化塩素水溶液若しくは安定化二酸化塩素液を製造し得るようにしたものである。
また、前記本発明方法で製した二酸化塩素水溶液若しくは安定化二酸化塩素液は、製造後もＰＨ１０内外で安定して長期間変化なくその作用・効果を保持し、また、使用時、使用後にも塩素臭が殆どしないことを特徴とするものである。The present invention is to dilute a strongly alkaline chlorine dioxide or stabilized chlorine dioxide concentration (PPM) solution inside or outside the PH (hydrogen ion concentration) 10 with a strong alkaline natural water which is a strong alkali inside or outside the PH 10. Diluting a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution with strong alkaline natural water, which eliminates or minimizes PH movement and eliminates or minimizes the generation of chlorine odor due to acidification accompanying PH movement If there is an equipment that can be stirred and mixed with a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution diluted by the method, a special equipment such as a conventional one is unnecessary, and it is safe and extremely anywhere. An aqueous chlorine dioxide solution or a stabilized chlorine dioxide solution diluted to a set concentration (PPM) can be easily produced. Than is.
In addition, the aqueous chlorine dioxide solution or the stabilized chlorine dioxide solution produced by the method of the present invention stably maintains its action and effect for a long period of time in and out of the PH10 after production, and also during use and after use. It is characterized by almost no odor.
「二酸化塩素（ＣｌＯ２）について」
従来、二酸化塩素（ＣｌＯ２）は、消臭・殺菌・防腐等において極めて強力かつ優れた効果を発揮するものとして知られており、塩素（Ｃｌ）と比較して化学構造的に安定であり、アンモニア、フェノール類およびフミン酸と反応せず，クロラミン、クロロフェノール類およびトリハロメタンを生成しないこと、また、塩素のようにＰＨ値の上昇による殺菌力の低下がみられず、広範囲なＰＨ領域での有効性が認められること等の優れた特徴を有する。
二酸化塩素（ＣｌＯ２）は、気体（二酸化塩素ガス）であり、水溶性であるため、通常、水（Ｈ２Ｏ）で設定濃度（ＰＰＭ）に希釈した水溶液として流通しているが、該二酸化塩素水溶液は、常温でもガス化が常に進行して塩素ガスを発生して強い塩素臭を発し、よって、法的制約の有る特殊かつ大掛かりな製造設備装置を必要とし、貯蔵が困難である等の課題があるため、その用途はかなり限定されている。
また、２５〜３０万ＰＰＭの水溶液が原液（法的劇物危険物）として製造・販売されており、それを６００００ＰＰＭ内外（ＰＨ１０内外）に希釈した水溶液は法定危険物外で誰でも取扱えるものとして市販されているが、この水溶液でも、常にガス化が進行して二酸化塩素ガス、塩素ガスを発生して強い塩素臭を発しており、よって、これを一般的な消臭・殺菌等の使用目的で更に低濃度に水で希釈すると、水（ＰＨ７）へのＰＨ移動に伴う酸性化が進行する過程で、下記のように、塩素ガスが発生し、強烈な塩素臭を発する課題があった。
なお、二酸化塩素水溶液の作用・効果、濃度（ＰＰＭ）別の用途、及び、課題等は、下記の安定化二酸化塩素と略共通しているが、二酸化塩素水溶液の方は、安定化二酸化塩素に比し不安定なため、現在の作用・効果及び濃度（ＰＰＭ）別の用途等はかなり限定されている。“About chlorine dioxide (ClO 2 )”
Conventionally, chlorine dioxide (ClO 2 ) is known to exhibit extremely strong and excellent effects in deodorization, sterilization, preserving, etc., and is chemically structurally stable compared to chlorine (Cl), Does not react with ammonia, phenols and humic acid, does not produce chloramine, chlorophenols and trihalomethane, and does not show a decrease in bactericidal activity due to an increase in PH value like chlorine, and in a wide PH range. It has excellent characteristics such as effectiveness.
Chlorine dioxide (ClO 2 ) is a gas (chlorine dioxide gas) and is water-soluble, and therefore normally circulates as an aqueous solution diluted to a set concentration (PPM) with water (H 2 O). Chlorine aqueous solution is constantly gasified even at room temperature, generating chlorine gas and producing strong chlorine odor, thus requiring special and large production equipment with legal restrictions and difficult to store. Due to the challenges, their use is quite limited.
An aqueous solution of 25-300,000 PPM is manufactured and sold as a stock solution (legal and dangerous material dangerous), and an aqueous solution obtained by diluting it inside and outside 60000PPM (inside and outside of PH10) can be handled by anyone outside the legally dangerous materials However, even in this aqueous solution, gasification always proceeds and chlorine dioxide gas and chlorine gas are generated and a strong chlorine odor is emitted. Therefore, it is used for general deodorization and sterilization. When diluted with water for a lower concentration for the purpose, there was a problem in that chlorine gas was generated and intense chlorine odor was generated in the process of acidification accompanying the PH transfer to water (PH7) as follows. .
In addition, the action, effect, concentration (PPM) use and problem of chlorine dioxide aqueous solution are almost the same as the following stabilized chlorine dioxide. Because of its instability, the current actions / effects and applications by concentration (PPM) are considerably limited.
「安定化二酸化塩素（ＮａＣｌＯ２）について」
一方、近時、前記二酸化塩素（ＣｌＯ２）を、アルカリ性水溶液に溶存させて安定化処理した、安定化二酸化塩素（ＮａＣｌＯ２）液が製造販売されており、現在、濃度２０〜３０万ＰＰＭ液（これを原液とする）を、誰にでも安全・手軽に使用できる濃度に希釈した６００００ＰＰＭ内外（ＰＨ１０内外）のものが市販されている。
前記安定化二酸化塩素（ＮａＣｌＯ２）は、高ＰＨ域でも安定して塩素のように性質が劣化せず、例えば、水処理分野で、塩素添加ではフェノールが微量でもあるとクロロフェノールに変化してしまうが、安定化二酸化塩素はフェノールを酸化して無味無臭の物質に変化でき、味や臭いのもとになる鉄やマンガンの酸化除去を行うときも塩素よりはるかに速やかな効果があり、味や臭いのもとになる藻類の繁殖も抑え、特にトリハロメタンの発生の無い飲料水の殺菌・消臭剤として塩素にとって換わり得る特徴がある。“About Stabilized Chlorine Dioxide (NaClO 2 )”
On the other hand, recently, a stabilized chlorine dioxide (NaClO 2 ) solution in which the chlorine dioxide (ClO 2 ) is dissolved and stabilized in an alkaline aqueous solution has been manufactured and sold, and currently has a concentration of 200 to 300,000 PPM solution. 60000PPM internal and external (PH10 internal and external) diluted to a concentration that can be used safely and easily by anyone is commercially available.
The stabilized chlorine dioxide (NaClO 2 ) is stable and does not deteriorate like chlorine even in a high PH range. For example, in the water treatment field, when chlorine is added, the amount of phenol is changed to chlorophenol. However, stabilized chlorine dioxide can oxidize phenol and turn it into a tasteless and odorless substance, and it has a much quicker effect than chlorine when oxidizing and removing iron and manganese, which are the source of taste and smell. It also suppresses the growth of algae that cause odors and has the characteristics that it can replace chlorine as a disinfectant and deodorant for drinking water that does not generate trihalomethane.
なお、前記の市販されている二酸化塩素水溶液若しくは安定化二酸化塩素液は６００００ＰＰＭ内外という高濃度（ＰＰＭ）であるため、常態において、かなり強烈な塩素臭を発生しており、特に、二酸化塩素水溶液の方が不安定なため、二酸化塩素ガス、塩素ガスの放出が多く、塩素臭が強いものである。In addition, since the above-mentioned commercially available chlorine dioxide aqueous solution or stabilized chlorine dioxide solution has a high concentration (PPM) of 60000 PPM inside or outside, it generates a fairly intense chlorine odor in the normal state. Because it is more unstable, it emits a lot of chlorine dioxide gas and chlorine gas and has a strong chlorine odor.
「二酸化塩素水溶液若しくは安定化二酸化塩素液の主な作用・効果」
下記は、二酸化塩素水溶液若しくは安定化二酸化塩素液の現在知られている主な作用・効果であり、極めて優れた特徴を有することが判る。
（１）．魚介類、穀物類、乾物類、菓子・パン類、麺類、かまぼこ類、ハム類などの貯蔵・保存・輸送時の鮮度保持、長期保存と劣化防止の作用・効果。
（２）．病院、化学工場・食品工場・下水ゴミ処理場等、病院、レストラン、家庭内などからでる塩素系・硫化物系・フェノール類系・アミン類系等の消臭、消臭剤としての作用・効果、また、それらに関する殺菌・除菌、消毒剤としての作用・効果。
（３）．化粧品、医薬品類のなどの殺菌，消毒剤としての作用・効果、水虫、皮膚病などの治療成分や消毒液としての作用・効果。
（４）．ペット関係の皮膚病予防と殺菌・除菌，消臭の作用・効果。
（５）．農作物育成時のカビや病気の防止、収穫後の雑菌、カビ発生防止の作用・効果。
（６）．貯水槽・浄化槽・プール・鑑賞魚飼育水槽等の除菌・塩素臭・カビ臭等の消臭・藻類の除去の作用・効果。“Main functions and effects of chlorine dioxide aqueous solution or stabilized chlorine dioxide solution”
The following are the main actions and effects currently known of chlorine dioxide aqueous solution or stabilized chlorine dioxide solution, and it can be seen that they have extremely excellent characteristics.
(1). Actions and effects of keeping freshness during storage, preservation and transportation, long-term preservation and deterioration prevention of seafood, cereals, dried foods, confectionery and bread, noodles, kamabokos, hams, etc.
(2). Deodorizing and deodorizing agents such as chlorine, sulfide, phenols and amines from hospitals, chemical factories, food factories, sewage waste disposal plants, hospitals, restaurants, homes, etc. In addition, sterilization and sterilization related to them, action and effects as a disinfectant.
(3). Actions and effects as disinfectants for sterilization and disinfection of cosmetics, pharmaceuticals, etc. Actions and effects as treatment ingredients and disinfectants for athlete's foot and skin diseases.
(4). Actions and effects of pet-related skin disease prevention, sterilization, sterilization and deodorization.
(5). Actions and effects to prevent mold and disease when growing crops, to prevent germs and fungi after harvest.
(6). Actions and effects of sterilization, deodorization of chlorine odor, mold odor, and algae removal in water storage tanks, septic tanks, swimming pools, appreciation fish breeding tanks, etc.
「二酸化塩素水溶液若しくは安定化二酸化塩素液の濃度（ＰＰＭ）別の主な使用・用途例」
下記は、現在知られている二酸化塩素水溶液若しくは安定化二酸化塩素液の濃度（ＰＰＭ）別の主な使用・用途例である。
下記からして、通常は極く低濃度（ＰＰＭ）で足りることが判り、例えば、一般的な家庭用・軽い業務用等としては１０〜１００ＰＰＭ位で足り、業務専用としても１００〜５００ＰＰＭ位で十分であり、５００〜１０００ＰＰＭ、それ以上になるとは事業用・工業用など特殊なものが対象となることが判る。
（１）．１〜５〜１０ＰＰＭ
飲料水・冷却水・循環水等の、消臭・除菌。
プール・水槽等の、除菌・塩素・硫化水素臭除去・緑藻の除去。
（２）．１０〜１００ＰＰＭ
乾物類、穀物類、野菜・果物・魚介類、菓子、パン、麺、かまぼこ、ハム等の、鮮度保持・長期保存、劣化防止。
（３）．１００〜５００ＰＰＭ
浄化槽、排水、肉店、魚市場、鮮魚店、スーパー、業務用冷凍冷蔵庫、食品加工場、一般家庭、ゴミ置き場、台所ゴミ，オシボリ、靴、オシメ等の、極めて効果的な消臭・殺菌・消毒。
（４）．５００〜１０００ＰＰＭ
化学工場、下水処理場、し尿処理場、ゴミ処理場、畜産飼育場、畜産肉処理場、ペット関係、スポーツクラブ更衣室、公衆トイレ、病院・養護施設・老人ホーム等の極めて効果的な消臭・殺菌・消毒。
（５）．１０００〜１３００ＰＰＭ
植物繊維類、油脂類等の漂白・殺菌・消毒。
（６）．１０００〜５０００ＰＰＭ
下水、汲み取り式便所等の極めて効果的な消臭・殺菌・消毒。“Examples of main uses and applications by concentration of chlorine dioxide aqueous solution or stabilized chlorine dioxide solution (PPM)”
The following are examples of main uses and applications according to the concentration (PPM) of currently known chlorine dioxide aqueous solution or stabilized chlorine dioxide solution.
From the following, it can be seen that usually a very low concentration (PPM) is sufficient, for example, about 10-100 PPM is enough for general household use, light business use, etc., and about 100-500 PPM is also for business use only. It can be seen that if it is sufficient, 500-1000 PPM, or more, special products such as business and industrial use are targeted.
(1). 1 to 10 PPM
Deodorization and sterilization of drinking water, cooling water and circulating water.
Sanitization, removal of chlorine and hydrogen sulfide odors, removal of green algae from pools and water tanks
(2). 10-100PPM
Maintains freshness, long-term storage, and prevents deterioration of dried foods, cereals, vegetables, fruits, seafood, confectionery, bread, noodles, kamaboko, ham, etc.
(3). 100-500PPM
Septic tank, drainage, meat store, fish market, fresh fish store, supermarket, commercial refrigerator / freezer, food processing plant, general household, garbage storage, kitchen trash, osboli, shoes, urine etc. Disinfection.
(4). 500-1000PPM
Extremely effective deodorization of chemical factories, sewage treatment plants, human waste treatment plants, garbage processing plants, livestock breeding plants, livestock meat processing plants, pet-related, sports club changing rooms, public toilets, hospitals, nursing homes, nursing homes, etc.・ Sterilization and disinfection.
(5). 1000-1300PPM
Bleaching, sterilization and disinfection of plant fibers and fats.
(6). 1000-5000PPM
Extremely effective deodorization, sterilization and disinfection of sewage and flush toilets.
なお、安定化二酸化塩素液（ＮａＣｌＯ２）は殺菌・消臭・防腐・消毒等の作用・効果の点において二酸化塩素水溶液（ＣｌＯ２）にわずかに劣るが、長期間使用・保存が可能なその安定性において、また、塩素ガス・塩素臭の発生が少ない環境適合性の点で、二酸化塩素水溶液（ＣｌＯ２）に数段勝ることが認められている。Although stabilized chlorine dioxide solution (NaClO 2 ) is slightly inferior to chlorine dioxide aqueous solution (ClO 2 ) in terms of action and effect such as sterilization, deodorization, antiseptic and disinfection, it can be used and stored for a long time. In terms of stability and environmental compatibility with little generation of chlorine gas / chlorine odor, it is recognized that it is several times superior to an aqueous chlorine dioxide solution (ClO 2 ).
「従来の二酸化塩素水溶液若しくは安定化二酸化塩素液を製造する場合の課題」
而して、現在は、上記の一般的な使用目的に用いる低濃度（例、１０００ＰＰＭ以下）の二酸化塩素水溶液若しくは安定化二酸化塩素液を製造する場合、通常、市販されていて比較的取り扱いに安全な濃度６００００ＰＰＭ内外のものを使用し、該二酸化塩素水溶液若しくは安定化二酸化塩素液を水（中性、ＰＨ７）に混入して設定倍に希釈する方式で製造しており、例えば、１２０倍に希釈して５００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化塩素液を製造し、７５倍に希釈して８００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化塩素液を製造し、若しくは、前記の方式で希釈済みのものを用い、それを更に設定倍に希釈して１００ＰＰＭ以下の二酸化塩素水溶液若しくは安定化二酸化塩素液を製造するようにしている。“Problems in manufacturing conventional chlorine dioxide aqueous solution or stabilized chlorine dioxide solution”
Thus, at present, when producing a low concentration (for example, 1000 PPM or less) chlorine dioxide aqueous solution or stabilized chlorine dioxide solution used for the above general purpose of use, it is usually commercially available and relatively safe to handle. It is manufactured by using a solution with a concentration of 60,000 PPM inside or outside, and diluting the chlorine dioxide aqueous solution or stabilized chlorine dioxide solution into water (neutral, PH7) to a set multiple. 500PPM chlorine dioxide aqueous solution or stabilized chlorine dioxide solution, and dilute 75 times to produce 800PPM chlorine dioxide aqueous solution or stabilized chlorine dioxide solution, or use the one diluted in the above method Then, it is further diluted to a set factor to produce a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution of 100 PPM or less.
ところが、二酸化塩素水溶液（ＣｌＯ２）若しくは安定化二酸化塩素液（ＮａＣｌＯ２）は強アルカリ性液体（ＰＨ１０内外）であるため、水（中性、ＰＨ７）で希釈すると、
ＰＨ１０（ＣｌＯ２・ＮａＣｌＯ２）−ＰＨ７（Ｈ２Ｏ）＝ＰＨ３
の濃度差分（ＰＨ移動分）だけ、二酸化塩素水溶液若しくは安定化二酸化塩素液（ＣｌＯ２・ＮａＣｌＯ２）が酸性化（水酸イオンＯＨが減少してＰＨが減少する。）（全体がＰＨ７になるまで酸性化が進行する。）するため、塩素ガスが発生し強烈な塩素臭を生じる課題があり、その上、二酸化塩素水溶液若しくは安定化二酸化塩素液は強アルカリ性の塩素系化合物であり、希釈過程の塩素系ガスの発生と相俟って環境に悪影響を及ぼし、特に金属に対する腐食作用が極めて強く機械設備等を急速に腐食損傷するため普通の工場等に取扱いを嫌われる課題があった。However, since the aqueous chlorine dioxide solution (ClO 2 ) or the stabilized chlorine dioxide solution (NaClO 2 ) is a strong alkaline liquid (inside and outside of PH10), when diluted with water (neutral, PH7),
PH10 (ClO 2 · NaClO 2 ) −PH7 (H 2 O) = PH 3
The aqueous solution of chlorine dioxide or the stabilized chlorine dioxide solution (ClO 2 · NaClO 2 ) is acidified by the difference in concentration (PH transfer amount) (the hydroxyl ion OH is reduced and the PH is reduced.) As a result, chlorine gas is generated and a strong chlorine odor is generated. In addition, the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution is a strong alkaline chlorine compound. In combination with the generation of chlorine-based gas, it has an adverse effect on the environment. In particular, it has an extremely strong corrosive action on metals and rapidly damages machinery and equipment.
一方、５００ＰＰＭ以下の低濃度の二酸化塩素水溶液若しくは安定化二酸化塩素液でも、上記の通り、消臭・殺菌・防腐等の作用・効果を発揮するが、一部の菌類の殺菌・滅菌、長期の防臭、腐敗防止についてあまり有効でないことが知られ、よって、前記に対する作用・効果を向上するためには、１０００ＰＰＭ〜２０００ＰＰＭの高濃度の二酸化塩素水溶液若しくは安定化二酸化塩素液が必要とされるが、濃度ＰＰＭの数値が大になるほど、当然、水に対する二酸化塩素水溶液若しくは安定化二酸化塩素液の量（比率）も多くなるため、塩素ガスの発生量も大になり、塩素臭も強烈になる課題があった。
そのため、現在、通常の工場では１０〜１００ＰＰＭ位までが限界で、５００〜１０００ＰＰＭ、それ以上のものは適応設備を有する化学工場等の他は取り扱う工場がないという課題があり、その場合、製造ロットが大量になるため、コスト高にならざるを得ない課題があった。On the other hand, a low-concentration chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution of 500 PPM or less exerts the effects and effects such as deodorization, sterilization, and antiseptic as described above. It is known that it is not very effective for deodorization and anti-corruption. Therefore, in order to improve the action and effect against the above, a high concentration chlorine dioxide aqueous solution or stabilized chlorine dioxide solution of 1000 PPM to 2000 PPM is required. Naturally, the larger the value of the concentration PPM, the larger the amount (ratio) of the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution to the water, so that the amount of chlorine gas generated increases and the chlorine odor becomes intense. there were.
Therefore, there is a problem that there are currently no factories other than a chemical factory having an adaptable facility, such as a chemical factory having an adaptable facility, with a limit of 10 to 100 PPM in a normal factory, and a limit of 500 to 1000 PPM. Because of the large amount, there was a problem that the cost was inevitably high.
なお、従来、業者等は、低濃度に希釈済みの安定化二酸化塩素液（製品、商品）は臭いがしないと称しているが、実際は、僅かずつ酸化、酸性化するため、保管、使用時、使用後等に塩素ガスが発生し塩素臭がするのが避けられず、濃度が高くなる（例、２００ＰＰＭ以上）に従ってそれが強くなり、使用に差し障りになる課題があった。In addition, the traders have conventionally said that the stabilized chlorine dioxide solution (product, merchandise) diluted to a low concentration does not smell, but in fact, it is oxidized and acidified little by little. There is a problem that chlorine gas is generated after use and a smell of chlorine is unavoidable and becomes stronger as the concentration becomes higher (eg, 200 PPM or more), which hinders use.
「強アルカリ性水（Ｈ２Ｏ）について」
通常、同じ水（Ｈ２Ｏ）であっても、ＰＨ９〜１０以上の強アルカリ性水、例えば、電解で人工的に製造したＰＨが９〜１０以上の強アルカリ性電解水であると、還元、消毒、殺菌、滅菌、漂白等の作用に優れた特性を有するが、同時に、腐食性・毒性が強く、たんぱく質を分解するので直接皮膚に触れると炎症を起こし、目に入ると視力低下・失明の恐れがあり、そのような場合は直ちに多量の水で洗浄し、ホウ酸等で中和しないと極めて危険であり、直接、人体、皮膚等には到底使用できないものである。
特に、前記９〜１０以上の人工の強アルカリ性水は、安定性がないため、ＰＨ移動による酸性化が進行し、時間経過で次第に元のＰＨ７（中性）に戻ってしまう欠点があるため、その用途は極く限られていた。
この点、本発明で用いる下記の強アルカリ性天然水は、天然湧水で全く安定しているため、長期間９〜１０以上の強アルカリ性が全く変化しない。About strong alkaline water (H 2 O)
Usually, even if the same water (H 2 O) is used, strong alkaline water having a pH of 9 to 10 or more, for example, strong alkaline electrolytic water having a pH of 9 to 10 or more artificially produced by electrolysis is reduced and disinfected. It has excellent properties such as sterilization, sterilization, bleaching, etc., but at the same time it is highly corrosive and toxic and degrades protein, causing direct irritation and contact with the skin. In such a case, it is extremely dangerous unless it is immediately washed with a large amount of water and neutralized with boric acid or the like, and cannot be used directly on the human body or skin.
In particular, the above 9-10 or more artificial strong alkaline water has no stability, so acidification by PH movement proceeds, and there is a drawback that it gradually returns to the original PH7 (neutral) over time. Its use was extremely limited.
In this respect, the following strongly alkaline natural water used in the present invention is completely stable in natural spring water, and thus the strong alkalinity of 9 to 10 or more does not change at all for a long time.
「強アルカリ性天然水について」
（１）上記に対し、ＰＨ濃度が上記人工の強アルカリ性電解水と同等のＰＨ９〜１０以上の強アルカリ性でありながら、人体に無害なばかりでなく、極めて有益な天然水が存在する。
即ち、その天然水とは、ＰＨ９〜１０以上の強アルカリ性天然水を指し、該強アルカリ性天然水は自然界において温泉・鉱泉（温泉水・鉱泉水・ミネラルウォーター）として存在している。
（２）従来から温泉・鉱泉等を酸性泉，中性泉、アルカリ性泉のようにＰＨ濃度で分類することが行われており、その内、ＰＨ９〜１０以上の温泉・鉱泉等を強アルカリ性泉と称しているが、この自然界に存在する強アルカリ性泉は世界的にも稀にしか知られておらず、若しくは最近まで注目されたことが無く、国内でも殆ど知られず、存在していても注目されなかったが、近年、国内処々で主として非火山性（火山の影響の少ない所）の地下深層水（地中深くボーリングして汲み上げた）としてこの強アルカリ性泉水が発見され、また、温泉水・鉱泉水・ミネラルウォーターとして種々の優れた特徴を有することが判明するに及んで、新しい温泉（場）が処々に開かれ、また、この泉質を有する旧来の温泉（場）・鉱泉（場）が見直されつつある。
（３）前記強アルカリ性天然水の温泉としては、現在、国内で下記（５）記載、その他２０箇所以上の温泉場が知られており、何れも、ＰＨ９〜１０以上の強アルカリ性天然水であり、何れも温泉法で公認された温泉若しくは鉱泉であり、泉質は単純アルカリ泉のものが多いが、それ以外のものもある。
一般的に酸性泉は物質を溶かす力が強く溶存物質が多くなる傾向があるが、反対にアルカリ性泉は物質が沈殿しやすいために溶存物質が少なく、従って、無色澄明、無味無臭で身体に対する刺激が強くなく、皮膚病、消化器病、神経病、婦人病、痔疾、特に皮膚病に効くと言われ、肌がすべすべになり、お湯がやわらかくて入り心地がよく、湯冷めがしにくく、「美人の湯」などと呼ばれる温泉として多くの人に好まれている。
また、安全に飲用できて、上記諸病に効くとされ、ミネラルウォーターとしても使用・販売されている。
（４）本発明においては、前記強アルカリ性泉の温泉水・鉱泉水・ミネラルウォーターを「強アルカリ性天然水」と記する。
本発明は二酸化塩素水溶液若しくは安定化二酸化塩素液の希釈用の水（Ｈ２Ｏ）として、前記の強アルカリ性天然水に特定して使用することを特徴とするものである。
（５）強アルカリ性泉の国内の温泉・鉱泉の例
１．東京都西多摩郡−Ｈ温泉・・ＰＨ１０．４、泉温・１７．５℃
２．神奈川県厚木市−Ｉ温泉・・ＰＨ１０．４、泉温・２８．５℃
３．埼玉県比企郡−Ｏ温泉・・ＰＨ１０．１、泉温・２７．８℃
４．埼玉県比企郡−Ｔ温泉・・ＰＨ１１．３、泉温・１４．９℃
５．山梨県南都留郡−Ｙ温泉・・ＰＨ１０．０、泉温・２５．６℃
６．山梨県塩山市−Ｄ温泉・・ＰＨ１０．０、泉温・３０．３℃
７．長野県北安曇郡−Ｈ温泉・・ＰＨ１１．３、泉温・５２．４℃
８．長野県下伊那郡−Ａ温泉・・ＰＨ１０．４、泉温・２８．５℃
９．石川県輪島市−Ｎ温泉・・ＰＨ１０．５、泉温・３８．０℃
１０．岩手県久慈市−Ｓ温泉・・ＰＨ１０．５、泉温・１７．８℃About strong alkaline natural water
(1) Contrary to the above, there is natural water that is not only harmless to the human body but also extremely beneficial, although the PH concentration is strong alkaline having a pH of 9 to 10 or more equivalent to the artificial strong alkaline electrolyzed water.
That is, the natural water refers to strong alkaline natural water having a pH of 9 to 10 or more, and the strong alkaline natural water exists in nature as a hot spring / mineral spring (hot spring water / mineral water / mineral water).
(2) Conventionally, hot springs and mineral springs have been classified according to PH concentration, such as acidic springs, neutral springs, and alkaline springs. Among them, hot springs and mineral springs with a pH of 9-10 or more are strongly alkaline springs. However, this strong alkaline spring that exists in the natural world is rarely known in the world, or has not been noticed until recently, hardly known in the country, even if it exists In recent years, however, this strongly alkaline spring water has been found mainly as non-volcanic (less affected by volcanoes) underground deep water (deeply pumped up deep in the ground) in various places in Japan. New hot springs (places) were opened in various places as it was found to have various excellent characteristics as mineral spring water and mineral water, and the old hot springs (places) and mineral springs (places) with this spring quality Has been reviewed A.
(3) Currently, the hot alkaline natural water hot springs described in (5) below and other 20 or more hot springs are known in Japan, and all of them are strong alkaline natural waters having a pH of 9 to 10 or more. These are all hot springs or mineral springs certified by the hot spring method, and the quality of the springs is mostly simple alkaline springs, but there are others.
In general, acidic springs have a strong ability to dissolve substances and tend to have more dissolved substances, but alkaline springs, on the other hand, have less dissolved substances because substances tend to settle, and are therefore colorless and clear, tasteless and odorless and irritate the body. It is said to be effective for skin diseases, digestive tract diseases, neurological diseases, gynecological diseases, gonorrhea, especially skin diseases, the skin becomes smooth, the hot water is soft and comfortable, the hot water is hard to cool, Many people like it as a hot spring called “no-yu”.
In addition, it is safe to drink and is effective for the above-mentioned diseases, and is also used and sold as mineral water.
(4) In the present invention, the hot spring water, mineral spring water, and mineral water of the strong alkaline spring are referred to as “strong alkaline natural water”.
The present invention is characterized in that it is used as the above-mentioned strong alkaline natural water as water for diluting a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution (H 2 O).
(5) Examples of domestic hot springs and mineral springs with strong alkaline springs Nishitama-gun, Tokyo-H hot spring, PH 10.4, spring temperature, 17.5 ° C
2. Atsugi, Kanagawa-I Onsen, PH 10.4, spring temperature, 28.5 ° C
3. Hiki-gun, Saitama-O Onsen ··· PH 10.1, spring temperature · 27.8 ° C
4). Hiki-gun, Saitama-T hot springs, PH 11.3, spring temperature, 14.9 ° C
5. Minamitsuru-gun, Yamanashi-Y hot spring, PH 10.0, spring temperature, 25.6 ° C
6). Shioyama, Yamanashi-D hot springs, PH 10.0, spring temperature, 30.3 ° C
7). Kitazumi-gun, Nagano-H hot springs, PH 11.3, spring temperature, 52.4 ° C
8). Shimoina-gun, Nagano-A hot springs, PH 10.4, spring temperature, 28.5 ° C
9. Wajima-shi, Ishikawa-N hot springs, PH10.5, spring temperature, 38.0 ° C
10. Kuji-shi, Iwate-S hot springs, PH10.5, spring temperature, 17.8 ° C
「強アルカリ性天然水の課題」
上記のように、本発明で用いる前記強アルカリ性天然水は、ＰＨ１０内外の強アルカリ性でありながら、天然湧水で極めて安定しており長期間放置してもＰＨ１０内外が変動することがなく、所謂温泉等としての効能が認められて公認された温泉等として厳然として存在し、また、温泉水・鉱泉水・ミネラルウォーターとして安全に飲用されているものである。
然しながら、前記ＰＨ１０内外の強アルカリ性天然水も、従来は、極めて稀で特異かつ優れた特性を有する温泉水・鉱泉水・ミネラルウォーターということだけで、前記温泉水・鉱泉水・ミネラルウォーター以外の使用目的については全く考慮されたことが無かったものである。"Problems of strong alkaline natural water"
As described above, the strong alkaline natural water used in the present invention is strongly alkaline in and out of PH10, but is extremely stable with natural spring water, so that the inside and outside of PH10 do not fluctuate even if left for a long period of time. It is strictly recognized as a hot spring that has been recognized for its effectiveness as a hot spring, and is safely drunk as hot spring water, mineral spring water, or mineral water.
However, strong alkaline natural water inside and outside the PH10 has been used only for hot spring water, mineral spring water, and mineral water, which has been extremely rare and has unique and excellent characteristics. The purpose has never been considered.
前記のように、本願発明者は、先に、ＰＨ１０以上の強アルカリ性泉の国内某温泉場の存在を知り、その強アルカリ性天然水（温泉用の他、飲用のミネラルウォーターとしても販売されている。）を入手して、この温泉水の天然水がＰＨ１０以上の強アルカリ性であること、人工の強アルカリ性水が不安定で時間経過で元の水（中性・ＰＨ７）に戻ってしまうのに対し、天然水であるため極めて安定して長期間ＰＨ値が変動しない点に注目して、その新規な利用価値を開発する研究・開発を行ってきたものである。As described above, the inventor of the present application first knows the existence of a domestic hot spring resort with a strong alkaline spring having a pH of 10 or more, and is also sold as a strong alkaline natural water (for hot springs and drinking mineral water). )), The natural water of this hot spring water is strongly alkaline with a pH of 10 or more, and the artificial strong alkaline water is unstable and returns to the original water (neutral / PH7) over time. On the other hand, since it is natural water, it has been researched and developed to develop its new utility value, paying attention to the fact that the PH value is extremely stable and does not change for a long time.
他方、本願発明者は、従来、ＰＨ１０内外の強アルカリ性である二酸化塩素若しくは安定化二酸化塩素の設定濃度（ＰＰＭ）液を水（ＰＨ７）で希釈していたため、二酸化塩素若しくは安定化二酸化塩素のＰＨ１０内外がＰＨ７（希釈水）へＰＨ移動して酸性化が進行する過程で塩素ガスが発生し塩素臭が生じるのであるから、希釈水の方もＰＨ１０内外のものを使用すれば、ＰＨ移動が無く、従って、酸性化も無く、従って、塩素ガス発生、塩素臭発生も無いのではないかということに想到した。On the other hand, the inventor of the present application has conventionally diluted a set concentration (PPM) solution of chlorine dioxide or stabilized chlorine dioxide, which is strongly alkaline inside and outside PH10, with water (PH7). Therefore, PH10 of chlorine dioxide or stabilized chlorine dioxide is used. Since chlorine gas is generated and chlorine odor is generated in the process of acidification progressing when PH moves to PH7 (diluted water), there is no PH movement if the diluted water is also used inside and outside PH10. Therefore, it was thought that there was no acidification, and therefore there was no generation of chlorine gas or chlorine odor.
そこで、当初はＰＨ１０内外の電解水を種々試したのであるが、ＰＨ１０内外の電解水は危険物である上に、不安定で短時間で元の水ＰＨ７にもどってしまうため、全く不適合であった。Therefore, at first we tried various types of electrolyzed water inside and outside the PH10, but the electrolyzed water inside and outside the PH10 is dangerous and is unstable and returns to the original water PH7 in a short time. It was.
この時点で、前記のように新規な利用・応用法等を模索していたＰＨ１０内外の強アルカリ性天然水が、その元来安全で安定している特性が適合するのではないかということに着到し、該ＰＨ１０内外の強アルカリ性天然水でＰＨ１０内外の二酸化塩素水溶液若しくは安定化二酸化塩素液を希釈してみた結果、ＰＨ移動が無く若しくは殆ど無く、従って、酸性化も無く若しくは殆ど無く、従って、塩素ガス発生、塩素臭発生も無く若しくは殆ど無くすることが可能であると共に、塩素ガス発生、塩素臭発生が無く若しくは殆ど無いため、極く普通の工場と極めて簡単な設備装置で安全かつ容易に希釈することが可能であり、その上、低濃度（例、１０〜１００ＰＰＭ以上）から高濃度（例、３０００ＰＰＭ位）の希釈を同設備装置で安全かつ容易に希釈すること可能であることを実証して、今回、二酸化塩素水溶液若しくは安定化二酸化塩素液を強アルカリ性天然水で希釈する方法、及び、該方法で希釈した二酸化塩素水溶液若しくは安定化二酸化塩素液を開発・発明し、もって、従来の課題を解決したものである。At this point, we conclude that the strongly alkaline natural water inside and outside the PH10, which was searching for new uses and application methods as described above, is compatible with its inherently safe and stable characteristics. As a result of diluting the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution inside or outside the PH10 with strong alkaline natural water inside or outside the PH10, there is no or little PH movement, and therefore there is no or little acidification. In addition, there is no or almost no generation of chlorine gas and chlorine odor, and there is no or almost no generation of chlorine gas and chlorine odor, so it is safe and easy with a very ordinary factory and extremely simple equipment. In addition, it is possible to safely dilute from a low concentration (eg, 10 to 100 PPM or more) to a high concentration (eg, 3000 PPM) with the same equipment. This time, a method of diluting a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution with strongly alkaline natural water, and a chlorine dioxide aqueous solution or a stabilized chlorine dioxide diluted by this method were demonstrated. The solution has been developed and invented, thereby solving the conventional problems.
本発明の請求項１に記載の発明は、ＰＨ１０内外の強アルカリ性である二酸化塩素水溶液若しくは安定化二酸化塩素液を、ＰＨ１０内外の強アルカリ性である強アルカリ性天然水によって希釈することにより、ＰＨ移動を無くし若しくは僅少にして、ＰＨ移動に伴う酸性化による塩素臭の発生を無くし若しくは僅少にしたことを特徴とする、二酸化塩素水溶液若しくは安定化二酸化塩素液を強アルカリ性天然水で希釈する方法によって課題を解決したものである。According to the first aspect of the present invention, the aqueous solution of chlorine dioxide or the stabilized chlorine dioxide solution inside or outside the PH10 is diluted with strong alkaline natural water which is inside or outside the PH10, to thereby move PH. The problem is solved by a method of diluting a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution with strongly alkaline natural water, characterized by eliminating or reducing the generation of chlorine odor due to acidification accompanying PH movement or eliminating it to a minimum. It has been solved.
請求項２に記載の発明は、ＰＨ１０内外の強アルカリ性である二酸化塩素水溶液若しくは安定化二酸化塩素液を、ＰＨ１０内外の強アルカリ性である強アルカリ性天然水によって希釈して設けた、二酸化塩素水溶液若しくは安定化二酸化塩素液によって課題を解決したものである。According to the second aspect of the present invention, a chlorine dioxide aqueous solution or a stable chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution inside or outside PH10 is provided by diluting with a strong alkaline natural water which is a strong alkali inside or outside PH10. This is a solution to the problem with chlorine dioxide solution.
請求項３に記載の発明は、前記二酸化塩素若しくは安定化二酸化塩素の設定濃度（ＰＰＭ）液を、前記強アルカリ性天然水によって設定濃度（ＰＰＭ）に希釈するようにしたことを特徴とする、請求項１の二酸化塩素水溶液若しくは安定化二酸化塩素液を強アルカリ性天然水で希釈する方法によって課題を解決したものである。The invention described in claim 3 is characterized in that the set concentration (PPM) solution of chlorine dioxide or stabilized chlorine dioxide is diluted to the set concentration (PPM) with the strong alkaline natural water. The problem is solved by the method of diluting the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution according to Item 1 with strongly alkaline natural water.
請求項４に記載の発明は、前記二酸化塩素若しくは安定化二酸化塩素の設定濃度（ＰＰＭ）液を、前記強アルカリ性天然水によって設定濃度（ＰＰＭ）に希釈して設けた、請求項２の二酸化塩素水溶液若しくは安定化二酸化塩素液によって課題を解決したものである。The invention according to claim 4 is the chlorine dioxide according to claim 2, wherein the set concentration (PPM) liquid of the chlorine dioxide or stabilized chlorine dioxide is diluted to the set concentration (PPM) with the strong alkaline natural water. The problem is solved with an aqueous solution or a stabilized chlorine dioxide solution.
請求項５に記載の発明は、３０００ＰＰＭ以上の濃度の前記二酸化塩素水溶液若しくは安定化二酸化塩素液を、前記強アルカリ性天然水によって、３０００ＰＰＭ以下の濃度の二酸化塩素水溶液若しくは安定化二酸化塩素液に希釈するようにしたことを特徴とする、請求項１の二酸化塩素水溶液若しくは安定化二酸化塩素液を強アルカリ性天然水で希釈する方法によって課題を解決したものである。According to a fifth aspect of the present invention, the chlorine dioxide aqueous solution or stabilized chlorine dioxide solution having a concentration of 3000 PPM or more is diluted with the strong alkaline natural water into a chlorine dioxide aqueous solution or stabilized chlorine dioxide solution having a concentration of 3000 PPM or less. The problem is solved by a method of diluting a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution according to claim 1 with strongly alkaline natural water.
請求項６に記載の発明は、３０００ＰＰＭ以上の濃度の前記二酸化塩素水溶液若しくは安定化二酸化塩素液を、前記強アルカリ性天然水によって、３０００ＰＰＭ以下の濃度の二酸化塩素水溶液若しくは安定化二酸化塩素液に希釈して設けた、請求項２の二酸化塩素水溶液若しくは安定化二酸化塩素液によって課題を解決したものである。According to a sixth aspect of the present invention, the chlorine dioxide aqueous solution or stabilized chlorine dioxide solution having a concentration of 3000 PPM or more is diluted with the strong alkaline natural water to a chlorine dioxide aqueous solution or stabilized chlorine dioxide solution having a concentration of 3000 PPM or less. The problem is solved by the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution according to claim 2.
請求項７に記載の発明は、ホホバオイル、エタノール、シリコーン、グリセリン、木竹酢、キサンタンガム、炭酸カルシウム、香料の１以上と、ＰＨ１０内外の強アルカリ性である強アルカリ性天然水と、ＰＨ１０内外の強アルカリ性である二酸化塩素水溶液若しくは安定化二酸化塩素液とを混合して、二酸化塩素水溶液若しくは安定化二酸化塩素液の混合物を設けるようにしたことを特徴とする、請求項１の二酸化塩素水溶液若しくは安定化二酸化塩素液の混合物の製造法によって課題を解決したものである。The invention according to claim 7 includes at least one of jojoba oil, ethanol, silicone, glycerin, wood bamboo vinegar, xanthan gum, calcium carbonate, and fragrance, strong alkaline natural water that is strongly alkaline inside and outside PH10, and strong inside and outside PH10. The aqueous chlorine dioxide solution or stabilization according to claim 1, wherein the aqueous solution is mixed with an aqueous chlorine dioxide solution or stabilized chlorine dioxide solution that is alkaline to provide a mixture of aqueous chlorine dioxide solution or stabilized chlorine dioxide solution. The problem is solved by a method for producing a mixture of chlorine dioxide solution.
請求項８に記載の発明は、ホホバオイル、エタノール、シリコーン、グリセリン、木竹酢、キサンタンガム、炭酸カルシウム、香料の１以上と、ＰＨ１０内外の強アルカリ性である強アルカリ性天然水と、ＰＨ１０内外の強アルカリ性である二酸化塩素水溶液若しくは安定化二酸化塩素液とを混合して設けた、請求項２の二酸化塩素水溶液若しくは安定化二酸化塩素液の混合物によって課題を解決したものである。The invention according to claim 8 includes at least one of jojoba oil, ethanol, silicone, glycerin, wood bamboo vinegar, xanthan gum, calcium carbonate, and fragrance, strong alkaline natural water that is highly alkaline inside and outside PH10, and strong inside and outside PH10. The problem is solved by a mixture of an aqueous chlorine dioxide solution or a stabilized chlorine dioxide solution which is alkaline and a mixture of the aqueous chlorine dioxide solution or the stabilized chlorine dioxide solution according to claim 2.
従来、二酸化塩素水溶液若しくは安定化二酸化塩素液（ＰＨ１０内外）を、水（ＰＨ７）で希釈して設定濃度（ＰＰＭ）の二酸化塩素水溶液若しくは安定化二酸化塩素液を製造する場合、ＰＨ１０からＰＨ７へ酸性化が進行する過程で塩素ガスが発生し強烈な塩素臭を発することが大きな課題であったが、その点、本発明は、安定化二酸化塩素のＰＨ１０内外を、同じＰＨ１０内外の強アルカリ性天然水で希釈することによって、ＰＨ移動が無く若しくは殆ど無く、よって、酸性化が無く若しくは殆ど無く、従って、塩素ガス発生・強烈な塩素臭発生が無く若しくは殆ど無しで、設定濃度（ＰＰＭ）に希釈した二酸化塩素水溶液若しくは安定化二酸化塩素液を、極めて安全かつ簡単に製造することを可能とした革新的な効果がある。Conventionally, when a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution (within and outside PH10) is diluted with water (PH7) to produce a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution having a set concentration (PPM), it is acidic from PH10 to PH7. Although the generation of chlorine gas and the generation of a strong chlorine odor in the process of conversion, a major problem has been encountered. In that regard, the present invention is based on the fact that the stabilized chlorine dioxide has a highly alkaline natural water inside and outside the same PH10. Diluting to a set concentration (PPM) with little or no PH movement, and thus little or no acidification, and thus little or no generation of chlorine gas or intense chlorine odor. There is an innovative effect that makes it possible to produce a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution extremely safely and easily.
前記のように、二酸化塩素水溶液若しくは安定化二酸化塩素液の希釈工程で、塩素ガス発生・強烈な塩素臭発生を無く若しくは殆ど無くし得たので、従来のように、大掛かりな特殊化学工場や適応可能な特殊設備などの条件無しに、また、周辺環境に影響して嫌われること無しに、攪拌混合用の設備装置を備えただけで、小規模工場、町工場、個人実験室等の何所でも、大気中において、安全に周辺の環境に全く影響無しに、二酸化塩素水溶液若しくは安定化二酸化塩素液の希釈液を極めて安全・簡単・低コストに製造すること出来る優れた特徴がある。As mentioned above, it is possible to eliminate or hardly generate chlorine gas and intense chlorine odor in the dilution process of aqueous chlorine dioxide solution or stabilized chlorine dioxide solution, so that it can be applied to large special chemical factories as before. There are no special equipment or other conditions, and there is no dislike from the influence of the surrounding environment. In the atmosphere, there is an excellent feature capable of producing a dilute solution of a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution in an extremely safe, simple and low cost, safely and without any influence on the surrounding environment.
本発明は、例えば、市販の６００００ＰＰＭ内外の二酸化塩素水溶液若しくは安定化二酸化塩素液を希釈して、１０〜１００ＰＰＭ、１００〜５００ＰＰＭ、５００〜１０００ＰＰＭ、１０００〜１５００ＰＰＭ、２０００〜３０００ＰＰＭ等の二酸化塩素水溶液若しくは安定化二酸化塩素液を、設定濃度自在に安全・簡単・低コストで自在に製造可能である。
よって、従来の一般的な低濃度のものはもとより、従来は長期間の殺菌・腐敗防止・強力な防臭等のためには１５００ＰＰＭ以上の濃度が望ましいとされながら、前記塩素ガス発生・強烈な塩素臭発生の理由で簡単・低コストの製造が困難とされていた課題を、本発明は１５００ＰＰＭ以上〜２０００ＰＰＭ以上〜３０００ＰＰＭ位の二酸化塩素水溶液若しくは安定化二酸化塩素液の製造を実施して、全く容易に解決し得た。In the present invention, for example, a commercially available chlorine dioxide aqueous solution inside or outside of 60000 PPM or a stabilized chlorine dioxide solution is diluted to obtain a chlorine dioxide aqueous solution such as 10 to 100 PPM, 100 to 500 PPM, 500 to 1000 PPM, 1000 to 1500 PPM, 2000 to 3000 PPM, or the like. Stabilized chlorine dioxide solution can be freely manufactured at a set concentration freely, safely, easily and at low cost.
Therefore, in addition to the conventional general low concentration, the concentration of 1500 PPM or higher is desirable for long-term sterilization, anti-corruption, strong deodorization, etc. In the present invention, it is quite easy to manufacture a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution having a position of 1500 PPM or more to 2000 PPM or more to 3000 PPM, which is difficult to manufacture at a low cost due to odor generation. Could be solved.
本発明二酸化塩素水溶液若しくは安定化二酸化塩素液は、製造後もＰＨ１０内外で安定してＰＨ移動が生じないため、塩素ガス・塩素臭発生も殆ど無く、よって、長期間変化なくその作用・効果を保持し、また、使用時、使用後も塩素臭が殆どしない優れた特徴がある。The chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution of the present invention does not cause a stable PH movement in and out of the PH10 even after production. In addition, it has an excellent feature that there is almost no chlorine odor during and after use.
本発明は、本発明で設定濃度に希釈した二酸化塩素水溶液若しくは安定化二酸化塩素液に、ホホバオイル、シリコーン、エタノール、グリセリン、木竹酢、キサンタンガム、炭酸カルシウム、香料、その他の物質の１以上を混合して、二酸化塩素水溶液若しくは安定化二酸化塩素液との混合物を製造することを特徴としているが、二酸化塩素水溶液若しくは安定化二酸化塩素液及び強アルカリ性天然水は前記のようにＰＨ１０内外で全く安定しているため、その希釈液は全く安定した特性を有し、更に、希釈液と前記物質との混合物も安定した特性を有することが実証されており、よって、本発明で製造した製品は、長期間の保管・運搬、使用時、使用後も安定して塩素ガス発生・塩素臭発生が殆ど無い優れた特徴がある。In the present invention, one or more of jojoba oil, silicone, ethanol, glycerin, wood bamboo vinegar, xanthan gum, calcium carbonate, fragrance, and other substances are added to the chlorine dioxide aqueous solution or stabilized chlorine dioxide solution diluted to the set concentration in the present invention. It is characterized by mixing to produce a mixture with an aqueous chlorine dioxide solution or a stabilized chlorine dioxide solution, but the aqueous chlorine dioxide solution or stabilized chlorine dioxide solution and strong alkaline natural water are completely stable inside and outside the PH10 as described above. Therefore, the diluted solution has completely stable characteristics, and furthermore, it has been demonstrated that the mixture of the diluted solution and the substance also has stable characteristics. It has excellent characteristics such as stable generation of chlorine gas and chlorine odor during long-term storage, transportation, use and after use.
本願出願人発明者の先願発明方法によって強アルカリ性天然水に設定比率のホホバオイルを加えて攪拌混合すると、両者が乳化して極めて安定したエマルションを生成できるが、このエマルションにシリコーン、エタノール、グリセリン、木竹酢、キサンタンガム、炭酸カルシウム、香料、その他の物質（主として添加剤）の少なくても１を加え、また、本発明二酸化塩素水溶液若しくは安定化二酸化塩素液を加えて攪拌混合した場合も、乳化状態が維持されて極めて安定したエマルションを生成することができ、このエマルションは長期間分離しない優れた特徴がある。When jojoba oil at a set ratio is added to strong alkaline natural water by the method of the present applicant's prior invention and stirred and mixed, both can be emulsified to form an extremely stable emulsion. Silicone, ethanol, glycerin can be produced in this emulsion. , Wood bamboo vinegar, xanthan gum, calcium carbonate, fragrance, other substances (mainly additives) at least 1 is added, and when the chlorine dioxide solution of the present invention or stabilized chlorine dioxide solution is added and mixed with stirring, An emulsified state is maintained and an extremely stable emulsion can be produced, and this emulsion has an excellent feature that it does not separate for a long time.
本発明は、前記のような優れた特性を有する二酸化塩素水溶液若しくは安定化二酸化塩素液と、前記のような優れた特性を有する強アルカリ性天然水とから成るものであるため、両方の特性を併せ持った製品を、簡単に製造、提供できる点で極めて画期的である。The present invention comprises a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution having the above-mentioned excellent characteristics and strong alkaline natural water having the above-mentioned excellent characteristics, and thus has both characteristics. The product is extremely innovative in that it can be easily manufactured and provided.
更に、本発明のようなＰＨ１０内外の強アルカリ性が安定したままの二酸化塩素水溶液若しくは安定化二酸化塩素液は、従来、全く存在していなかったので、その点で、本発明二酸化塩素水溶液若しくは安定化二酸化塩素液、及び、該液と他物質の混合物は全く新規なものであり、よって、本願の出願人・発明者等も気付かない特性が数多く隠れていると思われ、今後もその新たな作用・効果・用途等の発見・展開を期待し得るものである。Furthermore, since the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution in which the strong alkalinity inside and outside the PH10 is stable as in the present invention has not existed at all, the chlorine dioxide aqueous solution or the stabilized Chlorine dioxide liquid and the mixture of the liquid and other substances are completely new. Therefore, it seems that many characteristics that the applicant / inventor of the present application do not notice are hidden, and the new action will continue in the future.・ We can expect discovery, development of effect, use.
例えば、市販されている６００００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化塩素液を希釈して、５００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化
前記の製造過程で、攪拌混合槽から塩素ガス、塩素臭が殆ど発生しないので、安全上、周辺環境衛生上等では大気中にオープンでも可であるが、通常は、最初の二酸化塩素水溶液（６００００ＰＰＭ）若しくは安定化二酸化塩素液（６００００ＰＰＭ）の塩素臭（製造過程で無くなる）及び、回転攪拌で泡が発生するのを防止するため、密閉真空式の回転攪拌混合槽を使用する。In the above production process, almost no chlorine gas or chlorine odor is generated from the stirring and mixing tank, so that it can be opened in the atmosphere for safety and surrounding environmental sanitation, but usually the first aqueous chlorine dioxide solution (60000 PPM). ) Or the chlorine odor of the stabilized chlorine dioxide liquid (60000 PPM) (which disappears in the manufacturing process) and the use of a closed vacuum type rotary stirring and mixing tank in order to prevent bubbles from being generated by rotary stirring.
低濃度（ＰＰＭ）の二酸化塩素水溶液若しくは安定化二酸化塩素液を製造する場合は、前記６００００ＰＰＭ等の高濃度二酸化塩素水溶液若しくは安定化二酸化塩素液を希釈するよりは、既に低濃度に希釈済みの二酸化塩素水溶液若しくは安定化二酸化塩素液等を使用して希釈した方が作業がし易く、また、少量製造に適する。When producing a low concentration (PPM) chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution, rather than diluting the above-mentioned high concentration chlorine dioxide aqueous solution or stabilized chlorine dioxide solution such as 60000PPM, the diluted dioxide dioxide has already been diluted to a low concentration. Dilution with a chlorine aqueous solution or a stabilized chlorine dioxide solution is easier to work and is suitable for small-scale production.
また、二酸化塩素水溶液若しくは安定化二酸化塩素液とシリコーン、エタノール、グリセリン、木竹酢、キサンタンガム、炭酸カルシウム、香料、その他の物質との混合物を製造する場合は、目的に応じた設定濃度（ＰＰＭ）に希釈済みの二酸化塩素水溶液若しくは安定化二酸化塩素液と攪拌混合して製造するが、その場合、設定量の強アルカリ性天然水に、前記二酸化塩素水溶液若しくは安定化二酸化塩素液を加えるタイミングを、少なくもシリコーンを入れて均等になるまで回転攪拌混合した後にすることが望ましい。Moreover, when manufacturing a mixture of chlorine dioxide aqueous solution or stabilized chlorine dioxide solution and silicone, ethanol, glycerin, bamboo vinegar, xanthan gum, calcium carbonate, fragrance, and other substances, set concentration (PPM) according to the purpose. In this case, the timing of adding the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution to the set amount of strong alkaline natural water is reduced. It is also desirable to add silicone after rotating and mixing until uniform.
なお、ホホバオイルを使用した場合、予め強アルカリ性天然水とホホバオイルを回転攪拌混合し乳化して両者のエマルションを生成し、該エマルションにその他の物質を回転攪拌混合すれば、それら全部のエマルション（サラサラした液状若しくはクリーム状・・化粧水、化粧ローション）を生成することが出来る。When jojoba oil is used, strong alkaline natural water and jojoba oil are preliminarily stirred and mixed to form an emulsion of both. If other substances are mixed with the emulsion by rotary stirring, all the emulsions ( Smooth liquid or cream-like (skin lotion, lotion) can be produced.
現在、二酸化塩素水溶液（ＣｌＯ２）若しくは安定化二酸化塩素液（ＮａＣｌＯ２）は、２５〜３０万ＰＰＭ位の高濃度のものが原液として製造されているが、本発明では、目的用途等からして１０〜３０００ＰＰＭ位の範囲で足りるので、近時、安全で取り扱い容易なものとして市販されている６００００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化塩素液を使用した。At present, a chlorine dioxide aqueous solution (ClO 2 ) or a stabilized chlorine dioxide solution (NaClO 2 ) is manufactured as a stock solution having a high concentration of about 25 to 300,000 PPM. Therefore, a 60000PPM chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution, which has recently been marketed as being safe and easy to handle, was used.
本発明を実施した結果、二酸化塩素水溶液（６００００ＰＰＭ）若しくは安定化二酸化塩素液（６００００ＰＰＭ）を希釈して、１０〜１００ＰＰＭ、１００〜５００ＰＰＭ、５００〜１０００ＰＰＭ、１０００〜１５００ＰＰＭ、２０００〜３０００ＰＰＭ等の二酸化塩素水溶液若しくは安定化二酸化塩素液を、設定濃度自在に安全・簡単・低コストで自在に製造することができた。As a result of carrying out the present invention, chlorine dioxide solution such as 10 to 100 PPM, 100 to 500 PPM, 500 to 1000 PPM, 1000 to 1500 PPM, 2000 to 3000 PPM is diluted by diluting a chlorine dioxide aqueous solution (60000 PPM) or a stabilized chlorine dioxide solution (60000 PPM). An aqueous solution or a stabilized chlorine dioxide solution could be freely produced at a set concentration freely at a safe, simple and low cost.
本発明を密閉真空式の回転攪拌混合槽の設備装置を備えた所謂町工場において実施した。
例えば、２０００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化塩素液を製造
For example, manufacture 2000PPM chlorine dioxide solution or stabilized chlorine dioxide solution
本発明では、攪拌混合槽から塩素ガス、塩素臭が殆ど発生しないので、安全上、周辺環境衛生上等では大気中にオープンでも可であるが、前記の製造では、最初の二酸化塩素水溶液（６００００ＰＰＭ）若しくは安定化二酸化塩素液（６００００ＰＰＭ）の塩素臭（製造過程で無くなる）、及び、回転攪拌で泡が発生するのを防止するため、密閉真空式の回転攪拌混合槽を使用した。
前記実施例と同様の工程で、二酸化塩素水溶液（６００００ＰＰＭ）若しくは安定化二酸化塩素液（６００００ＰＰＭ）を、５〜３０００ＰＰＭ内外までの希釈を全く自在かつ安全に実施することができた。
また、前記の製造過程中に、塩素ガス発生・塩素臭発生は無く若しくは殆ど無く、また、希釈済みの製品からも長期間保管して塩素ガス発生・塩素臭発生は無く若しくは殆ど無いことを実証し得た。In the present invention, since almost no chlorine gas or chlorine odor is generated from the stirring and mixing tank, it can be opened in the atmosphere for safety and environmental hygiene purposes. However, in the above production, the first chlorine dioxide aqueous solution (60000 PPM) is used. ) Or the chlorine odor of the stabilized chlorine dioxide liquid (60000 PPM) (which disappears in the manufacturing process) and the generation of bubbles by rotary stirring was used in a sealed vacuum type rotary stirring and mixing tank.
In the same process as in the previous example, the aqueous chlorine dioxide solution (60000 PPM) or the stabilized chlorine dioxide solution (60000 PPM) could be diluted freely from 5 to 3000 PPM and safely.
In addition, there is no or little chlorine gas generation / chlorine odor generation during the manufacturing process described above, and it has been demonstrated that the product can be stored for a long time from diluted products with little or no generation of chlorine gas / chlorine odor. It was possible.
本発明を実施して、シリコーン、エタノール、グリセリン、木竹酢、キサンタンガム、炭酸カルシウム、香料、その他の物質（主として添加物）と、強アルカリ性天然水と、二酸化塩素水溶液若しくは安定化二酸化塩素液との混合物を製造した。
この場合の二酸化塩素水溶液若しくは安定化二酸化塩素液の設定濃度（ＰＰＭ）は目的用途等に応じて任意であるが、前記実施例１と同じく二酸化塩素水溶液若しくは安定化二酸化塩素液（２０００ＰＰＭ）との混合物を製造した。By carrying out the present invention, silicone, ethanol, glycerin, wood bamboo vinegar, xanthan gum, calcium carbonate, fragrance, other substances (mainly additives), strong alkaline natural water, chlorine dioxide aqueous solution or stabilized chlorine dioxide solution, A mixture of was prepared.
In this case, the set concentration (PPM) of the aqueous chlorine dioxide solution or the stabilized chlorine dioxide solution is arbitrary depending on the intended use and the like, but in the same manner as in Example 1, the chlorine dioxide aqueous solution or the stabilized chlorine dioxide solution (2000 PPM) A mixture was prepared.
前記工程において、強アルカリ性天然水に二酸化塩素水溶液若しくは安定化二酸化塩素液を入れて希釈する工程をどの段階で行うかについて、試行した結果、シリコーン、エタノール、グリセリン（いずれも水溶性）を先にいれて、強アルカリ性天然水との水溶液にした後に、二酸化塩素水溶液若しくは安定化二酸化塩素液を徐々に入れるようにした方が安定した混合成果が得られ、製造後も長期間分離しない良好な混合物が得られた。In the above-mentioned process, as a result of an attempt at which stage to dilute a strong alkaline natural water with a chlorine dioxide aqueous solution or a stabilized chlorine dioxide solution, silicone, ethanol, glycerin (all of which are water-soluble) In order to obtain stable mixing results, it is better to gradually add an aqueous chlorine dioxide solution or a stabilized chlorine dioxide solution after making it into an aqueous solution with strong alkaline natural water, and a good mixture that does not separate for a long time after production. was gotten.
なお、前記実施例の製品は、ＰＨ１０内外・２０００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化塩素液の混合物という、従来の常識では到底考え及ばないものでありながら、美容用の化粧品（ローション・・主として肌用の基礎化粧品）を製造したものである。The product of the above-mentioned example is a mixture of PH10 inside / outside / 2000PPM chlorine dioxide aqueous solution or a mixture of stabilized chlorine dioxide solution, which cannot be considered by conventional common sense, but is a cosmetic for cosmetics (lotion, mainly skin). Basic cosmetics).
攪拌混合する物質の１つとしてホホバオイルを使用した。
該ホホバオイルは油脂であるため、通常は水と分離して混合出来ないが、本出願人・発明者が先に特許出願した発明方法によって、強アルカリ性天然水と攪拌混合すると容易に分離しない状態に乳化してサラサラした触感で白濁液状の強アルカリ性天然水・ホホバオイルのエマルションを生成した。
（本出願人・発明者による特許出願、整理番号Ｐ２１０６−０１、出願日平成２１年６月２５日、出願番号未通知）。Jojoba oil was used as one of the materials to be stirred and mixed.
Since the jojoba oil is a fat and oil, it cannot normally be separated from water and mixed, but when it is stirred and mixed with strong alkaline natural water by the invention method previously filed by the present applicant / inventor, the jojoba oil is not easily separated. An emulsion of strong alkaline natural water and jojoba oil in the form of a cloudy liquid was produced with a smooth feel after emulsification.
(Patent application by applicant / inventor, serial number P2106-01, application date June 25, 2009, application number not yet notified).
よって、まず、回転攪拌混合槽に強アルカリ性天然水を入れ、回転攪拌混合しながらその中にホホバオイルを設定比率加え、更に回転攪拌混合し十分に乳化して、両者のエマルションを設けた。
次いで、回転攪拌混合しながら前記エマルションにシリコーン、エタノール、グリセリンを入れ、次いで、二酸化塩素水溶液（２０００ＰＰＭ）若しくは安定化二酸化塩素液（２０００ＰＰＭ）を少しずつ加えながら回転攪拌混合し、次いで、木竹酢、キサンタンガム（増粘剤）、炭酸カルシウム、香料、その他の物質を入れて回転攪拌混合し、均等に混合するまで設定時間回転攪拌混合して、二酸化塩素水溶液（２０００ＰＰＭ）若しくは安定化二酸化塩素液（２０００ＰＰＭ）と前記物質との混合物を製造した。Therefore, first, strong alkaline natural water was put into a rotary stirring and mixing tank, jojoba oil was added to the mixture while rotating and mixing, and further mixed by rotary stirring and sufficiently emulsified to provide both emulsions.
Next, silicone, ethanol, and glycerin are added to the emulsion while rotating and mixing, and then rotating and mixing while adding chlorine dioxide aqueous solution (2000PPM) or stabilized chlorine dioxide solution (2000PPM) little by little. , Xanthan gum (thickening agent), calcium carbonate, fragrance, and other substances are mixed in a rotating stirrer and mixed with agitation for a set time until evenly mixed, a chlorine dioxide aqueous solution (2000PPM) or a stabilized chlorine dioxide liquid ( 2000PPM) and a mixture of the above substances were prepared.
なお、前記実施例の製品は、ＰＨ１０内外・２０００ＰＰＭの二酸化塩素水溶液若しくは安定化二酸化塩素液の混合物という、従来の常識では到底考え及ばないものでありながら、それら全部のエマルション（サラサラした液状若しくはクリーム状）であり、特に、ホホバオイルの美容用特性が付加された化粧品（ローション、クリーム・・主として肌用の基礎化粧品）を製造し得たものである。In addition, the product of the above-mentioned examples is a mixture of PH10 inside / outside / 2000PPM chlorine dioxide aqueous solution or stabilized chlorine dioxide solution, which is completely unthinkable by conventional common sense, but all these emulsions (smooth liquid or cream) In particular, it has been possible to produce cosmetics to which the cosmetic properties of jojoba oil have been added (lotions, creams, primarily skin cosmetics).
本発明は、前記のような優れた特性を有する二酸化塩素水溶液若しくは安定化二酸化塩素液と、前記のような優れた特性を有する強アルカリ性天然水とから成るものであるため、両方の特性を併せ持った製品を、簡単に製造、提供できる点において、更に、本発明のようなＰＨ１０内外の強アルカリ性が安定したままの二酸化塩素水溶液若しくは安定化二酸化塩素液は、従来、全く存在していなかったので、本発明二酸化塩素水溶液若しくは安定化二酸化塩素液、及び、該液と他物質の混合物は全く新規なものである点において、本願の出願人・発明者等も気付かない特性が数多く隠れていると思われ、今後もその新たな作用・効果・用途等の発見・展開を大いに期待し得るものである。The present invention is composed of a chlorine dioxide aqueous solution or stabilized chlorine dioxide solution having the above-mentioned excellent characteristics and strong alkaline natural water having the above-mentioned excellent characteristics, and therefore has both characteristics. In addition, there has been no conventional chlorine dioxide aqueous solution or stabilized chlorine dioxide solution in which strong alkalinity inside and outside the PH10 as in the present invention remains stable in that the product can be easily produced and provided. In the point that the chlorine dioxide aqueous solution or the stabilized chlorine dioxide liquid of the present invention and the mixture of the liquid and other substances are completely novel, there are many hidden characteristics that the applicant / inventor of the present application does not notice. It seems that the discovery and development of new actions, effects, and uses can be greatly expected in the future.
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Citations (5)
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|---|---|---|---|---|
| JPS60161307A (en) * | 1984-01-27 | 1985-08-23 | Japan Carlit Co Ltd:The | Composition for generating gaseous chlorine dioxide |
| JPH06228469A (en) * | 1993-02-02 | 1994-08-16 | Honny Chem Ind Co Ltd | Antibacterial antifungal surface-treating agent composition |
| JP2004161641A (en) * | 2002-11-12 | 2004-06-10 | Nonogawa Shoji Kk | Cosmetic |
| JP2004187575A (en) * | 2002-12-11 | 2004-07-08 | Pure Kosen Kk | Seasoning and method for producing the same |
| JP2011026318A (en) * | 2009-06-25 | 2011-02-10 | Soku:Kk | Method for producing strongly alkaline natural water-jojoba oil emulsion and strongly alkaline natural water-jojoba oil emulsion prepared by the method |
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2009
- 2009-07-15 JP JP2009183858A patent/JP2011020986A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60161307A (en) * | 1984-01-27 | 1985-08-23 | Japan Carlit Co Ltd:The | Composition for generating gaseous chlorine dioxide |
| JPH06228469A (en) * | 1993-02-02 | 1994-08-16 | Honny Chem Ind Co Ltd | Antibacterial antifungal surface-treating agent composition |
| JP2004161641A (en) * | 2002-11-12 | 2004-06-10 | Nonogawa Shoji Kk | Cosmetic |
| JP2004187575A (en) * | 2002-12-11 | 2004-07-08 | Pure Kosen Kk | Seasoning and method for producing the same |
| JP2011026318A (en) * | 2009-06-25 | 2011-02-10 | Soku:Kk | Method for producing strongly alkaline natural water-jojoba oil emulsion and strongly alkaline natural water-jojoba oil emulsion prepared by the method |
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