JP2010254685A5 - - Google Patents

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JP2010254685A5
JP2010254685A5 JP2010084284A JP2010084284A JP2010254685A5 JP 2010254685 A5 JP2010254685 A5 JP 2010254685A5 JP 2010084284 A JP2010084284 A JP 2010084284A JP 2010084284 A JP2010084284 A JP 2010084284A JP 2010254685 A5 JP2010254685 A5 JP 2010254685A5
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acrylate
unsaturated
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alkoxyalkyl
unsaturated alkoxyalkyl
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下記一般式（Ｉ）：
Figure 2010254685
 （式中、Ｒ１は、水素原子又は炭素数１〜３０の有機基を表す。Ｒ２、Ｒ３及びＲ４は、同一若しくは異なって、水素原子又は炭素数１〜３０の有機基を表す。）で表されるα−（不飽和アルコキシアルキル）アクリレートとともに、酸化防止剤を含有する組成物であって、
該酸化防止剤は、フェノール系酸化防止剤及び／又はリン系酸化防止剤を含み、
該酸化防止剤の含有量は、該α−（不飽和アルコキシアルキル）アクリレート１００質量％に対して０．０３〜０．５質量％であることを特徴とするα−（不飽和アルコキシアルキル）アクリレート組成物。 The following general formula (I):
Figure 2010254685
 (In the formula, R 1 represents a hydrogen atom or an organic group having 1 to 30 carbon atoms. R 2 , R 3 and R 4 are the same or different and represent a hydrogen atom or an organic group having 1 to 30 carbon atoms. .) And an α- (unsaturated alkoxyalkyl) acrylate represented by an antioxidant,
The antioxidant includes a phenolic antioxidant and / or a phosphorus antioxidant,
The content of the antioxidant is 0.03 to 0.5% by mass with respect to 100% by mass of the α- (unsaturated alkoxyalkyl) acrylate, and the α- (unsaturated alkoxyalkyl) acrylate is characterized in that Composition. 前記α−（不飽和アルコキシアルキル）アクリレートは、α−（アリルオキシメチル）アクリレートを含むことを特徴とする請求項１に記載のα−（不飽和アルコキシアルキル）アクリレート組成物。 The α- (unsaturated alkoxyalkyl) acrylate composition according to claim 1, wherein the α- (unsaturated alkoxyalkyl) acrylate includes α- (allyloxymethyl) acrylate. 前記組成物は、不飽和アルキルエステル含有量が、前記α−（不飽和アルコキシアルキル）アクリレート１００質量％に対して１質量％以下であることを特徴とする請求項１又は２に記載のα−（不飽和アルコキシアルキル）アクリレート組成物。 The α- of claim 1 or 2 , wherein the composition has an unsaturated alkyl ester content of 1% by mass or less based on 100% by mass of the α- (unsaturated alkoxyalkyl) acrylate. (Unsaturated alkoxyalkyl) acrylate compositions. 前記組成物は、窒素含有量が、前記α−（不飽和アルコキシアルキル）アクリレート１００質量％に対して１００ｐｐｍ以下であることを特徴とする請求項１〜３のいずれかに記載のα−（不飽和アルコキシアルキル）アクリレート組成物。 The composition, the nitrogen content of the alpha-(unsaturated alkoxyalkyl) according to any one of claims 1 to 3, characterized in that at 100ppm or less with respect to acrylate 100 mass% alpha-(not Saturated alkoxyalkyl) acrylate composition. 前記組成物は、過酸化物量が、前記α−（不飽和アルコキシアルキル）アクリレート１００質量％に対して５０ｐｐｍ以下であることを特徴とする請求項１〜４のいずれかに記載のα−（不飽和アルコキシアルキル）アクリレート組成物。 The α- (unsaturated) according to any one of claims 1 to 4 , wherein the composition has a peroxide amount of 50 ppm or less with respect to 100% by mass of the α- (unsaturated alkoxyalkyl) acrylate. Saturated alkoxyalkyl) acrylate composition. 下記一般式（Ｉ）：
Figure 2010254685
 （式中、Ｒ１は、水素原子又は炭素数１〜３０の有機基を表す。Ｒ２、Ｒ３及びＲ４は、同一若しくは異なって、水素原子又は炭素数１〜３０の有機基を表す。）で表されるα−（不飽和アルコキシアルキル）アクリレートを含有する組成物を製造する方法であって、
該製造方法は、粗α−（不飽和アルコキシアルキル）アクリレートから精製α−（不飽和アルコキシアルキル）アクリレートを得る精製工程後に、精製α−（不飽和アルコキシアルキル）アクリレートに酸化防止剤を添加する工程を含むことを特徴とするα−（不飽和アルコキシアルキル）アクリレート組成物の製造方法。 The following general formula (I):
Figure 2010254685
 (In the formula, R 1 represents a hydrogen atom or an organic group having 1 to 30 carbon atoms. R 2 , R 3 and R 4 are the same or different and represent a hydrogen atom or an organic group having 1 to 30 carbon atoms. A composition comprising an α- (unsaturated alkoxyalkyl) acrylate represented by:
The production method comprises a step of adding an antioxidant to the purified α- (unsaturated alkoxyalkyl) acrylate after the purification step of obtaining the purified α- (unsaturated alkoxyalkyl) acrylate from the crude α- (unsaturated alkoxyalkyl) acrylate. A process for producing an α- (unsaturated alkoxyalkyl) acrylate composition. 前記製造方法は、α−（ヒドロキシメチル）アクリレートと、下記一般式（ＩＩＩ）：
Figure 2010254685
 （式中、Ｒ２、Ｒ３及びＲ４は、前記一般式（Ｉ）における各記号と同様である。）で表される不飽和アルコールとを反応させる工程を含むことを特徴とする請求項６に記載のα−（不飽和アルコキシアルキル）アクリレート組成物の製造方法。 The production method includes α- (hydroxymethyl) acrylate and the following general formula (III):
Figure 2010254685
 (Wherein R 2 , R 3 and R 4 are the same as the symbols in the general formula (I)), and a step of reacting with an unsaturated alcohol represented by the formula (I). 6. A method for producing an α- (unsaturated alkoxyalkyl) acrylate composition according to 6 . 前記不飽和アルコールは、アリルアルコールを含むことを特徴とする請求項７に記載のα−（不飽和アルコキシアルキル）アクリレート組成物の製造方法。 The said unsaturated alcohol contains allyl alcohol, The manufacturing method of the alpha- (unsaturated alkoxyalkyl) acrylate composition of Claim 7 characterized by the above-mentioned. 前記製造方法は、アミン系触媒の存在下で反応させる工程を含むことを特徴とする請求項６〜８のいずれかに記載のα−（不飽和アルコキシアルキル）アクリレート組成物の製造方法。 The said manufacturing method includes the process made to react in presence of an amine catalyst, The manufacturing method of the alpha- (unsaturated alkoxyalkyl) acrylate composition in any one of Claims 6-8 characterized by the above-mentioned. 前記製造方法により得られる組成物は、不飽和アルキルエステル含有量が、前記α−（不飽和アルコキシアルキル）アクリレート１００質量％に対して１質量％以下であることを特徴とする請求項６〜９のいずれかに記載のα−（不飽和アルコキシアルキル）アクリレート組成物の製造方法。 The composition obtained by the production method, an unsaturated alkyl ester content, claim 6-9, wherein the α- at 1 mass% or less with respect to the (unsaturated alkoxyalkyl) acrylate 100 mass% The manufacturing method of the alpha- (unsaturated alkoxyalkyl) acrylate composition in any one of. 前記酸化防止剤は、フェノール系酸化防止剤及び／又はリン系酸化防止剤を含むことを特徴とする請求項６〜１０のいずれかに記載のα−（不飽和アルコキシアルキル）アクリレート組成物の製造方法。The said antioxidant contains a phenolic antioxidant and / or phosphorus antioxidant, The manufacture of the alpha- (unsaturated alkoxyalkyl) acrylate composition in any one of Claims 6-10 characterized by the above-mentioned. Method. 請求項１〜５のいずれかに記載のα−（不飽和アルコキシアルキル）アクリレート組成物を含む重合原料を環化重合して得られることを特徴とする環構造含有重合体。A ring structure-containing polymer obtained by cyclopolymerizing a polymerization raw material containing the α- (unsaturated alkoxyalkyl) acrylate composition according to claim 1.
JP2010084284A 2009-03-31 2010-03-31 α- (Unsaturated alkoxyalkyl) acrylate composition and method for producing the same Active JP5520116B2 (en)

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JP5591543B2 (en) * 2010-01-04 2014-09-17 株式会社日本触媒 Reactive diluent
JP5583378B2 (en) * 2009-09-29 2014-09-03 株式会社日本触媒 Method for producing α- (alkoxyalkyl) acrylate
JP5496534B2 (en) * 2009-03-31 2014-05-21 株式会社日本触媒 Process for producing α- (unsaturated alkoxyalkyl) acrylate
JP5977063B2 (en) * 2012-04-05 2016-08-24 株式会社日本触媒 Polymerizable compound
JP6125933B2 (en) * 2012-07-13 2017-05-10 株式会社日本触媒 Stabilizer composition
JP2016160387A (en) * 2015-03-04 2016-09-05 株式会社クラレ Polymer composition

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DE4142913A1 (en) * 1991-12-24 1993-07-01 Basf Ag METHOD FOR PRODUCING OXADIMETHACRYLIC ACID
DE4142909A1 (en) * 1991-12-24 1993-07-01 Basf Ag OXADIMETHACRYLIC COMPOUNDS AND METHOD FOR THEIR PRODUCTION
JP3907738B2 (en) * 1995-03-24 2007-04-18 株式会社日本触媒 Method for producing allyl ethers
JP3943180B2 (en) * 1997-02-18 2007-07-11 株式会社日本触媒 Method for producing allyl ether compound
KR100281903B1 (en) * 1998-12-24 2001-03-02 윤종용 Photosensitive polymer having a cyclic structure of the backbone and a resist composition comprising the same
JP3953712B2 (en) * 1999-07-12 2007-08-08 三菱レイヨン株式会社 Resin resin and chemically amplified resist composition
JP2002131900A (en) * 2000-10-25 2002-05-09 Fuji Photo Film Co Ltd Original plate for forming mask
JP2004123819A (en) * 2002-09-30 2004-04-22 Nippon Shokubai Co Ltd Resin having leaving group by proton and photosensitive resin composition

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