JP2010241965A - Rubber composition and tire using the same - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a rubber composition for a tire complementing the problem that wet skid properties and control stability of the tire are reduced, when a high aromatic oil in which a polycyclic aromatic compound (PCA) component is controlled in <3 wt.% is used instead of a conventional high aromatic oil as a softening agent, and having excellent loss characteristics and rigidity, and to provide the tire using the rubber composition and having excellent dry road surface control stability and wet road surface braking properties. <P>SOLUTION: The composition is formed by compounding (A) 0.1 to 45 pts.mass resin containing an aromatic component having 30 to 80 mass% indene as a monomer ratio and (B) 1 to 150 pts.mass softening agent containing a polycyclic aromatic compound (PCA) having <3% dimethyl sulfoxide (DMSO) extraction amount by an IP 346 method per 100 pts.mass of at least one rubber component selected from diene polymers. The tire is also provided. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a tire rubber composition and a tire, and more specifically, a softener containing a polycyclic aromatic compound (PCA) component having a dimethyl sulfoxide (DMSO) extract amount of less than 3% by mass and a specific compound. And a tire using the same for a tread.

Conventionally, as a softener for rubber composition and a synthetic rubber extending oil, highly aromatic oils (aromatic oils) have been used from the viewpoint of imparting high loss characteristics (high hysteresis loss characteristics) and affinity with rubber. Have been used favorably in rubber compositions and other areas.
In recent years, DMSO extract, which is called “Treated Distilled Aromatic Extracts (TDAE)” or “Mild Extracted Solvates (MES)” obtained by processing highly aromatic oils produced from petroleum, is less than 3% by mass. Softeners are beginning to be used. (For example, see Patent Document 1)

However, the rubber composition using an alternative softener such as TDAE or MES has a lower softening point and viscosity of the softener itself than when a conventional highly aromatic oil is used. The temperature dependence of viscoelastic properties tends to shift to the low temperature side, and the glass transition temperature (Tg) and the storage elastic modulus (E ′) are lowered. Therefore, a rubber composition with a particularly large amount of softener is used as a tread. The high-performance tire used has a problem that the wet skid property and steering stability of the tire are lowered.
Therefore, in order to compensate for the decrease in steering stability, a conventional method for increasing the storage elastic modulus, for example, when increasing the amount of reinforcing filler such as carbon black or silica, or decreasing the amount of softening agent, The viscosity of unvulcanized rubber rises and the factory workability is greatly reduced.

Japanese Patent Application Laid-Open No. 11-302459

  Under such circumstances, the present invention uses a high aromatic oil containing less than 3% by weight of a polycyclic aromatic compound (PCA) component as a softening agent instead of the conventional high aromatic oil. Provided a tire rubber composition having excellent loss characteristics and rigidity that complements the problems, and a pneumatic tire excellent in dry road surface handling stability and wet road surface braking performance using the tire rubber composition having the characteristics It is intended to do.

As a result of intensive studies to achieve the above object, the present inventor has found that a specific amount of a specific resin and an amount of DMSO extract is less than 3% per 100 parts by mass of at least one rubber component selected from diene polymers. It was found that the purpose can be achieved by blending a specific amount of a softener containing a polycyclic aromatic compound (PCA). The present invention has been completed based on such findings.
That is, the present invention
[1] A resin containing an aromatic component and having an indene content of 30 to 80% by mass (A) per 100 parts by mass of at least one rubber component selected from diene-based polymers. 1 part by mass of (B) a softener containing a polycyclic aromatic compound (PCA) having a dimethyl sulfoxide (DMSO) extract amount of less than 3% by IP346 method, Rubber composition,
[2] The rubber composition according to [1], wherein the component (A) is a petroleum resin.
[3] The rubber composition according to the above [1] or [2], wherein the softening point of the component (A) is in the range of 80 to 150 ° C.
[4] The rubber composition according to any one of claims 1 to 3, wherein the ratio of indene in the component (A) is in the range of 50 to 70% by mass in terms of monomer ratio.
[5] The softening agent containing PCA having a DMSO extract amount of less than 3% as the component (B) is a light extraction solvate (MES), a treated distillate aromatic distillate (TDAE), or heavy naphthene. A rubber composition according to any one of the above [1] to [4], which is at least one selected from oils
[6] The rubber composition according to any one of the above [1] to [5], wherein the softener of the component (B) further contains a naphthenic oil and / or a hydrogenated naphthenic oil,
[7] The hydrogenated naphthenic oil is obtained by hydrogenating a naphthenic oil having a naphthenic hydrocarbon content (% C _N ) of 30 or more measured according to ASTM D2140. A rubber composition of the above [6],
[8] In addition to the softener of component (B), an asphalt having a kinematic viscosity at 120 ° C. of 300 mm ² / sec or less and an asphaltene of 5% by mass or less is converted into naphthenic oil and / or hydrogenated naphthenic oil / asphalt. Tread the rubber composition according to any one of the above [1] to [7] and [9] the rubber composition according to any one of [1] to [8] which are contained in a mass ratio of 95/5 to 5/95. Pneumatic tire, characterized by being used for
Is to provide.

  According to the present invention, the wetness of a tire when a high aromatic oil in which a polycyclic aromatic compound (PCA) component is controlled to be less than 3% by weight is used as a softener instead of a conventional high aromatic oil. Complementing the problem of reduced skidability and steering stability, the tire rubber composition having excellent loss characteristics and rigidity, and excellent dry road surface handling stability and wet road surface braking performance using the rubber composition Tires can be provided.

  The rubber composition of the present invention is a resin containing an aromatic component having an indene content of 30 to 80% by mass (A) per 100 parts by mass of at least one rubber component selected from diene polymers. 1 to 45 parts by mass, (B) 1 to 150 parts by mass of a softening agent containing a polycyclic aromatic compound (PCA) having a dimethyl sulfoxide (DMSO) extract amount of less than 3% by IP346 method. Cost.

<Rubber component>
The rubber component used in the rubber composition of the present invention is not particularly limited as long as it is a substance that is crosslinked with sulfur, peroxide, resin, or the like, and natural rubber (NR) and synthetic rubber are used. Examples of the synthetic rubber include synthetic polyisoprene rubber (IR), polybutadiene rubber (BR), solution polymerization styrene-butadiene rubber (S-SBR), emulsion polymerization styrene-butadiene rubber (E-SBR), chloroprene rubber (CR), Examples thereof include diene rubbers such as nitrile rubber (NBR) and butyl rubber (IIR). Among these, natural rubber, styrene-butadiene rubber and polybutadiene rubber produced by an emulsion polymerization method or a solution polymerization method are preferable in consideration of a balance of various performances in the tire tread. These rubber components may be used alone or in combination of two or more.

<Indene-containing resin>
In the present invention, in order to ensure the loss characteristics and rigidity of the rubber composition, it is necessary to blend 0.1 to 45 parts by mass of a resin containing (A) 30 to 80% by mass of indene as a monomer ratio. If the blending amount is less than 0.1 parts by mass, the desired effect of the present invention cannot be obtained. On the other hand, if it exceeds 45 parts by mass, not only an effect commensurate with the increase is obtained, The loss characteristic is not obtained, and the wet road surface braking performance tends to decrease rather as the tire performance. From this point, the blending amount of the component (A) is preferably 1 to 30 parts by mass.
In order to obtain a desired effect, the amount of indene in the component (A) is more preferably 50 to 70% by mass in terms of monomer ratio.

Further, the component (A) preferably has a softening point of 80 ° C. or more, particularly preferably in the range of 100 to 150 ° C., considering the balance between loss characteristics and rigidity. Within this range, the rubber composition for tires of the present invention can provide a performance balanced at a high level in both loss characteristics and rigidity.
As the resin containing indene as the component (A), indene contained in coal tar can be used, but C9 fraction obtained mainly by thermal decomposition of naphtha, for example, α-methylstyrene, styrene, indene, vinyl A petroleum resin such as an alkylstyrene indene resin obtained by heat polymerization of toluene or the like using a catalyst such as sulfuric acid or anhydrous aluminum chloride is used. Moreover, as C9 type petroleum resin containing the said indene, a commercial item can be used conveniently, for example, brand name "Neopolymer" [made by Nippon Oil Corporation], brand name "Toho High Resin" [Toho Chemical Co., Ltd. Manufactured by Kogyo Co., Ltd.].

<Softener with PCA component (polycyclic aromatic compound)] controlled to less than 3% by mass>
In the rubber composition of the present invention, the softening agent in which the DMSO extract amount [PCA component (polycyclic aromatic compound)] by the IP346 method is controlled to be less than 3% by mass is used as the component (B). It is necessary to blend 1 to 150 parts by mass with respect to parts. Preferably it is 2-100 mass parts. Examples of the softening agent whose DMSO extract amount is controlled to be less than 3% by mass include the above-mentioned light extraction solvate (MES), treated distillate aromatic extract (TDAE), heavy naphthenic oil, and the like. Preferably used.

<Hydrogenated naphthenic oil>
Furthermore, in the softening agent of this (B) component, it is preferable to mix | blend hydrogenated naphthenic oil. This hydrogenated naphthenic oil can be obtained by hydrorefining a naphthenic oil in advance by a high-temperature high-pressure hydrorefining technique. The naphthenic oil to be hydrogenated preferably has a naphthenic hydrocarbon content (% C _N ) of 30 or more as measured in accordance with ASTM D2140 (that is, by common ring analysis).

  The amount of the hydrogenated naphthenic oil is preferably added in the range of 20 to 70% by mass with respect to the amount of the softener whose DMSO extract amount is less than 3% by mass. Such hydrogenated naphthenic oils are specifically available as commercial products such as SNH8, SNH46, SNH220, SNH440 (all are trademarks) manufactured by Sankyo Oil Chemical Co., Ltd.

<Asphalt>
Further, the softening agent can include asphalt. In consideration of compatibility with the synthetic rubber to be used and the effect as a softening agent, the asphalt preferably has an asphaltene component of 5% by mass or less. In addition, an asphaltene component is quantified from the composition analysis measured based on JPI method (Japan Petroleum Institute method). Such asphalt is particularly preferably naphthenic straight asphalt, and preferably has a kinematic viscosity at 120 ° C. of 300 mm ² / sec or less.
The blending amount of the asphalt is preferably in the range of 95/5 to 5/95 as a blending mass ratio of naphthenic oil and / or hydrogenated naphthenic oil and asphalt. If the asphalt exceeds 95% by mass, there is a problem in compatibility with the synthetic rubber used, and the effect may be reduced.

The asphalt mixing method is not particularly limited, and the asphalt is mixed with naphthenic oil and / or hydrogenated naphthenic softener in advance, or the main component of asphalt in the refining process of conventional hydrogenated naphthenic oil is naphthenic. A softener prepared by making it exist in an appropriate ratio in oil and / or hydrogenated naphthenic oil may be used, but from the viewpoint of ease of preparation of the softener and economic efficiency, asphalt and naphthenic oil and A method of preparing by dissolving in hydrogenated naphthenic oil (including extension oil and blended oil) is preferable.
In the rubber composition for tires of the present invention, the softener of the component (B) is (1) a softener having a DMSO extract amount of less than 3% by mass, (2) a naphthenic oil and / or a hydrogenated naphthenic oil, And (3) It is preferable to mix | blend 1-100 mass parts with respect to 100 mass parts of rubber components as a total amount of asphalt. If this range is not satisfied, it is difficult to obtain excellent performance in both fracture characteristics and wear characteristics.

In the tire rubber composition of the present invention, carbon black and / or silica can be used as the reinforcing filler. A preferable amount of carbon black is 5 to 100 parts by mass with respect to 100 parts by mass of the rubber component. Moreover, the total compounding quantity of carbon black and a silica is 30-120 mass parts normally with respect to 100 mass parts of rubber components, Preferably it is 40-100 mass parts. By combining carbon black and silica within the above range, it is possible to improve wear resistance, steering stability, reduction of rolling resistance, and improvement of wet skid property.
Examples of the carbon black include FEF, SRF, HAF, ISAF, and SAF. Among these, HAF, ISAF, and SAF that are particularly excellent in wear resistance are preferable. When silica is used, it is preferable to use a silane coupling agent in combination.

Further, the tire rubber composition of the present invention includes various compounding agents usually used in the rubber industry, for example, a vulcanizing agent, a vulcanization accelerator, and an anti-aging agent, as long as the object of the present invention is not impaired. Agents, scorch inhibitors, softeners, zinc white, stearic acid, and the like. And the rubber composition for tires of this invention is used suitably for the tread rubber and tread base rubber of a tire. In addition, the tire of this invention is manufactured by a normal method. That is, if necessary, the tire rubber composition of the present invention containing various chemicals as described above is extruded into a tread member at an unvulcanized stage, and is subjected to a normal method on a tire molding machine. Paste molding is performed to form a green tire. The green tire is heated and pressed in a vulcanizer to obtain a tire.
As the gas filled in the tire, normal or air with a changed oxygen partial pressure, or an inert gas such as nitrogen can be used.

EXAMPLES Next, although an Example demonstrates this invention further in detail, this invention is not limited at all by these examples. Various measurements and evaluation methods were performed based on the following methods.
1. Determination of indene in each resin a. Measurement About each resin, pyrolysis GC-MS measurement was performed on condition of the following.
Apparatus: GC-MS2010 “manufactured by Shimadzu Corporation”, column: HP-5MS (length, 30 m, inner diameter, 25 mm, film thickness, 1 μm), thermal decomposition temperature: 590 ° C.
Column temperature conditions: initial temperature 50 ° C. (5 min) → temperature increase 25 ° C./min (10 min) → final temperature 300 ° C. (12 min)
b. Results The indene fraction of each resin was determined by the TIC peak area ratio (compared to α-methylstyrene) with other components.
2. Evaluation with Rubber Composition <Loss Characteristics: Measurement of 0 ° C. tan δ>
Using a viscoelasticity tester [Rheograph Solid L-1R type manufactured by Toyo Seiki Co., Ltd.], using a vulcanized rubber sheet (5 mm × 45 mm × 2 mm) as a test piece, tan δ at 0 ° C. under conditions of 5% strain and frequency 15 Hz (Dynamic loss characteristics) were measured.
The comparative example 1 and the comparative example 11 were set to 100, and it displayed with the index | exponent. A larger index value indicates better loss characteristics.
<Measurement of storage elastic modulus (E ') at 30 ° C>
The storage elastic modulus (E ′) was measured using a spectrometer (manufactured by Toyo Seiki Co., Ltd.) under the conditions of 30 ° C., dynamic strain 1%, and frequency 15 Hz. The comparative example 1 and the comparative example 11 were set to 100, and it displayed with the index | exponent. It shows that rigidity is so high that an index value is large.

3. Evaluation with tires <Steering stability on dry road>
Run the actual vehicle on a dry road test course (tire size: 195 / 65R15), comprehensively evaluate the driving performance, braking performance, steering wheel response, braking performance during operation, and give a score of 1-10 points, Each item was averaged to give a handling stability score.
It shows that steering stability is so favorable that a numerical value is large.
<Brake performance on wet road>
Test tires (tire size: 195 / 65R15, internal pressure: 196 kPa) are mounted on four wheels of a passenger car, and the braking distance on a wet road surface is measured at an initial speed of 70 km on the test course. Comparative Example 1 and Comparative Example 11 The reciprocal of the braking distance of the tire was expressed as an index with 100 as the inverse. The larger the index, the shorter the braking distance and the better the wet road surface braking performance.

Examples 1 to 7 and Comparative Examples 1 to 5 (Rubber component: Styrene-butadiene rubber)
Based on the content of each compound shown in Table 1, rubber compositions of Examples and Comparative Examples were prepared by a conventional method.
The rubber composition was vulcanized by a conventional method to prepare each test sample, and the tan δ at 0 ° C. and the storage elastic modulus (E ′) at 30 ° C. were measured for each sample. The measurement results are shown in Table 1.
Next, a test passenger radial tire and tire size 195 / 65R15 were manufactured by a conventional method using each of the obtained rubber compositions as a tread. Using the obtained tire, the handling stability on a dry road surface and the braking performance on a wet road surface were evaluated. The evaluation results are shown in Table 1.

［注］
＊１．スチレン・ブタジエンゴム：乳化重合ＳＢＲ＃１５００、ＪＳＲ社製
＊２．カーボンブラック：Ｎ２３４、商品名「旭＃７８」、旭カーボン社製
＊３．オイルＡ：Ｔ−ＤＡＥ（Treated Distilled Aromatic Extracts）ＤＭＳＯ抽出物量３％未満の軟化剤 出光興産社製
＊４．オイルＢ：水添ナフテン系オイル(三共油化工業社製)、とアスファルト（アスファルテン分含量５％以下）との質量比５０／５０ブレンド物、（ＤＭＳＯ抽出物量１．８％）
＊５．樹脂Ａ：「エスコレッツ１１０２Ｂ」、エクソン社製、(軟化点１００℃、インデン比率０％)
＊６．樹脂Ｂ：「エスクロンＧ９０」、新日鐵化学社製、(軟化点１００℃、インデン比率９７％)
＊７．樹脂Ｃ：「日石ネオポリマーＬ９０」、新日本石油社製、(軟化点１００℃、インデン比率３８％)］
＊８．樹脂Ｄ：「日石ネオポリマー１４０」、新日本石油社製、(軟化点１４０℃、インデン比率５２％)］
＊９．樹脂Ｅ：「トーホーハイレジン＃１２０」、東邦化学社製、(軟化点１２０℃、インデン比率６０％)］
＊１０．樹脂Ｆ：「トーホーハイレジン＃１４０」、東邦化学社製、(軟化点１４０℃、インデン比率６０％)］
＊１１．「ＮＯＶＡＲＥＳ ＴＤ１００」、ルトガーズ社製、(軟化点１００℃、インデン比率４０％)］
＊１２．「ＮＯＶＡＲＥＳ ＴＴ１４０」、ルトガーズ社製、(軟化点１００℃、インデン比率５５％)］
＊１３．「ＮＯＶＡＲＥＳ ＴＮ１４０」、ルトガーズ社製、(軟化点１００℃、インデン比率７６％)］
＊１４．老化防止剤：「ノクラック６Ｃ」、大内新興工業社製、Ｎ−（１，３−ジメチル−ブチル）−Ｎ’−フェニル−ｐ−フェニレンジアミン
＊１５．加硫促進剤Ａ：「ノクセラーＮＳ−Ｆ」、大内新興工業社製、Ｎ−ｔ−ブチル−２−ベンゾチアジル−スルフェンアミド
＊１６．加硫促進剤Ｂ：「ノクセラーＴＯＴ」、大内新興工業社製、テトラキス−２エチルヘキシルチウラムジスルフィド

[note]
* 1. Styrene-butadiene rubber: Emulsion polymerization SBR # 1500, manufactured by JSR * 2. Carbon black: N234, trade name “Asahi # 78”, manufactured by Asahi Carbon * 3. Oil A: T-DAE (Treated Distilled Aromatic Extracts) DMSO extract less than 3% softener made by Idemitsu Kosan Co., Ltd. * 4. Oil B: hydrogenated naphthenic oil (manufactured by Sankyo Oil Chemical Co., Ltd.) and asphalt (asphaltene content 5% or less) in a 50/50 mass ratio blend (DMSO extract amount 1.8%)
* 5. Resin A: “Escollet 1102B”, manufactured by Exxon, (softening point 100 ° C., indene ratio 0%)
* 6. Resin B: “Esclon G90”, manufactured by Nippon Steel Chemical Co., Ltd. (softening point 100 ° C., indene ratio 97%)
* 7. Resin C: “Nisseki Neopolymer L90” manufactured by Nippon Oil Corporation (softening point 100 ° C., indene ratio 38%)]
* 8. Resin D: “Nisseki Neopolymer 140” manufactured by Nippon Oil Corporation (softening point 140 ° C., indene ratio 52%)]
* 9. Resin E: “Toho High Resin # 120” manufactured by Toho Chemical Co., Ltd. (softening point 120 ° C., indene ratio 60%)]
* 10. Resin F: “Toho High Resin # 140”, manufactured by Toho Chemical Co., Ltd. (softening point 140 ° C., indene ratio 60%)]
* 11. “NOVARES TD100”, manufactured by Rutgers, (softening point 100 ° C., indene ratio 40%)]
* 12. “NOVARES TT140”, manufactured by Rutgers (softening point 100 ° C., indene ratio 55%)]
* 13. “NOVARES TN140”, manufactured by Rutgers (softening point 100 ° C., indene ratio 76%)]
* 14. Anti-aging agent: “NOCRACK 6C”, manufactured by Ouchi Shinko Kogyo Co., Ltd., N- (1,3-dimethyl-butyl) -N′-phenyl-p-phenylenediamine * 15. Vulcanization accelerator A: “Noxeller NS-F”, manufactured by Ouchi Shinko Kogyo Co., Ltd., Nt-butyl-2-benzothiazyl-sulfenamide * 16. Vulcanization accelerator B: “Noxeller TOT”, manufactured by Ouchi Shinko Kogyo Co., Ltd., tetrakis-2 ethylhexyl thiuram disulfide

Examples 8 to 19 and Comparative Examples 6 to 7 (rubber component: styrene-butadiene rubber)
Based on the content of each compound shown in Table 2, rubber compositions of Examples and Comparative Examples were prepared by a conventional method.
The rubber composition was vulcanized by a conventional method to prepare each test sample, and the tan δ at 0 ° C. and the storage elastic modulus (E ′) at 30 ° C. were measured for each sample. The measurement results are shown in Table 2.
Next, a test passenger radial tire and tire size 195 / 65R15 were manufactured by a conventional method using each of the obtained rubber compositions as a tread. Using the obtained tire, the handling stability on a dry road surface and the braking performance on a wet road surface were evaluated. The evaluation results are shown in Table 2.

［注］
＊１７．樹脂Ｈ：「トーホーハイレジン＃９０」、東邦化学社製、(軟化点１００℃、インデン比率５０％)］
＊１８．樹脂I：「トーホーハイレジン＃１１０T」、東邦化学社製、(軟化点１１０℃、インデン比率５０％)］

[note]
* 17. Resin H: “Toho High Resin # 90” manufactured by Toho Chemical Co., Ltd. (softening point 100 ° C., indene ratio 50%)]
* 18. Resin I: “Toho High Resin # 110T” manufactured by Toho Chemical Co., Ltd. (softening point 110 ° C., indene ratio 50%)]

Examples 20 to 31 and Comparative Examples 8 to 10 (rubber component: styrene-butadiene rubber)
Based on the content of each compound shown in Table 3, rubber compositions of Examples and Comparative Examples were prepared by a conventional method.
The rubber composition was vulcanized by a conventional method to prepare each test sample, and the tan δ at 0 ° C. and the storage elastic modulus (E ′) at 30 ° C. were measured for each sample. The measurement results are shown in Table 3.
Next, a test passenger radial tire and tire size 195 / 65R15 were manufactured by a conventional method using each of the obtained rubber compositions as a tread. Using the obtained tire, the handling stability on a dry road surface and the braking performance on a wet road surface were evaluated. The evaluation results are shown in Table 3.

［注］
＊１９．オイルＣ：ナフテン系オイル「ＳＮＨ２２０」(三共油化工業社製)、ナフテン系炭化水素の含有量（％Ｃ_N）４４％（ＤＭＳＯ抽出物量２．２％）
＊２０．オイルＤ：ナフテン系オイル「ＳＮＨ８」、(三共油化工業社製)、ナフテン系炭化水素の含有量（％Ｃ_N）５６％（ＤＭＳＯ抽出物量１．９％）
＊２１．オイルＥ：パラフィン系オイル「スーパーオイルＹ２２」、（新日本石油化学社製）（ＤＭＳＯ抽出物量２．１％）

[note]
* 19. Oil C: naphthenic oil “SNH220” (manufactured by Sankyo Oil Chemical Co., Ltd.), naphthenic hydrocarbon content (% C _N ) 44% (DMSO extract amount 2.2%)
* 20. Oil D: Naphthenic oil “SNH8” (manufactured by Sankyo Oil Chemical Co., Ltd.), naphthenic hydrocarbon content (% C _N ) 56% (DMSO extract amount 1.9%)
* 21. Oil E: Paraffinic oil “Super Oil Y22” (manufactured by Nippon Petrochemical Co., Ltd.) (DMSO extract amount 2.1%)

Examples 32-37 and Comparative Examples 11-14 (Rubber component: blend system of natural rubber and butadiene rubber)
Based on the content of each compound shown in Table 3, rubber compositions of Examples and Comparative Examples were prepared by a conventional method.
The rubber composition was vulcanized by a conventional method to prepare each test sample, and the tan δ at 0 ° C. and the storage elastic modulus (E ′) at 30 ° C. were measured for each sample. The measurement results are shown in Table 4.
Next, a test passenger radial tire and tire size 195 / 65R15 were manufactured by a conventional method using each of the obtained rubber compositions as a tread. Using the obtained tire, the handling stability on a dry road surface and the braking performance on a wet road surface were evaluated. The evaluation results are shown in Table 4.

［注］
＊２２．ブタジエンゴム：「ＢＲ−０１」、ＪＳＲ社製
＊２３．カーボンブラック：Ｎ２２０、「シースト６」、東海カーボン社製
＊２４．加硫促進剤Ｃ：「ノクセラーＤＺ−Ｇ」、大内新興工業社製、Ｎ，Ｎ’−ジシクロヘキシル−２−ベンゾチアゾリルスルフェンアミド
＊２５．加硫促進剤Ｄ：「ノクセラーＤＭ」、大内新興工業社製、ジベンゾチアジルジスルファイド

[note]
* 22. Butadiene rubber: “BR-01” manufactured by JSR * 23. Carbon black: N220, “Seast 6”, manufactured by Tokai Carbon Co., Ltd. * 24. Vulcanization accelerator C: “Noxeller DZ-G”, manufactured by Ouchi Shinko Kogyo Co., Ltd., N, N′-dicyclohexyl-2-benzothiazolylsulfenamide * 25. Vulcanization accelerator D: “Noxeller DM”, manufactured by Ouchi Shinko Kogyo Co., Ltd., dibenzothiazyl disulfide

  According to the present invention, there is a problem when a high aromatic oil in which a polycyclic aromatic compound (PCA) component is controlled to be less than 3% by weight is used as a softening agent instead of a conventional high aromatic oil. It is possible to provide a tire rubber composition having excellent loss characteristics and rigidity, and a tire excellent in dry road surface handling stability and wet road surface braking performance using the rubber composition.

Claims (9)

  0.1 to 45 parts by mass of a resin containing an aromatic component having an indene content of 30 to 80% by mass (A) per 100 parts by mass of at least one rubber component selected from diene polymers, (B ) A rubber composition comprising 1 to 150 parts by mass of a softening agent containing a polycyclic aromatic compound (PCA) having a dimethyl sulfoxide (DMSO) extract amount of less than 3% by the IP346 method.   The rubber composition according to claim 1, wherein the component (A) is a petroleum resin.   The rubber composition according to claim 1 or 2, wherein the softening point of the component (A) is in the range of 80 to 150 ° C.   The rubber composition according to any one of claims 1 to 3, wherein the ratio of indene as the component (A) is in the range of 50 to 70% by mass in terms of monomer ratio.   (B) The softener containing PCA having a DMSO extract amount of less than 3% is obtained from a light extraction solvate (MES), a treated distillate aromatic distillate (TDAE), or a heavy naphthenic oil. The rubber composition according to claim 1, which is at least one selected.   The rubber composition according to any one of claims 1 to 5, wherein the softening agent of component (B) further contains naphthenic oil and / or hydrogenated naphthenic oil. Claim wherein the hydrogenated naphthenic oil, in which the content of the measured naphthenic hydrocarbons in compliance with ASTM D2140 (% C _N) is obtained by over 30 naphthenic oil is hydrogenated 6. The rubber composition according to 6. In addition to the softener of the component (B), asphalt having a kinematic viscosity at 120 ° C. of 300 mm ² / sec or less and 5% by mass or less of asphaltene is used as a mass ratio of naphthenic oil and / or hydrogenated naphthenic oil / asphalt. The rubber composition according to any one of claims 1 to 7, which is contained in a range of 95/5 to 5/95.   A pneumatic tire using the rubber composition according to claim 1 for a tread.