JP2010235885A - Vibration deadening coating composition for roofs and roof structure - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a vibration deadening coating composition for roofs and a roof structure, which can increase the effects of reducing the sound of rain and suppressing the occurrence of defect such as generation of pin holes or irregular surface appearance and can easily improve coating properties and adhesion. <P>SOLUTION: The vibration deadening coating composition for roofs contains an aqueous resin dispersion liquid in which resin particles forming a coating film 12 are dispersed in an aqueous dispersion medium and a filler comprising non-swelling mica and calcium carbonate. The content of the filler ranges from 320 to 740 pts.mass based on 100 pts.mass of resin particles and ranges from 220 to 430 pts.mass based on 100 pts.mass of water content. The content of calcium carbonate ranges from 80 to 110 pts.mass based on 30 pts.mass of non-swelling mica. A metal roof material 11 is coated with the vibration deadening coating composition for roofs. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a vibration-damping coating composition for roof and a roof structure using the same.

  As a roof structure in consideration of vibration damping properties, a structure in which a roof material and a base material are bonded using a vibration damping adhesive, a structure in which a vibration damping sheet is pasted on the back side of a folded plate, and the like are known. (See Patent Documents 1 and 2). Such a roof structure reduces the sound of rain generated by metal roofing materials during rainfall. Moreover, the coating material containing scaly pigments, such as mica, is known as a coating material applied to a roofing material (refer patent document 3).

JP 2005-009205 A JP-A-10-306550 JP 2003-238897 A

  By the way, in the vibration-damping coating composition for roofs, for example, as the drying temperature is increased, the surface appearance of the coating film becomes uneven or the pinhole is easily formed in the coating film. This phenomenon is generally referred to as an armpit and can be a defect on the surface of the coating film. In conventional anti-vibration coating compositions for roofs, it has been achieved to suppress the occurrence of such cracks and to improve the coating properties of coatings on metal roofing materials, the adhesion of coating films, and the effect of reducing rain noise. Not in. In addition, when the adhesiveness of the coating film is not sufficiently obtained, there is a problem that the durability of the coating film cannot be sufficiently obtained, and as a result, the rain noise reduction effect is lowered. Furthermore, the applicability of the composition causes a decrease in application efficiency.

  In the present invention, by containing a predetermined amount of non-swellable mica and a predetermined amount of calcium carbonate with respect to the resin particles and moisture contained in the composition, the effect of reducing rain noise and the suppression of occurrence of armpits are sufficient. It was made by finding out that the applicability and adhesion are also improved. An object of the present invention is to provide a roof anti-vibration coating composition and a roof structure that are easy to improve the rain noise reduction effect and the suppression effect of the occurrence of wrinkles and improve the coating properties and adhesion.

  In order to achieve the above object, a vibration-damping coating composition for a roof according to claim 1 includes an aqueous resin dispersion in which resin particles forming a coating film are dispersed in an aqueous dispersion medium, and a non-swellable mica. And a filler composed of calcium carbonate, and is a roof damping coating composition applied to a metal roofing material, wherein the content of the filler is based on 100 parts by mass of the resin particles. 320 to 740 parts by mass, 220 to 430 parts by mass with respect to 100 parts by mass of water, and the calcium carbonate content is 80 to 110 parts by mass with respect to 30 parts by mass of the non-swellable mica. It is a summary.

The invention according to claim 2 is characterized in that, in the vibration-damping coating composition for roof according to claim 1, acrylic resin particles are included as the resin particles.
The gist of the roof structure of the invention described in claim 3 is that the coating film formed from the vibration-damping coating composition for roof according to claim 1 or 2 is laminated on a metal roofing material. To do.

  ADVANTAGE OF THE INVENTION According to this invention, it becomes easy to improve an applicability | paintability and adhesiveness while improving the rain sound reduction effect and the suppression effect of the occurrence of a bran.

The fragmentary sectional view which shows the roof structure of this embodiment. The schematic diagram which shows the outline of a rain sound test apparatus.

DESCRIPTION OF EMBODIMENTS Hereinafter, embodiments embodying the present invention will be described in detail.
The roof vibration-damping coating composition in this embodiment contains an aqueous resin dispersion in which resin particles forming a coating film are dispersed in an aqueous dispersion medium, and a filler composed of non-swellable mica and calcium carbonate. Yes.

  Examples of the polymer material constituting the resin particles include acrylic resins, acrylic / styrene resins, urethane resins, phenol resins, vinyl chloride resins, vinyl acetate resins, vinyl acetate / acrylic resins, ethylene / acetic acid. Examples thereof include at least one selected from vinyl resins, epoxy resins, polyester resins, alkyd resins, acrylonitrile / butadiene copolymer rubber, styrene / butadiene copolymer rubber, butadiene rubber, and isoprene rubber. These polymer materials may be modified.

  The resin particles may be formed of a single type of polymer material or may be formed of a plurality of types of polymer material. Furthermore, the aqueous resin dispersion may contain resin particles composed of these polymer materials alone, or may contain a plurality of types of resin particles.

Among the resin particles, it is preferable to include acrylic resin particles from the viewpoint that it is easy to adjust the temperature range in which the vibration damping performance is exhibited to around room temperature.
Examples of the acrylic resin forming the acrylic resin particles include homopolymers containing acrylic acid, acrylic ester, methacrylic acid and methacrylic ester as monomers, mixtures of these homopolymers, and monomers. And a copolymer obtained by polymerizing. Examples of acrylic acid ester and methacrylic acid ester include methyl ester, ethyl ester, propyl ester, butyl ester, 2-ethylhexyl ester, ethoxyethyl ester and the like.

  Among the acrylic resin particles, a copolymer of methyl methacrylate and butyl acrylate is preferable from the viewpoint that it is easier to adjust the temperature range in which vibration damping performance is exhibited to around room temperature.

  The content of the acrylic resin particles with respect to the total amount of the resin particles is preferably 90% by mass or more, more preferably 95% by mass or more. Most preferably, the total amount of resin particles is acrylic resin particles.

Examples of the aqueous dispersion medium for dispersing the resin particles include water and a mixed liquid of water and a monohydric alcohol. Examples of the monohydric alcohol include methanol and ethanol.
A filler composed of non-swellable mica and calcium carbonate enhances the vibration damping performance of the coating film. Examples of the non-swellable mica include synthetic non-swellable mica such as fluorine phlogopite and potassium tetrasilicon mica, and natural non-swellable mica such as muscovite, phlogopite, biotite, and sericite.

  Calcium carbonate is not particularly limited as long as it is in a powder form. Examples of calcium carbonate include light calcium carbonate and heavy calcium carbonate. Such calcium carbonate may contain a single species or a combination of a plurality of species.

  Content of the said filler is 320-740 mass parts with respect to 100 mass parts of resin particles contained in a composition. If the content of the filler is less than 320 parts by mass with respect to 100 parts by mass of the resin particles contained in the composition, the rain noise reduction effect may not be sufficiently obtained. On the other hand, when the content of the filler exceeds 740 parts by mass with respect to 100 parts by mass of the resin particles contained in the composition, the coating property of the composition on the metal roofing material and the coating on the metal roofing material Adhesion may not be sufficiently obtained.

  Moreover, content of a filler is 220-430 mass parts with respect to 100 mass parts of water | moisture contents contained in a composition. When the content of the filler is less than 220 parts by mass with respect to 100 parts by mass of water contained in the composition, there is a problem that a crack is likely to occur. On the other hand, when content of a filler exceeds 430 mass parts with respect to 100 mass parts of moisture contained in a composition, there exists a possibility that said applicability | paintability may not fully be obtained.

  Furthermore, content of calcium carbonate is 80-110 mass parts with respect to 30 mass parts of non-swellable mica. When the content of calcium carbonate is less than 80 parts by mass with respect to 30 parts by mass of non-swellable mica, the rain noise reduction effect may not be sufficiently obtained. On the other hand, even when the content of calcium carbonate exceeds 110 parts by mass with respect to 30 parts by mass of non-swellable mica, the rain noise reduction effect may not be sufficiently obtained.

In consideration of dispersibility and the like, the average particle size of the non-swellable mica is preferably, for example, in the range of 1 to 200 μm in the average particle size measured by the laser diffraction method.
The average particle size of calcium carbonate is preferably 1.0 to 7.0 μm, from the viewpoint of enhancing applicability, adhesion, and rain noise reduction effect, and further facilitating suppression of the occurrence of cracks. Preferably it is 1.2-5.0 micrometers, More preferably, it is 1.5-3.5 micrometers. In addition, an average particle diameter shows the average particle diameter computed from a specific surface area. That is, it is an average particle diameter calculated from the following formula using a specific surface area value per gram by a powder specific surface area measuring device.

Average particle diameter (μm) = 6 / (specific gravity × specific surface area) × 10000
If necessary, the roof vibration-damping coating composition may contain a filler other than the above fillers as long as it does not impair the effects of the above-described inclusion of the predetermined amount of filler. . Examples of fillers other than the above fillers include talc, clay, barium sulfate, magnesium carbonate, glass, silica, aluminum oxide, aluminum, aluminum hydroxide, iron, titanium oxide, iron oxide, diatomaceous earth, zeolite, and ferrite. It is done.

  Anti-vibration coating compositions for roofs require flame retardants, colorants, antioxidants, antistatic agents, stabilizers, foaming agents, lubricants, dispersants, gelling agents, film-forming aids, antifreeze agents, etc. It can be contained according to.

  The vibration-damping coating composition for roof can be prepared by mixing an aqueous resin dispersion, non-swellable mica and calcium carbonate using a known mixing means. And a coating film is formed in a roofing material by drying, after applying the damping paint composition for roofs to the predetermined part of a roofing material. As a coating method, a known coating device such as a roll coater or a spray gun can be used. Examples of the method for drying the paint include hot air drying and infrared drying. In such application, since the anti-swelling mica and calcium carbonate are contained in the above-described content in the vibration-damping coating composition for roofs, problems such as uneven application and fading are unlikely to occur. That is, good applicability is exhibited. Moreover, when the coating film is dried, the occurrence of cracks is suppressed.

Next, the roof structure to which the vibration-damping coating composition for roof is applied will be described.
As shown in FIG. 1, the roof structure has a configuration in which a coating film 12 is laminated on a metal roof material 11. As a metal which comprises the roofing material 11, steel, stainless steel, an aluminum alloy, a zinc alloy, copper, titanium etc. are mentioned, for example. The roof material 11 may be plated with various metals. The metal roof having the above-described roof structure is formed by a method such as a folded plate, a tile rod, a vertical flat, a flat plane, a horizontal plane, or a metal tile. The coating film 12 is laminated on the back surface of the roofing material 11 when the surface of the roofing material 11 exposed to rain is the front surface.

  The building having the above-described roof structure is not particularly limited, and examples include a warehouse, a factory, a parking lot, a bicycle parking lot, a gymnasium, an arcade, a temple, a shrine, and a general house. The metal roofing material 11 is advantageous in that the weight of the roof can be reduced as compared with a roofing material such as clay tile. Moreover, the rain sound generated by the metal roofing material 11 can become noise in the vicinity of the building in addition to noise in the lower part of the roofing material 11 (for example, inside the building). That is, since the roof material 11 vibrates when raindrops collide with the roof material 11 during rainfall, noise can be generated around the roof material 11. For this reason, the roof structure is advantageous in that noise is suppressed in the vicinity of a building having a metal roof, for example, in an area where houses are densely packed, an area where parking lots and houses are densely packed, or the like.

  Here, since the predetermined amount of filler described above is dispersed in the coating film 12 of this embodiment, the rain noise reduction effect is easily exhibited. And since the adhesiveness with the roofing material 11 is improved in this coating film 12, the rain sound reduction effect is easy to be exhibited continuously.

  In addition, the thickness of a coating film becomes like this. Preferably they are 10 micrometers-900 micrometers, More preferably, they are 10 micrometers-500 micrometers. By making the thickness of the coating film 10 μm or more, excellent vibration damping performance is easily exhibited, so that an excellent rain noise reduction effect is easily obtained. On the other hand, when the thickness of a coating film exceeds 900 micrometers, there exists a possibility of becoming the hindrance of the weight reduction of an applied material.

The effects exhibited by this embodiment will be described below.
(1) Since the content of the filler in the vibration-damping coating composition for roof is 320 to 740 parts by mass with respect to 100 parts by mass of the resin particles, the rain noise reduction effect is enhanced and the metal roofing material is added. It becomes easy to ensure the applicability of the composition and the adhesion of the coating film to the metal roofing material. Moreover, since content of a filler is 220-430 mass parts with respect to 100 mass parts of water | moisture contents, generation | occurrence | production of a bran is suppressed and said applicability | paintability becomes easy to be ensured. Moreover, since the content of calcium carbonate is 80 to 110 parts by mass with respect to 30 parts by mass of non-swellable mica, the rain noise reduction effect is further enhanced. In this way, by adding a predetermined amount of filler to the resin particles and water contained in the composition, the rain noise reduction effect and the suppression effect of the occurrence of oysters are enhanced, and the coatability and adhesion are improved. Easy to do.

  (2) By including acrylic resin particles as the resin particles, it is easy to adjust the temperature range where the vibration damping performance is exhibited to near room temperature, so that the rain noise reduction effect can be exhibited near room temperature. Can do. Therefore, it is possible to provide a vibration-damping coating composition for roofs that can easily exhibit a rain noise reduction effect in a rainy environment.

  (3) According to the roof structure in which the coating film 12 formed from the vibration-damping coating composition for roof according to the present embodiment is laminated on the metal roofing material 11, rain noise is reduced by improving the adhesion. The effect is easily exhibited continuously. Moreover, in such a roof structure, since peeling of the coating film 12 is suppressed, there is an advantage that the durability of the coating film 12 is excellent.

The embodiment may be modified as follows.
A metal foil such as an aluminum foil may be bonded to the surface of the coating film 12 laminated on the roof material 11. In this case, a constrained vibration damping structure using a metal foil as a constraining layer can be configured.

  The vibration damping coating composition for roof may be applied to the entire surface of the roof material 11 or may be partially applied to the surface of the roof material 11.

Next, the embodiment will be described more specifically with reference to examples and comparative examples.
(Examples 1-3)
A non-swelling mica, calcium carbonate, water and other components are blended into an acrylic emulsion (Dainippon Ink Chemical Co., Ltd., BC-280) and mixed with a stirrer to obtain a vibration-damping coating composition for roofs. Prepared. 100 parts by mass of the acrylic emulsion contains 50 parts by mass of resin particles. The resin particles are a copolymer of methyl methacrylate and butyl acrylate, and the mass ratio of methyl methacrylate to butyl acrylate in the copolymer is 55:45. The average particle size of non-swellable mica is 97 μm. Calcium carbonate is heavy calcium carbonate, and its average particle size is 2.2 μm. In addition, about 4 mass% of dispersing agents etc. are contained in the vibration damping coating composition for roofs with respect to the composition whole quantity as other components.

(Comparative Examples 1-7)
In each comparative example, a roof vibration-damping coating composition was prepared in the same manner as in each example except that the content of each component was changed as shown in Tables 2 and 3.

<Evaluation of applicability>
The anti-vibration coating composition for roofs of each example was used as a viscosity cup No. The diluted composition diluted with water was measured so that it might become 40 to 100 seconds as measured by 2. After the diluted composition was applied to the entire surface of the urethane roller, the diluted composition was applied to the SPCC steel sheet by reciprocating the urethane roller five times on the SPCC steel sheet. The coating film immediately after coating was visually observed and evaluated according to the criteria shown in Table 4. The results are also shown in Tables 1 to 3.

<Confirmation of armpit suppression effect and adhesion evaluation>
After coating the anti-vibration coating composition for roof in each example on a 5 mm thick SPCC steel plate with a bar coater, the SPCC steel plate was placed in a heating furnace and the anti-vibration coating composition was heated and dried to form a coating film. . In this heat drying, the temperature in the heating furnace was set so that the surface temperature of the SPCC steel sheet was 220 ° C., and the treatment was performed at that temperature for 40 seconds. In addition, the application amount of the anti-vibration coating composition for roof in each example is adjusted so that the thickness of the coating film is about 70 μm. Next, the surface state of the coating film was observed, and as shown in Table 4, the presence or absence of armpits was confirmed. Subsequently, adhesion was evaluated. After fully cooling the coating film of each example, the cellophane tape was stuck on the coating-film surface, and the cellophane tape was peeled off at a stretch. The peeling state of the coating film at this time was confirmed, and the adhesion was evaluated according to the criteria shown in Table 4. The results are also shown in Tables 1 to 3.

<Confirmation of rain noise reduction effect>
After applying the anti-vibration coating composition for roofs of each example to one side of the SPCC steel plate using a spray gun, the specimens of each example were prepared by drying at room temperature for 30 minutes. In addition, the coating amount of the anti-vibration coating composition for roof in each example was adjusted so that the thickness after drying was constant. About each test piece, the outdoor sound and the indoor sound were measured simultaneously using the rain sound test apparatus shown in FIG. The rain sound test apparatus is provided inside a box-shaped apparatus main body 21, a rain part 22 provided above the apparatus main body 21, an outdoor sound microphone 23 provided outside the apparatus main body 21, and the apparatus main body. And an indoor sound microphone 24. A test body 31 is arranged on the upper part of the apparatus main body 21 so that the surface of the SPCC steel plate faces the rain part 22. Each microphone 23, 24 is connected to a sound level meter. The measurement condition is background noise of 39.3 dB, and rainfall is made constant from the rainfall section 22 to the surface of the SPCC steel sheet. The measurement of the outdoor sound and the indoor sound was repeated five times, and the average value of the measured values was calculated. Based on the measured outdoor sound and room sound, the evaluation criteria shown in Table 4 were used for evaluation. The results are also shown in Tables 1 to 3.

  As shown in Table 1, in each of the examples, good results were obtained in all of the rain noise reduction effect, coating property, adhesion, and armpit suppression effect. On the other hand, in Comparative Examples 1 to 4 shown in Table 2, the content of the filler with respect to the resin particles and moisture, and the content of non-swellable mica with respect to the content of calcium carbonate are included in the above-described range. Therefore, the rain noise reduction effect is inferior to each example. Further, in Comparative Examples 5 and 6 shown in Table 3, the content of the non-swelling mica relative to the content of calcium carbonate is the above range, although the content of the filler with respect to the resin particles and moisture is included in the above range. Therefore, the rain sound reduction effect is inferior to each example. In Comparative Example 7, although the content of non-swellable mica with respect to the content of calcium carbonate is included in the above-described range, the content of the filler with respect to resin particles and moisture is not included in the above-described range. The effect is inferior to each example.

  11 ... Roofing material, 12 ... Paint film.

Claims (3)

A roofing system applied to a metal roofing material, comprising an aqueous resin dispersion in which resin particles forming a coating film are dispersed in an aqueous dispersion medium, and a filler made of non-swellable mica and calcium carbonate. A vibration paint composition comprising:
The content of the filler is 320 to 740 parts by mass with respect to 100 parts by mass of the resin particles, and 220 to 430 parts by mass with respect to 100 parts by mass of water.
The content of the calcium carbonate is 80 to 110 parts by mass with respect to 30 parts by mass of the non-swellable mica. The anti-vibration coating composition for roof according to claim 1, wherein acrylic resin particles are included as the resin particles. A roof structure, wherein a coating film formed from the vibration-damping coating composition for roof according to claim 1 or 2 is laminated on a metal roof material.

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