JP2010217758A - Printing method of precision pattern - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a printing method of a precision pattern, which is stable, has excellent cost performance and can be used mainly for manufacture of a color filter (CF) and by which the CF where overlap between partition pattern and a colored layer pattern and between colored layer patterns in the printed matter are suppressed to the minimum is obtained. <P>SOLUTION: In the printing method of the precision pattern for forming an ink pattern having an area smaller than that of a region partitioned by a partition pattern 20 on an ink peelable film base material 10 in the region partitioned by the partition pattern 20 previously provided on a base material 30 to be printed for selectively disposing an ink, performing positioning to the partition pattern 20 on the base material 30 to be printed and then performing pressure transfer to uniformly spread the ink in the region partitioned by the partition pattern 20, the partition pattern 20 has ink repellency. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a printing method for forming a high-definition pattern on a flexible substrate such as a glass substrate or a plastic film.

  Conventionally, printing technology developed for paper and film has also been applied to the electronics field, contributing to the mass production and cost reduction of precision equipment. In particular, in flat panel displays that have been remarkably developed in recent years, precision patterning technology is used for many members, and there is an increasing demand for increasing the size and cost of members using these precision patterning technologies.

  For example, a color filter (CF) used in a color liquid crystal display device, which is one of flat panel displays, has three colors of fine red (R), green (G), and blue (B) on a transparent substrate. The pattern of the colored layers is regularly arranged, for example, in the form of dots or stripes. In addition, a lattice-shaped or stripe-shaped light shielding layer, so-called black matrix (BM), which is a partition wall for optically separating the colored layers, is manufactured between the colored layers using a precision patterning technique. .

  In the early stages of CF production, vapor deposition and dyeing methods were used. However, a complicated process of depositing dozens of thin films for each adjacent pixel is necessary (vapor deposition method). The organic layer has a problem in the organic layer and color resistance (dyeing method), etc. (Patent Documents 1 and 2).

  In addition, attempts have been made to perform CF patterning using an existing printing method such as offset printing or screen printing (Patent Document 3).

  However, in screen printing, the screen plate is easily deformed, and there is a problem in the deformation of the print pattern and the pattern overlay accuracy.

  Further, in offset printing, there is a problem in that the pattern is crushed or blotted at the time of receiving or transferring the pattern from the blanket, and a difference in ink film thickness occurs between the pattern center portion and the contour portion during pressurization.

  Therefore, in recent years, the photolithography method (also referred to as pigment dispersion method) in which each layer of the above-mentioned BM and three color patterns is applied on a transparent substrate, respectively, by repeating a pigment dispersion resist coating, exposure, development process, etc. is the center of the production method. It has become.

  In the photolithography method, the process required for patterning each color including the BM is complicated, and there is a problem of an increase in equipment scale accompanying an increase in size for a television product or the like. Further, miniaturization of CF patterning obtained by a photolithography method is a problem for small panels.

  In the photolithography method, in general, an error in alignment accuracy (positioning accuracy) of each coloring pattern with respect to the BM pattern is considered, and each coloring pattern is designed to be larger than a pixel area formed in advance with the BM pattern.

  Therefore, when looking at the cross section of the CF, a part of the colored pattern rides on the surface of the BM pattern (overlap), resulting in a step, which causes disorder of liquid crystal alignment and unevenness.

  In addition, the display resolution has been increasing in TV products and mobile products, and pixel size reduction and BM line width miniaturization are required. Therefore, the overlapping width of the colored pattern with respect to the BM pattern can hardly be set. Tend.

  Therefore, a method has been devised in which a BM pattern is used as a partition of a pixel pattern, and after printing is performed on the opening using offset printing, the pixel surface is pressed as it is with the blanket cylinder used for printing, and the ink is extended over the entire opening. (Patent Document 4).

  In this method, it is possible to spread the ink over the entire surface of the pixel without certainly setting the overlap between the BM pattern and the pixel pattern. However, since pressure is applied at a stage where the fluidity of the ink is high, color mixing is prevented. If the height of the partition wall is ensured for the purpose, it is difficult to make the pressurization to the ink uniform, and it is difficult to achieve high definition because of using normal offset printing.

  On the other hand, CF manufacturing technology using inkjet (IJ) is being developed for the purpose of simplifying the manufacturing process and reducing ink used.

  In the IJ method, an image receiving layer method using a laminated ink-absorbing resin layer or a partition method in which ink repellency is imparted to a light shielding pattern is mainly used.

  However, in the image receiving layer method, it is difficult to control expansion when colored ink is absorbed and to impart resistance to the processed surface layer.

  In addition, since it is difficult to increase the viscosity of the ink in the ink jet method, the amount of ink that is several times the height of the partition wall must be maintained without being broken immediately after ejection in the partition wall method, and the pattern has bleeding and color mixing. It tends to occur (Patent Document 5).

  Furthermore, in order to obtain the landing elasticity of the droplets ejected from the inkjet head and the stability of continuous ejection, the size of the ink droplets that generally land is about 20 μm to 40 μm, the width of the pixel opening, If landing position errors due to mechanical accuracy are included, the pixel pattern cannot be used for high-definition patterning with a width of 60 μm or less.

  Therefore, a new printing method has been devised as a method for forming such a fine pattern.

  For example, in the printing method described in Patent Document 6, an ink film is applied to the surface of a blanket installed in a cylinder, the ink is not completely dried on the blanket, and then the surface is unevenly removed. In this method, a plate is pressed and excess ink other than the pattern is removed from the plate surface, and then a necessary pattern is transferred onto the substrate to be printed.

  In general offset printing and screen printing, the fluidity of the ink is high, so there was a problem that bleeding and unevenness occurred inevitably during high-definition patterning. The ink liquid film was made into a semi-dry state and then patterned using a removal plate, thereby suppressing the flow of ink and enabling high-definition patterning.

  Further, the printing process is simple, the scale of the equipment and the installation area can be reduced, and there is an advantage that the development cost is not required unlike the photolithography method and the running cost can be reduced.

  However, since this printing method uses a blanket base material with a thickness of several millimeters, it is difficult to ensure the uniformity of the blanket, and further, swelling occurs due to the absorption of the ink solvent into the blanket, and the linearity and reproduction of the pattern There was a problem of impairing sex.

  In addition, the overlay of the pattern on the blanket installed on the cylinder and the existing pattern provided on the substrate to be printed cannot be observed directly, and there was a problem with the overlay accuracy of the high-definition pattern. .

  For this reason, when superimposing the patterns, it is necessary to design the pattern in consideration of the overlap with the existing pattern, as in the photolithography method.

JP-A 63-26361 Japanese Patent Laid-Open No. 4-86801 JP-A-11-314341 JP-A-2-297502 JP-A-6-186416 JP 2001-56405 A

  The present invention has been made to solve the above-mentioned problems, and the problem is that it is stable and excellent in cost performance, and can be used mainly for producing a color filter (CF). It is an object of the present invention to provide a precision pattern printing method capable of obtaining a CF with a minimum overlap between colored layer patterns and between partition wall patterns and colored layer patterns of a printed material.

As a means for solving the above-described problems, the invention according to claim 1 is directed to an ink for selectively disposing ink in a region partitioned by a partition pattern provided in advance on a substrate to be printed. An ink pattern having a smaller area than the area partitioned by the partition wall pattern is formed on the releasable film substrate, aligned with the partition wall pattern on the substrate to be printed, and then transferred by pressure. In the printing method of the precision pattern provided by spreading the ink uniformly in the area partitioned by the partition pattern,
The partition pattern has ink repellency, and is a precision pattern printing method.

  The invention according to claim 2 is characterized in that a material having silicon atoms is used as a material for imparting ink repellency to the partition wall pattern. It is.

  The invention according to claim 3 is characterized in that a material having fluorine atoms is used as a material for imparting ink repellency to the partition wall pattern. It is.

  According to a fourth aspect of the present invention, the barrier rib pattern has an upper surface portion and a lower portion other than the upper surface portion, and the ink repellency of the upper surface portion of the barrier rib pattern is greater than the ink repellency of the lower portion of the barrier rib pattern. The method for printing a precision pattern according to any one of claims 1 to 3.

  The invention according to claim 5 is a method for obtaining an ink pattern having an area smaller than an area partitioned by the partition pattern on the ink peelable film substrate. This is a method in which a liquid film is applied, the ink liquid film is pre-dried, and then a relief plate having a required image pattern as a recess is pressed against the ink liquid film to transfer an excess pattern to the plate protrusion. The precision pattern printing method according to any one of claims 1 to 4.

  In the invention according to claim 6, the alignment of the partition pattern provided in advance on the substrate to be printed and the ink pattern on the ink peelable film substrate is the same as that of the substrate to be printed and the ink peelability. The film base material is arranged in parallel while maintaining a distance of 20 μm to 500 μm, and alignment of both base materials is performed based on an image observed using an optical device. It is the printing method of the precision pattern as described in a crab.

  The invention according to claim 7 is an ink in which the shape of the area partitioned by the partition wall pattern is reduced by 5% to 10% in at least one direction as an ink pattern having a smaller area than the area partitioned by the partition wall pattern. The pattern printing method according to claim 1, wherein a pattern is used.

  The invention according to claim 8 uses a dot pattern composed of a plurality of areas for one area as an ink pattern having an area smaller than that of the area partitioned by the partition wall pattern. 8. The precision pattern printing method according to any one of claims 1 to 7, wherein the amount of ink to be transferred is adjusted by a pattern density consisting of the number.

  The invention according to claim 9 is characterized in that the ink peelable film substrate is formed by laminating a silicone resin layer on a transparent film substrate. It is the printing method of the precision pattern as described in a crab.

  The invention described in claim 10 is characterized in that a glass plate or a resin plate is used as a relief plate for removing the pre-dried ink film. It is.

  Further, in the invention described in claim 11, the method of providing the partition pattern in advance on the substrate to be printed is provided by applying an ink liquid film for the partition pattern on the ink peelable film substrate. After the ink liquid film has been pre-dried, a relief printing plate having a required image pattern as a recess is pressed against the ink liquid film, and an excess pattern is transferred to the plate projection, and then the ink peelable film substrate The method for printing a precision pattern according to any one of claims 1 to 10, wherein the ink liquid film forming the partition pattern formed on the substrate is transferred to the substrate to be printed.

  A printing method in which ink is selectively disposed in a region partitioned by a partition pattern provided in advance on a substrate to be printed, and the partition pattern has ink repellency, so that the ink on the top surface of the partition pattern It is possible to suppress pattern overlap. Therefore, even when different ink patterns are successively formed in adjacent regions, the already formed ink pattern is printed without being affected by surface irregularities because there is no overlap with the upper surface of the partition wall. It is possible to obtain a high-definition pattern printed matter without color mixing, unevenness, and ink pattern omission.

  A method of obtaining an ink pattern with an area smaller than the area partitioned by the partition pattern on the ink-releasable film substrate by applying an ink liquid film on the ink-releasable film substrate, After drying, press the relief printing plate with the required image pattern as a depression on the ink film, and transfer the excess pattern to the relief on the printing substrate. Can be transferred into the barrier rib pattern, and a printed matter with less pattern bleeding and unevenness can be obtained.

  The alignment of the partition pattern provided in advance on the substrate to be printed and the ink liquid film pattern on the ink peelable film substrate allows the distance between 20 μm and 500 μm between the substrate to be printed and the ink peelable film substrate. Keeping them parallel to each other and aligning both substrates based on images observed using an optical device such as a camera can accurately align the partition pattern on the substrate to be printed. It has become possible.

  By using a pattern in which the shape of the area partitioned by the partition wall pattern is reduced as the ink pattern having a smaller area than the area partitioned by the partition wall pattern, and adjusting the amount of ink transferred according to the thickness of the ink pattern, the partition wall pattern The alignment accuracy margin can be expanded, and the ink liquid film can be provided in the partition pattern without any unevenness.

  By using a plurality of dot patterns as the ink pattern of an area smaller than the area partitioned by the partition pattern, by adjusting the amount of ink transferred by the pattern density consisting of the film thickness, area and number of dot patterns, The margin of alignment accuracy with the partition wall pattern is widened, and an ink liquid film having a predetermined film thickness can be provided in the partition wall pattern.

  By providing a silicone resin layer on a transparent film base material as an ink peelable film base material, it is possible to facilitate the alignment of the transfer pattern and to provide an inexpensive printing method.

  By using a plate made of glass or resin as a relief plate for removing the pre-dried ink film, a fine pattern can be stably obtained.

  As a method of providing a partition pattern in advance on a substrate to be printed, an ink liquid film for a partition pattern is applied on an ink peelable film substrate, and after the ink liquid film is pre-dried, a necessary image pattern Is pressed against the ink liquid film, the excess pattern is transferred to the plate convex part, and then the ink liquid film forming the partition pattern formed on the ink peelable film substrate is coated with the ink liquid film. By using a method of transferring to a printing substrate, it has become possible to provide a printing method that is cheaper than conventional methods.

It is a figure explaining the structure of the ink peelable film base material. It is a figure explaining the formation process of the partition pattern by the printing method using an ink peelable film base material. It is explanatory drawing of the partition pattern which has the ink-repellent upper surface part formed on the to-be-printed base material. It is a figure explaining the transfer process of the ink liquid film pattern to the to-be-printed base material in which the partition pattern was formed.

  The precision pattern printing method according to the present invention will be described below with reference to FIGS. 1 to 4 and will be described according to an actual printing process. However, the present invention is not limited thereto.

  The film substrate 11 used in the present invention can be processed and used as a flexible substrate such as plastic. For example, films and sheets of polyethylene terephthalate, polyethylene naphthalate, polyether sulfone, cycloolefin polymer, polyimide, nylon, aramid, polycarbonate, polymethyl methacrylate, polyvinyl chloride, triacetyl cellulose, and the like can be used. Further, by using a light-transmitting substrate, alignment can be facilitated during pattern superposition.

  As shown in FIG. 1, the ink peelable film substrate 10 used in the present invention is coated with a release agent represented by silicone oil and silicone varnish as the ink peelable silicone layer 12 on the surface of the film substrate 11. Alternatively, a thin film layer of silicone rubber may be formed. For the same purpose, fluorine-based resins and fluorine-based rubbers may be used, or the fluororesin fine powder may be mixed with silicone rubber or ordinary rubber to obtain releasability.

  These silicone-based coatings usually have low adhesion to the film substrate 11, but the film substrate 11 is preliminarily used as an adhesive resin layer (anchor layer) with a thermosetting or ultraviolet curable acrylic resin, epoxy resin, or the like. It can also be provided above.

  In any case, it is desirable that a uniform ink liquid film can be formed at the time of ink coating, and at the same time, the ink liquid film that has been coated once has complete ink peelability.

  Specific silicones include dimethylpolysiloxanes with various molecular weights, other methylhydropolysiloxanes, methylphenylsilicone oils, methylchlorinated phenylsilicone oils, or copolymers of these polysiloxanes with organic compounds. Can be used.

  Silicone rubber is a combination of two-component diorganopolysiloxane and a tri- or higher functional silane as a crosslinking agent, or a combination of siloxane and a curing catalyst, or one-component diorganopolysiloxane, acetone oxime, and various methoxys. Combinations of silane, methyltriacetoxysilane, and the like are used, and other polysiloxanes for adjusting rubber hardness are appropriately used.

  The ink releasability with respect to the ink releasable film substrate 10 thus obtained is preferably such that the contact angle when the ink is dropped onto the treated surface is 10 ° or more and 90 ° or less, more preferably 20 ° or more. 70 ° or less. If this contact angle is small, ink releasability in the subsequent process is reduced and pattern defects (such as poor reproducibility) are likely to occur. If the contact angle is large, repelling occurs when forming the ink liquid film, It becomes difficult to form a uniform ink liquid film.

  As a method for forming an ink liquid film on the ink releasable film substrate 10 shown above, a known coating method can be used depending on the viscosity of the ink and the drying property of the solvent. For example, dipping method, roll coating, gravure coating, reverse coating, air knife coating, comma coating, die coating, screen printing method, spray coating, gravure offset method and the like can be mentioned. Among them, a coating method such as die coating, cap coating, roll coating, and applicator can form a uniform ink liquid film for inks having a wide range of viscosity.

  After forming an ink liquid film on the ink peelable film substrate 10 by the above method, the ink liquid film is preliminarily dried. For this preliminary drying, natural drying, cold / hot air drying, microwave, reduced pressure drying, or the like can be used, and radiation such as ultraviolet rays or electron beams can also be used.

  This preliminary drying is intended to increase the viscosity, thixotropy and brittleness of the ink liquid film, and does not completely dry the ink liquid film. When the drying is insufficient, the ink liquid film is torn and a defect occurs when the convex portion of the ink removal plate described in a later step is pressed and peeled off. Furthermore, the pattern is greatly crushed during transfer to the partition pattern, and the partition protrudes.

  On the other hand, when the drying is excessive, the ink is not transferred to the ink removing plate. Further, when transferring to a position surrounded by the partition wall pattern, the pattern is not crushed so that the ink cannot be provided uniformly. Therefore, the dry state is adjusted according to the composition of the ink used.

  After the ink liquid film has been pre-dried, the ink liquid film is pressed against an ink removal plate (letter plate) having a required image pattern as a recess, and the excess ink liquid film is transferred to the ink removal plate, so that the ink liquid film pattern Form.

  As an ink removal plate, a mask pattern is formed on a surface of a low expansion glass such as an alkali-free glass using a photosensitive resin, and then an existing dry etching process, a wet etching process, or a sand blasting process is used. A plate provided with a plate depth can be used. If the plate depth is too small, the ink liquid film contacts the plate bottom and the pattern cannot be reproduced. If the plate depth exceeds a certain level, the shape of the obtained pattern is not changed, but there is a problem that the pattern provided on the plate cannot be made high resolution.

  The ink removal plate may be made of nylon, acrylic, silicone resin, styrene-diene copolymer or the like. Also, rubber plates such as ethylene-propylene, butyl, and urethane rubbers can be used. Such resin-made ink removal plates are already used for relief printing and flexographic printing, and can be produced by pouring a predetermined resin into a previously produced mold or by engraving, A method using a photosensitive resin can be manufactured with higher accuracy.

  When the partition pattern of the substrate to be printed is formed using the above printing method, an ink removal plate for the partition pattern is prepared in addition to the ink removal plate for the pixel pattern.

  As a method for forming the partition wall pattern on the substrate to be printed, a printing method by transfer from the above-described ink peelable film substrate can be used.

  When the partition wall pattern has an upper surface portion and a lower portion, and the partition wall pattern having ink repellency is formed only on the partition wall pattern upper surface portion 21, first, as shown in FIG. After coating the material 10 with an ink added with an ink repellent agent which becomes the upper surface portion of the partition wall pattern, the ink liquid film 21 which becomes the upper surface portion of the formed partition wall pattern is preliminarily dried.

  As shown in FIG. 2 (b), an ink which becomes the lower part of the partition pattern is coated on the ink peelable film substrate 10 on which the ink liquid film 21 which becomes the upper part of the partition pattern is uniformly pre-dried. After laminating the ink liquid film 22 which becomes the lower part of the partition pattern on the ink liquid film 21 which becomes the upper surface part of the pattern, the ink liquid film 22 which becomes the lower part of the partition pattern is preliminarily dried.

  As shown in FIGS. 2 (c) and 2 (d), the ink removing plate 40 is pressed against the ink peelable film substrate 10 on which the ink liquid film to be a partition pattern is formed, and the unnecessary ink liquid film is removed by ink. The ink is transferred to the plate 40, and a partition pattern ink liquid film 23 is formed on the ink peelable film substrate 10. The partition pattern ink liquid film 23 is composed of the ink liquid film 21 that is the upper surface portion of the partition pattern and the ink liquid film 22 that is the lower portion of the partition pattern.

  As shown in FIG. 3, the partition pattern ink liquid film 23 composed of the ink liquid film 21 that is the upper surface portion of the formed partition pattern and the ink liquid film 22 that is the lower part of the partition pattern is transferred to the printing substrate 30. In addition, it is possible to form a partition wall pattern 20 including a partition wall pattern upper surface portion whose upper surface portion has ink repellency and a lower partition wall pattern lower portion having no ink repellency on the substrate 30 to be printed.

  Further, as a method for forming the partition wall pattern 20 on the substrate to be printed 30, a known patterning technique using a photolithography method can be used.

  In order to form a barrier rib pattern having an upper surface portion and a lower portion, and the barrier rib pattern upper surface portion having a higher ink repellency than the lower portion by photolithography, first, the barrier rib pattern is formed on the substrate to be printed. After the lower part is formed, patterning by photolithography is performed again to form the partition wall pattern upper surface part.

  In such a method, in order to form a pattern with the same design on one substrate to be printed, two photolithography steps are required, and when the upper surface portion of the partition wall pattern is laminated and formed, Therefore, high accuracy is required for alignment.

  The film thickness of the partition wall pattern previously provided on the side of the substrate to be printed is preferably 0.8 μm to 2.0 μm, which has both light shielding properties and ink acceptability. When the film thickness is 2.0 μm or more, the linearity of the pattern end face cannot be reproduced during patterning by the ink removal plate.

  On the other hand, when the pixel pattern is finally pressed against the substrate to be printed, the ink film thickness, pattern shape, pattern area, and dot density are selected so as not to protrude from the partition pattern, and an ink removal plate is produced. I can do it.

  Although the pixel pattern depends on the pre-dried state of the ink liquid film, a similar pattern having a small area of 5 to 10% with respect to the opening pattern prepared by the partition wall pattern can be used.

  By reducing the pre-drying of the ink liquid film at the time of transfer, the collapse of the patterned ink film at the time of transfer increases, so the pixel pattern can be reduced accordingly, but there is a concern that the ink spreads over the partition pattern is there. On the other hand, by providing a large amount of preliminary drying, the spread due to crushing can be reduced, but the overlay accuracy with the partition wall pattern is required.

  In addition to the similar shape of the opening pattern prepared by the partition wall pattern, the pixel pattern can be filled with small dot patterns (a plurality of circles and polygons). In this case, in addition to the ink film thickness and the dot shape, the dot density with respect to the opening can be adjusted between 80% and 95%.

  In this way, the formed ink liquid film pattern is fixed in parallel to the substrate to be printed on which the partition wall pattern is formed, and the fine position of the ink liquid film pattern is determined based on the mutual pattern and the alignment pattern provided on the substrate. After the adjustment, the ink liquid film pattern on the ink peelable film substrate is transferred to the substrate to be printed.

  As shown in FIG. 4, if the ink liquid film pattern 50 formed on the ink peelable film substrate 10 is a colored ink for a pixel pattern, the ink peelable film substrate 10 is preliminarily attached to the partition pattern 20. The ink liquid film pattern 50 is transferred onto the substrate to be printed 30 after being arranged in parallel to the formed substrate to be printed 30 and aligning the two substrates.

  The distance between the ink peelable film substrate 10 and the substrate 30 to be printed at the time of alignment does not cause contact with the substrate due to charging or adsorption of the ink peelable film substrate 10, and the alignment. In consideration of the depth of field and focus control of the observation camera used in the above, it is preferable to arrange them in parallel while maintaining a distance of 20 μm to 500 μm.

  As the ink used for the partition pattern and the coloring pattern, an ink in which a pigment component and a resin component are dissolved and dispersed in a solvent can be used.

  Examples of the pigment include the following pigments that can be used in red, green, and blue colors. The type of pigment is a color index (CI) No. It shows with. 97, 122, 123, 149, 168, 177, 180, 192, 208, 209, 215, etc. as red pigments, 7, 36, etc. as green pigments, 15, 15: 1, 15: 3 as blue pigments. 15: 6, 22, 60, 64, and the like. Examples of black pigments include carbon black and titanium black. Further, in order to improve the color adjustment of these red, green and blue pigments and the fluidity of the ink, the following pigments can be added in necessary amounts.

  Besides red, green, and blue, for example, yellow pigments such as 17, 83, 109, 110, and 128, purple pigments such as 19, 23, and white pigments such as 18, 21, 27, and 28, etc. Examples of the orange pigment include 38 and 43. In addition to the simple substance, the pigment may be a pigment dispersion in which the pigment is previously dispersed in a dispersant or an organic solvent.

  Moreover, as a black pigment used for a partition pattern, carbon black and titanium black are used individually or in mixture.

  As the resin component of the ink, one or more selected from the group consisting of polyester resins, acrylic resins, epoxy resins, melamine resins, and benzoguanamine resins are used.

  Further, ester solvents, alcohol solvents, ether solvents, hydrocarbon solvents, and the like are used as the solvent. As ester solvents, propylene glycol monomethyl ether acetate, ethoxyethyl propionate, and alcohol solvents, 1-butanol, 3 methoxy-3-methyl-1-butanol, 1-hexanol, 1,3 butanediol, 1-pentanol, 2 -Methyl 1-butanol, 4-methyl-2-pentanol, ether solvents such as propylene glycol monomethyl ether, propylene glycol monoethyl ether, propylene glycol tertiary butyl ether, dipropylene glycol monomethyl ether, ethylene glycol butyl ether, ethylene glycol ethyl As ether, ethylene glycol methyl ether, diethylene glycol butyl ether, diethylene glycol ethyl ether, hydrocarbon solvents Solvesso 100, Solvesso 150 (trade name, manufactured by Exxon Chemical Co., Ltd.) and the like.

  Organic compounds that impart ink repellency to the partition pattern include those having silicon atoms and / or fluorine atoms that have a low affinity for the resin contained in the partition pattern ink, such as silanes containing siloxane groups or fluorine atoms. It is preferable to use a coupling agent.

  Examples of the compound that can be preferably used for imparting the first ink repellency include, but are not limited to, long-chain fluoroalkylsilanes, hydrolyzable group-containing siloxanes, fluoroalkyl group-containing oligomers, and the like. Absent.

  As a method for imparting ink repellency to the partition wall pattern, the silane coupling agent can be added to the ink component used for forming the partition wall pattern.

  The silane coupling agent selected for forming the partition pattern having ink repellency varies depending on the ink used, but such as methyltrimethoxysilane, n-hexyltrimethoxysilane, n-octyltrimethoxysilane, dodecyltrimethoxysilane, etc. Alkylsilane coupling agents are preferred.

  The precision pattern printing method of the present invention can be applied to printing on glass or plastic plates. For example, polyethylene terephthalate (PET), polyethylene naphthalate (PEN), polyethersulfone, cycloolefin polymer, polyimide, nylon Films and sheets of aramid, polycarbonate, polymethyl methacrylate, etc. can also be used. What is necessary is just to select according to the drying and hardening conditions of the ink applied to printing, and polyethylene naphthalate, polyether sulfone, cycloolefin polymer, a polyimide, etc. are suitable as a heat resistant thing.

  Moreover, the base material which consists of material which added the inorganic filler to resin and improved heat resistance may be sufficient. The film and sheet may be a stretched film or an unstretched film, and the flexible substrate is laminated with a gas barrier layer, a smoothing layer, or an ink image-receiving layer on the printing surface or other surface as necessary. May be.

  Hereinafter, the present invention will be described in more detail with reference to examples. However, the present invention is not limited to these examples.

  The CF produced in practice was produced on a 300 mm □ glass substrate, and had a pattern in which an opening portion of 80 μm × 300 μm openings continuously partitioned by a BM width of 20 μm was formed in the central portion of the substrate at 150 mm □.

(Ink peelable film substrate)
As an ink peelable film substrate, a silicone-based release polyester film: K1504 (manufactured by Toyobo Co., Ltd.) having a substrate thickness of about 120 μm was prepared in a roll shape of 300 mm width and 500 m.

(Preparation of the ink for the top surface of the partition pattern having ink repellency)
10 parts by weight of polyimide precursor (“Semicofine SP-510” manufactured by Toray Industries, Inc.), 7.5 parts by weight of carbon black, 130 parts by weight of solvent (N-methylpyrrolidone), 5 parts by weight of dispersant (copper phthalocyanine derivative), light A partition wall pattern ink was prepared by dispersing 5 parts by weight of an initiator and 0.5 parts by weight of an ink repellent (polyalkylsiloxane) for 3 hours while cooling with a bead mill disperser.

(Preparation of partition wall pattern ink)
10 parts by weight of polyimide precursor (“Semicofine SP-510” manufactured by Toray Industries, Inc.), 7.5 parts by weight of carbon black, 130 parts by weight of solvent (N-methylpyrrolidone), 5 parts by weight of dispersant (copper phthalocyanine derivative), light A partition wall pattern ink was prepared by dispersing 5 parts by weight of an initiator for 3 hours while cooling with a bead mill disperser.

(Preparation of partition pattern substrate)
On the ink-peeling film substrate, the ink for the partition pattern upper surface part having ink repellency is applied to a 200 mm square using a die coat, preliminarily dried at 120 ° C. for 60 seconds, and then the partition pattern lower part ink. And pre-dried at 120 ° C. for 120 seconds.

  Next, after pressing the ink removing plate in which the partition wall pattern becomes a concave portion against the ink stripping film substrate, the partition pattern is formed on the ink stripping film substrate by peeling.

  After the partition pattern on the ink peelable film substrate was transferred to the glass substrate, post-baking was performed at 230 ° C. for 1 hour in an oven to form a partition pattern. The partition wall thickness was 1.0 μm.

(Preparation of colored ink)
First, 20 parts by weight of methacrylic acid, 10 parts by weight of methyl methacrylate, 55 parts by weight of butyl methacrylate and 15 parts by weight of hydroxyethyl methacrylate are dissolved in 100 parts by weight of butyl lactate, and 0.75 parts by weight of azobisisobutylnitrile is added in a nitrogen atmosphere. In addition, an acrylic copolymer resin was obtained by a reaction at 70 ° C. for 5 hours. The obtained acrylic copolymer resin was diluted with propylene glycol monomethyl ether acetate so that the resin concentration was 20% to obtain an acrylic resin varnish.

  As a colored dispersion, C.I. I. Pigment Red 254 (“Ilgar Forred B-CF” manufactured by Ciba Specialty Chemicals) 18 parts by weight, C.I. I. 2 parts by weight of Pigment Red 177 (“Chromophthal Red A2B” manufactured by Ciba Specialty Chemicals) and 108 parts by weight of the acrylic resin varnish (solid content: 20%) were sufficiently mixed.

  100 parts by weight of the above dispersion, 20 parts by weight of methylated methylol melamine MW-30 (manufactured by Sanyo Kasei Co., Ltd.), 1 part by weight of Mega-Fac F-483SF (manufactured by DIC) as a leveling agent, and propylene glycol monomethyl ether 85 as a diluent Weight parts were mixed to obtain a colored ink.

  First, after the said ink peelable film base material was conveyed from the roll and fixed on the adsorption table, coloring ink was applied to 200 mm □ using the die coat.

  The colored ink was dried at room temperature for 2 minutes and then dried in an oven at 70 ° C. for 2 minutes at a conveyance speed of 10 mm / s.

  Next, the ink removal plate having a colored pattern as a concave portion and the ink film surface of the ink peelable film substrate face each other in parallel, and then pressed with a rubber roller.

  The ink removing plate is a 300 mm square glass plate provided with a pattern having a plate depth of 10 μm. In order to make the area smaller than the opening provided in the partition wall pattern, both the long side and the short side are 76 μm shorter by 5%. A rectangular continuous pattern of × 285 μm was used.

  Next, the ink peelable film base material was peeled from the glass ink removal plate at a uniform speed of 30 mm / s, and a pixel pattern was obtained on the ink peelable film base material.

  In addition, the ink peelable film substrate on which the image pattern is formed is faced in parallel in the same manner on the glass substrate on which the partition wall pattern is provided, and is positioned with reference to the alignment mark provided outside the pixel pattern. After the alignment, pressurization with a rubber roller was performed to transfer the pixel pattern to the glass substrate side.

  After the obtained glass substrate was cured at 210 ° C. for 20 minutes, it was observed with a microscope, and it was confirmed that the pixel pattern portion did not leak light or ooze out to the adjacent opening.

  The printing method of the present invention can stably perform high-definition patterning on a flexible substrate such as a glass substrate or a plastic film, and is a display-related member mainly composed of a color filter (CF). It can be used for the manufacture of electronics components.

DESCRIPTION OF SYMBOLS 10 ... Ink peelable film base material 11 ... Film base material 12 ... Ink peelable silicone layer 20 ... Partition pattern 21 ... Ink liquid film used as upper surface part of partition pattern 22 ... Ink liquid film below the partition pattern 23... Partition pattern ink liquid film 24... Partition pattern upper surface portion 25... Partition wall pattern lower portion 30... Printed substrate 40.・ Ink liquid film pattern

Claims (11)

In order to selectively dispose ink in a region partitioned by a partition pattern provided in advance on a substrate to be printed, an area smaller than the region partitioned by the partition pattern on the ink peelable film substrate After forming an ink pattern and aligning the partition pattern on the substrate to be printed, the ink is uniformly spread and provided in an area partitioned by the partition pattern by pressure transfer. In the precision pattern printing method,
A method for printing a precision pattern, wherein the partition pattern has ink repellency.   2. The precision pattern printing method according to claim 1, wherein a material having silicon atoms is used as a material for imparting ink repellency to the partition wall pattern.   2. The precision pattern printing method according to claim 1, wherein a material having fluorine atoms is used as a material for imparting ink repellency to the partition wall pattern.   The partition wall pattern has an upper surface portion and a lower portion other than the upper surface portion, and the ink repellency of the partition wall pattern upper surface portion is larger than the ink repellency of the partition wall pattern lower portion. A method of printing a precision pattern according to crab.   A method of obtaining an ink pattern having an area smaller than the area partitioned by the partition pattern on the ink peelable film substrate by coating an ink liquid film on the ink peelable film substrate, 5. The method according to claim 1, wherein after the liquid film is pre-dried, a relief plate having a required image pattern as a recess is pressed against the ink liquid film, and an excess pattern is transferred to the plate projection. The printing method of the precision pattern in any one.   The alignment of the partition pattern provided in advance on the substrate to be printed and the ink pattern on the ink peelable film substrate is such that the substrate to be printed and the ink peelable film substrate have a distance of 20 μm to 500 μm. The method for printing a precision pattern according to any one of claims 1 to 5, wherein the printing method is carried out based on an image which is arranged in parallel while being maintained, and the alignment of both substrates is observed using an optical device.   2. The ink pattern obtained by reducing the shape of the area partitioned by the partition wall pattern by 5% to 10% in at least one direction is used as the ink pattern having a smaller area than the area partitioned by the partition wall pattern. The printing method of the precision pattern in any one of -6.   As the ink pattern having a smaller area than the area partitioned by the partition pattern, a plurality of dot patterns are used for one area, and the amount of ink transferred by the pattern density consisting of the thickness, area and number of dot patterns. The method for printing a precision pattern according to any one of claims 1 to 7, characterized in that the adjustment is performed.   The method for printing a precision pattern according to any one of claims 1 to 8, wherein the ink-peelable film substrate is formed by laminating a silicone resin layer on a transparent film substrate.   6. The precision pattern printing method according to claim 5, wherein a glass plate or a resin plate is used as a relief plate for removing the pre-dried ink liquid film.   The method of providing the partition pattern in advance on the substrate to be printed is provided by applying an ink liquid film for the partition pattern on the ink peelable film substrate, and preliminarily drying the ink liquid film. The ink which forms the partition pattern formed on the ink-peeling film substrate after pressing the relief plate with the required image pattern as a recess against the ink liquid film and transferring the excess pattern to the relief plate The method for printing a precision pattern according to claim 1, wherein the liquid film is transferred to the substrate to be printed.

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