JP2010183922A - Flour paste - Google Patents

Flour paste Download PDF

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JP2010183922A
JP2010183922A JP2010128474A JP2010128474A JP2010183922A JP 2010183922 A JP2010183922 A JP 2010183922A JP 2010128474 A JP2010128474 A JP 2010128474A JP 2010128474 A JP2010128474 A JP 2010128474A JP 2010183922 A JP2010183922 A JP 2010183922A
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parts
soybean protein
acid
soluble soybean
texture
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Inventor
Isao Ochi
勇生 越智
Shigeru Ashida
茂 芦田
Jiro Kanamori
二朗 金森
Yukari Nakano
由香理 中野
Kenji Taguchi
賢司 田口
Atsushi Ono
敦史 大野
Tsutomu Saito
努 齋藤
Eiji Iwaoka
栄治 岩岡
Junichi Noguchi
淳市 野口
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Fuji Oil Co Ltd
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Fuji Oil Co Ltd
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Priority to JP2010128474A priority Critical patent/JP2010183922A/en
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    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D2/00Treatment of flour or dough by adding materials thereto before or during baking
    • A21D2/08Treatment of flour or dough by adding materials thereto before or during baking by adding organic substances
    • A21D2/24Organic nitrogen compounds
    • A21D2/26Proteins
    • A21D2/264Vegetable proteins
    • A21D2/266Vegetable proteins from leguminous or other vegetable seeds; from press-cake or oil bearing seeds
    • AHUMAN NECESSITIES
    • A21BAKING; EDIBLE DOUGHS
    • A21DTREATMENT, e.g. PRESERVATION, OF FLOUR OR DOUGH, e.g. BY ADDITION OF MATERIALS; BAKING; BAKERY PRODUCTS; PRESERVATION THEREOF
    • A21D13/00Finished or partly finished bakery products
    • A21D13/06Products with modified nutritive value, e.g. with modified starch content
    • A21D13/064Products with modified nutritive value, e.g. with modified starch content with modified protein content
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L11/00Pulses, i.e. fruits of leguminous plants, for production of food; Products from legumes; Preparation or treatment thereof
    • A23L11/05Mashed or comminuted pulses or legumes; Products made therefrom
    • A23L11/07Soya beans, e.g. oil-extracted soya bean flakes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L29/00Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/212Starch; Modified starch; Starch derivatives, e.g. esters or ethers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/101Addition of antibiotics, vitamins, amino-acids, or minerals
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/109Types of pasta, e.g. macaroni or noodles
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/109Types of pasta, e.g. macaroni or noodles
    • A23L7/11Filled, stuffed or multilayered pasta
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/117Flakes or other shapes of ready-to-eat type; Semi-finished or partly-finished products therefor
    • A23L7/13Snacks or the like obtained by oil frying of a formed cereal dough
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L7/00Cereal-derived products; Malt products; Preparation or treatment thereof
    • A23L7/10Cereal-derived products
    • A23L7/157Farinaceous granules for dressing meat, fish or the like
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Nutrition Science (AREA)
  • Polymers & Plastics (AREA)
  • Agronomy & Crop Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • Zoology (AREA)
  • Botany (AREA)
  • Molecular Biology (AREA)
  • General Health & Medical Sciences (AREA)
  • Bakery Products And Manufacturing Methods Therefor (AREA)
  • Noodles (AREA)
  • Confectionery (AREA)
  • Grain Derivatives (AREA)
  • Seeds, Soups, And Other Foods (AREA)
  • General Preparation And Processing Of Foods (AREA)
  • Cereal-Derived Products (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide acidic flour paste having favorable flavor, smooth palate feeling and good meltability in the mouth. <P>SOLUTION: The flour paste which achieves these purposes is produced by adding acidic and soluble soybean protein to starchy raw material. The addition of the acidic and soluble soybean protein preferably accounts for 50 wt.% based on the starchy raw material. The flour paste preferably has pH 3.5 to 5.9. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

この発明は、澱粉性食品素材若しくは澱粉性食品に関するものである。   The present invention relates to a starchy food material or a starchy food.

小麦粉、米粉、または澱粉をボディーの主原料にした混捏生地(ドウ)を、焙焼などの加熱を行って得る焼き菓子や、同じく混捏生地を発酵させ、焼成を行って得るパン、同じく混捏生地を蒸しあげて得られるうどん、中華麺などの麺類の食品は、世界中でポピュラーな澱粉性食品の例である。このような澱粉性食品の食感を改良する方法の一つに、蛋白素材を添加することが公知であるが、従来より用いられている蛋白素材では、生地中での分散性が悪く、十分な効果が得られない、といった問題点が指摘されており、使用するたん白素材の平均粒子径を気流粉砕や凍結粉砕により格別小さくすることが提案されている(特許文献1)。そこにおいて澱粉性食品の品質改良の目標は、菓子またはパンの食味を損なうことなく、蒸しもの類は、ふっくらとした食感で、舌触り及び口溶けが良く、焼き菓子類は、サクサクとしてしっかりした食感であるが、中はソフトで口溶けが良く、ケーキ類は、パサパサせずにふわっとした食感でしっとりしており、パン類などにおいては、表面はサクサクとして歯切れが良く、ソフトで口溶けの良い食感で、ボリューム感などの外観にも優れており、保管中にも老化しにくい菓子またはパンを提供することであった。   A baked confectionery made from wheat flour, rice flour, or starch, the main ingredient of the body being heated, such as roasting, baked confectionery obtained by fermenting the kneaded dough and baking, and the same kneaded dough Noodles such as noodles and Chinese noodles obtained by steaming rice are examples of starchy foods that are popular all over the world. As one of the methods for improving the texture of such starchy foods, it is known to add a protein material. However, conventionally used protein materials have poor dispersibility in the dough, and are sufficient. It has been suggested that the average particle size of the protein material to be used is significantly reduced by airflow pulverization or freeze pulverization (Patent Document 1). Therefore, the goal of improving the quality of starchy foods is that the flavor of the confectionery or bread is not impaired, the steamed food has a fluffy texture, good touch and melts, and the baked confectionery has a solid texture. However, the inside is soft and melts in the mouth, and the cakes are moist with a fluffy texture without being crispy, and in bread etc. the surface is crispy and crispy, soft and meltable It was to provide a confectionery or bread that is excellent in appearance such as voluminous feel and that does not age easily during storage.

また澱粉性食品素材を食品表面の衣材(バッター)とする、フライ食品の製造において、フライ直後の食感のサクサクした或いはクリスピーな食感を可及的長く維持させようとする課題、或いは冷凍・冷蔵後電子レンジで調理した場合でも、製造直後のものと同様のサクサクした或いはクリスピーな食感を味わうことができることを課題として、やはりたん白素材を添加することが行われている(例えば特許文献2)。   In addition, in the production of fried foods, where starchy food materials are used as food materials (batters), the problem of maintaining a crispy or crispy texture immediately after frying as long as possible, or freezing -Even when cooked in a microwave oven after refrigeration, protein materials are added as a problem because it can taste the same crispy or crispy texture as that immediately after manufacture (for example, patents) Reference 2).

さらに、春巻きの皮や餃子の皮も、フライ若しくは焼成後に長時間放置された場合に皮のパリパリ感を失わず歯ざわりのよい食感を維持する課題があり、やはり大豆たん白の使用が検討されている(特許文献3)。   In addition, spring rolls and dumpling skins also have a problem of maintaining a crispy texture without losing the crispy texture when left for a long time after fried or baked, and soy protein is also being considered for use. (Patent Document 3).

一方、麺類に大豆たん白を使用すると、コシが強くなる一方で、しなやかさに欠け食感が悪化する傾向にあった。   On the other hand, when soybean protein is used for noodles, the firmness becomes strong, but the lack of flexibility tends to deteriorate the texture.

その他大豆たん白を澱粉性食品の品質改良に使用する試みは多数あるが、かかる提案の多さは、大豆たん白の使用が一定の改善効果があることと示すと同時に、なお改善の余地があることを示す。   There are many other attempts to use soy protein to improve the quality of starchy foods, but many of these proposals indicate that the use of soy protein has a certain improvement effect, and there is still room for improvement. Indicates that there is.

大豆たん白を澱粉性食品特に小麦粉を用いたベーカリー製品にしばしば遭遇する難点の一つは、製品塊容積の損失、外観の悪さが顕著化し、大豆たん白の中でも精製度が高まるに連れて製品塊容積の損失、外観の悪さが増大する傾向にあり、かといって低精製度の大豆たん白を使用すると大豆臭味を呈しやすい難点があり、このため、大豆たん白を油性物質と予め非加水系で混合してから小麦粉生地の成分とする方法が提案されている(特許文献4)。また大豆たん白を小麦粉生地と混合するのに大豆たん白の使用量が増すにつれ、生地の粘性が増し、小麦粉ドウを形成するのに作業性が低下する難点もあった。   One of the difficulties often encountered with soy protein in starchy foods, especially in bakery products using wheat flour, is the loss of product lump volume and poor appearance, and the soy protein is increasingly refined as the degree of purification increases. There is a tendency for the loss of lump volume and poor appearance to increase, and when using low-purity soy protein, there is a drawback that it tends to give a soy odor. There has been proposed a method of mixing with a water-based system and using it as a component of flour dough (Patent Document 4). In addition, as the amount of soy protein used is increased when mixing soy protein with flour dough, the viscosity of the dough increases, and there is a problem that workability is reduced in forming flour dough.

他方、大豆たん白は、一般にその等電点をpH4.5付近にもち、この付近の酸性領域において不溶性であり、不溶性であると十分に機能しない問題があったところ、酸性領域において溶解性を改善する方法が提案され、酸性領域で用いることが試みられている(特許文献5及び特許文献6)が、そのような大豆たん白の用途は酸性食品を主眼とするものであって、非酸性食品を意図したものはなく、また改善対象も全体として澱粉性食品とはいいがたいものであった。   On the other hand, soybean protein generally has an isoelectric point near pH 4.5, is insoluble in the acidic region in the vicinity, and has a problem that it does not function sufficiently when insoluble. Although the method of improving is proposed and it is tried to use in an acidic region (patent document 5 and patent document 6), the use of such soybean protein is mainly for acidic foods, and is non-acidic. None of the foods were intended, and the overall improvement was not a starchy food.

特開2002‐171897号JP 2002-171897 特開2002‐58437号JP 2002-58437 A 特開2002‐65192号JP 2002-65192 A 特開昭59‐118034号JP 59-118034 A 特公昭53‐19669号Japanese Patent Publication No.53-19669 WO 02/067690 A1WO 02/067670 A1

本発明者は、酸性食品ではない前記の澱粉性食品の製造において、pH4.5以下の酸性で可溶の大豆たん白を使用すると、その他の大豆たん白に比べて意外にも食感改良効果(水分活性により多少異なるが、AW約0.5以上の高水分乃至中間水分の焼成食品にあっては、ふっくらとした食感で、舌触り及び口溶けが良く、他方水分活性が低い焼き菓子類やトーストしたパンにあっては、サクサクとした軽い食感、うどんや中華麺にあっては適度な弾力を有するしなやかな食感)が増大し、従い少量使用ですむので、多量使用の場合の難点(製品塊容積の損失、外観の悪さ)や使い辛さ(作業性の低下)もよく軽減されることを見出し、この発明を完成するにいたった。   The present inventor unexpectedly improved the texture when using an acidic and soluble soybean protein having a pH of 4.5 or less in the production of the starchy food that is not an acidic food. (Although it varies slightly depending on the water activity, in the case of a baked food with a high or intermediate moisture of AW of about 0.5 or more, it has a fluffy texture, good touch and mouth melt, and on the other hand a low water activity baked confectionery For toasted bread, the texture is light and crunchy, and for udon and Chinese noodles, it has a moderate elasticity and a flexible texture. It has been found that (loss of product lump volume, poor appearance) and ease of use (decrease in workability) are alleviated, and the present invention has been completed.

すなわちこの発明は、
(1)澱粉性原料に酸性可溶大豆たん白を加配して得たフラワーペースト。
(2)澱粉性原料が、澱粉性穀粉、それから得られる澱粉若しくは加工澱粉、またはそれらの混合物を主材とするものである(1)に記載のフラワーペースト。
(3)酸性可溶大豆たん白が澱粉性原料に対して50重量%以下である、(1)記載のフラワーペースト。
(4)フラワーペーストのpHが3.5〜5.9である(1)記載のフラワーペースト
である。
That is, this invention
(1) A flour paste obtained by adding an acidic soluble soybean protein to a starchy raw material.
(2) The flour paste according to (1), wherein the starchy raw material is mainly composed of starchy flour, starch obtained from the starch, processed starch, or a mixture thereof.
(3) The flour paste according to (1), wherein the acid-soluble soybean protein is 50% by weight or less based on the starchy raw material.
(4) The flour paste according to (1), wherein the pH of the flour paste is 3.5 to 5.9.

この発明によって、少量の大豆たん白の使用で、澱粉性食品の食感改良、澱粉性食品の製造過程特に混合から成形にいたる過程においての作業性改善の効果が生じる。そして従来大豆たん白を多量に使用する場合の難点(製品塊容積の損失、外観の悪さ)や使い辛さ(作業性の低下)もよく軽減させることができる。   According to the present invention, the use of a small amount of soybean protein has the effect of improving the texture of starchy foods and improving the workability in the process of producing starchy foods, particularly from mixing to molding. And the difficulty (loss of product lump volume, bad appearance) and usability (decrease in workability) when using soy protein in a large amount can be well reduced.

この発明において用いる澱粉性原料は、公知のものでよく、小麦、米、コーン、馬鈴薯、タピオカ、米、キャッサバ、甘藷等の澱粉性穀粉、それらから得られる、小麦澱粉、コーンスターチ、馬鈴薯澱粉、タピオカ澱粉、米澱粉、キャッサバ澱粉、甘藷澱粉等の穀物澱粉類、並びにそれら穀物澱粉の酢酸エステル化、燐酸架橋、ヒドロキシプロピルエーテル化、オクテニルコハク酸エステル化、α化等の化学的あるいは物理的処理が施された加工澱粉、さらにはデキストリンを始めとして、難消化性デキストリン、分枝デキストリン等のデキストリン類が例示でき、それらの混合物も使用できる。   The starchy raw material used in the present invention may be a known one, and starchy flours such as wheat, rice, corn, potato, tapioca, rice, cassava, sweet potato, wheat starch, corn starch, potato starch, tapioca obtained therefrom. Cereal starches such as starch, rice starch, cassava starch, and sweet potato starch, and chemical or physical treatments such as acetate esterification, phosphoric acid crosslinking, hydroxypropyl etherification, octenyl succinate esterification, and alphatization of the grain starch Dextrins such as indigestible dextrin, branched dextrin, etc. can be exemplified, including processed starch, and dextrin, and mixtures thereof can also be used.

また、澱粉性原料が小麦粉のようにグルテンを含有する場合、とりわけ澱粉性原料中30重量%以上の小麦粉が含まれる場合や、これと同程度のグルテンを小麦粉以外の澱粉性原料例えば米粉と併用する場合は、グルテンの粘性と相俟って通常の大豆たん白を多量使用する場合のような難点すなわち、製品塊容積の損失、外観の悪さ、粘性増加による使い辛さ(作業性の低下)などを、よく軽減させることができる。   Also, when the starchy raw material contains gluten such as wheat flour, especially when the starchy raw material contains 30% by weight or more of wheat flour, or the same amount of gluten as used together with starchy raw materials other than wheat flour such as rice flour If this is the case, it is difficult to use a large amount of normal soybean protein in combination with the viscosity of gluten, that is, loss of product lump volume, poor appearance, and difficulty in use due to increased viscosity (decrease in workability). Etc. can be reduced well.

本発明において使用する酸性可溶大豆たん白は、pH4.0での溶解率が60%以上、好ましくは65%以上、より好ましくは80%以上、更に好ましくは90%以上のものが適しており、その部分加水分解物であってもよい。   The acid-soluble soybean protein used in the present invention has a solubility at pH 4.0 of 60% or more, preferably 65% or more, more preferably 80% or more, and still more preferably 90% or more. The partial hydrolyzate may be used.

*溶解率(%)はたん白の溶媒に対する可溶化の尺度であり、たん白粉末をたん白質分が5.0重量%になるように水に分散させ十分撹拌した溶液を、必要に応じてpHを調整した後、10,000G×5分間遠心分離した上清たん白の全たん白に対する割合をケルダール法、ローリー法等のたん白質定量法により測定する。 * Solution rate (%) is a measure of solubilization of protein in a solvent. If necessary, a solution in which protein powder is dispersed in water so that the protein content is 5.0% by weight is sufficiently stirred. After adjusting the pH, the ratio of the supernatant protein centrifuged at 10,000 G × 5 minutes to the total protein is measured by a protein quantification method such as Kjeldahl method or Raleigh method.

酸性可溶大豆たん白の製造法は種々あるが、大豆たん白質を含む溶液(豆乳、脱脂豆乳、分離大豆たん白の水溶液など)を、該たん白質の等電点のpHより酸性域で、100℃を越える温度で加熱処理する方法が好ましい。加熱品はその後乾燥することにより、自体でpH4.5よりも酸性であり、かつ、酸性で高い溶解率を持つ、酸性可溶大豆たん白粉末を得ることができる。   There are various methods for producing acidic soluble soy protein, but a solution containing soy protein (soy milk, defatted soy milk, aqueous solution of separated soy protein, etc.) is more acidic than the pH of the isoelectric point of the protein, A method of heat treatment at a temperature exceeding 100 ° C. is preferred. The heated product is then dried to obtain an acidic soluble soybean protein powder that is acidic by itself and has a higher dissolution rate than pH 4.5.

酸性可溶大豆たん白は、中でもWO02/67690号公報に公開されている製造法により得られたものが、pH4.5以下での溶解性が高くでき最も好ましい。その製造方法は、大豆たん白質を含む溶液において、(A)該溶液中の原料たん白質由来のポリアニオン物質を除去するか不活性化する処理、例えば大豆中のフィチン酸をフィターゼ等で分解除去する処理、又は(B)該溶液中にポリカチオン物質を添加する処理、例えばキトサンを添加する処理を行い、かかる(A)又は(B)いずれか若しくは両方の処理を行った後に、該たん白質の等電点のpHより酸性域で100℃を越える温度で該たん白質溶液を加熱処理することであり、通常その後乾燥する。   Among them, an acid-soluble soybean protein obtained by a production method disclosed in WO 02/67690 is most preferable because it has high solubility at pH 4.5 or lower. In the solution containing soybean protein, (A) a process of removing or inactivating the polyanionic substance derived from the raw material protein in the solution, for example, decomposing and removing phytic acid in soybean with phytase or the like Treatment, or (B) a treatment of adding a polycationic substance to the solution, for example, a treatment of adding chitosan, and after the treatment of either (A) or (B) or both, The protein solution is heat-treated at a temperature exceeding 100 ° C. in the acidic region from the pH of the isoelectric point, and usually dried thereafter.

本発明における酸性可溶大豆たん白は、部分分解物であってもよく、また、これ以外の窒素化合物である、酸性で難溶解性のたん白やたん白加水分解物、ペプチド、アミノ酸等を澱粉性食品素材若しくは澱粉性食品中に含むことを妨げない。   The acidic soluble soy protein in the present invention may be a partially decomposed product, and other nitrogen compounds, such as acidic and poorly soluble proteins, protein hydrolysates, peptides, amino acids and the like. Does not interfere with inclusion in starchy food materials or starchy foods.

酸性可溶大豆たん白は澱粉性原料に対して0.05から50重量%の広い範囲にわたって使用することができるが、同3重量%以下や2.5重量%以下の少量の範囲においても従来の大豆たん白をこれより多量に用いた場合に比べて十分優れた効果を発揮できる。上限の数値は目的により変化し、パンやケーキ等の膨化された製品では5重量%以下が好ましい。或いはフラワーペースト等澱粉性原料の使用量が系中に10重量%以下と少ない製品では、澱粉性原料当りの酸性可溶大豆たん白が50重量%以下の添加が好ましい。   Acid-soluble soybean protein can be used over a wide range of 0.05 to 50% by weight with respect to the starchy raw material, but also in the conventional small amount range of 3% or less or 2.5% or less. As compared with the case of using soy protein in a larger amount than this, a sufficiently excellent effect can be exhibited. The upper limit value varies depending on the purpose, and is preferably 5% by weight or less for expanded products such as bread and cakes. Alternatively, in a product in which the amount of starchy raw material such as flour paste used is as low as 10% by weight or less in the system, addition of 50% by weight or less of acidic soluble soybean protein per starchy raw material is preferable.

この発明は、酸性可溶大豆たん白を用いるからといって、澱粉性食品素材若しくは澱粉性食品が酸性である必要は全くなく、むしろ含水状態のpHで4.5〜9である澱粉性食品素材若しくは澱粉性食品に好適に用いることができ、最も通常にはpH5〜7.5の範囲にある。但し、鹹水を使用する中華麺では、pH7.5〜9が好適である。   This invention does not require the starchy food material or starchy food to be acidic at all because an acid-soluble soybean protein is used. Rather, it is a starchy food having a hydrous pH of 4.5 to 9. It can be suitably used for raw materials or starchy foods, and is most usually in the range of pH 5 to 7.5. However, for Chinese noodles using brine, pH 7.5-9 is preferred.

すなわち澱粉性食品は、ビスケット・クッキー類、ケーキ類、パン類、シューパフ、衣付けしたフライ食品、またはスナック食品、うどん、中華麺などの麺類であることができ、これらの分類に必ずしも判然と属するとは限らないその他の焼菓子、ベーカリー製品、例えばドーナツ、ホットケーキ、アメリカンドッグ、蒸し物例えば蒸パン、餡饅頭中の他、たこ焼き、お好み焼きなども包含する。またこれら澱粉性食品の素材である、澱粉性食品素材が、粉状、ドウ状、ペースト状、バッター状、または後三者の含気物であることができ、プレミックス、ミックス粉、打ち粉、バッター粉、春巻きの皮、餃子の皮、フラワーペーストなどの混合態様若しくは用途を付した名称の素材を包含する。   That is, starchy foods can be biscuits / cookies, cakes, breads, shoe puffs, dressed fried foods, or noodles such as snack foods, udon, and Chinese noodles, and they definitely belong to these categories. Other baked confectionery and bakery products such as donuts, hot cakes, American dogs, steamed products such as steamed bread, buns, takoyaki, okonomiyaki, etc. are also included. In addition, the starchy food material, which is a material of these starchy foods, can be powdery, doughy, pasty, battery, or the latter three components, premix, mixed powder, dusting , Batter powder, spring roll skin, dumpling skin, flour paste, etc.

澱粉性食品素材乃至澱粉性食品には、当該目的素材ないし目的食品の原料として公知の素材、添加物、及び水性原料を、公知の範囲で用いることができ、公知の方法で加工して得ることができる。例えば、油脂は動植物性油脂やその分別、硬化、もしくはエステル交換油、バター、マーガリンやショートニング、水中油型のクリーム類を例示でき、乳化剤は、レシチン、グリセリン脂肪酸エステル(グリセリン脂肪酸モノエステル、グリセリン脂肪酸ジエステル、グリセリン脂肪酸有機酸エステル)、ポリグリセリン脂肪酸エステル、蔗糖脂肪酸エステルなどが例示されるし、目的に応じた乳化剤を加配したいわゆる乳化油脂も販売されている。   In the starchy food material or starchy food, known materials, additives, and aqueous materials can be used in a known range as the target material or the raw material of the target food, and processed by a known method. Can do. For example, the fats and oils can be exemplified by animal and vegetable fats and oils, fractionated, hardened or transesterified oils, butter, margarine and shortening, oil-in-water creams, and the emulsifiers are lecithin, glycerin fatty acid esters (glycerin fatty acid monoesters, glycerin fatty acids). Examples include diesters, glycerin fatty acid organic acid esters), polyglycerin fatty acid esters, and sucrose fatty acid esters, and so-called emulsified oils and fats with an emulsifier according to the purpose are also available.

増粘剤や安定剤、或いは食物繊維等として、グアーガム、ローカストビーンガム、グルコマンナン、タマリンド種子ガム、プルラン、ポリデキストロース、難消化性デキストリン、グアーガム分解物、水溶性大豆多糖類、サイリウムシードガム、アラビアガム、アルギン酸プロピレングリコールエステル、寒天等が例示できる。膨張剤やかんすいとして炭酸水素アンモニウム、炭酸水素ナトリウム、それらを含むベーキングパウダーを用いることができる。水性原料の水は、水そのものの他、牛乳、酒類、卵などに由来してもよい。   As a thickener, stabilizer, or dietary fiber, guar gum, locust bean gum, glucomannan, tamarind seed gum, pullulan, polydextrose, indigestible dextrin, guar gum degradation product, water-soluble soybean polysaccharide, psyllium seed gum, Examples include gum arabic, propylene glycol alginate, and agar. Ammonium hydrogen carbonate, sodium hydrogen carbonate, and baking powder containing them can be used as the swelling agent and the rinsing. Aqueous raw material water may be derived from milk, alcoholic beverages, eggs and the like in addition to the water itself.

澱粉性原料に酸性可溶大豆たん白を添加する方法は、直接澱粉性原料と混合することに限定されず、酸性可溶大豆たん白が系中に分散できる方法であれば特に問題はない。例えば、澱粉性原料以外の粉体、油中水型乳化物、油脂等に予め分散したものや、水中油型乳化物に予め溶解したものを澱粉性原料に加えても良い。   The method of adding the acidic soluble soybean protein to the starchy raw material is not limited to mixing directly with the starchy raw material, and there is no particular problem as long as the acidic soluble soybean protein can be dispersed in the system. For example, powders other than starchy raw materials, water-in-oil emulsions, oils and fats previously dispersed, or those previously dissolved in oil-in-water emulsions may be added to the starchy raw materials.

加工は、澱粉性原料に酸性可溶大豆たん白を加配した、水性の生地を、醗酵もしくは醗酵せずして、焙焼、蒸し、マイクロ波加熱、フライなどの加熱を行い最終食品とされる。生地の状態または加熱の後に冷凍若しくは冷蔵の過程を経ることもできる。   Processing is done by adding acid-soluble soy protein to starchy raw materials, and then heating or baking a water-based dough, without fermenting or fermenting, and making it the final food. . It can also undergo freezing or refrigeration after the dough or heating.

以下、この発明の実施例を示すが、本発明がこれらによってその技術範囲が限定されるものではない。また、特にことわりのない限り%は重量%を、部は重量部を指す。   Examples of the present invention are shown below, but the technical scope of the present invention is not limited by these examples. Unless otherwise specified, “%” means “% by weight” and “part” means “part by weight”.

<製造例1>
大豆を圧扁し、n-ヘキサンを抽出溶媒として油を抽出分離除去して得られた低変性脱脂大豆(窒素可溶指数(NSI):91)5kgに35kgの水を加え、希水酸化ナトリウム溶液でpH7に調整し、室温で1時間攪拌しながら抽出後、4,000Gで遠心分離しオカラおよび不溶分を分離し、脱脂豆乳を得た。この脱脂豆乳をリン酸にてpH4.5に調整後、連続式遠心分離機(デカンター)を用い2,000Gで遠心分離し、不溶性画分(酸沈殿カード)および可溶性画分(ホエー)を得た。酸沈殿カードを固形分10重量%になるように加水し酸沈殿カードスラリーを得た。これをリン酸でpH3.5に調整した後、連続式直接加熱殺菌装置にて120℃15秒間加熱した。これを噴霧乾燥し酸性可溶大豆たん白粉末(以下Sと略す)を得た。このたん白の溶解率はpH4.0で61%であった。
<Production Example 1>
35 kg of water is added to 5 kg of low-denatured defatted soybean (nitrogen soluble index (NSI): 91) obtained by compressing soybean and extracting and removing oil using n-hexane as an extraction solvent. The solution was adjusted to pH 7 and extracted while stirring at room temperature for 1 hour, followed by centrifugation at 4,000 G to separate okara and insoluble matter to obtain skim soymilk. The defatted soymilk is adjusted to pH 4.5 with phosphoric acid and then centrifuged at 2,000 G using a continuous centrifuge (decanter) to obtain an insoluble fraction (acid precipitation card) and a soluble fraction (whey). It was. The acid precipitation card | curd was watered so that it might become 10 weight% of solid content, and the acid precipitation card | curd slurry was obtained. This was adjusted to pH 3.5 with phosphoric acid and then heated at 120 ° C. for 15 seconds in a continuous direct heat sterilizer. This was spray-dried to obtain an acid-soluble soybean protein powder (hereinafter abbreviated as S). The dissolution rate of this protein was 61% at pH 4.0.

<製造例2>
製造例1と同様にして得られた酸沈殿カードスラリーをリン酸でpH4.0に調整後、40℃になるように加温した。この溶液に固形分あたり8unit相当のフィターゼ(NOVO社製)を加え、30分間酵素作用を行った。反応後、pH3.5に調整して連続式直接加熱殺菌装置にて120℃15秒間加熱した。これを噴霧乾燥し酸性可溶大豆たん白粉末(以下Tと略す)1.5kgを得た。このたん白の溶解率はpH4.0で95%であった。
<Production Example 2>
The acid precipitation curd slurry obtained in the same manner as in Production Example 1 was adjusted to pH 4.0 with phosphoric acid and then heated to 40 ° C. To this solution, 8 units of phytase (manufactured by NOVO) per solid content was added, and the enzyme action was performed for 30 minutes. After the reaction, the solution was adjusted to pH 3.5 and heated at 120 ° C. for 15 seconds with a continuous direct heating sterilizer. This was spray-dried to obtain 1.5 kg of acid-soluble soybean protein powder (hereinafter abbreviated as T). The dissolution rate of this protein was 95% at pH 4.0.

実施例1〜6 :スポンジケーキの製造
全卵150部、上白糖110部、乳化油脂(不二製油株式会社製)「パーミングH」20部、ソルビトール製剤(東和化成工業株式会社製)「フードル70」10部、水0〜5部を25℃の室温下でケンウッドミキサー(アイコー社製)、撹拌羽根ホイッパーで低速で30秒混合し、更に薄力粉(日本製粉社製)「バイオレット」95〜99.9部、ベーキングパウダー(愛国産業株式会社製)「ベーキングパウダー赤缶」1部、上記製造例2で得た酸性可溶大豆たん白粉末Tを0.1〜5部をホイッパーで低速で30秒混合しペースト状態の生地を得た。ペースト生地を撹拌羽根ホイッパーを用い高速で3分30秒混合し、生地比重を0.43とした実施例1〜6のホイップ生地を得た(変動部数は表1参照)。更に、これらのホイップ生地を6号寸のケーキデコ用の内容積1500ccの焼成型に入れ、170℃に調整した藤澤製作所製の電気オーブンPRINCEIIにて35分焼成しこれらの結果を表2まとめた。
Examples 1 to 6: Manufacture of sponge cake 150 parts of whole egg, 110 parts of super white sugar, emulsified oil (made by Fuji Oil Co., Ltd.) 20 parts "Perming H", sorbitol preparation (made by Towa Kasei Kogyo Co., Ltd.) "Foodle 70 10 parts of water and 0-5 parts of water are mixed at a low speed with a Kenwood mixer (manufactured by Aiko Co., Ltd.) and a stirring blade whip for 30 seconds at a room temperature of 25 ° C., and further, soft flour (manufactured by Nippon Flour Mills Co., Ltd.) “Violet” 95-99. 9 parts, baking powder (manufactured by Aikoku Sangyo Co., Ltd.) 1 part “baking powder red can”, 0.1-5 parts of acid-soluble soybean protein powder T obtained in Production Example 2 above with a whip at low speed for 30 seconds By mixing, a pasty dough was obtained. The paste dough was mixed at high speed for 3 minutes and 30 seconds using a stirring blade whipper to obtain the whipped dough of Examples 1 to 6 having a dough specific gravity of 0.43 (see Table 1 for the number of parts to be changed). Furthermore, these whipped doughs were put into a baking mold having an internal volume of 1500 cc for No. 6 size cake deco and baked for 35 minutes in an electric oven PRINCEII manufactured by Fujisawa Seisakusho adjusted to 170 ° C. Table 2 summarizes the results.

実施例7〜8
実施例1において、酸性可溶大豆たん白に代え、上記製造例1で得た酸性可溶大豆たん白粉末Sを1〜0.5部、他は表1の配合に従って、同様にしてペースト状態の生地を得、また同様に焼成した。
Examples 7-8
In Example 1, in place of the acid-soluble soybean protein, 1 to 0.5 parts of the acid-soluble soybean protein powder S obtained in Production Example 1 above, and the other paste states in the same manner according to the formulation in Table 1 The dough was obtained and fired in the same manner.

比較例1〜3
実施例1〜6において、酸性可溶大豆たん白に代えて、市販調製豆乳粉末(不二製油株式会社製)「ソヤフィット2000を0〜10部(大豆たん白質含有量62.8%重量/ドライ製品換算、たん白の溶解率pH4.0で20%)」使用する他は、同様にしてペースト状態の生地を得、また同様に焼成した。
Comparative Examples 1-3
In Examples 1 to 6, instead of acidic soluble soy protein, commercially available soymilk powder (manufactured by Fuji Oil Co., Ltd.) “0-10 parts of Soyafit 2000 (soy protein content 62.8% weight / dry The product was obtained in the same manner except that it was used as a product, 20% at a protein dissolution rate of pH 4.0).

Figure 2010183922
Figure 2010183922

Figure 2010183922
Figure 2010183922

表2中の断面積指数の測定は次の方法で行った。すなわち、ケーキナイフを用い焼成スポンジケーキの上面から底面に向かい左右均等に二分割し、左右どちらか一方を測定サンプルとして用いる。サンプルの断面をコピー機(富士ゼロックス社製)「DocuCenter Color a450型」にて等倍コピーし、コピーされた用紙の断面積が写っている部分を切り取り重量測定し、コピー用紙の面積/重量比率から写っている部分の面積cm2を計算した。比較例1の断面積を100と固定し比較例2〜3、実施例1〜8の面積を指数で表し、指数値の大きいものがボリューム良好であった。   The cross-sectional area index in Table 2 was measured by the following method. That is, a cake knife is used to divide the fired sponge cake from the top surface to the bottom surface, and the left and right portions are equally divided into two, and one of the left and right is used as a measurement sample. Copy the cross section of the sample with a copier (Fuji Xerox Co., Ltd.) “DocuCenter Color a450”, cut out the portion where the cross-sectional area of the copied paper is shown, measure the weight, and copy the area / weight ratio of the paper The area cm2 of the part reflected from the above was calculated. The cross-sectional area of Comparative Example 1 was fixed at 100, and the areas of Comparative Examples 2 and 3 and Examples 1 to 8 were expressed as indexes, and those with large index values had good volume.

表2中の焼成品の内層状態の評価は次のように行った。断面積指数の測定に用いたサンプルの断面内層の状態を10名のパネラーが目視にて5点評価し平均点を用いた。ポーラスな内層であり且つ気泡状態が均質に揃い手造り的で良好な内層を5点とし、不明瞭な特長の弱い内層を3点、大小の気泡が混在し粗すぎザラザラした不良内層を1点とした。   The evaluation of the inner layer state of the fired product in Table 2 was performed as follows. Ten panelists evaluated the state of the inner layer of the cross section of the sample used for the measurement of the cross-sectional area index by five points, and used the average point. The inner layer is porous and has a uniform bubble structure, with 5 points for the handmade and good inner layer, 3 points for the weak inner layer with obscure features, and 1 point for the defective inner layer that is too rough due to the mixing of large and small bubbles. did.

表2中の焼成品の食感の評価は次のように行った。断面積指数の測定に用いたサンプルの断面内層の状態を5名のパネラーが試食し10点評価し平均点を用いた。適度な弾力と歯切れの良さを有し、且つ咽ごしの良い良好な食感を5点とし、唾液を取られネタツき特長の弱い食感を3点とし、ザラザラした良くない食感を1点とした。
大豆たん白製品の一種である調整豆乳粉末を薄力粉に対し5.26%〜11.1%使用した比較例2〜3は大豆たん白製品を使用していない比較例1に対し内層及び食感が改良された結果であるが、スポンジケーキのボリュームが小さくなる欠点がみられ、又効果を発揮する為には多量の調整豆乳粉末が必要であった。
Evaluation of the texture of the baked product in Table 2 was performed as follows. Five panelists sampled the state of the inner layer of the sample used for the measurement of the cross-sectional area index, evaluated 10 points, and used the average score. It has a moderate elasticity and crispness, and has a good texture with a good throat, 5 points, and 3 points with a weak texture that has a characteristic of being spoiled. Points.
Comparative Examples 2 to 3 in which 5.26% to 11.1% of the adjusted soymilk powder, which is a kind of soybean protein product, is used for the soft flour, the inner layer and the texture compared to Comparative Example 1 in which no soy protein product is used. However, there was a drawback that the volume of the sponge cake was reduced, and a large amount of adjusted soymilk powder was necessary to exert the effect.

実施例1〜8の酸性可溶大豆たん白使用スポンジケーキは手作り的な特徴のある内層と良好な食感を有し総合的に良好な品質結果であった。更に調整豆乳粉末に対し低レベルの使用量で効果を発揮しボリュームの低下もなく、従来の大豆たん白製品とは差別化された効果がみられた。特に酸性可溶大豆たん白粉末Tは、同粉末Sに比較し、より好ましい内層状態と食感を示した。   The sponge cake using the acid-soluble soybean protein of Examples 1 to 8 had a handmade characteristic inner layer and good texture, and was a good overall quality result. Furthermore, the modified soymilk powder exhibited an effect at a low level of use, and there was no decrease in volume, and a differentiated effect from the conventional soybean protein product was observed. In particular, the acidic soluble soybean protein powder T showed a more preferable inner layer state and texture compared to the powder S.

実施例9〜11:バターケーキの製造
上白糖120部、ショートニング(不二製油株式会社製)「パンパスLB」5部、乳化油脂(不二製油株式会社製)「パーミングH」5部、食塩2部を25℃の室温下でケンウッドミキサー(アイコー社製)、撹拌羽根ビーターで低速で30秒混合し、更に薄力粉(日本製粉社製)「バイオレット」97〜100部、コーンスターチ5部、ベーキングパウダー(愛国産業株式会社製)「ベーキングパウダー赤缶」3部、酸性可溶大豆たん白粉末T 0.5〜3部をビーターを添加し低速で30秒混合後全卵(正味)85部、水60〜63部、サラダ油(不二製油株式会社製)「ナタネサラダ油」60部を順番に添加しビーター低速で2分間混合し均一なペースト状のバターケーキ生地を得、更に、これらのペースト状の生地を長方形のバターケーキ焼成型サイズ130mm×56mm×高さ15mmに150g入れ、160℃に調整した藤澤製作所製の電気オーブンPRINCEIIにて30分間焼成しこれらの結果を表4まとめた。
Examples 9 to 11: Production of butter cake 120 parts of white sucrose, 5 parts of shortening (Fuji Oil Co., Ltd.) “Pampas LB”, 5 parts of emulsified fat (Fuji Oil Co., Ltd.) “Perming H”, salt 2 Parts at room temperature of 25 ° C. with a Kenwood mixer (manufactured by Aiko Co., Ltd.) and mixing with a stirring blade beater at low speed for 30 seconds. Further, 97 to 100 parts of soft flour (manufactured by Nippon Flour Mills) “Violet”, 5 parts of corn starch, baking powder ( Made by Aikoku Sangyo Co., Ltd.) "Baking powder red can" 3 parts, acid soluble soy protein powder T 0.5-3 parts beaten and mixed for 30 seconds at low speed, then 85 parts whole egg (net), 60 parts water ~ 63 parts, 60 parts of salad oil (manufactured by Fuji Oil Co., Ltd.) “rapeseed salad oil” were added in order and mixed for 2 minutes at a low speed of beater to obtain a uniform paste-like butter cake dough, and these Put 150g pasty dough into rectangular butter cake baking mold size 130 mm × 56 mm × height 15 mm, the fired results of these are summarized in Table 4 for 30 minutes at adjusted Fujisawa Seisakusho electric oven PRINCEII to 160 ° C..

比較例4
酸性可溶大豆たん白を使用しない他は、実施例9と同じ製法で生地を調製,焼成した。
Comparative Example 4
A dough was prepared and baked by the same manufacturing method as in Example 9 except that acid-soluble soybean protein was not used.

Figure 2010183922
Figure 2010183922

焼成品の内層状態と食感を10名のパネラーにて5点法の評価を行ない表4に結果をまとめた。   The inner layer state and texture of the baked product were evaluated by a 10-point method using 10 panelists, and the results are summarized in Table 4.

表4の結果の如く、酸性可溶大豆たん白を添加した実施例9〜11は比較例4との比較の如く大きな食感改良の効果がみられた。   As shown in the results of Table 4, Examples 9 to 11 to which acidic soluble soybean protein was added showed a great texture improvement effect as compared with Comparative Example 4.

Figure 2010183922
Figure 2010183922

実施例12〜14:ドーナツの製造
薄力粉(日本製粉社製)「バイオレット」97〜99.5部、酸性可溶大豆たん白粉末T 0.5〜3部、上白糖33.8部、食塩1.5部、ベーキングパウダー(愛国産業株式会社製)「ベーキングパウダー赤缶」3部、脱脂粉乳3部を25℃の室温下でケンウッドミキサー(アイコー社製)、撹拌羽根ビーターで低速で30秒混合し、更に全卵(正味)15部、水52〜55部、植物性マーガリン(不二製油株式会社製)「パリオール500」60部を湯煎で溶解し順番に添加しビーター低速で2分間混合し均一なペースト状のドーナツ生地を得、実施例12〜14の表5にまとめた。ペースト状の生地をドーナツ生地絞り出し器(関東商事株式会社)「アルミドーナツメーカー」に入れ180℃に加熱したフライヤー(マッハ機器株式会社)「電気式フライヤー」の中に一個45g前後の重量で絞り入れ表裏合計4分間フライした。
Examples 12-14: Manufacture of donuts Soft flour (Nippon Flour Mills) "Violet" 97-99.5 parts, Acid-soluble soybean protein powder T 0.5-3 parts, Super white sugar 33.8 parts, Salt 1 .5 parts, baking powder (manufactured by Aikoku Sangyo Co., Ltd.) 3 parts of “baking powder red can” and 3 parts of skimmed milk powder are mixed at a low temperature for 30 seconds with a Kenwood mixer (manufactured by Aiko Co., Ltd.) and a stirring blade beater. Further, 15 parts of whole egg (net), 52 to 55 parts of water, 60 parts of vegetable margarine (Fuji Oil Co., Ltd.) “Pariol 500” are dissolved in a hot water bath and added in order, and mixed at a beater low speed for 2 minutes. A uniform pasty donut dough was obtained and summarized in Table 5 of Examples 12-14. Put pasty dough into donut dough squeezer (Kanto Shoji Co., Ltd.) “Aluminum donut maker” and heat it to 180 ° C in a fryer (Mach Equipment Co., Ltd.) “Electric fryer”. Fry for a total of 4 minutes.

比較例5
酸性可溶大豆たん白を用いないほかは実施例14とほぼ同じ配合で表5のペースト状の生地を得、同条件でフライした。
Comparative Example 5
A pasty dough as shown in Table 5 was obtained with substantially the same formulation as in Example 14 except that acid-soluble soybean protein was not used, and fried under the same conditions.

Figure 2010183922
Figure 2010183922

フライ品の内層状態と食感を10名のパネラーにて5点法の評価を行ない表6に結果をまとめた。   The inner layer state and texture of the fried product were evaluated by a 10-point method using 10 panelists, and the results are summarized in Table 6.

表6の結果の如く、酸性可溶大豆たん白を添加した実施例12〜14は比較例5との比較の如く大きな食感改良の効果がみられた。   As shown in Table 6, Examples 12 to 14 to which acidic soluble soybean protein was added showed a significant texture improvement effect as compared with Comparative Example 5.

Figure 2010183922
Figure 2010183922

実施例15:シューパフの製造
シューパフ専用マーガリン(不二製油株式会社製)「シュートップD」130部、水120部をケンウッドミキサー(アイコー社製)の容器に計量し、これをガス火で加熱沸騰させる。沸騰したマーガリンと水の混合物の中に薄力粉(日本製粉社製)「バイオレット」79部、強力粉(日本製粉社製)「イーグル」20部、酸性可溶大豆たん白粉末T 1部を加え、羽根ビーター、中速で3分間混合し粉体中に含まれるたん白質、澱粉と沸騰したマーガリンと水の混合物を均一に混合し水和させる。全卵(正味)200部、炭酸水素アンモニウム(膨化剤)「株式会社八宝商会」1部、炭酸水素ナトリウム(膨化剤)「株式会社八宝商会」0.5部を予備混合し3等分する。粉体と沸騰したマーガリンと水の混合物に前記の卵と膨化剤の混合物の3分の1を加え羽根ビーター、中速で2分混合し、更に混合物の3分の1を加え中速で2分混合、最後に残りの混合物の3分の1を加え中速で2分混合しペースト状のシューパフ生地を得、表7にまとめた。 ペースト状のシューパフ生地を袋に入れ鉄板に一個20gで球状に絞り200℃に調整した藤澤製作所製の電気オーブンPRINCEIIにて16分間焼成した。
Example 15: Manufacture of shoe puff Shoe puff dedicated margarine (manufactured by Fuji Oil Co., Ltd.) “Shoe Top D” 130 parts and water 120 parts were weighed into a container of Kenwood mixer (manufactured by Aiko Co., Ltd.), and heated and boiled with gas fire Let In a mixture of boiled margarine and water, add 79 parts of "Violet" soft flour (Nippon Flour Mills), 20 parts of "Eagle" strong flour (Nippon Flour Mills), 1 part of acid soluble soy protein powder T, feather Mix in a beater at medium speed for 3 minutes to evenly mix and hydrate the protein, starch, boiled margarine and water mixture contained in the powder. 200 parts of whole egg (net), 1 part of ammonium hydrogen carbonate (expansion agent) "Happo Shokai Co., Ltd.", 0.5 parts of sodium hydrogen carbonate (expansion agent) "Happo Shokai Co., Ltd." To do. Add 1/3 of the egg and leavening agent mixture to the mixture of powder, boiled margarine and water and mix with a feather beater at medium speed for 2 minutes, then add 1/3 of the mixture at medium speed to 2 Mixing was completed, and finally one third of the remaining mixture was added and mixed at medium speed for 2 minutes to obtain a pasty shoe puff dough. The paste-like shoe puff dough was put in a bag and baked for 16 minutes in an electric oven PRINCE II manufactured by Fujisawa Seisakusho, which was squeezed spherically with 20 g on an iron plate and adjusted to 200 ° C.

比較例6
酸性可溶大豆たん白を用いない他は、実施例15と略同じ製法で生地を調製した。
Comparative Example 6
A dough was prepared by substantially the same production method as in Example 15 except that the acid-soluble soybean protein was not used.

Figure 2010183922
Figure 2010183922

焼成品の内層状態と食感を10名のパネラーにて5点法の評価を行ない表8に結果をまとめた。   The inner layer state and texture of the baked product were evaluated by a 10-point method using 10 panelists, and the results are summarized in Table 8.

表8の結果の如く、酸性可溶大豆たん白を添加した実施例15は比較例6との比較の如く大きな食感改良の効果がみられた。   As shown in the results of Table 8, Example 15 to which acidic soluble soybean protein was added showed a great texture improvement effect as compared with Comparative Example 6.

Figure 2010183922
Figure 2010183922

実施例16及び比較例7:クッキーの製造
下表の配合で定法によりクッキーを製造した。
Example 16 and Comparative Example 7: Production of Cookies Cookies were produced by the usual method with the composition shown in the table below.

Figure 2010183922
Figure 2010183922

クッキーの試作には卓上縦型ミキサーを使用し、アタッチメントにはビーターを装着した。まず、上記配合を、比重0.85を目標に低速攪拌混合し、そこに全卵を4、5回に分けて添加した。更に、攪拌しながら、水に溶いた炭安を添加、次いで、洋酒を順次添加混合した。攪拌を止め、薄力粉を一度に加え最低速度で攪拌し、粉が全体にまぶされたら攪拌を停止し、手で均一になるようざっくりと混ぜ、この生地を密閉保存し、冷蔵庫で1晩寝かせた。翌日、生地(品温6〜7℃)をゲージ厚6mmでシーターにかけ、生地厚6.2mmに延ばし、直径45mmのセルクルで型抜き(約11.5g/枚)し、 釜上200℃、釜下160℃、で9分間焼成した。実施例は生地の調製などの作業性には全く問題はなく、焼成時の生地ダレも発生しなかった。   A desktop vertical mixer was used for the cookie prototype, and a beater was attached to the attachment. First, the above blend was mixed at low speed with the target of a specific gravity of 0.85, and the whole egg was added in 4 or 5 portions. Further, with stirring, charcoal dissolved in water was added, and then Western liquor was sequentially added and mixed. Stop stirring, add weak flour all at once, stir at the lowest speed, stop stirring when the powder is sprinkled all over, mix gently by hand, keep this dough tightly, store in a refrigerator overnight It was. The next day, the fabric (product temperature 6-7 ℃) is put on a sheeter with a gauge thickness of 6mm, stretched to a fabric thickness of 6.2mm, and die-cut (about 11.5g / sheet) with a diameter of 45mm. Bake at 9 ° C. for 9 minutes. In the examples, there was no problem in workability such as preparation of dough, and dough sagging during firing did not occur.

比較例7のクッキーはほぐれが遅く、ぎしぎしと詰まるような噛み応えであるのに対し、実施例16のクッキーは、適度な歯応えがあり、かつほぐれがよい特徴を有した。   While the cookie of Comparative Example 7 was slow to loose and chewed tightly, the cookie of Example 16 had characteristics of moderate crunch and good looseness.

実施例17〜19及び比較例8:コロッケの製造
2倍重量の温水に対して日本食研(株)製の「クックコロッケ」(コロッケの具材の素)を添加し、均一になるようによく混合し、冷却したコロッケの中種生地を、ドラム式の成型機(日本キャリア工業(株)製)を用いて1個45gになるように成型した。この中種1個に対して、バッター15g、パン粉15gを付け急速凍結した後、175℃で5分間フライした。バッターは予め必要な粉体資材をプレミックスしたものを、5℃の冷水に分散させて調製した。そのバッターの配合を表10に示した。
Examples 17 to 19 and Comparative Example 8: Manufacture of croquette Add "Cook croquette" (elementary ingredient of croquette) made by Nippon Shokuken Co., Ltd. to twice the weight of warm water, and make it uniform. The mixed and cooled medium-sized dough of croquette was molded to 45 g using a drum type molding machine (manufactured by Nippon Carrier Kogyo Co., Ltd.). One medium seed was fast-frozen with 15 g of batter and 15 g of bread crumbs, and then fried at 175 ° C. for 5 minutes. The batter was prepared by pre-mixing necessary powder materials in 5 ° C. cold water. The composition of the batter is shown in Table 10.

Figure 2010183922
Figure 2010183922

フライしたコロッケを室温にて7時間放置したものを官能にて評価した。評価の結果を表11に示す。食感評価は10人のパネラーに5点満点として優れている順に5から1の段階評価をしてもらい、平均点で示した。   A frozen croquette that was allowed to stand at room temperature for 7 hours was evaluated by sensory evaluation. The evaluation results are shown in Table 11. The texture was evaluated by 10 panelists in the order of 5 to 1 in the order of 5 points, and expressed as an average score.

Figure 2010183922
Figure 2010183922

酸性可溶大豆たん白粉末Tを添加することで、衣のさくさく感とクリスピー感が付与されており、比較例に比べて良好であった。但し、添加量が多くなると、噛みだしの硬さが気になり、機能改善効果は弱まる傾向にあった。総合的には1%添加区が食感のバランスが良好であった。また、フライ後4時間及び7時間経過したものを評価した。酸性可溶大豆たん白を添加した実施例では、経時的な衣のへたりが少なく、比較例と比べて食感が良好であった。   By adding the acid-soluble soybean protein powder T, a crumpled feeling and a crispy feeling were imparted, which was better than the comparative example. However, as the amount added increased, the hardness of the bite was bothering and the function improvement effect tended to be weakened. Overall, the 1% addition group had a good texture balance. Moreover, what passed 4 hours and 7 hours after frying was evaluated. In the example to which the acid-soluble soybean protein was added, there was little sag of clothing over time, and the texture was better than in the comparative example.

実施例20〜21及び比較例9:かき揚げの製造

Figure 2010183922
Examples 20-21 and comparative example 9: manufacture of kakiage
Figure 2010183922

Figure 2010183922
Figure 2010183922

表12及び表13の配合に従い、野菜に打ち粉を添加し混合した後、衣液を添加し更に混合した。(1食ずつ手作業で実施した。)かき揚げ作成用のフライカップに生地を入れて、165℃で1分30秒フライし、急速冷凍した。調理する際には、170℃×1分15秒で再フライし、食感の評価を実施した。   According to the composition of Table 12 and Table 13, the flour was added to the vegetables and mixed, and then the dressing liquid was added and further mixed. (Each meal was carried out manually.) The dough was put in a frying cup for making kakiage, fried at 165 ° C. for 1 minute 30 seconds, and quickly frozen. When cooking, the food texture was evaluated by re-frying at 170 ° C. × 1 minute 15 seconds.

フライ後2時間経過したものを官能にて評価した。評価の結果を表14に示す。食感評価は10人のパネラーに5点満点として優れている順に5から1の段階評価をしてもらい、平均点で示した。   The sensory evaluation was made after 2 hours from frying. The evaluation results are shown in Table 14. The texture was evaluated by 10 panelists in the order of 5 to 1 in the order of 5 points, and expressed as an average score.

Figure 2010183922
Figure 2010183922

酸性可溶大豆たん白を添加することで、衣のさくさく感とクリスピー感が付与されており、経時的な衣のへたりが少なく、比較例に比べて良好であった。但し、添加量が多くなると、噛みだしの硬さが気になるため、総合的には1%添加区が食感のバランスが良好であった。   By adding the acid-soluble soybean protein, a soft and crispy sensation was given to the clothing, and there was little sag of the clothing over time, which was better than the comparative example. However, as the added amount increases, the hardness of the bite becomes worrisome, and overall, the 1% added section has a good texture balance.

実施例22及び比較例10:パン製造
下表の配合で、定法によりパンを製造した。
Example 22 and Comparative Example 10: Bread Production Bread was produced by a conventional method with the composition shown in the table below.

Figure 2010183922
Figure 2010183922

Figure 2010183922
Figure 2010183922

Figure 2010183922
Figure 2010183922

Figure 2010183922
Figure 2010183922

酸性可溶大豆たん白粉末Tを配合した実施例22の作業性は、未配合である比較例10に対し、ミキシング初期にはややかためだったが、捏ね上げ時ではコントロールとほぼ同じであり、作業性はほぼ同等であった。生地物性は、エキソテンソグラフによる測定の結果、抗張力、伸長度、形状係数ともに同等であり、ほぼ同じ生地物性であることが示された(表17)。また、焼成後の外観については容積が同等であり、内層の外観は色調・目の粗さや形等において大きな差がなかった。パン比容積についても比較例とほぼ同等であった(表18)。   The workability of Example 22 in which the acidic soluble soybean protein powder T was blended was somewhat harsh at the beginning of mixing compared to the unblended Comparative Example 10, but it was almost the same as the control at the time of kneading. The workability was almost the same. As a result of measurement by exotensograph, the physical properties of the fabric were the same in terms of tensile strength, elongation, and shape factor, and it was shown that the fabric properties were almost the same (Table 17). Further, the appearance after firing was the same in volume, and the appearance of the inner layer was not significantly different in color tone, eye roughness, shape and the like. The pan specific volume was also almost the same as the comparative example (Table 18).

生地物性やパン容積は同等であるが、パンの食感については実施例22は比較例10と比べて優れていた。即ち、トーストをしない生の状態では、口の中でダンゴ状になりにくく、口溶けが良好であり、トーストをした場合は、軽くさくさくした食感に改質されており、好ましかった。   Although the dough physical properties and bread volume were the same, Example 22 was superior to Comparative Example 10 in terms of bread texture. That is, in the raw state without toast, it was difficult to form a dango shape in the mouth and the mouth melted well. When toasted, it was modified to a light and crunchy texture, which was preferable.

実施例23:ノンフライ麺の製造
常温の水680部に攪拌しながら塩類(食塩30部、炭酸カリウム3部、炭酸ナトリウム3部)を添加し、10分間攪拌溶解を行った(加水調整液の作製)。小麦粉(日清製粉社製)「飛龍」1800部、タピオカ澱粉(日澱化学社製)「Z−100」200部、上記製造例2で得た酸性可溶大豆たん白粉末T 20部を十分に粉体混合し、200メッシュをパスさせた。コートミキサーに粉体混合物を入れ、低速にて攪拌しながら加水調整液を5回に分けて2分間で添加し、低速攪拌7分間、中速攪拌8分間行った。オカラ状になったドウ(pH8.5)を製麺機に移し、複合(厚さ2.7mmに調整)を行い麺帯にした。さらに圧延を繰り返し、最終的に厚さ0.7mmに調整した。適当な大きさに麺帯をカットし、スチーマーにて麺線を6分間蒸した。蒸しあがった麺線を熱風乾燥機にて85℃60分間乾燥し、乾燥後麺を常温に放置して冷却した。
Example 23: Manufacture of non-fried noodles Salts (30 parts of salt, 3 parts of potassium carbonate, 3 parts of sodium carbonate) were added to 680 parts of water at room temperature while stirring, and the mixture was stirred and dissolved for 10 minutes (preparation of a water adjustment liquid) ). Wheat flour (made by Nisshin Seifun Co., Ltd.) “Hiryu” 1800 parts, tapioca starch (manufactured by Nissho Chemical Co., Ltd.) “Z-100” 200 parts, acid-soluble soybean protein powder T 20 parts obtained in Production Example 2 The powder was mixed and passed through 200 mesh. The powder mixture was put into a coat mixer, and the hydration adjusting solution was added in 5 minutes while stirring at low speed, and added in 2 minutes, followed by low speed stirring for 7 minutes and medium speed stirring for 8 minutes. The okara-shaped dough (pH 8.5) was transferred to a noodle making machine, combined (adjusted to a thickness of 2.7 mm), and made into a noodle band. Further, rolling was repeated and finally the thickness was adjusted to 0.7 mm. The noodle strip was cut to an appropriate size, and the noodle strings were steamed with a steamer for 6 minutes. The steamed noodle strings were dried with a hot air dryer at 85 ° C. for 60 minutes, and after drying, the noodles were allowed to cool to room temperature.

比較例11
実施例23に於て、酸性可溶大豆たん白粉末Tを添加しない以外は同様の方法にて調製した。
Comparative Example 11
In Example 23, it was prepared in the same manner except that the acid-soluble soybean protein powder T was not added.

比較例12
実施例23に於て、酸性可溶大豆たん白粉末T 20部の代わりに、分離大豆たん白(不二製油社製)「フジプロF(たん白の溶解率pH4.0で10%)」20部を使用した以外は、実施例23と同様の方法にて調製した。
Comparative Example 12
In Example 23, instead of 20 parts of acidic soluble soybean protein powder T, separated soybean protein (Fuji Oil Co., Ltd.) “Fujipro F (protein dissolution rate: pH 4.0, 10%)” 20 Prepared in the same manner as in Example 23, except that parts were used.

Figure 2010183922
Figure 2010183922

Figure 2010183922
Figure 2010183922

表20に示す通り、作業工程中の状態について、麺帯は比較例11に対し、比較例12が硬もろい触感であったが、実施例23では逆に比較例11に対し軟らかくしなやかな触感であり、明らかに分離大豆たん白が生地の粘性が増すのに対し、酸性可溶大豆たん白では生地の粘性が増加せず、逆に適度に低下した。   As shown in Table 20, with respect to the state during the work process, the noodle band was harder to the comparative example 11 than the comparative example 12, but in Example 23, it was softer and more flexible to the comparative example 11 on the contrary. Yes, apparently the soy protein isolate increased in dough viscosity, whereas the acid-soluble soy protein did not increase in dough viscosity, but decreased moderately.

麺の評価方法は、カップに麺を入れ沸騰水を注ぎ、湯戻り後の麺の食感を10名のパネラーによる官能試験により行った。湯戻り後の食感を見たところ、比較例11は粉っぽさがあり、くずれやすくねちゃつきがあり、比較例12は麺が硬く感じ、ぶちぶち切れやすかったのに対し、実施例23は粉っぽさ、ねちゃつきが少なく、噛み切るときに適度な弾力やしなやかさを感じ好ましかった。   The noodle evaluation method was carried out by putting noodles into a cup, pouring boiling water, and eating the noodles after returning to hot water by a sensory test with 10 panelists. As a result of looking at the texture after returning to the hot water, Comparative Example 11 was powdery, easy to break, and sticky, and Comparative Example 12 felt that the noodles were hard and easily cut off. No. 23 had little powderiness and stickiness, and it was preferable to feel moderate elasticity and suppleness when biting.

また、即席乾燥食品の場合には湯戻り・湯伸び・ほぐれといった特有の課題があり、これらの点を評価した。
「湯戻り」:湯戻り3分後、5分後、7分後の復元性を見たところ、比較例11、12は5分後でも硬く芯が残り、7分後に復元が完了したのに対し、実施例23は5分後にほぼ復元が完了し、湯戻りが早い傾向が見られた。
「湯伸び」:湯戻り10分以降の食感を見たところ、比較例11、12は軟らかくねちゃつきが増大し、明らかに湯伸びしていたのに対し、実施例23は軟らかくなるが適度な硬さを維持しており、湯伸びしにくい傾向が見られた。
「ほぐれ」:湯戻り3分後、5分後の麺のほぐれ性を見たところ、比較例11、12は麺がほぐれにくくまとまっていたのに対し、実施例23は絡まりが少なく明らかにほぐれやすい傾向を示した。
In the case of instant dry foods, there are specific problems such as rejuvenation, stretch, and loosening, and these points were evaluated.
“Return to hot water”: Restoration after 3 minutes, 5 minutes, and 7 minutes after hot water return showed that Comparative Examples 11 and 12 had a hard core remaining after 5 minutes, and the restoration was completed after 7 minutes. On the other hand, in Example 23, restoration was almost completed after 5 minutes, and there was a tendency for hot water to return quickly.
“Hot water elongation”: When the texture after 10 minutes of hot water return was observed, Comparative Examples 11 and 12 were soft and increased in stickiness, and apparently hot water was stretched, whereas Example 23 was softer. A moderate hardness was maintained, and there was a tendency for hot water to stretch.
“Feeling”: When the loosening properties of the noodles after 3 minutes after returning to the hot water were observed, Comparative Examples 11 and 12 showed that the noodles were not easily loosened, while Example 23 was clearly loosened with little entanglement. The tendency was easy.

以上の結果から、即席乾燥食品の課題である湯戻り・湯伸び・ほぐれといった課題についても効果が認められることがわかった。   From the above results, it was found that the effects of instant dry foods such as hot water return, hot water stretch, and loosening were also recognized.

また、実施例23の酸性可溶大豆たん白粉末Tに代えて、上記製造例1で得た酸性可溶大豆たん白粉末Sを用いたいところ、実施例23と同じ傾向の麺質改良効果が得られたが、実施例23の方が食感のしなやかさにおいて優れていた。以上のように、酸性可溶大豆たん白を添加することでノンフライ麺の麺質改善効果が得られることがわかった。   In addition, instead of the acid-soluble soybean protein powder T of Example 23, the acid-soluble soybean protein powder S obtained in Production Example 1 is used. As a result, Example 23 was superior in the supple texture. As described above, it was found that the effect of improving the noodle quality of non-fried noodles can be obtained by adding acidic soluble soybean protein.

実施例24〜26:うどんの製造
常温の水40部に対し攪拌しながら食塩4部を添加し、10分間攪拌溶解を行った。(加水調整液の作製)。うどん用中力粉(日東製粉社製)100部に酸性可溶大豆たん白粉末T(0.5部、1.0部、1.5部)を十分に粉体混合し200メッシュをパスさせた。コートミキサーに粉体混合物を入れ、低速にて攪拌しながら加水調整液を5回に分けて2分間で添加し、攪拌を始めてから5分後に掻き落としを行い、さらに5分間(計10分間)攪拌を行った。そぼろ状になったドウを製麺機に移し、複合(厚さ5.0mm)を行い麺帯とした。その麺帯に対し圧延を3回繰り返し最終厚さ2.0mmの麺帯をとした。その麺帯を麺切り機にて幅3mmにカットし生うどんを得た。
Examples 24-26: Manufacture of udon 4 parts of salt was added to 40 parts of water at room temperature while stirring, and the mixture was stirred and dissolved for 10 minutes. (Preparation of water adjustment liquid). 100 parts of neutral powder for udon (manufactured by Nitto Flour Mills Co., Ltd.) is sufficiently mixed with acid-soluble soybean protein powder T (0.5 part, 1.0 part, 1.5 part) and passed through 200 mesh. It was. Add the powder mixture to the coat mixer, add the hydration adjustment solution in 5 minutes while stirring at low speed, add it over 2 minutes, scrape off 5 minutes after starting the stirring, and further 5 minutes (10 minutes in total) Stirring was performed. The dough that was in the shape of a rag was transferred to a noodle making machine and combined (thickness 5.0 mm) to form a noodle strip. The noodle strip was repeatedly rolled three times to obtain a noodle strip having a final thickness of 2.0 mm. The noodle strip was cut into a width of 3 mm with a noodle cutter to obtain raw udon.

一晩冷蔵にて静置後、生めんに対し10倍量の沸騰水を準備し、生めんを入れ10分間加熱しうどんを得た。   After standing still in the refrigerator overnight, 10 times the amount of boiling water was prepared for the raw noodles, and the raw noodles were added and heated for 10 minutes to obtain udon.

比較例13
酸可溶性大豆たん白粉末を添加しない以外は実施例24と同じ方法で調製した。
Comparative Example 13
It was prepared in the same manner as in Example 24 except that acid-soluble soybean protein powder was not added.

Figure 2010183922
Figure 2010183922

Figure 2010183922
Figure 2010183922

評価方法は茹で上げ直後の「食感」と温かいスープに浸した状態での「茹で伸び」について10名のパネラーにより官能評価法にて行った。茹で上げ直後の「食感」についてみたところ、比較例13ではうどんの硬さも弱く、弾力、コシがあまりないのに対し実施例24〜26ではうどんへの硬さ、麺の弾力、コシが付与されており好ましい食感であることが確認された。酸可溶性大豆たん白の添加量では1.0部が最もうどんの硬さ付与、麺の弾力、コシにおいて好ましく、次いで1,5部添加、0,5部添加の順に好ましいものであった。   The evaluation method was a sensory evaluation method by 10 panelists regarding “texture” immediately after boiled and “boiled stretch” in a state soaked in warm soup. Examination of the “texture” immediately after boiling, in Comparative Example 13, the hardness of the udon is weak and there is not much elasticity and stiffness, whereas in Examples 24-26, the hardness to the udon, elasticity of the noodles, and stiffness are imparted It was confirmed that the texture was favorable. In the addition amount of acid-soluble soybean protein, 1.0 part was most preferable in terms of imparting the hardness of udon, elasticity of noodles, and stiffness, followed by addition of 1,5 parts and then addition of 0.5 parts.

「茹で伸び」において、80℃に調整したスープに茹で上げた直後のうどんを浸し、5分後、10分後の状態についてみたところ、5分後の状態では比較例はうどんが柔らかく、やや伸びた状態であったのに対し、実施例では茹で上げ直後の食感が保たれていた。10分後の状態では比較例は茹で伸びが進みうどんが柔らかくさらにコシの少ない状態であったのに対し、実施例ではやや茹で伸びが起こっているにも関わらず比較例にはない硬さ、弾力、コシがあることが確認された。   In “boiled and stretched”, the soup adjusted to 80 ° C. was soaked with udon immediately after boiling, and after 5 minutes and 10 minutes, the comparative example showed that the udon was soft and slightly stretched after 5 minutes. In contrast, in the examples, the texture immediately after being boiled was maintained. In the state after 10 minutes, the comparative example was in a state where the growth of the udon progressed with the cocoon and the udon was soft and less stiff, whereas in the example, the hardness which is not in the comparative example despite the slight extension of the cocoon, It was confirmed that there was elasticity and stiffness.

以上のように酸化可溶性大豆たん白を添加することでうどんへの麺質改良効果が得られることがわかった。   As described above, it was found that the effect of improving the noodle quality on udon can be obtained by adding oxidized soluble soybean protein.

実施例27:フラワーペースト
上記製造例2で得た酸性可溶大豆たん白粉末Tを用いて、フラワーペーストを調製した。凍結卵黄「ゴールドヨーク」(キューピー社製)4.0部、ラクトグロブリン「サンラクトN5」(太陽化学社製)2.0部、脱脂粉乳4.0部、デキストリン10.0部、水44.5部、菜種油(不二製油社製)14.0部、グラニュー糖16.0部、酸性可溶大豆たん白粉末T 1.0部、コーンスターチ「MXPP」(日澱化学社製)4.5部を添加した。その後、60℃で10分間調合した。混合液のpHは5.9であった。さらに、100kg/cm2の圧力下に均質化した後、ニーダーで間接加熱処理する方法で100℃まで加熱し、澱粉をα化して糊状とした。ニーダーからの取り出し直後も、保形性のあるしっかりしたものであった。冷蔵庫内(5℃)で冷却後のフラワーペーストの風味は良好でかつ、食感は滑らかで口どけも良好であった。
Example 27: Flour paste Using the acid-soluble soybean protein powder T obtained in Production Example 2, a flour paste was prepared. Frozen egg yolk “Gold York” (manufactured by Kewpie) 4.0 parts, lactoglobulin “Sunlacto N5” (manufactured by Taiyo Kagaku) 2.0 parts, skim milk powder 4.0 parts, dextrin 10.0 parts, water 44.5 Parts, rapeseed oil (produced by Fuji Oil Co., Ltd.) 14.0 parts, granulated sugar 16.0 parts, acid-soluble soybean protein powder 1.0 parts, corn starch “MXPP” (manufactured by Nippon Star Chemical Co., Ltd.) 4.5 parts Was added. Then, it mix | blended for 10 minutes at 60 degreeC. The pH of the mixed solution was 5.9. Furthermore, after homogenizing under a pressure of 100 kg / cm 2, it was heated to 100 ° C. by a method of indirect heat treatment with a kneader, and the starch was gelatinized to form a paste. Immediately after removal from the kneader, it was a solid shape-retaining material. The flavor of the flour paste after cooling in the refrigerator (5 ° C.) was good, the texture was smooth and the mouthfeel was good.

比較例14
実施例27に於て、酸性可溶性大豆たん白をを添加しない以外は同様の方法にて、フラワーペーストを調製した。ニーダーからの取り出し直後も、保形性のあるしっかりしたものであった。冷蔵庫内(5℃)で冷却後のフラワーペーストの風味は良好だが、食感は澱粉の糊感が強く、非常に重たい口溶けであり好ましくなかった。
Comparative Example 14
A flour paste was prepared in the same manner as in Example 27 except that acid-soluble soy protein was not added. Immediately after removal from the kneader, it was a solid shape-retaining material. The flavor of the flour paste after cooling in the refrigerator (5 ° C.) was good, but the texture was unfavorable because the starch had a strong paste and was very heavy in the mouth.

実施例28:酸性フラワーペースト
上記製造例2で得た酸性可溶大豆たん白粉末Tを用いて、酸性フラワーペーストを調製した。市販100%オレンジジュース20部、水35.5部、菜種油(不二製油社製)14部、グラニュー糖23部、酸性可溶大豆たん白粉末T 3部、コーンスターチ「MXPP」(日澱化学社製)4.5部を添加した。その後、60℃で10分間調合した。混合液のpHは3.8であった。さらに、100kg/cm2の圧力下に均質化した後、ニーダーで間接加熱処理する方法で85℃まで加熱し、澱粉をα化して糊状とした。ニーダーからの取り出し直後も、保形性のあるしっかりしたものであった。冷蔵庫内(5℃)で冷却後のフラワーペーストの食感もしっかりしており、口どけも良好であった。また、オレンジの風味がはっきりしており、自然な味に仕上がっていた。
Example 28: Acidic flour paste An acidic flour paste was prepared using the acidic soluble soybean protein powder T obtained in Production Example 2 above. 20 parts of commercially available 100% orange juice, 35.5 parts of water, 14 parts of rapeseed oil (manufactured by Fuji Oil Co., Ltd.), 23 parts of granulated sugar, 3 parts of acid-soluble soybean protein powder T, corn starch “MXPP” (Nissho Chemical Co., Ltd.) 4.5 parts) was added. Then, it mix | blended for 10 minutes at 60 degreeC. The pH of the mixed solution was 3.8. Furthermore, after homogenizing under a pressure of 100 kg / cm 2, the starch was heated to 85 ° C. by a method of indirect heat treatment with a kneader, and starch was gelatinized to form a paste. Immediately after removal from the kneader, it was a solid shape-retaining material. The texture of the flour paste after cooling in the refrigerator (5 ° C.) was firm and the mouthfeel was good. Also, the orange flavor was clear and finished in a natural taste.

実施例29
酸性可溶大豆たん白粉末Tを2部、水分を36.5部とした以外は、実施例28に準じてフラワーペーストを得た。このものは実施例28のフラワーペーストに比べやや保形性が弱いものの、食感もしっかりとしていた。口どけは、実施例28同様、良好であった。風味に関しても、実施例28同様、自然な果汁の風味が感じられる物になっていた。
Example 29
A flour paste was obtained in the same manner as in Example 28 except that the acid-soluble soybean protein powder T was 2 parts and the water content was 36.5 parts. This was slightly weaker in shape retention than the flour paste of Example 28, but had a firm texture. The mouthfeel was good as in Example 28. Regarding the flavor, as in Example 28, the flavor of natural fruit juice was felt.

比較例15
実施例28において、酸性可溶大豆たん白を全量、乳清たん白「サンラクトN5」(太陽化学社製)に代替した。混合液のpHを乳酸により3.8に調整した。それ以外は、実施例28に準じて行った。このようにして、得られたフラワーペーストは、実施例28で得られたもののような保形性はなく、傾けると流れだし、金型で絞りだした時にもだれてしまう液状であった。オレンジの風味も乳風味と混じって、ぼやけてしまい、すきっとしたオレンジ風味が感じにくくなっていた。また実施例28に比較して酸味が非常に強く感じられ、好ましくなかった。
Comparative Example 15
In Example 28, the whole amount of acidic soluble soy protein was replaced with whey protein “Sanlacto N5” (manufactured by Taiyo Kagaku Co.). The pH of the mixture was adjusted to 3.8 with lactic acid. The others were carried out according to Example 28. Thus, the obtained flower paste had no shape retention like that obtained in Example 28, and it flowed when tilted, and was a liquid that would sag when squeezed with a mold. The orange flavor was mixed with the milk flavor and was blurred, making it hard to feel the orange flavor. Further, compared to Example 28, the acidity was felt very strongly, which was not preferable.

比較例15
比較例15において、コーンスターチの使用量を7.5部にし、グラニュー糖を20部とし、混合液のpHを乳酸により3.8に調整した。それ以外は、実施例28に準じて行った。得られたペーストは、比較例15よりは、保形性があったが、澱粉由来の保形性であり、喉通りが悪く、糊っぽさが感じられ実施例29に及ぶ食感ではなかった。
Comparative Example 15
In Comparative Example 15, the amount of corn starch used was 7.5 parts, granulated sugar was 20 parts, and the pH of the mixture was adjusted to 3.8 with lactic acid. The others were carried out according to Example 28. The obtained paste had a shape retaining property as compared with Comparative Example 15, but had a shape retaining property derived from starch, had a poor throat passage, had a pasty feel, and was not textured as in Example 29. It was.

実施例28〜29、比較例15〜16のフラワーペーストの配合および評価を表23に纏めた。   Table 23 shows the composition and evaluation of the flour pastes of Examples 28 to 29 and Comparative Examples 15 to 16.

Figure 2010183922
Figure 2010183922

実施例30
上記製造例2で得た酸性可溶大豆たん白を用いて、酸性フラワーペーストを調製した。パッションフルーツ濃縮混濁果汁(糖度50.5°、酸度13.90%、東京フードテクノ社製)10部、水45.5部、菜種油(不二製油社製)14部、グラニュー糖23部、酸性可溶大豆たん白粉末T3部、コーンスターチ「MXPP」(日澱化学社製)4.5部を添加した。その後、60℃で10分間調合した。混合液のpHは3.5であった。さらに、100kg/cm2の圧力下に均質化した後、ニーダーで間接加熱処理する方法で85℃まで加熱し、澱粉をα化して糊状とした。ニーダーからの取り出し直後でも、保形性のあるしっかりしたものであった。冷蔵庫内(5℃)で冷却後のフラワーペーストの食感もしっかりしており、口どけも良好であった。また、パッションフルーツの風味がはっきりしており、自然な味に仕上がっていた。
Example 30
An acidic flour paste was prepared using the acidic soluble soybean protein obtained in Production Example 2 above. Passion fruit concentrated turbid juice (sugar content 50.5 °, acidity 13.90%, Tokyo Food Techno Co., Ltd.) 10 parts, water 45.5 parts, rapeseed oil (Fuji Oil Co., Ltd.) 14 parts, granulated sugar 23 parts, acidic 3 parts of soluble soybean protein powder T and 4.5 parts of corn starch “MXPP” (manufactured by Nissho Chemical Co., Ltd.) were added. Then, it mix | blended for 10 minutes at 60 degreeC. The pH of the mixed solution was 3.5. Furthermore, after homogenizing under a pressure of 100 kg / cm 2, the starch was heated to 85 ° C. by a method of indirect heat treatment with a kneader, and starch was gelatinized to form a paste. Even immediately after taking out from the kneader, it was a solid shape-retaining material. The texture of the flour paste after cooling in the refrigerator (5 ° C.) was firm and the mouthfeel was good. In addition, the flavor of passion fruit was clear and finished in a natural taste.

実施例31:酸性可溶大豆たん白を配合した酸性クリームの製造
酸性可溶大豆たん白T2部、ショ糖脂肪酸エステル(三菱化学フーズ株式会社製)「リョートーシュガーエステルS−570」0.2部を粉体混合し、水52.8部に添加溶解し水相を調製する。サラダ油45部を添加し、油相と水相を70℃15分間ホモミキサーで攪拌し予備乳化した後1MPaの均質化圧力で均質化し、超高温滅菌装置によって、144℃、4秒間の直接加熱方式による滅菌処理を行った後、4MPaの均質化圧力で均質化して、直ちに5℃に冷却した。冷却後約24時間エージングして、酸性クリーム(pH3.5)を得た。
Example 31: Production of acidic cream containing acidic soluble soybean protein T2 part of acidic soluble soybean protein, sucrose fatty acid ester (manufactured by Mitsubishi Chemical Foods) "Ryoto Sugar Ester S-570" 0.2 Part of the mixture is mixed with powder and added to and dissolved in 52.8 parts of water to prepare an aqueous phase. 45 parts of salad oil is added, the oil phase and aqueous phase are stirred with a homomixer at 70 ° C for 15 minutes and pre-emulsified, then homogenized at a homogenization pressure of 1 MPa, and directly heated at 144 ° C for 4 seconds using an ultra-high temperature sterilizer. After performing the sterilization treatment by the above, the mixture was homogenized at a homogenization pressure of 4 MPa and immediately cooled to 5 ° C. After cooling, the mixture was aged for about 24 hours to obtain an acidic cream (pH 3.5).

比較例1の配合100部に対し、上記酸性可溶大豆たん白を配合した酸性クリームを25部添加してスポンジケーキを製造した。得られたスポンジケーキは、実施例1〜8と同様の手作り的な特徴のある内層と良好な食感を有していた。このように酸性可溶大豆たん白を予め水中油型クリームに調製してから添加しても同様に得られることから、酸性可溶大豆たん白を配合し、スポンジケーキ練り込み用クリームとして使用することも可能である。   25 parts of acidic cream blended with the above-mentioned acidic soluble soybean protein was added to 100 parts of Comparative Example 1 to produce a sponge cake. The obtained sponge cake had the same handmade inner layer and good texture as in Examples 1-8. In this way, the acid-soluble soybean protein can be obtained in the same manner by previously preparing an oil-in-water cream and then adding it, so that the acid-soluble soybean protein is blended and used as a sponge cake kneading cream It is also possible.

実施例32:酸性可溶大豆たん白を配合したショートニングの製造
酸性可溶大豆たん白T16.7部を加熱溶解したショートニング(不二製油株式会社製)「パンパスLB」83.3部に添加し、攪拌しながら練り込み、酸性可溶大豆たん白を配合したショートニングを製造した。実施例22の酸性可溶大豆たん白1部とパンパスLB5部の代わりに上記酸性可溶大豆たん白を配合したショートニング6部を使用する以外は、実施例22と同じ方法でパンを製造した。
Example 32: Production of shortening blended with acid-soluble soybean protein Acid-soluble soybean protein T16.7 parts was added to 83.3 parts of "Pampas LB" shortening (manufactured by Fuji Oil Co., Ltd.). Then, kneading was carried out with stirring to produce a shortening blended with acid-soluble soybean protein. Bread was produced in the same manner as in Example 22 except that 6 parts of the shortening blended with the above acidic soluble soybean protein was used in place of 1 part of the acid soluble soybean protein of Example 22 and 5 parts of Pampas LB.

その結果、作業性においても、生地物性においても、焼成後の外観、比容積においても、さらには、食感においてもほぼ実施例22と同等となり、予め酸性可溶大豆たん白をショートニングに練り込み、ショートニングとして使用することが可能であることが示された。   As a result, the workability, the physical properties of the dough, the appearance after firing, the specific volume, and the texture are almost the same as in Example 22, and the acid-soluble soybean protein is kneaded into the shortening in advance. It has been shown that it can be used as a shortening.

Claims (4)

澱粉性原料に酸性可溶大豆たん白を加配して得たフラワーペースト。 A flour paste obtained by adding acidic soluble soybean protein to starchy raw materials. 澱粉性原料が、澱粉性穀粉、それから得られる澱粉若しくは加工澱粉、またはそれらの混合物を主材とするものである請求項1に記載のフラワーペースト。 The flour paste according to claim 1, wherein the starch-based raw material is mainly composed of starch-based flour, starch obtained from the starch, processed starch, or a mixture thereof. 酸性可溶大豆たん白が澱粉性原料に対して50重量%以下である、請求項1記載のフラワーペースト。 The flour paste according to claim 1, wherein the acid-soluble soybean protein is 50% by weight or less based on the starchy raw material. フラワーペーストのpHが3.5〜5.9である請求項1記載のフラワーペースト。 The flour paste according to claim 1, wherein the flour paste has a pH of 3.5 to 5.9.
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