JP2010180181A - Detergent composition - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a detergent composition free from slimy feeling in rinsing, giving refreshing feeling after washing and having good frothing property and foam quality (creaminess). <P>SOLUTION: The detergent composition is produced by compounding a detergent composition with a polyol, another polyol having an average molecular weight larger than that of the former polyol by ≥5 times, and one or more surfactants selected from nonionic surfactants, anionic surfactants and ampholytic surfactants. These two kinds of polyols preferably have similar structures. The ratio of the average molecular weights of both polyols is ≥5, preferably ≥10, more preferably ≥15. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

  The present invention relates to a cleaning composition, and more particularly, to a cleaning composition that does not feel wet when rinsed, has a refreshing finish, and has good foaming and foam quality (creaminess).

  Conventionally, in a skin cleanser composition, it is possible to improve foaming, foam quality (creaminess), cleaning power, feel during use, etc. by combining a water-soluble polymer and a surfactant. It has been known. For example, a skin cleansing composition containing a dimethyldiallylammonium chloride / acrylamide copolymer which is a water-soluble polymer is disclosed (for example, see Patent Document 1). However, when such a water-soluble polymer is blended, there are disadvantages such as slickness at the time of rinsing and a refreshing feeling after washing. That is, it does not satisfy foaming, foam quality (creaminess), no slickness at the time of rinsing, and refreshing washing.

  Also, cosmetics containing cationized guar gum, cationized locust bean gum, cationized tara gum, etc. for the purpose of providing a moist feeling while giving the skin a feeling of elasticity and plumpness after use. Although a composition is disclosed (for example, refer to Patent Document 2), the effect of improving foaming and foam quality is seen in the composition, but a feeling of stickiness and a feeling of after-residue specific to a polymer occurs after use. There is no change. That is, here too, the improvement of foaming and foam quality (creaminess) is not compatible with the absence of slickness during rinsing.

  Further, although a fatty acid soap, an alkyldimethylaminoacetic acid betaine, and a highly polymerized polyethylene glycol are used, a cosmetic composition having good stability and usability and having good foam quality and foaming is disclosed (for example, Patent Document 3), and the foam quality and foaming improvement effect of the composition are limited. Therefore, in order to improve foam quality and foaming using the same composition, it is necessary to use a large amount of highly polymerized polyethylene glycol, and as a result, it becomes slippery during rinsing. That is to say, this also does not achieve both foaming and improvement in foam quality (creaminess) and lack of luster when rinsing. Moreover, if the blending amount of such a water-soluble polymer is reduced to reduce the feeling of stickiness, foaming and foam quality are also deteriorated at the same time. In other words, there was no technology that could simultaneously satisfy foaming, foam quality (creaminess), no slickness at the time of rinsing, and a refreshing wash, which was not satisfactory.

  On the other hand, the present inventors also formulated a water-soluble polymer in order to improve the foaming property, foam quality (creaminess), feel during rinsing, or washing-up of the cleaning composition (for example, patents). Reference 4)), cationized polymers (for example, see Patent Document 5), and cationized polysaccharides (for example, see Patent Document 6) have been added. The demands are becoming more demanding.

JP 2005-154360 A JP 2006-62979 A JP-A-9-183996 JP 2006-193484 A JP 2008-179583 A JP2008-179586

  In view of the above circumstances, as a result of intensive studies, the present inventors have found that, in a detergent composition containing a surfactant, by blending two or more types of polyols having different average molecular weights, the slickness is increased during rinsing. The present invention has been completed by finding that both foaming and foaming quality (creamy properties) can be satisfactorily achieved while having a clean wash.

  That is, an object of the present invention is to provide a cleaning composition having good foaming, foam quality (creamy property), no slickness at the time of rinsing, and a refreshing finish.

  The present invention provides a cleaning composition comprising (A) a polyol, (B) a polyol having an average molecular weight of 5 times or more that of the polyol (A), (C) a nonionic surfactant, an anionic surfactant, and The said objective is achieved by mix | blending 1 type, or 2 or more types of surfactant chosen from the group which consists of an amphoteric surfactant.

  In the cleaning composition of the present invention, the polyol (A) has an average molecular weight of 10,000 or less, preferably 0.001 to 30% by mass, and the polyol (B) is polyol (A). ) And an average molecular weight of 15 times or more, and the blending amount is preferably 0.001 to 30 mass%.

Furthermore, the polyol (A) and the polyol (B) preferably have the same repeating unit, and particularly preferably a repeating unit represented by the following general formula (1).
[Chemical 1]
-(OCH ₂ CH ₂ )-(1)

  According to the present invention, it is possible to provide a cleaning composition that has good foaming and foam quality (creaminess), does not feel wet when rinsed, and has a refreshing finish.

  Hereinafter, embodiments of the present invention will be described in detail.

  The polyol according to the present invention can be used without any particular limitation as long as it is a polyol that can be used as a cleaning composition. For example, a polyhydric alcohol, polyvinyl alcohol, saccharides, etc. are mentioned. Specific examples of the polyhydric alcohol include ethylene glycol, diethylene glycol, triethylene glycol, polyethylene glycol, propylene glycol, dipropylene glycol, polypropylene glycol, glycerin, diglycerin, polyglycerin, and 3-methyl-1,3-butanediol. 1,3-butylene glycol and the like. Specific examples of the saccharide include sorbitol, mannitol, glucose, sucrose, fructose, xylitol, lactose, maltose, maltose, trehalose, erythritol and the like.

As the polyol (A) and polyol (B) according to the present invention, it is preferable to use glycerin (molecular weight 92), propylene glycol and polyethylene glycol among the above-mentioned polyols. Specifically, as polyglycerin, polyglycerin-3 (average molecular weight of about 240), polyglycerin-4 (average molecular weight of about 310), polyglycerin-
6 (average molecular weight of about 460) and polyglycerin-10 (average molecular weight of about 760). Polyethylene glycol includes PEG-4 (average molecular weight of about 190), PEG-6 (average molecular weight of about 280), PEG-8 (average molecular weight of about 370), PEG-12 (average molecular weight of about 550), PEG-16 (Average molecular weight of about 720), PEG-20 (average molecular weight of about 900), PEG-30 (average molecular weight of about 1300), PEG-32 (average molecular weight of about 1400), PEG-40 (average molecular weight of about 1800), PEG-60 (Average molecular weight of about 2700), PEG-75 (average molecular weight of about 3300), PEG-90 (average molecular weight of about 4000), PEG-150 (average molecular weight of about 6600), PEG-180 (average molecular weight of 7900), PEG-240 ( Average molecular weight 11000), PEG-400 (average molecular weight 18000), PEG 2M (average molecular weight 88000), PEG-5M (average molecular weight 220,000), PEG-7M (average molecular weight 310000), PEG-9M (average molecular weight 400000), PEG-14M (average molecular weight 620000), PEG-20M (average molecular weight 880000) ), PEG-23M (average molecular weight of about 1000000), PEG-25M (average molecular weight of about 1100000), PEG-45M (average molecular weight of about 200000), PEG-65M (average molecular weight of about 2900000), PEG-90M (average molecular weight of about 4000000) ), PEG-115M (average molecular weight of about 5100000), and the like.

  As the polyol (A), the above-mentioned various polyols can be used, but the polyol is not limited to one kind, and can be blended in combination. The average molecular weight of the polyol (A) used is preferably 10,000 or less, preferably 4000 or less, and more preferably 1000 or less. The total content when one or more are blended is desirably 0.001 to 30% by mass, preferably 0.001 to 20% by mass, more preferably 0.001 to 10%, based on the mass of the entire cleaning composition. It is more desirable that it is mass%. This condition is suitable for realizing the stability required for the cleaning composition and excellent usability.

The polyol (B) according to the present invention can also use the above-mentioned various polyols as in the case of the polyol (A), but is not limited to one type and can be blended in combination. However, the polyol (B) to be used must have an average molecular weight of 5 times or more, preferably 10 times or more, more preferably 15 times or more compared to the polyol (A). Is desirable. Moreover, it is desirable that the polyol (B) to be used has the same repeating unit and structure as the polyol (A). It is particularly preferable to have a repeating unit represented by the following general formula (1).
[Chemical 1]
-(OCH ₂ CH ₂ )-(1)

  For example, when PEG-4 is used as the polyol (A), the polyol (B) may be PEG-30 having an average molecular weight of 5 times or more compared with the polyol (A), or PEG- having a higher average molecular weight. It is necessary to use 32 or more, preferably PEG-60 that is 10 times or more, or PEG-75 or more that has a higher average molecular weight, more preferably PEG-75 that is 15 times or more, more average A PEG-90 or higher having a large molecular weight may be used. At this time, a plurality of polyols having an average molecular weight 5 times or more that of the polyol (A) may be combined. These combinations are desirable because they have the same repeating unit represented by the general formula (1). Similarly, when glycerin is used as the polyol (A), the polyol (B) may be polyglycerin-6, polyglycerin-10, PEG-12 having an average molecular weight of 5 times or more, or PEG- having a larger average molecular weight. It is necessary to use 16 or more, but since it is desirable that the polyol (B) used has the same repeating unit and structure as the polyol (A), polyglycerin-6 and polyglycerin than those of PEG-12 or more. −10 may be used, and polyglycerin-10 is more preferable.

  Further, the average molecular weight of the polyol (B) needs to be 5 times or more that of the polyol (A). However, if the difference in the average molecular weight is smaller than this, the effect of improving foaming is reduced and it is difficult to realize the actual feeling. . By using these polyols, foaming and foamy creaminess are improved. In the present invention, the total content when one or a plurality of polyols (B) are blended is desirably 0.001 to 30% by mass with respect to the total mass of the present cleaning composition, preferably 0.00. It is more desirable that it is 001-20 mass%, More preferably, it is 0.001-10 mass%. This condition is suitable for realizing the stability required for the cleaning composition and excellent usability.

  Next, in the present invention, it is necessary to add one or more surfactants selected from the group consisting of (C) a nonionic surfactant, an anionic surfactant, and an amphoteric surfactant. It is essential. In the present invention, by blending these, the effect which is the object of the present invention, that is, there is no wetness at the time of rinsing, it has a refreshing wash-up, and foaming and foam quality (creaminess) are further improved. It is preferable in that it can be performed. As such a surfactant, it can be used without particular limitation as long as it can be used as a cosmetic. Examples of the anionic surfactant include potassium laurate and sodium myristate. Various fatty acid salts, palm kernel fatty acid triethanolamine, sodium α-lauroyl sulfonate, sodium myristoyl allyl sulfonate, sodium lauryl naphthalene sulfonate, triethanolamine lauryl sulfate, ammonium lauryl sulfate, sodium lauryl ether sulfate, polyoxyethylene lauryl Sodium ether sulfate (3E.O.), polyoxyethylene coconut oil fatty acid amide ether potassium sulfate, sodium lauryl phosphate, sodium lauroylmethyl taurate, potassium palmitate, coconut oil Nonionic surfactants such as potassium fatty acid, N-coconut oil fatty acid potassium glutamate, palm oil fatty acid monoethanolamide, disodium lauryl sulfosuccinate, sodium polyoxyethylene lauryl ether acetate (4.5EO) Are, for example, polyoxyethylene cetyl ether, sorbitan monostearate, polyoxyethylene sorbitan triisostearate (20E.O.), polyoxyethylene (60) hydrogenated castor oil, polyoxyethylene (6) monoisostearate, poly Oxyethylene (12) glyceryl dioleate, coconut oil fatty acid diethanolamide, coconut oil fatty acid monoethanolamide, coconut oil fatty acid N-methylethanolamide, polyoxyethylene (160) polyoxypropylene (30) glyco , Polyethylene glycol monolaurate (12E.O.) and the like are amphoteric surfactants such as amide propyl betaine laurate, fatty acid amide propyl betaine, lauryl dimethylaminoacetic acid betaine, 2-alkyl-N-carboxymethyl. -N-hydroxyethyl imidazolinium betaine, sodium laurylaminodiacetate, sodium β-aminopropionate, N-lauroyl-N'-carboxymethyl-N'-hydroxyethylethylenediamine sodium, etc. is not. In addition, what is necessary is just to select these 1 type, or 2 or more types as appropriate.

  In addition to the above-described components, the skin cleansing composition of the present invention has other components as long as the object of the present invention is not impaired, such as surfactants other than those described above, hydrocarbons, esters, higher alcohols, polyhydric alcohols, Oils, powders (pigments, dyes, resins, etc.), water, preservatives, fragrances, moisturizers, physiologically active ingredients, salts, solvents, antioxidants, chelating agents, pearling agents, neutralizing agents, pH adjusters, Ingredients such as insect repellents and enzymes can be added as appropriate.

Examples of the oil agent include volatile and non-volatile oil agents, solvents, and resins that are usually used in cosmetics. The oil agent may be a liquid, a paste, or a solid at room temperature, but a liquid that is excellent in handling is preferable. Specifically, as the oil agent, for example, higher alcohols such as cetyl alcohol, isostearyl alcohol, lauryl alcohol, hexadecyl alcohol, octyldodecanol, fatty acids such as isostearic acid, undecylenic acid, oleic acid, myristyl myristate, hexyl laurate , Decyl oleate, isopropyl myristate, hexyl decyl dimethyloctanoate, glyceryl monostearate, diethyl phthalate, ethylene glycol monostearate, octyl oxystearate, hydrocarbons such as liquid paraffin, petrolatum, squalane, Examples include waxes such as lanolin, reduced lanolin, carnauba wax, mink oil, cacao butter, palm oil, palm kernel oil, camellia oil, sesame oil, castor oil, olive oil, and the like. Examples of silicones include dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, polyether-modified organopolysiloxane, fluoroalkyl / polyoxyalkylene co-modified organopolysiloxane, alkyl-modified organopolysiloxane, dimethiconol, and terminal-modified. Examples thereof include silicone compounds such as organopolysiloxane, fluorine-modified organopolysiloxane, amodimethicone, amino-modified organopolysiloxane, silicone gel, acrylic silicone, trimethylsiloxysilicic acid, silicone RTV rubber, and fluorine-modified silicone resin.

  Examples of the powder include pigments such as red No. 201, yellow No. 4, blue No. 1, black No. 401, lake pigments such as yellow No. 4 Al lake, yellow No. 203 Ba lake, nylon powder, silk powder, Silicone powder, cellulose powder, silicone elastomer spherical powder, polymers such as polyethylene powder, yellow iron oxide, red iron oxide, chromium oxide, carbon black, colored pigments such as ultramarine and bitumen, white pigments such as zinc oxide and titanium oxide , Body pigments such as talc, mica, sericite, kaolin, pearl pigments such as titanium mica, metal salts such as barium sulfate, calcium carbonate, magnesium carbonate, magnesium silicate, inorganic powders such as silica and alumina, bentonite, smectite, Examples thereof include boron nitride. There are no particular restrictions on the shape of these powders (spherical, rod-like, needle-like, plate-like, indeterminate, flake-like, spindle-like, etc.).

  The above powder is conventionally known surface treatment such as fluorine compound treatment, silicone treatment, silicone resin treatment, pendant treatment, silane coupling agent treatment, titanium coupling agent treatment, oil agent treatment, N-acylated lysine treatment, polyacrylic. The surface treatment may or may not be performed in advance by acid treatment, metal soap treatment, amino acid treatment, inorganic compound treatment, plasma treatment, mechanochemical treatment, or the like.

  Examples of the solvent include purified water, ethanol, light liquid isoparaffin, lower alcohol, ethers, LPG, fluorocarbon, N-methylpyrrolidone, fluoroalcohol, volatile linear silicone, and next-generation chlorofluorocarbon.

  Examples of the physiologically active ingredient include substances that impart some physiological activity to the skin when applied to the skin. For example, anti-inflammatory agents, anti-aging agents, UV protection agents, tanning agents, antioxidants, moisturizers, blood circulation promoters, antibacterial agents, bactericides, desiccants, cooling agents, warming agents, vitamins, amino acids, Examples include wound healing promoters, stimulus-relieving agents, analgesics, cell activators, enzyme components, and the like. Examples of the physiologically active component include natural plant extract components, seaweed extract components, herbal medicine components, and compounds. Among these, natural plant extract components, seaweed extract components, herbal medicine components are particularly safe. This is preferable.

Examples of the above natural plant extract component, seaweed extract component, herbal medicine component include, for example, Ashitaba extract, Achacha extract, Altea extract, Aloe extract, Apricot extract, Ginkgo biloba extract, Fennel extract, Oolong tea extract, Ages extract, Ogon extract, Oat extract, Hypericum extract, Dutch mustard extract, Orange extract, Seawater dried product, Seaweed extract, Hydrolyzed wheat powder, Hydrolyzed silk, Chamomile extract, Carrot extract, Kawara mugwort extract, Licorice extract, Kiwi extract, Cucumber extract, Gardenia extract, Kumazasa extract, Clara extract, Walnut extract, Grapefruit extract, Chlorella extract, Mulberry extract, Black tea extract, Yeast extract, Rice bran extract, Rice germ oil, Collagen, Carambola fruit fruit , Pomegranate extract, Salvia extract, Soap extract, Hawthorn extract, Giant extract, Shikon extract, Perilla extract, Peony extract, Birch extract, Japanese horse chestnut extract, Horseshoe extract, Hawthorn extract, Elderberry extract, Achillea millefolium extract, Atlantic Peppermint extract, sage extract, senkyu extract, assembly extract, thyme extract, thyme extract, tea extract, tea seed extract, clove extract, chimpi extract, camellia extract, touki extract, tonin extract, dokudami extract, tomato extract, natto extract, carrot extract, Garlic extract, Novara extract, honey, hamamelis extract, toad extract, bisabolol, loquat extract, broom extract, propolis, loofah extract Peppermint extract, body sage extract, hop extract, marronnier extract, mugwort extract, melissa extract, peach extract, peach leaf extract, saxifrage extract, yuzu extract, mugwort extract, lychee seed extract, lavender extract, lemon extract, forsythia extract, rosemary extract, royal jelly An extract etc. can be mentioned.

  Examples of components other than the above-mentioned natural plant extract components, seaweed extract components, and herbal medicine components include deoxyribonucleic acid, mucopolysaccharide, sodium hyaluronate, sodium chondroitin sulfate, collagen, elastin, chitin, chitosan, hydrolyzed eggshell membrane Moisturizing ingredients such as biopolymers such as amino acids, sodium lactate, urea, sodium pyrrolidone carboxylate, betaine, whey, oily ingredients such as sphingolipids, ceramides, cholesterol, cholesterol derivatives, phospholipids, ε-aminocaproic acid, glycyrrhizic acid , Β-glycyrrhetinic acid, lysozyme chloride, guaiazulene, hydrocortisone and other anti-inflammatory agents, vitamins (A, B2, B6, C, D, E), calcium pantothenate, biotin, nicotinamide, vitamin C esters, etc. Active ingredients such as amines, allantoin, diisopropylamine dichloroacetate, 4-aminomethylcyclohexanecarboxylic acid, antioxidants such as tocopherol, carotenoid, flavonoid, tannin, lignan, saponin, α-hydroxy acid, β-hydroxy acid, etc. Cell activators, blood circulation promoters such as γ-oryzanol, vitamin E derivatives, bactericides such as isopropylmethylphenol, triclosan, hinokitiol, benzalkonium chloride, cooling agents such as l-menthol and peppermint oil, retinol, retinol derivatives And wound healing agents.

  The cleaning composition of the present invention can be applied to various cleaning agents such as hair, scalp and various parts of the body, and cleaning agents for tableware, body shampoos, hand soaps, facial cleansers, solid soaps, etc. It can be suitably used as a cleaning agent. Further, it can be used in various forms such as solid, liquid, cream, gel, aerosol foam, pump foam, squeeze foam, mist, and preferably used as a liquid or paste-like cleaning material.

  The cleaning composition of the present invention can be prepared according to various conventional methods. For example, in the case of a body shampoo, it can be prepared by blending all ingredients, heating, neutralizing, mixing, and cooling.

  EXAMPLES Next, although an Example demonstrates this invention in detail, this invention is not limited to these Examples.

Based on the formulations shown in Table 1, the body washes of Examples 1-6 and Comparative Examples 1-5 were prepared according to conventional methods, foaming, foam quality (creaminess), no slickness during rinsing, and no washing Evaluation was made on four items of refreshing feeling. As a practical test, a panel (20 persons) actually used the body cleansing materials shown in Examples and Comparative Examples in a home bathroom, and evaluated the above four items. In the evaluation of each item, a five-step evaluation of very good, good, normal, bad, and very bad was performed. The numbers in Table 1 are the total number of panelists who answered very good or good. All compounding amounts are mass%. The evaluation results are shown in Table 1.

As is clear from the results in Table 1, the body cleaning materials of the examples had no sliminess when rinsed, had a clean wash, and had good foaming and foam quality (creamy properties). However, in the comparative example, it was inferior about each of these items.

  Hereinafter, various cleaning compositions of the present invention were prepared in the same manner as in the method of Table 1 and shown as examples. These can be widely used as cleaning agents such as body soaps and hand soaps. In addition, when these carried out said effect test, the outstanding result was obtained in all.

Example 7
Ingredient Amount (%)
Lauric acid 6.0
Myristic acid 10.0
Palmitic acid 8.0
Stearic acid 8.0
Potassium hydroxide 5.7
Palm oil fatty acid monoethanolamide 1.0
PEG-2M 0.2
PEG-4 2.0
Polyquaternium-7 0.5
Olive oil 0.5
Glycosyl trehalose 1.0
Hydrolyzed hydrogenated starch 1.0
Edetic acid tetrasodium tetrahydrate 0.1
Perfume appropriate amount Ion exchange water Residual

Example 8
Ingredient Amount (%)
Lauric acid 6.0
Myristic acid 10.0
Palmitic acid 8.0
Stearic acid 8.0
Potassium hydroxide 5.7
Lauryl hydroxysultain 1.0
Cationized guar gum 0.1
N-coconut oil fatty acid acyl-L-glutamate potassium 1.0
Hydroxypropyl methylcellulose 0.05
PEG-75 2.0
PEG-4 2.0
Peach leaf extract 1.0
Edetic acid tetrasodium tetrahydrate 0.1
Perfume appropriate amount Ion exchange water Residual

Example 9
Ingredient Amount (%)
Lauric acid 6.0
Myristic acid 10.0
Palmitic acid 8.0
Stearic acid 8.0
Potassium hydroxide 5.7
Lauryl hydroxysultain 1.0
Cationized cellulose 0.1
N-coconut oil fatty acid acyl-L-glutamate potassium 1.0
Hydroxypropyl methylcellulose 0.05
Carboxyvinyl polymer 0.05
PEG-20M 0.01
PEG-75 2.0
Castor oil 0.5
Peach leaf extract 1.0
Edetic acid tetrasodium tetrahydrate 0.1
Perfume appropriate amount Ion exchange water Residual

Example 10
Ingredient Amount (%)
Lauric acid 6.0
Myristic acid 10.0
Palmitic acid 8.0
Stearic acid 8.0
Potassium hydroxide 5.7
Lauryl hydroxysultain 0.5
Lauramidopropyl betaine 0.5
Cationized guar gum 0.05
Cationized cellulose 0.05
Sodium carboxymethylcellulose 0.1
PEG-4 3.0
PEG-7M 0.2
Yuzu fruit extract 1.0
Edetic acid tetrasodium tetrahydrate 0.1
Perfume appropriate amount Ion exchange water Residual

Example 11
Ingredient Amount (%)
Lauric acid 6.0
Myristic acid 10.0
Palmitic acid 8.0
Stearic acid 8.0
Potassium hydroxide 5.7
Cationized guar gum 0.1
Sodium carboxymethylcellulose 0.1
Carboxyvinyl polymer 0.05
PEG-20M 0.01
PEG-20 2.0
Olive oil 0.25
Castor oil 0.25
Aloe vera leaf extract 1.0
Edetic acid tetrasodium tetrahydrate 0.1
Perfume appropriate amount Ion exchange water Residual

Example 12
Ingredient Amount (%)
Lauric acid 6.0
Myristic acid 10.0
Palmitic acid 8.0
Stearic acid 8.0
Potassium hydroxide 5.7
Lauryl hydroxysultain 1.0
Cationized guar gum 0.1
PEG-90M 0.01
PEG-75 2.0
Glycosyl trehalose 1.0
Hydrolyzed hydrogenated starch 1.0
Peach leaf extract 1.0
Yuzu fruit extract 1.0
Edetic acid tetrasodium tetrahydrate 0.1
Perfume appropriate amount Ion exchange water Residual

Example 12
Ingredient Amount (%)
Lauric acid 3.24
Myristic acid 2.0
Palmitic acid 1.5
Stearic acid 0.5
Potassium hydroxide 1.8
Arginine 0.2
Sodium polyoxyethylene lauryl ether sulfate (3E.O) 5.0
Coconut oil fatty acid N-methylethanolamide 2.0
Lauramidopropyl betaine 6.0
Ethylene glycol distearate 1.0
PEG-4 1.0
PEG-2M 0.1
Glycerin 2.0
Rose water 1.0
Edetic acid disodium 0.1
Perfume appropriate amount Ion exchange water Residual

Example 13
Ingredient Amount (%)
Lauric acid 3.0
Myristic acid 2.0
Palmitic acid 1.5
Stearic acid 0.5
Potassium hydroxide 1.8
Sodium polyoxyethylene lauryl ether sulfate (3E.O) 5.0
Coconut oil fatty acid N-methylethanolamide 2.0
Lauramidopropyl betaine 5.5
Lauryl hydroxysulfobetaine solution 0.5
Ethylene glycol distearate 1.0
PEG-4 3.0
PEG-2M 0.3
Glycerin 2.0
Raspberry extract 1.0
Edetic acid disodium 0.1
Perfume appropriate amount Ion exchange water Residual

Example 14
Ingredient Amount (%)
Lauric acid 7.0
Myristic acid 4.0
Palmitic acid 2.0
Stearic acid 1.0
Potassium hydroxide 3.7
Sodium polyoxyethylene lauryl ether sulfate (3E.O) 2.5
Coconut oil fatty acid N-methylethanolamide 2.0
Polyoxyethylene sorbitan monolaurate (20E.O) 5.0
Lauramidopropyl betaine 3.0
Lauric acid amidopropyl betaine solution 1.5
PEG-4 2.0
PEG-65M 0.01
Glycerin 10.0
Pomegranate extract 1.0
Edetic acid disodium 0.1
Perfume appropriate amount Ion exchange water Residual

Claims (4)

A cleaning composition comprising the following components (A) to (C):
(A): Polyol (B): Polyol having an average molecular weight of 5 or more times that of the polyol (A) (C): selected from the group consisting of nonionic surfactants, anionic surfactants and amphoteric surfactants One or more surfactants   The polyol (A) having an average molecular weight of 10,000 or less is contained in an amount of 0.001 to 30% by mass, and the polyol (B) having an average molecular weight 15 times or more that of the polyol (A) is contained in an amount of 0.001 to 30% by mass. The cleaning composition as described.   The cleaning composition according to any one of claims 1 to 3, wherein the polyol (A) and the polyol (B) have the same repeating unit. The cleaning composition according to claim 4, wherein the repeating unit is represented by the following general formula (1).
[Chemical 1]
-(OCH ₂ CH ₂ )-(1)