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JP2010069452A5
JP2010069452A5 JP2008242178A JP2008242178A JP2010069452A5 JP 2010069452 A5 JP2010069452 A5 JP 2010069452A5 JP 2008242178 A JP2008242178 A JP 2008242178A JP 2008242178 A JP2008242178 A JP 2008242178A JP 2010069452 A5 JP2010069452 A5 JP 2010069452A5
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adsorption tower
carbon monoxide
desorption
adsorption
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特公昭61−37968号公報Japanese Patent Publication No. 61-37968 特公昭61−37970号公報Japanese Patent Publication No. 61-37970 特開平5−23524号公報Japanese Patent Laid-Open No. 5-23524

Claims (10)

一酸化炭素吸着剤が充填された吸着塔を用いて、一酸化炭素を含む混合ガスから一酸化炭素を濃縮分離する方法であって、前記吸着塔内が相対的に高圧である状態にて、当該吸着塔に前記混合ガスを導入して当該混合ガス中の一酸化炭素を前記吸着剤に吸着させ且つ当該吸着塔から非吸着ガスを導出する吸着工程と、吸着塔に洗浄ガスを導入し且つ当該吸着塔から非吸着ガスを導出する洗浄工程と、前記吸着塔内を降圧して、前記吸着剤から一酸化炭素を脱着させ且つ当該吸着塔から脱着ガスを導出する脱着工程と、を含むサイクルを繰り返し行う一酸化炭素分離方法において、
前記脱着工程は、前記洗浄工程が終了した後の当該脱着工程の開始から途中までにおいて前記吸着塔から第1脱着ガスを導出する第1脱着工程と、前記吸着塔から第2脱着ガスを導出する、前記第1脱着工程の後の第2脱着工程とを含み、前記第2脱着ガスを分離取得する、一酸化炭素分離方法。
A method of concentrating and separating carbon monoxide from a mixed gas containing carbon monoxide using an adsorption tower filled with a carbon monoxide adsorbent, wherein the inside of the adsorption tower is at a relatively high pressure, An adsorption step of introducing the mixed gas into the adsorption tower to adsorb carbon monoxide in the mixed gas to the adsorbent and deriving a non-adsorbed gas from the adsorption tower; introducing a cleaning gas into the adsorption tower; A cycle comprising: a washing step for deriving non-adsorbed gas from the adsorption tower; and a desorption step for depressurizing the inside of the adsorption tower to desorb carbon monoxide from the adsorbent and derive desorbed gas from the adsorption tower. In the carbon monoxide separation method of repeatedly performing
The desorption step includes a first desorption step of deriving a first desorption gas from the adsorption tower and starting a second desorption gas from the adsorption column from the start to the middle of the desorption step after the cleaning step is completed. And a second desorption step after the first desorption step, and separating and acquiring the second desorption gas.
一酸化炭素吸着剤が充填された複数の吸着塔を用いて、一酸化炭素を含む混合ガスから一酸化炭素を濃縮分離する方法であって、吸着塔に前記混合ガスを導入して当該吸着塔内の圧力を上昇させる昇圧工程と、吸着塔に前記混合ガスを導入して当該混合ガス中の一酸化炭素を前記吸着剤に吸着させ且つ当該吸着塔から非吸着ガスを導出する吸着工程と、吸着塔に洗浄ガスを導入し且つ当該吸着塔から非吸着ガスを導出する洗浄工程と、吸着塔内を降圧して、前記吸着剤から一酸化炭素を脱着させ且つ当該吸着塔から脱着ガスを導出する脱着工程と、を含むサイクルを、前記吸着塔の各々において繰り返し行う一酸化炭素分離方法において、
前記脱着工程は、前記洗浄工程が終了した後の当該脱着工程の開始から途中までにおいて吸着塔から第1脱着ガスを導出する第1脱着工程と、当該吸着塔から第2脱着ガスを導出する、前記第1脱着工程の後の第2脱着工程とを含み、前記第2脱着ガスを分離取得する、一酸化炭素分離方法。
A method of concentrating and separating carbon monoxide from a mixed gas containing carbon monoxide using a plurality of adsorption towers filled with a carbon monoxide adsorbent, wherein the mixed gas is introduced into the adsorption tower, and the adsorption tower A pressure-increasing step for increasing the internal pressure, an adsorption step for introducing the mixed gas into an adsorption tower, adsorbing carbon monoxide in the mixed gas to the adsorbent, and deriving a non-adsorbed gas from the adsorption tower; A cleaning step of introducing a cleaning gas into the adsorption tower and deriving a non-adsorbed gas from the adsorption tower, and depressurizing the inside of the adsorption tower to desorb carbon monoxide from the adsorbent and derive a desorption gas from the adsorption tower. In the carbon monoxide separation method in which a cycle including a desorption step is repeatedly performed in each of the adsorption towers,
The desorption step includes a first desorption step of deriving the first desorption gas from the adsorption tower from the start to the middle of the desorption step after the cleaning step is completed, and deriving a second desorption gas from the adsorption tower. And a second desorption step after the first desorption step, and separating and obtaining the second desorption gas.
前記昇圧工程は、前記第1脱着工程にある吸着塔から導出された第1脱着ガスを前記混合ガスとともに昇圧対象の吸着塔に導入する第1昇圧工程と、当該吸着塔に前記混合ガスを導入する、前記第1昇圧工程の後の第2昇圧工程とを含む、請求項2に記載の一酸化炭素分離方法。   The boosting step includes a first boosting step of introducing the first desorption gas derived from the adsorption tower in the first desorption step into the adsorption tower to be boosted together with the mixed gas, and introducing the mixed gas into the adsorption tower. The carbon monoxide separation method according to claim 2, further comprising: a second boosting step after the first boosting step. 前記洗浄工程は、前記第1脱着工程にある吸着塔から導出された第1脱着ガスを前記洗浄ガスとして洗浄対象の吸着塔に導入する第1洗浄工程と、分離取得された前記第2脱着ガスを前記洗浄ガスとして洗浄対象の当該吸着塔に導入する、前記第1洗浄工程の後の第2洗浄工程とを含む、請求項2に記載の一酸化炭素分離方法。   The cleaning step includes a first cleaning step of introducing the first desorption gas derived from the adsorption tower in the first desorption step into the adsorption tower to be cleaned as the cleaning gas, and the second desorption gas obtained separately. The carbon monoxide separation method according to claim 2, further comprising: a second cleaning step after the first cleaning step, wherein the gas is introduced into the adsorption tower to be cleaned as the cleaning gas. 前記第2洗浄工程では、前記第2脱着工程にある吸着塔から導出された第2脱着ガスも前記洗浄ガスとして洗浄対象の吸着塔に導入する、請求項4に記載の一酸化炭素分離方法。   5. The carbon monoxide separation method according to claim 4, wherein, in the second cleaning step, the second desorption gas derived from the adsorption tower in the second desorption step is also introduced into the adsorption tower to be cleaned as the cleaning gas. 前記第1脱着工程において吸着塔から導出される第1脱着ガスの総量は、当該吸着塔から導出される第1脱着ガスの流量に基づいて制御される、請求項1から5のいずれか一つに記載の一酸化炭素分離方法。   The total amount of the first desorption gas derived from the adsorption tower in the first desorption step is controlled based on the flow rate of the first desorption gas derived from the adsorption tower. The carbon monoxide separation method described in 1. 前記第1脱着工程において吸着塔から導出される第1脱着ガスの総量は、当該第1脱着工程にある吸着塔の内部圧力に基づいて制御される、請求項1から5のいずれか一つに記載の一酸化炭素分離方法。   The total amount of the first desorption gas derived from the adsorption tower in the first desorption step is controlled based on the internal pressure of the adsorption tower in the first desorption step. The carbon monoxide separation method described. 前記第1脱着工程において吸着塔から導出される第1脱着ガスの総量は、当該第1脱着工程の開始からの時間に基づいて制御される、請求項1から5のいずれか一つに記載の一酸化炭素分離方法。   The total amount of the first desorption gas led out from the adsorption tower in the first desorption step is controlled based on the time from the start of the first desorption step. Carbon monoxide separation method. 請求項2に記載の一酸化炭素分離方法により、一酸化炭素を含む混合ガスから一酸化炭素を濃縮分離するための装置であって、
第1ガス通過口および第2ガス通過口を有し当該第1および第2ガス通過口の間において一酸化炭素吸着剤が充填された複数の吸着塔と、
ガス吸入口およびガス送出口を有するガス送出手段と、
前記吸着塔の内部を減圧するための減圧手段と、
一酸化炭素を貯留するための容器と、
混合ガス導入端を有し且つ前記ガス送出手段の前記ガス吸入口に接続された第1配管と、
前記ガス送出手段の前記ガス送出口に接続された主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第1ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第2配管と、
ガス排出端を有する主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第2ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第3配管と、
前記減圧手段に接続された主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第1ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第4配管と、
前記減圧手段および前記容器の間を連結し且つ開閉弁が付設された第5配管と、
前記容器に接続された主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第1ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第6配管と、
前記第5配管における前記開閉弁よりも前記減圧手段側の箇所および前記第1配管の間を連結し且つ開閉弁が付設された第7配管と、を備える一酸化炭素分離装置。
An apparatus for concentrating and separating carbon monoxide from a mixed gas containing carbon monoxide by the carbon monoxide separation method according to claim 2 ,
A plurality of adsorption towers having a first gas passage opening and a second gas passage opening and filled with a carbon monoxide adsorbent between the first and second gas passage openings;
Gas delivery means having a gas inlet and a gas outlet;
Decompression means for decompressing the inside of the adsorption tower;
A container for storing carbon monoxide;
A first pipe having a mixed gas introduction end and connected to the gas inlet of the gas delivery means;
A main trunk connected to the gas delivery port of the gas delivery means, and a plurality of parts provided for each adsorption tower and connected to the first gas passage opening side of the adsorption tower and provided with an on-off valve. A second pipe having a branch,
A third pipe having a main passage having a gas discharge end and a plurality of branch passages provided for each of the adsorption towers and connected to the second gas passage side of the adsorption tower and provided with on-off valves When,
A main passage connected to the decompression means, and a plurality of branch passages provided for each of the adsorption towers and connected to the first gas passage opening side of the adsorption tower and provided with on-off valves. 4 pipes,
A fifth pipe connected between the decompression means and the container and provided with an on-off valve;
A sixth main passage connected to the vessel, and a plurality of branch passages provided for each adsorption tower and connected to the first gas passage side of the adsorption tower and provided with on-off valves. Piping,
A carbon monoxide separation device comprising: a seventh pipe connected to a position closer to the pressure reducing means than the on-off valve in the fifth pipe and between the first pipe and provided with an on-off valve.
請求項2に記載の一酸化炭素分離方法により、一酸化炭素を含む混合ガスから一酸化炭素を濃縮分離するための装置であって、
第1ガス通過口および第2ガス通過口を有し当該第1および第2ガス通過口の間において一酸化炭素吸着剤が充填された複数の吸着塔と、
ガス吸入口およびガス送出口を有するガス送出手段と、
前記吸着塔の内部を減圧するための減圧手段と、
一酸化炭素を貯留するための容器と、
混合ガス導入端を有し且つ前記ガス送出手段の前記ガス吸入口に接続された第1配管と、
前記ガス送出手段の前記ガス送出口に接続された主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第1ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第2配管と、
ガス排出端を有する主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第2ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第3配管と、
前記減圧手段に接続された主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第1ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第4配管と、
前記減圧手段および前記容器の間を連結し且つ開閉弁が付設された第5配管と、
前記容器に接続され且つ開閉弁が付設された主幹路、および、前記吸着塔ごとに設けられて当該吸着塔の前記第1ガス通過口側に接続され且つ開閉弁が付設された複数の分枝路、を有する第6配管と、
前記第5配管における前記開閉弁よりも前記減圧手段側の箇所、および、前記第6配管の前記主幹路における前記開閉弁よりも前記吸着塔側の箇所を連結し、且つ、開閉弁が付設された、第7配管と、を備える一酸化炭素分離装置。
An apparatus for concentrating and separating carbon monoxide from a mixed gas containing carbon monoxide by the carbon monoxide separation method according to claim 2 ,
A plurality of adsorption towers having a first gas passage opening and a second gas passage opening and filled with a carbon monoxide adsorbent between the first and second gas passage openings;
Gas delivery means having a gas inlet and a gas outlet;
Decompression means for decompressing the inside of the adsorption tower;
A container for storing carbon monoxide;
A first pipe having a mixed gas introduction end and connected to the gas inlet of the gas delivery means;
A main trunk connected to the gas delivery port of the gas delivery means, and a plurality of parts provided for each adsorption tower and connected to the first gas passage opening side of the adsorption tower and provided with an on-off valve. A second pipe having a branch,
A third pipe having a main passage having a gas discharge end and a plurality of branch passages provided for each of the adsorption towers and connected to the second gas passage side of the adsorption tower and provided with on-off valves When,
A main passage connected to the decompression means, and a plurality of branch passages provided for each of the adsorption towers and connected to the first gas passage opening side of the adsorption tower and provided with on-off valves. 4 pipes,
A fifth pipe connected between the decompression means and the container and provided with an on-off valve;
A main trunk connected to the vessel and provided with an opening / closing valve; and a plurality of branches provided for each adsorption tower and connected to the first gas passage opening side of the adsorption tower and provided with an opening / closing valve. A sixth pipe having a path;
A location closer to the pressure reducing means than the on-off valve in the fifth piping and a location closer to the adsorption tower than the on-off valve in the main passage of the sixth piping are connected, and an on-off valve is attached. A carbon monoxide separator comprising a seventh pipe.
JP2008242178A 2008-09-22 2008-09-22 Method for separating carbon monoxide and carbon monoxide separation apparatus Pending JP2010069452A (en)

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