JP2010039263A5 - - Google Patents

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JP2010039263A5
JP2010039263A5 JP2008202912A JP2008202912A JP2010039263A5 JP 2010039263 A5 JP2010039263 A5 JP 2010039263A5 JP 2008202912 A JP2008202912 A JP 2008202912A JP 2008202912 A JP2008202912 A JP 2008202912A JP 2010039263 A5 JP2010039263 A5 JP 2010039263A5
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magnetic toner
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electrostatic charge
charge image
fine powder
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Claims (9)

静電荷像を担持するための静電荷像担持体を、該静電潜像担持体に接触配置した帯電部材によって帯電し、帯電された静電荷像担持体に静電荷像を形成し、トナー担持体に担持された磁性トナーによって静電荷像を現像してトナー像を形成する工程を有する画像形成方法であり、
該静電荷像担持体は、25℃、湿度50%の環境下でビッカース四角錐ダイヤモンド圧子を用い度試において、荷重5mNで押し込んだ時の弾性変形率が30%以上45%以下であり、
磁性トナーは結着樹脂及び磁性体を含む磁性トナー粒子と、無機微粉体及び有機微粉体とを含
該磁性トナーは、下記式(1)
圧縮率={1−(見掛け密度/タップ密度)}×100 式(1)
から得られる圧縮率が30%以下であり、
該有機微粉体が個数平均粒径(D1)0.05μm以上1.00μm以下の樹脂粒子であり、
該樹脂粒子の該磁性トナー粒子からの遊離率が3質量%以下であることを特徴とする画像形成方法
An electrostatic charge image carrier for carrying an electrostatic charge image is charged by a charging member placed in contact with the electrostatic latent image carrier, and an electrostatic charge image is formed on the charged electrostatic image carrier to carry a toner. developing the electrostatic image by a magnetic toner carried on the body is an image forming how to have a process for forming a toner image,
Electrostatic charge image bearing member, 25 ° C., under humidity of 50% in hard Do試 test using Vickers quadrangular pyramid diamond indenter, an elastic deformation rate when pushed by the load 5mN less than 45% 30% Yes,
The magnetic toner, viewed contains a binder resin and a magnetic material including magnetic toner particles and an inorganic fine powder and organic fine powder,
The magnetic toner has the following formula (1)
Compression rate = {1- (apparent density / tap density)} × 100 Formula (1)
The compression ratio obtained from is 30% or less,
The organic fine powder is a resin particle having a number average particle diameter (D1) of 0.05 μm or more and 1.00 μm or less,
An image forming method, wherein a liberation rate of the resin particles from the magnetic toner particles is 3% by mass or less.
該静電荷像担持体が、その表面層が下記式(2)
Figure 2010039263
(式(2)中、Xは単結合、−O−、−S−又は置換もしくは無置換のアルキリデン基を示す。R11〜R18は同一又は異なって、水素原子、ハロゲン原子、アルコキシ基、ニトロ基、置換もしくは無置換のアルキル基又は置換もしくは無置換のアリール基を示す。)
で示され、且つ重量平均分子量(Mw)が7.5×103以上2.0×104以下である構成単位を有するポリカーボネート樹脂を5質量%以上30質量%以下含有する感光体であることを特徴とする請求項1に記載の画像形成方法
The electrostatic charge image carrier has a surface layer represented by the following formula (2):
Figure 2010039263
(In the formula (2), X represents a single bond, —O—, —S—, or a substituted or unsubstituted alkylidene group. R 11 to R 18 are the same or different and represent a hydrogen atom, a halogen atom, an alkoxy group, A nitro group, a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group is indicated.)
In indicated, and the weight average molecular weight (Mw) of Ru photoreceptor der containing 30 mass% or less than 5 wt% of a polycarbonate resin having a structural unit is 7.5 × 10 3 or more 2.0 × 10 4 or less the image forming method according to claim 1, wherein the this.
該磁性トナーの粉体流動性測定装置において測定されたTotal Energyが下記式(3)及び(4)
800≦TE10≦1400 式(3)
TE10/TE100≦1.60 式(4)
(TE10;撹拌速度が10回転の時のTotal Energy、TE100;撹拌速度が100回転の時のTotal Energy)
を満足することを特徴とする請求項1または2に記載の画像形成方法
The total energy measured with the powder flowability measuring device of the magnetic toner is expressed by the following formulas (3) and (4).
800 ≦ TE 10 ≦ 1400 Formula (3)
TE 10 / TE 100 ≦ 1.60 Formula (4)
(TE 10 ; Total Energy when the stirring speed is 10 revolutions, TE 100 ; Total Energy when the stirring speed is 100 revolutions)
The image forming method according to claim 1, wherein:
該樹脂粒子のBET法で測定される比表面積が10m2/g以上80m2/g以下であり、重量平均分子量(Mw)が5万以上100万以下であることを特徴とする請求項1乃至3のいずれかに記載の画像形成方法The specific surface area of the resin particles measured by the BET method is 10 m 2 / g or more and 80 m 2 / g or less, and the weight average molecular weight (Mw) is 50,000 or more and 1,000,000 or less. 4. The image forming method according to any one of 3 above. 該磁性トナーは、磁場79.6kA/mで着磁されたときの残留磁化が3.0Am2/kg以下であることを特徴とする請求項1乃至4のいずれかに記載の画像形成方法5. The image forming method according to claim 1 , wherein the magnetic toner has a residual magnetization of 3.0 Am 2 / kg or less when magnetized at a magnetic field of 79.6 kA / m. 該磁性トナーは、該磁性トナー粒子が懸濁重合法で製造されたトナー粒子であることを特徴とする請求項1乃至のいずれかに記載の画像形成方法Magnetic toner, image forming method according to any one of claims 1 to 5, characterized in that the magnetic toner particles are toner particles produced by suspension polymerization. 該磁性トナーは、該磁性トナー粒子が熱処理による表面改質工程を含む粉砕法により製造されたことを特徴とする請求項1乃至5のいずれかに記載の画像形成方法The image forming method according to claim 1, wherein the magnetic toner is produced by a pulverization method in which the magnetic toner particles include a surface modification step by heat treatment. 静電荷像担持体、及び、磁性トナーを有する現像容器を有するプロセスカートリッジであり、
該静電荷像担持体は、25℃、湿度50%の環境下でビッカース四角錐ダイヤモンド圧子を用いて硬度を試験した時、荷重5mNで押し込んだ時の弾性変形率が30%以上45%以下であり、
該磁性トナーは、結着樹脂及び磁性体を含む磁性トナー粒子と、無機微粉体及び有機微粉体とを含み、
該磁性トナーは、下記式(1)
圧縮率={1−(見掛け密度/タップ密度)}×100 式(1)
から得られる圧縮率が30%以下であり、
該有機微粉体が個数平均粒径(D1)0.05μm以上1.00μm以下の樹脂粒子であり、
該樹脂粒子の該磁性トナー粒子からの遊離率が3質量%以下であることを特徴とするプロセスカートリッジ。
A process cartridge having an electrostatic charge image carrier and a developer container having magnetic toner;
The electrostatic charge image bearing member has an elastic deformation ratio of 30% or more and 45% or less when pressed with a load of 5 mN when tested for hardness using a Vickers square pyramid diamond indenter in an environment of 25 ° C. and 50% humidity. Yes,
The magnetic toner includes magnetic toner particles containing a binder resin and a magnetic material, inorganic fine powder and organic fine powder,
The magnetic toner has the following formula (1)
Compression rate = {1- (apparent density / tap density)} × 100 Formula (1)
The compression ratio obtained from is 30% or less,
The organic fine powder is a resin particle having a number average particle diameter (D1) of 0.05 μm or more and 1.00 μm or less,
A process cartridge having a release rate of the resin particles from the magnetic toner particles of 3% by mass or less .
静電荷像を担持するための静電荷像担持体を、該静電荷像担持体に接触配置した帯電部材によって帯電し、帯電された静電荷像担持体に静電荷像を形成し、トナー担持体に担持された磁性トナーによって静電荷像を現像してトナー像を形成する工程を有する画像形成方法に適用される磁性トナーであり、An electrostatic charge image carrier for carrying an electrostatic charge image is charged by a charging member disposed in contact with the electrostatic charge image carrier, and an electrostatic charge image is formed on the charged electrostatic charge image carrier, thereby forming a toner carrier. A magnetic toner applied to an image forming method including a step of developing an electrostatic charge image with a magnetic toner carried on the toner to form a toner image;
該静電荷像担持体は、25℃、湿度50%の環境下でビッカース四角錐ダイヤモンド圧子を用いて硬度を試験した時、荷重5mNで押し込んだ時の弾性変形率が30%以上45%以下であり、The electrostatic charge image bearing member has an elastic deformation rate of 30% or more and 45% or less when pressed with a load of 5 mN when tested for hardness using a Vickers square pyramid diamond indenter in an environment of 25 ° C. and 50% humidity. Yes,
該磁性トナーは、結着樹脂及び磁性体を含む磁性トナー粒子と、無機微粉体及び有機微粉体とを含み、The magnetic toner includes magnetic toner particles containing a binder resin and a magnetic material, inorganic fine powder and organic fine powder,
該磁性トナーは、下記式(1)The magnetic toner has the following formula (1)
圧縮率={1−(見掛け密度/タップ密度)}×100 式(1)Compression rate = {1- (apparent density / tap density)} × 100 Formula (1)
から得られる圧縮率が30%以下であり、The compression ratio obtained from is 30% or less,
該有機微粉体が個数平均粒径(D1)0.05μm以上1.00μm以下の樹脂粒子であり、The organic fine powder is a resin particle having a number average particle diameter (D1) of 0.05 μm or more and 1.00 μm or less,
該樹脂粒子の該磁性トナー粒子からの遊離率が3質量%以下であることを特徴とする磁性トナー。A magnetic toner, wherein the resin particles have a liberation rate of 3% by mass or less from the magnetic toner particles.
JP2008202912A 2008-08-06 2008-08-06 Image forming method and process cartridge Active JP5230296B2 (en)

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EP2616884B1 (en) 2010-09-16 2017-12-13 Canon Kabushiki Kaisha Toner
JP2012068589A (en) * 2010-09-27 2012-04-05 Mitsubishi Chemicals Corp Image formation device and process cartridge
JP5879691B2 (en) * 2011-02-17 2016-03-08 富士ゼロックス株式会社 Image forming apparatus and image forming method
JP6100106B2 (en) * 2012-06-27 2017-03-22 キヤノン株式会社 toner
JP6008001B2 (en) * 2015-02-03 2016-10-19 三菱化学株式会社 Image forming apparatus and process cartridge
JP6821389B2 (en) * 2016-10-25 2021-01-27 キヤノン株式会社 Toner manufacturing method
JP6965528B2 (en) * 2017-03-02 2021-11-10 富士フイルムビジネスイノベーション株式会社 Image forming device and removal method
JP2019191448A (en) * 2018-04-27 2019-10-31 キヤノン株式会社 toner

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JPH08160663A (en) * 1994-12-01 1996-06-21 Dainippon Ink & Chem Inc Manufacture of electrophotographic toner
JP2000194158A (en) * 1998-10-23 2000-07-14 Canon Inc Image forming device and process cartridge
JP4402276B2 (en) * 2000-10-20 2010-01-20 キヤノン株式会社 Electrophotographic photosensitive member, process cartridge having the electrophotographic photosensitive member, and electrophotographic apparatus
JP2006195156A (en) * 2005-01-13 2006-07-27 Canon Inc Toner and image forming method
US7371495B2 (en) * 2005-03-15 2008-05-13 Kabushiki Kaisha Toshiba Toner

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