JP2010019332A - Manufacturing method and device of foam roller - Google Patents

Manufacturing method and device of foam roller Download PDF

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JP2010019332A
JP2010019332A JP2008180135A JP2008180135A JP2010019332A JP 2010019332 A JP2010019332 A JP 2010019332A JP 2008180135 A JP2008180135 A JP 2008180135A JP 2008180135 A JP2008180135 A JP 2008180135A JP 2010019332 A JP2010019332 A JP 2010019332A
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roller
foam
rubber foam
foaming
irradiation
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Koichi Sato
公一 佐藤
Toshihiko Takahashi
俊彦 高橋
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Canon Chemicals Inc
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Canon Chemicals Inc
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a manufacturing method of a foam roller capable of increasing the cell opening area to an area within a specified range by opening closed cells at the peripheral surface of a rubber foam body produced through the molding process of the foam roller and suppressing fluctuation of the opening area. <P>SOLUTION: The manufacturing method for a foam roller includes a foam roller molding process to shape a cylindrical rubber foam body using a die on the periphery of a core metal, and a cell opening process to cast a TEA-CO<SB>2</SB>laser beam onto the rubber foam body peripheral surface of the molded roller so as to at least open the cell surface of the rubber foam body. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、芯金の外周にゴム発泡体を形成した発泡ローラの製造方法及び発泡ローラの製造装置に関する。詳しくは、電子写真方式の画像形成装置に適宜用いられるトナー供給ローラ、現像ローラ、帯電ローラ、転写ローラ等各種ウレタン発泡ローラの製造方法及び製造装置に関する。   The present invention relates to a foaming roller manufacturing method and a foaming roller manufacturing apparatus in which a rubber foam is formed on the outer periphery of a metal core. More specifically, the present invention relates to a manufacturing method and manufacturing apparatus for various urethane foam rollers such as a toner supply roller, a developing roller, a charging roller, and a transfer roller, which are appropriately used in an electrophotographic image forming apparatus.

発泡ローラのゴム発泡体には、隔壁で区切られた各セルが連通する連続気泡体と、各セルが連通せず独立する独立気泡体がある。また、ゴム発泡体の外周面にスキン層が形成されたものと、スキン層が形成されずゴム発泡体外周面のセルが開口したものが有る。画像形成装置のローラには、温度変化によるゴム発泡体の外形変化が少ない連続気泡体を有し、印字用紙やトナーの搬送力を得るため、表面の摩擦抵抗が大きい外周面のセルが開口したゴム発泡体を有するものが多く使用されている。   The rubber foam of the foaming roller includes an open cell body in which cells separated by a partition communicate with each other and a closed cell body in which each cell does not communicate and is independent. Also, there are those in which a skin layer is formed on the outer peripheral surface of the rubber foam and those in which the skin layer is not formed and cells on the outer peripheral surface of the rubber foam are opened. The roller of the image forming apparatus has an open cell body in which the external shape change of the rubber foam due to the temperature change is small, and an outer peripheral cell having a large surface frictional resistance is opened in order to obtain a conveyance force for printing paper and toner. Many having a rubber foam are used.

連続気泡体を有し、ゴム発泡体外周面のセルが開口した発泡ローラの製造方法には、製造工程の短縮化が比較的容易な型成形方法が用いられている。即ち、成形型にゴム原料を注型し、該ゴム原料の硬化工程で発泡及び開口させるものである。ここで、ゴム発泡体の連続気泡体は、ゴム原料の硬化と気泡化の競争反応により形成され、一定の安定したセル径を得るには緻密な製造条件の管理を必要とする。加えて、ゴム発泡体表面のセルの開口は、ゴム原料が直接接触する離型剤や離型剤を介して接触する成形型の表面粗さ、成形サイクルを重ねるに伴いゴム原料や離型剤が成形型表面に堆積する型汚れ等の影響を強く受ける。このため、未開口のセルが多くなったり、セル開口面積がゴム発泡体の場所によりばらつく開口ムラ等の欠陥が生じる場合があり、安定して高品質の発泡ローラを得るのは容易ではなかった。   As a method for manufacturing a foam roller having an open cell body and having cells on the outer peripheral surface of a rubber foam, a molding method in which the manufacturing process can be shortened relatively easily is used. That is, a rubber raw material is cast into a mold, and foamed and opened in a curing step of the rubber raw material. Here, the open cell body of the rubber foam is formed by a competitive reaction between the curing of the rubber raw material and the bubble formation, and it is necessary to manage the manufacturing conditions precisely in order to obtain a certain stable cell diameter. In addition, the opening of the cell on the surface of the rubber foam is the surface roughness of the mold that comes in contact with the rubber raw material directly through the mold release agent, the rubber raw material and the mold release agent as the molding cycle is repeated. Is strongly affected by mold dirt and the like accumulated on the mold surface. For this reason, there are cases where the number of unopened cells increases, or defects such as unevenness of the opening in which the cell opening area varies depending on the location of the rubber foam, and it is not easy to stably obtain a high-quality foaming roller. .

そこで、このような開口ムラ等の欠陥を解決する発泡ローラ表面のセル開口方法が提案されている。例えば、多数の針を具備した冶具をゴム発泡体表面に突き刺し、穿孔する方法がある(例えば、特許文献1参照)。また、軟質ポリウレタンフォーム表面のスキン層にプラズマ照射し、セルを開口する方法がある(例えば、特許文献2参照)。また、成形型の離型剤にフッ素樹脂コーティングを施したものも有る(例えば、特許文献3参照)。
特開2001−114926号公報 特開2002−039162号公報 特開平09−274373号公報
Thus, a cell opening method on the surface of the foaming roller that solves such defects as opening unevenness has been proposed. For example, there is a method of piercing and punching a jig having a large number of needles on the surface of a rubber foam (see, for example, Patent Document 1). Further, there is a method in which a skin layer on the surface of a flexible polyurethane foam is irradiated with plasma to open a cell (for example, see Patent Document 2). There is also a mold release agent that is coated with a fluororesin (see, for example, Patent Document 3).
JP 2001-114926 A JP 2002-039162 A JP 09-274373 A

しかしながら、上述した従来の針を突き刺す方法では、セルを機械的に裂く方法であり、ゴム発泡体の連続気泡化はできるが、発泡体表面の一部を選択的に除去する所謂アブレーション加工は困難である。そのため、ゴム発泡体のセル開口面積のバラツキを抑えるように、所定範囲の面積にセル開口を拡大することはできない。また、針の温度をゴム発泡体の溶融温度以上に昇温させてゴム発泡体に刺すことにより、針に接触したゴム発泡体が溶融または軟化することでセル開口が拡大するが、針に溶融したゴム材が付着する場合があり、安定して一定の開口率(ゴム発泡体外周表面積中の発泡体外周面のセル開口面積をいう、以下開口率と記す場合がある。)を得ることが難しい。   However, the conventional method of piercing the needle described above is a method of mechanically tearing the cell, and the foamed rubber foam can be made open, but the so-called ablation process for selectively removing a part of the foam surface is difficult. It is. Therefore, the cell opening cannot be enlarged to an area within a predetermined range so as to suppress variation in the cell opening area of the rubber foam. In addition, when the temperature of the needle is raised above the melting temperature of the rubber foam and stabbed into the rubber foam, the cell foam expands as the rubber foam in contact with the needle melts or softens. In some cases, the rubber material adheres, and it is possible to stably obtain a certain opening ratio (referred to as the opening ratio of the cell outer peripheral surface of the foam in the rubber foam outer surface area, hereinafter referred to as the opening ratio). difficult.

また、上述ポリウレタンフォームのスキン層をプラズマ照射しセルを開口する方法は、プラズマトーチから噴出する高温で高エネルギー密度のプラズマを連続照射するものである。プラズマの照射の制御は、被加工物とプラズマトーチの移動に限られ、微細パルス的なプラズマ照射時間の制御が困難である。特にゴム発泡体のセル隔壁が薄い場合、セル隔壁の厚みのバラツキにより隔壁を含め発泡ローラ表面が溶融し、発泡ローラの外径が縮小したり、表面にシワが発生したり、逆にセル開口部の閉口が生じたりと、安定した開口率が得られない場合がある。また、成形型の離型層に弗素樹脂コーティングを施したものは、成形回数を重ねると成形型に局部的にゴム材料が残留し、セル開口ムラの原因になる場合がある。   The method of opening the cell by irradiating the skin layer of the polyurethane foam with plasma is to continuously irradiate high-energy density plasma ejected from a plasma torch. Control of plasma irradiation is limited to the movement of the workpiece and the plasma torch, and it is difficult to control the plasma irradiation time in the form of fine pulses. Especially when the cell partition of rubber foam is thin, the foam roller surface including the partition melts due to the variation in the thickness of the cell partition, the outer diameter of the foam roller is reduced, the surface is wrinkled, and the cell opening is reversed. If a part is closed, a stable aperture ratio may not be obtained. In addition, when the mold release layer of the mold is coated with a fluorine resin, the rubber material may locally remain in the mold when the number of molding is repeated, which may cause unevenness of the cell opening.

本発明は、発泡ローラの成形工程で生じたゴム発泡体外周面の未開口セルを開口し、また開口面積のバラツキを抑え、所定範囲の面積にセル開口を拡大可能な発泡ローラの製造方法及び製造装置を提供することを目的とする。   The present invention relates to a method for producing a foam roller that opens an unopened cell on the outer peripheral surface of a rubber foam produced in the foaming roller molding step, suppresses variation in the opening area, and expands the cell opening to a predetermined area. An object is to provide a manufacturing apparatus.

本発明は、このような従来の問題を解決できる発泡ローラの製造方法、製造装置を提供するものである。   The present invention provides a foaming roller manufacturing method and manufacturing apparatus capable of solving such conventional problems.

(1)本発明に係る発泡ローラの製造方法は、芯金の外周に円筒状のゴム発泡体を型成形する発泡ローラ成形工程と、成形された該発泡ローラのゴム発泡体外周面にTEA−CO2レーザ光をパルス照射し、少なくとも該ゴム発泡体のセル表面を開口するセル開口工程と、を含むことを特徴とする。 (1) A method for producing a foam roller according to the present invention includes a foam roller molding step in which a cylindrical rubber foam is molded on the outer periphery of a core metal, and a rubber foam outer peripheral surface of the molded foam roller. A cell opening step of irradiating at least the cell surface of the rubber foam with pulse irradiation of CO 2 laser light.

(2)また、本発明に係る発泡ローラの製造装置は、TEA−CO2レーザ発振器で生成したレーザ光を発泡ローラのゴム発泡体外周面の照射面形状に整形し、該発泡ローラのゴム発泡体外周面にレーザ光を導くレーザ光照射手段と、前記発泡ローラの芯金部を把持し発泡ローラの芯金を中心に回動させるローラ回動手段と、前記ローラ回動手段を前記発泡ローラの軸方向に移動させるローラ移動手段と、前記レーザ光照射手段、前記ローラ回動手段及び前記ローラ移動手段を連動させ、前記発泡ローラのゴム発泡体外周面全体に亘りレーザ光を逐次パルス照射する制御手段と、を具備することを特徴とする。 (2) Further, the foaming roller manufacturing apparatus according to the present invention shapes the laser beam generated by the TEA-CO 2 laser oscillator into an irradiation surface shape of the rubber foam outer peripheral surface of the foaming roller, and rubber foaming of the foaming roller. Laser beam irradiating means for guiding laser light to the outer peripheral surface of the body, roller rotating means for gripping the cored bar portion of the foaming roller and rotating about the cored bar of the foaming roller, and the roller rotating means for the foaming roller The roller moving means for moving in the axial direction, the laser light irradiating means, the roller rotating means and the roller moving means are interlocked to sequentially irradiate laser light over the entire outer peripheral surface of the rubber foam of the foam roller. And a control means.

(3)また、本発明に係る発泡ローラの製造装置は、前記レーザ照射手段と、発泡ローラのゴム発泡体外周面との間に、該ゴム発泡体外周面へのレーザ光の照射を制限するための遮光マスクを有し、前記遮光マスクには、前記ゴム発泡体の平均セル径の0.5〜2.0倍の幅を有する複数のスリット、或いは、前記ゴム発泡体の平均セル径の0.5〜2.0倍の直径を有する複数の円形孔が存在することを特徴とする。   (3) In addition, the foaming roller manufacturing apparatus according to the present invention limits the irradiation of the laser foam outer peripheral surface between the laser irradiation means and the rubber foam outer peripheral surface of the foaming roller. A plurality of slits having a width of 0.5 to 2.0 times the average cell diameter of the rubber foam, or the average cell diameter of the rubber foam. A plurality of circular holes having a diameter of 0.5 to 2.0 times exist.

(4)前記スリット間の非照射幅が、前記ゴム発泡体の平均セル径の0.5倍以上であり、前記円形孔間の非照射幅が、前記ゴム発泡体の平均セル径の0.3倍以上であることを特徴とする。   (4) The non-irradiation width between the slits is 0.5 times or more the average cell diameter of the rubber foam, and the non-irradiation width between the circular holes is 0. 0 of the average cell diameter of the rubber foam. It is characterized by being 3 times or more.

(5)また、本発明に係る発泡ローラの製造方法は、前記(2)乃至(4)のいずれかに記載の発泡ローラの製造装置を用いて、発泡ローラを製造することを特徴とする。   (5) Moreover, the manufacturing method of the foaming roller which concerns on this invention manufactures a foaming roller using the manufacturing apparatus of the foaming roller in any one of said (2) thru | or (4), It is characterized by the above-mentioned.

(6)また、本発明に係る発泡ローラは、前記(1)又は(5)に記載の発泡ローラの製造方法により製造されることを特徴とする。   (6) Moreover, the foaming roller which concerns on this invention is manufactured by the manufacturing method of the foaming roller as described in said (1) or (5).

本発明によれば、TEA−CO2レーザ光をゴム発泡体の表面にパルス照射することで、発泡ローラの成形工程で生じたゴム発泡体外周面の未開口セルを開口でき、また開口面積のバラツキを抑え、所定範囲の面積にセル開口を拡大させることができる。これにより、印字用紙やトナーの搬送力に優れる、表面の摩擦抵抗が大きい発泡ローラを安定して製造することが可能となる。 According to the present invention, by irradiating the surface of the rubber foam with TEA-CO 2 laser light, unopened cells on the outer peripheral surface of the rubber foam generated in the molding process of the foaming roller can be opened. Variations can be suppressed and the cell opening can be enlarged to a predetermined area. As a result, it is possible to stably produce a foaming roller having a high surface frictional resistance and excellent transporting force for printing paper and toner.

本発明に係る発泡ローラの製造方法は、芯金の外周に円筒状のゴム発泡体を型成形する発泡ローラ成形工程と、成形された該発泡ローラのゴム発泡体外周面にTEA−CO2レーザ光をパルス照射し、該ゴム発泡体のセル表面を開口するセル開口工程とを含む。 The foaming roller manufacturing method according to the present invention includes a foaming roller molding step in which a cylindrical rubber foam is molded on the outer periphery of a core metal, and a TEA-CO 2 laser on the outer peripheral surface of the molded foamed rubber foam. A cell opening step of irradiating light with a pulse to open the cell surface of the rubber foam.

前記発泡ローラの成形工程において、発泡ローラの成形品は公知の方法で作成される。例えば、成形型の円筒状キャビティの両端部に装着する型駒で芯金を支持し、例えば、ポリイソシアネート、ポリオール、水、触媒等を主成分とする発泡ウレタンゴム原料を注型機で攪拌混合する。前記原料を金型のキャビティに注型し、所定時間加熱することで芯金の外周にゴム発泡体を形成し、芯金と一体化したゴム発泡体を芯金諸共成形型から脱型することで発泡ローラの成形品を得る。   In the foaming roller molding step, the foamed roller molded product is prepared by a known method. For example, a metal core is supported by mold pieces attached to both ends of a cylindrical cavity of a molding die, and, for example, a foamed urethane rubber raw material mainly composed of polyisocyanate, polyol, water, catalyst, etc. is stirred and mixed with a casting machine. To do. The raw material is poured into a mold cavity and heated for a predetermined time to form a rubber foam around the core metal, and the rubber foam integrated with the core metal is removed from the core metal co-molding mold. To obtain a molded product of a foam roller.

前記ゴム発泡体の原料としては、所謂軟質ウレタンフォームの各種ウレタン原料が適用できる。例えば、ポリエステル、ポリエーテル、ポリカーボネート他のポリオールが、またポリイソシアネートとしては、ジフェニルメタンジイソシアネート(MDI)、トリレンジイソシアネート(TDI)、ナフタレンジイソシアネート(NDI)、ヘキサメチレンジイソシアネート(HDI)、イソホロンジイソシアネート(IPDI)、キシリレンジイソシアネート(XDI)他が単独または複数併用され、触媒、発泡剤、整泡剤他と共に用いられる。発泡方法としては、発泡剤として水を用いる水発泡法或いは原料中に細かな空気を混合するメカニカルフロス法等が例示できる。   As the raw material of the rubber foam, various urethane raw materials of so-called flexible urethane foam can be applied. For example, polyester, polyether, polycarbonate and other polyols, and polyisocyanates include diphenylmethane diisocyanate (MDI), tolylene diisocyanate (TDI), naphthalene diisocyanate (NDI), hexamethylene diisocyanate (HDI), isophorone diisocyanate (IPDI). Xylylene diisocyanate (XDI) and the like are used alone or in combination, and are used together with a catalyst, a foaming agent, a foam stabilizer and the like. Examples of the foaming method include a water foaming method using water as a foaming agent, or a mechanical floss method in which fine air is mixed in the raw material.

前記セル開口工程において、前記発泡ローラの成形品のゴム発泡体外周面に照射するレーザ光には、TEA−CO2レーザ発振器で発生させたレーザ光を用いる。 In the cell opening step, a laser beam generated by a TEA-CO 2 laser oscillator is used as the laser beam irradiated to the rubber foam outer peripheral surface of the foamed roller molded product.

前記レーザ光は、発泡ローラのゴム発泡体外周面にパルス照射される。TEA−CO2レーザでは1μsecのパルス照射が可能であり、その照射面積もYAGレーザ等照射面積の小さいスポットではなく比較的広範囲のエリアを同時に照射できる。 The laser beam is applied to the rubber foam outer peripheral surface of the foam roller in a pulsed manner. The TEA-CO 2 laser can irradiate a pulse of 1 μsec, and the irradiation area can be simultaneously irradiated over a relatively wide area, not a spot with a small irradiation area such as a YAG laser.

レーザ光照射によるセルの開口は、セル骨格部(スキン層内側のセル形成領域)とセル薄肉部(スキン層)の微細な熱容量差によると考えられ、照射パルス数、照射間隔、照射時間等の照射条件を適宜選択することにより、セル開口径を均質化することができる。また、ゴム発泡体の変形を抑え、ゴム発泡体表面に発生するシワを低減することができる。   The opening of the cell due to laser light irradiation is thought to be due to a minute heat capacity difference between the cell skeleton (cell formation area inside the skin layer) and the cell thin part (skin layer), and the number of irradiation pulses, irradiation interval, irradiation time, etc. By appropriately selecting the irradiation conditions, the cell opening diameter can be homogenized. Further, deformation of the rubber foam can be suppressed and wrinkles generated on the rubber foam surface can be reduced.

さらに、レーザ光の照射により、ゴム発泡体表面のセル薄肉部がアブレーションされ、セル未開口部が開口し、セルが開口している部分の開口面積も拡大し、セル開口率が増加する。例えば、図2に示すように、ゴム発泡体41表面のセル開口不十分部41bにレーザ光照射をすることにより、セル開口十分部41aのごとくセル開口率を向上させ、セル開口径を均質化することができる。   Furthermore, by the irradiation of the laser beam, the cell thin portion on the surface of the rubber foam is ablated, the cell non-opening portion is opened, the opening area of the portion where the cell is opened is enlarged, and the cell opening ratio is increased. For example, as shown in FIG. 2, by applying laser light to the cell opening insufficient portion 41b on the surface of the rubber foam 41, the cell opening ratio is improved like the cell opening sufficient portion 41a, and the cell opening diameter is homogenized. can do.

前記セル開口工程には、図1に示す発泡ローラの製造装置を用いることができる。   The foaming roller manufacturing apparatus shown in FIG. 1 can be used for the cell opening step.

まず、発泡ローラ4を、ローラ移動手段5上のローラ回動手段3上に載せ、芯金部を支持させた後、ローラ回動手段3を起動させ、発泡ローラ4を周方向に回動させる。その後、レーザ1を発泡ローラ4表面に照射する。レーザ光1の照射は、回動する発泡ローラ4をゴム発泡体の軸方向一端からゴム発泡体の軸方向他端の位置までローラ移動手段5により移動させることで、ゴム発泡体外周表面全体をスキャニングしつつレーザ光1を逐次パルス照射する。   First, the foaming roller 4 is placed on the roller rotating unit 3 on the roller moving unit 5 and the cored bar portion is supported. Then, the roller rotating unit 3 is activated to rotate the foaming roller 4 in the circumferential direction. . Thereafter, the surface of the foaming roller 4 is irradiated with the laser 1. The laser beam 1 is irradiated by moving the rotating foam roller 4 from one end of the rubber foam in the axial direction to the position of the other end in the axial direction of the rubber foam by the roller moving means 5, thereby The laser beam 1 is sequentially pulsed while scanning.

レーザ光1のパルス照射は、不図示の制御手段により、レーザ光照射手段、ローラ回動手段3、ローラ移動手段5と連動させて行われる。具体的には、制御手段は公知の制御技術でよく、図5は制御手段の概念図で、統合コントローラは、回動手段の回動ドライバ、移動手段の移動ドライバ及びレーザ光照射手段の照射ドライバと電気信号を入出可能に接続される。回動ドライバにはエンコーダ付きのサーボモータの回動モータが、移動ドライバにはエンコーダ付きのサーボモータの移動モータが、照射ドライバにはレーザ発振器が各々接続される。統合コントローラはパソコン或いはシーケンサが用いられ、回動、移動、照射の各手ドライバにパルス信号を適宜送信することで、回動手段の回転方向、回転速度及び回転数を、移動手段の移動方向、移動速度及び移動量を、照射手段の照射パルス速度及び照射パルス数等を制御することで、ゴム発泡体の回転と軸方向の移動及びレーザ照射を連動させゴム発泡体の外周表面全体に亘りレーザ光を照射する。通常、回動、移動の各手段は高精度な制御が可能なフィードバック制御が用いられる。   The pulse irradiation of the laser beam 1 is performed in conjunction with the laser beam irradiation unit, the roller rotating unit 3 and the roller moving unit 5 by a control unit (not shown). Specifically, the control means may be a known control technique. FIG. 5 is a conceptual diagram of the control means. The integrated controller includes a rotation driver for the rotation means, a movement driver for the movement means, and an irradiation driver for the laser light irradiation means. And electrical signals can be input / output. A rotation motor of a servo motor with an encoder is connected to the rotation driver, a movement motor of a servo motor with an encoder is connected to the movement driver, and a laser oscillator is connected to the irradiation driver. As the integrated controller, a personal computer or a sequencer is used, and by appropriately transmitting a pulse signal to each driver of rotation, movement, and irradiation, the rotation direction, rotation speed, and number of rotations of the rotation unit are changed. By controlling the movement speed and movement amount, the irradiation pulse speed and the number of irradiation pulses of the irradiation means, the rotation of the rubber foam and the movement in the axial direction and the laser irradiation are linked, and the laser is applied to the entire outer peripheral surface of the rubber foam. Irradiate light. Usually, feedback control capable of highly accurate control is used for each means of rotation and movement.

前記レーザ光1の照射には、例えば図4に示すレーザ照射装置100を用いることができる。   For the irradiation with the laser beam 1, for example, a laser irradiation apparatus 100 shown in FIG. 4 can be used.

図4のレーザ照射装置100は、レーザ照射手段としてTEA−CO2(Transversely Excited Atmospheric Pressure−CO2)レーザ光学系を用いる。レーザ発振器101からのレーザ光を反射ミラー103にて方向変換し、一次遮光マスク102でレーザ光外縁部のレーザ出力密度の不安定部を除去し、シリンドリカルレンズ104で集光し矩形の照射面形状に整形される。更に、整形されたレーザ光1は直接或いは遮光マスク2を経由して発泡ローラ4のゴム発泡体外周面に照射される。 The laser irradiation apparatus 100 of FIG. 4 uses a TEA-CO 2 (Transversally Excited Atmospheric Pressure-CO 2 ) laser optical system as laser irradiation means. The direction of the laser beam from the laser oscillator 101 is changed by the reflection mirror 103, the unstable portion of the laser output density at the outer edge of the laser beam is removed by the primary light shielding mask 102, and the rectangular irradiation surface shape is condensed by the cylindrical lens 104. To be shaped. Further, the shaped laser beam 1 is irradiated to the rubber foam outer peripheral surface of the foaming roller 4 directly or via the light shielding mask 2.

前記遮光マスク2によりレーザ光照射部とレーザ光非照射部を隣接させることにより、レーザ光照射部のアブレーションによるゴム発泡体の変形をレーザ非照射部即ち非加熱部が制限する。これにより、遮光マスク2を使用しない場合と比較して、ゴム発泡体表面に発生するシワを低減できる。   By making the laser light irradiation part and the laser light non-irradiation part adjacent to each other by the light shielding mask 2, the laser non-irradiation part, that is, the non-heating part, restricts deformation of the rubber foam due to the ablation of the laser light irradiation part. Thereby, the wrinkles which generate | occur | produce on the rubber foam surface can be reduced compared with the case where the light shielding mask 2 is not used.

図3は、本発明で利用可能な遮光マスク2の例を示す。本発明では、遮光マスク2a、2b、2c及び2dのいずれも用いることができるが、発泡ローラの回動速度、移動速度及びレーザ光パルス照射速度等のレーザ光の照射条件により、遮光マスク2a、2b、2c及び2dから適宜選択される。   FIG. 3 shows an example of a light shielding mask 2 that can be used in the present invention. In the present invention, any of the light shielding masks 2a, 2b, 2c, and 2d can be used. Depending on the laser light irradiation conditions such as the rotation speed, movement speed, and laser light pulse irradiation speed of the foam roller, the light shielding mask 2a, It is appropriately selected from 2b, 2c and 2d.

遮光マスク2aには、発泡ローラ軸方向に対し傾斜したスリット状の照射窓2a1が存在する。遮光マスク2bには、発泡ローラ軸方向に平行なスリット状の照射窓2b1が存在する。遮光マスク2cには、発泡ローラ軸方向に直交するスリット状の照射窓2c1が存在する。遮光マスク2dには、円形状の照射孔2d1が存在する。   The light shielding mask 2a has a slit-shaped irradiation window 2a1 that is inclined with respect to the direction of the foaming roller axis. The light shielding mask 2b has a slit-shaped irradiation window 2b1 parallel to the axial direction of the foaming roller. The light shielding mask 2c has a slit-shaped irradiation window 2c1 orthogonal to the direction of the foam roller axis. The light shielding mask 2d has a circular irradiation hole 2d1.

遮光マスク2a、2b及び2cの照射窓2a1、2b1及び2c1のスリット幅は、ゴム発泡体の平均セル径の0.5倍以上、2倍以下であることが好ましい。また、遮光マスク2dの照射窓(円形孔)2d1の直径は、ゴム発泡体の平均セル径の0.5倍以上、2倍以下が好ましい。照射窓2a1、2b1及び2c1のスリット幅及び照射窓2d1の直径がゴム発泡体の平均セル径の0.5倍未満のとき、加工時間が延長したり、ゴム発泡体セルの開口が不十分となる場合がある。逆に、照射窓2a1、2b1及び2c1のスリット幅及び照射窓2d1の直径がゴム発泡体の平均セル径の2倍を超えるとき、ゴム発泡体の表面が荒れる場合がある。   The slit widths of the irradiation windows 2a1, 2b1, and 2c1 of the light shielding masks 2a, 2b, and 2c are preferably 0.5 times or more and 2 times or less of the average cell diameter of the rubber foam. The diameter of the irradiation window (circular hole) 2d1 of the light shielding mask 2d is preferably 0.5 times or more and 2 times or less the average cell diameter of the rubber foam. When the slit width of the irradiation windows 2a1, 2b1 and 2c1 and the diameter of the irradiation window 2d1 are less than 0.5 times the average cell diameter of the rubber foam, the processing time is extended or the opening of the rubber foam cell is insufficient. There is a case. Conversely, when the slit widths of the irradiation windows 2a1, 2b1 and 2c1 and the diameter of the irradiation window 2d1 exceed twice the average cell diameter of the rubber foam, the surface of the rubber foam may be roughened.

照射窓2a1、2b1及び2c1のスリット間の非照射幅、ゴム発泡体の平均セル径の0.5倍以上、照射窓2d1の円形孔間の照射部の間隔は、ゴム発泡体の平均セル径の0.3倍以上であれば、ゴム発泡体表面のシワ発生を抑制できるため好ましい。   The non-irradiation width between the slits of the irradiation windows 2a1, 2b1 and 2c1, 0.5 times the average cell diameter of the rubber foam, and the distance between the irradiation parts between the circular holes of the irradiation window 2d1 are the average cell diameter of the rubber foam. If it is 0.3 times or more, the occurrence of wrinkles on the surface of the rubber foam can be suppressed, which is preferable.

ここで、ゴム発泡体の平均セル径は、ゴム発泡体を軸に対して垂直方向に輪切し、輪切されたゴム発泡体の外周近傍で、各セルの最大径で切断されていると思われるセルを10個選択し、光学顕微鏡で該セルの直径を測定し、各セルの直径を加算し、加算したセルの個数で除算し算出したものである。また、セルの開口率(%)は、ゴム発泡体表面の軸方向直線上10mm間にある全セルの開口長を光学顕微鏡で測定・加算し、この加算値を測定範囲長で除算し、100倍して算出したものである。   Here, the average cell diameter of the rubber foam is obtained by cutting the rubber foam in a direction perpendicular to the axis, and cutting the maximum diameter of each cell in the vicinity of the outer periphery of the rubber foam. This was calculated by selecting 10 possible cells, measuring the diameter of the cells with an optical microscope, adding the diameters of the cells, and dividing the result by the number of added cells. Further, the cell opening ratio (%) is obtained by measuring and adding the opening lengths of all the cells between 10 mm on the straight line in the axial direction of the rubber foam surface with an optical microscope, and dividing the added value by the measurement range length. It is calculated by multiplying.

なお、遮光マスクのレーザ照射窓形状は、図3に示した遮光マスク2a、2b、2c及び2dの照射窓形状に限らず、レーザ光が通過すれば良く、また、遮光マスクの加工が容易な丸穴、長穴に限らず楕円、多角形穴等でも良い。   The shape of the laser irradiation window of the light shielding mask is not limited to the shape of the irradiation windows of the light shielding masks 2a, 2b, 2c, and 2d shown in FIG. 3, and it is sufficient that laser light passes, and the processing of the light shielding mask is easy. Not only a round hole and a long hole but an ellipse, a polygon hole, etc. may be sufficient.

また、図4では遮光マスク2を使用する例を示したが、ゴム発泡体のセル骨格とセル薄肉部の厚みの比が、即ちセル骨格部の熱容量がセル薄肉部の熱容量より十分大きい場合は、遮光マスク2が無い場合でも、セル薄肉部に対してセル骨格部のアブレーションされる度合が軽微であるため、ゴム発泡体41のセル開口率を増加させることができる。   FIG. 4 shows an example in which the light shielding mask 2 is used. However, when the ratio of the thickness of the cell skeleton of the rubber foam to the thin portion of the cell, that is, the heat capacity of the cell skeleton is sufficiently larger than the heat capacity of the thin portion of the cell. Even when the light shielding mask 2 is not provided, since the degree of ablation of the cell skeleton portion relative to the thin cell portion is slight, the cell opening ratio of the rubber foam 41 can be increased.

また、図4ではレーザ照射手段として、短パルス照射で一時に比較的大面積のレーザ照射が可能なTEA−CO2レーザ発振器を例示したが、同様の機能を有するレーザ光なら良く、エキシマレーザ発振器も適用可能である。 In FIG. 4, a TEA-CO 2 laser oscillator capable of performing laser irradiation of a relatively large area at a time by short pulse irradiation is exemplified as the laser irradiation means. However, a laser beam having the same function may be used, and an excimer laser oscillator Is also applicable.

本発明に係る製造方法により得られる発泡ローラは、電子写真装置に用いられるトナー除去・供給ローラ、現像ローラ、帯電ローラ、転写ローラ等に用いることができる。なお、トナー除去・供給ローラとは、現像ローラと当接し、現像ローラ上に残留する旧トナーを摺擦除去すると同時に、新トナーを現像ローラ上に供給するローラである。   The foaming roller obtained by the production method according to the present invention can be used for a toner removing / supplying roller, a developing roller, a charging roller, a transfer roller and the like used in an electrophotographic apparatus. The toner removing / supplying roller is a roller that contacts the developing roller and removes old toner remaining on the developing roller by rubbing and simultaneously supplies new toner onto the developing roller.

[実施例1]
以下、本発明の実施例を説明するが、本発明はこれら実施例に限定されるものではない。なお、「部」は質量基準である。
[Example 1]
Examples of the present invention will be described below, but the present invention is not limited to these examples. “Part” is based on mass.

発泡ローラのゴム発泡体の原料として、以下に示すA系原料及びB系原料を用いた。   As raw materials for the rubber foam of the foaming roller, the following A-based raw materials and B-based raw materials were used.

A系原料には、以下の化合物を予め混合したものを用いた。   As the A-based material, a mixture of the following compounds in advance was used.

ポリエーテルポリオール(商品名:「FA−908」、三洋化成工業(株)製)90部
ポリマーポリオール(商品名:「POP−31−28」、三井武田ケミカル(株)製)10部
第3級アミン触媒(商品名:「TOYOCAT−ET」、東ソー(株)製)0.10部
第3級アミン触媒(商品名:「TOYOCAT−MR」、東ソー(株)製)0.30部
水(発泡剤)2部
シリコン整泡剤(商品名:「L5366」、日本ユニカー(株)製)1部。
90 parts of polyether polyol (trade name: “FA-908”, manufactured by Sanyo Chemical Industries) 10 parts of polymer polyol (trade name: “POP-31-28”, manufactured by Mitsui Takeda Chemical Co., Ltd.) Amine catalyst (trade name: “TOYOCAT-ET”, manufactured by Tosoh Corporation) 0.10 parts Tertiary amine catalyst (trade name: “TOYOCAT-MR”, manufactured by Tosoh Corporation) 0.30 parts Water (foaming) Agent) 2 parts 1 part of silicone foam stabilizer (trade name: “L5366”, manufactured by Nippon Unicar Co., Ltd.).

また、B系原料には、イソシアネート(商品名:「コロネート1025」、日本ポリウレタン工業(株)製)22部を用いた。   In addition, 22 parts of isocyanate (trade name: “Coronate 1025”, manufactured by Nippon Polyurethane Industry Co., Ltd.) was used as the B-based material.

まず、成形型の円筒状キャビティの両端部に装着する型駒で棒鋼に無電解ニッケルメッキを施した芯金を支持した。次に、注型機にA系、B系原料を投入し、注型機の混合ヘッドで攪拌し、60℃に予熱された前記成形型に注型・硬化させた。その後脱型し、ローラ端部を突切り、発泡ローラの成形品を得た。得られた発泡ローラの成形品のゴム発泡体の発泡状態を調べた結果、セル開口径の分布、セル開口率は表2に示す通りであった。   First, a metal core having electroless nickel plating applied to a steel bar was supported by mold pieces attached to both ends of a cylindrical cavity of a mold. Next, A-type and B-type raw materials were charged into the casting machine, stirred with the mixing head of the casting machine, and cast and cured into the molding die preheated to 60 ° C. Thereafter, the mold was removed, and the end of the roller was cut off to obtain a foamed roller molded product. As a result of examining the foaming state of the rubber foam of the obtained foamed roller molded product, the cell opening diameter distribution and the cell opening ratio were as shown in Table 2.

その後、図1に示す発泡ローラの製造装置及び図4に示すTEA−CO2レーザ照射装置を用いて、前記発泡ローラの成形品のゴム発泡体表面に対してレーザ光を照射した。TEA−CO2レーザ照射装置100には、「IMPACT2500」(商品名、(株)篠崎製作所製)を用いた。レーザ発振器101出口でのレーザ光のサイズは、長さ9mm×幅8mmであり、これを一次遮光マスク102に通してレーザ光のサイズを長さ8mm×幅7mmにカットした。さらに、シリンドリカルレンズ104でゴム発泡体の表面に接するレーザ光1のサイズが、長さ8mm×幅2mmに集光するよう調節し、レーザ光の長さ方向が発泡ローラ4の軸方向と平行になるようにした。レーザ光1のサイズより大きい照射窓範囲を有する遮光マスク2は、図4に示すように発泡ローラ4の軸中心と同心となるように、また、ゴム発泡体の表面までの距離が5mmとなるように配置した。また、遮光マスク2には、図3に示す遮光マスク2aを用いた。遮光マスク2aの照射窓2a1のスリット幅は900μmであり、ゴム発泡体の平均セル径の1.5倍であった。 Thereafter, using the foaming roller manufacturing apparatus shown in FIG. 1 and the TEA-CO 2 laser irradiation apparatus shown in FIG. 4, the rubber foam surface of the foamed roller molded product was irradiated with laser light. As the TEA-CO 2 laser irradiation apparatus 100, “IMPACT 2500” (trade name, manufactured by Shinozaki Seisakusho Co., Ltd.) was used. The size of the laser beam at the exit of the laser oscillator 101 was 9 mm long × 8 mm wide, and this was passed through the primary shading mask 102 to cut the size of the laser beam into 8 mm long × 7 mm wide. Further, the size of the laser beam 1 in contact with the surface of the rubber foam with the cylindrical lens 104 is adjusted so as to be condensed to 8 mm in length × 2 mm in width, and the length direction of the laser beam is parallel to the axial direction of the foaming roller 4. It was made to become. The shading mask 2 having an irradiation window range larger than the size of the laser beam 1 is concentric with the center of the axis of the foaming roller 4 as shown in FIG. 4, and the distance to the surface of the rubber foam is 5 mm. Arranged. As the light shielding mask 2, the light shielding mask 2a shown in FIG. The slit width of the irradiation window 2a1 of the light shielding mask 2a was 900 μm, which was 1.5 times the average cell diameter of the rubber foam.

表1に示すレーザ照射条件で、図1に示す製造装置を用いてゴム発泡体表面にレーザを照射したところ、レーザ照射前には図2の41bに示されるような開口ムラがあったのに対し、レーザ照射後には41aに示されるように開口ムラが減少した。また、表2に示すように、レーザ照射後のセル開口径の分布及びセル開口率は共に大幅に改善した。また、レーザ照射前後での発泡ローラの外形の変化及び発泡ローラ表面のシワの発生は認められなかった。本実施例で得られた発泡ローラは、トナー除去・供給ローラとして用いた場合、高い性能を示した。   Under the laser irradiation conditions shown in Table 1, when the surface of the rubber foam was irradiated using the manufacturing apparatus shown in FIG. 1, there was opening unevenness as shown by 41b in FIG. 2 before the laser irradiation. On the other hand, after the laser irradiation, the opening unevenness decreased as shown by 41a. Moreover, as shown in Table 2, both the cell aperture diameter distribution and the cell aperture ratio after laser irradiation were greatly improved. In addition, no change in the outer shape of the foam roller before and after laser irradiation and no occurrence of wrinkles on the surface of the foam roller were observed. The foaming roller obtained in this example showed high performance when used as a toner removal / supply roller.

[実施例2]
発泡ローラのゴム発泡体の原料のうち、ウレタン発泡用泡化触媒である第3級アミン触媒(商品名:「TOYOCAT−ET」、東ソー(株)製)の量を、0.10部から0.07部に減量した以外は、実施例1と同一原料、同一条件で成形した。これにより、ゴム発泡体表面にスキン層が形成された発泡ローラの成形品を得た。
[Example 2]
The amount of tertiary amine catalyst (trade name: “TOYOCAT-ET”, manufactured by Tosoh Corporation), which is a foaming catalyst for foaming urethane, of the rubber foam raw material of the foaming roller is reduced from 0.10 parts to 0. Molding was performed using the same raw materials and the same conditions as in Example 1 except that the amount was reduced to 0.07 parts. As a result, a foamed roller molded product having a skin layer formed on the surface of the rubber foam was obtained.

この発泡ローラの成形品を実施例1と同一条件でレーザ光を照射したところ、表2に示すようにセル開口径の分布及びセル開口率共に大幅に改善した。また、レーザ照射前後での発泡ローラの外形の変化及び発泡ローラ表面のシワの発生は認められなかった。本実施例で得られた発泡ローラは、トナー除去・供給ローラとして用いた場合、高い性能を示した。   When the molded product of the foaming roller was irradiated with laser light under the same conditions as in Example 1, both the cell opening diameter distribution and the cell opening ratio were greatly improved as shown in Table 2. In addition, no change in the outer shape of the foam roller before and after laser irradiation and no occurrence of wrinkles on the surface of the foam roller were observed. The foaming roller obtained in this example showed high performance when used as a toner removal / supply roller.

[実施例3]
実施例1の遮光マスク2aを他の遮光マスク2b、2cの長円の照射窓2b1、2c1に変更する以外実施例1の装置及び加工品を使用し、ゴム発泡体全表面に亘りレーザ光を照射したところ、実施例1と同様の効果が得られた。また実施例1の装置及び加工品を使用し、遮光マスク2dの照射窓2d1の直径を前記長円の幅と同一にした遮光マスクを使用しゴム発泡体全表面に亘りレーザ光を照射したところ、セル開口率は80(%)と僅かに低下したがシワの発生は長円より更に改善した。
[Example 3]
Except for changing the light-shielding mask 2a of Example 1 to the elliptical irradiation windows 2b1 and 2c1 of the other light-shielding masks 2b and 2c, the apparatus and processed product of Example 1 were used, and laser light was applied to the entire surface of the rubber foam. When irradiated, the same effect as in Example 1 was obtained. Further, when the apparatus and processed product of Example 1 were used and the light shielding mask having the same diameter of the irradiation window 2d1 of the light shielding mask 2d as the width of the ellipse was used, the entire surface of the rubber foam was irradiated with the laser beam. The cell opening ratio slightly decreased to 80 (%), but the generation of wrinkles was further improved from that of an ellipse.

Figure 2010019332
Figure 2010019332

Figure 2010019332
Figure 2010019332

本発明に係る発泡ローラの製造装置を用いた、発泡ローラのゴム発泡体表面へのレーザ照射状態の斜視図である。It is a perspective view of the laser irradiation state to the rubber foam surface of a foaming roller using the manufacturing apparatus of the foaming roller which concerns on this invention. 本発明に係る製造方法により製造された発泡ローラのゴム発泡体表面の発泡状態を示す部分拡大図である。It is the elements on larger scale which show the foaming state of the rubber foam surface of the foaming roller manufactured by the manufacturing method which concerns on this invention. 本発明に係る製造装置に用いる各種遮光マスクを示す斜視図である。It is a perspective view which shows the various light shielding masks used for the manufacturing apparatus which concerns on this invention. 本発明に係る製造方法に用いるTEA−CO2レーザ照射装置の概略図である。It is a schematic diagram of a TEA-CO 2 laser irradiation apparatus used in the production method according to the present invention. 本発明に係る製造装置に用いる制御手段の概念図である。It is a conceptual diagram of the control means used for the manufacturing apparatus which concerns on this invention.

符号の説明Explanation of symbols

1 レーザ光
2 遮光マスク
2a 発泡ローラ軸方向に対し傾斜した照射窓を有する遮光マスク
2a1 発泡ローラ軸方向に対し傾斜した照射窓
2b 発泡ローラ軸方向に平行な照射窓を有する遮光マスク
2b1 発泡ローラ軸方向に平行な照射窓
2c 発泡ローラ軸方向に垂直な照射窓を有する遮光マスク
2c1 発泡ローラ軸方向に垂直な照射窓
2d 円形状の照射窓を有する遮光マスク
2d1 円形状の照射窓
3 ローラ回動手段
4 発泡ローラ
5 ローラ移動手段
41 ゴム発泡体
41a レーザ照射前の開口状態
41b レーザ照射後の開口状態
42 芯金
100 レーザ照射装置
101 TEA−CO2レーザ発振器
102 一次遮光マスク
103 反射ミラー
104 シリンドリカルレンズ
DESCRIPTION OF SYMBOLS 1 Laser beam 2 Shading mask 2a Shading mask 2a1 which has irradiation window inclined with respect to foaming roller axial direction Irradiation window 2b which inclined with respect to foaming roller axial direction Shading mask 2b1 which has irradiation window parallel to foaming roller axial direction Foaming roller axis Irradiation window 2c parallel to the direction Light-shielding mask 2c1 having an irradiation window perpendicular to the foaming roller axial direction Irradiation window 2d perpendicular to the foaming-roller axial direction Light-shielding mask 2d1 having a circular irradiation window 3 Circular irradiation window 3 Roller rotation Means 4 Foam roller 5 Roller moving means 41 Rubber foam 41a Open state before laser irradiation 41b Open state after laser irradiation 42 Core metal 100 Laser irradiation device 101 TEA-CO 2 laser oscillator 102 Primary light shielding mask 103 Reflective mirror 104 Cylindrical lens

Claims (6)

芯金の外周に円筒状のゴム発泡体を型成形する発泡ローラ成形工程と、
成形された該発泡ローラのゴム発泡体外周面にTEA−CO2レーザ光をパルス照射し、少なくとも該ゴム発泡体のセル表面を開口するセル開口工程と、
を含むことを特徴とする発泡ローラの製造方法。
A foaming roller molding process in which a cylindrical rubber foam is molded on the outer periphery of the core metal;
A cell opening step of irradiating the rubber foam outer peripheral surface of the molded foam roller with a pulse of TEA-CO 2 laser light to open at least the cell surface of the rubber foam;
A method for producing a foam roller, comprising:
TEA−CO2レーザ発振器で発生させたレーザ光を発泡ローラのゴム発泡体外周面の照射面形状に整形し、該発泡ローラのゴム発泡体外周面にレーザ光を導くレーザ光照射手段と、
前記発泡ローラの芯金部を支持し、該発泡ローラの芯金を中心に回動させるローラ回動手段と、
前記ローラ回動手段を前記発泡ローラの軸方向に移動させるローラ移動手段と、
前記レーザ光照射手段、前記ローラ回動手段及び前記ローラ移動手段を連動させ、前記発泡ローラのゴム発泡体外周面の全体に亘りレーザ光を逐次パルス照射する制御手段と、
を具備することを特徴とする発泡ローラの製造装置。
Laser light irradiation means for shaping the laser light generated by the TEA-CO 2 laser oscillator into an irradiation surface shape of the rubber foam outer peripheral surface of the foam roller, and guiding the laser light to the rubber foam outer peripheral surface of the foam roller;
Roller rotating means for supporting the cored bar portion of the foaming roller and rotating the cored bar of the foaming roller;
Roller moving means for moving the roller rotating means in the axial direction of the foaming roller;
Control means for sequentially irradiating laser light over the entire rubber foam outer peripheral surface of the foaming roller by interlocking the laser light irradiation means, the roller rotating means and the roller moving means;
A foaming roller manufacturing apparatus comprising:
前記レーザ光照射手段と、発泡ローラのゴム発泡体外周面との間に、該ゴム発泡体外周面へのレーザ光の照射を制限するための遮光マスクを有し、
前記遮光マスクには、前記ゴム発泡体の平均セル径の0.5倍以上、2倍以下の幅を有する複数のスリット、或いは、前記ゴム発泡体の平均セル径の0.5倍以上、2倍以下の直径を有する複数の円形孔が存在することを特徴とする請求項2に記載の発泡ローラの製造装置。
Between the laser light irradiation means and the rubber foam outer peripheral surface of the foaming roller, a light shielding mask for limiting the laser light irradiation to the rubber foam outer peripheral surface,
The light shielding mask includes a plurality of slits having a width of 0.5 to 2 times the average cell diameter of the rubber foam, or 0.5 to 2 times the average cell diameter of the rubber foam. The apparatus for producing a foam roller according to claim 2, wherein there are a plurality of circular holes having a diameter less than double.
前記スリット間の非照射幅が、前記ゴム発泡体の平均セル径の0.5倍以上であり、
前記円形孔間の非照射幅が、前記ゴム発泡体の平均セル径の0.3倍以上であることを特徴とする請求項3に記載の発泡ローラの製造装置。
The non-irradiation width between the slits is 0.5 times or more the average cell diameter of the rubber foam,
The apparatus for producing a foam roller according to claim 3, wherein a non-irradiation width between the circular holes is 0.3 times or more an average cell diameter of the rubber foam.
請求項2乃至4のいずれか1項に記載の発泡ローラの製造装置を用いて、発泡ローラを製造することを特徴とする請求項1に記載の発泡ローラの製造方法。   The foaming roller manufacturing method according to claim 1, wherein the foaming roller is manufactured using the foaming roller manufacturing apparatus according to claim 2. 請求項1又は5に記載の発泡ローラの製造方法により製造される発泡ローラ。   A foam roller manufactured by the method for manufacturing a foam roller according to claim 1.
JP2008180135A 2008-07-10 2008-07-10 Manufacturing method and device of foam roller Pending JP2010019332A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012088630A (en) * 2010-10-22 2012-05-10 Tokai Rubber Ind Ltd Sponge roll for electrophotographic apparatus
JP2013103431A (en) * 2011-11-15 2013-05-30 Toppan Printing Co Ltd Method and device for production of transfer roller
US11576837B2 (en) 2019-10-03 2023-02-14 Jfxd Trx Acq Llc Multi-zonal roller and method of use thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012088630A (en) * 2010-10-22 2012-05-10 Tokai Rubber Ind Ltd Sponge roll for electrophotographic apparatus
JP2013103431A (en) * 2011-11-15 2013-05-30 Toppan Printing Co Ltd Method and device for production of transfer roller
US11576837B2 (en) 2019-10-03 2023-02-14 Jfxd Trx Acq Llc Multi-zonal roller and method of use thereof

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