JP6452532B2 - Method for producing foamed elastic roller - Google Patents

Method for producing foamed elastic roller Download PDF

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JP6452532B2
JP6452532B2 JP2015084768A JP2015084768A JP6452532B2 JP 6452532 B2 JP6452532 B2 JP 6452532B2 JP 2015084768 A JP2015084768 A JP 2015084768A JP 2015084768 A JP2015084768 A JP 2015084768A JP 6452532 B2 JP6452532 B2 JP 6452532B2
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foamed
foamed elastic
rubber composition
roller
elastic layer
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JP2016203421A (en
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槙佑 宮坂
槙佑 宮坂
史貴 茂木
史貴 茂木
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Shin Etsu Polymer Co Ltd
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本発明は、発泡弾性ローラの製造方法に関し、さらに詳しくは、発泡弾性層が厚肉であっても高い振れ精度を有する発泡弾性ローラの製造方法に関する。 The present invention relates to a method of manufacturing a foamed elastic row La, more particularly to a method for producing a foamed elastic rows La having a high deflection accuracy even thick foamed elastic layer.

レーザープリンター及びビデオプリンター等のプリンター、複写機、ファクシミリ、これらの複合機等には、電子写真方式を利用した各種の画像形成装置が採用されている。このような画像形成装置は、通常、記録体上に転写された現像剤を定着させるために発泡弾性層を有する定着ローラを備えている。
このような定着ローラは、記録体上に転写された現像剤を記録体に押圧すると共に加熱することにより、現像剤を記録体に定着させる。したがって、現像剤を所望のように記録体に定着させるため、定着ローラには、発泡弾性層の中心点と軸体の中心点とのズレ間隔が小さい(発泡弾性層の振れ精度が高い)ことが求められる。
Various image forming apparatuses using an electrophotographic system are employed in printers such as laser printers and video printers, copiers, facsimiles, and multi-function machines thereof. Such an image forming apparatus usually includes a fixing roller having a foamed elastic layer for fixing the developer transferred onto the recording medium.
Such a fixing roller fixes the developer onto the recording body by pressing the developer transferred onto the recording body against the recording body and heating it. Therefore, in order to fix the developer to the recording body as desired, the fixing roller has a small gap between the center point of the foamed elastic layer and the center point of the shaft body (the deflection accuracy of the foamed elastic layer is high). Is required.

発泡弾性層を備えたローラとして、例えば、特許文献1には、発泡性ゴム組成物を金型内で発泡成形した後にスキン層を研磨する弾性ロールの製造方法が記載されている。また、特許文献2には、ゴム硬化体の表面を圧接することによって、所定の連泡率を有する弾性ローラを製造する方法が記載されている。   As a roller having a foamed elastic layer, for example, Patent Document 1 describes a method for producing an elastic roll in which a skin layer is polished after foaming a foamable rubber composition in a mold. Patent Document 2 describes a method of manufacturing an elastic roller having a predetermined open cell ratio by pressing the surface of a cured rubber body.

特許第3241938号公報Japanese Patent No. 3224138 特開2008−292533号公報JP 2008-292533 A

ところで、近年の画像形成装置は、印字速度の高速化が図られ、また耐久性の向上も志向されている。これらの要求に応えるべく、定着ローラの発泡弾性層は厚肉化される傾向にある。しかし、発泡弾性層が厚肉化されると、発泡弾性層が発泡体であることから、振れ精度が低下することがあった。また、製造過程において発泡弾性層となる発泡硬化体を押圧処理する場合には、押圧して発泡硬化体を潰した後に押圧を解除したときの、発泡硬化体の復元が遅いと、高い振れ精度が得られないことがある。これらの場合、製造される発泡弾性層が定着ローラに求められる特性を満たさないことがあった。   By the way, in recent image forming apparatuses, the printing speed is increased and the durability is also improved. In order to meet these requirements, the foamed elastic layer of the fixing roller tends to be thickened. However, when the foamed elastic layer is thickened, the deflection accuracy may be lowered because the foamed elastic layer is a foam. In addition, when the foamed cured body that will be the foamed elastic layer is pressed during the manufacturing process, if the foamed cured body is slowly restored and then the foamed cured body is slowly restored, the high runout accuracy May not be obtained. In these cases, the produced foamed elastic layer may not satisfy the characteristics required for the fixing roller.

本発明は、発泡弾性層が厚肉であっても高い振れ精度を有する発泡弾性ローラ及びその製造方法を提供することを、課題にする。   An object of the present invention is to provide a foamed elastic roller having a high runout accuracy even when the foamed elastic layer is thick and a method for manufacturing the same.

本発明者らは、厚さが9mmを越える発泡弾性層を備えた発泡弾性ローラの製造方法において、発泡硬化体を、まず、初期の硬度低下を軽減する等のために押圧処理し、次いで研磨処理すると、押圧処理によって肉厚の発泡押圧体に特有に生じる歪変形を補整できることを見出した。また、発泡押圧体が厚肉であるためにゴム押圧体が発泡状態であっても研磨処理による研磨均一性を損なわない場合もあることを見出した。これらの知見に基づき本発明をなすに至った。   In the method for producing a foamed elastic roller having a foamed elastic layer having a thickness exceeding 9 mm, the present inventors first press-treated the foamed cured body to reduce initial hardness reduction, and then polished it. When it processed, it discovered that distortion deformation peculiar to a thick foaming press object by pressure processing can be compensated. Moreover, since the foaming press body was thick, it discovered that even if the rubber press body was a foaming state, the polishing uniformity by a grinding | polishing process might not be impaired. The present invention has been made based on these findings.

本発明の課題は、以下の手段によって達成された。
(1)軸体の外周に押出された発泡ゴム組成物を加硫し、次いで発泡ゴム組成物の表面に形成されたスキン層を除去して、厚さが9mmを越える発泡硬化体を得る工程と、該発泡硬化体を押圧処理して発泡押圧体を得る工程と、該発泡押圧体を研磨して、該発泡押圧体に生じた歪変形を補整した発泡弾性層を得る工程とを有する発泡弾性ローラの製造方法。
(2)前記発泡硬化体を得る工程が、前記発泡ゴム組成物を一次加硫し、次いで二次加硫した後にスキン層を除去する工程である(1)に記載の発泡弾性ローラの製造方法。
(3)前記発泡硬化体を得る工程が、前記二次加硫後であってスキン層を除去する前に三次加硫する工程である(2)に記載の発泡弾性ローラの製造方法
The object of the present invention has been achieved by the following means.
(1) A step of vulcanizing the foamed rubber composition extruded on the outer periphery of the shaft and then removing the skin layer formed on the surface of the foamed rubber composition to obtain a foamed cured product having a thickness exceeding 9 mm And a step of obtaining a foamed pressed body by pressing the foamed cured body, and a step of polishing the foamed pressed body to obtain a foamed elastic layer that compensates for distortion deformation generated in the foamed pressed body. A method for producing an elastic roller.
(2) The method for producing a foamed elastic roller according to (1), wherein the step of obtaining the foamed cured product is a step of primary vulcanizing the foamed rubber composition and then secondary vulcanizing and then removing the skin layer. .
(3) The method for producing a foamed elastic roller according to (2), wherein the step of obtaining the foamed cured product is a step of tertiary vulcanization after the secondary vulcanization and before removing the skin layer .

本発明により、発泡弾性層が厚肉であっても高い振れ精度を有する発泡弾性ローラ及びその製造方法の提供が可能になる。したがって、本発明の発泡弾性ローラは、画像形成装置に装着されると、現像剤を記録体に所望のように定着させて、画像の高品質化に貢献できる。   According to the present invention, it is possible to provide a foamed elastic roller having a high runout accuracy and a manufacturing method thereof even when the foamed elastic layer is thick. Therefore, when the foamed elastic roller of the present invention is attached to the image forming apparatus, the developer can be fixed to the recording body as desired, thereby contributing to the improvement of the image quality.

図1は、本発明の発泡弾性ローラの一例を示す概略斜視図である。FIG. 1 is a schematic perspective view showing an example of a foamed elastic roller of the present invention. 図2は、発泡弾性ローラの振れ精度を説明する説明図である。FIG. 2 is an explanatory diagram for explaining the deflection accuracy of the foamed elastic roller. 図3は、本発明の発泡弾性ローラを製造するのに好適に用いられる押圧処理装置を示す模式図である。FIG. 3 is a schematic view showing a pressure processing apparatus suitably used for producing the foamed elastic roller of the present invention.

まず、本発明の発泡弾性ローラについて説明する。本発明の発泡弾性ローラは、振れ精度が0.14mm以下である。振れ精度が0.14mm以下であると、印字速度の高速化及び/又は耐久性の向上が図られた近年の画像形成装置に定着ローラとして装着されても、加熱ローラとのニップ幅が均一になる。これにより、記録体に転写された現像剤を均一に押圧及び加熱して定着させることができ、画像品質の向上に貢献できる。画像品質の向上にさらに貢献できる点で、振れ精度は0.1mm以下であるのが好ましく、0.07mm以下であるのがさらに好ましい。なお、振れ精度の下限は、特に限定されないが、現実的には0.02mm以上である。   First, the foamed elastic roller of the present invention will be described. The foamed elastic roller of the present invention has a deflection accuracy of 0.14 mm or less. When the runout accuracy is 0.14 mm or less, the nip width with the heating roller is uniform even if it is installed as a fixing roller in a recent image forming apparatus in which the printing speed is increased and / or the durability is improved. Become. As a result, the developer transferred to the recording medium can be uniformly pressed and heated to be fixed, thereby contributing to improvement in image quality. The shake accuracy is preferably 0.1 mm or less, more preferably 0.07 mm or less, in that it can further contribute to the improvement of image quality. In addition, the lower limit of the shake accuracy is not particularly limited, but is practically 0.02 mm or more.

本発明において、発泡弾性層の振れ精度とは、上記のように、発泡弾性層の中心点と軸体の中心点とのズレ間隔をいう。図2を参照して具体的に説明する。図2は、振れ精度を説明する概略図である。図2(a)は振れ精度を説明するためのローラの正面図であり、図2(b)は図2(a)におけるH−H線での断面図である。振れ精度はこの断面図における(J2−J1)で求める。J1及びJ2は、発泡弾性層の中心点及び軸体の中心点を結ぶ直線が発泡弾性層の外周面と交わる2点それぞれと、軸体の中心点との間の距離である。求められる値は、理想的にはゼロとなる。現実には、中心軸上の各位置で相違する。
本発明においては、発泡弾性層の振れ精度は、少なくとも、発泡弾性層における中央部と両端部近傍との3点を測定点として求めた各測定点における(J2−J1)の平均値とする。ここで、J1及びJ2は、軸体を中心として発泡弾性ローラを回転させながら、レーザ測長機により、各測定点における発泡弾性層の厚さ(軸体の中心点から発泡弾性層の外周面までの距離)を測定することにより、求めることができる。
振れ精度は、後述する本発明の定着ローラの製造方法によって、例えば、研磨条件を変更すること等によって、所定の範囲に設定することができる。
In the present invention, the deflection accuracy of the foamed elastic layer refers to the gap between the center point of the foamed elastic layer and the center point of the shaft body as described above. This will be specifically described with reference to FIG. FIG. 2 is a schematic diagram for explaining the shake accuracy. FIG. 2A is a front view of the roller for explaining the deflection accuracy, and FIG. 2B is a cross-sectional view taken along the line H-H in FIG. The runout accuracy is determined by (J2-J1) in this cross-sectional view. J1 and J2 are distances between two points where a straight line connecting the center point of the foamed elastic layer and the center point of the shaft body intersects the outer peripheral surface of the foamed elastic layer and the center point of the shaft body. The calculated value is ideally zero. In reality, each position on the central axis is different.
In the present invention, the deflection accuracy of the foamed elastic layer is at least the average value of (J2-J1) at each measurement point obtained by measuring three points of the central portion and the vicinity of both ends of the foamed elastic layer. Here, J1 and J2 are the thicknesses of the foamed elastic layer at each measurement point (from the center point of the shaft body to the outer peripheral surface of the foamed elastic layer) by the laser length measuring machine while rotating the foamed elastic roller around the shaft body. Can be obtained by measuring the distance.
The shake accuracy can be set within a predetermined range by, for example, changing the polishing conditions by the method for manufacturing the fixing roller of the present invention described later.

本発明の発泡弾性ローラは、好ましくは形状均一性を有している。形状均一性とは、発泡弾性層の軸線方向に沿う端部に潰れ等の変形が実質的にないことをいう。   The foamed elastic roller of the present invention preferably has shape uniformity. Shape uniformity means that there is substantially no deformation such as crushing at the end along the axial direction of the foamed elastic layer.

本発明の発泡弾性ローラは、発泡弾性層が肉厚であり、具体的には9mmを越える厚さを有している。発泡弾性層がこのように肉厚に形成されていると、ニップを大幅に確保でき、また断熱性が向上して蓄積した熱を保持できるから、印字速度の高速化及び/又は耐久性の向上が図られた近年の画像形成装置に定着ローラとして好適に用いられる。発泡弾性層の厚さは、用途、機能等に応じて一義的には定まらないが、9mmを超えていればよく、例えば、10〜20mmが好ましく、10〜15mmがさらに好ましい。発泡弾性層の厚さは、振れ精度の測定と同様にして測定される。   In the foamed elastic roller of the present invention, the foamed elastic layer is thick, and specifically has a thickness exceeding 9 mm. If the foamed elastic layer is formed in this way, the nip can be secured greatly, and the heat insulation can be improved to retain the accumulated heat, so the printing speed is increased and / or the durability is improved. It is suitably used as a fixing roller in a recent image forming apparatus in which the above is achieved. The thickness of the foamed elastic layer is not uniquely determined depending on the application, function, etc., but may be more than 9 mm, for example, preferably 10-20 mm, more preferably 10-15 mm. The thickness of the foamed elastic layer is measured in the same manner as the measurement of runout accuracy.

本発明の発泡弾性ローラは、上記厚さの発泡弾性層を備え、振れ精度が上記範囲内にあれば、その構造等は特に限定されず、発泡弾性層の他に、軸体、表面層又はチューブ層等を有していてもよい。
表面層及びチューブ層は特に限定されず、公知の構成を適宜に適用できる。例えば、表面層はウレタン樹脂等の各種樹脂で形成され、チューブ層はフッ素樹脂等の各種樹脂製のチューブを発泡弾性層に被覆して形成される。
The foamed elastic roller of the present invention includes the foamed elastic layer having the above thickness, and the structure and the like are not particularly limited as long as the runout accuracy is within the above range. In addition to the foamed elastic layer, the shaft body, the surface layer, or You may have a tube layer etc.
A surface layer and a tube layer are not specifically limited, A well-known structure can be applied suitably. For example, the surface layer is formed of various resins such as urethane resin, and the tube layer is formed by coating a foamed elastic layer with a tube made of various resins such as fluororesin.

本発明の発泡弾性ローラの一例としての発泡弾性ローラ1は、図1に示されるように、軸体2と、その外周面に形成された発泡弾性層3とを備えている。この発泡弾性ローラ1は、振れ精度が0.14mm以下である。振れ精度については上記した通りである。   As shown in FIG. 1, a foamed elastic roller 1 as an example of a foamed elastic roller of the present invention includes a shaft body 2 and a foamed elastic layer 3 formed on the outer peripheral surface thereof. The foamed elastic roller 1 has a deflection accuracy of 0.14 mm or less. The runout accuracy is as described above.

軸体2は、良好な導電特性を有していればよく、通常、鉄、アルミニウム、ステンレス鋼、真鍮等の金属で構成された所謂「芯金」と称される。この軸体2は、熱可塑性樹脂若しくは熱硬化性樹脂等の絶縁性芯体にメッキを施して導電化した軸体であってもよく、さらには、熱可塑性樹脂若しくは熱硬化性樹脂等に導電性付与剤としてカーボンブラック又は金属粉体等を配合した導電性樹脂で形成された軸体であってもよい。   The shaft body 2 only needs to have good conductive properties, and is generally referred to as a so-called “core metal” made of a metal such as iron, aluminum, stainless steel, or brass. The shaft body 2 may be a shaft body that is made conductive by plating an insulating core body such as a thermoplastic resin or a thermosetting resin. Furthermore, the shaft body 2 is electrically conductive with a thermoplastic resin or a thermosetting resin. A shaft formed of a conductive resin containing carbon black or metal powder as a property-imparting agent may be used.

発泡弾性層3は、後述する発泡ゴム組成物によって、軸体2の外周面に形成されている。この発泡弾性層3は、その内部及び/又は外表面に気泡(図1において図示しない。)を有する、所謂「スポンジ状」になっている。この発泡弾性層3は、独立気泡と連通気泡とを有している。ここで独立気泡とは近傍の他の気泡と接していない気泡をいい、連通気泡とは、近接する気泡同士の壁に小さな孔が開いて気泡同士が繋がっているものをいう。ここで、気泡は、発泡弾性層3を形成する後述の発泡ゴム組成物に含有される発泡剤の発泡又は分解等によって生じる発泡弾性層3内又は表面の中空領域をいう。   The foamed elastic layer 3 is formed on the outer peripheral surface of the shaft body 2 by a foamed rubber composition to be described later. The foamed elastic layer 3 has a so-called “sponge-like” shape having bubbles (not shown in FIG. 1) inside and / or on the outer surface thereof. This foamed elastic layer 3 has closed cells and open cells. Here, a closed cell refers to a bubble that is not in contact with other nearby bubbles, and a communicating bubble refers to a bubble in which small holes are opened in the walls of adjacent bubbles. Here, the bubble refers to a hollow region in or on the surface of the foamed elastic layer 3 that is generated by foaming or decomposition of a foaming agent contained in a foamed rubber composition described later that forms the foamed elastic layer 3.

発泡弾性層3は、肉厚に形成されており、具体的には上記範囲の厚さを有している。   The foamed elastic layer 3 is formed thick, and specifically has a thickness in the above range.

発泡弾性層3は、アスカーC硬度が35〜50であるのが好ましく、40〜46であるのがさらに好ましい。これにより、画像形成装置が高速機であっても高反発を維持し、かつ破泡等の破壊にも耐えることができる。アスカーC硬度は、JIS K 6253に準拠して、発泡弾性層の軸方向に等間隔に4分割した箇所を測定したときの平均値である。   The foamed elastic layer 3 preferably has an Asker C hardness of 35 to 50, and more preferably 40 to 46. Thereby, even if the image forming apparatus is a high-speed machine, it can maintain high resilience and can withstand destruction such as bubble breakage. The Asker C hardness is an average value when a portion divided into four at equal intervals in the axial direction of the foamed elastic layer is measured according to JIS K 6253.

発泡弾性層3は、セル径が100〜400μmであるのが好ましく、150〜300μmであるのがさらに好ましい。これにより、画像形成装置が高速機でも画質が安定し、かつ破泡等の破壊にも耐えることができる。セル径は、発泡弾性層3の表面又は任意の面で切断したときの切断面において、約20mmの領域を電子顕微鏡等で観察し、観察視野内に存在する各セルにおける開口部の最大長さを測定して、測定された最大長さを算術平均して得られた平均長さとして、求める。 The foamed elastic layer 3 preferably has a cell diameter of 100 to 400 μm, and more preferably 150 to 300 μm. As a result, even if the image forming apparatus is a high-speed machine, the image quality is stable and it is possible to withstand destruction such as broken bubbles. The cell diameter is the maximum length of the opening in each cell existing in the observation field by observing an area of about 20 mm 2 with an electron microscope or the like on the surface of the foamed elastic layer 3 or a cut surface when cut by an arbitrary surface. Then, the maximum length measured is obtained as an average length obtained by arithmetic averaging.

本発明の発泡弾性ローラの製造方法は、発泡弾性を備えた発泡弾性ローラ、特に厚さが9mmを越える発泡弾性を備え、振れ精度が0.14mm以下である本発明の発泡弾性ローラを製造するのに、好適である。   The method for producing a foamed elastic roller of the present invention produces a foamed elastic roller having foamed elasticity, particularly a foamed elastic roller of the present invention having a foamed elasticity exceeding 9 mm in thickness and having a runout accuracy of 0.14 mm or less. Therefore, it is preferable.

本発明の発泡弾性ローラの製造方法は、軸体の外周に押出された発泡ゴム組成物を加硫して厚さが9mmを越える発泡硬化体を得る工程と、該発泡硬化体を押圧処理して発泡押圧体を得る工程と、該発泡押圧体を研磨して発泡弾性層を得る工程とを有する。
以下、本発明の発泡弾性ローラの製造方法を説明する。
The method for producing a foamed elastic roller of the present invention comprises a step of vulcanizing a foamed rubber composition extruded on the outer periphery of a shaft body to obtain a foamed cured product having a thickness exceeding 9 mm, and pressing the foamed cured product. And obtaining a foamed elastic layer by polishing the foamed pressure body.
Hereinafter, the manufacturing method of the foaming elastic roller of this invention is demonstrated.

本発明の発泡弾性ローラの製造方法(以下、本発明の製造方法という)においては、軸体を準備する。軸体は上述の通りであり、上述の金属又は樹脂等で適宜の形状及び寸法に形成する。軸体は、必要に応じて予め、その外周面に接着剤又はプライマーをスプレー法、浸漬法等によって塗布し、その外周面に接着層又はプライマー層を形成しておくのがよい。   In the method for manufacturing a foamed elastic roller of the present invention (hereinafter referred to as the manufacturing method of the present invention), a shaft body is prepared. The shaft body is as described above, and is formed into an appropriate shape and size using the above-described metal or resin. The shaft body is preferably coated with an adhesive or primer on its outer peripheral surface in advance by a spray method, a dipping method or the like as necessary, and an adhesive layer or primer layer is formed on its outer peripheral surface.

本発明の製造方法において、軸体の外周に押出された発泡ゴム組成物を加硫して、厚さが9mmを越える発泡硬化体を得る工程を行う。
この工程においては、まず、軸体の外周面に、発泡ゴム組成物を、押出成形による連続加熱成形、プレス、インジェクションによる型成形等によって、配置する。軸体の外周面にゴム組成物を配置する方法としては、例えば、押出機等により軸体と発泡ゴム組成物とを一体に分出する方法等が挙げられる。この方法は、作業が容易で、作業を連続して行うことができる点で、好ましい。
本発明の製造方法においては、発泡弾性層が9mmを越える厚さになるように、発泡ゴム組成物の押出し量を設定することが好ましい。発泡ゴム組成物の押出し量の上限は特に限定されず、研磨量等に応じて適宜に設定される。
In the production method of the present invention, a step of vulcanizing the foamed rubber composition extruded on the outer periphery of the shaft body to obtain a foamed cured product having a thickness exceeding 9 mm is performed.
In this step, first, the foamed rubber composition is disposed on the outer peripheral surface of the shaft body by continuous heat molding by extrusion molding, pressing, mold molding by injection, or the like. Examples of the method for disposing the rubber composition on the outer peripheral surface of the shaft include a method of dispensing the shaft and the foamed rubber composition integrally with an extruder or the like. This method is preferable in that the work is easy and the work can be performed continuously.
In the production method of the present invention, it is preferable to set the extrusion amount of the foamed rubber composition so that the foamed elastic layer has a thickness exceeding 9 mm. The upper limit of the extrusion amount of the foam rubber composition is not particularly limited, and is appropriately set according to the polishing amount and the like.

用いる発泡ゴム組成物は、ゴムと、発泡剤と、所望により各種添加剤等とを含有する組成物であればよく、例えば、発泡シリコーンゴム系組成物、特に付加反応型発泡シリコーンゴム組成物が好ましい。付加反応型発泡シリコーンゴム組成物として、ビニル基含有シリコーン生ゴムと、シリカ系充填材と、発泡剤と、付加反応架橋剤と、付加反応触媒と、反応制御剤と、導電性付与剤とを含有し、所望により有機過酸化物架橋剤と各種添加剤とを含有する付加反応型発泡シリコーンゴム組成物が挙げられる。この付加反応型発泡シリコーンゴム組成物は、特開2008−076751号公報に記載の「付加反応型発泡シリコーンゴム組成物」を用いることができ、この公報に記載された内容は本明細書に組み込まれる。   The foamed rubber composition to be used may be a composition containing rubber, a foaming agent, and various additives as required. For example, a foamed silicone rubber-based composition, particularly an addition reaction type foamed silicone rubber composition may be used. preferable. As an addition reaction type foamed silicone rubber composition, it contains a vinyl group-containing silicone raw rubber, a silica-based filler, a foaming agent, an addition reaction crosslinking agent, an addition reaction catalyst, a reaction control agent, and a conductivity imparting agent. If desired, an addition reaction type foamed silicone rubber composition containing an organic peroxide crosslinking agent and various additives may be mentioned. As this addition reaction type foamed silicone rubber composition, the “addition reaction type foamed silicone rubber composition” described in JP-A-2008-076751 can be used, and the contents described in this publication are incorporated herein. It is.

次いで、軸体の外周面に配置した発泡ゴム組成物を加硫する。本発明の製造方法において、発泡ゴム組成物の加硫方法は、発泡ゴム組成物が加硫される限り、特に限定されない。例えば、発泡ゴム組成物を一回で加硫することもでき、複数回にわけて加硫することもできる。本発明の製造方法において、発泡ゴム組成物の加硫方法は、発泡ゴム組成物を一次加硫し、次いで二次加硫する方法が好ましく、さらに三次加硫する方法がより好ましい。   Next, the foamed rubber composition disposed on the outer peripheral surface of the shaft body is vulcanized. In the production method of the present invention, the method for vulcanizing the foamed rubber composition is not particularly limited as long as the foamed rubber composition is vulcanized. For example, the foamed rubber composition can be vulcanized at one time, or can be vulcanized in multiple times. In the production method of the present invention, the method for vulcanizing the foamed rubber composition is preferably a method in which the foamed rubber composition is subjected to primary vulcanization and then secondary vulcanization, and more preferably tertiary vulcanization.

発泡ゴム組成物を一回で加硫する場合の加硫条件、及び、一次加硫の加硫条件は、発泡ゴム組成物に含まれるゴム、例えば、ビニル基含有シリコーン生ゴムが架橋し、かつ、発泡剤が分解又は発泡するのに十分な条件であればよい。例えば、発泡ゴム組成物を、通常、赤外線加熱炉又は熱風炉等の加熱炉、乾燥機等の加熱機等により、170〜500℃程度、好ましくは200〜400℃で、数分以上1時間以下、好ましくは5〜30分間にわたって、加熱する。   The vulcanization conditions for vulcanizing the foamed rubber composition at one time, and the vulcanization conditions for the primary vulcanization are the rubbers contained in the foamed rubber composition, for example, vinyl group-containing silicone raw rubber is crosslinked, and The conditions may be sufficient as long as the foaming agent is decomposed or foamed. For example, the foamed rubber composition is usually about 170 to 500 ° C., preferably 200 to 400 ° C., for several minutes to 1 hour or less in a heating furnace such as an infrared heating furnace or a hot air furnace, or a heating machine such as a dryer. Heat for preferably 5-30 minutes.

発泡ゴム組成物の二次加硫は、所望により又は好適に行われる加硫工程であり、一次加硫で加硫(架橋)された発泡ゴム組成物をより確実に架橋させる。この二次加硫により、発泡ゴム組成物が硬化して成る発泡硬化体の物性が安定する。二次加硫は、例えば、一次加硫された発泡ゴム組成物を、さらに、押出成形された状態のままで、例えば、180〜250℃、好ましくは190〜230℃で、1〜24時間、好ましくは3〜10時間にわたって、加熱されることによって、行われる。又は、金型を用いて、例えば、130〜200℃、好ましくは150〜180℃で、5分以上24時間以下、好ましくは10分以上10時間以下にわたって、再度加熱されることによって、行われる。   The secondary vulcanization of the foamed rubber composition is a vulcanization step that is performed as desired or suitably, and more reliably crosslinks the foamed rubber composition vulcanized (crosslinked) by the primary vulcanization. This secondary vulcanization stabilizes the physical properties of the foamed cured product obtained by curing the foamed rubber composition. In the secondary vulcanization, for example, the foamed rubber composition subjected to the primary vulcanization is further extruded, for example, at 180 to 250 ° C., preferably 190 to 230 ° C., for 1 to 24 hours. Preferably it is carried out by heating for 3 to 10 hours. Or it is performed by heating again using a mold at, for example, 130 to 200 ° C., preferably 150 to 180 ° C. for 5 minutes to 24 hours, preferably 10 minutes to 10 hours.

発泡ゴム組成物の三次加硫は、所望により又は好適に行われる加硫工程である。この三次加硫は、二次加硫で架橋された発泡ゴム組成物の残留物をさらに除去し、耐久性を向上させることができる。三次加硫によって発泡ゴム組成物が硬化して成る発泡硬化体の物性が安定する。三次加硫は、例えば、二次加硫された発泡ゴム組成物を、さらに、押出成形された状態のままで、例えば、150〜230℃、好ましくは180〜200℃で、1〜24時間、好ましくは1.5〜15時間にわたって、再度加熱されることによって、行われる。   The tertiary vulcanization of the foamed rubber composition is a vulcanization step that is performed as desired or suitably. This tertiary vulcanization can further remove the residue of the foam rubber composition cross-linked by the secondary vulcanization and improve the durability. The physical properties of the foamed cured product obtained by curing the foamed rubber composition by tertiary vulcanization are stabilized. In the tertiary vulcanization, for example, the secondary vulcanized foamed rubber composition is further extruded, for example, at 150 to 230 ° C., preferably 180 to 200 ° C., for 1 to 24 hours. Preferably it is carried out by heating again for 1.5 to 15 hours.

発泡硬化体を得る工程においては、所望により、発泡ゴム組成物の加硫後にスキン層を除去する。この除去処理は、粗研磨処理とも称され、発泡ゴム組成物の表面に形成されたセルのない表面層を除去する処理である。この製品寸法に研磨するとき、より精度良く研磨することができる。スキン層の除去処理条件は、スキン層を除去できれば特に限定されず、例えば、後述する研磨条件が挙げられる。   In the step of obtaining a foamed cured product, the skin layer is removed after vulcanization of the foamed rubber composition, if desired. This removal process is also referred to as a rough polishing process, and is a process of removing a cell-free surface layer formed on the surface of the foamed rubber composition. When polishing to this product size, it is possible to polish with higher accuracy. The condition for removing the skin layer is not particularly limited as long as the skin layer can be removed, and examples thereof include polishing conditions described later.

本発明の製造方法においては、次いで、発泡硬化体を得る工程において得られた発泡硬化体を押圧処理して、発泡押圧体を得る工程を行う。この工程は、発泡硬化体の表面を所定の条件で圧接、すなわち押圧する方法を好適に採用することができる。この押圧処理は、発泡硬化体の外周面を均一に押圧することができれば、手作業で実施してもよく、また、装置を用いてもよい。   Next, in the production method of the present invention, the foamed cured product obtained in the step of obtaining the foamed cured product is subjected to a pressing process to obtain a foamed pressed product. For this step, a method of pressing the surface of the foam cured body under a predetermined condition, that is, a method of pressing can be suitably employed. This pressing process may be performed manually or an apparatus may be used as long as the outer peripheral surface of the foam cured body can be pressed uniformly.

この工程に好適に用いられる押圧装置としては、例えば、特許文献2に記載の押圧装置(図3参照)等が挙げられる。
具体的には、図3に示されるように、この押圧処理装置10は、軸体2の外周面に発泡硬化体を備えた硬化体付軸体7をその中心軸を中心にして固定する固定手段11、例えば、軸体2を両端から挟持して固定する1組の挟持部材と、固定手段11に連結され、固定手段11を介して硬化体付軸体7を軸体2の中心軸を中心にして回転させる回転手段12、例えばモータと、硬化体付軸体7の発泡硬化体を押圧する押圧ローラ13と、押圧ローラ13を硬化体付軸体7の軸線方向に相対的に移動させると共に、押圧ローラ13を硬化体付軸体7の中心方向に移動させ、硬化体付軸体7に対する押圧率d(%)を調整する移動調整手段14と、押圧ローラ13を回転可能に支持し、移動手段13上を移動可能に設けられた押圧ローラ支持治具15とを備えている。
Examples of the pressing device suitably used in this step include a pressing device described in Patent Document 2 (see FIG. 3).
Specifically, as shown in FIG. 3, the press processing device 10 is a fixing that fixes a shaft body 7 with a hardened body having a foamed hardened body on the outer peripheral surface of the shaft body 2 around its central axis. Means 11, for example, a pair of clamping members that clamp and fix the shaft body 2 from both ends, and the fixing means 11 are connected to the shaft body 2 with the hardening body via the fixing means 11. Rotating means 12 that rotates about the center, for example, a motor, a pressure roller 13 that presses the foamed and cured body of the shaft body 7 with the cured body, and the pressure roller 13 is relatively moved in the axial direction of the shaft body 7 with the cured body. At the same time, the pressing roller 13 is moved in the center direction of the shaft body 7 with the cured body, and the movement adjusting means 14 for adjusting the pressing rate d (%) with respect to the shaft body 7 with the cured body, and the pressing roller 13 are rotatably supported. The pressing roller support jig 1 movably provided on the moving means 13 It is equipped with a door.

押圧ローラ13は、軸体とその外周面に形成されたゴム弾性体とを備えている。この軸体の寸法及び材料等は、特に限定されない。例えば、図3に示される押圧ローラ13における軸体は、その外径が34mm程度、軸線方向の長さが50mm程度であり、例えば、発泡弾性ローラ1の軸体2と同様の材料で形成されている。また、押圧ローラ13におけるゴム弾性体の寸法及び材料等は特に限定されない。例えば、図3に示される押圧ローラ13におけるゴム弾性体は、その外径が58mm程度、軸線方向の長さが49mm程度であり、例えば、弾性ローラ1の発泡弾性層3と同様の材料で形成されている。押圧ローラ13におけるゴム弾性体は、所望の発泡弾性層3を形成するには、特定の硬度を有することが重要であり、この押圧処理装置10における押圧ローラ13において、ゴム弾性体の硬度は、JIS A硬度で、20〜80であるのが好ましい。押圧ローラ13のゴム弾性体はJIS A硬度が20である。JIS A硬度は、JIS K 6301に準拠して測定することができる。   The pressing roller 13 includes a shaft body and a rubber elastic body formed on the outer peripheral surface thereof. The dimensions and materials of the shaft body are not particularly limited. For example, the shaft body in the pressing roller 13 shown in FIG. 3 has an outer diameter of about 34 mm and an axial length of about 50 mm. For example, the shaft body is formed of the same material as the shaft body 2 of the foamed elastic roller 1. ing. Further, the size and material of the rubber elastic body in the pressing roller 13 are not particularly limited. For example, the rubber elastic body in the pressing roller 13 shown in FIG. 3 has an outer diameter of about 58 mm and an axial length of about 49 mm, and is formed of the same material as the foamed elastic layer 3 of the elastic roller 1, for example. Has been. It is important that the rubber elastic body in the pressure roller 13 has a specific hardness in order to form the desired foamed elastic layer 3. In the pressure roller 13 in the pressure processing apparatus 10, the rubber elastic body has a hardness of The JIS A hardness is preferably 20-80. The rubber elastic body of the pressing roller 13 has a JIS A hardness of 20. The JIS A hardness can be measured according to JIS K 6301.

この押圧処理装置10を用いて硬化体付軸体7を押圧処理するには、まず、図3に示されるように、硬化体付軸体7を軸体2の両端から挟持して1組の挟持部材11に固定する。次いで、移動調整手段14を操作して、押圧ローラ13を硬化体付軸体7の一端部近傍において、押圧ローラ13を硬化体付軸体7の中心方向に移動させ、発泡硬化体が押圧ローラ13によって押し込まれた量が所定の値(押圧率)d(%)、例えば20%になるように、押圧ローラ13の位置を、調整する。   In order to perform the pressing process on the shaft body 7 with the cured body using the press processing device 10, first, as shown in FIG. 3, the shaft body 7 with the cured body is sandwiched from both ends of the shaft body 2 and a set of Fix to the clamping member 11. Next, the movement adjusting means 14 is operated to move the pressing roller 13 toward the center of the shaft 7 with the cured body near the one end of the shaft 7 with the cured body. The position of the pressing roller 13 is adjusted so that the amount pressed by 13 becomes a predetermined value (pressing rate) d (%), for example, 20%.

次いで、回転手段12を起動して、固定手段11に固定された硬化体付軸体7を軸体2の中心軸を中心にして回転させる。硬化体付軸体7を回転させると、硬化体付軸体7を押圧している押圧ローラ13は硬化体付軸体7と共に回転する。この状態を維持しつつ、移動調整手段14を起動して、押圧ローラ13を硬化体付軸体7の一端部から他端部にかけて一方向(例えば図3に示された矢印の方向)又は両方向に移動させる。このようにして、発泡硬化体における、ゴム弾性体によって押圧された領域に連続気泡が形成される。   Next, the rotating unit 12 is activated to rotate the shaft body 7 with the cured body fixed to the fixing unit 11 around the central axis of the shaft body 2. When the shaft body 7 with the cured body is rotated, the pressing roller 13 pressing the shaft body 7 with the cured body rotates together with the shaft body 7 with the cured body. While maintaining this state, the movement adjusting means 14 is activated, and the pressing roller 13 is moved in one direction (for example, the direction of the arrow shown in FIG. 3) or both directions from one end portion to the other end portion of the shaft body 7 with the cured body. Move to. In this way, open cells are formed in the area of the foamed cured body pressed by the rubber elastic body.

押圧処理の条件として下記条件が挙げられる。下記条件を採用することにより、振れ精度を上述の範囲内に、設定できる。
硬化体付軸体7の回転数:好ましくは10〜100rpm、より好ましくは14〜50rpm
押圧ローラ13の移動方向:左右両方向への片側移動又は往復移動
押圧ローラ13の移動回数(片側移動を1回とする):好ましくは1〜20回、より好ましくは1〜10回
押圧率d:好ましくは10〜70%、より好ましくは20〜65%
総押圧時間:好ましくは0.5〜60min、より好ましくは1〜6min
The following conditions are mentioned as conditions of a press process. By adopting the following conditions, the runout accuracy can be set within the above-mentioned range.
Rotational speed of the shaft body 7 with a cured body: preferably 10 to 100 rpm, more preferably 14 to 50 rpm
Movement direction of the pressing roller 13: one-sided movement in both left and right directions or reciprocating movement The number of movements of the pressing roller 13 (one-sided movement is defined as one time): preferably 1 to 20 times, more preferably 1 to 10 times pressing rate d: Preferably 10 to 70%, more preferably 20 to 65%
Total pressing time: preferably 0.5-60 min, more preferably 1-6 min

本発明の製造方法においては、次いで、発泡押圧体を得る工程で得られた発泡押圧体を研磨して、発泡弾性層を得る工程を行う。この研磨工程は、好ましくは発泡押圧体が発泡状態であっても研磨均一性を損なうことなく、押圧処理によって発泡硬化体に生じた歪変形を補整できる。   In the production method of the present invention, the step of polishing the foamed press body obtained in the step of obtaining the foamed press body and then obtaining the foamed elastic layer is performed. This polishing step is preferably capable of correcting distortion deformation generated in the foamed cured body by the pressing process without impairing the polishing uniformity even when the foamed pressed body is in a foamed state.

研磨条件は、特に制限されない。歪変形を所望のように補整できる点で、下記条件が好ましい。
砥石に関して、砥石粗さとしては、例えば、#20〜#200、好ましくは#50〜#150が挙げられる。また、砥石幅としては、例えば、15〜100mm、好ましくは20〜40mmが挙げられる。砥石回転数としては、例えば、1000〜7000rpm、好ましくは1500〜6000rpmが挙げられる。
研磨条件に関して、研削量としては、例えば、0.1〜10mm、好ましくは0.5〜5mmが挙げられる。また、研削速度としては、例えば、10〜1000mm/min、好ましくは400〜800mm/minが挙げられる。ワーク回転数としては、例えば、50〜3000rpm、好ましくは100〜2000rpmが挙げられる。
Polishing conditions are not particularly limited. The following conditions are preferable in that distortion deformation can be corrected as desired.
Regarding the grindstone, examples of the grindstone roughness include # 20 to # 200, preferably # 50 to # 150. Moreover, as a grindstone width, 15-100 mm, for example, Preferably 20-40 mm is mentioned. As a grindstone rotation speed, 1000-7000 rpm, for example, Preferably 1500-6000 rpm is mentioned.
Regarding the polishing conditions, the grinding amount is, for example, 0.1 to 10 mm, preferably 0.5 to 5 mm. Moreover, as a grinding speed, 10-1000 mm / min, for example, Preferably 400-800 mm / min is mentioned. Examples of the work rotation speed include 50 to 3000 rpm, preferably 100 to 2000 rpm.

このようにして、発泡弾性層3を得ることができる。   In this way, the foamed elastic layer 3 can be obtained.

本発明の製造方法においては、発泡押圧体を得る工程の後に熱処理をしないのがよい。通常、熱処理は形状不均一性を改善するために行われるが、本発明の製造方法では発泡弾性層の形状均一性が優れ、熱処理を省略することができる。   In the manufacturing method of this invention, it is good not to heat-process after the process of obtaining a foaming press body. Usually, the heat treatment is performed to improve the shape non-uniformity, but in the production method of the present invention, the shape uniformity of the foamed elastic layer is excellent and the heat treatment can be omitted.

本発明の製造方法においては、所望により、表面層又はチューブ層を設ける工程を、公知の手段により、行うことができる。   In the production method of the present invention, the step of providing a surface layer or a tube layer can be performed by a known means, if desired.

このようにして、本発明の製造方法が実施され、発泡弾性ローラが製造される。製造される発泡弾性ローラは、厚さが9mmを越える発泡弾性を備え、振れ精度が0.14mm以下である。
したがって、この発泡弾性ローラは、画像形成装置の定着ローラとして好適に用いられ、特に印字速度の高速化及び/又は耐久性の向上が図られた近年の画像形成装置の定着ローラとして好適に用いられる。
In this way, the manufacturing method of the present invention is performed, and the foamed elastic roller is manufactured. The foamed elastic roller to be manufactured has foam elasticity exceeding 9 mm in thickness and has a deflection accuracy of 0.14 mm or less.
Therefore, this foamed elastic roller is suitably used as a fixing roller of an image forming apparatus, and particularly suitably used as a fixing roller of a recent image forming apparatus in which the printing speed is increased and / or the durability is improved. .

本発明の発泡弾性ローラ及びその製造方法は、上述した例に限定されることはなく、本発明の目的を達成することができる範囲において、種々の変更が可能である。   The foamed elastic roller and the manufacturing method thereof according to the present invention are not limited to the above-described examples, and various modifications can be made within a range in which the object of the present invention can be achieved.

(実施例1)
本例では、図1に示す発泡弾性ローラ1を、図3に示す押圧装置10を用いて、製造した。
まず、無電解ニッケルメッキ処理が施された軸体2(直径12mm、長さ350mm、SUM22)をトルエンで洗浄し、プライマー「No.31A/B」(信越化学工業株社製:商品名)を塗布した。プライマー処理した軸体2を、ギアーオーブンを用いて、180℃の温度にて30分焼成処理した後、常温にて30分以上冷却し、プライマー層を形成した。
Example 1
In this example, the foamed elastic roller 1 shown in FIG. 1 was manufactured using the pressing device 10 shown in FIG.
First, the shaft body 2 (diameter 12 mm, length 350 mm, SUM22) subjected to electroless nickel plating was washed with toluene, and a primer “No. 31A / B” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) was used. Applied. The primer-treated shaft body 2 was baked at a temperature of 180 ° C. for 30 minutes using a gear oven, and then cooled at room temperature for 30 minutes or more to form a primer layer.

次いで、ビニル基含有シリコーン生ゴムとシリカ系充填材とを含むシリコーンゴム組成物「KE−904FU」(信越化学工業社製:商品名)100質量部と、付加反応架橋剤「C−153A」(信越化学工業社製:商品名)2.0質量部と、有機系発泡剤アゾビス−イソブチロニトリル「KEP−13」(信越化学工業社製:商品名)2.5質量部と、付加反応触媒としての白金触媒適量と、反応制御剤「R−153A」(信越化学工業社製:商品名)0.5質量部と、有機過酸化物架橋剤「C−3」(信越化学工業社製:商品名)適量と、耐熱性向上剤「KEP−12」(信越化学工業社製:商品名)1.0質量部とを、二本ロールで十分に混練して、付加反応型発泡シリコーンゴム組成物を調製した。   Next, 100 parts by mass of a silicone rubber composition “KE-904FU” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name) containing a vinyl raw silicone rubber and a silica-based filler, and an addition reaction crosslinking agent “C-153A” (Shin-Etsu) Chemical Industry Co., Ltd .: trade name) 2.0 parts by mass, organic foaming agent azobis-isobutyronitrile “KEP-13” (Shin-Etsu Chemical Co., Ltd .: trade name) 2.5 parts by mass, and addition reaction catalyst An appropriate amount of platinum catalyst, 0.5 parts by mass of a reaction control agent “R-153A” (manufactured by Shin-Etsu Chemical Co., Ltd .: trade name), and an organic peroxide crosslinking agent “C-3” (manufactured by Shin-Etsu Chemical Co., Ltd .: (Product name) An appropriate amount and 1.0 part by mass of a heat resistance improver “KEP-12” (manufactured by Shin-Etsu Chemical Co., Ltd .: product name) are sufficiently kneaded with two rolls, and an addition reaction type foamed silicone rubber composition A product was prepared.

押出成形機にて厚さが12mmとなるように付加反応型発泡シリコーンゴム組成物と軸体とを一体分出し、次いで、赤外線加熱炉(IR炉)を用いて付加反応型発泡シリコーンゴム組成物を250℃で10分間、一次加硫した。その後、さらに、ギアーオーブンを用いて、200℃で7時間にわたって二次加硫し、常温にて1時間放置した。次いで、ギアーオーブンを用いて、200℃で10時間にわたって加熱し、三次加硫した。
このようにして加硫した発泡ゴム組成物は、厚さが20mmになっていた。
The addition reaction type foamed silicone rubber composition and the shaft are integrally separated so as to have a thickness of 12 mm by an extrusion molding machine, and then the addition reaction type foamed silicone rubber composition using an infrared heating furnace (IR furnace). Was primarily vulcanized at 250 ° C. for 10 minutes. Then, further using a gear oven, secondary vulcanization was performed at 200 ° C. for 7 hours, and the mixture was left at room temperature for 1 hour. Next, using a gear oven, the mixture was heated at 200 ° C. for 10 hours to be tertiary vulcanized.
The foamed rubber composition vulcanized in this way had a thickness of 20 mm.

この発泡ゴム組成物のスキン層を、砥石粗さが#50、砥石幅が40mmの砥石を用いて、砥石回転数2000rpm、研削量4mm、研削速度800mm/min及びワーク回転数2000rpmの条件で、研磨除去(粗研磨処理)し、厚さが16mmの発泡硬化体を得た。   The skin layer of this foamed rubber composition, using a grindstone having a grindstone roughness of # 50 and a grindstone width of 40 mm, under the conditions of a grindstone rotational speed of 2000 rpm, a grinding amount of 4 mm, a grinding speed of 800 mm / min, and a workpiece rotational speed of 2000 rpm, Polishing removal (coarse polishing treatment) was performed to obtain a foamed cured product having a thickness of 16 mm.

この発泡硬化体を、図3に示される上記押圧装置10を用いて、下記条件で押圧処理して、発泡押圧体を得た。
硬化体付軸体7(発泡硬化体)の回転数:30rpm
押圧ローラの移動方向:左方向への片側移動(押圧時間内での移動回数2回)
押圧率d:40%
総押圧時間:3min
The foamed cured body was subjected to a pressure treatment under the following conditions using the pressing device 10 shown in FIG. 3 to obtain a foamed pressed body.
Number of rotations of the shaft body 7 (cured cured body) with a cured body: 30 rpm
Movement direction of the pressure roller: One-sided movement to the left (the number of movements within the pressing time is twice)
Press rate d: 40%
Total pressing time: 3min

この発泡押圧体を下記のように研磨して、厚さが14mmの発泡弾性層3を得た。
具体的には、砥石粗さ#80、砥石幅40mmの砥石を用いて、砥石回転数1500rpm、研削量2mm、研削速度400mm/min及びワーク回転数100rpmの条件で、発泡押圧体を研磨した。
The foamed pressed body was polished as follows to obtain a foamed elastic layer 3 having a thickness of 14 mm.
Specifically, the foaming pressing body was polished using a grindstone having a grindstone roughness of 80 and a grindstone width of 40 mm under the conditions of a grindstone rotational speed of 1500 rpm, a grinding amount of 2 mm, a grinding speed of 400 mm / min, and a workpiece rotational speed of 100 rpm.

このようにして実施例1の発泡弾性ローラ1を製造した。   Thus, the foamed elastic roller 1 of Example 1 was manufactured.

(実施例2)
直径20mmの軸体2を用いて、実施例1の発泡弾性ローラ1の製造と同様にして、軸体2の外周で前記付加反応型発泡シリコーンゴム組成物を一次加硫、二次加硫及び三次加硫した。このとき、加硫した発泡ゴム組成物は厚さが16mmであった。
次いで、この発泡ゴム組成物のスキン層を、実施例1の発泡弾性ローラ1の製造と同様にして、粗研磨して、厚さが12mmの発泡硬化体を得た。この発泡硬化体を実施例1の発泡弾性ローラ1の製造と同様にして押圧処理して得た発泡押圧体を、実施例1の発泡弾性ローラ1の製造と同様にして研磨して、厚さが10mmの発泡弾性層3を備えた発泡弾性ローラ1を製造した。
(実施例3)
実施例1の製造において、三次加硫をしなかったこと以外は、実施例1と同様にして、発泡弾性ローラ1を製造した。
(実施例4)
実施例1の製造において、加硫時間を30分に変更して付加反応型発泡シリコーンゴム組成物の一次加硫をし、二次加硫及び三次加硫をしなかったこと以外は、実施例1と同様にして、発泡弾性ローラ1を製造した。
(Example 2)
Using the shaft body 2 having a diameter of 20 mm, the addition reaction type foamed silicone rubber composition was subjected to primary vulcanization, secondary vulcanization and the like on the outer periphery of the shaft body 2 in the same manner as in the production of the foamed elastic roller 1 of Example 1. Tertiary vulcanization. At this time, the vulcanized foamed rubber composition had a thickness of 16 mm.
Subsequently, the skin layer of this foamed rubber composition was roughly polished in the same manner as in the production of the foamed elastic roller 1 of Example 1 to obtain a foamed cured product having a thickness of 12 mm. The foamed pressed body obtained by pressing the foamed cured body in the same manner as in the production of the foamed elastic roller 1 in Example 1 was polished in the same manner as in the production of the foamed elastic roller 1 in Example 1 to obtain a thickness. Produced a foamed elastic roller 1 having a foamed elastic layer 3 of 10 mm.
Example 3
In the production of Example 1, the foamed elastic roller 1 was produced in the same manner as in Example 1 except that tertiary vulcanization was not performed.
(Example 4)
In the production of Example 1, except that the vulcanization time was changed to 30 minutes, primary vulcanization of the addition reaction type foamed silicone rubber composition was performed, and secondary vulcanization and tertiary vulcanization were not performed. In the same manner as in Example 1, a foamed elastic roller 1 was produced.

(比較例1)
実施例1において、押圧処理と研磨処理との実施順を逆にした(すなわち、スキン層を除去後、研磨工程及び押圧工程をこの順で実施した)こと以外は実施例1と同様にして、比較例1の発泡弾性ローラを製造した。
(Comparative Example 1)
In Example 1, in the same manner as in Example 1 except that the order of performing the pressing process and the polishing process was reversed (that is, the polishing process and the pressing process were performed in this order after removing the skin layer), The foamed elastic roller of Comparative Example 1 was produced.

(振れ精度の測定)
製造した各発泡弾性ローラの振れ精度を上述のようにして測定した。その結果を表1に示す。
(Measurement of runout accuracy)
The runout accuracy of each foamed elastic roller produced was measured as described above. The results are shown in Table 1.

Figure 0006452532
Figure 0006452532

表1から明らかなように、本発明の製造方法で製造された発泡弾性ローラ1は、発泡弾性層3の厚さが14mmでも、振れ精度が小さく、振れ精度に優れることが分かった(実施例1、3及び4)。また、発泡弾性層3の厚さが10mmであっても(実施例2)、また、三次加硫を実施しない場合(実施例3及び4)も、同様に、振れ精度に優れることが分かった。
これに対して、比較例1で製造した発泡弾性ローラは、振れ精度が大きく、必要な精度が得られなかった。
As is apparent from Table 1, it was found that the foamed elastic roller 1 produced by the production method of the present invention had small runout accuracy and excellent runout accuracy even when the foamed elastic layer 3 had a thickness of 14 mm (Example) 1, 3 and 4). Moreover, even when the thickness of the foamed elastic layer 3 was 10 mm (Example 2), and when the tertiary vulcanization was not performed (Examples 3 and 4), it was found that the deflection accuracy was also excellent. .
On the other hand, the foamed elastic roller manufactured in Comparative Example 1 had a large runout accuracy, and the required accuracy could not be obtained.

1 発泡弾性ローラ
2 軸体
3 発泡弾性層
7 硬化体付軸体
10 押圧処理装置
11 固定手段
12 回転手段
13 押圧ローラ
14 移動調整手段
15 押圧ローラ支持治具
DESCRIPTION OF SYMBOLS 1 Foam elastic roller 2 Shaft body 3 Foam elastic layer 7 Shaft body 10 with a hardening body Press processing apparatus 11 Fixing means 12 Rotating means 13 Pressing roller 14 Movement adjusting means 15 Pressing roller support jig

Claims (3)

軸体の外周に押出された発泡ゴム組成物を加硫し、次いで発泡ゴム組成物の表面に形成されたスキン層を除去して、厚さが9mmを越える発泡硬化体を得る工程と、該発泡硬化体を押圧処理して発泡押圧体を得る工程と、該発泡押圧体を研磨して、該発泡押圧体に生じた歪変形を補整した発泡弾性層を得る工程とを有する発泡弾性ローラの製造方法。 Vulcanizing the foamed rubber composition extruded on the outer periphery of the shaft , and then removing the skin layer formed on the surface of the foamed rubber composition to obtain a foamed cured product having a thickness exceeding 9 mm; A foamed elastic roller comprising: a step of pressing a foamed cured body to obtain a foamed pressed body; and a step of polishing the foamed pressed body to obtain a foamed elastic layer that compensates for distortion deformation generated in the foamed pressed body . Production method. 前記発泡硬化体を得る工程が、前記発泡ゴム組成物を一次加硫し、次いで二次加硫した後にスキン層を除去する工程である請求項1に記載の発泡弾性ローラの製造方法。 The method for producing a foamed elastic roller according to claim 1, wherein the step of obtaining the foamed cured product is a step of removing the skin layer after primary vulcanization and then secondary vulcanization of the foamed rubber composition. 前記発泡硬化体を得る工程が、前記二次加硫後であってスキン層を除去する前に三次加硫する工程である請求項2に記載の発泡弾性ローラの製造方法。 The method for producing a foamed elastic roller according to claim 2, wherein the step of obtaining the foamed cured product is a step of performing tertiary vulcanization after the secondary vulcanization and before removing the skin layer .
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