JP2009288522A - Panel for information display and method for manufacturing the same - Google Patents

Panel for information display and method for manufacturing the same Download PDF

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JP2009288522A
JP2009288522A JP2008140929A JP2008140929A JP2009288522A JP 2009288522 A JP2009288522 A JP 2009288522A JP 2008140929 A JP2008140929 A JP 2008140929A JP 2008140929 A JP2008140929 A JP 2008140929A JP 2009288522 A JP2009288522 A JP 2009288522A
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substrates
substrate
partition
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space
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Hirotaka Yamazaki
博貴 山崎
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Bridgestone Corp
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Bridgestone Corp
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<P>PROBLEM TO BE SOLVED: To provide a manufacturing method for uniformizing a filling amount of cells with particle groups as a display medium and inexpensively obtaining a panel for information display with high productivity. <P>SOLUTION: One transparent substrate 2 on which a barrier wall part 4-2-2 functioning to both secure a gap between substrates and partition the space between the substrates is formed, is laminated with the other substrate 1 on which a barrier wall part 4-2-1 exclusively for partitioning the space between substrates is formed, to obtain a panel structure; and the panel structure has a plurality of cells 7 partitioned by barrier walls 4-2, in which particles having an optical reflectance and capable of being electrically driven are disposed by using a mask 11 having a large opening regardless of the opening of cells. The barrier wall parts 4-2-1 and 4-2-2 formed on the substrates 1 and 2, respectively, exclusively for partitioning the space between the substrates are opposed to each other through a gap D1 or with particles 3Wa and 3Ba constituting the groups of particles 3W, 3B as a display medium and having an average particle diameter D0 partially interposed therebetween. The panel structure is configured to satisfy D0≤D1≤1.5×D0. <P>COPYRIGHT: (C)2010,JPO&INPIT

Description

本発明は、少なくとも一方が透明である、所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された一方の基板と、専ら基板間の空間を仕切るための隔壁部分が形成されたもう一方の基板とを、所定基板間ギャップをもって貼り合せたパネル構造体の隔壁で仕切られた複数のセル内に、光学的反射率を有し、電気的に駆動可能な粒子を含んだ粒子群として構成した表示媒体を配置し、表示媒体を電気的に駆動させて画像等の情報を表示する情報表示用パネルおよびその製造方法に関するものである。   According to the present invention, at least one of the substrates is transparent, in order to partition the space between the substrates exclusively, one substrate formed with a partition wall portion that serves to secure a predetermined inter-substrate gap and partition the space between the substrates. In the multiple cells partitioned by the partition walls of the panel structure that is bonded to the other substrate on which the partition wall portion is formed with a predetermined inter-substrate gap, it has optical reflectivity and can be electrically driven The present invention relates to an information display panel in which a display medium configured as a particle group including various particles is disposed, and information such as an image is displayed by electrically driving the display medium, and a manufacturing method thereof.

従来、電気的に駆動可能な粒子を含んだ粒子群を表示媒体として駆動させる粒子移動方式の情報表示用パネルとして、パネルを構成する基板間を隔壁で仕切って構成し、その隔壁で囲まれた小部屋(セル)内に帯電性粒子を含んだ粒子群を表示媒体として封入し、表示媒体に電界を付与して、表示媒体を移動させて画像等の情報を表示する情報表示用パネルが知られている。   Conventionally, as a particle movement type information display panel that drives a group of particles containing electrically drivable particles as a display medium, the substrates constituting the panel are configured by partitioning and surrounded by the partition There is known an information display panel in which a group of particles containing charged particles is enclosed in a small room (cell) as a display medium, an electric field is applied to the display medium, and the display medium is moved to display information such as an image. It has been.

さらに、上述した帯電粒子移動方式の情報表示用パネルとして、隔壁をパネルを構成する基板の双方に設け、隔壁の交点部分の高さをそれ以外の部分の高さよりも高くした構成として、双方のパネルを構成する基板を貼り合わせたときに、隔壁の一部分では隙間が形成されるようにした情報表示用パネルも知られている(例えば、特許文献1参照)。   Furthermore, as the above-mentioned information display panel of the charged particle movement system, the partition wall is provided on both of the substrates constituting the panel, and the height of the intersection part of the partition wall is made higher than the height of the other parts, An information display panel is also known in which a gap is formed in a part of a partition when a substrate constituting the panel is bonded (see, for example, Patent Document 1).

さらにまた、帯電性粒子を含んだ粒子群を表示媒体として駆動させる帯電粒子移動型ディスプレイパネルを製造する際の粒子充填工程では、パネル基板に平板状のマスクを載せて、パネル基板の上方から粒子を落下させ、マスク開口部に対応したパネル基板上に粒子を配置する方法が用いられることも知られている。   Furthermore, in the particle filling process when manufacturing a charged particle movement type display panel that drives a group of particles containing chargeable particles as a display medium, a flat mask is placed on the panel substrate, and the particles are applied from above the panel substrate. It is also known that a method of dropping particles and arranging particles on a panel substrate corresponding to the mask opening is used.

図6(a)〜(e)および図7(a)〜(c)はそれぞれ従来の情報表示用パネルを平板状のマスクを用いて製造する方法の一例を説明するための図である。図6(a)〜(e)に従って、従来の情報表示用パネルの製造方法を説明すると、まず、図6(a)に示すように、パネル基板51上に形成された隔壁54上にセル57に合わせた開口部61を有する平板状のマスク62を載せ、マスク62の上方から第1の表示媒体粒子群(本例では負帯電性白色粒子53Waを含んだ粒子群である白色表示媒体53W)を落下させ、マスク62の開口部61に対応した、隔壁54で仕切られたパネル基板51上のセル57内に白色表示媒体3Wを配置する。次に、図6(b)に示すように、マスク62の上方から第2の表示媒体粒子群(本例では正帯電性黒色粒子53Baを含んだ粒子群である黒色表示媒体3B)を落下させ、すでに配置した白色表示媒体53W上に配置する。次に、図6(c)に示すように、マスク62を取り外し、隔壁54にパネル基板貼り合わせ用の接着剤63を配置する。最後に、図6(d)に示すように、もう一方のパネル基板52を、接着剤63を配置済のパネル基板51に貼り合わせて、図6(e)に示すように、情報表示用パネルを作製している。また、図7(a)〜(c)に示す例では、隔壁54が形成された2枚の基板のうち一方の基板51上のセル57内に、上述した図6(a)〜(e)と同様の方法で2種類の表示媒体3W、3B(粒子群)を配置後(図7(a))、どちらか一方の基板51上の隔壁54の頂上に接着剤63を配置して(図7(b))、2枚の基板51、52上の隔壁54の頂上同士を接合して貼り合わせて情報表示用パネルを作製している(図7(c))。   FIGS. 6A to 6E and FIGS. 7A to 7C are views for explaining an example of a method for manufacturing a conventional information display panel using a flat mask. A conventional method for manufacturing an information display panel will be described with reference to FIGS. 6A to 6E. First, as shown in FIG. 6A, a cell 57 is formed on a partition wall 54 formed on a panel substrate 51. A flat mask 62 having an opening 61 is placed on the first display medium particle group (in this example, a white display medium 53W which is a particle group including negatively charged white particles 53Wa) from above the mask 62. The white display medium 3 </ b> W is placed in the cell 57 on the panel substrate 51 that is partitioned by the partition wall 54, corresponding to the opening 61 of the mask 62. Next, as shown in FIG. 6B, the second display medium particle group (in this example, the black display medium 3B, which is a particle group including the positively charged black particles 53Ba) is dropped from above the mask 62. Then, it is arranged on the white display medium 53W that has already been arranged. Next, as shown in FIG. 6C, the mask 62 is removed, and an adhesive 63 for attaching the panel substrate is disposed on the partition wall 54. Finally, as shown in FIG. 6 (d), the other panel substrate 52 is bonded to the panel substrate 51 on which the adhesive 63 has been placed, and as shown in FIG. 6 (e), the information display panel Is making. In the example shown in FIGS. 7A to 7C, the above-described FIGS. 6A to 6E are placed in the cell 57 on one of the two substrates 51 on which the partition wall 54 is formed. After two types of display media 3W and 3B (particle groups) are arranged in the same manner as in FIG. 7 (FIG. 7A), an adhesive 63 is arranged on the top of the partition wall 54 on one of the substrates 51 (FIG. 7). 7 (b)) The tops of the partition walls 54 on the two substrates 51 and 52 are joined and bonded together to produce an information display panel (FIG. 7C).

特開2006−23541号公報JP 2006-23541 A

帯電性粒子を含んだ粒子群を表示媒体として駆動させる帯電粒子移動型の情報表示用パネルをはじめとして、表示媒体に粒子群を用いる情報表示用パネルでは、平均粒子径が1〜20μmの粒子群を、200μm程度の大きさを下限として、それよりも大きいセルに充填していた。充填時にはセル開口に合わせた開口を有するマスクを用いるが、セル開口が200μm程度よりも小さい、たとえば100μm程度になると、マスク開口も100μm程度となり、この場合には、粒子がマスク開口部を通過しにくくなり、セルに充填される粒子量にバラツキがでる不具合があった。   In an information display panel using a particle group as a display medium, including a charged particle movement type information display panel that drives a particle group containing a chargeable particle as a display medium, the particle group having an average particle diameter of 1 to 20 μm Was filled in a larger cell, with a size of about 200 μm as the lower limit. When filling, a mask having an opening corresponding to the cell opening is used. When the cell opening is smaller than about 200 μm, for example, about 100 μm, the mask opening is also about 100 μm. In this case, the particles pass through the mask opening. There was a problem that the amount of particles filled in the cell became uneven and the amount of particles filled was uneven.

すなわち、図8(a)〜(d)にそれぞれ図6(a)〜(e)に対応した製造工程を示すように、マスクの開口部の小さいマスク62を使用すると、図8(a)に示すように、第1の表示媒体粒子群としての白色粒子53Waの充填量が不均一となり、図8(b)に示すように、次の第2の表示媒体粒子群としての黒色粒子53Baの充填量も不均一になり、その結果、図8(c)に示すように隔壁54上に接着剤63を配置して、図8(d)に示すように、もう一方の基板52を貼り合わせて得られる情報表示用パネルにおいて、セル57ごとに表示媒体となる粒子群の充填量が不均一となる。図9(a)〜(d)にそれぞれ図7(a)〜(c)に対応した製造工程を示した例においても、マスクの開口部の小さいマスク62を使用すると、同様に、最終的に得られる情報表示用パネルにおいて、セル57ごとに表示媒体となる粒子群の充填量が不均一となる。   That is, as shown in FIGS. 8A to 8D, the manufacturing process corresponding to FIGS. 6A to 6E is used, and when a mask 62 having a small mask opening is used, FIG. As shown, the filling amount of the white particles 53Wa as the first display medium particle group becomes non-uniform, and as shown in FIG. 8B, the black particles 53Ba as the next second display medium particle group are filled. As a result, the amount of adhesive becomes uneven, and as a result, the adhesive 63 is disposed on the partition wall 54 as shown in FIG. 8C, and the other substrate 52 is bonded as shown in FIG. 8D. In the obtained information display panel, the filling amount of the particle group serving as the display medium for each cell 57 becomes non-uniform. 9A to 9D also show the manufacturing processes corresponding to FIGS. 7A to 7C, respectively, when the mask 62 having a small mask opening is used, similarly, finally, In the obtained information display panel, the filling amount of the particle group serving as the display medium for each cell 57 becomes non-uniform.

また、セル開口が200μm以上、例えば300μm程度であってもセル開口に合せた開口を有するマスクを準備することはマスク作製のための工数が複雑になる分高価なマスクとなってしまうことも問題となっていた。   Moreover, even if the cell opening is 200 μm or more, for example, about 300 μm, it is problematic that preparing a mask having an opening that matches the cell opening results in an expensive mask due to the complexity of the mask manufacturing process. It was.

本発明の目的は、セル開口と関係なく大きな開口を有するマスクを用いて上述した不具合を発生することなく作製できる構造の情報表示用パネルおよびその構造の情報表示用パネルを生産性よく安価に得るための製造方法を提供しようとするものである。   An object of the present invention is to obtain an information display panel having a structure that can be manufactured without using the above-described problems by using a mask having a large opening irrespective of cell openings, and an information display panel having the structure with low productivity and low cost. The manufacturing method for this is intended to be provided.

本発明の情報表示用パネルは、少なくとも一方が透明である、所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された一方の基板と、専ら基板間の空間を仕切るための隔壁部分が形成されたもう一方の基板とを、所定基板間ギャップをもって貼り合せたパネル構造体の隔壁で仕切られた複数のセル内に、光学的反射率を有し、電気的に駆動可能な粒子を含んだ粒子群として構成した表示媒体を配置し、表示媒体を電気的に駆動させて画像等の情報を表示する情報表示用パネルであって、前記双方の基板にそれぞれ分割して形成され、専ら基板間の空間を仕切るための隔壁部分は、隙間D1をもって対向するか、あるいは、平均粒子径がD0の表示媒体とする粒子群を構成する粒子を部分的に挟んで対向するものであって、このとき、D0≦D1≦1.5×D0を満たすことを特徴とするものである。   The information display panel according to the present invention has at least one transparent substrate, and is formed between one substrate on which a partition wall portion that serves to secure a predetermined inter-substrate gap and partition a space between the substrates is formed, and exclusively between the substrates In the plurality of cells partitioned by the partition wall of the panel structure, which is bonded to the other substrate on which the partition wall portion for partitioning the space is formed, with a predetermined inter-substrate gap, has optical reflectance, An information display panel in which a display medium configured as a particle group including electrically drivable particles is disposed, and information such as an image is displayed by electrically driving the display medium, on both the substrates The partition portions that are formed by dividing each other and exclusively partition the space between the substrates face each other with a gap D1, or partially sandwich particles constituting a particle group serving as a display medium having an average particle diameter of D0. so Be one countercurrent, this time, it is characterized in that satisfy D0 ≦ D1 ≦ 1.5 × D0.

本発明の情報表示用パネル好適例としては、双方の基板にそれぞれ分割して形成され、専ら基板間の空間を仕切るための隔壁部分のうち、所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された基板ではない方の基板に形成された専ら基板間の空間を仕切るための隔壁部分には、厚さが1μm〜D0/2の接着剤層が形成されていること、専ら基板間の空間を仕切るための隔壁部分が対向して配置されたときに形成される隙間D1は、基板間ギャップにおいて中央付近の位置にあること、専ら基板間の空間を仕切るための隔壁部分が対向して配置されたときに形成される隙間D1は、基板間ギャップにおいて背面側基板に近い位置にあること、がある。   As a preferred example of the information display panel according to the present invention, a predetermined gap between the substrates and a space between the substrates are formed among the partition walls for dividing the space between the substrates. An adhesive layer having a thickness of 1 μm to D0 / 2 is formed on the partition wall portion for exclusively partitioning the space between the substrates formed on the substrate that is not the substrate on which the partition wall portion that also functions as a partition is formed. The gap D1 formed when the partition wall portions for partitioning the space between the substrates are arranged opposite to each other is located in the vicinity of the center in the inter-substrate gap, and the space between the substrates exclusively. The gap D1 formed when the partition wall portions for partitioning are arranged to face each other may be at a position close to the back side substrate in the inter-substrate gap.

また、本発明の情報表示用パネルの製造方法は、少なくとも一方が透明である、所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された一方の基板と、専ら基板間の空間を仕切るための隔壁部分が形成されたもう一方の基板とを、所定基板間ギャップをもって貼り合せたパネル構造体の隔壁で仕切られた複数のセル内に、光学的反射率を有し、電気的に駆動可能な粒子を含んだ粒子群として構成した表示媒体を配置し、表示媒体を電気的に駆動させて画像等の情報を表示する上述した構成の情報表示用パネルの製造方法であって、2枚の基板のうち所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された基板上のセル内に表示媒体を充填し、この基板に形成された所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分の頂上およびもう一方の基板に形成された専ら基板間の空間を仕切るための隔壁部分の頂上に、接着剤を配置して、2枚の基板を貼り合せてパネル構造体とすることを特徴とするものである。   In addition, in the method for manufacturing an information display panel according to the present invention, at least one of the substrates is transparent, and one substrate on which a partition wall portion that serves to secure a predetermined inter-substrate gap and partition a space between the substrates is formed. And optically reflected in a plurality of cells partitioned by partition walls of a panel structure in which a partition portion for partitioning a space between the substrates is formed with a predetermined gap between the substrates. An information display panel having the above-described configuration, in which a display medium configured as a particle group including particles that can be electrically driven is disposed, and information such as an image is displayed by electrically driving the display medium The method includes: filling a display medium into a cell on a substrate formed with a partition wall portion that serves to secure a predetermined gap between the two substrates and partition a space between the substrates. On this board On the top of the partition wall part that serves to ensure the gap between the predetermined substrates formed and partition the space between the substrates and on the top of the partition wall part for partitioning the space between the substrates exclusively formed on the other substrate, An adhesive is disposed, and two substrates are bonded to form a panel structure.

本発明では、基板間ギャップ確保用隔壁部分は一方の基板に設け、セル形成用隔壁部分は、双方の基板に、パネルとした時に、隙間D1をもって対向するようにそれぞれ分割して配置したので、基板間ギャップ確保用隔壁部分の頂上を確実にマスクし、他のセル形成用隔壁部分はマスクしてもマスクしなくてもよいようにしてマスク開口を200μmより大きくすることができ、表示媒体とする粒子群を、開口が200μmより小さいセル内にも精度よく配置した情報表示用パネルが、低コストで得られる。   In the present invention, the partition wall portion for securing the gap between the substrates is provided on one substrate, and the partition wall portion for cell formation is arranged separately on both substrates so as to face each other with a gap D1 when the panel is formed. The mask opening can be made larger than 200 μm so that the top of the partition wall for securing the inter-substrate gap can be reliably masked, and the other partition walls for cell formation can be masked or not masked. An information display panel in which the particle groups to be arranged are accurately arranged in a cell having an opening smaller than 200 μm can be obtained at low cost.

特に、白色表示媒体と黒色表示媒体と三原色カラーフィルターとを用いてカラー表示を行う情報表示用パネルでは、少なくともRGB3色のカラーフィルター3枚分の面積を1表示単位とするため、各色カラーフィルターに対応する画素(ピクセル)サイズはできるだけ小さくすることが高精細カラー表示の面で求められており、このような場合においても、開口が200μmよりも小さいセルへ高精度で粒子群を配置できるようになるとともに、マスク部で基板貼り合せ時の接合部分となる基板間ギャップ確保用隔壁部分の頂上を低コストのマスクで確実にマスクできるので接合部分への粒子付着による弊害を防止でき、表示性能に優れた情報表示用パネルが低コストで得られる。   In particular, in an information display panel that performs color display using a white display medium, a black display medium, and three primary color filters, an area corresponding to at least three RGB color filters is set as one display unit. The size of the corresponding pixel (pixel) is required to be as small as possible in terms of high-definition color display. Even in such a case, the particle group can be arranged with high accuracy in a cell having an opening smaller than 200 μm. At the same time, the top of the partition for securing the gap between the substrates, which becomes the bonding part when bonding the substrates together at the mask part, can be reliably masked with a low-cost mask, so it is possible to prevent harmful effects due to particle adhesion to the bonding part and display performance An excellent information display panel can be obtained at low cost.

まず、本発明の対象となる情報表示用パネルの一例として帯電粒子移動方式の情報表示用パネルの基本的な構成について説明する。前記情報表示用パネルでは、対向する2枚の基板間に封入した帯電性粒子を含んだ粒子群として構成した表示媒体に電界が付与される。付与された電界方向にそって、表示媒体が電界による力やクーロン力などによって引き寄せられ、表示媒体が電界方向の変化によって移動することにより、画像等の情報表示がなされる。従って、表示媒体が、均一に移動し、かつ、繰り返し表示を書き換える時あるいは表示情報を継続して表示する時の安定性を維持できるように、情報表示用パネルを設計する必要がある。ここで、表示媒体を構成する粒子にかかる力は、粒子同士のクーロン力により引き付けあう力の他に、電極や基板との電気鏡像力、分子間力、液架橋力、重力などが考えられる。   First, a basic configuration of an information display panel of a charged particle movement type will be described as an example of an information display panel that is an object of the present invention. In the information display panel, an electric field is applied to a display medium configured as a particle group including a chargeable particle sealed between two opposing substrates. Along with the applied electric field direction, the display medium is attracted by an electric field force or a Coulomb force, and the display medium is moved by a change in the electric field direction, whereby information such as an image is displayed. Therefore, it is necessary to design the information display panel so that the display medium can move uniformly and maintain stability when rewriting the display repeatedly or when displaying the display information continuously. Here, as the force applied to the particles constituting the display medium, in addition to the force attracting each other by the Coulomb force between the particles, an electric mirror image force between the electrode and the substrate, an intermolecular force, a liquid cross-linking force, gravity and the like can be considered.

以下、本発明の製造方法を用いて製造される帯電粒子移動方式の情報表示用パネルの例を、図1(a)〜(c)乃至図3(a)〜(c)に基づき説明する。   Hereinafter, an example of a charged particle movement type information display panel manufactured by using the manufacturing method of the present invention will be described with reference to FIGS. 1 (a) to (c) to FIGS. 3 (a) to (c).

図1(a)〜(c)に示す例では、少なくとも光学的反射率と帯電性とを有する粒子を含む粒子群であって、互いに光学的反射率および帯電特性の異なる表示媒体を2種以上(ここでは負帯電性白色粒子3Waを含んだ粒子群として構成した白色表示媒体3Wと正帯電性黒色粒子3Baを含んだ粒子群として構成した黒色表示媒体3Bを示す)基板間に封入し、隔壁4で形成された各セル7において、基板1に設けた電極5(ライン電極)と基板2に設けた電極6(ライン電極)とが対向直交交差して形成する画素電極対の間に電圧を印加することにより発生する電界に応じて、基板1、2と垂直に移動させる。そして、図1(a)に示すように白色表示媒体3Wを観察者に視認させて白色ドット表示を行うか、あるいは、図1(b)に示すように黒色表示媒体3Bを観察者に視認させて黒色ドット表示を行っている。なお、図1(a)、(b)において、手前にある隔壁は省略している。各セル7に対応したドット状電極対となるようにライン電極5、6を直交対向させた画素とし、各画素(いいかえれば各セル7)に対応してRGBのカラーフィルターを配置した構成とすれば、カラー表示ができる。   In the example shown in FIGS. 1A to 1C, two or more kinds of display media each including a particle group including particles having at least optical reflectance and chargeability, and having different optical reflectance and charging characteristics from each other. (Here, a white display medium 3W configured as a particle group including negatively charged white particles 3Wa and a black display medium 3B configured as a particle group including positively charged black particles 3Ba are shown). In each cell 7 formed by 4, a voltage is applied between a pair of pixel electrodes formed by an electrode 5 (line electrode) provided on the substrate 1 and an electrode 6 (line electrode) provided on the substrate 2 facing each other. The substrate is moved perpendicular to the substrates 1 and 2 in accordance with the electric field generated by the application. Then, as shown in FIG. 1A, the white display medium 3W is visually recognized by the observer and white dot display is performed, or as shown in FIG. 1B, the black display medium 3B is visually recognized by the observer. Black dots are displayed. In addition, in FIG. 1 (a), (b), the partition in front is abbreviate | omitted. The line electrodes 5 and 6 are pixels that are orthogonally opposed so as to form a dot electrode pair corresponding to each cell 7, and an RGB color filter is disposed corresponding to each pixel (in other words, each cell 7). Color display.

本実施例では、図1(a)、(b)に基板間ギャップ確保用隔壁部分として配置する隔壁間に、セル形成用隔壁部分を構成する2本の隔壁を設けた例を示すように、隔壁4を、(1)複数のセル7(本例では、図1(c)にパネルを上から見た図を示すように、3×3=9個のセル7)に対応して形成され、所望の基板間ギャップに対応する高さを有し、情報表示用パネルの基板間ギャップを保持するための基板間ギャップ確保用隔壁部分4−1と、(2)基板間ギャップ確保用隔壁部分4−1以外の部分で形成され、基板1、2間で隙間8または白色粒子3Waを有し、情報表示用パネルの各セル7を形成するためのセル形成用隔壁部分4−2と、から構成している。また、本実施例では、基板間ギャップ確保用隔壁部分4−1を、基板2に所望の基板間ギャップに対応する高さで形成し、その他の基板間空間をセル7に仕切るための隙間8または白色粒子3Waを有するセル形成用隔壁部分4−2を、双方の基板1、2に互いに対向して重なる位置に、双方の隔壁4−2−1、4−2−2の高さを合わせた長さが基板間ギャップ確保用隔壁部分4−1の高さ以下になるよう形成し、基板間ギャップ確保用隔壁部分4−1と背面側の基板1との間および隔壁4−2−1の頂上に接着剤9を配置して基板間ギャップ確保用隔壁部分4−1ともう一方の基板1とを貼り合わせて接合した構造としている。本例では、セル形成用隔壁部分4−2を構成する隔壁4−2−1と隔壁4−2−2との間に挟まれた白色粒子3Waは、接着剤9により固定されている。なお、対向隙間8をD1、表示媒体を構成する粒子群の平均粒子径をD0としたとき、D0≦D1≦1.5×D0となるよう設定し、配置する接着剤層の厚さを1μm〜D0/2とし、隙間8の位置が基板間の中間付近とすることが、パネル基板を歪なく貼り合わせることができるとともに、粒子群を反転移動させて行う表示書き換えを、繰り返すうちに粒子が隣接セルに移動することを抑えられるため好ましい。   In this embodiment, as shown in FIG. 1A and FIG. 1B, as shown in an example in which two partition walls constituting the cell forming partition wall portion are provided between the partition walls arranged as the partition gap securing substrate gap, The partition walls 4 are formed corresponding to (1) a plurality of cells 7 (in this example, 3 × 3 = 9 cells 7 as shown in FIG. 1C when the panel is viewed from above). A partition portion 4-1 for securing a gap between substrates for maintaining a gap between substrates of the information display panel, and (2) a partition portion for securing a gap between substrates. 4-1 is formed in a portion other than 4-1 and has a gap 8 or white particle 3 Wa between the substrates 1 and 2, and a cell-forming partition wall portion 4-2 for forming each cell 7 of the information display panel. It is composed. Further, in the present embodiment, the inter-substrate gap securing partition wall portion 4-1 is formed on the substrate 2 at a height corresponding to the desired inter-substrate gap, and the gap 8 for partitioning the other inter-substrate spaces into the cells 7 is formed. Alternatively, the height of both the partition walls 4-2-1 and 4-2-2 is adjusted so that the cell-forming partition wall part 4-2 having the white particles 3 Wa overlaps with both the substrates 1 and 2. The length is less than the height of the inter-substrate gap securing partition wall portion 4-1, and the distance between the inter-substrate gap securing partition wall portion 4-1 and the substrate 1 on the back side and the partition wall 4-2-1. The adhesive 9 is disposed on the top of the substrate, and the inter-substrate gap securing partition wall portion 4-1 and the other substrate 1 are bonded and bonded together. In this example, the white particles 3 </ b> W sandwiched between the partition 4-2-1 and the partition 4-2-2 constituting the cell forming partition part 4-2 are fixed by the adhesive 9. When the opposing gap 8 is D1 and the average particle diameter of the particle group constituting the display medium is D0, D0 ≦ D1 ≦ 1.5 × D0 is set, and the thickness of the adhesive layer to be arranged is 1 μm. When the position of the gap 8 is in the vicinity of the middle between the substrates, the panel substrate can be bonded without distortion, and the display rewrite performed by reversing the particle group is repeated while the particles are repeatedly displayed. Since it can suppress moving to an adjacent cell, it is preferable.

図2(a)〜(c)に示す例では、少なくとも光学的反射率と帯電性とを有する粒子を含む粒子群であって、互いに光学的反射率および帯電特性が異なる表示媒体を少なくとも2種以上(ここでは負帯電性白色粒子3Waを含んだ粒子群として構成した白色表示媒体3Wと正帯電性黒色粒子3Baを含んだ粒子として構成した黒色表示媒体3Bを示す)基板間に封入し、隔壁4で形成された各セル7において、基板1に設けた電極5(画素電極)と基板2に設けた電極6(画素電極)との間に電圧を印加することにより発生する電界に応じて、基板1、2と垂直に移動させる。そして、図2(a)に示すように白色表示媒体3Wを観察者に視認させて白色ドット表示を行うか、あるいは、図2(b)に示すように黒色表示媒体3Bを観察者に視認させて黒色ドット表示を行っている。なお、図2(a)、(b)において、手前にある隔壁は省略している。この場合も、前述した図1と同様に、カラーフィルターを組み合わせればカラー表示ができる。   In the example shown in FIGS. 2A to 2C, at least two types of display media, each of which includes particles having at least optical reflectance and chargeability, and have different optical reflectance and charging characteristics from each other. As described above, the white display medium 3W configured as a particle group including the negatively charged white particles 3Wa and the black display medium 3B configured as the particles including the positively charged black particles 3Ba are shown between the substrates. In each cell 7 formed by 4, according to the electric field generated by applying a voltage between the electrode 5 (pixel electrode) provided on the substrate 1 and the electrode 6 (pixel electrode) provided on the substrate 2, Move perpendicular to the substrates 1 and 2. Then, as shown in FIG. 2 (a), the white display medium 3W is visually recognized by the observer and white dot display is performed, or as shown in FIG. 2 (b), the black display medium 3B is visually recognized by the observer. Black dots are displayed. In addition, in FIG. 2 (a), (b), the partition in front is abbreviate | omitted. In this case as well, as in FIG. 1 described above, color display can be achieved by combining color filters.

本実施例では、図2(a)、(b)に基板間ギャップ確保用隔壁部分として配置する隔壁間に、セル形成用隔壁部分を構成する2本の隔壁を設けた例を示すように、隔壁4を、(1)複数のセル7(本例では、図2(c)にパネルを上から見た図を示すように、3×3=9個のセル7)に対応して形成され、所望の基板間ギャップに対応する高さを有し、情報表示用パネルの基板間ギャップを保持するための基板間ギャップ確保用隔壁部分4−1と、(2)基板間ギャップ確保用隔壁部分4−1以外の部分で形成され、基板1、2間で隙間8または白色粒子3Waを有し、情報表示用パネルの各セル7を形成するためのセル形成用隔壁部分4−2と、から構成している。また、本実施例では、基板間ギャップ確保用隔壁部分4−1を、基板2に所望の基板間ギャップに対応する高さで形成し、その他の基板間空間をセル7に仕切るための隙間8または白色粒子3Waを有するセル形成用隔壁部分4−2を、双方の基板1、2に互いに対向して重なる位置に、双方の隔壁4−2−1、4−2−2の高さを合わせた長さが基板間ギャップ確保用隔壁部分4−1の高さ以下になるよう形成し、基板間ギャップ確保用隔壁部分4−1と背面側の基板1との間および隔壁4−2−1の頂上に接着剤9を配置して基板間ギャップ確保用隔壁部分4−1ともう一方の基板1とを貼り合わせて接合した構造としている。本例では、セル形成用隔壁部分4−2を構成する隔壁4−2−1と隔壁4−2−2との間に挟まれた白色粒子3Waは、接着剤9により固定されている。なお、対向隙間8をD1、表示媒体を構成する粒子群の平均粒子径をD0としたとき、D0≦D1≦1.5×D0となるよう設定し、配置する接着剤層の厚さを1μm〜D0/2とし、隙間8の位置が基板間の中間付近とすることが、パネル基板を歪なく貼り合わせることができるとともに、粒子群を反転移動させて行う表示書き換えを、繰り返すうちに粒子が隣接セルに移動することを抑えられるため好ましい。   In this embodiment, as shown in FIGS. 2A and 2B, an example in which two partition walls constituting a partition wall portion for cell formation are provided between partition walls arranged as partition wall portions for securing an inter-substrate gap, The partition wall 4 is formed corresponding to (1) a plurality of cells 7 (in this example, 3 × 3 = 9 cells 7 as shown in FIG. 2C when the panel is viewed from above). A partition portion 4-1 for securing a gap between substrates for maintaining a gap between substrates of the information display panel, and (2) a partition portion for securing a gap between substrates. 4-1 is formed in a portion other than 4-1 and has a gap 8 or white particle 3 Wa between the substrates 1 and 2, and a cell-forming partition wall portion 4-2 for forming each cell 7 of the information display panel. It is composed. Further, in the present embodiment, the inter-substrate gap securing partition wall portion 4-1 is formed on the substrate 2 at a height corresponding to the desired inter-substrate gap, and the gap 8 for partitioning the other inter-substrate spaces into the cells 7 is formed. Alternatively, the height of both the partition walls 4-2-1 and 4-2-2 is adjusted so that the cell-forming partition wall part 4-2 having the white particles 3 Wa overlaps with both the substrates 1 and 2. The length is less than the height of the inter-substrate gap securing partition wall portion 4-1, and the distance between the inter-substrate gap securing partition wall portion 4-1 and the substrate 1 on the back side and the partition wall 4-2-1. The adhesive 9 is disposed on the top of the substrate, and the inter-substrate gap securing partition wall portion 4-1 and the other substrate 1 are bonded and bonded together. In this example, the white particles 3 </ b> W sandwiched between the partition 4-2-1 and the partition 4-2-2 constituting the cell forming partition part 4-2 are fixed by the adhesive 9. When the opposing gap 8 is D1 and the average particle diameter of the particle group constituting the display medium is D0, D0 ≦ D1 ≦ 1.5 × D0 is set, and the thickness of the adhesive layer to be arranged is 1 μm. When the position of the gap 8 is in the vicinity of the middle between the substrates, the panel substrate can be bonded without distortion, and the display rewrite performed by reversing the particle group is repeated while the particles are repeatedly displayed. Since it can suppress moving to an adjacent cell, it is preferable.

図3(a)〜(c)に示す例では、少なくとも光学的反射率と帯電性とを有する粒子を含む粒子群であって、互いに光学的反射率および帯電特性の異なる表示媒体を2種以上(ここでは負帯電性白色粒子3Waを含んだ粒子群として構成した白色表示媒体3Wと正帯電性黒色粒子3Baを含んだ粒子群として構成した黒色表示媒体3Bを示す)基板間に封入し、隔壁4で形成された各セル7において、基板1に設けた電極5(ライン電極)と基板2に設けた電極6(ライン電極)とが対向直交交差して形成する画素電極対の間に電圧を印加することにより発生する電界に応じて、基板1、2と垂直に移動させる。そして、図3(a)に示すように白色表示媒体3Wを観察者に視認させて白色ドット表示を行うか、あるいは、図3(b)に示すように黒色表示媒体3Bを観察者に視認させて黒色ドット表示を行っている。なお、図4(a)、(b)において、手前にある隔壁は省略している。   In the example shown in FIGS. 3A to 3C, two or more kinds of display media each including a particle group including particles having at least optical reflectance and chargeability, and having different optical reflectance and charging characteristics from each other. (Here, a white display medium 3W configured as a particle group including negatively charged white particles 3Wa and a black display medium 3B configured as a particle group including positively charged black particles 3Ba are shown). In each cell 7 formed by 4, a voltage is applied between a pair of pixel electrodes formed by an electrode 5 (line electrode) provided on the substrate 1 and an electrode 6 (line electrode) provided on the substrate 2 facing each other. The substrate is moved perpendicular to the substrates 1 and 2 in accordance with the electric field generated by the application. Then, the white display medium 3W is visually recognized by the observer as shown in FIG. 3A, or white dot display is performed, or the black display medium 3B is visually recognized by the observer as shown in FIG. Black dots are displayed. In addition, in FIG. 4 (a), (b), the partition in front is abbreviate | omitted.

本実施例では、図3(a)、(b)に基板間ギャップ確保用隔壁部分として配置する隔壁間に、セル形成用隔壁部分を構成する2本の隔壁を設けた例を示すように、隔壁4を、(1)複数のセル7(本例では、図3(c)にパネルを上から見た図を示すように、3×3=9個のセル7)に対応して形成され、所望の基板間ギャップに対応する高さを有し、情報表示用パネルの基板間ギャップを保持するための基板間ギャップ確保用隔壁部分4−1と、(2)基板間ギャップ確保用隔壁部分4−1以外の部分で形成され、基板1、2間で隙間8または白色粒子3Waを有し、情報表示用パネルの各セル7を形成するためのセル形成用隔壁部分4−2と、から構成している。また、本実施例では、基板間ギャップ確保用隔壁部分4−1を、基板2に所望の基板間ギャップに対応する高さで形成し、その他の基板間空間をセル7に仕切るための隙間8または白色粒子3Waを有するセル形成用隔壁部分4−2を、双方の基板1、2に互いに対向して重なる位置に、双方の隔壁4−2−1、4−2−2の高さを合わせた長さが基板間ギャップ確保用隔壁部分4−1の高さ以下になるよう形成し、基板間ギャップ確保用隔壁部分4−1と背面側の基板1との間、および、隔壁4−2−1と隔壁4−2−2との間に接着剤9を配置して基板間ギャップ確保用隔壁部分4−1ともう一方の基板1とを貼り合わせて接合した構造としている。本例では、セル形成用隔壁部分4−2を構成する隔壁4−2−1と隔壁4−2−2との間に挟まれた白色粒子3Waは、接着剤9により固定されている。なお、本例では、対向するセル形成用隔壁部分4−2を構成する隔壁4−2−1、4−2−2の高さは、背面側の基板1に設ける隔壁4−2−1の方を短くして、隙間8がややパネルの背面側に近い中央付近の位置になるようにしている。このようにすることで、隙間8に粒子がはさまって固定された場合でも表示面側から、このはまった粒子が見えにくくなり、表示性の面で好ましい。   In this embodiment, as shown in FIGS. 3A and 3B, two partition walls constituting the cell forming partition wall portion are provided between the partition walls disposed as the inter-substrate gap securing partition wall portion. The partition walls 4 are formed corresponding to (1) a plurality of cells 7 (in this example, 3 × 3 = 9 cells 7 as shown in FIG. 3C when the panel is viewed from above). A partition portion 4-1 for securing a gap between substrates for maintaining a gap between substrates of the information display panel, and (2) a partition portion for securing a gap between substrates. 4-1 is formed in a portion other than 4-1 and has a gap 8 or white particle 3 Wa between the substrates 1 and 2, and a cell-forming partition wall portion 4-2 for forming each cell 7 of the information display panel. It is composed. Further, in the present embodiment, the inter-substrate gap securing partition wall portion 4-1 is formed on the substrate 2 at a height corresponding to the desired inter-substrate gap, and the gap 8 for partitioning the other inter-substrate spaces into the cells 7 is formed. Alternatively, the height of both the partition walls 4-2-1 and 4-2-2 is adjusted so that the cell-forming partition wall part 4-2 having the white particles 3 Wa overlaps with both the substrates 1 and 2. The length is less than the height of the inter-substrate gap securing partition wall portion 4-1, so that the inter-substrate gap securing partition wall portion 4-1 and the rear substrate 1 and the partition wall 4-2 are formed. 1 and the partition wall 4-2, the adhesive 9 is disposed, and the partition wall portion 4-1 for securing the inter-substrate gap and the other substrate 1 are bonded and bonded together. In this example, the white particles 3 </ b> W sandwiched between the partition 4-2-1 and the partition 4-2-2 constituting the cell forming partition part 4-2 are fixed by the adhesive 9. In this example, the height of the partition 4-2-1 and 4-2-2 constituting the opposing cell-forming partition part 4-2 is the same as that of the partition 4-2-1 provided on the substrate 1 on the back side. The gap 8 is shortened so that the gap 8 is located near the center near the back side of the panel. By doing in this way, even when a particle is sandwiched and fixed in the gap 8, it is difficult to see the trapped particle from the display surface side, which is preferable in terms of display properties.

次に、本発明の情報表示用パネルの製造方法の一例を、図4(a)〜(e)および図5(a)〜(c)に基づき説明する。   Next, an example of the manufacturing method of the information display panel of this invention is demonstrated based on Fig.4 (a)-(e) and Fig.5 (a)-(c).

図4(a)〜(e)に示す例に従って製造方法の一実施例を説明すると、まず、図4(a)〜(e)の工程を実施する前に、表示媒体とする粒子群を充填する方の基板には、セル形成用隔壁部分4−2および基板間ギャップ確保用隔壁部分4−1を形成する。セル形成用隔壁部分4−2は、隔壁4−2−1、4−2−2が対向したときにその頂上間に対向隙間8ができるように構成する。次に、図4(a)に示すように、隔壁4−2−2とそれよりも高い基板間ギャップ確保用隔壁部分4−1とを有するパネル基板2上に、図5(a)に一例を示す基板間ギャップ確保用隔壁頂上部分をマスクする構造の開口部12を有するマスク11を図5(b)に示すセル7に対し図5(c)に示すように配置し、マスク11の上方から第1の表示媒体(本例では負帯電性白色粒子3Waを含んだ粒子群として構成した白色表示媒体3W)を落下させ、マスク11の開口部12に対応した、隔壁4−2−2および基板間ギャップ確保用隔壁部分4−1で仕切られたパネル基板2上のセル7内に白色表示媒体3Wを配置する。続いて、図4(b)に示すように、マスク11の上方から第2の表示媒体(本例では正帯電性黒色粒子3Baを含んだ粒子群として構成した黒色表示媒体3B)を落下させ、すでに配置した白色表示媒体3W上に配置する。   An example of the manufacturing method will be described in accordance with the example shown in FIGS. 4A to 4E. First, before the steps of FIGS. 4A to 4E are performed, a particle group serving as a display medium is filled. A cell forming partition wall portion 4-2 and an inter-substrate gap securing partition wall portion 4-1 are formed on the other substrate. The cell forming partition wall portion 4-2 is configured such that a facing gap 8 is formed between the tops of the partition walls 4-2-1 and 4-2-2 when facing each other. Next, as shown in FIG. 4A, an example is shown in FIG. 5A on a panel substrate 2 having a partition wall 4-2-2 and a partition portion 4-1 for securing an inter-substrate gap higher than that. As shown in FIG. 5C, a mask 11 having an opening 12 having a structure for masking the top portion of the inter-substrate gap securing partition is disposed as shown in FIG. The first display medium (in this example, the white display medium 3W configured as a particle group including the negatively charged white particles 3Wa) is dropped, and the partition 4-2-2 corresponding to the opening 12 of the mask 11 and The white display medium 3W is disposed in the cell 7 on the panel substrate 2 partitioned by the partition wall portion 4-1 for securing the inter-substrate gap. Subsequently, as shown in FIG. 4B, the second display medium (in this example, the black display medium 3B configured as a particle group including the positively charged black particles 3Ba) is dropped from above the mask 11, It arrange | positions on the white display medium 3W already arrange | positioned.

この表示媒体を構成する粒子群の充填にあたっては、セル7の開口部上にマスク11のマスク部分がないことになるので、粒子群はセル7内に均一に充填され、セル7ごとのばらつきがない。特に、セル7の開口部の最大対角距離が100μm程度となるような粒子の直径とセル開口部とにあまり差違のない場合に上記効果が大きくなる。また、図4(b)に示すように、セル形成用隔壁部分4−2を構成する隔壁4−2−2上に粒子が付着していても、後述するように、パネル貼り合わせ時に接着剤で固定され、所定の基板間ギャップを保って貼り合わすことができる。   In filling the particle group constituting the display medium, since there is no mask portion of the mask 11 on the opening of the cell 7, the particle group is uniformly filled in the cell 7, and the variation for each cell 7 varies. Absent. In particular, the above effect is enhanced when there is not much difference between the particle diameter and the cell opening such that the maximum diagonal distance of the opening of the cell 7 is about 100 μm. Further, as shown in FIG. 4 (b), even when particles are adhered on the partition wall 4-2-2 constituting the cell-forming partition wall portion 4-2, as described later, an adhesive is used at the time of bonding the panels. Can be bonded together with a predetermined gap between the substrates.

次に、図4(c)に示すように、マスク11を取り外し、基板間ギャップ確保用隔壁部分4−1上にパネル基板貼り合わせ用の接着剤9を配置する。そして、図4(d)に示すように、表示媒体を充填しなかった基板1側のセル形成用隔壁部分4−2を構成するセル4−2−1の頂上にも接着剤9を厚さ1μm〜D0/2で配置し、隔壁4−2−2上に黒色粒子3Baが残っていてもそのままの状態で、基板1、2を貼り合わせる。その結果、図4(e)に示すように、セル形成用隔壁部分4−2を構成する隔壁4−2−1と4−2−2との間に粒子が挟まった状態が部分的に存在する隙間8を有するセル形成用隔壁部分4−2を構成した情報表示用パネルを作製している。なお、隔壁4−2−2上に粒子が残っていない部分には、D0≦D1≦1.5×D0(D1は隙間間隔、D0は平均粒子径)の隙間8が形成されている。   Next, as shown in FIG. 4C, the mask 11 is removed, and the adhesive 9 for laminating the panel substrates is disposed on the inter-substrate gap securing partition wall portion 4-1. Then, as shown in FIG. 4D, the adhesive 9 is also thickened on the top of the cell 4-2-1 that constitutes the cell forming partition part 4-2 on the substrate 1 side that is not filled with the display medium. Even if the black particles 3Ba remain on the partition wall 4-2-2, the substrates 1 and 2 are bonded together in the state of 1 μm to D0 / 2. As a result, as shown in FIG. 4E, there is a partial state in which particles are sandwiched between the barrier ribs 4-2-1 and 4-2-2 constituting the barrier rib portion 4-2 for cell formation. Thus, an information display panel having a cell-forming partition wall portion 4-2 having a gap 8 is produced. A gap 8 of D0 ≦ D1 ≦ 1.5 × D0 (D1 is a gap interval and D0 is an average particle diameter) is formed in a portion where no particles remain on the partition wall 4-2-2.

以下、本発明の情報表示用パネルを構成する各部材の材料等について、さらに詳細に説明する。   Hereinafter, materials and the like of each member constituting the information display panel of the present invention will be described in more detail.

一方のパネル基板に形成された基板間ギャップ確保用隔壁部分の頂上およびもう一方の基板間ギャップ確保用隔壁部分が形成されていないパネル基板に形成されたセル形成用隔壁部分の頂上に配置するパネル基板貼り合せ用接着剤は、1μm〜D0/2(D0は表示媒体とする粒子群の平均粒子径)の範囲の厚さで各隔壁部分の頂上に配置する。
接着剤としては、アクリル樹脂、メタクリル樹脂やそれらの混合物を主成分とするアクリル系接着剤や、エポキシ系樹脂を主成分とするエポキシ系接着剤が好適であるが、その他の汎用接着剤を用いることもできる。
基板間ギャップ確保用隔壁部分の頂上に配置する接着剤は、貼り合わされたパネル構造体の接合部分を保持するために接合強度に優れることが好ましく、配置する接着剤層としての厚さは、前述した1μm〜D0/2に限定する必要はなく、接合強度を勘案した適正な厚さで上記接着剤を配置する。
A panel arranged on the top of the partition for securing the gap between substrates formed on one panel substrate and on the top of the partition for forming a cell formed on the panel substrate on which the partition for securing the gap between the other substrates is not formed. The substrate bonding adhesive is disposed on the top of each partition wall with a thickness in the range of 1 μm to D0 / 2 (D0 is the average particle diameter of the particle group used as the display medium).
As the adhesive, an acrylic adhesive mainly composed of an acrylic resin, a methacrylic resin or a mixture thereof, or an epoxy adhesive mainly composed of an epoxy resin is suitable, but other general-purpose adhesives are used. You can also.
The adhesive disposed on the top of the partition for securing the gap between the substrates preferably has excellent bonding strength in order to hold the bonded portion of the bonded panel structure, and the thickness as the adhesive layer to be disposed is as described above. It is not necessary to limit to 1 μm to D0 / 2, and the adhesive is disposed with an appropriate thickness considering the bonding strength.

基板間ギャップ確保用隔壁部分4−1およびセル形成用隔壁部分4−2の形成材料としては、ドライフィルムレジストが好適に用いられる。一例として、アルフォNIT2(ニチゴーモートン社製)やPDF300(新日鐵化学社製)を使用することができる。   A dry film resist is suitably used as a material for forming the inter-substrate gap securing partition 4-1 and the cell forming partition 4-2. As an example, Alfo NIT2 (manufactured by Nichigo Morton) or PDF300 (manufactured by Nippon Steel Chemical Co., Ltd.) can be used.

基板間ギャップ確保用隔壁部分4−1や、セル形成用隔壁部分4−2を形成する基板に、所望の隔壁高さに相当する厚さのドライフィルムレジストを積層後、フォトリソ法によって不要部分を除去して隔壁部分を形成する。基板間ギャップ確保用隔壁部分4−1とセル形成用隔壁部分4−2とを同じドライフィルムレジストを積層して用いてすべて同じ材料構成で双方の隔壁4−2−1、4−2−2を形成することもできるし、それぞれ別のドライフィルムレジストを用いて積層後それぞれの隔壁部分を形成したり、双方のパネル基板に対向形成するセル形成用隔壁部分4−2を構成する隔壁4−2−1、4−2−2を、それぞれ別のドライフィルムレジストを用いて形成することもできる。セルと画素とを対応させる場合には、セル配置は格子状マトリックス配置とする。   After laminating a dry film resist having a thickness corresponding to the desired partition wall height on the substrate on which the inter-substrate gap securing partition part 4-1 and the cell formation partition part 4-2 are formed, unnecessary portions are formed by photolithography. A partition wall portion is formed by removing. The partition wall portion 4-1 for securing the inter-substrate gap and the partition wall portion 4-2 for cell formation are laminated with the same dry film resist, and both the partition walls 4-2-1 and 4-2-2 are formed with the same material configuration. The barrier ribs 4 may be formed by using different dry film resists to form the respective barrier rib portions, or to form the barrier rib portions 4-2 for forming cells facing both panel substrates. 2-1 and 4-2-2 can also be formed using different dry film resists. When the cells and the pixels are associated with each other, the cell arrangement is a lattice matrix arrangement.

基板間ギャップ確保用として設ける基板間ギャップ確保用隔壁部分4−1の部分とセル形成用隔壁部分4−2の部分とで構成されるセル配置は、格子状、ハニカム状、網目状などがあり、セルの横断面形状は、四角形、三角形、六角形等の多角形や、円形、楕円形、レーストラック形等がありいずれでも良いし、複数の形状を組み合わせても良い。表示部の開口率を大きくできる点からは四角形や六角形が好ましく、表示媒体を構成する粒子を移動しやすくできる点からは曲線を有する形状が好ましい。前記二つの点から角丸付きの四角形、各丸付きの六角形が好ましく用いられる。   The cell arrangement composed of the inter-substrate gap securing partition part 4-1 and the cell-forming partition part 4-2 provided for securing the inter-substrate gap includes a lattice shape, a honeycomb shape, a mesh shape, and the like. The cross-sectional shape of the cell may be a polygon such as a quadrangle, a triangle, or a hexagon, a circle, an ellipse, a racetrack, or the like, or a combination of a plurality of shapes. From the point that the aperture ratio of the display unit can be increased, a quadrangle or hexagon is preferable, and from the point that particles constituting the display medium can be easily moved, a shape having a curve is preferable. From the two points, a square with rounded corners and a hexagon with each round are preferably used.

マスク11は、材料にステンレス鋼(SUS304など)、アルミニウム、鉄、銅等の金属を用いたメタルマスクや、汎用プラスチックを用いた樹脂製マスクおよびメタルと樹脂とを組み合わせた積層マスクなどが用いられる。メタルマスクの一部に絶縁部材を設けて部分的に絶縁性部分を有する導電性メタルマスクとしたり、樹脂製マスクの一部に導電部材を設けて部分的に導電性部材を有する導電性マスクとしたりすることができる。   As the mask 11, a metal mask using a metal such as stainless steel (SUS304, etc.), aluminum, iron, copper, etc., a resin mask using a general-purpose plastic, a laminated mask combining a metal and a resin, or the like is used. . An insulating member is provided on a part of the metal mask to form a conductive metal mask having a partially insulating portion, or a conductive mask is provided on a part of a resin mask to form a conductive mask having a partially conductive member. Can be.

基板に電極を設ける場合に、対向して配置する電極の電極材料としては、透明基板側に設ける透明電極としては、酸化インジウム錫(ITO)、酸化インジウム、亜鉛ドープ酸化インジウム(IZO)、アルミニウムドープ酸化亜鉛(AZO)、アンチモン錫酸化物(ATO)、導電性酸化錫、導電性酸化亜鉛等の透明導電金属酸化物類、ポリアニリン、ポリピロール、ポリチオフェン等の透明導電性高分子類が挙げられる。   When an electrode is provided on the substrate, as an electrode material of the electrode disposed to face the transparent electrode provided on the transparent substrate side, indium tin oxide (ITO), indium oxide, zinc-doped indium oxide (IZO), aluminum doped Examples thereof include transparent conductive metal oxides such as zinc oxide (AZO), antimony tin oxide (ATO), conductive tin oxide, and conductive zinc oxide, and transparent conductive polymers such as polyaniline, polypyrrole, and polythiophene.

背面基板側に設ける電極としては、酸化インジウム錫(ITO)、酸化インジウム、亜鉛ドープ酸化インジウム(IZO)、アルミニウムドープ酸化亜鉛(AZO)、アンチモン錫酸化物(ATO)、導電性酸化錫、導電性酸化亜鉛等の導電金属酸化物類、ポリアニリン、ポリピロール、ポリチオフェン等の導電性高分子類や、金、銀、銅、アルミニウム、ニッケル、クロム等の金属や、これらの金属を主成分とする合金が挙げられる。背面側基板に設ける電極は透明であってもよいし、透明でなくても良い。   As an electrode provided on the back substrate side, indium tin oxide (ITO), indium oxide, zinc-doped indium oxide (IZO), aluminum-doped zinc oxide (AZO), antimony tin oxide (ATO), conductive tin oxide, conductive Conductive metal oxides such as zinc oxide, conductive polymers such as polyaniline, polypyrrole and polythiophene, metals such as gold, silver, copper, aluminum, nickel and chromium, and alloys based on these metals Can be mentioned. The electrode provided on the back side substrate may be transparent or may not be transparent.

電極の形成方法としては、上記例示の材料をスパッタリング法、真空蒸着法、CVD(化学蒸着)法、塗布法等で薄膜状に形成する方法や金属箔(例えば圧延銅箔)をラミネートする方法、導電剤を溶媒や合成樹脂バインダーに混合して塗布したりする方法が用いられる。パターン形成可能で導電性である上記材料を好適に用いることもできる。なお、表示面側電極厚みは、導電性が確保でき光透過性が支障がなければ良く、0.01〜10μmが好ましく、0.05〜5μmがより好ましい。また、背面側電極厚みは、導電性が確保できれば良く、0.01〜10μmが好ましく、0.05〜5μmがより好ましい。   As a method for forming an electrode, a method of forming the above-described material into a thin film by sputtering, vacuum deposition, CVD (chemical vapor deposition), coating, or the like, a method of laminating a metal foil (for example, rolled copper foil), A method in which a conductive agent is mixed with a solvent or a synthetic resin binder and applied. The above-mentioned material that can be patterned and is electrically conductive can also be suitably used. The display surface side electrode thickness is preferably 0.01 to 10 [mu] m, more preferably 0.05 to 5 [mu] m, as long as electrical conductivity can be secured and light transmittance is not hindered. Moreover, the back side electrode thickness should just ensure electroconductivity, 0.01-10 micrometers is preferable and 0.05-5 micrometers is more preferable.

表示面側電極として好適な透明導電性材料は、金属材料に比べて可とう性が小さいため透明電極材中での断線防止のため、金属細線と併用することが好ましい。この金属細線の幅は、1μm〜10μmとすれば表示視認性の妨げにならないので好ましい。背面側電極は光透過性を考慮する必要がないので電気抵抗が小さく、可とう性にも優れた前記金属材料が好適に用いられる。また、背面側電極厚みは電気抵抗および生産性、コストの観点から、0.01〜10μmに設計される。   Since a transparent conductive material suitable as a display surface side electrode is less flexible than a metal material, it is preferably used in combination with a thin metal wire in order to prevent disconnection in the transparent electrode material. The width of the fine metal wire is preferably 1 μm to 10 μm because display visibility is not hindered. Since the back side electrode does not need to consider light transmittance, the metal material having low electrical resistance and excellent flexibility is preferably used. The thickness of the back electrode is designed to be 0.01 to 10 μm from the viewpoint of electrical resistance, productivity, and cost.

本発明の情報表示用パネルは、ノートパソコン、電子手帳、PDA(Personal Digital Assistants)と呼ばれる携帯型情報機器、携帯電話、ハンディターミナル等のモバイル機器の表示部、電子書籍、電子新聞等の電子ペーパー、看板、ポスター、黒板(ホワイトボード)等の掲示板、電子卓上計算機、家電製品、自動車用品等の表示部、ポイントカード、ICカード等のカード表示部、電子広告、情報ボード、電子POP(Point Of Presence, Point Of Purchase advertising)、電子値札、電子棚札、電子楽譜、RF−ID機器の表示部のほか、POS端末、カーナビゲーション装置、時計など様々な電子機器の表示部に好適に用いられるほか、外部書換え手段に接続して表示書換えを行う表示部(リライタブルペーパー)や外部電界形成手段等を用いて電気的に駆動可能な粒子を含んだ粒子群として構成した表示媒体を電気的に駆動させて表示書き換えを行う表示部(リライタブルペーパー)としても好適に用いられる   The information display panel according to the present invention includes a notebook computer, an electronic notebook, a portable information device called PDA (Personal Digital Assistants), a display unit of a mobile device such as a mobile phone and a handy terminal, an electronic paper such as an electronic book and an electronic newspaper. , Billboards such as signboards, posters, blackboards (whiteboards), electronic desk calculators, display units for home appliances, automotive products, card display units such as point cards, IC cards, electronic advertisements, information boards, electronic POPs (Point Of) Presence, Point Of Purchase advertising), electronic price tag, electronic shelf label, electronic score, display part of RF-ID equipment, as well as other electronic equipment display parts such as POS terminals, car navigation devices, watches, etc. Can be electrically driven using a display unit (rewritable paper) that rewrites the display by connecting to external rewriting means, external electric field forming means, etc. It is also suitably used as a display unit (rewritable paper) that performs display rewriting by electrically driving a display medium configured as a particle group including active particles.

本発明の情報表示用パネルに用いる表示媒体については、これまでに説明した帯電性粒子を含んだ粒子群や導電性粒子を含んだ粒子群、半導体性粒子を含んだ粒子群など電気的駆動が可能な粒子を含んだ粒子群を用いることができる。本発明の情報表示用パネルの駆動方式については、パネル自体にスイッチング素子を用いない単純マトリックス駆動方式やスタティック駆動方式、また、薄膜トランジスタ(TFT)で代表される三端子スイッチング素子あるいは薄膜ダイオード(TFD)で代表される二端子スイッチング素子を用いたアクティブマトリックス駆動方式や、種々のタイプの駆動方式が適用できる。   For the display medium used in the information display panel of the present invention, the electric drive such as the particle group including the chargeable particle, the particle group including the conductive particle, the particle group including the semiconductor particle, which has been described so far, can be performed. Particle groups containing possible particles can be used. As for the driving method of the information display panel of the present invention, a simple matrix driving method and a static driving method which do not use a switching element in the panel itself, a three-terminal switching element represented by a thin film transistor (TFT) or a thin film diode (TFD). An active matrix driving method using a two-terminal switching element represented by, and various types of driving methods can be applied.

(a)〜(c)はそれぞれ本発明の情報表示用パネルの一例の構成を示す図である。(A)-(c) is a figure which shows the structure of an example of the information display panel of this invention, respectively. (a)〜(c)はそれぞれ本発明の情報表示用パネルの他の例の構成を示す図である。(A)-(c) is a figure which shows the structure of the other example of the information display panel of this invention, respectively. (a)〜(c)はそれぞれ本発明の情報表示用パネルのさらに他の例の構成を示す図である。(A)-(c) is a figure which shows the structure of the further another example of the information display panel of this invention, respectively. (a)〜(e)はそれぞれ本発明の情報表示用パネルの製造方法の一例を説明するための図である。(A)-(e) is a figure for demonstrating an example of the manufacturing method of the information display panel of this invention, respectively. (a)〜(c)はそれぞれ本発明の情報表示用パネルを製造する際に好適に用いるマスクと隔壁との関係を説明するための図である。(A)-(c) is a figure for demonstrating the relationship between the mask suitably used when manufacturing the information display panel of this invention, and a partition, respectively. (a)〜(e)はそれぞれ従来の情報表示用パネルを従来の平板状のマスクを用いて製造する方法の一例を説明するための図である。(A)-(e) is a figure for demonstrating an example of the method of manufacturing the conventional information display panel using the conventional flat mask. (a)〜(c)はそれぞれ従来の情報表示用パネルを従来の平板状のマスクを用いて製造する方法の他の例を説明するための図である。(A)-(c) is a figure for demonstrating the other example of the method of manufacturing the conventional information display panel, respectively using the conventional flat mask. (a)〜(d)はそれぞれ図6(a)〜(e)に示した従来の情報表示用パネルの製造方法における問題点を説明するための図である。(A)-(d) is a figure for demonstrating the problem in the manufacturing method of the conventional information display panel shown to Fig.6 (a)-(e), respectively. (a)〜(d)はそれぞれ図7(a)〜(c)に示した従来の情報表示用パネルの製造方法における問題点を説明するための図である。(A)-(d) is a figure for demonstrating the problem in the manufacturing method of the conventional information display panel shown to Fig.7 (a)-(c), respectively.

符号の説明Explanation of symbols

1、2 基板
3W 白色表示媒体(白色粒子群)
3Wa 白色粒子
3B 黒色表示媒体(黒色粒子群)
3Ba 黒色粒子
4−1 基板間ギャップ確保用隔壁部分
4−2 セル形成用隔壁部分
4−2−1、4−2−2 セル形成用隔壁部分を構成する部分
5、6 電極
7 セル
9 接着剤
11 マスク
12 マスクの開口部
1, 2 substrate 3W white display medium (white particles)
3Wa White particles 3B Black display medium (Black particles group)
3Ba Black particles 4-1 Separation part for securing gap between substrates 4-2 Separation part for cell formation 4-2-1, 4-2-2 Part constituting cell formation partition part 5, 6 Electrode 7 Cell 9 Adhesive 11 Mask 12 Mask opening

Claims (5)

少なくとも一方が透明である、所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された一方の基板と、専ら基板間の空間を仕切るための隔壁部分が形成されたもう一方の基板とを、所定基板間ギャップをもって貼り合せたパネル構造体の隔壁で仕切られた複数のセル内に、光学的反射率を有し、電気的に駆動可能な粒子を含んだ粒子群として構成した表示媒体を配置し、表示媒体を電気的に駆動させて画像等の情報を表示する情報表示用パネルであって、
前記双方の基板にそれぞれ分割して形成され、専ら基板間の空間を仕切るための隔壁部分は、隙間D1をもって対向するか、あるいは、平均粒子径がD0の表示媒体とする粒子群を構成する粒子を部分的に挟んで対向するものであって、このとき、D0≦D1≦1.5×D0を満たすことを特徴とする情報表示用パネル。
At least one of the substrates is transparent, and the partition wall portion for partitioning the space between the substrates is provided with one substrate formed with a partition wall portion that serves to ensure a predetermined gap between the substrates and partition the space between the substrates. A plurality of cells partitioned by partition walls of a panel structure in which the other substrate formed is bonded with a predetermined inter-substrate gap, and containing electrically reflective particles having optical reflectivity. An information display panel that arranges a display medium configured as a particle group and electrically drives the display medium to display information such as an image,
Particles that are formed separately on both the substrates and that form a group of particles that are used as a display medium having a gap D1 opposed to each other with a gap D1 exclusively for partitioning the space between the substrates. Is an information display panel characterized by satisfying D0 ≦ D1 ≦ 1.5 × D0.
前記双方の基板にそれぞれ分割して形成され、専ら基板間の空間を仕切るための隔壁部分のうち、所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された基板ではない方の基板に形成された専ら基板間の空間を仕切るための隔壁部分には、厚さが1μm〜D0/2の接着剤層が形成されていることを特徴とする請求項1に記載の情報表示用パネル。   Formed separately on both of the substrates, a partition portion that exclusively serves to partition the space between the substrates and to partition the space between the substrates among the partition portions for partitioning the space between the substrates exclusively. 2. An adhesive layer having a thickness of 1 μm to D0 / 2 is formed in a partition wall portion for partitioning a space between the substrates exclusively formed on the substrate that is not the formed substrate. 2. The information display panel according to 1. 専ら基板間の空間を仕切るための隔壁部分が対向して配置されたときに形成される隙間D1は、基板間ギャップにおいて中央付近の位置にあることを特徴とする請求項1または2に記載の情報表示用パネル。   3. The gap D <b> 1 formed when the partition wall portions for partitioning the space between the substrates are arranged opposite to each other are located in the vicinity of the center in the inter-substrate gap. 4. Information display panel. 専ら基板間の空間を仕切るための隔壁部分が対向して配置されたときに形成される隙間D1は、基板間ギャップにおいて背面側基板に近い位置にあることを特徴とする請求項1または2に記載の情報表示用パネル。   3. The gap D <b> 1 formed when the partition wall portions for partitioning the space between the substrates are disposed so as to face each other is in a position close to the back side substrate in the inter-substrate gap. The information display panel described. 少なくとも一方が透明である、所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された一方の基板と、専ら基板間の空間を仕切るための隔壁部分が形成されたもう一方の基板とを、所定基板間ギャップをもって貼り合せたパネル構造体の隔壁で仕切られた複数のセル内に、光学的反射率を有し、電気的に駆動可能な粒子を含んだ粒子群として構成した表示媒体を配置し、表示媒体を電気的に駆動させて画像等の情報を表示する情報表示用パネルの製造方法であって、
2枚の基板のうち所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分とが形成された基板上のセル内に表示媒体を充填し、この基板に形成された所定基板間ギャップを確保することと基板間の空間を仕切ることとを兼ねる隔壁部分の頂上およびもう一方の基板に形成された専ら基板間の空間を仕切るための隔壁部分の頂上に、接着剤を配置して、2枚の基板を貼り合せてパネル構造体とすることを特徴とする請求項1〜4のいずれか1項に記載の情報表示用パネルの製造方法。
At least one of the substrates is transparent, and the partition wall portion for partitioning the space between the substrates is provided with one substrate formed with a partition wall portion that serves to ensure a predetermined gap between the substrates and partition the space between the substrates. A plurality of cells partitioned by partition walls of a panel structure in which the other substrate formed is bonded with a predetermined inter-substrate gap, and containing electrically reflective particles having optical reflectivity. A method of manufacturing an information display panel in which a display medium configured as a particle group is arranged and the display medium is electrically driven to display information such as an image,
A display medium is filled in a cell on a substrate formed with a partition wall portion that serves to secure a predetermined gap between the two substrates and to partition a space between the substrates, and is formed on the substrate. Adhesive is applied to the top of the partition wall portion that serves to ensure a predetermined gap between the substrates and partition the space between the substrates, and to the top of the partition wall portion for exclusively partitioning the space between the substrates formed on the other substrate. The method for manufacturing an information display panel according to any one of claims 1 to 4, wherein the panel is formed by arranging and bonding two substrates together.
JP2008140929A 2008-05-29 2008-05-29 Panel for information display and method for manufacturing the same Pending JP2009288522A (en)

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