JP2009213701A - Heat storable heating apparatus - Google Patents

Heat storable heating apparatus Download PDF

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JP2009213701A
JP2009213701A JP2008061296A JP2008061296A JP2009213701A JP 2009213701 A JP2009213701 A JP 2009213701A JP 2008061296 A JP2008061296 A JP 2008061296A JP 2008061296 A JP2008061296 A JP 2008061296A JP 2009213701 A JP2009213701 A JP 2009213701A
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container
heat storage
latent heat
paraffin
heat
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JP2009213701A5 (en
JP4621264B2 (en
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Kunihiko Komiya
邦彦 小宮
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YAMAICHI KK
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D20/02Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00 using latent heat
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F7/00Heating or cooling appliances for medical or therapeutic treatment of the human body
    • A61F7/02Compresses or poultices for effecting heating or cooling
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K5/00Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
    • C09K5/02Materials undergoing a change of physical state when used
    • C09K5/06Materials undergoing a change of physical state when used the change of state being from liquid to solid or vice versa
    • C09K5/063Materials absorbing or liberating heat during crystallisation; Heat storage materials
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61FFILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
    • A61F7/00Heating or cooling appliances for medical or therapeutic treatment of the human body
    • A61F7/02Compresses or poultices for effecting heating or cooling
    • A61F2007/0292Compresses or poultices for effecting heating or cooling using latent heat produced or absorbed during phase change of materials, e.g. of super-cooled solutions
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28HEAT EXCHANGE IN GENERAL
    • F28DHEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D20/00Heat storage plants or apparatus in general; Regenerative heat-exchange apparatus not covered by groups F28D17/00 or F28D19/00
    • F28D2020/0004Particular heat storage apparatus
    • F28D2020/0008Particular heat storage apparatus the heat storage material being enclosed in plate-like or laminated elements, e.g. in plates having internal compartments
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Biomedical Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Heart & Thoracic Surgery (AREA)
  • Veterinary Medicine (AREA)
  • Vascular Medicine (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Combustion & Propulsion (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Thermotherapy And Cooling Therapy Devices (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a heat storable heating apparatus where a paraffin-based latent heat thermal storage material prepared into powder particles are sealed air-tightly in a bag container, and the solid powder-like particles of the paraffin-based latent heat thermal storage material always keep the flowability, and enough flexibility is secured over the whole heating apparatus to provide good fitting property to an affected part of a body. <P>SOLUTION: The paraffin-based latent heat thermal storage material 1 is sealed in a bag container 2 of the heating apparatus, and the bag container 2 has an interior container 3 where the wall surface is formed of a sheet stock having air permeability and impermeability to the powder-like particles of potentially-heating heat storage material and water, and a first exterior container 5 which is formed of a rubber with a roughly oblong shape and covered via an air layer 4 to the interior container 3 without direct contact, and a plurality of first exterior containers 5 are stored in a cloth exterior holder type second container of the heat storable heating apparatus in order to row and fold them. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

この発明は、身体の一部を温める温熱療法などに利用され、健康器具や医療器具として用いられる潜熱蓄熱材を用いた蓄熱性温熱器具に関する。   The present invention relates to a heat storage type thermal appliance using a latent heat storage material which is used for a thermal therapy for warming a part of a body and used as a health appliance or a medical appliance.

一般に、温熱湿布、ホットパックまたは温熱用パックとも称される蓄熱性温熱器具は、人体表面に熱を与えて血流量を増やし、痛みを和らげる効能があり、最近の研究では人体の筋力向上にも効果があると言われている。そのような蓄熱性温熱器具は、例えば病後のリハビリテーションや老人介護、さらにはスポーツの事前事後の筋肉維持にも活用できるものである。   In general, thermal storage devices, also called thermal compresses, hot packs or thermal packs, have the effect of applying heat to the human body surface to increase blood flow and relieve pain. It is said to be effective. Such a heat storage heat appliance can be used for, for example, rehabilitation after illness, elderly care, and muscle maintenance before and after sports.

このような蓄熱性温熱器具である所謂温熱用パックは、医療器具として薬事法の管轄下にあり、一般医療器具(区分1)または管理医療器具(区分n)に該当し、厚生労働省の管轄下で温熱パックの適合性について調査が行われ、かつ認証されてから、初めて市場に出荷される。そのため、温熱用パックは、厳しい品質管理と技術管理の下に製造されており、一般的な商品に比較して技術的な不具合や品質不良となるような問題の発生率は低く抑えられている。   The so-called thermal pack, which is such a thermal storage device, is under the jurisdiction of the Pharmaceutical Affairs Law as a medical device, falls under the category of general medical device (Category 1) or managed medical device (Category n), and is under the jurisdiction of the Ministry of Health, Labor and Welfare. Will be shipped to the market for the first time after being investigated and certified for the suitability of the thermal pack. For this reason, thermal packs are manufactured under strict quality control and technical control, and the incidence of problems that cause technical defects or poor quality is kept low compared to general products. .

また、温熱用パックの主な機能性を示す熱特性、温熱パック時間の医学的検証及び商品的特徴が検討され、即ち効率経済性、安全性、環境への配慮などの観点から特徴のある商品開発が期待される。
因みに、温熱用パックの熱特性として人体に接触する温度は40℃から43℃の範囲内が適正とみられている。43℃を超えると人体の皮膚に対して長時間温熱パックによる低温火傷を発症する恐れがある。発熱量としては、例えば前記温度範囲で20〜30分安定して発生し、かつ患部に充分な熱量が必要である。その他にも熱的性能として温熱パック温度の皮膚への浸透の深さが充分にあり、目的とする血流量の改善、痛みの解消、筋力の回復等ができるものであることにある。
すなわち、発生熱の安定的な持続性と人体に深く浸透する充分な発熱量が、温熱パックや温熱用パックとして有効に作用するために必要である。
In addition, thermal characteristics indicating the main functionality of the thermal pack, medical verification of the thermal pack time, and product characteristics are studied, that is, products with characteristics from the viewpoint of efficiency, economy, safety, consideration for the environment, etc. Development is expected.
Incidentally, it is considered that the temperature in contact with the human body is appropriate within the range of 40 ° C to 43 ° C as the thermal characteristics of the thermal pack. If it exceeds 43 ° C, there is a risk of developing low-temperature burns due to the long-time heat pack on the human skin. As the calorific value, for example, a stable calorific value is required in the above temperature range for 20 to 30 minutes and a sufficient amount of heat is required for the affected part. In addition, as the thermal performance, there is a sufficient depth of penetration of the hot pack temperature into the skin, which can improve the target blood flow rate, eliminate pain, recover muscle strength, and the like.
That is, a stable sustainability of generated heat and a sufficient calorific value that penetrates deeply into the human body are necessary to effectively act as a heat pack or a heat pack.

温度、熱量等を人体に伝達する手段として機能、安全性、経済性の観点から最も有効と思われる蓄熱性温熱器具を開発する必要があるが、温熱パック具の機能として発熱体のメカニズム、その温度及び熱量の特徴、温熱パックとしての医学的見地からの効果評価、温熱パック具としての取扱性、設備又は機器のコスト、更には環境影響、安全性も評価の対象になる。   It is necessary to develop a thermal storage heater that seems to be most effective from the viewpoint of function, safety, and economy as a means of transmitting temperature, heat, etc. to the human body. The characteristics of temperature and quantity of heat, evaluation of effects from a medical point of view as a heat pack, handling properties as a heat pack device, cost of equipment or equipment, as well as environmental impact and safety are also subject to evaluation.

ところで、公知の加温治療具としては、融点40〜80℃の蓄熱材を、そのまま水不透過性の密閉容器に充填し、これを通水性や通気性のある布帛からなる袋に収容したものが知られている(特許文献1)。   By the way, as a known warming treatment device, a heat storage material having a melting point of 40 to 80 ° C. is filled in a water-impermeable sealed container as it is and is stored in a bag made of a water-permeable or breathable fabric. Is known (Patent Document 1).

また、体温付近の融点を有するワックス類を容器に封入し、またはワックス類をゲル等に吸収させて粒状に細分化し、水に分散させて容器内に封入した温熱器も知られている(特許文献2)。   Also known is a heater in which a wax having a melting point near body temperature is enclosed in a container, or the wax is absorbed into a gel or the like to be subdivided into granules, dispersed in water and enclosed in the container (patent) Reference 2).

しかし、このような公知技術では、蓄熱材が液状であるか、または粉状蓄熱材の分散媒が液状のものであり、そのような蓄熱材が容器内で重力方向に偏って移動してしまうため、温熱器具が身体の姿勢に関係なく広い面積が覆われるようにすることは困難なことであった。   However, in such a known technique, the heat storage material is in a liquid state or the dispersion medium of the powder heat storage material is in a liquid state, and such a heat storage material moves in the direction of gravity in the container. Therefore, it has been difficult for the thermal appliance to cover a large area regardless of the posture of the body.

このような欠点がないように、液体化したパラフィンが流出したり散逸したりしないように、多孔質担持体に潜熱蓄熱剤が含浸され、さらにその表面を合成樹脂で覆って封入した潜熱蓄熱剤が知られている(特許文献3)。   In order not to have such drawbacks, the latent heat storage agent in which the porous carrier is impregnated with a latent heat storage agent and the surface thereof is covered with a synthetic resin so that the liquefied paraffin does not flow out or dissipate. Is known (Patent Document 3).

さらに、パウダー状の蓄熱剤の容器内での偏りを防止しつつゴム材やエラストマー材で包んだ状態に設けた温熱パック具が知られている(特許文献4)。   Furthermore, there is known a thermal pack device provided in a state of being wrapped with a rubber material or an elastomer material while preventing the powdery heat storage agent from being biased in the container (Patent Document 4).

実開昭61−057919号公報Japanese Utility Model Publication No. 61-057919 実開平02−124451号公報Japanese Utility Model Publication No. 02-124451 特開2004−75711号公報JP 2004-75711 A 実用新案登録第3125565号公報Utility Model Registration No. 3125565

しかし、パラフィン系潜熱蓄熱剤を粉粒体状に調製して小袋状の容器に気密状態に封入し、吸湿を防止して気密状態で使用される際、加熱と放熱を何度も繰り返すうちに、徐々に容器内から加熱膨張した空気が容器外に漏れ出し、減圧され大気圧で押し潰された小袋状容器内のパラフィン系潜熱蓄熱剤は圧縮されて固形状化し、このような状態では、温熱器具の柔軟性が失われ、身体の患部に沿わせるためのフィット性がなくなるという問題点がある。   However, when the paraffin-based latent heat storage agent is prepared in a granular form and sealed in a pouch-like container in an airtight state to prevent moisture absorption and used in an airtight state, heating and heat dissipation are repeated many times. The air that has been heated and expanded gradually from the inside of the container leaks out of the container, and the paraffinic latent heat storage agent in the sachet container that has been decompressed and crushed at atmospheric pressure is compressed and solidified. There is a problem in that the flexibility of the heating device is lost, and the fit to fit the affected part of the body is lost.

そこで、この発明の課題は、上記した問題点を解決してパラフィン系潜熱蓄熱剤を粉粒体状に調製して袋状容器に気密状態に封入した蓄熱性温熱器具において、固形で粉粒体状のパラフィン系潜熱蓄熱剤が、常に流動性を維持し、温熱器具全体に充分な柔軟性を確保して、身体の患部に対してフィット性に優れた蓄熱性温熱器具にすることである。   Accordingly, an object of the present invention is to solve the above-described problems, in a heat storage thermal appliance in which a paraffin-based latent heat storage agent is prepared in a powder form and sealed in a bag-like container in a hermetic state. The paraffin-based latent heat storage agent is to maintain fluidity at all times, ensure sufficient flexibility for the entire thermal apparatus, and make a thermal storage thermal apparatus excellent in fit to the affected part of the body.

また、このように得られたフィット性により、人体に接触する面積が充分に確保できるようにし、患部に充分な熱量を与えることができてパラフィン系潜熱蓄熱剤の特性が充分に及ぶようにし、それによって所要の温度と熱量を安定的に供給して保温機能に優れた蓄熱性温熱器具にすることである。   In addition, the fit obtained in this way allows sufficient area to be in contact with the human body, sufficient heat can be given to the affected area, and the characteristics of the paraffin-based latent heat storage agent are sufficiently extended. Thus, the required temperature and amount of heat are stably supplied to make a heat storage type thermal appliance having an excellent heat retaining function.

上記の課題を解決するために、この発明においては、パラフィン系潜熱蓄熱剤を粉粒体状に調製して袋状容器に封入した温熱器具からなり、前記袋状容器が、1枚以上のシート素材(シート状素材を含めていう。以下同じ。)で内壁面が形成された内装容器と、この内装容器に密接せず空気層を介して外装された外装容器とを備えたものであり、前記シート素材は粉粒体状潜熱蓄熱材および水に対する不透過性を有すると共に空気透過性を有するシート素材である蓄熱性温熱器具としたのである。   In order to solve the above-described problems, in the present invention, a paraffin-based latent heat storage agent is prepared in the form of a granular material and is composed of a heating device sealed in a bag-like container, and the bag-like container is one or more sheets. An interior container having an inner wall surface formed of a material (including a sheet-like material; the same shall apply hereinafter) and an exterior container that is externally contacted through an air layer without being in close contact with the interior container, The sheet material is a granular latent heat storage material and a heat storage device that is impervious to water and a sheet material having air permeability.

上記したように構成されるこの発明の蓄熱性温熱器具は、内装容器が粉粒体状のパラフィン系潜熱蓄熱剤を保持する際、内装容器の内壁面を構成するシート素材によって容器外の水から隔絶されたパラフィン系潜熱蓄熱剤が、常に乾燥した状態に保たれ流動性は水分によって阻害されない。また、加熱と放熱が繰り返されても内装容器内の空気は容器外に通じているので、内装容器の内外の気圧は等圧に維持されており、容器内外の圧力差によってパラフィン系潜熱蓄熱剤が押し固められることなく流動性は阻害されない。   When the interior container holds the granular paraffin-based latent heat storage agent, the heat storage heat appliance of the present invention configured as described above is made from the water outside the container by the sheet material constituting the inner wall surface of the interior container. The isolated paraffinic latent heat storage agent is always kept dry, and the fluidity is not hindered by moisture. Also, even if heating and heat dissipation are repeated, the air inside the inner container communicates with the outside of the container, so that the atmospheric pressure inside and outside the inner container is maintained at an equal pressure, and the paraffin-based latent heat storage agent due to the pressure difference between the inside and outside of the container The fluidity is not hindered without being compacted.

外装容器は、このような内装容器の外側が常に空気に曝されるようにしており、内装容器の空気透過性を促進して、前記のシート素材の機能を妨げない。外装容器は、使用状態において完全に気密性が保たれる密封が可能である素材を採用するならば、空気透過性でなくてもよく、製造コストなどを考慮して実用的には空気透過性を有する素材で形成される。積極的に空気透過性を確保するために、適当な大きさで通気孔を形成しても良い。
このような外装容器は、上記した内装容器の機能を補完するために、粉粒体状潜熱蓄熱材および水に対する不透過性を有する素材を用いて形成されることは好ましい。
The exterior container is such that the outside of such an interior container is always exposed to the air, and the air permeability of the interior container is promoted and the function of the sheet material is not hindered. The outer container need not be air permeable as long as it is made of a material that can be hermetically sealed so that it is completely airtight in use, and practically air permeable in consideration of manufacturing costs. It is formed with the material which has. In order to positively ensure air permeability, the air holes may be formed in an appropriate size.
Such an external container is preferably formed using a granular latent heat storage material and a material that is impermeable to water in order to complement the function of the above-described internal container.

また、上記のフィット性を充分に確保すると共にクッション性を向上させるために、外装容器が、エラストマーで成形された弾力性のある外装容器であることが好ましい。
このように内装容器内で自在に流動して柔らかな感触のパラフィン系潜熱蓄熱剤が、空気層を介してさらに弾性変形可能な外装容器に保持されていることにより、皮膚などから受ける圧力に応じて充分に弾性変形できるクッション性を発揮できるものになり、いわゆる「肌当たり」や触感のよい蓄熱性温熱器具になる。
このようにして、温熱器具の全体に柔軟性が確保され、患部の形状に応じて変形して熱伝導面積をできるだけ多くできるフィット性およびクッション性に優れた蓄熱性温熱器具になる。
Further, in order to sufficiently secure the above fit and improve the cushioning property, it is preferable that the outer container is a resilient outer container formed of an elastomer.
In this way, the paraffinic latent heat storage agent that flows freely in the interior container and has a soft feel is held in the outer container that can be further elastically deformed through the air layer, so that it responds to the pressure received from the skin and the like. It is possible to exhibit a cushioning property that can be sufficiently elastically deformed, and it becomes a so-called “skin contact” and a heat storage thermal appliance having a good tactile sensation.
In this way, flexibility is ensured for the entire heating device, and the heat storage device can be deformed according to the shape of the affected part and can have as much heat conduction area as possible and has excellent fit and cushioning properties.

融解潜熱が大きくて、より多くの熱量を安定供給できる蓄熱性温熱器具にするために、粉粒体状潜熱蓄熱材が、パラフィン系潜熱蓄熱剤を多孔質担持体に含浸した粉粒体状潜熱蓄熱材またはパラフィン系潜熱蓄熱剤をマイクロカプセル化した粉粒体状潜熱蓄熱材であることが好ましい。   In order to make a thermal storage device that has a large latent heat of fusion and can stably supply more heat, the granular latent heat storage material is impregnated with a paraffinic latent heat storage agent in a porous carrier. A granular latent heat storage material in which a heat storage material or a paraffin-based latent heat storage agent is encapsulated is preferable.

さらに、内装容器のシート素材の機能として、所要の空気透過性を維持すると共に粉粒体状潜熱蓄熱材および水に対する不透過性の機能をより高めるために、シート素材が、合成樹脂シート、金属箔または金属蒸着合成樹脂シートを利用したものであることが好ましい。   Furthermore, as a function of the sheet material of the interior container, in order to maintain the required air permeability and further improve the function of impermeability to the granular latent heat storage material and water, the sheet material is made of a synthetic resin sheet, a metal It is preferable to use a foil or a metal-deposited synthetic resin sheet.

蓄熱性温熱器具に設定される好ましい体感温度としては40〜43℃であり、このような温度に安定して調整するために、断熱性を有する外装容器を設けることと、パラフィン系潜熱蓄熱剤が、炭素数28〜32の飽和炭化水素からなる発熱温度60〜70℃のパラフィン系潜熱蓄熱剤であることが好ましい。炭素数28未満の飽和炭化水素では、液相と固相の相変化が60℃未満であり、すなわち潜熱による発熱温度が60℃未満になるので好ましくなく、炭素数が32を超える飽和炭化水素では、液相と固相の相変化が70℃を超え、すなわち潜熱による発熱温度が70℃超になるので好ましくない。   As a preferable sensation temperature set in the heat storage thermal appliance, it is 40 to 43 ° C. In order to stably adjust to such a temperature, providing a heat-insulating outer container, and a paraffin-based latent heat storage agent is used. It is preferably a paraffin-based latent heat storage agent having an exothermic temperature of 60 to 70 ° C. composed of a saturated hydrocarbon having 28 to 32 carbon atoms. In saturated hydrocarbons having less than 28 carbon atoms, the phase change between the liquid phase and the solid phase is less than 60 ° C., that is, not preferable because the exothermic temperature due to latent heat is less than 60 ° C., and in saturated hydrocarbons having more than 32 carbon atoms, The phase change between the liquid phase and the solid phase exceeds 70 ° C., that is, the exothermic temperature due to latent heat exceeds 70 ° C., which is not preferable.

この発明は、パラフィン系潜熱蓄熱剤を粉粒体状に調製して袋状容器に封入した温熱器具を内装容器と外装容器とで構成し、その内装容器のシート素材を粉粒体状潜熱蓄熱材および水に対する不透過性を有すると共に空気透過性を有するもので構成したので、固形で粉粒体状のパラフィン系潜熱蓄熱剤が、常に流動性を維持し、温熱器具全体に充分な柔軟性を確保して、身体の患部に対してフィット性やクッション性に優れた蓄熱性温熱器具となる利点がある。   The present invention comprises a heating apparatus in which a paraffin-based latent heat storage agent is prepared in a granular form and enclosed in a bag-like container, which is composed of an inner container and an outer container, and the sheet material of the inner container is used as a granular latent heat storage Because it is made of material and water impervious as well as air permeable, the solid and granular paraffin-based latent heat storage agent always maintains fluidity and is flexible enough for the entire heating device Is ensured, and there is an advantage that it becomes a heat storage heat appliance excellent in fit and cushioning properties against the affected part of the body.

また、このように得られたフィット性により、人体に接触する面積が充分に確保できるようになり、患部に充分な熱量を与えることができてパラフィン系潜熱蓄熱剤の特性が充分に及ぶようになり、それによって所要の温度と熱量を安定的に供給して保温機能に優れた蓄熱性温熱器具になる利点がある。   In addition, the fit obtained in this way makes it possible to secure a sufficient area in contact with the human body so that sufficient heat can be given to the affected area and the characteristics of the paraffin-based latent heat storage agent are sufficiently extended. Accordingly, there is an advantage that a required temperature and heat amount are stably supplied and a heat storage heat appliance having an excellent heat retaining function is obtained.

以下に、蓄熱性温熱器具の実施形態を添付図面に基づいて説明する。
図1および図2に示すように、第1の実施形態は、粉粒体状に調製したパラフィン系潜熱蓄熱剤1を袋状容器2に封入した温熱器具であり、袋状容器2は、粉粒体状潜熱蓄熱材および水に対する不透過性を有すると共に空気透過性を有するシート素材で壁面が形成された内装容器3と、この内装容器3に密接せずに空気層4を介して外装されたゴム製(厚さ約2mm)の略長方形状の成形体からなる第1の外装容器5とを備えたものであり、さらに第1の外装容器5を4個並べて折り曲げ可能であるように、布製外装ホルダ型の第2の外装容器6に収納した蓄熱性温熱器具である。
Below, embodiment of a thermal storage thermal appliance is described based on an accompanying drawing.
As shown in FIG. 1 and FIG. 2, the first embodiment is a thermal appliance in which a paraffin-based latent heat storage agent 1 prepared in a powder form is enclosed in a bag-like container 2. An interior container 3 in which a wall surface is formed of a granular raw heat storage material and a water-impermeable sheet material that is impervious to water, and is packaged through an air layer 4 without being in close contact with the interior container 3 And a first outer container 5 made of a substantially rectangular shaped body made of rubber (thickness of about 2 mm), and further, four first outer containers 5 can be arranged side by side and bent. It is a heat storage thermal appliance housed in a cloth exterior holder type second exterior container 6.

内装容器3は、1枚以上のシート素材で内壁面が形成されたものを用い、熱媒体である粉粒体状のパラフィン系潜熱蓄熱剤1を直接に充填する。内装容器3の壁面には、少なくとも二重のシート素材を用いて漏洩を防止し、かつ防水性を確実にすることが好ましい。   The inner container 3 is made of one or more sheet materials having an inner wall surface, and is directly filled with the granular paraffin-based latent heat storage agent 1 as a heat medium. It is preferable to use at least a double sheet material on the wall surface of the interior container 3 to prevent leakage and to ensure waterproofness.

シート素材に所要の特性は、粉粒体状潜熱蓄熱材および水に対する不透過性を有すると共に空気透過性を有することである。また堅牢性及びシール性が良い特性のものを採用することが好ましい。
防水性(疎水性)のあるフィルムなどのシート素材例としては、ナイロンシート、アルミシート、アルミ蒸着シート、塩化ビニールシート等が選択される。
The required properties of the sheet material are that it has air permeability as well as impermeability to the granular latent heat storage material and water. Moreover, it is preferable to employ a material having good fastness and sealing properties.
As an example of a sheet material such as a waterproof (hydrophobic) film, a nylon sheet, an aluminum sheet, an aluminum deposited sheet, a vinyl chloride sheet, and the like are selected.

前述のように、内装容器内の空気が減少するとパウダーやビーズの流動性が低下し、固化する傾向がみられるため、それを防止するために、内装容器の空気透過性が必要であり、例えば内装容器に、粉粒体状潜熱蓄熱材や水を透過させない微小な小孔(例えば0.1〜10μm)を物理化学的に周知な手段によって穿ち、容器内外のガス通過性を向上させる。   As described above, when the air in the interior container decreases, the fluidity of the powder and beads decreases, and there is a tendency to solidify.To prevent this, the air permeability of the interior container is necessary, for example, A minute small hole (for example, 0.1 to 10 μm) that does not allow permeation of the granular latent heat storage material or water is formed in the interior container by a well-known physicochemical method to improve gas permeability inside and outside the container.

前記の疎水性のシート素材に空気透過性(通気性とも称される。)を持たせるには、例えば、疎水性シートに、BaSO、CaCOなどのフィラーと異種ポリマーとの混合による相分離層を形成したり、後工程で抽出可能な成分を予めシート素材にミクロ分散させておき、シート成形後にその成分を抽出して孔を形成したり、または発泡剤により微細な連続発泡構造を形成するなどの手段によってミクロポーラスな構造を持たせることにより形成できる。 In order to give the hydrophobic sheet material air permeability (also referred to as air permeability), for example, phase separation by mixing a hydrophobic sheet with a filler such as BaSO 4 and CaCO 3 and a different polymer. Layers are formed, components that can be extracted in the subsequent process are microdispersed in advance in the sheet material, and the components are extracted after forming the sheet to form pores, or a fine continuous foam structure is formed using a foaming agent It can be formed by giving a microporous structure by means such as.

具体例としては、孔径が0.1μm〜10μmの多数の不規則形状の微細孔が形成されたポリテトラフルオロエチレン樹脂製やウレタン樹脂製などの多孔質膜が挙げられる。また、セルロースなどの疎水性不織布の表面に撥水処理を施すことによっても水に対する不透過性を有すると共に空気透過性を有するシートを作製することができる。また、耐水性フィルムと通気性フィルムをラミネートしてもよい。
撥水性および空気透過性のあるシートの市販品としては、ポリプロピレンフィルムその他のポリオレフィンフィルムを3層積層した出光ユニテック社製のユニラックスRSが挙げられる。
Specific examples include porous films made of polytetrafluoroethylene resin or urethane resin in which a large number of irregularly shaped micropores having a pore diameter of 0.1 μm to 10 μm are formed. In addition, a sheet having water impermeability and air permeability can also be produced by subjecting the surface of a hydrophobic nonwoven fabric such as cellulose to water repellent treatment. Further, a water resistant film and a breathable film may be laminated.
As a commercial product of a sheet having water repellency and air permeability, Unilux RS manufactured by Idemitsu Unitech Co., Ltd. in which three layers of polypropylene film and other polyolefin films are laminated.

このようにシート素材は、1枚で内装容器を形成することもできるが、その特性を阻害しないように2枚以上の素材が積層または単に多重包装されたものであってもよく、積層構造または多重包装によって補強されたものとすることができる。
例えば前記の出光ユニテック社製のユニラックスRSフィルムをポリプロピレンスパンボンド製織布にラミネートした素材の市販品としては、出光ユニテック社製のストラマイティMF(通気度11.0ml/cm・秒(KES法))が挙げられる。
In this way, the sheet material can form an interior container with one sheet, but two or more sheets may be laminated or simply multiple-packed so as not to impede its properties. It can be reinforced by multiple packaging.
For example, as a commercial product of a material obtained by laminating the above-mentioned Unilux RS film manufactured by Idemitsu Unitech Co., Ltd. on a woven fabric made of polypropylene spunbond, STRAMITY MF manufactured by Idemitsu Unitech Co., Ltd. (air permeability 11.0 ml / cm 2 · second (KES Law)).

この発明に用いる外装容器5、6は、上記した内装容器に密接せず空気層を介して外装されたものであればよく、特にその素材や形状は限定せずに設けることができる。前述した内装容器の素材を一部または全体に利用した空気透過性の外装容器であってもよい。   The outer containers 5 and 6 used in the present invention may be provided without being in close contact with the above-described inner container and covered with an air layer, and the materials and shapes thereof are not particularly limited. It may be an air permeable exterior container using part or all of the material of the interior container described above.

この発明に用いるパラフィン系潜熱蓄熱剤は、粉粒体状に調製されたものを用いる。一般には飽和炭化水素の炭素数は広範囲に存在するが、この発明では炭素数19以上の飽和炭化水素を用いる。特に温熱パック温度は40〜43℃が適温と考えられるため、熱媒体をパックする容器素材の構成による熱伝導を勘案して60〜70℃に相変化する飽和炭化水素を用いる。60〜70℃に相当する炭素数は28〜32である。   As the paraffin-based latent heat storage agent used in the present invention, one prepared in a granular form is used. In general, saturated hydrocarbons have a wide range of carbon numbers. In the present invention, saturated hydrocarbons having 19 or more carbon atoms are used. In particular, since the temperature of the hot pack is considered to be 40 to 43 ° C., a saturated hydrocarbon whose phase changes to 60 to 70 ° C. is used in consideration of heat conduction due to the configuration of the container material for packing the heat medium. The number of carbons corresponding to 60 to 70 ° C. is 28 to 32.

熱媒体に相変化する化合物を用いることは物質の比熱による蓄熱のみではなく、固体から液体へ相変化する場合に消費される潜熱の蓄熱性を付加することにより、数十倍の熱量を蓄熱し、液体から固体へ変化する際に発生する蓄熱熱量を利用することが可能となる。
温熱パックには多量の熱量を長時間必要とするが、比熱量では効率が低く、潜熱量を加えることにより温熱パックに対応する熱量を確保することが可能となる。従来の蓄熱性温熱器具は、一般的に40〜45℃で15〜30分、皮膚面を加熱することが条件となっていたが、潜熱を付加した熱媒体に蓄熱される熱量を用いることにより、極めてコンパクトな容量の蓄熱性温熱器具とすることができる。
The use of a compound that changes phase in the heat medium not only stores heat by the specific heat of the substance, but also adds heat storage of latent heat that is consumed when the phase changes from solid to liquid, thereby storing several tens of times the amount of heat. It is possible to use the amount of heat stored when the liquid changes to a solid.
Although the heat pack requires a large amount of heat for a long time, the efficiency is low with the specific heat amount, and it becomes possible to secure the heat amount corresponding to the heat pack by adding the latent heat amount. Conventional heat-storing heat appliances are generally required to heat the skin surface at 40 to 45 ° C. for 15 to 30 minutes, but by using the amount of heat stored in the heat medium to which latent heat is added. It is possible to provide a heat storage device having an extremely compact capacity.

パラフィン系潜熱蓄熱剤が有するもう1つの特徴は、相変化が進行している間は所定の温度は変化しないと言うことである。この現象は潜熱の特徴であり、比熱の熱量と温度の相関とは異なる。例えば70℃で固体から液体へ変化する場合、加温により全ての蓄熱剤が液体になるまで70℃の温度は維持される。逆に70℃に加温された蓄熱剤を液体から固体へ変化させる場合は、蓄熱剤全部が固体になるまで70℃は維持される。70℃で相変化する蓄熱剤を用いれば、70℃の温度維持は長時間保持されることになる。この発明では60〜70℃で相変化する飽和炭化水素を主に用いて温熱パック用の熱媒体とすることが好ましいが、例えば、通常より低温や高温で行なう特殊な場合もあることを勘案すると、30〜80℃の範囲で相変化する飽和炭化水素を用いることもできる。   Another characteristic of the paraffinic latent heat storage agent is that the predetermined temperature does not change while the phase change is in progress. This phenomenon is a characteristic of latent heat, and the correlation between the heat quantity of specific heat and temperature is different. For example, when changing from solid to liquid at 70 ° C., the temperature of 70 ° C. is maintained until all the heat storage agent becomes liquid by heating. Conversely, when the heat storage agent heated to 70 ° C. is changed from liquid to solid, 70 ° C. is maintained until all of the heat storage agent becomes solid. If a heat storage agent that changes phase at 70 ° C. is used, the temperature maintenance at 70 ° C. is maintained for a long time. In the present invention, it is preferable to use mainly saturated hydrocarbons that change phase at 60 to 70 ° C. to make a heat medium for a heat pack, but for example, taking into consideration that there are special cases where the heat medium is performed at a lower or higher temperature than usual Saturated hydrocarbons that change phase in the range of 30 to 80 ° C can also be used.

このようなパラフィン系潜熱蓄熱剤に対して、相変化しても物質の状態に影響を与えないように粉粒体状に調製する加工を行なう。以下の3つのパターンが例示できる。
先ず第1例の加工は、多孔質無機化合物に該飽和炭化水素を包含させ、浸み出しを防ぐために樹脂コーテイングして、パウダー状にする加工である。
第2例の加工としては、熱媒体である飽和炭化水素を芯にして外殻をセルロースとしてビーズ化する加工法である。
第3例の加工としては、熱媒体である飽和炭化水素をアクリル樹脂によりマイクロカプセル化してパウダーとする加工である。
Such a paraffin-based latent heat storage agent is processed to be prepared in a powder form so as not to affect the state of the substance even if the phase changes. The following three patterns can be exemplified.
First, the process of the first example is a process in which the saturated hydrocarbon is included in a porous inorganic compound, and resin coating is performed to prevent leaching and powdering is performed.
The processing of the second example is a processing method in which a saturated hydrocarbon as a heat medium is used as a core, and the outer shell is beaded as cellulose.
The processing of the third example is processing in which a saturated hydrocarbon as a heat medium is microencapsulated with an acrylic resin to form a powder.

これらの加工により、得られるパウダー及びビーズは、内蔵されている相変化性飽和炭化水素の温度による形態即ち相変化による影響は極めて少なくなり、それぞれの状態を温度の変化に関係なく安定して保つことができる。これらのパウダー及びビーズを温熱用パックの熱媒体として用いることができ、パウダー粒径は30〜70μmが好ましく、ビーズ径は2.5〜4.0mmであるものが、飽和炭化水素の保持効率と流動性を適切に行なわせる観点から好ましいものである。   By these processes, the resulting powder and beads are extremely less affected by the temperature of the built-in phase change saturated hydrocarbons, that is, the phase change, and each state is stably maintained regardless of the temperature change. be able to. These powders and beads can be used as a heating medium for the heat pack, and the powder particle size is preferably 30 to 70 μm, and the bead diameter is 2.5 to 4.0 mm. This is preferable from the viewpoint of appropriately achieving fluidity.

例えば、パラフィン系潜熱蓄熱剤の形態として、粒度50〜100μmの多孔質酸化ケイ素(多孔質シリカとも称される。)に含浸して粉体化するか、または粒径5μm前後のビーズまたは1〜50μmのマイクロカプセル化したものを用いる。
その場合の形態として重要なファクターは、飽和炭化水素成分の純度であり、純度が50%以上であることが所要の熱効率を得るために適当である。好ましくは70%以上あれば温熱効果が安定して好ましい。純度100%の飽和炭化水素成分が最良である。
For example, as a form of the paraffin-based latent heat storage agent, a porous silicon oxide having a particle size of 50 to 100 μm (also referred to as porous silica) is impregnated and powdered, or beads having a particle size of about 5 μm or 1 to 50 μm microencapsulated one is used.
An important factor as a form in that case is the purity of the saturated hydrocarbon component, and a purity of 50% or more is appropriate for obtaining the required thermal efficiency. Preferably, if it is 70% or more, the thermal effect is stable and preferable. A 100% pure saturated hydrocarbon component is the best.

次に、パラフィン系潜熱蓄熱剤の使用量と発熱量が比例するので、温熱器具のサイズに応じて必要量を決定する。例えば所定のサイズ及び容量の一例として、縦横高さの寸法が37cm×29cm×3cmであり、容積が3219mlの温熱器具ならば、1000gの粉粒体状のパラフィン系潜熱蓄熱剤を充填することは適当である。   Next, since the usage amount of the paraffin-based latent heat storage agent and the calorific value are proportional, the required amount is determined according to the size of the thermal appliance. For example, as an example of a predetermined size and capacity, if a thermal appliance having a vertical and horizontal height dimension of 37 cm × 29 cm × 3 cm and a volume of 3219 ml is filled with 1000 g of granular paraffinic latent heat storage agent, Is appropriate.

このように蓄熱材を充填した後、充填された蓄熱材の伝熱量をコントロールするために袋状容器を二重または三重に包装して各空間に適当な厚さの空気層を作り、温熱器具の表面温度を40〜45℃に体感温度を設定する。   After filling the heat storage material in this way, in order to control the heat transfer amount of the filled heat storage material, the bag-like container is wrapped in double or triple to create an air layer of appropriate thickness in each space, The body temperature is set to 40 to 45 ° C.

図1、2にも示すように、第1実施形態の蓄熱性温熱器具は、並べて折り曲げ可能であるように、布製の第2の外装容器6に第1の外装容器5を複数個並べて保持させた蓄熱性温熱器具とすることが好ましい。このように構成すると、発生する熱量を調整し、また効率的に利用することができ、さらには蓄熱性温熱器具に人体へのフィット性を向上させることができる。   As shown in FIGS. 1 and 2, the thermal storage heater according to the first embodiment holds a plurality of first exterior containers 5 side by side in a cloth-made second exterior container 6 so that they can be folded side by side. It is preferable to use a thermal storage device. If comprised in this way, the calorie | heat amount to generate | occur | produce can be adjusted and it can utilize efficiently, Furthermore, the fit property to a human body can be improved to a thermal storage thermal appliance.

第1の外装容器用の素材としては、天然ゴム、合成ゴム、熱可塑性エラストマーなどのエラストマーを成型したものが挙げられ、第2の外装容器6の素材としては、テント地又はカバン地のように厚手の織物またはアラミド繊維織物等のように耐熱性や高強力性の織物により縫製された容器用素材が好ましいものとして挙げられる。前記織物としては、防・撥水加工したものが、容器内側を常に乾燥状態に保っておく素材であることで好ましいものである。   Examples of the material for the first exterior container include those obtained by molding an elastomer such as natural rubber, synthetic rubber, and thermoplastic elastomer. Examples of the material for the second exterior container 6 include a tent place or a bag place. A container material sewn with a heat-resistant or high-strength fabric such as a thick fabric or an aramid fiber fabric is preferable. As the woven fabric, a fabric that has been water-repellent and water-repellent is preferable because it is a material that always keeps the inside of the container in a dry state.

上記のように構成された第1実施形態の蓄熱性温熱器具は、内装容器3が粉粒体状のパラフィン系潜熱蓄熱剤を保持する際、内装容器3の内壁面を構成するシート素材によって容器外の水から隔絶されたパラフィン系潜熱蓄熱剤が、常に乾燥した状態に保たれ、その流動性は水分によって阻害されない。また、加熱と放熱が繰り返されても内装容器3内の空気は容器外に通じているので、内装容器3の内外の気圧は等圧に維持されており、圧力差によってパラフィン系潜熱蓄熱剤が押し固められることがなく、その流動性は常に阻害されない。そのため、患部の形状に応じて変形して熱伝導面積をできるだけ多くできるフィット性に優れた蓄熱性温熱器具になる。
このような実施形態を使用するには、特に限定されないが、乾式で雰囲気を介して熱量を伝導して加熱するもので適当であり、例えば電熱による熱風加熱式の加温器を用い、通常3〜4時間程度、必要な熱量だけ加熱して用いる。加熱温度は、パラフィン系潜熱蓄熱剤の融点以上の温度であればよく、必要に応じて30〜90℃程度にセットする。
The heat storage thermal appliance of the first embodiment configured as described above is a container made of a sheet material that forms the inner wall surface of the interior container 3 when the interior container 3 holds the granular paraffinic latent heat storage agent. The paraffinic latent heat storage agent isolated from the outside water is always kept dry, and its fluidity is not inhibited by moisture. Moreover, even if heating and heat dissipation are repeated, the air in the interior container 3 is communicated to the outside of the container, so that the pressure inside and outside the interior container 3 is maintained at an equal pressure, and the paraffin-based latent heat storage agent is caused by the pressure difference. It is not compacted and its fluidity is not always disturbed. Therefore, it becomes a heat storage type thermal appliance excellent in fitting property that can be deformed according to the shape of the affected part to increase the heat conduction area as much as possible.
Although there is no particular limitation to use such an embodiment, it is appropriate to dry and heat by conducting heat through an atmosphere. For example, a hot air heating type heater using electric heat is usually used. About 4 hours, use only the necessary amount of heat. The heating temperature should just be the temperature more than melting | fusing point of a paraffin type latent heat storage agent, and is set to about 30-90 degreeC as needed.

因みに、温熱療法は、熱媒体の温度とその熱媒体の量が決め手であり、容器素材によって温度及び量は決められる。即ちゴム等の成型品と厚地の織物では熱媒体の温度は異なり、その素材の熱伝導の比較により決められる。容器中の空気の含量によるが、織物パックの方が熱媒体の温度を比較的よく下げる方向にある。外装容器は、堅牢な素材を用いて繰返し使用に耐える物性をもたねばならない。人体にフィットする性能を要求される。フィット性は、素材の性質と共に外装容器の形態および柔軟な弾性が要求される。   Incidentally, in the thermotherapy, the temperature of the heat medium and the amount of the heat medium are the decisive factors, and the temperature and amount are determined by the container material. That is, the temperature of the heat medium differs between a molded product such as rubber and a thick fabric, and is determined by comparing the heat conduction of the material. Depending on the air content in the container, the fabric pack tends to lower the temperature of the heat medium relatively well. The outer container must have physical properties that can withstand repeated use using a robust material. Performance that fits the human body is required. For the fit, the shape of the outer container and flexible elasticity are required along with the properties of the material.

次に、図3、4に示す第2実施形態は、第1実施形態の内装容器3に代えて、出光ユニテック社製のユニラックスRSフィルム7aをポリプロピレンスパンボンド製織布7bにラミネートした素材の市販品である出光ユニテック社製のストラマイティMF(通気度11.0ml/cm・秒(KES法))からなる内装容器7を用いたものである。 Next, in the second embodiment shown in FIGS. 3 and 4, instead of the interior container 3 of the first embodiment, a material obtained by laminating a Unilux RS film 7a made by Idemitsu Unitech Co., Ltd. on a woven cloth 7b made of polypropylene spunbond. An internal container 7 made of Idemitsu Unitech's stramity MF (air permeability 11.0 ml / cm 2 · second (KES method)), which is a commercial product, is used.

そして、第2実施形態では、上記の内装容器7が補強された剛性の高いものを用いているため、外装の構成を簡略化して布製の外装容器8に内装容器7を直接に複数個収納した蓄熱性温熱器具としている。
このようにすれば、構成が簡単で第1実施形態と同様の性能を有するものを製造することができる。
In the second embodiment, since the above-described interior container 7 is reinforced and has a high rigidity, the configuration of the exterior is simplified and a plurality of interior containers 7 are directly stored in the cloth exterior container 8. It is a thermal storage device.
In this way, it is possible to manufacture a product having a simple configuration and the same performance as that of the first embodiment.

第1実施形態および第2実施形態では、外装容器6、8は、4〜8個の外装容器5または内装容器7を保持できる布製のホルダ型のものを示したが、図5に示すように、外装容器9、10、11は、それぞれ首、肩、膝に対応する立体型の形態に形成されることも好ましいことである。
また、外装容器の形態ばかりではなく、全体に適正な弾性を付与する必要がある場合には、外装容器の中に存在する空気量を調整すればよい。適正な空気量は外装容器に数箇所の小孔を形成することにより可能である。なお、人体の肩、腰、膝、首、腕に対するフィット性は堅牢性と相反するので、容器の素材選択は重要である。
In the first embodiment and the second embodiment, the outer containers 6 and 8 are of a cloth-type holder that can hold the four to eight outer containers 5 or the inner containers 7, but as shown in FIG. The outer containers 9, 10, and 11 are preferably formed in a three-dimensional shape corresponding to the neck, shoulder, and knee, respectively.
In addition, when it is necessary to give appropriate elasticity not only to the form of the outer container but also to the whole, the amount of air present in the outer container may be adjusted. An appropriate amount of air can be obtained by forming several small holes in the outer container. It should be noted that the material selection for the container is important because the fit to the shoulder, waist, knees, neck and arms of the human body conflicts with the robustness.

第1実施形態と同じ形態の蓄熱性温熱器具であり、粉粒体状潜熱蓄熱材として、相変化物質で融点70℃のn−パラフィンを主成分とする蓄熱材を多孔質酸化ケイ素に60%含浸したパウダー(山一社製:ノポス)を用いた。
内装容器は、それぞれ0.2μm程度の孔を形成したナイロンフィルム製袋とポリエチレンフィルム製袋で二重にしてゴム製パックからなる第1の外装容器に充填した。これをナイロン製織物パックに4個保持させ、蓄熱性温熱器具とした。
得られた製品の蓄熱性温熱器具のサイズ及び容量は、縦横高さの寸法が37cm×29cm×3cmであり、容積が3219mlで、800gの粉粒体状のパラフィン系潜熱蓄熱剤が充填されていて総重量1500gであった。
It is a heat storage thermal appliance of the same form as the first embodiment, and as a granular latent heat storage material, a phase change material and a heat storage material mainly composed of n-paraffin having a melting point of 70 ° C. is made of 60% porous silicon oxide. An impregnated powder (manufactured by Yamaichi Co., Ltd .: Nopos) was used.
The inner container was filled with a first outer container made of a rubber pack by duplicating a nylon film bag and a polyethylene film bag each having a hole of about 0.2 μm. Four of these were held in a nylon fabric pack to make a heat storage thermal appliance.
The size and capacity of the heat-storing thermal appliance of the product obtained are 37 cm x 29 cm x 3 cm in height and width, and the volume is 3219 ml, filled with 800 g of granular paraffinic latent heat storage agent. The total weight was 1500 g.

第1実施形態と同じ形態の蓄熱性温熱器具であり、粉粒体状潜熱蓄熱材として、相変化物質で融点70℃のn−パラフィンを主成分とする蓄熱材を多孔質酸化ケイ素に60%含浸したパウダー(山一社製:ノポス)を用いた。
内装容器は、それぞれ0.2μm程度の孔を形成したアルミニウムコーティングフィルム製袋とナイロンフィルム製袋で二重にしてゴム製パックからなる第1の外装容器に充填した。これをナイロン製織物パックに4個保持させ、蓄熱性温熱器具とした。
得られた製品の蓄熱性温熱器具のサイズ及び容量は、縦横高さの寸法が37cm×29cm×3cmであり、容積が3219mlで、800gの粉粒体状のパラフィン系潜熱蓄熱剤が充填されていて総重量850gであった。
It is a heat storage thermal appliance of the same form as the first embodiment, and as a granular latent heat storage material, a phase change material and a heat storage material mainly composed of n-paraffin having a melting point of 70 ° C. is made of 60% porous silicon oxide. An impregnated powder (manufactured by Yamaichi Co., Ltd .: Nopos) was used.
The inner container was filled with a first outer container made of a rubber pack by duplicating an aluminum coating film bag and a nylon film bag each having a hole of about 0.2 μm. Four of these were held in a nylon fabric pack to make a heat storage thermal appliance.
The size and capacity of the heat-storing thermal appliance of the product obtained are 37 cm x 29 cm x 3 cm in height and width, and the volume is 3219 ml, filled with 800 g of granular paraffinic latent heat storage agent. The total weight was 850 g.

第1実施形態と同じ形態の蓄熱性温熱器具であり、粉粒体状潜熱蓄熱材として、相変化物質で融点70℃のn−パラフィンを主成分とする蓄熱材をセルロースビーズに含浸した粒径5mmのビーズ形のものを用いた。
内装容器は、それぞれ0.2μm程度の孔を形成したアルミニウムコーティングフィルム製袋とナイロンフィルム製袋で二重にしてゴム製パックからなる第1の外装容器に充填した。これをナイロン製織物パックに4個保持させ、蓄熱性温熱器具とした。
得られた製品の蓄熱性温熱器具のサイズ及び容量は、縦横高さの寸法が37cm×29cm×3cmであり、容積が3219mlで、600gの粉粒体状のパラフィン系潜熱蓄熱剤が充填されていて総重量650gであった。
A heat storage device having the same form as that of the first embodiment, and a particle size obtained by impregnating cellulose beads with a heat storage material mainly composed of a phase change material and an n-paraffin having a melting point of 70 ° C. as a granular latent heat storage material A 5 mm bead shape was used.
The inner container was filled with a first outer container made of a rubber pack by duplicating an aluminum coating film bag and a nylon film bag each having a hole of about 0.2 μm. Four of these were held in a nylon fabric pack to make a heat storage thermal appliance.
The size and capacity of the heat-storing thermal appliance of the product obtained are 37 cm x 29 cm x 3 cm in height and width, the volume is 3219 ml, and 600 g of granular paraffinic latent heat storage agent is filled. The total weight was 650 g.

第2実施形態と同じ形態の蓄熱性温熱器具であり、粉粒体状潜熱蓄熱材として、相変化物質で融点70℃のn−パラフィンを主成分とする蓄熱材を多孔質酸化ケイ素に60%含浸したパウダー(山一社製:ノポス)を用いた。
内装容器は、出光ユニテック社製のユニラックスRSフィルムをポリプロピレンスパンボンド製織布にラミネートした素材の市販品である出光ユニテック社製のストラマイティMF(通気度11.0ml/cm・秒 (KES法))製の袋とし、外装容器はポリエステル製織物からなる袋とし、内装容器を4つ外装容器に保持させて蓄熱性温熱器具とした。
It is a heat storage thermal appliance of the same form as the second embodiment, and as a granular latent heat storage material, a phase change material and a heat storage material mainly composed of n-paraffin having a melting point of 70 ° C. is made of 60% porous silicon oxide. An impregnated powder (manufactured by Yamaichi Co., Ltd .: Nopos) was used.
Inner container is Idemitsu Unitech Co. of UNILAX RS film is a commercially available material which is laminated to a polypropylene spunbond woven fabric Idemitsu Unitech Co. Stra Mighty MF (air permeability 11.0 ml / cm 2 · sec (KES Method)), and the outer container was a bag made of polyester fabric, and four inner containers were held in the outer container to form a heat storage thermal appliance.

以上のようにして得られた実施例1〜4の製品について、従来一般的に使用されているシリカゲルを用いた湿式法温湿布製品との比較による効果を長崎大学医学部保健学科にて実施された実験により判定した。   About the product of Examples 1-4 obtained as mentioned above, the effect by the comparison with the wet method hot compress product using the silica gel generally used conventionally was implemented in Nagasaki University medical department health department. Judgment was made by experiment.

実施例の蓄熱性温熱器具の表面温度変化、温熱処理された皮膚温度変化、温熱処理された血流変化、連続使用能力について従来品との比較にて発明の効果を判定したところ、保温機能、皮膚温の変化、血流変化と皮膚温変化、連続使用能について、いずれもシリカゲルを用いた従来の湿式法温湿布製品に比べて優れているものとの結果が得られた。   When the effect of the invention was determined by comparison with the conventional product with respect to the surface temperature change, the heat-treated skin temperature change, the heat-treated blood flow change, and the continuous use ability of the heat storage heat appliance of the example, the heat retention function, The results showed that the skin temperature change, blood flow change and skin temperature change, and continuous use ability were all superior to conventional wet method hot compress products using silica gel.

また、熱風加熱式の加温器から取出して、そのまま使用できる簡便性であり、かつ安全なホットパックであり、また従来の乾性ホットパックと比較して保温機能に優れており、温熱効果を発揮することができるものと結論された。   In addition, it is a hot pack that is easy to use and can be used as it is after being taken out of a hot air heating type heater, and also has a better heat retention function than a conventional dry hot pack, and exhibits a thermal effect. It was concluded that it could be done.

第1実施形態の斜視図Perspective view of the first embodiment 第1実施形態の要部断面図Sectional drawing of the principal part of 1st Embodiment 第2実施形態の斜視図Perspective view of the second embodiment 第2実施形態の要部断面図Main part sectional drawing of 2nd Embodiment 他の実施形態の斜視図Perspective view of another embodiment

符号の説明Explanation of symbols

1 パラフィン系潜熱蓄熱剤
2 袋状容器
3、7 内装容器
4 空気層
5 第1の外装容器
6 第2の外装容器
7a フィルム
7b 織布
8、9、10、11 外装容器
DESCRIPTION OF SYMBOLS 1 Paraffin-type latent heat storage agent 2 Bag-shaped container 3, 7 Interior container 4 Air layer 5 First exterior container 6 Second exterior container 7a Film 7b Woven cloth 8, 9, 10, 11 Exterior container

Claims (6)

パラフィン系潜熱蓄熱剤を粉粒体状に調製して袋状容器に封入した温熱器具からなり、前記袋状容器が、1枚以上のシート素材で内壁面が形成された内装容器と、この内装容器に密接せず空気層を介して外装された外装容器とを備えたものであり、前記シート素材は粉粒体状潜熱蓄熱材および水に対する不透過性を有すると共に空気透過性を有するシート素材である蓄熱性温熱器具。   An interior container comprising a thermal apparatus in which a paraffin-based latent heat storage agent is prepared in a granular form and enclosed in a bag-like container, and the bag-like container has an inner wall formed of one or more sheet materials, and the interior A sheet material that is impervious to the granular latent heat storage material and water and has air permeability, without being in close contact with the container. Is a heat storage thermal appliance. 外装容器が、エラストマーで成形された外装容器である請求項1に記載の蓄熱性温熱器具。   The heat storage thermal apparatus according to claim 1, wherein the outer container is an outer container formed of an elastomer. 粉粒体状潜熱蓄熱材が、パラフィン系潜熱蓄熱剤を多孔質担持体に含浸した粉粒体状潜熱蓄熱材またはパラフィン系潜熱蓄熱剤をマイクロカプセル化した粉粒体状潜熱蓄熱材である請求項1に記載の蓄熱性温熱器具。   The granular latent heat storage material is a granular latent heat storage material in which a porous carrier is impregnated with a paraffin latent heat storage agent or a particulate latent heat storage material in which a paraffin latent heat storage agent is microencapsulated. Item 2. The thermal storage heater according to Item 1. シート素材が、合成樹脂シート、金属箔または金属蒸着合成樹脂シートを用いたシート素材である請求項1に記載の蓄熱性温熱器具。   The regenerative thermal apparatus according to claim 1, wherein the sheet material is a sheet material using a synthetic resin sheet, a metal foil, or a metal-deposited synthetic resin sheet. パラフィン系潜熱蓄熱剤が、炭素数28〜32の飽和炭化水素からなる発熱温度60〜70℃のパラフィン系潜熱蓄熱剤である請求項1に記載の蓄熱性温熱器具。   The regenerative thermal apparatus according to claim 1, wherein the paraffin-based latent heat storage agent is a paraffin-based latent heat storage agent having an exothermic temperature of 60 to 70 ° C composed of a saturated hydrocarbon having 28 to 32 carbon atoms. 外装容器が、体感温度を40〜43℃に調整可能な断熱性を有する外装容器である請求項5に記載の蓄熱性温熱器具。   The regenerative thermal apparatus according to claim 5, wherein the outer container is an outer container having a heat insulating property capable of adjusting a sensible temperature to 40 to 43 ° C.
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