JP2009207506A - Phthalocyanine-supporting photothermal catalyst - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for sustaining antibacterial, sterilizing, deodorizing and air cleaning effects even in a state without light by using a phthalocyanine-supporting photothermal catalyst in which titanium dioxide is made to support phthalocyanine. <P>SOLUTION: The method comprises mixing phthalocyanine and titanium dioxide, adding a substance excellent in tackiness such as an acrylic resin or egg white as a support aid further and grinding them appropriately for a fixed time in an industrial mortar, thereby forming a state that a phthalocyanine pigment is fixed to the surface of titanium dioxide to dye fiber thread as a dye, and using the phthalocyanine-supporting photothermal catalyst which demonstrates the synergistic effect by a phthalocyanine thermal catalyst and a titanium dioxide photo catalyst. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

The present invention relates to various related technologies for utilizing sterilizing the air cleaning effect using light thermal catalyst such as titanium dioxide, a deodorant maximally.

Many proposals have been made for techniques for removing harmful organic substances and odors in the air using a photocatalytic substance such as titanium dioxide and related technologies.

It is known as a method for removing harmful substances and deodorizing effects utilizing the thermal catalytic effect of phthalocyanine substances, that is, a method for removing dirt or harmful organic substances adhering to the surface of a substrate.

Phthalocyanine substances have a planar molecular structure and exhibit a strong color, but some complexes exhibit a blue to green color and are used as pigments because of their excellent durability.

Copper phthalocyanine series is called phthalocyanine blue and high chlorinated copper phthalocyanine series is called phthalocyanine green, which is known as a representative of blue to green organic pigments. Therefore, using these pigment phthalocyanine substances When applied to a fiber substrate or substrate, a blue color is generally observed.
The following documents exist regarding inventions that utilize dyes and functions of phthalocyanine substances.
JP-A-2005-153511 JP 2006-269819 A

However, when the planar molecular structure of the phthalocyanine substance is a surface distribution using a fixing agent, the phthalocyanine substance is hidden from the surface inside the fixing agent, and an effective catalytic effect cannot be exhibited.

The present invention was devised by repeatedly examining such problems in the prior art, and is a method of using phthalocyanine as a main catalyst by changing the viewpoint of the conventional photocatalyst using titanium dioxide. .

Another object of the present invention is not only to produce an effective dye by adsorbing phthalocyanine molecules on the surface of titanium dioxide, but also to sufficiently exhibit the catalytic effect of light and heat.

That is, the photothermal catalyst makes it possible to remove the harmful organic compounds and odors in the air or without day and night or light thereby effectively coupling the light heat catalytic effect of the catalytic effect of titanium dioxide and phthalocyanine We are going to propose a new method by

In particular, it relates to an optical thermal catalyst article was filling coating on woven and nonwoven fabrics made of fibrous, also, window glass, guard rail, wall, roof, appliances wall, paper, ink, light thermal catalyst to the substrate surface such as black The present invention relates to a method for simply applying an article.

Further, the catalyst to remove only beyond, harmful organic compounds even where there is no light or odor dirt and harmful organic substances adhering on a substrate to decompose and remove by exciting light heat catalyst composition by light in the ultraviolet The present invention relates to a method for forming a photothermal catalyst layer that has both effects and can effectively remove harmful substances and odor factors synergistically by the circulation cycle.

When a white turbid powder of titanium dioxide is added to phthalocyanine and mixed with a solvent, an appropriate white color and a transparent blue color can be emitted depending on the application. Thereby, the composition can be adjusted or the color can be changed, and it can be applied as a shirt, suit, or underwear on the wall or the outer wall.

The present invention is a technique in the field of providing industrially a phthalocyanine-supported photothermal catalyst material by mixing such a phthalocyanine material and titanium dioxide.

(1) Titanium dioxide, which is a photocatalytic reaction material, carries out a catalytic reaction not only with visible light but also with infrared rays with a level of heat that reacts with an infrared camera, and further supports phthalocyanine that undergoes a catalytic reaction even without light. By using phthalocyanine-supported photothermal catalyst mainly composed of phthalocyanine, the photocatalytic effect of titanium dioxide has a method that can maintain antibacterial, sterilization, deodorization, and air cleaning effects even in the absence of light. The removal of harmful substances, antibacterial and deodorizing methods with a phthalocyanine-supported photothermal catalytic substance that has the synergistic effect of being able to completely decompose harmful substances such as allergens through a catalytic reaction with sunlight.

(2) Based on the technical idea of using phthalocyanine as the main catalyst, the fixing agent, phthalocyanine and titanium dioxide are mixed and applied or separately applied to the substrate, but 0.01 to 50 with respect to the titanium dioxide content. % Capacity phthalocyanine adsorbs organic compounds at room temperature even in the absence of light, phthalocyanine decomposes organic compounds in the air during adsorption, and decomposes harmful substances by titanium dioxide that undergoes photocatalytic reaction in the daytime In the nighttime, phthalocyanine is adsorbed and decomposed with phthalocyanine. The main catalyst is phthalocyanine, which decomposes and removes organic compounds in the air. Phthalocyanine-supported photothermal catalytic material with a synergistic effect that can completely decompose harmful substances such as Removal of hazardous substances by, antibacterial, deodorant method.

(3) Since it is difficult to disperse neatly by mixing phthalocyanine and titanium dioxide with a diluent such as water, a substance with excellent adhesive properties such as acrylic resin or egg white as a loading aid in a transparent diluent The phthalocyanine pigment is fixed on the surface of the titanium dioxide by admixing the diluted solution, phthalocyanine pigment and titanium dioxide, and rubbed appropriately in an industrial mortar for a certain period of time, so that the phthalocyanine and titanium dioxide are adsorbed individually as dyes. Photothermal catalytic material carrying phthalocyanine that has a synergistic effect of being able to completely decompose harmful substances such as allergens by catalyzing reaction with sunlight by titanium dioxide with photocatalytic effect in a state of dyeing fiber yarns. Remove harmful substances, antibacterial and deodorant methods.

(4) The fiber dyed with phthalocyanine absorbs house dust, pollen and grain allergens, which are typical allergens, and easily peels off in a laundry basket in the presence of a surfactant, and is reversible with adsorption of allergen substances. A photocatalytic phthalocyanine-supported photoheat that is capable of decomposing harmful substances such as allergens by the catalytic reaction with sunlight by the titanium dioxide with photocatalytic effect, while the desorption phenomenon is easy. Removal of harmful substances, antibacterial and deodorizing methods using catalytic substances.

(5) If the amount is less than 0.1% by volume, organic substances such as dirt are not decomposed, and sufficient photothermal catalytic action cannot be exhibited. Is mixed with a phthalocyanine substance having a content of 0.01 to 50% by volume with respect to the content of titanium dioxide. A method using a phthalocyanine-supported photothermal catalytic material that can be clouded.

(6) By mixing phthalocyanine and titanium dioxide, the titanium dioxide is dyed, and the material is wrapped around the titanium dioxide and synthesized in the pores of the microporous material by the bottle ship synthesis method in the base pores. Titanium dioxide with a photocatalytic effect, which aims to catalyze the decomposition of harmful substances, which can exchange metal ions in the skeleton in the pores with other metal ions that have been electrolyzed. This is a method of removing harmful substances, antibacterial and deodorizing with a phthalocyanine-supported photothermal catalytic substance that has a synergistic effect that it can completely decompose harmful substances such as allergens.

(7) Can be applied to substrate surfaces such as window glass, guardrails, walls, roofs, electrical appliances, fiber and non-fiber products, while shirts, underwear, suits, easy order, formal, shirts, ties, Denim, sweater, T-shirt, inner, leather, fur, pajamas, dress, kimono, Nagatoro, children's clothing, inner, Arimatsu squeeze, white robe (nurse), white robe (food) white robe (clinic), white robe (nursing), office work Clothing, uniforms, school uniforms, nursing supplies, nursing supplies (sheets), golf pants, golf shirts, athletics, skis, snowboards, swimwear, hats, martial arts wears, mountaineering, snowboarding, athletic clothing, pajamas, futons, sheets, pillowcases , Towel, blanket, kotack, curtain, roll curtain, carpet, bedding, mask, insole, shoes, Bottom, mop, bag, toiletry, towel, mask, thread, cloth bag, seat cover, car seat, deodorant escalator, train, cold air blower, wiper, interior, processing fluid, non-woven fabric, material, coating, interlining, agricultural use gloves can be applied or dyed light thermal catalytic article simply as washing spray, the titanium dioxide having a photocatalytic effect, and the sunlight and catalytic reaction, to completely decompose harmful substances such as allergens Removal of harmful substances, antibacterial and deodorizing methods using a photothermal catalytic material carrying phthalocyanine that has a synergistic effect.

(8) A phthalocyanine dye, a titanium compound dye, and a fixing agent are added and mixed in an aqueous solution, and the mixture is mixed in a natural solution or a mixture having a mixing ratio of 0.01: 10 to 1:10 to 5:10. Titanium dioxide with photocatalytic effect has a method in which artificial fibers are impregnated and the fibers are dyed by applying a certain percentage of heat, so that it reacts with sunlight to completely remove harmful substances such as allergens. Removal of harmful substances, antibacterial and deodorizing methods with a phthalocyanine-supported photothermal catalytic material that has a synergistic effect that can be decomposed into

(9) By blending a phthalocyanine dye and a titanium compound dye, titanium dioxide with a photocatalytic effect has an effective color composition that has a function of producing a deodorizing effect as an image by giving a visual clean feeling. Removal of harmful substances, antibacterial and deodorizing methods with a phthalocyanine-supported photothermal catalytic substance that has a synergistic effect that can completely decompose harmful substances such as allergens through a catalytic reaction with sunlight.

(10) By using natural-derived fixing agents, the negative effects of conventional petroleum-based fixing agents on the human body are completely eliminated, and titanium dioxide with a photocatalytic effect is used to catalyze with sunlight to cause harmful substances such as allergens. Removal of harmful substances, antibacterial and deodorizing methods with a phthalocyanine-supported photothermal catalytic material that has a synergistic effect that can be completely decomposed.

(11) The fixing agent has an oil component, and the oil component is an oil component composed of a natural product-derived wax, a mineral spirit solvent, a vegetable oil, and the like, and a conventional surfactant. Among these, the waxes derived from natural products include carbana wax, candelilla wax, rice bran wax, cucumber wax, sugar cane wax, jojoba wax, oilseed wax, molasses, urushi wax, beeswax, etc. Well, these oil components exhibit water repellency, gloss on the coated surface, and have a characteristic of being compatible with synthetic resin. Catalytic reaction with sunlight by photocatalytic titanium dioxide, allergens, etc. Removal of harmful substances with anti-phthalocyanine-supported photothermal catalytic material with synergistic effect that can completely decompose harmful substances, etc. , Deodorant method.

(12) Increase the distribution of phthalocyanine on the lining, which is easy to sweat and cannot be seen from the outside, or devise it by applying it to the side of the side where the sweat is likely to come out or on the soles around the neck. Titanium dioxide, which has photocatalytic effect, is capable of catalyzing with sunlight to completely decompose harmful substances such as allergens. Deodorizing method.

The present invention supports titanium dioxide, which is a photocatalytic reaction material, with phthalocyanine that catalyzes reaction not only with visible light but also with infrared rays with a level of heat that reacts with an infrared camera, and even with no light. Titanium dioxide with a photocatalytic effect with a method that allows the phthalocyanine-supported phthalocyanine-supported photothermal catalyst to maintain antibacterial, sterilization, deodorization, and air cleaning effects even in the absence of light Can remove harmful substances, antibacterial, and deodorant with a phthalocyanine-supported photothermal catalytic substance that has a synergistic effect that can completely decompose harmful substances such as allergens through a catalytic reaction with sunlight. became.

Therefore, based on the technical idea of using phthalocyanine as the main catalyst, the fixing agent, phthalocyanine and titanium dioxide are mixed and applied or separately applied to the substrate, but 0.01 to 50% of the content of titanium dioxide. Capacitance phthalocyanine adsorbs organic compounds at room temperature even in the absence of light, phthalocyanine decomposes organic compounds in the air during adsorption, and has the effect of decomposing harmful substances by titanium dioxide that performs photocatalytic reaction during the day. Demonstrated, it became possible to decompose and remove organic compounds in the air using phthalocyanine, which is adsorbed and decomposed with phthalocyanine at night, as the main catalyst.

On the other hand, since it is difficult to disperse neatly by simply mixing phthalocyanine and titanium dioxide with a diluent such as water, a substance with excellent adhesive properties such as acrylic resin or egg white as a loading aid in a transparent diluent The phthalocyanine pigment is fixed on the surface of the titanium dioxide by admixing the diluted solution, phthalocyanine pigment and titanium dioxide, and rubbed appropriately in an industrial mortar for a certain period of time, so that the phthalocyanine and titanium dioxide are adsorbed individually as dyes. Created a state of dyeing fiber yarn.

The phthalocyanine-dyed fiber adsorbs typical allergens such as house dust, pollen and grain allergens, and easily peels off in a laundry basket in the presence of a surfactant, which is reversible with allergen substance adsorption. Could be done easily.

If the amount is less than 0.1% by volume, organic matter such as dirt is not decomposed and sufficient photothermal catalytic action cannot be exhibited. If the amount exceeds 20% by volume, transparency of the surface of the substrate is obtained. By mixing a phthalocyanine substance with a content of 0.01 to 50% by volume with respect to the content of titanium dioxide, which causes inconvenience that there is no inconvenience, a phthalocyanine substance having a blue tendency can be clouded with a titanium compound depending on the application. It was.

By mixing phthalocyanine and titanium dioxide, the titanium dioxide is dyed, and the titanium dioxide is materially wrapped and synthesized in the pores of the microporous material by the bottle ship synthesis method in the base pores. The ability to exchange metal ions in the skeleton with other metal ions that have been electrolyzed makes it possible to catalyze the decomposition of harmful substances.

In the above manner, it can be applied to the surface of substrates such as window glass, guardrails, walls, roofs, electrical appliances, fibers and non-woven products, while shirts, underwear, suits, easy order, formal, Shirt, tie, denim, sweater, T-shirt, inner, leather, fur, pajamas, dress, kimono, long sleeve, children's clothing, inner, Arimatsu squeeze, white robe (nurse), white robe (food) white robe (clinic), white robe (nursing care) ), Office work clothes, uniforms, school uniforms, nursing supplies, nursing supplies (sheets), golf pants, golf shirts, athletics, skis, snowboards, swimsuits, hats, martial arts wears, mountaineering, snowboarding, sports clothes, pajamas, futons, Sheets, pillowcases, towels, blankets, kotatsu racks, curtains, roll curtains, carpets, bedding, masks, masks Sole, shoes, socks, mops, bags, toiletries, towels, masks, threads, cloth bags, seat covers, car seats, deodorant escalators, trains, cold air blowers, wipers, interiors, processing fluids, non-woven fabrics, materials, coatings, cores land, agricultural gloves, can also be coated or stain the light heat catalyst article to a simple as washing spray was able to.

A phthalocyanine dye, a titanium compound dye, and a fixing agent are added and mixed in an aqueous solution, and a natural or artificial fiber is mixed in a mixed solution having a mixing ratio of 0.01: 10 to 1:10 to 5:10. The fiber could be dyed by impregnating and heating at a certain rate.

By blending a phthalocyanine dye and a titanium compound dye, it was possible to have an effective color composition that has a function of producing a deodorizing effect as an image by providing a visual clean feeling.

Furthermore, by using a naturally-derived fixing agent, it was possible to eliminate any adverse effects of conventional petroleum-based fixing agents on the human body.

The fixing agent has an oil component, and the oil component is an oil component composed of a natural product-derived wax, a mineral spirit solvent, a vegetable oil, and a conventional surfactant, As the wax derived from natural products, there are carbana wax, candelilla wax, rice bran wax, cucumber wax, sugar cane wax, jojoba wax, oil candy wax, molasses, urushi wax, beeswax, etc. These oil components exhibit water repellency, gloss on the coated surface, and have properties of being compatible with acrylic synthetic resins.

It is possible to devise by increasing the distribution of phthalocyanine on the lining part that is easy to sweat and not visible from the outside, or by applying it to the side part where the sweat easily occurs and the sole around the neck at one point It was.

Some examples of specific embodiments relating to a method for decomposing and removing organic compounds in the air using the phthalocyanine of the present invention as the main catalyst as described above will be described below with reference to the accompanying drawings.
First, the technical idea of using phthalocyanine as a main catalyst and titanium dioxide, which is a photocatalytic substance, as an auxiliary catalyst in properly decomposing and removing organic compounds and the like to exert an air cleaning effect will be described. In pursuit of air purification using photocatalytic substances such as titanium dioxide, various research and development have been made based on the idea of decomposing and removing organic compounds in the air using photocatalytic oxidation / reduction reactions. However, the improvement of the photocatalytic effect cannot be easily obtained especially in parts with little light, in parts not exposed to light, and at night, etc. is the start of the present invention.

That is, in order to achieve more effective antibacterial, sterilization, deodorization, and air cleaning effects with a photothermal catalytic material, a photocatalyst layer forming method, an effective application to a substrate, and an article for realizing a dyed layer, dispersion Research and development has been progressing on a method for uniformly dispersing photocatalytic substance particles from the agent, but there is still a situation where the expected results have not yet been obtained.

In the process of investigating the cause of the current situation, the inventor used a photothermal catalytic material containing phthalocyanine as an auxiliary agent that performs an auxiliary function, and the light from the outside was blocked at night. It was noted that antibacterial, antibacterial, deodorizing, and air cleaning effects still exist for a certain period of time even when there is no visible light or no visible light.

Here, the inventor paid attention to the fact that phthalocyanine also has a redox action as a catalyst. However, phthalocyanine is originally a pigment-based material, and it is difficult to adsorb or soak it into the substrate by itself. However, it has been difficult to maintain the state of adsorption or coating or dyeing over a long period of time.

Therefore, not only did we pay attention to the hydrophilicity of titanium dioxide, which has a photocatalytic effect, and the dispersion effect in the solvent, but it was also found that the pigment of the phthalocyanine substance can be made cloudy depending on the application.

Furthermore, it is possible to dissolve pigment pigments more evenly in a solvent by using a diluent such as an acrylic resin as an auxiliary agent, and it becomes possible to easily dye and apply to a substrate.

That is, the inventor has reached a new idea that phthalocyanine is used as a main catalyst that performs an air cleaning function, and a photocatalytic substance such as titanium dioxide is used to decompose toxic organic compounds adsorbed on the surface of phthalocyanine. Thus, the present invention has been completed.

Specifically, based on the technical idea of using phthalocyanine as a main catalyst, a fixing agent, phthalocyanine and titanium dioxide are mixed and applied or separately applied to a substrate. Phthalocyanine with 50% capacity adsorbs organic compounds at room temperature even in the absence of light, phthalocyanine decomposes organic compounds in the air during adsorption, and decomposes harmful substances with titanium dioxide that undergoes photocatalytic reaction during the day It has been effective, and has led to a method of decomposing and removing organic compounds in the air using phthalocyanine, which is adsorbed and decomposed with phthalocyanine at night, as the main catalyst.

FIG. 1 is an individual coating diagram of a phthalocyanine-supported photothermal catalyst, and shows a form when a phthalocyanine layer and a titanium dioxide layer are separately formed on a substrate in the phthalocyanine-supported photothermal catalyst method of the present invention. 1 is visible light such as sunlight and heat, 2 is a titanium dioxide layer, 3 is a phthalocyanine layer, 4 is a base layer, and 5 is external heat.

FIG. 2 is a phthalocyanine-supported photothermal catalyst titanium dioxide mixed coating diagram. In the phthalocyanine-supported photothermal catalyst method of the present invention, phthalocyanine and titanium dioxide are mixed to form a phthalocyanine-supported titanium dioxide material layer on a substrate. It is shown. 1 'is visible light such as sunlight and heat, 2' is a phthalocyanine-supporting titanium dioxide material layer, 3 'is a base layer, and 4' is external heat.

FIG. 3 is a cross-sectional view of adsorption of a phthalocyanine-supported photothermal catalytic fiber. In the phthalocyanine-supported photothermal catalyst method of the present invention, phthalocyanine and titanium dioxide are mixed and the phthalocyanine-supported titanium dioxide material is adhered to a fiber yarn as a substrate. The form of is shown. 1 ″ is visible light such as sunlight and heat, 2 ″ is a phthalocyanine-supported titanium dioxide material layer, 3 ″ is external heat, and 4 ″ is a cross section of the fiber yarn as a substrate.

When according to the present invention as described above, phthalocyanine is used as a main catalyst and titanium dioxide is used as a secondary catalyst. It is possible to provide the society with functions to exert sterilization, deodorization, and air cleaning effects easily and inexpensively, and it has been difficult or temporarily exerted a conventional catalytic effect as a means. In the present invention, the present invention provides a new means for effectively exerting the catalytic effect even inside the clothes. Is understood to be an invention excellent in industrial applicability.

Individual application of phthalocyanine-supported photothermal catalyst Phthalocyanine-supported photothermal catalyst titanium dioxide mixed coating diagram Adsorption cross section of phthalocyanine-supported photothermal catalytic fiber

Explanation of symbols

1 is visible light such as sunlight and heat 2 is titanium dioxide layer 3 is phthalocyanine layer 4 is base layer 5 is external heat 1 'is visible light such as sunlight and heat 2' is phthalocyanine-supporting titanium dioxide material layer 3 ' The substrate layer 4 'has external heat 1 "visible light such as sunlight and heat 2" is phthalocyanine-supported titanium dioxide material layer 3 "is external heat, and 4" is a cross section of the fiber yarn as the substrate.

Claims (12)

Titanium dioxide, which is a photocatalytic reactant, reacts not only with visible light but also with infrared rays with a level of heat that reacts with an infrared camera, and further supports phthalocyanine that catalyzes reaction even without light. By using photocatalytic catalyst carrying phthalocyanine as the main component, titanium dioxide with photocatalytic effect has a method that enables antibacterial, sterilization, deodorization, and air cleaning effects to be sustained even in the absence of light. This is a method of removing harmful substances, antibacterial and deodorizing with a phthalocyanine-supported photothermal catalytic substance that has a synergistic effect that it can completely decompose harmful substances such as allergens. Based on the technical idea of using phthalocyanine as the main catalyst, the fixing agent, phthalocyanine and titanium dioxide are mixed and applied or separately applied to the substrate, but the content is 0.01 to 50% with respect to the content of titanium dioxide. Phthalocyanine adsorbs organic compounds at room temperature even in the absence of light, phthalocyanine decomposes organic compounds in the air during adsorption, and exhibits the effect of decomposing harmful substances by titanium dioxide that performs photocatalytic reaction during the daytime. In the nighttime, phthalocyanine is decomposed by adsorption and decomposition with phthalocyanine. It has a method of decomposing and removing organic compounds in the air using phthalocyanine as the main catalyst. Phthalocyanine-supported photothermal catalytic material with a synergistic effect that can completely decompose materials, etc. Removal of harmful substances, antibacterial, deodorant method. Since it is difficult to disperse neatly by simply mixing phthalocyanine and titanium dioxide with a diluent such as water, put a substance with excellent adhesive properties such as acrylic resin or egg white as a loading aid in the transparent diluent. Mix the diluted solution, phthalocyanine pigment and titanium dioxide, and rub them properly in an industrial mortar for a certain period of time to fix the phthalocyanine pigment on the surface of titanium dioxide, so that phthalocyanine and titanium dioxide adsorb to each other individually as dyes into the fiber yarn. Hazardous substance by photothermal catalytic material carrying phthalocyanine with synergistic effect that it can catalyze with sunlight and completely decompose harmful substances such as allergens by titanium dioxide with photocatalytic effect in dyed state Removal, antibacterial and deodorant methods. The phthalocyanine-dyed fiber adsorbs typical allergens such as house dust, pollen and grain allergens, and easily peels off in a laundry basket in the presence of a surfactant, which is reversible with allergen substance adsorption. The photocatalytic substance supported by phthalocyanine has a synergistic effect in that it can be decomposed by alleviating harmful substances such as allergens by the catalytic reaction with sunlight by titanium dioxide having photocatalytic effect. Removal of harmful substances, antibacterial and deodorizing methods. If the amount is less than 0.1% by volume, organic matter such as dirt is not decomposed and sufficient photothermal catalytic action cannot be exhibited. If the amount exceeds 20% by volume, transparency of the surface of the substrate is obtained. By mixing a phthalocyanine substance having a content of 0.01 to 50% by volume with respect to the content of titanium dioxide, which causes inconvenience that there is no inconvenience, a phthalocyanine substance having a blue tendency can be clouded with a titanium compound depending on the application. However, a method using a phthalocyanine-supported photothermal catalytic material. By mixing phthalocyanine and titanium dioxide, the titanium dioxide is dyed, and the titanium dioxide is materially wrapped and synthesized in the pores of the microporous material by the bottle ship synthesis method in the base pores. Catalytic reaction with sunlight by titanium dioxide with photocatalytic effect, mainly for the purpose of catalysis targeting the decomposition of harmful substances, which can exchange metal ions in the skeleton with other metal ions that have been electrolyzed The removal of harmful substances, antibacterial and deodorizing methods with a phthalocyanine-supported photothermal catalytic substance that has a synergistic effect that can completely decompose harmful substances such as allergens. It can also be applied to substrate surfaces such as window glass, guardrails, walls, roofs, electrical appliances, textiles and non-wovens, while shirts, underwear, suits, easy order, formal, shirts, ties, denim, sweaters , T-shirt, inner, skin, fur, pajamas, dress, kimono, long sleeve, children's clothing, inner, Arimatsu squeezed, white coat (nurse), white coat (food) white coat (clinic), white coat (nursing), office work clothes, uniform , School uniforms, care products, care products (sheets), golf pants, golf shirts, athletics, skiing, snowboarding, swimwear, hats, martial arts clothing, mountaineering, snowboarding, sportswear, pajamas, futons, sheets, pillowcases, towels, Blanket, kotack, curtain, roll curtain, carpet, bedding, mask, insole, shoes, socks, , Bags, toiletries, towels, masks, thread, cloth bags, seat covers, car seats, deodorant escalators, trains, cold air machines, wipers, interiors, processing fluids, nonwoven fabrics, materials, coatings, interlinings, agricultural gloves it can be applied or dyed light thermal catalytic article simply as washing spray, the titanium dioxide having a photocatalytic effect, and the sunlight and catalytic reaction, to completely decompose harmful substances such as allergens Removal of harmful substances, antibacterial and deodorizing methods using phthalocyanine-supported photothermal catalytic material with synergistic effects. A phthalocyanine dye, a titanium compound dye, and a fixing agent are added and mixed in an aqueous solution, and a natural or artificial fiber is mixed in a mixed solution having a mixing ratio of 0.01: 10 to 1:10 to 5:10. The titanium dioxide with photocatalytic effect has a method of impregnating the fiber and dyeing the fiber by applying a certain rate of heat to catalyze with sunlight to completely decompose harmful substances such as allergens. Removal of harmful substances, antibacterial and deodorizing methods with a phthalocyanine-supported photothermal catalytic material that has a synergistic effect. By blending a phthalocyanine dye and a titanium compound dye, the titanium dioxide with photocatalytic effect has an effective color composition that has the function of producing a deodorizing effect as an image by giving a visual clean feeling, sunlight and Removal of harmful substances, antibacterial and deodorizing methods using a phthalocyanine-supported photothermal catalytic substance that has a synergistic effect that can completely decompose harmful substances such as allergens through a catalytic reaction. By using natural-derived fixing agent, titanium dioxide with photocatalytic effect that completely eliminates the negative effects of conventional petroleum-based fixing agents on the human body and catalyzes sunlight to completely remove harmful substances such as allergens. Removal of harmful substances, antibacterial and deodorizing methods with a phthalocyanine-supported photothermal catalytic material that has a synergistic effect that can be decomposed into The fixing agent has an oil component, and the oil component is an oil component composed of a natural product-derived wax, a mineral spirit solvent, a vegetable oil, and a conventional surfactant, As waxes derived from natural products, there are carbana wax, candelilla wax, rice bran wax, cucumber wax, sugar cane wax, jojoba wax, oilseed wax, molasses, urushi wax, beeswax, etc. The oil component exhibits water repellency, gloss on the coated surface, and compatibility with synthetic resin. Catalytic reaction with sunlight by titanium dioxide with photocatalytic effect causes harmful substances such as allergens. Removal of toxic substances, antibacterial and deodorant by phthalocyanine-supported photothermal catalytic material that has a synergistic effect that can be completely decomposed Law. Photocatalytic effect that increases the distribution of phthalocyanine on the lining, which is easy to sweat and cannot be seen from the outside, or is applied by applying it to the side of the sweat or the side of the neck where it is easy to sweat. Titanium dioxide has a synergistic effect that it can completely decompose harmful substances such as allergens by catalyzing reaction with sunlight. Removal of harmful substances, antibacterial and deodorant by phthalocyanine-supported photothermal catalytic substance Method.