JP2009192698A5 - - Google Patents

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Publication number
JP2009192698A5
JP2009192698A5 JP2008031727A JP2008031727A JP2009192698A5 JP 2009192698 A5 JP2009192698 A5 JP 2009192698A5 JP 2008031727 A JP2008031727 A JP 2008031727A JP 2008031727 A JP2008031727 A JP 2008031727A JP 2009192698 A5 JP2009192698 A5 JP 2009192698A5
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JP
Japan
Prior art keywords
group
negatively chargeable
producing
toner
chargeable toner
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JP2008031727A
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Japanese (ja)
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JP5186233B2 (en
JP2009192698A (en
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Priority claimed from JP2008031727A external-priority patent/JP5186233B2/en
Priority to JP2008031727A priority Critical patent/JP5186233B2/en
Priority to US12/671,576 priority patent/US8288070B2/en
Priority to CN2008801005109A priority patent/CN101765813B/en
Priority to DE112008002107.4T priority patent/DE112008002107B4/en
Priority to PCT/JP2008/064133 priority patent/WO2009020155A1/en
Publication of JP2009192698A publication Critical patent/JP2009192698A/en
Publication of JP2009192698A5 publication Critical patent/JP2009192698A5/ja
Publication of JP5186233B2 publication Critical patent/JP5186233B2/en
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Claims (9)

(1)水系媒体中で、酸基を有するポリエステルを含有する結着樹脂に、オキサゾリン基及びアジリジン基からなる群から選ばれる少なくとも一種の官能基を有する化合物を結合させて、体積中位粒径(D50)が2〜10μmのトナー粒子を得る工程、及び  (1) A volume-median particle size obtained by binding a compound having at least one functional group selected from the group consisting of an oxazoline group and an aziridine group to a binder resin containing an acid group-containing polyester in an aqueous medium. A step of obtaining toner particles having (D50) of 2 to 10 μm, and
(2)工程(1)で得られたトナー粒子を、数平均粒子径が10〜200nmである正帯電性の酸化マグネシウムと、数平均粒子径が6〜30nmであるシリカ又は酸化チタンとを含む外添剤で外添処理する工程  (2) The toner particles obtained in step (1) contain positively chargeable magnesium oxide having a number average particle diameter of 10 to 200 nm and silica or titanium oxide having a number average particle diameter of 6 to 30 nm. Process of external addition with external additives
を有する、電子写真用負帯電性トナーの製造方法。A method for producing a negatively chargeable toner for electrophotography.
工程(1)が、  Step (1)
(a)水系媒体中で、酸基を有するポリエステルを含有する結着樹脂を乳化して乳化粒子を得る工程、  (A) a step of emulsifying a binder resin containing a polyester having an acid group in an aqueous medium to obtain emulsified particles;
(b)工程(a)で得られた乳化粒子を凝集して凝集粒子を得る工程、  (B) a step of aggregating the emulsified particles obtained in step (a) to obtain agglomerated particles;
(c)工程(b)で得られた凝集粒子を合一してトナー粒子を得る工程、及び  (C) combining the aggregated particles obtained in step (b) to obtain toner particles; and
(d)工程(a)以後に、オキサゾリン基及びアジリジン基からなる群から選ばれる少なくとも一種の官能基を有する化合物を添加する工程  (D) A step of adding a compound having at least one functional group selected from the group consisting of an oxazoline group and an aziridine group after step (a).
を有する、請求項1に記載の電子写真用負帯電性トナーの製造方法。The method for producing a negatively chargeable toner for electrophotography according to claim 1, comprising:
酸化マグネシウムが、アミノシランで疎水化処理されたものである、請求項1又は2に記載の電子写真用負帯電性トナーの製造方法The method for producing a negatively chargeable toner for electrophotography according to claim 1 or 2, wherein the magnesium oxide is hydrophobized with aminosilane. 酸化マグネシウムが、更にシリコーンオイル系の疎水化処理剤で表面が処理されたものである、請求項3に記載の電子写真用負帯電性トナーの製造方法。  The method for producing a negatively chargeable toner for electrophotography according to claim 3, wherein the surface of the magnesium oxide is further treated with a silicone oil-based hydrophobizing agent. 工程(2)における外添剤の添加量が、トナー粒子に対する酸化マグネシウムとシリカ又は酸化チタンの含有割合(酸化マグネシウムの含有量/シリカ又は酸化チタンの含有量)が、重量比で0.4〜1.5となる量である、請求項1〜のいずれかに記載の電子写真用負帯電性トナーの製造方法 The additive amount of the external additive in the step (2) is such that the content ratio of magnesium oxide and silica or titanium oxide to the toner particles (magnesium oxide content / silica or titanium oxide content) is 0.4 to 0.4 by weight. The method for producing a negatively chargeable toner for electrophotography according to any one of claims 1 to 4 , wherein the amount is 1.5. オキサゾリン基及びアジリジン基からなる群から選ばれる少なくとも一種の官能基を有する化合物が、オキサゾリン基を有する重合体である、請求項1〜5のいずれかに記載の電子写真用負帯電性トナーの製造方法。  6. The negatively chargeable toner for electrophotography according to claim 1, wherein the compound having at least one functional group selected from the group consisting of an oxazoline group and an aziridine group is a polymer having an oxazoline group. Method. 酸基を有するポリエステルを含有する結着樹脂中のカルボキシル基のモル数に対する、オキサゾリン基を有する重合体中のオキサゾリン基のモル数が、0.01倍以上、0.8倍以下である、請求項6に記載の電子写真用負帯電性トナーの製造方法。  The number of moles of the oxazoline group in the polymer having an oxazoline group is 0.01 times or more and 0.8 times or less, relative to the number of moles of the carboxyl group in the binder resin containing the polyester having an acid group, Item 7. A method for producing a negatively chargeable toner for electrophotography according to Item 6. さらに数平均粒子径が100〜600nmの有機微粒子を外添剤として含む、請求項1〜のいずれかに記載の電子写真用負帯電性トナーの製造方法The method for producing a negatively chargeable toner for electrophotography according to any one of claims 1 to 7 , further comprising organic fine particles having a number average particle diameter of 100 to 600 nm as an external additive. 請求項1〜8のいずれかに記載の製造方法により得られる電子写真用負帯電性トナー。  An electrophotographic negatively chargeable toner obtained by the production method according to claim 1.
JP2008031727A 2007-08-08 2008-02-13 Negatively chargeable toner for electrophotography Active JP5186233B2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2008031727A JP5186233B2 (en) 2008-02-13 2008-02-13 Negatively chargeable toner for electrophotography
PCT/JP2008/064133 WO2009020155A1 (en) 2007-08-08 2008-08-06 Process for producing toner for electrophotography
CN2008801005109A CN101765813B (en) 2007-08-08 2008-08-06 Method for producing toner for electrophotography
DE112008002107.4T DE112008002107B4 (en) 2007-08-08 2008-08-06 Process for producing a toner for electrophotography
US12/671,576 US8288070B2 (en) 2007-08-08 2008-08-06 Process for producing toner for electrophotography

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2008031727A JP5186233B2 (en) 2008-02-13 2008-02-13 Negatively chargeable toner for electrophotography

Publications (3)

Publication Number Publication Date
JP2009192698A JP2009192698A (en) 2009-08-27
JP2009192698A5 true JP2009192698A5 (en) 2011-03-24
JP5186233B2 JP5186233B2 (en) 2013-04-17

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JP2008031727A Active JP5186233B2 (en) 2007-08-08 2008-02-13 Negatively chargeable toner for electrophotography

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JP (1) JP5186233B2 (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5119074B2 (en) * 2008-07-24 2013-01-16 シャープ株式会社 Toner manufacturing method, toner, developer, developing device, and image forming apparatus
JP5482477B2 (en) * 2010-06-11 2014-05-07 コニカミノルタ株式会社 Method for producing electrostatic charge developing toner and electrostatic charge developing toner
JP5482478B2 (en) * 2010-06-11 2014-05-07 コニカミノルタ株式会社 Toner production method for electrostatic charge development, toner for electrostatic charge development
JP6569645B2 (en) * 2016-02-25 2019-09-04 京セラドキュメントソリューションズ株式会社 Toner for electrostatic latent image development

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69230072T2 (en) * 1991-08-22 2000-03-09 Lucky Ltd METHOD FOR PRODUCING A BINDING RESIN, USERALLY IN ELECTROPHOTOGRAPHIC TONERS
JPH1195487A (en) * 1997-09-25 1999-04-09 Dainippon Ink & Chem Inc Plate making method of direct drawing type lithographic printing master plate
JP2000292968A (en) * 1999-04-02 2000-10-20 Canon Inc Dry toner
JP2004191532A (en) * 2002-12-10 2004-07-08 Canon Inc Image forming method and developer for replenishment used in image forming method
JP2005215607A (en) * 2004-02-02 2005-08-11 Seiko Epson Corp Electrophotographic toner
JP2005215608A (en) * 2004-02-02 2005-08-11 Seiko Epson Corp Method for manufacturing electrophotographic toner

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