JP2009173777A - Detergent - Google Patents

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Publication number
JP2009173777A
JP2009173777A JP2008014330A JP2008014330A JP2009173777A JP 2009173777 A JP2009173777 A JP 2009173777A JP 2008014330 A JP2008014330 A JP 2008014330A JP 2008014330 A JP2008014330 A JP 2008014330A JP 2009173777 A JP2009173777 A JP 2009173777A
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water
cleaning
sodium silicate
article
cleaned
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Daisuke Tokunaga
大輔 徳永
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ALCHEMY CO Ltd
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ALCHEMY CO Ltd
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Priority to JP2008014330A priority Critical patent/JP2009173777A/en
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  • Cleaning By Liquid Or Steam (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Detergent Compositions (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a detergent suitable for cleaning that can decrease cleaning frequency. <P>SOLUTION: Raw water is processed by a reverse osmosis membrane method to generate active water, and sodium silicate is incorporated into the active water to prepare the detergent. An article to be cleaned is subjected to cleaning or wipe-off cleaning with the detergent, and a film of sodium silicate is formed on the surface of the article to be cleaned. This film prevents adherence of stains. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、自動車や建築物の内装、OA機器、玩具等の人が頻繁に接する物品の清掃に適した洗浄剤に関する。   The present invention relates to a cleaning agent suitable for cleaning articles such as interiors of automobiles and buildings, office automation equipment, and toys, which are frequently contacted by people.

従来より、逆浸透膜法により処理して得られる活性水は、種々の物品の清掃(洗浄清掃及び拭き取り清掃)に利用されていた。
逆浸透膜法とは、例えば、水槽を半透膜にて二区画に仕切り、一方の区画に食塩水を注入し、他方の区画に純水を注入すると、自然に純水側が減少し、食塩水側が増加し、食塩水が希釈されることとなるが、これは半透膜が極微小の細孔を有し、食塩水中のナトリウムイオンや塩素イオン、これらイオンと水分子が会合して成る集合体は、その細孔を透過することが出来ず、クラスター(複数の水分子が会合して成る集合体)の小さな水分子だけが半透膜を透過し、二区画間を行き交うためであり、この半透膜を利用し、一方の区画のみに原水(水道水等でミネラルイオン等を微量含有する。)を注入し、該原水に加圧することで、強制的に半透膜を透過させ、このとき半透膜にて原水含有の不純物を除去すると共に、クラスターを分断し、活性水を生成して、他方側の区画に貯溜する様にした方法である。
この活性水は、これを構成する水分子のクラスターが小さいため、表面張力が小さく、浸透性に優れており、被清掃物品と、それに付着している汚れの間の微細な隙間にまで浸入することが出来ることから、洗浄力が高く、有機系界面活性剤等の洗剤の使用を不要にすることが出来きた。
しかし、そもそもクラスターの形成は、水分子が元来有する極性が原因であるため、活性水の生成後、クラスターは徐々に再成長し、時間経過に伴い洗浄力は低下するため、活性水の長期保存は出来なかった。
ところで、上記の活性水同様、洗剤不要で環境に優しく、洗浄力の高い水として、アルカリイオン水が挙げられる。
しかし、アルカリイオン水は、原水に印加し、水分子の会合状態、電荷状態を調整することによって、洗浄力を付与しているため、被清掃物品との接触により、急激に通常の水に戻ってしまい、また貯溜状態で空気と接触しているだけでも、徐々に元の水に戻り、洗浄力を長期間維持させることは出来なかった。
そこで、電解装置により生成したアルカリイオン水を逆浸透膜法により更に処理し、得られた活性水を再度電解処理して生成する様にした洗浄水が発明された(下記特許文献1を参照)。
この洗浄水は、pH値を12以上にすると共に、含有不純物を除去することによって、洗浄水中の電子が容易に空中に放電しない様にし、洗浄力低下の防止を図る様にしたものであった。
Conventionally, the active water obtained by processing by the reverse osmosis membrane method has been used for cleaning various articles (cleaning cleaning and wiping cleaning).
In the reverse osmosis membrane method, for example, when a water tank is divided into two compartments by a semipermeable membrane, when saline is injected into one compartment and pure water is injected into the other compartment, the pure water side naturally decreases, The water side increases and the saline solution is diluted. This is because the semipermeable membrane has extremely small pores, and sodium ions and chloride ions in the saline solution, and these ions and water molecules are associated with each other. This is because the aggregate cannot penetrate the pores, and only small water molecules in the cluster (an aggregate composed of multiple water molecules) permeate the semipermeable membrane and move between the two compartments. Using this semipermeable membrane, raw water (containing a small amount of mineral ions etc. in tap water) is injected into only one compartment, and the semipermeable membrane is forced to permeate by pressurizing the raw water. At this time, while removing raw water-containing impurities in the semipermeable membrane, the cluster is divided, It generates a sex water, a method was set to be accumulated in compartment on the other side.
Since this active water has small clusters of water molecules constituting it, it has a low surface tension and excellent permeability, and penetrates into the fine gap between the article to be cleaned and the dirt adhering to it. Therefore, the detergency is high and the use of a detergent such as an organic surfactant can be eliminated.
However, since the formation of clusters is primarily due to the inherent polarity of water molecules, after the generation of active water, the clusters gradually re-grow, and the cleaning power decreases with time. I couldn't save it.
By the way, like the above-mentioned active water, alkaline ionized water is an example of water that does not require detergent and is environmentally friendly and has high detergency.
However, alkaline ionized water is applied to the raw water and adjusts the association state and charge state of water molecules to provide detergency, so it suddenly returns to normal water when contacted with the article to be cleaned. Moreover, even if it was in contact with air in the reservoir state, it gradually returned to the original water and the detergency could not be maintained for a long time.
Then, the washing water which invented the alkaline ion water produced | generated with the electrolysis apparatus further by the reverse osmosis membrane method, and produced | generated the activated water obtained again by electrolytic treatment was invented (refer the following patent document 1). .
This washing water was designed to prevent the electrons from being easily discharged into the air by preventing impurities from being contained by removing the contained impurities while setting the pH value to 12 or more. .

特開2001−70899号公報(要約、特許請求の範囲)JP 2001-70899 A (Abstract, Claims)

ところが、例えば、エアコン等の空調機器、OA機器等の様に静電気により汚れが付着し易い物品に上記特許文献1の発明品を使用し、清掃を行っても、清掃後、短期間に汚れが再度付着し、例えば店舗等の様に常時外見を綺麗に保たなければならない場所では、頻繁に清掃を繰り返し行わねばならず、かかる点においては、従前の界面活性剤利用の場合と何ら変わらなかった。   However, even if the product of the above-mentioned Patent Document 1 is used for an article that easily adheres to dirt due to static electricity, such as an air conditioner such as an air conditioner, an OA machine, etc. In places where it must be re-attached and the appearance must be kept clean, such as in a store, etc., cleaning must be repeated frequently. In this respect, there is no difference from the case of using a conventional surfactant. It was.

本発明は、上記課題に鑑み、原水を逆浸透膜法により処理して活性水を生成し、該活性水に珪酸ナトリウムを配合して洗浄剤を調製し、該洗浄剤にて被清掃物品を洗浄、或いは拭き取り清掃すると共に、被清掃物品表面に珪酸ナトリウムによる被膜を形成し、該被膜により、汚れの付着を防止する様にして、上記課題を解決する。   In view of the above problems, the present invention produces raw water by treating raw water by a reverse osmosis membrane method, prepares a cleaning agent by adding sodium silicate to the active water, and cleans the article to be cleaned with the cleaning agent. In addition to cleaning or wiping and cleaning, a film made of sodium silicate is formed on the surface of the article to be cleaned, and the film solves the above problem by preventing the adhesion of dirt.

要するに本発明は、原水を逆浸透膜法により処理して活性水を生成し、該活性水に珪酸ナトリウムを配合して調製したので、かかる洗浄剤は浸透力が高く、汚れを至極簡単に除去できると共に、清掃を行うことによって、被清掃物品の表面に珪酸ナトリウム(所謂、水ガラス)の被膜を形成でき、被膜により汚れが付着し難くなって、清掃回数を減らすことが出来る。
又、水ガラスの被膜の表面は、親水性が高く、被膜表面と付着汚れの間に、通常の水でも浸透し易くなり、初回の被膜形成後の次回以降の清掃をより容易なものとすることが出来る。
又、水ガラスの被膜により、静電気の発生が減少するため、例えば、OA機器、家電品等を当該洗浄剤にて拭き取り掃除すれば、その後の汚れの付着量を激減できる。
更には、活性水に水ガラスを含有させることで、クラスターの成長が抑制され、クラスターが小さいままに維持されることから、長期間にわたり、洗浄力が維持され、使い勝手が良く、また水ガラスは人体に対し無害であるため、安全性が高く、人が接する機会の多い身の回りの物品の清掃に好適である等その実用的効果甚だ大である。
In short, since the present invention was prepared by treating raw water by a reverse osmosis membrane method to produce active water and blending the active water with sodium silicate, such a detergent has high osmotic power and removes dirt very easily. In addition, by performing cleaning, a coating of sodium silicate (so-called water glass) can be formed on the surface of the article to be cleaned, and the coating makes it difficult for dirt to adhere, thereby reducing the number of cleanings.
In addition, the surface of the water glass coating is highly hydrophilic and can easily penetrate even with normal water between the coating surface and the attached dirt, making it easier to clean the next time after the first coating is formed. I can do it.
In addition, since the generation of static electricity is reduced by the water glass coating, for example, if OA equipment, home appliances, and the like are wiped and cleaned with the cleaning agent, the amount of dirt adhered thereafter can be drastically reduced.
Furthermore, by containing water glass in the active water, the growth of clusters is suppressed and the clusters are kept small, so that the cleaning power is maintained over a long period of time and the usability is good. Since it is harmless to the human body, it is highly safe and has practical effects such as being suitable for cleaning personal items that have many opportunities for human contact.

以下、本発明の洗浄剤について詳細に説明する。
本発明の洗浄剤は、原水を逆浸透膜法により処理して活性水を生成し、該活性水に珪酸ナトリウムを配合して調製したものである。
Hereinafter, the cleaning agent of the present invention will be described in detail.
The cleaning agent of the present invention is prepared by treating raw water by a reverse osmosis membrane method to produce active water and blending the active water with sodium silicate.

原水は、蒸留水、精製水の他、通常の水道水でも良く、上記活性水とは、前記原水に圧力を加えて強制的に半透膜を透過させて得られたもの(所謂、逆浸透膜水)であり、この活性水は、原水に含有の各種イオン、極微細の浮遊微粒子等の不純物が除去され、且つ、水分子のクラスターが分断され、より小さなクラスターの水に改質されたものである。
尚、逆浸透膜装置としては、例えば、ピュアウォーター株式会社より市販のSW−150型が挙げられ、この様な市販のものの中から適宜選択し使用すれば良い。
The raw water may be ordinary tap water in addition to distilled water and purified water, and the active water is obtained by applying a pressure to the raw water to forcibly permeate the semipermeable membrane (so-called reverse osmosis). This active water is modified into water of a smaller cluster by removing impurities such as various ions contained in the raw water, ultrafine suspended particles, etc., and by dividing the water molecule cluster. Is.
In addition, as a reverse osmosis membrane apparatus, SW-150 type marketed from Pure Water, Inc. is mentioned, for example, What is necessary is just to select and use suitably from such a commercially available thing.

珪酸ナトリウムは、珪酸ソーダ又は水ガラスともいい、その種類としてはメタ珪酸ナトリウム(Na2 SiO3 )の他、オルト珪酸ナトリウム(Na4 SiO4 )、メタ二珪酸ナトリウム(Na2 Si25 )、メタ四珪酸ナトリウム(Na2 Si49 )などがあり、また無水物と水和物とがあるが、その種類は問わず、通常の市販のものを適宜選択して使用すれば良い。 Sodium silicate is also referred to as sodium silicate or water glass. As types, sodium metasilicate (Na 2 SiO 3 ), sodium orthosilicate (Na 4 SiO 4 ), sodium metadisilicate (Na 2 Si 2 O 5 ) There are sodium metatetrasilicate (Na 2 Si 4 O 9 ) and the like, and there are anhydrides and hydrates, and any ordinary commercially available one may be selected and used.

珪酸ナトリウムの配合量は、珪酸ナトリウムが5重量%未満の場合、被清掃物品に対する珪酸ナトリウム被膜の形成が困難であり、35重量%超過の場合、活性水に溶解させて安定させることが困難で沈殿を生じ易くなるため、各成分の配合としては、活性水65〜95重量%、珪酸ナトリウム5〜35重量%の範囲が良い。   When the amount of sodium silicate is less than 5% by weight, it is difficult to form a sodium silicate coating on the article to be cleaned, and when it is more than 35% by weight, it is difficult to stabilize by dissolving in active water. In order to easily cause precipitation, the composition of each component is preferably in the range of 65 to 95% by weight of active water and 5 to 35% by weight of sodium silicate.

本発明の洗浄剤は、以上の通りの構成よりなり、逆浸透膜水を主成分としているため、表面張力が小さく、浸透力が高いことから、この洗浄剤を、例えば、物品に直接多量に噴射し洗浄を行ったり、物品に少量の洗浄剤を噴霧し、布、ペーパー等で拭き取れば、至極簡単に汚れが除去され、清掃後、被清掃物品表面から逆浸透膜水は蒸散して乾燥し、被清掃物品表面には洗浄剤に含有の珪酸ナトリウムが残留し、珪酸ナトリウムの被膜が形成され、この被膜により汚れの付着が減少する。
又、逆浸透膜水に珪酸ナトリウムを含有させることで、水分子クラスターサイズの膨大化が抑制され、洗浄力が長期間にわたり維持される。
Since the cleaning agent of the present invention has the above-described configuration and is mainly composed of reverse osmosis membrane water, the surface tension is small and the osmotic power is high. By spraying and washing, spraying a small amount of cleaning agent on the article, and wiping with a cloth, paper, etc., dirt is removed very easily, and after cleaning, reverse osmosis membrane water evaporates from the surface of the article to be cleaned and is dried. However, the sodium silicate contained in the cleaning agent remains on the surface of the article to be cleaned, and a sodium silicate film is formed. This film reduces the adhesion of dirt.
In addition, by containing sodium silicate in the reverse osmosis membrane water, the enlargement of the water molecule cluster size is suppressed, and the detergency is maintained for a long period of time.

Claims (1)

原水を逆浸透膜法により処理して活性水を生成し、該活性水に珪酸ナトリウムを配合して調製したことを特徴とする洗浄剤。   A cleaning agent prepared by treating raw water by a reverse osmosis membrane method to produce active water and blending the active water with sodium silicate.
JP2008014330A 2008-01-25 2008-01-25 Detergent Pending JP2009173777A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012077344A1 (en) * 2010-12-08 2012-06-14 株式会社美都白 Method of producing a water glass coating composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08269755A (en) * 1995-03-28 1996-10-15 Hitachi Zosen Corp Method for degreasing and cleaning aluminum parts or the like
JP2001070899A (en) * 1999-09-08 2001-03-21 Pcg Tekunika:Kk Washing water
JP2005213307A (en) * 2004-01-28 2005-08-11 Try Company Cold-keeping material and method for producing the same
JP2005298232A (en) * 2004-04-07 2005-10-27 Atsuo Majima Hydrogen production system
JP2006150272A (en) * 2004-11-30 2006-06-15 Amano Corp Electrolytic water for alkali cleaning and method and apparatus for producing the same

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08269755A (en) * 1995-03-28 1996-10-15 Hitachi Zosen Corp Method for degreasing and cleaning aluminum parts or the like
JP2001070899A (en) * 1999-09-08 2001-03-21 Pcg Tekunika:Kk Washing water
JP2005213307A (en) * 2004-01-28 2005-08-11 Try Company Cold-keeping material and method for producing the same
JP2005298232A (en) * 2004-04-07 2005-10-27 Atsuo Majima Hydrogen production system
JP2006150272A (en) * 2004-11-30 2006-06-15 Amano Corp Electrolytic water for alkali cleaning and method and apparatus for producing the same

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012077344A1 (en) * 2010-12-08 2012-06-14 株式会社美都白 Method of producing a water glass coating composition
JP5098107B1 (en) * 2010-12-08 2012-12-12 株式会社アトティス Water glass paint composition

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