JP2009144288A - Textile product treatment agent composition contained in spray can - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a textile product treatment agent composition which can remove static electricity and an objectionable odor originating from sweat by only being sprayed, and has a lasting deodorizing effect and antistatic and deodorizing functions. <P>SOLUTION: The textile product treatment agent composition includes (A) a neutralized tertiary amine having one or more 8-24 C straight-chain or branched hydrocarbon groups in a molecule, one or more kinds of a cationic compound selected from the group consisting of a quaternized tertiary amine, which may be divided by an amide group, an ester group and/or an ether group, (B) a polyol compound selected from the group consisting of a polyethylene glycol and a polypropylene glycol, (C) a plant extract, and (D) filled in a spray can. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a treatment composition for textile products such as clothing. More specifically, the present invention relates to a fiber product treating agent composition that is filled in a spray container having a deodorizing function that is excellent in antistatic properties and excellent in sustainability.

In recent years, uniforms (uniforms) worn in department stores and offices are increasingly made of polyester from the viewpoint of durability and economy. These polyester fabrics are derived from the property that it is difficult to retain moisture, and have a property that they are very easily charged with static electricity. In addition, women often wear nylon stockings under a skirt made of these materials. Looking at the charged column, polyester is a material that easily charges positively, and nylon is a material that easily charges negatively. That is, it can be seen that the combination of these materials is a combination that is very likely to generate static electricity, which causes frequent static electricity troubles in department stores and offices.
On the other hand, static electricity troubles tend to be perceived as being peculiar to the dry season in winter, but as the performance of air conditioners (cooling) improves, department stores and offices change to an environment where the humidity is low and the static electricity easily occurs in the summer. ing. However, when commuting to work, commuting under high temperature and humidity, the stockings sweat, and unpleasant odors from sweat are likely to occur.
Patent Documents 2 and 3 are listed as antistatic agents for clothing, but there is no deodorizing effect. On the other hand, Patent Documents 1 and 4 are listed as compositions having a deodorizing and deodorizing effect, but the antistatic effect is particularly pronounced. Absent.

JP 2003-96667 A JP 2005-154645 A JP 2006-143852 A JP 2006-249599 A

  Therefore, the problem to be solved by the present invention is to eliminate both static electricity and sweat-related unpleasant odor at the same time by spraying. Another object of the present invention is to provide a treatment composition for textile products.

As a result of intensive studies by the present inventors to overcome the above-mentioned problems, the antistatic performance of the cationic compound is impaired by combining the specific cationic compound and the specific solvent with the plant extract. It has become clear that an excellent deodorizing function can also be achieved without ending up, leading to the present invention.
That is, the present invention is (A) a tertiary amine having one or more C8-24 linear or branched hydrocarbon groups in the molecule, which may be separated by an amide group, an ester group and / or an ether group. And one or more cationic compounds selected from the group consisting of a quaternized product of the tertiary amine,
(B) A polyol compound selected from the group consisting of polyethylene glycol and polypropylene glycol, and (C) a plant extract, and (D) a textile product treating agent composition filled in a spray container.

  The composition of the present invention has both a deodorizing property and an antistatic property excellent in sustainability, which can simultaneously erase sweat-related unpleasant odor and static electricity.

Component (A) Component (A) is usually used as a cationic surfactant, and can exhibit antistatic properties and deodorant sustainability together with component (B). The component (A) may be divided by an amide group, an ester group and / or an ether group, and has at least one C8-24, preferably C10-C18 linear or branched hydrocarbon group in the molecule. , Preferably a neutralized product of a tertiary amine having one or two, or a quaternized product of the tertiary amine. It is preferably a quaternary ammonium salt having one or two C8 to C18, preferably C10 to C18 linear or branched hydrocarbon groups that do not have a separating group in the middle. The hydrocarbon group may be saturated or unsaturated. (A) A component can be used as 1 type, or 2 or more types of mixtures.
Specific examples include neutralized products of tertiary amine compounds shown below with organic or inorganic acids, and quaternized products of the tertiary amine compounds.

R constituting the cationic surfactant is a hydrocarbon group having 8 to 24 carbon atoms, preferably 8 to 18 carbon atoms, preferably a saturated or unsaturated linear or branched group, more preferably a linear or branched alkyl group. Or an alkenyl group. When it has an unsaturated group, a cis isomer and a trans isomer are present, and the mass ratio is preferably cis / trans = 25/75 to 100/0, particularly preferably 40/60 to 80/20. Moreover, it is preferable that the ratio of a saturated and unsaturated hydrocarbon group is 95 / 5-50 / 50 (wt / wt).
R1 constituting the cationic surfactant is a residue obtained by removing a carboxyl group from a fatty acid, and is a long-chain hydrocarbon group derived from any of a saturated fatty acid, an unsaturated fatty acid, a linear fatty acid, and a branched fatty acid. . In the case of an unsaturated fatty acid, a cis isomer and a trans isomer are present, and the mass ratio is preferably cis / trans = 25/75 to 100/0, particularly preferably 40/60 to 80/20.
Examples of the fatty acid that is the basis of R and R1 include the following. Examples include stearic acid, palmitic acid, myristic acid, lauric acid, oleic acid, elaidic acid, partially hydrogenated palm oil fatty acid (iodinated 10-60), partially hydrogenated beef tallow fatty acid (iodinated 10-60), and the like. Among these, stearic acid, palmitic acid, myristic acid, oleic acid and elaidic acid are combined in a predetermined amount, the saturation / unsaturation ratio is 95/5 to 50/50 (wt / wt), and the cis / trans isomer mass ratio is 40/60 to 80/20, the iodine value is 10 to 50, the ratio of carbon number 18 is 80% by mass or more, the fatty acid having 20 carbon atoms is 2% by mass or less, and the fatty acid having 22 carbon atoms is 1% by mass or less. It is preferable to use a fatty acid composition adjusted to be. Here, R and R1 present in the formula may all be the same or different.

Examples of the acid used for neutralizing the tertiary amine include hydrochloric acid, sulfuric acid, and methyl sulfuric acid. The tertiary amine used in the present invention is preferably used in the form of an amine salt neutralized with hydrochloric acid, sulfuric acid or methyl sulfuric acid. In the neutralization step, a tertiary amine previously neutralized may be dispersed in water, or the tertiary amine may be introduced into the acid aqueous solution in liquid or solid form. Of course, a tertiary amine and an acid component may be added simultaneously. Examples of the quaternizing agent used for the quaternization of the tertiary amine include methyl chloride and dimethyl sulfate.
The compounds of the general formulas (A-IV) and (AV) can be synthesized by a condensation reaction of the above fatty acid composition or fatty acid methyl ester composition and methyldiethanolamine. At that time, from the viewpoint of improving the dispersion stability, it is preferable to synthesize so that the abundance ratio of the compounds (A-IV) and (AV) is 99/1 to 50/50 by mass ratio. Further, when the quaternized product is used, methyl chloride, dimethyl sulfate or the like is used as a quaternizing agent. However, methyl chloride is more preferable in that it has a low molecular weight and requires less quaternizing agent weight for quaternizing. preferable. At that time, the abundance ratio of the quaternized esteramine represented by (A-IV) and (AV) can be synthesized so that the mass ratio is 99/1 to 50/50 from the viewpoint of dispersion stability. preferable. When (A-IV) and (AV) are quaternized, esteramine that is not quaternized remains after the quaternization reaction. In that case, it is preferable that the ratio of the quaternized / non-quaternized ester amine is a mass ratio of 99/1 to 70/30 in terms of mass ratio from the viewpoint of hydrolysis stability of the ester group.

  Compounds of the general formulas (A-VI), (A-VII), and (A-VIII) can be synthesized by a condensation reaction of the above fatty acid composition or fatty acid methyl ester composition and triethanolamine. At that time, from the viewpoint of improving the dispersion stability, the abundance ratio of the compounds of [(A-VI) + (A-VII)] and (A-VIII) is 99/1 to 50/50 by mass ratio. It is preferable to synthesize. Further, when the quaternized product is used, methyl chloride, dimethyl sulfate or the like is used as a quaternizing agent, and dimethyl sulfate is more preferable from the viewpoint of reactivity. At that time, the abundance ratio of the quaternized product of the ester amine represented by [(A-VI) + (A-VII)] and (A-VIII) is 99/1 to 50 in mass ratio from the viewpoint of dispersion stability. It is preferable to synthesize so as to be / 50. In addition, when (A-VI), (A-VII), and (A-VIII) are quaternized, esteramine that is not quaternized generally remains after the quaternization reaction. In that case, it is preferable that the ratio of the quaternized / non-quaternized ester amine is a mass ratio of 99/1 to 70/30 in terms of mass ratio from the viewpoint of hydrolysis stability of the ester group.

The compounds represented by the general formulas (A-IX) and (AX) are known from “J. Org. Chem., 26, 3409 (1960)” from the adduct of the above fatty acid composition, N-methylethanolamine and acrylonitrile. It can be synthesized by a condensation reaction with N- (2-hydroxyethyl) -N-methyl-1,3-propylenediamine synthesized by the method. In that case, it is preferable to synthesize | combine so that the abundance ratio of the compound of (A-IX) and (AX) may become 99/1-50/50 by mass ratio. Further, when the quaternized product is used, it is quaternized with methyl chloride, but the abundance ratio of the ester amine quaternized product represented by (A-IX) and (AX) is 99/1 to 50 / by mass ratio. It is preferable to synthesize so as to be 50. When (A-IX) and (AX) are quaternized, esteramine that is not quaternized remains after the quaternization reaction. In that case, it is preferable that the ratio of the quaternized / non-quaternized ester amine is a mass ratio of 99/1 to 70/30 in terms of mass ratio from the viewpoint of hydrolysis stability of the ester group.
As the cationic surfactant that can be used in the present invention, a salt of a fatty acid amide alkyl tertiary amine derived from a higher fatty acid can be used, and the fatty acid may be saturated or unsaturated.

  Specific examples of the fatty acid amide alkyl tertiary amine include capric acid dimethylaminopropylamide, lauric acid dimethylaminopropylamide, myristic acid dimethylaminopropylamide, palmitic acid dimethylaminopropylamide, stearic acid dimethylaminopropylamide, and behenic acid. Examples thereof include fatty acid amide alkyl tertiary amines such as dimethylaminopropylamide and dimethylaminopropylamide oleate or salts thereof. Among them, since its own odor is low and good, capric acid dimethylaminopropylamide, lauric acid dimethylaminopropylamide, myristic acid dimethylaminopropylamide, palmitic acid dimethylaminopropylamide, stearic acid dimethylaminopropylamide, behenic acid Dimethylaminopropylamide and oleic acid dimethylaminopropylamide are preferred, and palmitic acid dimethylaminopropylamide and stearic acid dimethylaminopropylamide are more preferred.

Specific products of long-chain amines include, for example, Katanal MPAS-R manufactured by Toho Chemical Co., Ltd. (trade name, mixture of palmitic acid dimethylaminopropylamide and stearic acid dimethylaminopropylamide 3/7), Armin APA168-65E (trade name, 65 mass% ethanol solution of a mixture of palmitic acid dimethylaminopropylamide and stearic acid dimethylaminopropylamide in a 3/7 mass ratio) manufactured by Lion Akzo Co., Ltd. is preferably used.
The above-mentioned “fatty acid amide alkyl tertiary amine or a salt thereof” is obtained by, for example, subjecting a fatty acid or a fatty acid derivative such as a fatty acid lower alkyl ester or animal / vegetable oil and fat to a condensation reaction with a dialkylaminoalkylamine, The dialkylaminoalkylamine of the reaction is obtained by distilling off under reduced pressure or nitrogen blowing.

  Here, as the fatty acid or fatty acid derivative, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, behenic acid, erucic acid, 12-hydroxystearic acid, coconut oil fatty acid, cottonseed oil fatty acid, corn oil fatty acid Specific examples thereof include beef tallow fatty acid, palm kernel oil fatty acid, soybean oil fatty acid, linseed oil fatty acid, castor oil fatty acid, olive oil fatty acid and the like, or their methyl esters, ethyl esters, glycerides and the like. Of these, capric acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, and behenic acid are preferred because of their excellent adsorption performance to textile products in the washing and rinsing process. These fatty acids or fatty acid derivatives may be used alone or in combination of two or more.

Cationic surfactants include amine compounds represented by the above formula (AI), (A-II), (A-III), (A-VI), (A-VII) or (A-VIII). Quaternized compounds are preferred, (AI), (A-II) and (A-III) are more preferred, and (AI) and (A-III) are more preferred. Among these, quaternized amine compounds represented by formulas (AI) and (A-III), in which R is a linear saturated or unsaturated hydrocarbon group having 10 to 18 carbon atoms, are preferred. In particular, quaternized compounds of amine compounds having a total carbon number of 32 or less in the molecule are preferred, particularly didecyldimethylammonium salt and stearyltrimethylammonium salt, or a mixture thereof, and the counter ion is chloride, bromide, methyl. Sulfate and ethyl sulfate are preferred. In particular, when a water-soluble cationic compound is used, the performance can be improved because the components can be uniformly adhered, and the concentration of ethanol that can be used as a solvent can be lowered, so that the safety can be increased, and trigger spraying can be performed. It is most preferable because it can be used also in finger spray.
The amount of component (A) is preferably 2% or less, more preferably 1% or less, even more preferably 0.5% or less, preferably 0.01% or more, based on the total weight of the composition. More preferably, it is 0.02% or more, More preferably, it is 0.05% or more. Within the above range, excellent antistatic performance can be obtained, and since antibacterial properties are also high, deodorant sustainability is further improved, which is further preferable from an economical viewpoint.

(B) Component A polyol compound selected from the group consisting of polyethylene glycol and polypropylene glycol. The (B) component can release the (C) component continuously for a predetermined time together with the (A) component. It is desirable that polyethylene glycol and polypropylene glycol are liquid at room temperature. Polyethylene glycol is preferable, and polyethylene glycol having a weight average molecular weight of 100 to 1000 is particularly preferable. Furthermore, polyethylene glycol having a weight average molecular weight of more than 200 and less than 600 is more preferable. In addition, in this specification, a weight average molecular weight can be measured by the average molecular weight test of the polyethyleneglycol 300 described in Quasi-drug raw material specification 2006.
The amount of component (B) is preferably 5% or less, more preferably 4% or less, even more preferably 3% or less, preferably 0.1% or more, more preferably, based on the total weight of the composition. Is 0.2% or more, more preferably 0.4% or more. Within the above range, excellent antistatic performance can be obtained, and by supporting the component (C) that is a deodorant, the deodorant property and the deodorant sustainability are improved. There is no generation of stains or stickiness of clothing when sprayed.

(C) Component Plant Extract (C) Component can be used without any particular limitation as long as it exhibits a deodorizing effect, especially if it exhibits an effect to eliminate unpleasant odors derived from sweat. Of these, the following are preferably contained.
Mallow mushrooms, mushrooms such as Acacia catechu and gardenia, aceae mushrooms such as akebi, cruciferous plants such as ginkgo biloba, ginkgo plants such as ginkgo biloba, aquatic plants such as aristolochia, usbasaicin, urchinaceae, cashew Ursiaceae plants such as Psyllium, Psyllidaceae plants such as Psyllium, Oysters such as oysters, Gramineae plants such as sugarcane, Birch plants such as birch, Cyperaceae plants such as scallops, Orchidaceae plants such as myrrh, Coleopterous plants such as garlic, chrysanthemum, chamomile, yarrow, Arnica, tarragon, okera, gossip strawberry, fujibakama, etc. A camphoraceae such as camphor, walnut, a walnut such as walnut, a mulberry such as magwa, a hopaceae such as hopweed, pepper, and chickweed; , Arachnaceae plants such as blossoms and crows, pomegranates such as pomegranates, oaks, terminarias and other species, star anise and other shikimidae plants, perilla, rosemary, sage, basil, ogon, oregano, marjoram, black Mint, Meadow, Ginger, Thyme, Melissa, Naginata, Sevoly, Salvia, Hakka, Western mint, Dutch mint, Lavender, Scarabae, etc., Linden, etc., Linden, etc., Gazette, Sanna, Turmeric, Cardamom, Ryo Ginger family plants such as Leopard, Yakuchi, Suzuku, Soka, Honeysuckle plant such as Honeysuckle, Sugiaceae plant such as Metasequoia, Shishiudo, Celery, Dill, Ammi, Anise, Cumin, Kasamochi, Yoroigusa, Mishimasaiko, Caraway, etc. Apiaceae, Senda, Neem, etc., Apiaceae, Dianthus, Willow, etc., Acebi, Azalea, Azalea, Azalea, Azalea, Azalea, Azalea, Azalea, Acacia, Paprika Eggplants such as genus genus, genus Cranaceae such as cattle, etc., rosaceae such as Japanese cherry, owl, strawberries, ume, hawthorn, cedar, almonds, cypresses such as cypress, peasaceae such as senega, peaflies such as peafowl , Gloves, eucalyptus, allspice, etc. Tomato) plant, beech family plant such as Kercus, pine family plant such as cedar, sugi, latania, licorice, ogi, senna, ebisugua, clara and other leguminous plant, hamamelis and other witch family, salamander, yellowfin Citrus plants such as mandarin oranges, goshuyu, Mizukiaceae plants such as sanshuyu, purple plants such as purple, cypress, pinewood plants such as pinewood, barberry plants such as nanten and licorice, barberry plants such as pinewood, forsythia Asteraceae plants such as Asteraceae, Asteraceae, Alaska, Hoonoki, Ganoderma, etc., A mistletoe plant such as mistletoe, A genus plant such as a bayberry, A genus plant such as Achacha, an aloeaceae plant such as aloe, a silane, etc. Orchids and hypericum plants such as hypericum Extracts of plants like that.

Among them, Lamiaceae plants, legumes, mulberry plants, Futomidaceae plants, hypericaceae plants, camellia plants, aloeaceae plants, podaceae plants, rose family plants, cypress family plants, sphagnum family plants, aceae family Preference is given to extracts from plants, magnoliaceae plants, gramineous plants, cypress plants. Among them, extracts from Lamiaceae plants, legumes, mulberry plants, corns, hypericaceae plants, and camellia plants are preferred. In particular, rosemary (Lamiaceae), lavender (Lamiaceae), sage (Lamiaceae), Clara (Leguminosae), Magwa (Plumaceae), Eucalyptus (Pleurotus), Hypericum (Hypericaceae), Cha ( Extracts from Camellia are preferred. Most preferred are extracts from Lamiaceae plants, among which extracts from rosemary, lavender and sage are particularly preferred.
The said plant extract can be used individually by 1 type or in combination of 2 or more types as appropriate.

[Extraction method]
The plant extract used in the present invention can be extracted by a known method, or a commercially available one can be used. Examples of preferable extraction methods from these plants include the following methods.
Raw or dried raw materials can be cut and pulverized to an appropriate size, and extracted extracts or components can be used as separated and purified. Extraction can be obtained by solvent extraction by a conventional method. If the extraction solvent is harmless in use, the extract can be used as it is, or it can be appropriately concentrated extract, dried powder such as freeze-dried, -A material adjusted to a strike shape can be used.

Solvents used to obtain the plant extract include water, hydrophilic organic solvents such as alcohols such as methanol, ethanol and butanol, glycerin, 1,3-butylene glycol, diethylene glycol and dipropylene glycol. , Glycols such as propylene glycol, and hydrophobic solvents such as hexane, heptane, cyclohexane, ethyl acetate, acetone, monoterpenes, etc., one of these can be used alone or two or more can be mixed. Can be used. Among these solvents, ethanol, water, glycerin, 1,3-butylene glycol, propylene glycol, diethylene glycol, monoterpenes, and a mixture thereof are particularly preferable. Ethanol, a mixture of water and ethanol, 1,3 -Butylene glycol, a mixture of water and 1,3-butylene glycol, and a mixture of ethanol and 1,3-butylene glycol are preferred. The mixture of water and ethanol preferably has an ethanol concentration of 50 to 90% by mass, more preferably 60 to 80% by mass. The extraction treatment can be performed by a conventional method such as cold immersion, digestion, heating reflux, and percolation method. In addition to solvent extraction, an extract obtained by supercritical extraction performed by steam distillation or carbon dioxide gas in a supercritical state can be similarly performed. In addition to extracting each plant individually, it can also be extracted after mixing several species in advance. Extraction separation and purification can be performed by subjecting the extract to carbonic acid treatment, liquid-liquid distribution, column chromatography, liquid chromatography, or the like.
The blending amount of component (C) is preferably 0.1% or less, more preferably 0.01% or less, and still more preferably 0.005, based on the total weight of the composition as the extract excluding the extraction solvent. % Or less, preferably 0.000005% or more, more preferably 0.00005% or more, and further preferably 0.00025% or more. If it is within the above range, it can exert a good and lasting deodorizing effect, does not color the fiber product to be treated, and does not add extra when the effect reaches saturation. This makes it possible to suppress the economy.

(D) Spray container Specific examples of the spray container that can be used in the present invention include an aerosol spray container, a trigger spray container (direct pressure type or pressure accumulation type), and a finger spray container. Examples of the aerosol spray container include those described in JP-A-9-58765. When filling an aerosol spray container, LPG (liquefied propane gas), DME (dimethyl ether), carbon dioxide gas, nitrogen gas, nitrous oxide gas, or the like can be used as a propellant. These propellants may be used alone or in combination of two or more. Examples of the trigger spray container include those described in JP-A-9-268473, JP-A-9-256272, JP-A-10-76196, and the like. When filling and using a finger spray container, examples of the finger spray container include those described in JP-A-9-256272.
By using a composition filled in a spray container, the antistatic component and the deodorant component can be directly attached to the fiber product. It can also be used for textile products that cannot be washed at home (coats, suits, carpets, etc.), and can impart an antistatic effect and a sustained deodorizing effect by a simple method. Since the amount of adhesion is not uniform except for a spray container such as a coating container, the drying speed is not preferable in terms of dispersion performance.

The fiber product treating agent composition of the present invention can contain the following optional components in addition to the essential components as long as the effects of the present invention are not impaired.
[Optional component: Solvent]
The textile product treating agent composition of the present invention can be used by dissolving in any solvent. Among these, from the viewpoint of safety, it is preferable to use it by dissolving it in an ethanol aqueous solution in which the mass ratio of ethanol to water is in the range of ethanol: water = 80: 20 to 10:90.
The water is preferably water from which hardness components such as calcium and magnesium present in trace amounts and heavy metals such as iron are removed, and ion-exchanged water or distilled water can be used.
[Optional ingredients: perfume composition]
Although it does not specifically limit as a fragrance | flavor, The list | wrist of the fragrance | flavor raw material which can be used is various literature, for example, "Perfume and Flavor Chemicals", Vol. Iand II, Steffen Arctander, Allured Pub. Co. (1994) and "Synthetic fragrance chemistry and commercial knowledge", Motoichi Into, Chemical Industry Daily (1996) and "Perfume and Flavor Materials of Natural Origin", Stephen Arctander, Allred Pub. Co. (1994) and "Encyclopedia of Scents", edited by Japan Fragrance Association, Asakura Shoten (1989) and "Performer Material Performance V.3.3", Boelens Aroma Chemical Information Service (1996) and "Flower oil". , Danute Lajaujis An
onis, Allured Pub. Co. (1993), etc., each of which is incorporated herein by reference.

[Optional component: Silicone compound]
As the silicone compound used in the present invention, any of modified and unmodified silicones can be used. Unmodified dimethyl silicone, amino-modified silicone, amino / polyether-modified silicone, amide-modified silicone, amide / polyether-modified silicone, Silicones selected from alkyl-modified silicones, alkyl-polyether-modified silicones, and polyether-modified silicones are preferred, and polyether-modified silicones and dimethyl silicones are more preferred. Particularly preferred is a polyether-modified silicone.
In the case of a modified silicone, the modification site of various modification groups with respect to the siloxane skeleton may be either a side chain portion or a portion in which the main chain is partially broken, but those having a modification group in the side chain are more preferable. . In any case, the most terminal of the main chain is preferably a methyl group, a hydroxyl group, or a hydrogen atom.
Of these, polyether-modified silicones represented by the following general formula (I) are most preferable.

In the formula (I), -Z is independently -R, -O-R, -OH, -O-X-R, or -O-X-H, and R may be the same or different, All are saturated or unsaturated linear or branched hydrocarbon groups having 1 to 4 carbon atoms. -Z is preferably -R or -OH, and R is preferably a saturated hydrocarbon group (alkyl group) such as a methyl group, an ethyl group, a propyl group, or a butyl group, and more preferably a methyl group.
X is a polyoxyalkylene group. Specific examples include polyoxyethylene, polyoxypropylene, polyoxybutylene groups, etc., and one of these may be added, or an oxyethylene unit, oxypropylene unit, or oxybutylene. Different types of oxyalkylene groups such as units may be arranged in blocks or randomly. However, in any case, the mass ratio of the polyoxyethylene chain portion in X is preferably 10 to 50 mass%, more preferably 15 to 45 mass%, based on the mass of the whole molecule, Preferably it is 20-35 mass%.

—Y is —R 1 —O—X—R 2 or —O—X—R 2, R 1 is a saturated or unsaturated linear or branched hydrocarbon group having 1 to 4 carbon atoms, and R 2 is a hydrogen atom Or it is a C1-C4 saturated or unsaturated linear or branched hydrocarbon group. Here, R 1 is a saturated or unsaturated linear or branched hydrocarbon group having 1 to 4 carbon atoms, and among them, a saturated hydrocarbon group such as methylene group, ethylene group, propylene group, butylene group (alkylene). Group) is preferable, and a propylene group is particularly preferable among them. R2 is a hydrogen atom or a saturated or unsaturated linear or branched hydrocarbon group having 1 to 4 carbon atoms, and among them, a saturated hydrocarbon such as a hydrogen atom, a methyl group, an ethyl group, a propyl group, or a butyl group A group (alkyl group) is preferred. Particularly preferred R2 is a hydrogen atom or a methyl group.
L, M, and N all represent the average value of the number of each repeating unit. L is 0-50, preferably 0-10, more preferably 0-3, M is 1-1000, preferably 1-300, more preferably 1-50, and N is 10-10000, preferably It is 20 to 3000, more preferably 20 to 500. The modified silicone represented by the general formula (I) may have a block copolymer structure in which each repeating unit is arranged in a block shape, or each repeating unit is randomly arranged. It may have a random copolymer structure.

The molecular weight of the modified silicone used as an optional component of the present invention is not particularly limited, but the weight average molecular weight is preferably in the range of 500 to 1,000,000.
Specific examples of commercially available polyether-modified silicones that can be used in the present invention include SH3772M, SH3775M, SH3748, SH3749, SF8410, SH8700, BY22-008, SF8421, manufactured by Toray Dow Corning Co., Ltd. SILWET L-7001, SILWET L-7002, SILWET L-7602, SILWET L-7604, SILWET FZ-2104, SILWET FZ-2120, SILWET FZ-2161, SILWET FZ-2162, SILWET FZ-2164, SILW17F ABN SILWET FZ-F1-009-01, ABN SILWET FZ-F1-009-02, ABN SILWET FZ-F1-009-03, ABN S LWET FZ-F1-009-05, ABN SILWET FZ-F1-009-09, ABN SILWET FZ-F1-009-11, ABN SILWET FZ-F1-009-13, ABN SILWET FZ-F1-009-54, ABN SILWET FZ-2222, KF352A, KF6008, KF615A, KF6016, KF6017 manufactured by Shin-Etsu Chemical Co., Ltd., TSF4450, TSF4452 manufactured by GE Toshiba Silicone Co., Ltd., and the like are used alone or in combination of two or more. It can be used as a mixture.
The compounding amount of the above components in the composition of the present invention is not particularly limited, and is usually preferably 0.05 to 20% by mass, more preferably 0.2 to 10% by mass, based on the total amount of the composition. Particularly preferably, 0.5 to 5% by mass can be blended.

[Optional ingredients: Antioxidants]
In the present invention, an antioxidant can be added to improve the aroma stability and color tone stability of the composition. As the antioxidant, generally known natural antioxidants and synthetic antioxidants can be used. Specifically, a mixture of ascorbic acid, ascorbyl palmitate, propyl gallate, BHT (butylated hydroxytoluene), BHA (butylated hydroxyanisole), propyl gallate, and citric acid, hydroquinone, tertiary butylhydroquinone Natural tocopherol compounds, long-chain esters of gallic acid (C8 to C22) such as dodecyl gallate, irganox compounds available from Ciba Specialty Chemicals, citric acid and / or isopropyl citrate, 1- Hydroxyethylidene-1,1-diphosphonic acid (etidronic acid), 4,5-dihydroxy-m-benzenesulfonic acid / sodium salt, dimethoxyphenol, catechol, methoxyphenol, carotenoid, furans, amino acids, etc. That.
Among these, BHT (butylated hydroxytoluene), methoxyphenol, tocopherol compounds, and the like are preferable from the viewpoint of the appearance and storage stability of the composition. It is preferable that the compounding quantity of antioxidant is used in 0.001-1 mass%.

[Optional ingredient: pH adjuster]
As necessary, hydrochloric acid, sulfuric acid, phosphoric acid, alkyl sulfuric acid, benzoic acid, paratoluenesulfonic acid, citric acid, malic acid, succinic acid, lactic acid, glycolic acid, hydroxyethanediphosphonic acid, phytic acid, ethylenediaminetetraacetic acid, PH adjustment of short chain amine compounds such as triethanolamine, diethanolamine, dimethylamine, N-methylethanolamine, N-methyldiethanolamine, alkali metal hydroxides such as sodium hydroxide, alkali metal carbonates, and alkali metal silicates An agent can be used.

The pH of the textile product treating agent composition of the present invention is preferably weak acid to neutral from the viewpoint of safety.
The viscosity of the fiber product treating agent composition of the present invention is 10 mPa · s (BL viscometer, manufactured by TOKIMEC, rotor No. 1, 60 rpm, 25 ° C.) or less from the viewpoint of dischargeability when discharged from the container. Is preferable, and 5 mPa · s or less is more preferable.
The fiber to which the fiber product treating agent composition of the present invention is applied is not particularly limited, and synthetic fibers such as polyester, nylon, and acrylic, semi-synthetic fibers such as acetate, and regenerated fibers such as rayon, tencel, and polynosic. It can be used for a wide range of applications such as natural fibers such as cotton, wool and silk, and blended products, blended fabrics and blended products of these various fibers.

Table 1 shows the components used in Examples and Comparative Examples.

[Preparation of fiber product treating agent composition]
The fiber product treating agent composition was prepared by stirring and mixing the components shown in Tables 2 to 4 at room temperature. The textile product treating agent composition was filled into an aerosol can, and after clinching (closed can), a predetermined amount of a propellant gas was filled to obtain a treating agent composition for a textile product filled with a spray container. As the propellant gas, a mixed gas of DME: LPG = 60: 40 (mass ratio) was used, and the mixture was filled in a mass ratio of 50 g in the ratio of the mixed gas 35 to the textile product treating agent composition 65.
The treatment composition for textiles obtained in the same manner was filled into a trigger spray container or a finger spray container to obtain a treatment composition for textiles obtained by filling the spray container.
The fiber product treating agent composition filled in the spray container thus obtained was used to evaluate the deodorizing performance and antistatic properties described below. The results are shown in Tables 2-4.
In addition, in the table | surface of an Example, the compounding quantity of (C) component represents the density | concentration as an extract part.

[Containers used in Examples and Comparative Examples]
・ Aerosol container:
Can: Aluminum Aluminum BL45 × 150 (B2 reform coat) (Toyo Seikan Co., Ltd.)
Valve: DY02-H04222xC128R (manufactured by Toyo Aerosol)
Button: MB-8N09
・ Trigger spray:
Trigger type finger spray for style guard suit (trade name, manufactured by Lion Corporation):
Dispenser type for style guard suit (trade name, manufactured by Lion Corporation)

[Deodorization performance evaluation method]
After wearing nylon stockings, they exercised in the training room for 1 hour to sweat, and the stockings with sweat attached were collected. The collected stockings cut into 10 cm × 10 cm were placed in a plastic bag and allowed to stand overnight to obtain a model odor test cloth.
The model odor test cloth is uniformly sprayed with 1 g of the above-prepared textile product treating agent composition, left in the room for 1 hour and 24 hours, and then subjected to a sensory pair comparison with 10 panelists. Odor evaluation was performed based on the standard. A control model was a model odor test cloth after the fiber composition treating agent composition was left unsprayed for 1 hour and 24 hours.
Criterion +2: No odor apparently compared to the control
+1: It does not smell a little compared to the control
0: almost the same as the control
-1: The control does not smell a little
-2: The control does not clearly smell The average of the scores is taken, 1.1 to 2.0 points are ◎, 0.1 to 1.0 points are ◯, -1.0 to 0 points are △, -1.1 point or less was made x. Note that Δ or more was regarded as an allowable range. The evaluation after 1 hour was regarded as the deodorant property, and the evaluation after 24 hours was regarded as the deodorant sustainability result.

[Antistatic evaluation method: half-life measurement]
A commercially available polyester satin was used as a test cloth. The test fabric is cut into 30 cm × 30 cm, and the prepared fiber product treating agent composition is uniformly sprayed by aerosol spray, trigger sprayer or finger spray so that the composition becomes 1 g on the test fabric. It was adjusted. Humidity is adjusted for 24 hours at 20 ° C. and 20% RH, and then the half-life is measured according to JIS-L-1094-1997 (half-life measurement method) using STATIC HONESTEMETER TYPES-5109 (manufactured by Sisid Electrostatic Co., Ltd.) And judged according to the following criteria.
Judgment criteria A: Half-life less than 2 seconds
○: Half-life 2 seconds or more and less than 5 seconds
Δ: Half-life 5 seconds or more and less than 30 seconds
X: Half-life 30 seconds or more In addition, let Δ or more be the allowable range.

Claims (6)

(A) A neutralized product of a tertiary amine which has one or more C8-24 linear or branched hydrocarbon groups in the molecule, which may be separated by an amide group, an ester group and / or an ether group, And one or more cationic compounds selected from the group consisting of quaternized products of the tertiary amines,
(B) A polyol compound selected from the group consisting of polyethylene glycol and polypropylene glycol, and (C) a plant extract, and (D) a fiber product treating agent composition filled in a spray container.   The textile product treatment according to claim 1, wherein the compound (A) is a quaternized product of a tertiary amine having one or two C8 to C18 linear or branched hydrocarbon groups having no splitting group. Agent composition.   The textile product treating agent composition according to claim 1 or 2, wherein the polyol compound (B) is polyethylene glycol having a weight average molecular weight of 100 to 1,000.   The textile product treating agent composition according to claim 3, wherein the polyol compound (B) is polyethylene glycol having a weight average molecular weight of more than 200 and less than 600.   The plant extract (C) is a Lamiaceae plant, a legume plant, a mulberry plant, a Fusarium family plant, a Hypericaceae plant, a camellia plant, a teraceae plant, a rose family plant, a cypress family plant, or a cypress family. The textile product treating agent composition according to any one of claims 1 to 4, which is an extract of a plant selected from the group consisting of plants, oleaceae plants, magnoliaceae plants, gramineous plants, and cynoaceae plants.   The textile product treating agent composition according to claim 5, wherein the plant extract (C) is a Labiatae plant extract.