JP2009131215A - Fresh egg yolk-like processed food, method for producing the processed food, and food product utilizing the fresh egg yolk-like processed food - Google Patents

Fresh egg yolk-like processed food, method for producing the processed food, and food product utilizing the fresh egg yolk-like processed food Download PDF

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JP2009131215A
JP2009131215A JP2007310835A JP2007310835A JP2009131215A JP 2009131215 A JP2009131215 A JP 2009131215A JP 2007310835 A JP2007310835 A JP 2007310835A JP 2007310835 A JP2007310835 A JP 2007310835A JP 2009131215 A JP2009131215 A JP 2009131215A
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egg yolk
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yolk
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JP4786633B2 (en
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Hiroshi Shimura
洋 志村
Takahiko Kato
貴比古 加藤
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QP Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a fresh egg yolk-like processed food having texture closely resembling that of a fresh egg yolk coated with egg yolk membrane when treated with chopsticks or by the hands; to provide a method for producing the fresh egg yolk-like processed food; and to provide a food product utilizing the processed food. <P>SOLUTION: In the meth od for producing the yolk-like processed food, method for producing the processed food, and food product utilizing the fresh egg yolk-like processed food, the fresh egg yolk-like processed food has a part corresponding to an egg yolk membrane and formed of an alginate calcium membrane and is obtained by coating the egg yolk-like liquid with the membrane, wherein the rupture stress of the membrane is 10-100 g, the ratio of the height to the longer diameter is 1:1.8-3 when left to stand on a flat board, and the bottom surface is flat and represents a flattened spherical shape. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、箸や手で取り扱った際の質感が卵黄膜に包まれたままの生卵黄と酷似した生卵黄様加工食品及びその製造方法、並びに生卵黄様加工食品を用いた食品に関する。 The present invention relates to a raw egg yolk-like processed food whose texture when handled with chopsticks and hands is very similar to that of raw egg yolk as wrapped in an yolk membrane, a method for producing the same, and a food using the raw egg yolk-like processed food.

鶏卵等を割卵し、卵白と分離して取り出した生卵黄は、厚さ15μm程度の卵黄膜で卵黄液が包まれた球状物であり、表面を軽く押圧すると反発し、強く押圧すると卵黄膜が破れて崩れる特有の質感を有する。 Raw egg yolk, which is obtained by splitting chicken eggs, etc. and separated from egg white, is a spherical material in which the yolk liquid is wrapped in an egg yolk membrane with a thickness of about 15 μm. Has a peculiar texture that breaks and collapses.

このような卵黄膜につつまれたまま生卵黄は、鮮やかな黄色い色調であることに加えて、箸等で崩した時に卵黄液が流れ出す状態変化が目を引くことから、食事の楽しさを演出する素材として種々の料理に使用されている。このような料理としては、例えば、卵を卵黄膜を崩さないようにそのまま割り入れた蕎麦やうどん等や、卵白と分けた生卵黄を卵黄膜を崩さずにトッピングしたトロロやユッケ等の料理が挙げられる。 In addition to being vivid yellow, the raw egg yolk is surrounded by the yolk membrane, and the change in the state in which the yolk liquid flows out when broken with chopsticks, etc. draws attention, creating the enjoyment of meals As a material to be used in various dishes. Examples of such dishes include dishes such as buckwheat and udon that have been cut into eggs so as not to disrupt the yolk membrane, and dishes such as Tororo and Yukke topped with raw egg yolk separated from egg white without breaking the yolk membrane. Can be mentioned.

一方、卵黄は、良質の蛋白質や脂質を含み栄養価の高い食品であるものの、高脂血症体質や腎臓病患者等の人は、コレステロールや蛋白質等の摂取量を制限しなければならない場合がある。そのような場合に用いる卵製品として、例えば、特開2001−157560号公報(特許文献1)には、低コレステロール乾燥卵黄を用いた成分調整された卵製品が提案されている。そこで、このような成分調整した卵製品についても、卵黄膜につつまれたままの生卵黄と似た形で提供することができれば、料理素材としての使用の幅が広がり大変好ましい。 On the other hand, egg yolk is a highly nutritious food containing high-quality proteins and lipids, but people with hyperlipidemia or kidney disease may have to limit their intake of cholesterol, protein, etc. is there. As an egg product used in such a case, for example, JP 2001-157560 A (Patent Document 1) proposes an egg product in which components are adjusted using low cholesterol dry egg yolk. Thus, if such an egg product prepared with ingredients adjusted can be provided in a form similar to raw egg yolk as it is wrapped in the yolk membrane, the range of use as a cooking material is greatly increased.

従来、卵黄膜につつまれたままの卵黄を模した食品としては、特開平3−43046号公報(特許文献2)に特定量の卵白を含む乳化液をアルギン酸カルシウム皮膜で被覆した卵黄代替物が提案されている。この卵黄代替物は、具体的には、前記乳化液を球状に凍結した後、これをカルシウム溶液及びアルギン酸溶液に順次浸漬して表層をアルギン酸カルシウムで覆うことにより製造される。しかしながら、この特許文献2記載の卵黄代替物は、加熱凝固させて用いることが前提とされており、未凝固の段階ではアルギン酸皮膜が不均一に形成された不自然な外観であり、取り扱いにより壊れ易く生卵黄の代替品としては使用できるものではなかった。 Conventionally, as a food imitating an egg yolk as it is encased in the yolk membrane, JP-A-3-43046 (Patent Document 2) describes an egg yolk substitute in which an emulsion containing a specific amount of egg white is coated with a calcium alginate film. Proposed. Specifically, the egg yolk substitute is produced by freezing the emulsion into a spherical shape, and subsequently immersing the emulsion in a calcium solution and an alginic acid solution and covering the surface layer with calcium alginate. However, it is assumed that the egg yolk substitute described in Patent Document 2 is heated and coagulated, and has an unnatural appearance in which an alginic acid film is formed unevenly at an uncoagulated stage, and is broken by handling. It was not easy to use as a substitute for raw egg yolk.

特開2001−157560号公報JP 2001-157560 A 特開平3−43046号公報JP-A-3-43046

そこで、本発明は、箸や手で取り扱った際の質感が卵黄膜に包まれたままの生卵黄と酷似した生卵黄様加工食品及びその製造方法、並びに生卵黄様加工食品を用いた食品を提供することを課題とする。 Therefore, the present invention provides a raw egg yolk-like processed food that closely resembles raw egg yolk with a texture when handled with chopsticks and hands, a method for producing the same, and a food using the raw egg yolk-like processed food. The issue is to provide.

本発明者等は、上記目的を達成するため鋭意研究を行った結果、アルギン酸アルカリ金属水溶液とカルシウムイオン含有水溶液を接触させるとアルギン酸カルシウムが形成する反応を利用し、当該接触反応を半球状カップを用いた特定の方法で行うことにより、アルギン酸カルシウム皮膜で卵黄様液が被覆された生卵黄様物が得られることを見出した。そして、製造条件を調整するならば、意外にも、皮膜が適度な柔軟性を有することと、平板上に静置した場合に底面が平らな扁平球形状を呈することの両者を満たした生卵黄と同じ特性の生卵黄様加工食品が得られ、当該生卵黄様加工食品は、箸や手で取り扱った際の質感が生卵黄と酷似したものとなることを見出し、遂に本発明を完成するに至った。 As a result of intensive studies to achieve the above object, the present inventors have utilized a reaction formed by calcium alginate when an alkali metal alginate aqueous solution and a calcium ion-containing aqueous solution are brought into contact with each other. It has been found that a raw egg yolk-like product in which an egg yolk-like liquid is coated with a calcium alginate film can be obtained by the specific method used. And if the production conditions are adjusted, surprisingly, the raw egg yolk satisfying both that the film has an appropriate flexibility and that it has a flat spherical shape with a flat bottom when left on a flat plate. In order to complete the present invention, it was found that the processed raw egg yolk-like food has the same characteristics as the raw egg yolk-like processed food, and the texture of the raw egg yolk-like processed food is very similar to that of raw egg yolk. It came.

すなわち、本発明は、
(1) アルギン酸カルシウム皮膜からなる卵黄膜相当部を有し、当該皮膜にて卵黄様液を内包する生卵黄様加工食品であって、前記皮膜の破断応力が10〜100gであり、平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈する生卵黄様加工食品、
(2) 前記卵黄様液の粘度が1〜30Pa・sである(1)記載の生卵黄様加工食品、
(3) 質量が3〜30gである(1)又は(2)記載の生卵黄様加工食品、
(4) (1)乃至(3)のいずれかに記載の生卵黄様加工食品を用いた食品。
(5) (1)乃至(3)のいずれかに記載の生卵黄様加工食品を液卵白に浸漬した卵液様加工食品、
(6) アルギン酸カルシウム皮膜からなる卵黄膜相当部を有し、当該皮膜にて卵黄様液を内包する生卵黄様加工食品の製造方法であって、アルギン酸アルカリ金属水溶液中に浸漬した半球状カップ内に、カルシウムイオンを含有する卵黄様液を充填し、次いで、前記卵黄様液を充填した半球状カップを揺動させながらアルギン酸アルカリ金属水溶液中に保持することにより、前記卵黄様液表面に破断応力が10〜100gであるアルギン酸カルシウム皮膜を形成させ、得られる生卵黄様加工食品が平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈するように成形する生卵黄様加工食品の製造方法、
(7) 前記半球状カップに多孔が設けてある(6)記載の生卵黄様加工食品の製造方法、
(8) 前記卵黄様液の粘度が1〜30Pa・sである(6)又は(7)記載の生卵黄様加工食品の製造方法、
である。
That is, the present invention
(1) A raw egg yolk-like processed food having an egg yolk membrane-corresponding portion made of a calcium alginate film and enclosing an egg yolk-like liquid in the film, the breaking stress of the film being 10 to 100 g, A raw egg yolk-like processed food that has a flat spherical shape with a flat bottom having a ratio of height to major axis of 1: 1.8 to 3 when left standing,
(2) The raw egg yolk-like processed food according to (1), wherein the egg yolk-like liquid has a viscosity of 1 to 30 Pa · s,
(3) Raw egg yolk-like processed food according to (1) or (2), having a mass of 3 to 30 g,
(4) A food using the raw yolk-like processed food according to any one of (1) to (3).
(5) An egg liquid-like processed food obtained by immersing the raw egg yolk-like processed food according to any one of (1) to (3) in liquid egg white,
(6) A method for producing a raw egg yolk-like processed food having an egg yolk membrane equivalent part composed of a calcium alginate film and encapsulating an egg yolk-like liquid in the film, wherein the inside of the hemispherical cup immersed in an aqueous alkali metal alginate solution The egg yolk-like liquid containing calcium ions is then filled, and then the hemispherical cup filled with the egg yolk-like liquid is held in an aqueous solution of alkali metal alginate while rocking, thereby breaking stress on the surface of the egg yolk-like liquid. When the resulting raw egg yolk-like processed food is allowed to stand on a flat plate, a flat spherical shape having a flat bottom with a ratio of height to major axis of 1: 1.8 to 3 is formed. A method for producing raw egg yolk-like processed food that is shaped to present
(7) The method for producing a raw egg yolk-like processed food according to (6), wherein the hemispherical cup is porous.
(8) The method for producing a raw egg yolk-like processed food according to (6) or (7), wherein the viscosity of the egg yolk-like liquid is 1 to 30 Pa · s,
It is.

本発明の生卵黄様加工食品は、箸や手で取り扱った際の質感が生卵黄と酷似したものである。そして、内包する卵黄様液として、種々の原料を選択して用いることができることから、栄養成分を調整したり保存性を持たせたりすることが可能である。このような本発明の生卵黄様加工食品を、病院等の事業所給食、レストラン、コンビニエンスストア等に提供することで、これらの食事のメニューの多様化や、付加価値の増大に貢献できる。 The raw egg yolk-like processed food of the present invention is very similar in texture to raw egg yolk when handled with chopsticks or hands. And since various raw materials can be selected and used as the egg yolk-like liquid to be included, it is possible to adjust the nutritional components and to have storage stability. By providing such raw egg yolk-like processed food of the present invention to establishments such as hospitals, restaurants, convenience stores, etc., it is possible to contribute to diversification of menus of these meals and increase in added value.

以下、図面を参照しつつ、本発明を詳細に説明する。また、特にことわりのない限り「部」は質量部を意味し、「%」は質量%を意味する。 Hereinafter, the present invention will be described in detail with reference to the drawings. Unless otherwise specified, “part” means part by mass, and “%” means mass%.

本発明において、生卵黄様加工食品とは、鶏、家鴨、鶉等の卵黄膜につつまれたままの生卵黄を模した加工食品をいう。鶏卵や家鴨卵の生卵黄は、通常10〜30g程度、鶉卵の生卵黄は、通常3〜6g程度であることから、本発明の生卵黄様加工食品の質量は、具体的には、好ましくは3〜30gである。 In the present invention, the raw egg yolk-like processed food refers to processed food imitating raw egg yolk as it is encased in an egg yolk membrane such as chicken, domestic duck, and salmon. Since the raw egg yolk of chicken eggs and duck eggs is usually about 10-30 g, and the raw egg yolk of eggplant eggs is usually about 3-6 g, the mass of the raw egg yolk-like processed food of the present invention is specifically preferably Is 3 to 30 g.

本発明の生卵黄様加工食品は、アルギン酸カルシウム皮膜からなる卵黄膜相当部を有し、当該皮膜にて卵黄様液が内包されていることを特徴とする。このような本発明の生卵黄様加工食品の一実施例としては、図1に示すような生卵黄様加工食品1が挙げられる。図1は、平板4上に静置した状態の生卵黄様加工食品1の平面図及び側面図を示し、図中、符号2はアルギン酸カルシウム皮膜、3は卵黄様液を示している。 The raw egg yolk-like processed food of the present invention has an egg yolk membrane equivalent part composed of a calcium alginate film, and the egg yolk-like liquid is included in the film. As an example of such a raw egg yolk-like processed food of the present invention, there is a raw egg yolk-like processed food 1 as shown in FIG. FIG. 1 shows a plan view and a side view of a raw egg yolk-like processed food 1 in a state of standing on a flat plate 4, in which 2 indicates a calcium alginate film and 3 indicates an egg yolk-like liquid.

本発明において、卵黄膜相当部を構成する前記アルギン酸カルシウム皮膜とは、アルギン酸アルカリ金属とカルシウムイオンの接触反応により形成されるアルギン酸カルシウムを主成分とする生卵黄様加工食品の最外層の薄膜をいう。皮膜の厚さは具体的には後述の製法により、好ましくは100μm〜3mm、より好ましくは100μm〜2mmとしてある。 In the present invention, the calcium alginate film constituting the egg yolk membrane-corresponding portion refers to a thin film of the outermost layer of a raw egg yolk-like processed food mainly composed of calcium alginate formed by a contact reaction between an alkali metal alginate and calcium ions. . Specifically, the thickness of the film is preferably 100 μm to 3 mm, more preferably 100 μm to 2 mm, according to the manufacturing method described later.

なお、本発明における前記アルギン酸カルシウム皮膜とは、アルギン酸カルシウムのみからなる皮膜ばかりでなく、アルギン酸カルシウムに加えて他の皮膜構成成分が混在している皮膜も含む。ここで他の皮膜構成成分とは、アルギン酸のカルシウム塩以外の多価金属塩、例えば、マグネシウム塩、アルミニウム塩等や、カルシウム等の二価のアルカリ土類金属でゲル化したペクチン等が挙げられる。 In addition, the said calcium alginate film | membrane in this invention includes not only the film | membrane which consists only of calcium alginate but the film | membrane in which another film | membrane structural component is mixed in addition to calcium alginate. Examples of other film constituents include polyvalent metal salts other than calcium salts of alginic acid, such as magnesium salts and aluminum salts, and pectin gelled with divalent alkaline earth metals such as calcium. .

アルギン酸カルシウム皮膜を得るために用いるアルギン酸アルカリ金属とは、多糖類として褐藻類に多く含まれるアルギン酸の塩類をいい、例えばアルギン酸ナトリウム、アルギン酸カリウム等をいう。また、本発明においては、カルシウムイオンを供するための水溶性カルシウム塩を用いるが、当該水溶性カルシウム塩としては、食用可能な水に溶解する性質を有するカルシウム塩であれば特に制限は無く、例えば、塩化カルシウム、乳酸カルシウム、グルコン酸カルシウム或いはこれらの化合物の水和物等が挙げられる。 The alkali metal alginate used for obtaining a calcium alginate film refers to a salt of alginic acid that is abundant in brown algae as a polysaccharide, such as sodium alginate and potassium alginate. In the present invention, a water-soluble calcium salt for providing calcium ions is used, and the water-soluble calcium salt is not particularly limited as long as it is a calcium salt having a property of being dissolved in edible water. , Calcium chloride, calcium lactate, calcium gluconate or hydrates of these compounds.

上述したように本発明の生卵黄様加工食品は、アルギン酸カルシウム皮膜からなる卵黄膜相当部を有し、当該皮膜にて卵黄様液が内包されているものであるが、更に、本発明の生卵黄様加工食品は、皮膜が適度な柔軟性を有することと、平板上に静置した場合に底面が平らな扁平球形状を呈することの両者を満たしていて生卵黄と同じ特性であることを特徴とする。すなわち、本発明の生卵黄様加工食品は、前記皮膜の破断応力が10〜100g、好ましくは10〜80gであり、平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈することを特徴とする。 As described above, the raw egg yolk-like processed food of the present invention has an egg yolk membrane equivalent part composed of a calcium alginate film, and the egg yolk-like liquid is included in the film. Egg yolk-like processed foods have the same characteristics as raw egg yolk, satisfying both that the film has moderate flexibility and that it has a flat spherical shape with a flat bottom when placed on a flat plate. Features. That is, the raw egg yolk-like processed food of the present invention has a breaking stress of the film of 10 to 100 g, preferably 10 to 80 g, and the ratio of height to major axis when standing on a flat plate is 1: 1.8 to 3 has a flat sphere shape with a flat bottom surface.

ここで、前記皮膜の破断応力とは、FUDOH
RHEO METER NRM-2010J-CW((株)レオテック製)を用い、球形Φ6mmプランジャーを使用し、テーブル上昇速度6cm/分の条件で破断応力を測定した値である。具体的には、測定テーブルに品温20℃の生卵黄様加工食品を載せ、上面の略中心部分の破断応力を測定した値である。
Here, the breaking stress of the film is FUDOH
RHEO METER NRM-2010J-CW (manufactured by Rheotech Co., Ltd.) is used, a spherical Φ6 mm plunger is used, and the breaking stress is measured at a table ascending speed of 6 cm / min. Specifically, it is a value obtained by placing a raw egg yolk-like processed food with a product temperature of 20 ° C. on the measurement table and measuring the breaking stress at the substantially central portion of the upper surface.

また、平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈することは、品温20℃の生卵黄様加工食品を平板上に静置することにより評価できる。ここで、前記扁平球形状とは、図1の平面図に示すように平面視した場合に略円形である扁平な球形状をいい、底面が平らであるとは、図1の側面図に示すように平板4上に静置した場合の生卵黄様加工食品1の底面、つまり、平板4との接触面が平らであることをいう。更に、生卵黄様加工食品1を平板4上に静置した場合の高さとは、前記側面図に示される生卵黄様加工食品1の高さが最も高い部分であるαの長さであり、長径とは生卵黄様加工食品1の最も径が長い部分であるβの長さである。 Moreover, when it is left on a flat plate, the ratio of height to major axis is 1: 1.8 to 3 and the bottom surface is flat and flat, so that a raw egg yolk-like processed food with a product temperature of 20 ° C. is placed on the flat plate. It can be evaluated by standing still. Here, the flat sphere shape means a flat sphere shape that is substantially circular when viewed in plan as shown in the plan view of FIG. 1, and that the bottom surface is flat is shown in the side view of FIG. Thus, the bottom surface of the raw yolk-like processed food 1 when placed on the flat plate 4, that is, the contact surface with the flat plate 4 is flat. Furthermore, the height when the raw yolk-like processed food 1 is left on the flat plate 4 is the length of α, which is the highest part of the raw yolk-like processed food 1 shown in the side view, The major axis is the length of β which is the longest part of the raw yolk-like processed food 1.

このように、本発明の生卵黄様加工食品は、皮膜が適度な柔軟性を有することと、平板上に静置した場合に底面が平らな扁平球形状を呈することとの両者を満たしていて生卵黄と同じ特性であることから、箸や手で取り扱った際の質感が生卵黄と酷似したものとなる。特に、平板上での高さと長径の比が1:2〜1:2.8であると、箸で挟んだ際の質感が生卵黄と大変よく似たものとなりより好ましい。 In this way, the raw egg yolk-like processed food of the present invention satisfies both of the fact that the film has appropriate flexibility and that it has a flat spherical shape with a flat bottom when left on a flat plate. Because it has the same characteristics as raw egg yolk, the texture when handled with chopsticks or hand is very similar to that of raw egg yolk. In particular, it is more preferable that the ratio of the height to the major axis on the flat plate is 1: 2 to 1: 2.8 because the texture when sandwiched with chopsticks is very similar to that of raw egg yolk.

これに対して、例えば、後述の試験例に示すように、平板上での高さと長径の比が前記範囲であったとしても、皮膜の破断応力が前記特定範囲より高い場合は、箸で挟んだ際の弾力が強すぎ、箸で押圧した際に崩れ難く、対照の生卵黄と似た質感とならない。一方、皮膜の破断応力が前記特定範囲であったとしても、平板上での高さを1とした際の長径が3より大きい場合は、箸で挟んだ際の弾力が弱すぎて対照の生卵黄と似た質感とならない。 On the other hand, for example, as shown in a test example to be described later, even if the ratio of the height to the major axis on the flat plate is in the above range, if the breaking stress of the film is higher than the specific range, it is sandwiched with chopsticks. Its elasticity is too strong, it is hard to collapse when pressed with chopsticks, and it does not look like a raw egg yolk as a control. On the other hand, even if the breaking stress of the film is within the above specified range, if the major axis when the height on the flat plate is 1 is larger than 3, the elasticity when sandwiched between the chopsticks is too weak and the control is It does not look like egg yolk.

卵黄膜で卵黄液が包まれた生卵黄は、卵黄膜が適度な柔軟性を有し、平板上に静置した場合に底面が平らな扁平球形状を呈する特性を有しているが、アルギン酸カルシウム皮膜で卵黄様液を内包した本発明の生卵黄様加工食品も後述する製法により同様の性質とすることができる。このように同じ特性とすることができる理由は定かではないが、蛋白質を主成分とする卵黄膜と本発明で用いるアルギン酸カルシウム皮膜との間に伸展性や強度等の性質にある程度共通点があるためではないかと考えられる。 Raw egg yolk wrapped in yolk fluid with yolk membrane has a characteristic that the yolk membrane has moderate flexibility and a flat spherical shape with a flat bottom when left on a flat plate. The raw egg yolk-like processed food of the present invention in which the egg yolk-like liquid is encapsulated with a calcium film can be made to have similar properties by the production method described later. The reason why the same characteristics can be obtained is not clear, but there are some common points in properties such as extensibility and strength between the yolk membrane mainly composed of protein and the calcium alginate film used in the present invention. This is probably because of this.

一方、本発明における前記卵黄様液とは、生液卵黄を模した溶液をいい、本発明の卵黄様液はその粘度が好ましくは1〜30Pa・sである。粘度を前記特定範囲とすることにより、箸や手で取り扱った際の質感をより生卵黄と酷似したものとすることができる。特に、卵黄様液の粘度が1〜10Pa・sである場合は、箸で挟んだ際の質感が生卵黄と大変よく似たものとなり好ましい。なお、卵黄様液の粘度が1〜30Pa・sであると後述のアルギン酸アルカリ金属液中への浸漬工程において成形がし易い点からも好ましい。 On the other hand, the egg yolk-like liquid in the present invention refers to a solution that imitates a raw liquid egg yolk, and the viscosity of the egg yolk-like liquid of the present invention is preferably 1 to 30 Pa · s. By setting the viscosity within the specific range, the texture when handled with chopsticks or hands can be made more similar to that of raw egg yolk. In particular, when the viscosity of the egg yolk-like liquid is 1 to 10 Pa · s, the texture when sandwiched with chopsticks is very similar to that of raw egg yolk, which is preferable. In addition, it is preferable also from the point which is easy to shape | mold in the immersion process in the below-mentioned alkali metal alginate liquid as the viscosity of an egg yolk-like liquid is 1-30 Pa.s.

ここで、卵黄様液の粘度は、当該卵黄様液をBH型粘度計で、品温20℃、回転数10rpmの条件で、粘度が0.8Pa・s未満のときローターNo.1、0.8Pa・s以上3Pa・s未満のときローターNo.2、3Pa・s以上7Pa・s未満のときローターNo.3、7Pa・s以上14Pa・s未満のときローターNo.4、14Pa・s以上のときローターNo.5を使用し、測定開始後ローターが3回転した時の示度により求めた値である。なお、製品(生卵黄様加工食品)1個当たりに含まれる卵黄様液の量は3〜30gであり、量が少なくて前記方法による粘度測定が困難であるが、多数の製品から卵黄様液を取り出して200g程度を集めることにより製品の卵黄様液の粘度を測定することができる。また、前記製品に含まれる卵黄様液の粘度は、粒体を形成する前の原料の卵黄様液の粘度とほぼ変わらないことから、原料の卵黄様液の粘度を測定して評価してもよい。 Here, the viscosity of the egg yolk-like liquid is the same as that of the rotor No. 1, 0.00 when the viscosity of the egg yolk-like liquid is less than 0.8 Pa · s under the conditions of a product temperature of 20 ° C. and a rotation speed of 10 rpm. Rotor No. 2 when it is 8 Pa · s or more and less than 3 Pa · s Rotor No. 3 when it is 3 Pa · s or more and less than 7 Pa · s Rotor No. 4 when it is 7 Pa · s or more and less than 14 Pa · s When rotor No. 5 was used, the value was obtained from the reading when the rotor was rotated 3 times after the start of measurement. The amount of egg yolk-like liquid contained in one product (raw egg yolk-like processed food) is 3 to 30 g, and it is difficult to measure the viscosity by the above method due to the small amount. The viscosity of the egg yolk-like liquid of the product can be measured by collecting about 200 g. In addition, the viscosity of the egg yolk-like liquid contained in the product is almost the same as the viscosity of the egg yolk-like liquid of the raw material before forming the granule, so the viscosity of the egg yolk-like liquid of the raw material can be measured and evaluated. Good.

卵黄様液の粘度を前記範囲に調整するため、本発明の卵黄様液は、好ましくは増粘材を含む。用いる増粘材としては、前記粘度とすることができれば特に制限は無く、例えば、グアーガム、カラギーナン、キサンタンガム等の増粘多糖類、澱粉、ゼラチン等が挙げられる。増粘材の含有量としては、増粘材の種類にもよるが通常卵黄様液に対して好ましくは0.001〜10%、より好ましくは0.1〜5%である。 In order to adjust the viscosity of the egg yolk-like liquid to the above range, the egg yolk-like liquid of the present invention preferably contains a thickener. The thickening material to be used is not particularly limited as long as it can achieve the above viscosity, and examples thereof include thickening polysaccharides such as guar gum, carrageenan and xanthan gum, starch, gelatin and the like. The content of the thickener is preferably 0.001 to 10%, more preferably 0.1 to 5% with respect to the normal yolk-like liquid, although it depends on the type of the thickener.

また、卵黄様液には、風味を生卵黄に近づける点から液卵を含むことが好ましい。液卵としては、殻付生卵を割卵して溶きほぐして調製した生液全卵、殻付生卵を割卵して卵黄と卵白を分離してこれらをそれぞれ溶きほぐして調製した生液卵黄、生液卵白及びこれらの混合物、並びに乾燥卵を乾燥前の液卵の水分含有量となるように水戻ししたもの等であればよい。特に、卵黄成分を含む液全卵や液卵黄を配合するとより風味がよく好ましい。また、これら液全卵や液卵黄としては、アルコール抽出法や超臨界二酸化炭素抽出法等により脂質やコレステロールを低減処理されたものを用いてもよく、これにより、栄養成分が調整された生卵黄様加工食品を得ることができる。液卵の配合量としては、風味等を考慮して適宜調整すればよいが増粘材等のその他の原料を配合することを考慮して卵黄様液に対して好ましくは5〜90%程度とすればよい。 Moreover, it is preferable that a liquid egg is contained in an egg yolk-like liquid from the point which brings a flavor close to raw egg yolk. As the liquid egg, the whole raw egg prepared by breaking and melting the shelled raw egg, the raw egg yolk prepared by breaking the shelled raw egg and separating the egg yolk and the egg white, respectively, What is necessary is just what rehydrated raw liquid egg white and these mixtures, and dried egg so that it might become the water content of the liquid egg before drying. In particular, it is preferable to add liquid whole egg or liquid egg yolk containing an egg yolk component. In addition, as these liquid whole eggs and liquid egg yolks, those obtained by reducing lipids and cholesterol by an alcohol extraction method, a supercritical carbon dioxide extraction method or the like may be used. A processed food can be obtained. As the blending amount of the liquid egg, it may be appropriately adjusted in consideration of the flavor and the like, but it is preferably about 5 to 90% with respect to the egg yolk-like liquid in consideration of blending other raw materials such as a thickener. do it.

更に、本発明の前記卵黄様液には、後述するように、アルギン酸アルカリ金属液中への浸漬工程において、アルギン酸アルカリ金属との接触反応によりアルギン酸カルシウム皮膜を形成するための塩化カルシウム等の水溶性カルシウム塩を含む必要がある。また、卵黄様液には、アルギン酸アルカリ金属液中への浸漬工程において成形がし易いように、卵黄様液の比重をアルギン酸アルカリ金属液よりも高くなるように調整するための後述する糖類等の原料を好ましくは含む。更に、卵黄様液は、液卵黄やクチナシ色素等により黄色い色調としてあると卵黄液に似た外観となり好ましく、また、アルギン酸カルシウム皮膜は半透明であることから、このように卵黄様液が黄色い色調であると本発明の生卵黄様加工食品の外観も黄色い色調になり生卵黄とよく似た外観となって好ましい。 Further, the egg yolk-like liquid of the present invention is soluble in water such as calcium chloride for forming a calcium alginate film by a contact reaction with an alkali metal alginate in an immersion step in an alkali metal alginate solution, as will be described later. Need to contain calcium salt. In addition, the egg yolk-like liquid includes a saccharide or the like for adjusting the specific gravity of the egg yolk-like liquid to be higher than that of the alkali metal alginate so that it can be easily molded in the alkali metal alginate liquid. Raw materials are preferably included. Furthermore, when the yolk-like liquid has a yellow color tone due to the liquid egg yolk, gardenia pigment, etc., an appearance similar to that of the egg yolk liquid is preferable, and since the calcium alginate film is translucent, the yolk-like liquid has a yellow color tone. If it is, the appearance of the raw egg yolk-like processed food of this invention also becomes a yellow color tone, and becomes an external appearance very similar to raw egg yolk, and is preferable.

卵黄様液には上述した原料以外に、本発明の効果を損なわない範囲で種々の原料を含んでいてもよい。このような原料としては、例えば、風味や色調の改善、あるいは品質保持等の点から、牛乳やバター等の乳製品、カツオやコンブ等の動植物から抽出したエキス、醤油や食塩やグルタミン酸ナトリウム等の調味料、甘味料、クチナシ色素等の着色料、クエン酸、クエン酸塩等のpH調整材、保存料等の原料が挙げられる。 In addition to the raw materials described above, the egg yolk-like liquid may contain various raw materials as long as the effects of the present invention are not impaired. Examples of such raw materials include, for example, dairy products such as milk and butter, extracts extracted from animals and plants such as bonito and kombu, soy sauce, salt and sodium glutamate from the viewpoint of improving flavor and color tone or maintaining quality. Examples thereof include ingredients such as seasonings, sweeteners, colorants such as gardenia pigments, pH adjusting materials such as citric acid and citrate, and preservatives.

続いて、上述した本発明の生卵黄様加工食品を代表的な製造方法に基づき説明する。 Subsequently, the raw egg yolk-like processed food of the present invention described above will be described based on a typical production method.

本発明の生卵黄様加工食品を製するには、まず、増粘材、液卵、水溶性カルシウム塩、糖類、調味料、清水等の任意の原料に水溶性カルシウム塩を加えて混合し、粘度が好ましくは1〜30Pa・s、より好ましくは1〜10Pa・sの水溶性カルシウム塩を含む卵黄様液を製する。ここで、水溶性カルシウム塩は、後述するアルギン酸アルカリ金属液への浸漬工程により被膜を形成するためのカルシウム成分として配合するものであるが、本発明においては、得られる生卵黄様加工食品の皮膜が適度な柔軟性を有するように卵黄様液のカルシウムイオン濃度を調整する。具体的には、後述の試験例に示すように、卵黄様液のカルシウムイオン濃度が高くなるにつれて、アルギン酸カルシウム皮膜が硬くなり、一方、卵黄様液の塩化カルシウム濃度が低くなるにつれて、アルギン酸カルシウム皮膜の柔軟性が増すことを考慮して、卵黄様液のカルシウムイオン濃度を調整する。用いるアルギン酸アルカリ金属液の濃度や浸漬時間にもよるが、水溶性カルシウム塩として塩化カルシウムを用いた場合、皮膜の破断応力を前記範囲とするためには、卵黄様液の塩化カルシウム濃度を好ましくは0.1〜1.7%、より好ましくは0.3〜1.5%とすればよい。 In order to produce the raw egg yolk-like processed food of the present invention, first, a water-soluble calcium salt is added to and mixed with any raw materials such as thickener, liquid egg, water-soluble calcium salt, sugar, seasoning, and fresh water, An egg yolk-like liquid containing a water-soluble calcium salt having a viscosity of preferably 1 to 30 Pa · s, more preferably 1 to 10 Pa · s is prepared. Here, the water-soluble calcium salt is blended as a calcium component for forming a film by an immersion step in an alkali metal alginate solution described later. In the present invention, the film of the raw egg yolk-like processed food obtained is obtained. Adjust the calcium ion concentration of the egg yolk-like liquid so that it has moderate flexibility. Specifically, as shown in the test examples described later, as the calcium ion concentration of the egg yolk-like liquid increases, the calcium alginate film becomes harder, while as the calcium chloride concentration of the egg yolk-like liquid decreases, the calcium alginate film The calcium ion concentration of the egg yolk-like liquid is adjusted in consideration of the increased flexibility of the egg yolk. Depending on the concentration and immersion time of the alkali metal alginate solution used, when calcium chloride is used as the water-soluble calcium salt, the calcium chloride concentration of the egg yolk-like solution is preferably It may be 0.1 to 1.7%, more preferably 0.3 to 1.5%.

更に本発明の卵黄様液は、後述のアルギン酸アルカリ金属液中への浸漬工程において成形がし易いように、卵黄様液の比重をアルギン酸アルカリ金属液の比重よりも高く調整する必要がある。比重調整は、卵黄様液に比重調整用の例えば、シュクロース、トレハロース、デキストリン、還元デキストリン等の糖類等を配合して行うことができる。比重調整は比重計で両液の比重を測定しながら行ってもよいが事前に卵黄様液をアルギン酸アルカリ金属液中に投入し、当該卵黄様液が沈むかどうかを調べることにより容易に判断することができる。なお、比重差がありすぎても、後述する半球状カップで卵黄様液を略球形に成形し難くなることから、両液の比重差は好ましくは0.001〜0.2、より好ましくは0.005〜0.1である。 Furthermore, the egg yolk-like liquid of the present invention needs to be adjusted to have a specific gravity higher than that of the alkali metal alginate so that the egg yolk-like liquid can be easily molded in an alkali metal alginate liquid described later. The specific gravity can be adjusted by blending, for example, saccharides such as sucrose, trehalose, dextrin, reduced dextrin and the like for adjusting the specific gravity into the egg yolk-like liquid. The specific gravity may be adjusted while measuring the specific gravity of both liquids with a hydrometer, but it is easily judged by putting the egg yolk-like liquid into the alkali metal alginate in advance and checking whether the egg yolk-like liquid sinks. be able to. Even if there is too much difference in specific gravity, it becomes difficult to form an egg yolk-like liquid into a substantially spherical shape with a hemispherical cup, which will be described later, so the specific gravity difference between the two liquids is preferably 0.001 to 0.2, more preferably 0. 0.005 to 0.1.

次に、得られた卵黄様液をアルギン酸ナトリウム等のアルギン酸アルカリ金属液中に充填ノズル等により放出し、当該卵黄様液の外縁に皮膜を形成させて生卵黄様加工食品を得るが、この際、本発明においては、アルギン酸アルカリ金属液中に浸漬した半球状カップ内に卵黄様液を充填し、当該卵黄様液を塊状として崩れないように半球状カップを好ましくは上下に揺動させて塊状とした卵黄様液をカップ内で成形する。より詳しくは、前記卵黄様液を充填した半球状カップを揺動させながらアルギン酸アルカリ金属水溶液中に保持することにより、前記卵黄様液表面に破断応力が10〜100gであるアルギン酸カルシウム皮膜を形成させ、得られる生卵黄様加工食品が平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈するように成形する。 Next, the obtained egg yolk-like liquid is discharged into an alkali metal alginate solution such as sodium alginate with a filling nozzle or the like, and a film is formed on the outer edge of the egg yolk-like liquid to obtain a raw egg yolk-like processed food. In the present invention, an egg yolk-like liquid is filled in a hemispherical cup immersed in an alkali metal alginate solution, and the hemispherical cup is preferably rocked up and down so that the egg yolk-like liquid does not collapse as a lump. Mold the egg yolk-like solution in a cup. More specifically, a calcium alginate film having a breaking stress of 10 to 100 g is formed on the surface of the egg yolk-like liquid by holding the hemispherical cup filled with the egg yolk-like liquid in an alkali metal alginate solution while rocking. When the obtained raw egg yolk-like processed food is left on a flat plate, it is molded so as to exhibit a flat sphere shape with a flat bottom having a height to major axis ratio of 1: 1.8-3.

本発明で用いる前記半球状カップとしては、半球状に窪ませた凹部を有するカップであればその材質等に特に制限はないが、例えば、図2に示すような樹脂性の半球状カップ5が挙げられる。半球状カップは、製造する生卵黄様加工食品の大きさに合わせて、その半球状に窪ませた凹部の大きさを決定すればよい。また、半球状カップとしては、図2に示すように底部及び側壁面に、多数の小孔(多孔)6が設けてあると半球状カップ内への液の出入りによりカップ内のアルギン酸アルカリ金属液の濃度が均質に保たれ易く好ましい。半球状カップの揺動の周期と振幅は、生卵黄様加工食品の大きさにもよるが、好ましくは周期を5〜120秒間、振幅を1〜10cmとすると成形し易く好ましい。 The hemispherical cup used in the present invention is not particularly limited as long as it has a concave portion recessed in a hemispherical shape. For example, a resinous hemispherical cup 5 as shown in FIG. Can be mentioned. A hemispherical cup should just determine the magnitude | size of the recessed part dented in the hemispherical shape according to the magnitude | size of the raw egg yolk-like processed food to manufacture. In addition, as the hemispherical cup, when a large number of small holes (porous) 6 are provided on the bottom and side walls as shown in FIG. 2, the alkali metal alginate liquid in the cup enters and exits the hemispherical cup. It is preferable that the concentration of is easily kept uniform. The period and amplitude of the swinging of the hemispherical cup depend on the size of the raw yolk-like processed food, but preferably the period is 5 to 120 seconds and the amplitude is 1 to 10 cm for easy molding.

また、卵黄様液をカップ内で成形する際には、得られる生卵黄様加工食品を平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈するように成形する必要があるが、このように成形する方法としては、カップ内で扁平な球形状に成形してもよいが、カップ内では略球形に成形し、これを平板上に静置した場合にその自重で底面が平らな扁平球形状に変形するようにさせてもよい。カップ内に充填する卵黄様液の量に対してカップの大きさが大きい程、扁平な形状となる傾向がある。また、成形する際のカップの揺動周期が短いほどカップ内で成形する生卵黄様加工食品の形状がより球形に近くなる傾向があり、揺動周期が長いほど扁平な球状となる傾向がある。 In addition, when the egg yolk-like liquid is molded in the cup, when the raw egg yolk-like processed food obtained is left on a flat plate, the flatness where the bottom of the ratio of height to major axis is 1: 1.8-3 is flat. Although it is necessary to mold so as to exhibit a spherical shape, as a method of molding in this way, it may be molded into a flat spherical shape in the cup, but it is molded into a substantially spherical shape in the cup, and this is formed on a flat plate. When it is left standing, it may be deformed into a flat sphere shape with a flat bottom surface due to its own weight. There exists a tendency for a flat shape to become so large that the magnitude | size of a cup is large with respect to the quantity of the egg yolk-like liquid with which it fills in a cup. Moreover, the shape of the raw egg yolk-like processed food to be molded in the cup tends to be closer to a sphere as the cup oscillating cycle is shorter, and the longer the oscillating cycle is, the more likely it becomes a flat sphere. .

本発明においては、このように半球状カップを用いることにより、はじめて略球形の形状を有する生卵黄様加工食品を得ることができる。これに対して、後述の試験例に示すように、半球状カップを用いず単に卵黄様液をアルギン酸アルカリ金属液中に放出しただけではヒモ状の塊の生卵黄様加工食品となる。 In the present invention, by using a hemispherical cup in this way, a raw egg yolk-like processed food having a substantially spherical shape can be obtained for the first time. On the other hand, as shown in a test example described later, by simply releasing the yolk-like liquid into the alkali metal alginate liquid without using a hemispherical cup, a processed egg yolk-like processed food with a string-like mass is obtained.

半球状カップ1個あたりに充填する卵黄様液の量は、製造する生卵黄様加工食品の大きさにより決定すればよく、この充填量と得られる生卵黄様加工食品の質量はほぼ同じ値となる。 The amount of egg yolk-like liquid to be filled per hemispherical cup may be determined by the size of the raw egg yolk-like processed food to be produced, and this filling amount and the mass of the raw egg yolk-like processed food to be obtained are almost the same value. Become.

また、アルギン酸アルカリ金属液のアルギン酸アルカリ金属濃度は、アルギン酸カルシウム皮膜卵黄様液に含まれるカルシウムイオンとの接触反応によりアルギン酸カルシウム皮膜が形成される程度とすればよい。例えば、アルギン酸アルカリ金属としてアルギン酸ナトリウムを用いる場合は、好ましくは0.1〜10%、より好ましくは0.5〜5%とすればよい。 Further, the alkali metal alginate concentration of the alkali metal alginate solution may be such that the calcium alginate film is formed by the contact reaction with calcium ions contained in the calcium alginate film egg yolk-like solution. For example, when sodium alginate is used as the alkali metal alginate, it is preferably 0.1 to 10%, more preferably 0.5 to 5%.

卵黄様液をアルギン酸アルカリ金属液中に放出して皮膜を形成させる際の浸漬時間は、皮膜を充分に形成させるため、好ましくは1分以上、より好ましくは2分以上である。また、浸漬時間は長時間でも構わないが、あまり長すぎても生産効率が悪いことから、好ましくは30分以内、より好ましくは20分以内である。前記浸漬により、厚さが好ましくは100μm〜3mm、より好ましくは100μm〜2mmのアルギン酸カルシウム皮膜を形成することができる。 The immersion time when the egg yolk-like solution is released into the alkali metal alginate solution to form a film is preferably 1 minute or more, more preferably 2 minutes or more in order to sufficiently form the film. Further, the immersion time may be long, but if it is too long, the production efficiency is poor, and therefore, it is preferably within 30 minutes, more preferably within 20 minutes. By the immersion, a calcium alginate film having a thickness of preferably 100 μm to 3 mm, more preferably 100 μm to 2 mm can be formed.

なお、従来、このようなアルギン酸アルカリ金属水溶液とカルシウムイオンとの接触反応を利用して比較的大きな粒状物を得る方法としては、上述の特開平3−43046号公報に記載されているように、塩化カルシウムを配合していない卵黄様液を球状に凍結した後、カルシウム溶液及びアルギン酸溶液に順次浸漬して表層をアルギン酸カルシウムで覆うことにより製造する方法が知られているが、この方法では、均一な厚みのアルギン酸カルシウム皮膜が形成し難いため不自然な外観となるばかりでなく、水中から取り出して平板上へ静置しても破れないような球状物を得ることは困難である。また、アルギン酸アルカリ金属水溶液とカルシウムイオンとの接触反応を利用して粒状物を得る手法としては、アルギン酸ナトリウム溶液を塩化カルシウム溶液中に放出して粒状物とする方法も知られているが、この場合、得られた粒状物の内層までアルギン酸カルシウムが形成されてアルギン酸カルシウムが皮膜状とならないため、本願発明へ応用することはできない。 Conventionally, as a method for obtaining a relatively large granular material by utilizing such a contact reaction between an alkali metal alginate aqueous solution and calcium ions, as described in the above-mentioned JP-A-3-43046, A method is known in which egg yolk-like liquid that does not contain calcium chloride is frozen into a spherical shape and then immersed in a calcium solution and an alginic acid solution so that the surface layer is covered with calcium alginate. Since it is difficult to form a calcium alginate film having a large thickness, not only an unnatural appearance is obtained, but it is also difficult to obtain a spherical material that does not break even when taken out from water and left on a flat plate. Further, as a method for obtaining a granular material by utilizing a contact reaction between an alkali metal alginate aqueous solution and calcium ions, a method of releasing a sodium alginate solution into a calcium chloride solution to form a granular material is also known. In this case, since calcium alginate is formed up to the inner layer of the obtained granular material and calcium alginate does not become a film, it cannot be applied to the present invention.

以上のようにして皮膜が形成され略球状に成形された卵黄様液をアルギン酸アルカリ金属水溶液中から好ましくは半球状カップごと取り出すことにより、本発明の生卵黄様加工食品が得られるが、本発明においては、更に、得られた生卵黄様加工食品を清水中に5〜60分程度浸漬して水晒し、内包する卵黄様液中の塩化カルシウム濃度を低下させるとカルシウム成分による苦みを減らすことができ好ましい。塩化カルシウムは比較的低分子であることから、水晒しすることにより、アルギン酸カルシウム皮膜を通して水晒し液中に溶出させることができる。 The egg yolk-like liquid, which is formed into a film and formed into a substantially spherical shape as described above, is preferably taken out of the alkali metal alginate aqueous solution together with the hemispherical cup, whereby the raw egg yolk-like processed food of the present invention can be obtained. In addition, when the obtained raw egg yolk-like processed food is immersed in fresh water for about 5 to 60 minutes and exposed to water, and the calcium chloride concentration in the egg yolk-like liquid contained is reduced, the bitterness due to the calcium component can be reduced. This is preferable. Since calcium chloride has a relatively low molecular weight, it can be eluted in the water exposure solution through the calcium alginate film by exposure to water.

上述のように本発明の生卵黄様加工食品は、皮膜が適度な柔軟性を有することと、平板上に静置した場合に底面が平らな扁平球形状を呈することとの両者を満たしていて生卵黄と同じ特性であることから、箸や手で取り扱った際の質感が生卵黄と酷似している。したがって、卵黄膜に包まれたままの生卵黄と同様に種々の食品と組み合わせて用いることができる。このような本発明の生卵黄様加工食品を用いた食品としては、特に制限はないが、例えば、うどん、そば、焼きそば、ラーメン等の麺類、白飯、チャーハン、石焼ビビンバ等の米飯類、エッグトースト、ハンバーガー、サンドイッチ、ピザ等のベーカリー類、卵スープ、シチュー、カレー、パスタソース等のスープ、ソース類、トロロ、ユッケ、納豆、ハンバーグ、ネギトロ、お好み焼き等が挙げられる。 As described above, the raw egg yolk-like processed food of the present invention satisfies both of the fact that the film has an appropriate flexibility and that it has a flat spherical shape with a flat bottom when left on a flat plate. Because it has the same characteristics as raw egg yolk, the texture when handled with chopsticks and hands is very similar to that of raw egg yolk. Therefore, it can be used in combination with various foods in the same manner as raw egg yolk still wrapped in the yolk membrane. The food using the raw egg yolk-like processed food of the present invention is not particularly limited. For example, noodles such as udon, buckwheat, fried noodles, ramen, cooked rice such as white rice, fried rice, and stone-grilled bibimbap, eggs Examples include bakery items such as toast, hamburger, sandwich, pizza, soups such as egg soup, stew, curry, pasta sauce, sauces, tororo, yukke, natto, hamburger, negitoro, okonomiyaki.

また、本発明の生卵黄様加工食品は、例えば、液卵白と本発明の生卵黄様加工食品を樹脂性パウチ等に充填密封する等して、生卵黄様加工食品が液卵白に浸漬した状態とすることにより、割卵しただけの卵黄を崩していない卵液と大変良く似た卵液様加工食品が得られる。この卵液様加工食品も、上述した種々の食品と組み合わせて用いることができる。 The raw egg yolk-like processed food of the present invention is, for example, a state in which the raw egg yolk-like processed food is immersed in the liquid egg white by filling and sealing the liquid egg white and the raw egg yolk-like processed food of the present invention in a resinous pouch or the like. By doing so, an egg liquid-like processed food very similar to the egg liquid that has not broken the yolk which has just been broken is obtained. This egg liquid-like processed food can also be used in combination with the various foods described above.

以下、本発明の実施例、比較例及び試験例により、本発明を更に説明する。 Hereinafter, the present invention will be further described by way of examples, comparative examples and test examples of the present invention.

[実施例1]Mサイズ鶏卵の卵黄を模した生卵黄様加工食品
(1)卵黄様液の調製
卵黄様液を下記配合で調製した。調製は配合原料をミキサーで撹拌混合することによって行った。得られた卵黄様液の粘度は5.5Pa・sであり、比重は1.03であった。また、得られた卵黄様液は、黄色い色調であった。
[Example 1] Raw egg yolk-like processed food simulating egg yolk of M size chicken egg (1) Preparation of egg yolk-like liquid An egg yolk-like liquid was prepared with the following composition. Preparation was performed by stirring and mixing the blended raw materials with a mixer. The resulting egg yolk-like liquid had a viscosity of 5.5 Pa · s and a specific gravity of 1.03. The obtained egg yolk-like liquid had a yellow color tone.

<卵黄様液の配合>
液卵黄※ 70.0部
植物油脂 6.0部
α化澱粉 4.0部
還元デキストリン 1.0部
醸造酢 0.5部
キサンタンガム 0.5部
塩化カルシウム 0.4部
清水 17.6部
―――――――――――――
合計 100.0部
※ストレーナーで卵殻片等を除去したもの。
<Combination of egg yolk-like liquid>
Liquid egg yolk * 70.0 parts vegetable oil 6.0 parts pregelatinized starch 4.0 parts reduced dextrin 1.0 parts brewed vinegar 0.5 parts xanthan gum 0.5 parts calcium chloride 0.4 parts fresh water 17.6 parts ―――――――――――
Total 100.0 parts * Removed eggshell pieces with strainer.

(2)生卵黄様加工食品の調製
まず、半球状の凹部を有し、底部及び側壁面に多孔(径2mm)を設けた図2に示す形状の半球状カップ(凹部の口径40mm、深さ30mm)を用意した。この半球状カップを1%アルギン酸ナトリウム水溶液(比重1.00)を満たした水槽中に浸漬し、当該半球状カップ内に、卵黄様液を充填機(ノズル径、10mm)で18g充填した。次いで、卵黄様液を塊状として崩れないように半球状カップをアルギン酸ナトリウム水溶液中で上下に揺動(周期20秒、振幅5cm)することにより、半球状カップ内で卵黄様液を略球形に成形した。続いて、成形物をアルギン酸ナトリウム水溶液中に浸漬した状態のまま、ノギスで短径及び長径を測定した後、直ちに卵黄様液を半球状カップごと取り出し、アルギン酸カルシウム皮膜により卵黄様液が内包された生卵黄様加工食品を得た。卵黄様液がアルギン酸ナトリウム水溶液中に浸漬された時間は5分間であった。生卵黄様加工食品のアルギン酸ナトリウム水溶液中での短径は30mm、長径は33mmであった。また、得られた生卵黄様加工食品の質量は18gであり、皮膜の厚さは約1mmであった。更に、得られた生卵黄様加工食品は、黄色い色調であった。
(2) Preparation of raw egg yolk-like processed food First, a hemispherical cup having a hemispherical recess and having a pore (diameter 2 mm) on the bottom and side walls (diameter 40 mm, depth of recess) shown in FIG. 30 mm). This hemispherical cup was immersed in a water tank filled with a 1% sodium alginate aqueous solution (specific gravity 1.00), and 18 g of egg yolk-like liquid was filled into the hemispherical cup with a filling machine (nozzle diameter, 10 mm). Next, the egg yolk-like liquid is formed into a substantially spherical shape in the hemispherical cup by swinging up and down (period 20 seconds, amplitude 5 cm) in the sodium alginate aqueous solution so that the egg yolk-like liquid does not collapse as a lump. did. Subsequently, after measuring the short diameter and long diameter with a caliper while the molded product was immersed in the sodium alginate aqueous solution, the egg yolk-like liquid was immediately taken out together with the hemispherical cup, and the egg yolk-like liquid was encapsulated by the calcium alginate film. A raw egg yolk-like processed food was obtained. The time when the egg yolk-like liquid was immersed in the aqueous sodium alginate solution was 5 minutes. The breadth of the raw egg yolk-like processed food in an aqueous sodium alginate solution was 30 mm, and the major axis was 33 mm. Moreover, the mass of the obtained raw egg yolk-like processed food was 18 g, and the thickness of the film was about 1 mm. Further, the obtained raw egg yolk-like processed food had a yellow color tone.

[実施例2]
実施例1において、用いる半球状カップの凹部の口径と深さをそれぞれ50mm及び15mmに変えた他は、実施例1と同様にしてアルギン酸カルシウム皮膜により卵黄様液が内包された扁平球形状の生卵黄様加工食品を得た。生卵黄様加工食品のアルギン酸ナトリウム水溶液中での短径は21mm、長径は37mmであった。また、得られた生卵黄様加工食品の質量は18gであり、皮膜の厚さは約1mmであった。更に、得られた生卵黄様加工食品は、黄色い色調であった。
[Example 2]
In Example 1, except that the diameter and depth of the concave portion of the hemispherical cup used were changed to 50 mm and 15 mm, respectively, a flat spherical raw material encapsulating an egg yolk-like liquid with a calcium alginate film was used in the same manner as in Example 1. An egg yolk-like processed food was obtained. The minor axis of the raw egg yolk-like processed food in an aqueous sodium alginate solution was 21 mm, and the major axis was 37 mm. Moreover, the mass of the obtained raw egg yolk-like processed food was 18 g, and the thickness of the film was about 1 mm. Further, the obtained raw egg yolk-like processed food had a yellow color tone.

[比較例1]
実施例1において、卵黄様液に塩化カルシウムに換えてアルギン酸ナトリウムを配合した他は同様にして卵黄様液を得た。次に、1%アルギン酸ナトリウム水溶液に換えて1%塩化カルシウム水溶液を満たした水槽中で半球状カップを用いて前記卵黄様液を成形した他は、実施例1と同様にして略球形の生卵黄様加工食品を得た。なお、得られた生卵黄様加工食品は内層までゲル化が進んでしまいアルギン酸カルシウムは皮膜状とはならなかった。
[Comparative Example 1]
An egg yolk-like solution was obtained in the same manner as in Example 1 except that sodium alginate was added to the egg yolk-like solution instead of calcium chloride. Next, a substantially spherical raw egg yolk was formed in the same manner as in Example 1 except that the egg yolk-like liquid was formed using a hemispherical cup in a water tank filled with 1% calcium chloride aqueous solution instead of 1% sodium alginate aqueous solution. A processed food was obtained. The obtained raw egg yolk-like processed food was gelled to the inner layer, and the calcium alginate did not form a film.

[比較例2]
実施例2において、卵黄様液の塩化カルシウム濃度を2%に増やし、その増加分は清水の配合量を増やして補正した他は実施例2と同様にしてアルギン酸カルシウム皮膜により卵黄様液が内包された扁平球形状の生卵黄様加工食品を得た。
[Comparative Example 2]
In Example 2, the yolk-like liquid was encapsulated by the calcium alginate film in the same manner as in Example 2 except that the calcium chloride concentration of the egg yolk-like liquid was increased to 2% and the increase was corrected by increasing the blending amount of fresh water. A flat egg-shaped processed raw yolk-like processed food was obtained.

[比較例3]
実施例1において、卵黄様液をアルギン酸ナトリウム水溶液中に放出した際に半球状カップを用いない他は、実施例1と同様にして生卵黄様加工食品を得た。なお、得られた生卵黄様加工食品はアルギン酸ナトリウム水溶液中でヒモ状であった。
[Comparative Example 3]
In Example 1, a raw egg yolk-like processed food was obtained in the same manner as in Example 1 except that the hemispherical cup was not used when the egg yolk-like liquid was released into the sodium alginate aqueous solution. In addition, the obtained raw egg yolk-like processed food was string-like in the sodium alginate aqueous solution.

[比較例4]
実施例1において塩化カルシウムを配合せずその減少分は清水の配合量を増やして補正した他は同様にして卵黄様液を得た。得られた卵黄様液18gを球型の合わせ形に充填後凍結して質量18gの冷凍球状物を得た。得られた冷凍球状物を2%濃度の塩化カルシウム水溶液に5秒間浸漬し、次いで、1%濃度のアルギン酸ナトリウム水溶液に10秒間浸漬した後、取り出して略球形の生卵黄様加工食品を得た。なお、得られた生卵黄様加工食品はアルギン酸ナトリウム水溶液中で略球形であったが、アルギン酸カルシウム皮膜が不均一に形成されていて表面に凹凸を生じ不自然な外観であった。
[Comparative Example 4]
An egg yolk-like solution was obtained in the same manner as in Example 1 except that calcium chloride was not added and the decrease was corrected by increasing the amount of fresh water. The obtained egg yolk-like liquid (18 g) was filled into a spherical shape and then frozen to obtain a frozen spherical product having a mass of 18 g. The obtained frozen spherical product was immersed in a 2% strength aqueous solution of calcium chloride for 5 seconds, then immersed in a 1% strength aqueous solution of sodium alginate for 10 seconds, and then taken out to obtain a substantially spherical raw egg yolk-like processed food. In addition, although the obtained raw egg yolk-like processed food was substantially spherical shape in the sodium alginate aqueous solution, the calcium alginate film was formed unevenly and the surface was uneven | corrugated and was unnatural appearance.

[比較例5]
実施例1において、用いる半球状カップの凹部の口径と深さをそれぞれ70mm及び15mmに変えた他は、実施例1と同様にしてアルギン酸カルシウム皮膜により卵黄様液が内包された扁平球形状の生卵黄様加工食品を得た。
[Comparative Example 5]
In Example 1, except that the diameter and depth of the concave portion of the hemispherical cup used were changed to 70 mm and 15 mm, respectively, a flat spherical raw material encapsulating an egg yolk-like liquid with a calcium alginate film was obtained in the same manner as in Example 1. An egg yolk-like processed food was obtained.

[試験例1]
まず、以上の実施例及び比較例で製造した生卵黄様加工食品と比較するために、対照品の生卵黄を用意した。すなわち、Mサイズの殻付き鶏卵を割卵して卵黄膜が破れないようにセパレータで丁寧に卵白と分けて生卵黄を取り出した。
[Test Example 1]
First, in order to compare with the raw egg yolk-like processed food produced in the above Examples and Comparative Examples, a control raw egg yolk was prepared. That is, raw egg yolks were taken out by splitting M-sized shell eggs and separating them from egg whites with a separator so that the yolk membrane was not broken.

次に、実施例1、2及び比較例1〜5で得られた生卵黄様加工食品、並びに対照の生卵黄について、平板上での高さと長径の比を下記の方法で測定した。また、上述の実施形態に記載した方法により、生卵黄様加工食品の皮膜の破断応力を測定した。 Next, for the raw egg yolk-like processed foods obtained in Examples 1 and 2 and Comparative Examples 1 to 5, and the control raw egg yolk, the ratio of the height to the major axis on the flat plate was measured by the following method. Moreover, the breaking stress of the film | membrane of raw egg yolk processed food was measured by the method described in the above-mentioned embodiment.

続いて、各生卵黄様加工食品について、生卵黄を対照として、箸で挟んだ際の弾力及び崩れ易さを下記の評価基準で評価した。また、図3に示すように指先でつまんで3秒間吊持ち可能であるかを下記の評価基準で評価した。結果を表1に示す。 Subsequently, for each raw egg yolk-like processed food, the elasticity and ease of collapse when sandwiched with chopsticks were evaluated according to the following evaluation criteria, with the raw egg yolk as a control. Moreover, as shown in FIG. 3, it was evaluated according to the following evaluation criteria whether it can be held for 3 seconds by pinching with a fingertip. The results are shown in Table 1.

<平板上での生卵黄の高さと長径の測定方法>
水平面に保った表面が平滑な樹脂性の平板上に、生卵黄様加工食品又は対照の生卵黄を静置し、その高さを「卵白高、卵黄高測定器」で測定し、長径をノギスで測定した。
<Measurement of the height and major axis of raw egg yolk on a flat plate>
Place the raw egg yolk-like processed food or the control raw egg yolk on a resin flat plate that is kept flat on a horizontal surface, measure the height with the egg white height and egg yolk height measuring instrument, and measure the major axis with calipers. Measured with

表1より、皮膜の破断応力が10〜100gであることと、平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈することの両者を満たす点から生卵黄と同じ特性を有する実施例1及び2の生卵黄様加工食品は、箸で挟んだ際の弾力及び崩れ易さが対照の生卵黄と同程度であり、また、対照の生卵黄と同様に指先でつまんで吊持ち可能であったことから、箸や手で取り扱った際の質感が生卵黄と酷似しているといえる。 According to Table 1, the breaking stress of the film is 10 to 100 g, and when it is left on a flat plate, it has a flat sphere shape with a flat bottom surface with a ratio of height to major axis of 1: 1.8 to 3. The raw egg yolk-like processed foods of Examples 1 and 2 having the same characteristics as raw egg yolk in terms of satisfying both of them have the same degree of elasticity and ease of collapsing when sandwiched with chopsticks, and the control Like the raw egg yolk, it can be held by holding it with your fingertips, so it can be said that the texture when handled with chopsticks and hands is very similar to that of raw egg yolk.

これに対して、平板上での高さを1とした際の長径が3より大きい場合(比較例5)は、皮膜の破断応力が前記特定範囲であったものの、箸で挟んだ際の弾力が弱すぎて、対照の生卵黄と似た質感とならなかった。また、平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状となったとしても、皮膜の破断応力が前記特定範囲より高い場合(比較例2)は、箸で挟んだ際の弾力が強すぎ、箸で押圧した際に崩れ難く、対照の生卵黄と似た質感とならなかった。 On the other hand, when the major axis when the height on the flat plate is 1 is larger than 3 (Comparative Example 5), although the breaking stress of the film is in the specific range, the elasticity when sandwiched with chopsticks Was too weak to produce a texture similar to the control raw yolk. Further, even when the film is placed on a flat plate, even when the bottom surface has a flat and spherical shape with a ratio of height to major axis of 1: 1.8 to 3, the rupture stress of the film is higher than the specific range (comparison) In Example 2), the elasticity when pinched with chopsticks was too strong, and when pressed with chopsticks, it did not collapse easily, and the texture did not resemble that of a raw egg yolk.

一方、アルギン酸ナトリウムを配合した卵黄様液を塩化カルシウム溶液中で成形した比較例1の卵黄様食品は、内層までゲル化が進んでおり、箸や手で取り扱った際の質感が生卵黄と異なるものであった。また、卵黄様液をアルギン酸ナトリウム水溶液中に放出した際に、半球状カップを用いなかった比較例3の生卵黄様加工食品は、ヒモ状の形状となった。更に、塩化カルシウムを配合していない卵黄様液を用い、これを球状に凍結した後、カルシウム溶液及びアルギン酸溶液に順次浸漬して表層をアルギン酸カルシウムで覆うことにより製造した比較例4の生卵黄様加工食品は、平板上へ静置した際に破れてしまった。 On the other hand, the egg yolk-like food of Comparative Example 1 in which an egg yolk-like liquid containing sodium alginate was molded in a calcium chloride solution has been gelled to the inner layer, and the texture when handled with chopsticks and hands is different from that of raw egg yolk. It was a thing. In addition, when the egg yolk-like liquid was released into the aqueous sodium alginate solution, the raw egg yolk-like processed food of Comparative Example 3 that did not use the hemispherical cup became a string-like shape. Furthermore, the egg yolk-like liquid containing no calcium chloride was frozen in a spherical shape and then immersed in a calcium solution and an alginic acid solution to cover the surface layer with calcium alginate. Processed foods were torn when left on a flat plate.

[試験例2]
本試験例においては、卵黄様液の塩化カルシウム濃度と皮膜の硬さについて調べるために以下の試験を行った。すなわち、実施例1において、卵黄様液の塩化カルシウム濃度をそれぞれ0.05%、0.1%、0.3%、0.4%、1%及び2%に変え、その減少分あるいは増加分は清水の配合量で補正した他は同様にして、塩化カルシウム濃度の異なる6種類の卵黄様液を得た。次に、これらの卵黄様液を用いて、実施例1と同様にして6種類の生卵黄様加工食品を得た。なお、これらの生卵黄様加工食品は、いずれもアルギン酸ナトリウム水溶液中で略球形であった。また、得られた生卵黄様加工食品は、いずれも質量が18g、皮膜の厚さが約1mmであり、黄色い色調であった。
[Test Example 2]
In this test example, the following test was performed to examine the calcium chloride concentration of the egg yolk-like liquid and the hardness of the film. That is, in Example 1, the calcium chloride concentration of the egg yolk-like liquid was changed to 0.05%, 0.1%, 0.3%, 0.4%, 1%, and 2%, respectively, and the decrease or increase In the same manner except that it was corrected by the blending amount of fresh water, six types of egg yolk-like liquids having different calcium chloride concentrations were obtained. Next, using these egg yolk-like liquids, six kinds of raw egg yolk-like processed foods were obtained in the same manner as in Example 1. In addition, all of these raw egg yolk-like processed foods were substantially spherical in the sodium alginate aqueous solution. Moreover, all the obtained raw egg yolk-like processed foods were 18 g in mass, the thickness of the film was about 1 mm, and had a yellow color tone.

続いて、試験例1と同様に、各生卵黄様加工食品の平板上での高さと長径の比及び生卵黄様加工食品の皮膜の破断応力を測定した。 Subsequently, as in Test Example 1, the ratio of the height and the long diameter of each raw egg yolk-like processed food on the flat plate and the breaking stress of the film of the raw egg yolk-like processed food were measured.

更に、試験例1と同様にして、生卵黄を対照として箸で挟んだ際の弾力及び崩れ易さ、更に、指先でつまんで吊持ち可能であるかを評価した。結果を表2に示す。 Further, in the same manner as in Test Example 1, the elasticity and ease of collapse when sandwiched with chopsticks by using raw egg yolk as a control, and whether it can be suspended by fingertips were evaluated. The results are shown in Table 2.

表2より、卵黄様液の塩化カルシウム濃度が高くなるにつれて、アルギン酸カルシウム皮膜が硬くなり、一方、卵黄様液の塩化カルシウム濃度が低くなるにつれて、アルギン酸カルシウム皮膜の柔軟性が増すことがわかる。つまり、卵黄様液の塩化カルシウム濃度を変えることにより、アルギン酸カルシウム皮膜の柔軟性、つまり、生卵黄様加工食品の皮膜の破断応力が調整できることがわかる。 From Table 2, it can be seen that the calcium alginate film becomes harder as the calcium chloride concentration of the egg yolk-like liquid becomes higher, while the flexibility of the calcium alginate film increases as the calcium chloride concentration of the egg yolk-like liquid becomes lower. That is, it can be seen that by changing the calcium chloride concentration of the egg yolk-like solution, the flexibility of the calcium alginate film, that is, the breaking stress of the film of the raw egg yolk-like processed food can be adjusted.

また、表2より、皮膜の破断応力が10〜100gであり、平板上で高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈する本発明の生卵黄様加工食品(試験品2−2〜2−5)は、箸で挟んだ際の弾力及び崩れ易さが対照の生卵黄と同程度であり、また、対照の生卵黄と同様に指先でつまんで吊持ち可能であって、箸や手で取り扱った際の質感が生卵黄と酷似しているといえる。 Moreover, from Table 2, the breaking stress of the film is 10 to 100 g, and the raw egg yolk-like process of the present invention has a flat sphere shape with a flat bottom having a height to major axis ratio of 1: 1.8 to 3 on a flat plate. The food (test products 2-2 to 2-5) has the same elasticity and ease of collapse when sandwiched with chopsticks, and is pinched with a fingertip like the control raw egg yolk. It can be held, and the texture when handled with chopsticks and hands is very similar to that of raw egg yolk.

[試験例3]
本試験例においては、卵黄様液の粘度について調べるために以下の試験を行った。すなわち、実施例1において、卵黄様液のキサンタンガム濃度をそれぞれ0%、0.1%、0.5%、1%、2%及び3%に変え、その減少分あるいは増加分は清水の配合量で補正した他は同様にして、粘度の異なる6種類の卵黄様液を得た。次に、これらの卵黄様液を用いて、実施例1と同様にして6種類の生卵黄様加工食品を得た。なお、これらの生卵黄様加工食品は、いずれもアルギン酸ナトリウム水溶液中で略球形であった。また、得られた生卵黄様加工食品は、いずれも質量が18g、皮膜の厚さが約1mmであり、黄色い色調であった。
[Test Example 3]
In this test example, the following test was conducted to examine the viscosity of the egg yolk-like liquid. That is, in Example 1, the xanthan gum concentration of the egg yolk-like liquid was changed to 0%, 0.1%, 0.5%, 1%, 2%, and 3%, respectively, and the decrease or increase was the blending amount of fresh water 6 egg yolk-like liquids having different viscosities were obtained in the same manner as described above. Next, using these egg yolk-like liquids, six kinds of raw egg yolk-like processed foods were obtained in the same manner as in Example 1. In addition, all of these raw egg yolk-like processed foods were substantially spherical in the sodium alginate aqueous solution. Moreover, all the obtained raw egg yolk-like processed foods were 18 g in mass, the thickness of the film was about 1 mm, and had a yellow color tone.

続いて、試験例1と同様に、各生卵黄様加工食品の平板上での高さと長径の比及び生卵黄様加工食品の皮膜の破断応力を測定した。 Subsequently, as in Test Example 1, the ratio of the height and the long diameter of each raw egg yolk-like processed food on the flat plate and the breaking stress of the film of the raw egg yolk-like processed food were measured.

更に、試験例1と同様にして、生卵黄を対照として箸で挟んだ際の弾力及び崩れ易さ、更に、指先でつまんで吊持ち可能であるかを評価した。結果を表3に示す。 Further, in the same manner as in Test Example 1, the elasticity and ease of collapse when sandwiched with chopsticks by using raw egg yolk as a control, and whether it can be suspended by fingertips were evaluated. The results are shown in Table 3.

表3より、卵黄様液の粘度が好ましくは1〜30Pa・sである本発明の生卵黄様加工食品(試験品3−2〜3−5)は、箸で挟んだ際の弾力及び崩れ易さが対照の生卵黄と同程度であり、また、対照の生卵黄と同様に指先でつまんで吊持ち可能であって、箸や手で取り扱った際の質感が生卵黄と酷似していた。特に、卵黄様液の粘度が1〜10Pa・sである本発明の生卵黄様加工食品(試験品3−2〜3−4)は、箸で挟んだ際の質感が対照と大変似ていてより好ましかった。 From Table 3, the raw egg yolk-like processed food of the present invention (test products 3-2 to 3-5) in which the viscosity of the yolk-like liquid is preferably 1 to 30 Pa · s is elastic and easily collapsed when sandwiched with chopsticks. It was similar to the raw egg yolk of the control, and like the control raw egg yolk, it could be pinched with a fingertip and suspended, and the texture when handled with chopsticks or hands was very similar to that of the raw egg yolk. In particular, the raw egg yolk-like processed food of the present invention (test products 3-2 to 3-4) in which the viscosity of the yolk-like liquid is 1 to 10 Pa · s is very similar to the control when sandwiched with chopsticks. It was more preferable.

これに対して、粘度が30Pa・sよりも高く、平板上での高さを1とした際の長径が1.8より小さくく球形に近い場合(試験品3−6)は、箸で挟んだ際の弾力が強すぎて対照の生卵黄と似た質感とならなかった。一方、粘度が1Pa・sよりも低い場合(試験品3−1)は、箸で挟んだ際の質感がやや対照の生卵黄と異なった。 On the other hand, when the viscosity is higher than 30 Pa · s and the major axis is smaller than 1.8 when the height on a flat plate is 1, it is sandwiched with chopsticks (test product 3-6). The elasticity at the time was too strong and it did not look like the control raw yolk. On the other hand, when the viscosity was lower than 1 Pa · s (test product 3-1), the texture when sandwiched with chopsticks was slightly different from that of the control raw egg yolk.

[試験例4]
実施例1において、半球状カップの大きさ及び卵黄様液の充填量を表4に示すものに変えた他は同様にして、アルギン酸カルシウム皮膜により卵黄様液が内包された4種類の略球状の生卵黄様加工食品を得た。なお、卵黄様液の質量から、それぞれ試験品4−1は鶉卵の卵黄を模した生卵黄様加工食品、試験品4−2の生卵黄様加工食品はSSサイズ鶏卵の卵黄を模した生卵黄様加工食品、試験品4−3の生卵黄様加工食品はMサイズ鶏卵の卵黄を模した生卵黄様加工食品である。また、得られた生卵黄様加工食品は、いずれも皮膜の厚さが約1mmであり、黄色い色調であった。
[Test Example 4]
In the same manner as in Example 1, except that the size of the hemispherical cup and the filling amount of the yolk-like liquid were changed to those shown in Table 4, four types of substantially spherical shapes in which the yolk-like liquid was encapsulated by the calcium alginate film. A raw egg yolk-like processed food was obtained. In addition, from the mass of the yolk-like liquid, the test sample 4-1 is a raw egg yolk-like processed food that imitates the egg yolk of an egg yolk, and the raw egg yolk-like processed food of the test sample 4-2 is a raw that imitates the egg yolk of an SS size chicken egg. The yolk-like processed food, the raw yolk-like processed food of the test product 4-3 is a raw yolk-like processed food imitating the egg yolk of an M size chicken egg. Moreover, all the obtained raw egg yolk-like processed foods had a film thickness of about 1 mm and had a yellow color tone.

続いて、試験例1と同様に、各生卵黄様加工食品の平板上での高さと長径の比及び生卵黄様加工食品の皮膜の破断応力を測定した。 Subsequently, as in Test Example 1, the ratio of the height and the long diameter of each raw egg yolk-like processed food on the flat plate and the breaking stress of the film of the raw egg yolk-like processed food were measured.

更に、試験例1と同様にして、生卵黄を対照として箸で挟んだ際の弾力及び崩れ易さ、更に、指先でつまんで吊持ち可能であるかを評価した。結果を表5に示す。 Further, in the same manner as in Test Example 1, the elasticity and ease of collapse when sandwiched with chopsticks by using raw egg yolk as a control, and whether it can be suspended by fingertips were evaluated. The results are shown in Table 5.

表5より、皮膜の破断応力が10〜100gであり、平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈する点から生卵黄と同じ特性を有する本発明の生卵黄様加工食品(試験品4−1〜4−4)は、いずれも箸で挟んだ際の弾力及び崩れ易さが対照の生卵黄と同程度であり、また、対照の生卵黄と同様に指先でつまんで吊持ち可能であったことから、箸や手で取り扱った際の質感が生卵黄と酷似しているといえる。 From Table 5, the breaking stress of the film is 10 to 100 g, and the raw egg yolk has a flat sphere shape with a flat bottom having a ratio of height to major axis of 1: 1.8 to 3 when left on a flat plate. The raw egg yolk-like processed food of the present invention (test products 4-1 to 4-4) having the same characteristics as those of the raw egg yolk of the control is the same as the control raw egg yolk. Moreover, it can be said that the texture when handled with chopsticks or hands is very similar to that of raw egg yolk because it can be held and held by the fingertips like the control raw egg yolk.

[実施例4]
卵黄様液を下記配合で調製した。調製は配合原料をミキサーで撹拌混合することによって行った。得られた卵黄様液の粘度は8Pa・s、比重は1.04であり、黄色い色調であった。実施例2において、卵黄様液としてこの卵黄様液を用いた他は同様にしてアルギン酸カルシウム皮膜により卵黄様液が内包された扁平球形状の生卵黄様加工食品を得た。なお、生卵黄様加工食品のアルギン酸ナトリウム水溶液中での短径は28mm、長径は37mmであった。また、得られた生卵黄様加工食品の質量は18g、皮膜の厚さは約1mmであり、黄色い色調であった。
[Example 4]
An egg yolk-like liquid was prepared with the following composition. Preparation was performed by stirring and mixing the blended raw materials with a mixer. The resulting egg yolk-like liquid had a viscosity of 8 Pa · s and a specific gravity of 1.04, which was a yellow color tone. In Example 2, except that this egg yolk-like liquid was used as an egg yolk-like liquid, a flat sphere-shaped raw egg yolk-like processed food in which the egg yolk-like liquid was encapsulated by a calcium alginate film was obtained. In addition, the minor axis | shaft in the sodium alginate aqueous solution of raw egg yolk processed food was 28 mm, and the major axis was 37 mm. Moreover, the mass of the obtained raw egg yolk-like processed food was 18 g, the film thickness was about 1 mm, and it was a yellow color tone.

<卵黄様液の配合>
液卵白※ 73.0部
ゼラチン 5.0部
α化澱粉 2.0部
醸造酢 0.5部
塩化カルシウム 1.5部
クチナシ色素 0.1部
清水 17.9部
――――――――――――
合計 100.0部
※ストレーナーで卵殻片等を除去したもの。
<Combination of egg yolk-like liquid>
Liquid egg white * 73.0 parts Gelatin 5.0 parts Pregelatinized starch 2.0 parts Brewed vinegar 0.5 parts Calcium chloride 1.5 parts Gardenia pigment 0.1 parts Shimizu 17.9 parts ――――――― ――――
Total 100.0 parts * Removed eggshell pieces with strainer.

得られた生卵黄様加工食品は、箸や手で取り扱った際の質感が生卵黄と酷似していて好ましかった。なお、得られた生卵黄様加工食品を平板上に静置ところ、底面が平らな扁平球形状となった。また、平板上での高さと長径の比を測定したところ、高さと長径の比が1:2.5であった。更に、生卵黄様加工食品の皮膜の破断応力を測定したところ、78gであった。 The obtained raw yolk-like processed food was preferred because it was very similar in texture to raw egg yolk when handled with chopsticks and hands. In addition, when the obtained raw egg yolk-like processed food was left still on a flat plate, it became a flat sphere shape with a flat bottom. Further, when the ratio of the height to the major axis on the flat plate was measured, the ratio of the height to the major axis was 1: 2.5. Furthermore, when the breaking stress of the film | membrane of raw egg yolk processed food was measured, it was 78g.

[実施例5]
液卵白(ストレーナーで卵殻片等を除去したもの)37gと実施例1で得られた生卵黄様加工食品を樹脂製パウチに充填密封して生卵黄様加工食品が液卵白中に浸漬した状態とすることにより、容器詰めの卵液様加工食品を得た。得られた卵液様加工食品は、割卵しただけの卵黄を崩していない卵液と大変良く似たものであった。
[Example 5]
37 g of liquid egg white (with the egg shell pieces removed with a strainer) and the raw egg yolk-like processed food obtained in Example 1 were filled and sealed in a resin pouch, and the raw egg yolk-like processed food was immersed in the liquid egg white By doing so, an egg liquid-like processed food in a container was obtained. The resulting egg liquid-like processed food was very similar to the egg liquid that had not broken the egg yolk just broken.

次に、得られた容器詰めの卵液様加工食品を5℃で3日間保存した後に開封して、かけうどんの上に盛り付け、生卵黄様加工食品を箸で崩しながら食したところ、割卵しただけの卵黄を崩していない生卵液と同様に大変美味しいものであった。また、生卵黄様加工食品は、箸で触れたり崩したりした際の質感が生卵黄と酷似していた。 Next, the egg-packed processed food in the container was stored at 5 ° C for 3 days, then opened, placed on top of the udon and eaten while breaking the raw egg yolk-like processed food with chopsticks. It was as delicious as the raw egg liquid that did not break the yolk. In addition, raw egg yolk-like processed food was very similar to raw egg yolk in texture when touched or broken with chopsticks.

[実施例6]
トロロ200gを樹脂製の成形容器に入れ、その上に実施例1で得られた生卵黄様加工食品を載せた後、樹脂製の蓋を被せて容器詰めの惣菜を得た。得られた容器詰めの惣菜を5℃で3日間保存した後に開封して、生卵黄様加工食品を箸で崩しながら食したところ、生卵黄を用いたものと同様に大変美味しいものであった。また、生卵黄様加工食品は、箸で触れたり崩したりした際の質感が生卵黄と酷似していた。
[Example 6]
200 g of Trollo was placed in a resin molded container, and the raw egg yolk-like processed food obtained in Example 1 was placed thereon, and then a resin lid was put on to obtain a side dish in a container. The prepared side dish of the container was stored at 5 ° C. for 3 days, then opened, and the raw egg yolk-like processed food was crushed with chopsticks and found to be as delicious as that using raw egg yolk. In addition, raw egg yolk-like processed food was very similar to raw egg yolk in texture when touched or broken with chopsticks.

本発明の一実施例である生卵黄様加工食品を平板上に静置した状態を示す平面図及び側面図。The top view and side view which show the state which left still the raw egg yolk-like processed food which is one Example of this invention on the flat plate. 半球状カップの一実施例を示す斜視図。The perspective view which shows one Example of a hemispherical cup. 実施例1で得られた生卵黄様加工食品を吊持ちした状態を示す図面代用写真。The drawing substitute photograph which shows the state which suspended the raw egg yolk-like processed food obtained in Example 1. FIG.

符号の説明Explanation of symbols

1.生卵黄様加工食品
2.アルギン酸カルシウム皮膜
3.卵黄様液
4.平板
5.半球状カップ
6.多数の小孔
7.支軸
1. Raw egg yolk-like processed foods 1. 2. calcium alginate film Egg yolk-like liquid Flat plate 5. Hemispherical cup 6. Many small holes 7. Spindle

Claims (8)

アルギン酸カルシウム皮膜からなる卵黄膜相当部を有し、該皮膜にて卵黄様液を内包する生卵黄様加工食品であって、前記皮膜の破断応力が10〜100gであり、平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈することを特徴とする生卵黄様加工食品。 A raw egg yolk-like processed food containing a yolk membrane equivalent part composed of a calcium alginate film, and encapsulating an egg yolk-like liquid in the film, the breaking stress of the film being 10 to 100 g, which was left on a flat plate A raw egg yolk-like processed food characterized by having a flat spherical shape with a flat bottom having a height to major axis ratio of 1: 1.8 to 3. 前記卵黄様液の粘度が1〜30Pa・sである請求項1記載の生卵黄様加工食品。 The raw egg yolk-like processed food according to claim 1, wherein the egg yolk-like liquid has a viscosity of 1 to 30 Pa · s. 質量が3〜30gである請求項1又は2記載の生卵黄様加工食品。 The raw egg yolk-like processed food according to claim 1 or 2, having a mass of 3 to 30 g. 請求項1乃至3のいずれかに記載の生卵黄様加工食品を用いた食品。 A food using the raw egg yolk-like processed food according to any one of claims 1 to 3. 請求項1乃至3のいずれかに記載の生卵黄様加工食品を液卵白に浸漬した卵液様加工食品。 An egg liquid-like processed food obtained by immersing the raw egg yolk-like processed food according to any one of claims 1 to 3 in liquid egg white. アルギン酸カルシウム皮膜からなる卵黄膜相当部を有し、該皮膜にて卵黄様液を内包する生卵黄様加工食品の製造方法であって、アルギン酸アルカリ金属水溶液中に浸漬した半球状カップ内に、カルシウムイオンを含有する卵黄様液を充填し、次いで、前記卵黄様液を充填した半球状カップを揺動させながらアルギン酸アルカリ金属水溶液中に保持することにより、前記卵黄様液表面に破断応力が10〜100gであるアルギン酸カルシウム皮膜を形成させ、得られる生卵黄様加工食品が平板上に静置した場合に高さと長径の比が1:1.8〜3の底面が平らな扁平球形状を呈するように成形することを特徴とする生卵黄様加工食品の製造方法。 A method for producing a raw egg yolk-like processed food having an egg yolk membrane equivalent part composed of a calcium alginate film and encapsulating an egg yolk-like liquid in the film, wherein the calcium is contained in a hemispherical cup immersed in an aqueous alkali metal alginate solution. The egg yolk-like liquid containing ions is filled, and then the hemispherical cup filled with the egg yolk-like liquid is held in an aqueous alkali metal alginate solution while being swung, whereby a breaking stress of 10 to 10 is applied to the surface of the egg yolk-like liquid. When a calcium alginate film of 100 g is formed and the resulting raw egg yolk-like processed food is left on a flat plate, a flat sphere shape with a flat bottom surface with a ratio of height to major axis of 1: 1.8 to 3 is exhibited. A method for producing a raw egg yolk-like processed food, characterized by being molded into 前記半球状カップに多孔が設けてある請求項6記載の生卵黄様加工食品の製造方法。 The method for producing a raw egg yolk-like processed food according to claim 6, wherein the hemispherical cup is provided with a hole. 前記卵黄様液の粘度が1〜30Pa・sである請求項6又は7記載の生卵黄様加工食品の製造方法。 The method for producing a raw egg yolk-like processed food according to claim 6 or 7, wherein the egg yolk-like liquid has a viscosity of 1 to 30 Pa · s.
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JP2012044903A (en) * 2010-08-25 2012-03-08 Q P Corp Raw yolk-like frozen ball
JP6346705B1 (en) * 2017-11-30 2018-06-20 キユーピー株式会社 Egg processed products
JP2019135945A (en) * 2018-02-07 2019-08-22 キユーピー株式会社 Frozen spherical food and frozen spherical food production method

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JP2004290080A (en) * 2003-03-27 2004-10-21 Q P Corp Apparatus for producing poached egg-like food
JP2006087378A (en) * 2004-09-24 2006-04-06 Q P Corp Method for preparing poached egg-like food and preparation apparatus

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JP2012044903A (en) * 2010-08-25 2012-03-08 Q P Corp Raw yolk-like frozen ball
JP6346705B1 (en) * 2017-11-30 2018-06-20 キユーピー株式会社 Egg processed products
JP2019135945A (en) * 2018-02-07 2019-08-22 キユーピー株式会社 Frozen spherical food and frozen spherical food production method

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