JP2009120504A - Method for inhibiting hatching of egg of cockroach - Google Patents

Method for inhibiting hatching of egg of cockroach

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Publication number
JP2009120504A
JP2009120504A JP2007294044A JP2007294044A JP2009120504A JP 2009120504 A JP2009120504 A JP 2009120504A JP 2007294044 A JP2007294044 A JP 2007294044A JP 2007294044 A JP2007294044 A JP 2007294044A JP 2009120504 A JP2009120504 A JP 2009120504A
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Prior art keywords
cockroach
methyl
hatching
oil
egg
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Japanese (ja)
Inventor
Hiroshi Okamoto
央 岡本
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Sumitomo Chemical Co Ltd
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Sumitomo Chemical Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for inhibiting the hatching of an egg of a cockroach. <P>SOLUTION: The hatching of the egg of the cockroach is inhibited by allowing a composition comprising 1-methyl-2-nitro-3-[(3-tetrahydrofuryl)methyl]guanidine as an active ingredient (preferably, the composition further containing an ingestion-inducing material such as saccharides such as sugar, glucose, granulated sugar, fructose, lactose, maltose and raw sugar; a dairy product such as skim milk, powdered skim milk and cheese; starch derived from corn, potato or the like; flour such as wheat flour, a vegetable oil such as coconut oil, cacao oil, corn oil and sesame oil; and seasonings such as sauce and soy sauce, besides the compound) to be ingested by an adult of the cockroach (preferably, german cockroach) under brooding the egg. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明はゴキブリ卵の孵化を抑止する方法に関する。   The present invention relates to a method for inhibiting hatching of cockroach eggs.

従来よりゴキブリ成虫および幼虫を防除するための製剤やそれを用いた様々な防除方法が開発され実用に供されてきた(特許文献1及び特許文献2を参照)。しかしながら、ゴキブリの増殖力が高いことはよく知られているが、ゴキブリの増殖を抑止するとの観点からゴキブリ成虫および幼虫を防除するのみでは、ゴキブリの増殖を完全に抑制することは困難である。   Conventionally, preparations for controlling adult cockroaches and larvae and various control methods using the same have been developed and put to practical use (see Patent Document 1 and Patent Document 2). However, it is well known that cockroaches have a high proliferation ability, but it is difficult to completely inhibit the growth of cockroaches only by controlling adult cockroaches and larvae from the viewpoint of inhibiting the proliferation of cockroaches.

特開平09−202704号公報JP 09-202704 A 特開2004−137229号公報JP 2004-137229 A

本発明はゴキブリ卵の孵化を抑止する方法を提供することを課題とする。   An object of the present invention is to provide a method for inhibiting hatching of cockroach eggs.

本発明者は、各種のゴキブリ卵に対して孵化を抑止する方法を鋭意検討した結果、1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンを有効成分として含有する組成物を抱卵中のゴキブリ成虫に摂食させることにより、ゴキブリ卵の孵化が抑止されることを見出し、本発明に至った。   As a result of intensive studies on a method for inhibiting hatching of various cockroach eggs, the present inventor has a composition containing 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine as an active ingredient. It has been found that hatching of cockroach eggs is suppressed by feeding adults on cockroaches during incubation, leading to the present invention.

即ち、本発明は以下のものである。
[発明1]
ゴキブリ卵の孵化を抑止する方法であって、1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンを有効成分として含有する組成物を抱卵中のゴキブリ成虫に摂食させることを特徴とするゴキブリ卵の孵化抑止方法。
[発明2]
ゴキブリ成虫が、チャバネゴキブリ成虫である発明1記載のゴキブリ卵の孵化抑止方法。
[発明3]
1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンを有効成分として含有することを特徴とするゴキブリ卵の孵化抑止組成物。
[発明4]
1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンの含有量が0.001〜10重量%の範囲である発明3記載のゴキブリ卵の孵化抑止組成物。
That is, the present invention is as follows.
[Invention 1]
A method for inhibiting hatching of cockroach eggs, which feeds adult cockroaches containing 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine as an active ingredient A method for inhibiting hatching of cockroach eggs, characterized in that.
[Invention 2]
The method for inhibiting hatching of cockroach eggs according to invention 1, wherein the adult cockroach is an adult cockroach.
[Invention 3]
A composition for inhibiting hatching of cockroach eggs, comprising 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine as an active ingredient.
[Invention 4]
The composition for inhibiting hatching of cockroach eggs according to invention 3, wherein the content of 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine is in the range of 0.001 to 10% by weight.

本発明のゴキブリ卵の孵化抑止方法(以下、本発明方法と記す。)により、ゴキブリ卵の孵化を抑止することができ、ゴキブリの増殖を効果的に抑止することができる。更に、本発明方法においては、1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンを有効成分として含有する組成物(以下、本抑止組成物)を摂食したゴキブリ成虫も防除することができる場合もある。   According to the method for inhibiting hatching of cockroaches of the present invention (hereinafter referred to as the method of the present invention), hatching of cockroaches can be inhibited and the proliferation of cockroaches can be effectively inhibited. Furthermore, in the method of the present invention, adult cockroaches fed with a composition containing 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine as an active ingredient (hereinafter referred to as the present deterrent composition). Can also be controlled.

本抑止組成物における有効成分である1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジン(一般名:ジノテフラン。以下、本化合物と記す)は、下記式(I)で示される化合物であり、特開平07−179448号公報に記載される化合物であり、該特許公報に記載された方法により製造することができる。

Figure 2009120504
1-Methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine (generic name: dinotefuran, hereinafter referred to as the present compound), which is an active ingredient in the present deterrent composition, is represented by the following formula (I): Which is a compound described in JP-A-07-179448 and can be produced by the method described in the patent publication.
Figure 2009120504

本抑止組成物は通常、本化合物をゴキブリの喫食性担体(例えば、水や、炭水化物、たんぱく質、脂質等の栄養物)に保持させてなる組成物であり、必要に応じてゴキブリの摂食誘導物質が更に添加される。本抑止組成物における本化合物の含有量は通常0.001%〜10重量%の範囲である。   This deterrent composition is usually a composition in which the present compound is held in a cockroach eating carrier (eg, nutrients such as water, carbohydrates, proteins, lipids, etc.). More material is added. The content of the compound in the deterrent composition is usually in the range of 0.001% to 10% by weight.

本発明において用いられる喫食性担体および摂食誘導物質としては、例えば以下のものが挙げられる。
蔗糖、ブドウ糖、グラニュー糖、果糖、乳糖、麦芽糖、黒砂糖、赤砂糖、三温糖、デキストリン、アラビノース、ガラクトース、ソルビトース、糖蜜、蜂蜜などの糖類;脱脂乳、脱脂粉乳、チーズなどの乳製品;トウモロコシ、ジャガイモ、サツマイモ等に由来する澱粉;小麦粉、米粉、トウモロコシ粉、ジャガイモ粉などの穀物粉;ウシ、ブタ、魚介類、昆虫等の動物粉末や昆虫粉末;ヤシ油、カカオ油、コーン油、ゴマ油、落花生油、サラダ油等の植物油;哺乳類油である体脂、バター脂、鳥類、爬虫類、両生類、昆虫等から得られる油等の動物油;ソース、醤油等の調味料。
Examples of the eating carrier and feeding inducer used in the present invention include the following.
Sugars such as sucrose, glucose, granulated sugar, fructose, lactose, maltose, brown sugar, red sugar, tri-warm sugar, dextrin, arabinose, galactose, sorbitol, molasses, honey; dairy products such as skim milk, skim milk powder and cheese; Starch derived from corn, potato, sweet potato, etc .; Grain flour such as wheat flour, rice flour, corn flour, potato flour; animal powder and insect powder such as cow, pig, seafood, insect; palm oil, cacao oil, corn oil, Vegetable oils such as sesame oil, peanut oil, salad oil; animal oils such as oils obtained from body oils, butter fats, birds, reptiles, amphibians, insects and the like that are mammalian oils; seasonings such as sauces and soy sauces.

また本抑止組成物中には必要により、エリソルビン散、没食子散プロピルなどの酸化防止剤;安息香酸、ソルビン酸、デヒドロ酢散ナトリウム等の誤食防止剤;ホワイトカーボン、ベントナイトなどの増量剤;チーズ香料、バター香料、ピーナッツ香料、ストロベリー香料、ミルク香料、オニオン香料等の香料;黄色4号、赤色2号などの着色料等の助剤を含有させてもよく、その含有量は通常0.001%〜10重量%である。   In addition, antioxidants such as erythorbin powder and gallic powder propyl; antioxidants such as benzoic acid, sorbic acid and sodium dehydroacetate; bulking agents such as white carbon and bentonite; Perfumes such as fragrance, butter fragrance, peanut fragrance, strawberry fragrance, milk fragrance, and onion fragrance; auxiliary agents such as yellow No. 4, red No. 2, etc. may be added, and the content is usually 0.001% to 10% by weight.

また本抑止組成物は本抑止組成物の摂食性を損なわない範囲内にて、更に他の殺虫活性成分を含有させてもよい。かかる殺虫成分としては、ホウ酸、ヒドラメチルノン、N-フェニルピラゾール系化合物、ヘキサフルムロン、フルフェノクスロンなどのキチン形成阻害物質、ピリプロキシフェン、メトプレンなどの幼若ホルモン様物質などを挙げることができる。   In addition, the present deterrent composition may further contain other insecticidal active ingredients as long as the eating property of the present deterrent composition is not impaired. Examples of such insecticidal components include boric acid, hydramethylnon, N-phenylpyrazole compounds, chitin formation inhibitors such as hexaflumuron and flufenoxuron, and juvenile hormone-like substances such as pyriproxyfen and metoprene. Can do.

本抑止組成物は、特にその形態は限定されず、例えば顆粒状、塊状、錠剤形状、液状、半練り状、ゲル状など種々の形態をとりえる。   The form of the present deterrent composition is not particularly limited, and can take various forms such as a granular form, a lump form, a tablet form, a liquid form, a semi-kneaded form, and a gel form.

本発明方法においては、ゴキブリが集まりやすい場所(例えば、台所、食品庫、冷蔵庫の周辺)に、(1)本抑止組成物が粉状、顆粒状、塊状、錠剤形状等の固形物の場合は、本抑止組成物を撒いたり、あるいは開放容器に入れた後に設置する、(2)本抑止組成物が液状の場合は、本抑止組成物を塗布する、(3)本抑止組成物がゲル状もしくは半練り状の場合、本抑止組成物をベイトガン等を用いて隙間に注入したり、付着させたりする等により、設置し、抱卵中のゴキブリ成虫を誘引し、本抑止組成物を摂食させて行う。   In the method of the present invention, in a place where cockroaches are likely to gather (for example, around kitchens, food storage, refrigerators), (1) when the deterrent composition is a solid such as powder, granules, lumps, tablets, etc. (2) If the deterrent composition is liquid, apply this deterrence composition, (3) The deterrence composition is in the form of a gel Alternatively, in the case of a semi-kneaded shape, the deterrent composition is placed by injecting it into the gap using a bait gun or the like, or attached, attracting cockroach adults in the incubation and feeding the deterrent composition. Do it.

本発明方法により、ゴキブリ卵の孵化を抑止することのできるゴキブリの種類としては、チャバネゴキブリ、クロゴキブリ、ヤマトゴキブリ、ワモンゴキブリ、トビイロゴキブリ等が挙げられる。   Examples of cockroaches that can inhibit hatching of cockroaches eggs by the method of the present invention include German cockroaches, black cockroaches, Japanese cockroaches, American cockroaches, flying cockroaches and the like.

以下に実施例により、本発明をさらに詳しく説明するが、本発明はこれらに限定されるものではない。
製剤例1
本化合物の0.2%(w/v)アセトン溶液0.1mlを動物用粉末飼料(CE-2;日本クレア製)1gに滴下し、含浸させた後、充分に風乾した。風乾後、粉砕して、粉末状の本抑止組成物を得た。
製剤例2
ピーナッツバター(アヲハタ株式会社製)5.0g、ゴマ油(かどやの純正ごま油、かどや製油株式会社製)9.0gおよびグリセリン5.0gを加熱しながら混合した。次いで、ここにポリビニルアルコール(ゴーセノールGL‐05、日本合成化学工業株式会社製)の20重量%水溶液5.0g、ウスターソース(カゴメ株式会社製)2.0gおよび糖蜜(中日本氷糖株式会社製)31gを加熱下で加えて均一になるまで攪拌した。更に、本化合物0.5gおよびソルビン酸カリウム2gを加え、デキストリン34.5gおよびκ-カラギーナン6gを順次加えて、十分に混合した後に、室温まで冷却して、ゲル状の本抑止組成物100gを得た。
The present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples.
Formulation Example 1
0.1 ml of 0.2% (w / v) acetone solution of this compound was added dropwise to 1 g of animal powder feed (CE-2; manufactured by CLEA Japan), impregnated, and then sufficiently air-dried. After air drying, it was pulverized to obtain a powdery present inhibitory composition.
Formulation Example 2
Peanut butter (Aohata Co., Ltd.) 5.0 g, sesame oil (Kadoya genuine sesame oil, Kadoya Oil Co., Ltd.) 9.0 g and glycerin 5.0 g were mixed while heating. Next, 5.0 g of 20% by weight aqueous solution of polyvinyl alcohol (Gosenol GL-05, manufactured by Nippon Synthetic Chemical Industry Co., Ltd.), 2.0 g of Worcester sauce (produced by Kagome Co., Ltd.) and 31 g of molasses (produced by Central Nippon Ice Sugar Co., Ltd.) Added under heating and stirred until uniform. Further, 0.5 g of the present compound and 2 g of potassium sorbate were added, 34.5 g of dextrin and 6 g of κ-carrageenan were sequentially added and mixed well, and then cooled to room temperature to obtain 100 g of the gel-like inhibitory composition. .

試験例1
底面に濾紙を敷いた860mlプラスチックカップ内に、製剤例1で得られた粉末状殺卵剤1gと水を設置した。腹部に卵鞘を保持したチャバネゴキブリ♀成虫(Blattella germanica)10頭を該カップ内に放ち、25日後に観察した。
また、対照として、本化合物の0.2%(w/v)アセトン溶液の代わりにヒドラメチルノン(hydramethylnon )の20%(w/v)アセトン溶液を用いた以外は製剤例1と同様にして得られた粉末状の組成物(参考例1)、または有効成分を含有しない粉末状の組成物(参考例2)を用いて同じ試験を行った。試験は2反復で行い、結果を表1に示した。
Test example 1
In a 860 ml plastic cup with filter paper on the bottom, 1 g of the powdered ovicicide obtained in Formulation Example 1 and water were placed. Ten adult German cockroaches ( Battella germanica ) holding egg sheaths in the abdomen were released into the cup and observed 25 days later.
Further, as a control, it was obtained in the same manner as in Formulation Example 1 except that a 20% (w / v) acetone solution of hydramethylnon was used instead of the 0.2% (w / v) acetone solution of the present compound. The same test was conducted using a powdered composition (Reference Example 1) or a powdered composition containing no active ingredient (Reference Example 2). The test was performed in duplicate and the results are shown in Table 1.

(表1).

Figure 2009120504
(Table 1).
Figure 2009120504

本抑止法により、ゴキブリ卵の孵化を効果的に抑止することができる。   By this deterrence method, hatching of cockroach eggs can be effectively deterred.

Claims (4)

ゴキブリ卵の孵化を抑止する方法であって、1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンを有効成分として含有する組成物を抱卵中のゴキブリ成虫に摂食させることを特徴とするゴキブリ卵の孵化抑止方法。 A method for inhibiting hatching of cockroach eggs, which feeds adult cockroaches containing 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine as an active ingredient A method for inhibiting hatching of cockroach eggs, characterized in that. ゴキブリ成虫が、チャバネゴキブリ成虫である請求項1記載のゴキブリ卵の孵化抑止方法。 The method for inhibiting hatching of cockroach eggs according to claim 1, wherein the adult cockroach is an adult cockroach. 1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンを有効成分として含有することを特徴とするゴキブリ卵の孵化抑止組成物。 A composition for inhibiting hatching of cockroach eggs, comprising 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine as an active ingredient. 1‐メチル‐2‐ニトロ‐3‐[(3‐テトラヒドロフリル)メチル]グアニジンの含有量が0.001〜10重量%の範囲である請求項3記載のゴキブリ卵の孵化抑止組成物。 The composition for inhibiting hatching of cockroach eggs according to claim 3, wherein the content of 1-methyl-2-nitro-3-[(3-tetrahydrofuryl) methyl] guanidine is in the range of 0.001 to 10% by weight.
JP2007294044A 2007-11-13 2007-11-13 Method for inhibiting hatching of egg of cockroach Pending JP2009120504A (en)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06183918A (en) * 1992-07-22 1994-07-05 Ciba Geigy Ag Oxadiazine derivative
JP2000053505A (en) * 1998-08-04 2000-02-22 Sumitomo Chem Co Ltd Aqueous baiting agent for extermination of noxious insects
JP2005029562A (en) * 2003-06-16 2005-02-03 Sumitomo Chemical Co Ltd Gel-like poison bait agent for exterminating noxious insect

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06183918A (en) * 1992-07-22 1994-07-05 Ciba Geigy Ag Oxadiazine derivative
JP2000053505A (en) * 1998-08-04 2000-02-22 Sumitomo Chem Co Ltd Aqueous baiting agent for extermination of noxious insects
JP2005029562A (en) * 2003-06-16 2005-02-03 Sumitomo Chemical Co Ltd Gel-like poison bait agent for exterminating noxious insect

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