JP2009113269A - Information recording body and its manufacturing method - Google Patents

Information recording body and its manufacturing method Download PDF

Info

Publication number
JP2009113269A
JP2009113269A JP2007287129A JP2007287129A JP2009113269A JP 2009113269 A JP2009113269 A JP 2009113269A JP 2007287129 A JP2007287129 A JP 2007287129A JP 2007287129 A JP2007287129 A JP 2007287129A JP 2009113269 A JP2009113269 A JP 2009113269A
Authority
JP
Japan
Prior art keywords
layer
information recording
particles
recording body
transfer medium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2007287129A
Other languages
Japanese (ja)
Inventor
Makoto Maehira
誠 前平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toppan Inc
Original Assignee
Toppan Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toppan Printing Co Ltd filed Critical Toppan Printing Co Ltd
Priority to JP2007287129A priority Critical patent/JP2009113269A/en
Publication of JP2009113269A publication Critical patent/JP2009113269A/en
Pending legal-status Critical Current

Links

Images

Abstract

<P>PROBLEM TO BE SOLVED: To provide an information recording body which is manufactured by using an intermediate transfer medium and a medium to be transferred configured in such a manner that an easy-adhesion layer is stacked to one surface of a base material layer, strong in adhesion between each layer, regardless of the kind of the base material layer of the medium to be transferred and hardly forged, and to provide the manufacturing method of the information recording body. <P>SOLUTION: The information recording body is configured in such a manner that from the peeling layer of the intermediate transfer medium having the peeling layer and an adhesion layer used also as an image receiving layer on which information is recorded on at least one surface of a supporting base material layer in this order to the adhesion layer used also as the image receiving layer of the intermediate transfer medium is heated and transferred to the easy-adhesion layer surface of the medium to be transferred configured in such a manner that the easy-adhesion layer comprising at least a thermoplastic resin and thermally expandable particles is stacked to one surface of the base material layer. Heat expanded particles configured in such a manner that the thermally expandable particles are expanded are any one or more of colorless particles, coloring particles, particles excited by ultraviolet light, to emit light in a visible wavelength region and particles emitting light in an infrared wavelength region. The information recording body and the manufacturing method of the information recording body are provided. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、通帳、パスポート、免許証、各種証明書等の情報記録体及びその製造方法に関するものである。   The present invention relates to an information recording body such as a passbook, passport, driver's license, various certificates, and a method for manufacturing the same.

カード形状または冊子形状で、それらに画像や文字などの情報を記載した免許証、パスポートなどの各種証明書としての情報記録体が広く用いられている。前記情報記録体を作成する手段として、熱転写によって画像および文字などの情報を形成・担持してなる中間転写媒体の情報を被転写媒体に転写形成するものがある。前記情報記録体の作成に用いる熱転写可能な中間転写媒体は、例えば、支持基材層の片面に剥離層、中間層、受像層兼接着層を順次積層した構成であり、転写する時は、該受像層兼接着層側を被転写媒体上に重ねて加熱、加圧した後に、支持基材層のみを引き剥がして、残りの剥離層と中間層と受像層兼接着層を転写する。受像層兼接着層は、感熱転写プリンタやインクジェットプリンタ等の印刷技術によって、印刷の版無しで画像情報(文字、記号、等も含む)を記録できる受像適性を備えた層であり、中間転写媒体の転写前に染料または顔料による画像を設けることが可能となる。受像層兼接着層への情報の形成方法として、中間転写媒体をドラムとサーマルヘッドとでその主要部が構成される転写装置へ搬送し、色材が熱移行性材料である転写リボンの色材層を中間転写媒体の受像層兼接着層に当接させると共に、転写リボン側から前記サーマルヘッドを圧接し、かつ、画像データに基づき前記サーマルヘッドの発熱素子群を適宜発熱させて、画像データに基づく画像パターンを前記受像層兼接着層に形成、印刷する。なお、画像データが多色である場合には、色調の異なる転写リボン又は色調の異なる色材層を有する転写リボンを適用し、同様な工程を繰返して前記受像層兼接着層に多色の画像パターンが形成される。なお、前記中間層としては、例えば、OVD(Optical Variable Device)層があり、必要に応じて設ける。中間転写媒体を用いた、偽造防止性を有する情報記録体(例えば、特許文献1参照。)が提案されている。
特開2000−6555号公報
Information recording bodies are widely used as various certificates such as licenses, passports, etc. in which information such as images and characters is written in card or booklet shapes. As a means for producing the information recording body, there is a means for transferring and forming information on an intermediate transfer medium formed by carrying information such as images and characters by thermal transfer onto a transfer medium. The intermediate transfer medium capable of thermal transfer used for the preparation of the information recording body has, for example, a structure in which a release layer, an intermediate layer, and an image receiving layer / adhesive layer are sequentially laminated on one side of a support base material layer. After the image-receiving layer / adhesive layer side is superimposed on the transfer medium and heated and pressurized, only the supporting base material layer is peeled off, and the remaining release layer, intermediate layer, and image-receiving layer / adhesive layer are transferred. The image receiving layer / adhesive layer is a layer having an image receiving ability capable of recording image information (including characters, symbols, etc.) without a printing plate by a printing technique such as a thermal transfer printer or an ink jet printer. It is possible to provide an image with a dye or a pigment before transfer of the toner. As a method for forming information on the image receiving layer / adhesive layer, the intermediate transfer medium is transported to a transfer device comprising the main part of the drum and the thermal head, and the color material of the transfer ribbon is a heat transfer material. The layer is brought into contact with the image receiving layer / adhesive layer of the intermediate transfer medium, the thermal head is pressed from the transfer ribbon side, and the heating element group of the thermal head is appropriately heated on the basis of the image data, thereby generating the image data. An image pattern based thereon is formed and printed on the image receiving layer / adhesive layer. When the image data is multicolored, a transfer ribbon having a different color tone or a transfer ribbon having a color material layer having a different color tone is applied, and the same process is repeated to obtain a multicolor image on the image receiving layer / adhesive layer. A pattern is formed. The intermediate layer includes, for example, an OVD (Optical Variable Device) layer, which is provided as necessary. An information recording body having an anti-counterfeiting property using an intermediate transfer medium (for example, see Patent Document 1) has been proposed.
JP 2000-6555 A

しかしながら、前記提案されている情報記録体は、基材層の表面に凹凸を有する場合など、その凹凸部分で熱圧のかかり方が異なるため、中間転写媒体の密着強度に差が生じ、外部負荷をかけた場合に部分的な損傷を生じる可能性があった。特に、この問題は基材層が紙の場合に顕著であり、紙の種類によっては繊維の空隙が大きいため、空隙部分で中間転写体と基材層が密着せず、部分的に破壊が生じる問題があった。   However, the proposed information recording body has different unevenness in the adhesion strength of the intermediate transfer medium due to the difference in the application of heat pressure at the uneven portions, such as when the surface of the substrate layer has unevenness, and the external load May cause partial damage. In particular, this problem is remarkable when the base material layer is paper. Depending on the type of paper, the fiber gap is large, so the intermediate transfer member and the base material layer do not adhere to each other in the gap portion, resulting in partial destruction. There was a problem.

本発明の課題は、中間転写媒体と、基材層の片面に易接着層を積層してなる被転写媒体と、を用いて製造した情報記録体であって、被転写媒体の基材層の種類によらず各層間の密着が強固で、且つ、偽造し難い情報記録体及びその製造方法を提供することにある。   An object of the present invention is an information recording body manufactured using an intermediate transfer medium and a transfer medium in which an easy-adhesion layer is laminated on one side of a base material layer. An object of the present invention is to provide an information recording body and a method for manufacturing the same, in which the adhesion between the layers is strong regardless of the type and is difficult to forge.

本発明の請求項1に係る発明は、支持基材層の片面に少なくとも、剥離層、情報が記録された受像層兼接着層を前記順序で有する中間転写媒体の剥離層から受像層兼接着層迄を、基材層の片面に熱可塑性樹脂と、熱発泡性粒子と、からなる易接着層を積層してなる被転写媒体の易接着層面に加熱転写してなる情報記録体であって、前記熱発泡性粒子が発泡してなる加熱発泡済み粒子が無色の粒子、着色された粒子、紫外光で励起され可視波長領域で発光する粒子、赤外光又は可視光で励起され赤外波長領域又は可視波長領域で発光する粒子のいずれか1種以上であることを特徴とする情報記録体である。   According to the first aspect of the present invention, there is provided an image-receiving layer / adhesive layer from a release layer of an intermediate transfer medium having at least a release layer and an image-receiving layer / adhesive layer on which information is recorded in the above order on one side of a support base material layer. Up to, an information recording body formed by heat-transferring to an easily adhesive layer surface of a medium to be transferred formed by laminating an easily adhesive layer composed of a thermoplastic resin and thermally foamable particles on one side of a base material layer, Heat-foamed particles formed by foaming the thermally foamable particles are colorless particles, colored particles, particles that are excited by ultraviolet light and emit light in the visible wavelength region, infrared light or infrared light that is excited by visible light and infrared wavelength region. Or it is any 1 or more types of particle | grains which light-emit in visible wavelength range, It is an information recording body characterized by the above-mentioned.

本発明の請求項2に係る発明は、上記請求項1に係る発明において、前記被転写媒体の易接着層に蛍光体が含まれていることを特徴とする情報記録体である。   The invention according to claim 2 of the present invention is the information recording body according to claim 1, wherein the easy-adhesion layer of the transfer medium contains a phosphor.

本発明の請求項3に係る発明は、上記請求項2に係る発明において、前記蛍光体の平均粒子径が1〜10μmであることを特徴とする情報記録体である。   The invention according to claim 3 of the present invention is the information recording body according to claim 2, wherein the phosphor has an average particle diameter of 1 to 10 μm.

本発明の請求項4に係る発明は、上記請求項1乃至請求項3のいずれか1項に係る発明において、前記熱発泡性粒子の平均粒子径が未発泡時に10μm以下であることを特徴とする情報記録体である。   The invention according to claim 4 of the present invention is the invention according to any one of claims 1 to 3, characterized in that an average particle size of the thermally expandable particles is 10 μm or less when unexpanded. It is an information recording body.

本発明の請求項5に係る発明は、上記請求項1乃至請求項4のいずれか1項記載の情報記録体の剥離層と受像層兼接着層との間に、回折格子構造体が形成されたOVD(Optical Variable Device)層を有することを特徴とする情報記録体である。   According to a fifth aspect of the present invention, a diffraction grating structure is formed between the release layer and the image receiving layer / adhesive layer of the information recording body according to any one of the first to fourth aspects. An information recording medium comprising an optical variable device (OVD) layer.

本発明の請求項6に係る発明は、上記請求項1乃至請求項5のいずれか1項記載の情報記録体に、さらにエンボス模様が施されていることを特徴とする情報記録体である。   An invention according to claim 6 of the present invention is an information recording body, wherein the information recording body according to any one of claims 1 to 5 is further provided with an embossed pattern.

本発明の請求項7に係る発明は、上記請求項1乃至請求項6のいずれか1項に係る発明において、前記被転写媒体の易接着層中の熱発泡性粒子が加熱転写温度より低い温度で発泡することを特徴とする情報記録体である。   The invention according to claim 7 of the present invention is the invention according to any one of claims 1 to 6, wherein the heat-expandable particles in the easy-adhesion layer of the transfer medium are lower than the heat transfer temperature. It is an information recording body characterized by foaming.

本発明の請求項8に係る発明は、支持基材層の片面に少なくとも、剥離層、情報が記録された受像層兼接着層を前記順序で有する中間転写媒体の受像層兼接着層側を、基材層の片面に熱可塑性樹脂と、熱発泡性粒子と、からなる易接着層を積層してなる被転写媒体の易接着層面に重ね合わせ、中間転写媒体側から加熱、加圧して被転写媒体の易接着層中の熱発泡性粒子を発泡させ、加熱発泡済み粒子を生成させた状態で支持基材層を引き剥がすことを特徴とする情報記録体の製造方法である。   In the invention according to claim 8 of the present invention, the image receiving layer / adhesive layer side of the intermediate transfer medium having at least the release layer and the image receiving layer / adhesive layer on which information is recorded in the above order on one side of the support base material layer, The substrate layer is superposed on the easy-adhesion layer surface of the transfer medium, which is made by laminating an easy-adhesion layer consisting of thermoplastic resin and thermally foamable particles on one side, and is transferred by applying heat and pressure from the intermediate transfer medium side. A method for producing an information recording body, comprising: foaming heat-foamable particles in an easy-adhesion layer of a medium, and peeling off a support base material layer in a state where heat-foamed particles are generated.

本発明の請求項9に係る発明は、上記請求項8に係る発明において、前記被転写媒体の易接着層中に蛍光体が含まれていることを特徴とする情報記録体の製造方法である。   The invention according to claim 9 of the present invention is the method for manufacturing an information recording body according to the invention according to claim 8, wherein the easy-adhesion layer of the transfer medium contains a phosphor. .

本発明の請求項10に係る発明は、上記請求項8又は請求項9に係る発明において、表面に凹凸を有する加熱ロールで加熱、加圧することを特徴とする情報記録体の製造方法である。   The invention according to claim 10 of the present invention is the method for manufacturing an information recording body according to the invention according to claim 8 or claim 9, wherein the surface is heated and pressurized with a heating roll having irregularities.

本発明の情報記録体は、支持基材層の片面に少なくとも、剥離層、情報が記録された受像層兼接着層を前記順序で有する中間転写媒体の剥離層から受像層兼接着層迄を、基材層の片面に熱可塑性樹脂と、熱発泡性粒子と、からなる易接着層を積層してなる被転写媒体の易接着層面に加熱転写してなる情報記録体であって、前記熱発泡性粒子が発泡してなる加熱発泡済み粒子が無色の粒子、着色された粒子、紫外光で励起され可視波長領域で発光する粒子、赤外光又は可視光で励起され赤外波長領域又は可視波長領域で発光する粒子のいずれか1種以上であるので、偽造、改竄がし難い。また、被転写媒体の易接着層中に蛍光体を含有させることで、偽造、改竄防止効果が高まる。さらに、情報記録体に回折格子構造体が形成されたOVD(Optical Variable Device)層あるいはエンボス模様を具備させることで、偽造、改竄防止効果がさらに高まる。また、支持
基材層の片面に少なくとも、剥離層、情報が記録された受像層兼接着層を前記順序で有する中間転写媒体の受像層兼接着層側を、基材層の片面に少なくとも、熱可塑性樹脂と、熱発泡性粒子と、からなる易接着層を積層してなる被転写媒体の易接着層面に重ね合わせ、中間転写媒体側から加熱、加圧して被転写媒体の易接着層中の熱発泡性粒子を発泡させ、加熱発泡済み粒子を生成させた状態で、支持基材層を引き剥がす方法で製造するので、被転写媒体の基材層が表面に凹凸を有する紙の場合でも、中間転写媒体の加熱転写時に被転写媒体の易接着層の熱発泡性粒子が発泡し且つ熱可塑性樹脂が流動することで、受像層兼接着層と易接着層との密着不良が生じ難く、十分な密着が得られる。
The information recording body of the present invention has at least a release layer on one side of the support base material layer, from the release layer of the intermediate transfer medium having the image receiving layer / adhesive layer in which information is recorded to the image receiving layer / adhesive layer in the above order, An information recording body formed by heating and transferring to an easy-adhesion layer surface of a medium to be transferred, wherein an easy-adhesion layer comprising a thermoplastic resin and thermally foamable particles is laminated on one side of a base material layer, Heat-foamed particles formed by foaming conductive particles are colorless particles, colored particles, particles excited by ultraviolet light and emitting in the visible wavelength region, infrared light or visible light excited by infrared wavelength region or visible wavelength Since any one or more of the particles that emit light in the region, forgery and alteration are difficult. In addition, forgery and tampering prevention effects are enhanced by including a phosphor in the easy-adhesion layer of the transfer medium. Furthermore, by providing an OVD (Optical Variable Device) layer or an embossed pattern in which the diffraction grating structure is formed on the information recording body, the effect of preventing forgery and tampering is further enhanced. In addition, the image-receiving layer / adhesive layer side of the intermediate transfer medium having at least the release layer and the image-receiving layer / adhesive layer on which information is recorded in the above order on one side of the support base layer is at least on one side of the base layer. Overlay the easy-adhesion layer surface of the transfer medium formed by laminating an easy-adhesion layer composed of a plastic resin and thermally foamable particles, and heat and press from the intermediate transfer medium side in the easy-adhesion layer of the transfer medium. In the state where the thermally foamable particles are foamed and the heat-foamed particles are generated, the support base material layer is manufactured by the method of peeling off, so even when the base material layer of the transfer medium is a paper having irregularities on the surface, The heat-foamable particles of the easy-adhesion layer of the transfer medium foam and the thermoplastic resin flows during the heat transfer of the intermediate transfer medium, and it is difficult to cause poor adhesion between the image receiving layer / adhesive layer and the easy-adhesion layer. Good adhesion.

本発明の情報記録体及びその製造方法を、実施の形態に沿って以下に詳細に説明する。図2(a)は本発明の情報記録体に使用する被転写媒体の一実施形態を示す拡大側断面図であり、被転写媒体(10)は厚み方向に順に、熱可塑性樹脂(16)と熱発泡性粒子(17)とからなる易接着層(12)、基材層(11)を積層した構成になっている。図2(b)は本発明の情報記録体に使用する被転写媒体の他の実施形態を示す拡大側断面図であり、被転写媒体(10′)は厚み方向に順に、熱可塑性樹脂(16)と熱発泡性粒子(17)と蛍光体(18)とからなる易接着層(13)、基材層(11)を積層した構成になっている。   The information recording body and the manufacturing method thereof according to the present invention will be described in detail below along the embodiments. FIG. 2A is an enlarged side cross-sectional view showing an embodiment of a transfer medium used for the information recording medium of the present invention. The transfer medium (10) includes a thermoplastic resin (16) and a thermoplastic resin (16) in the thickness direction. It has the structure which laminated | stacked the easily bonding layer (12) which consists of a thermally foamable particle (17), and a base material layer (11). FIG. 2B is an enlarged side sectional view showing another embodiment of the transfer medium used in the information recording medium of the present invention. The transfer medium (10 ′) is in the order of the thermoplastic resin (16 ′) in the thickness direction. ), Heat-expandable particles (17) and phosphor (18), and an easy adhesion layer (13) and a base material layer (11) are laminated.

前記基材層(11)に使用する材料としては、紙、ポリエチレンテレフタレートやポリエチレンナフタレートのポエステル系フィルム、ポリ塩化ビニルフィルム、ポリカーボネートフィルム、ポリメタクリル酸メチルフィルム、ポリスチレンフィルムあるいは、前記フィルムや紙が種々組み合わされた積層フィルムが使用可能である。   Examples of the material used for the substrate layer (11) include paper, polyethylene terephthalate or polyethylene naphthalate polyester film, polyvinyl chloride film, polycarbonate film, polymethyl methacrylate film, polystyrene film, or the film or paper. Various combinations of laminated films can be used.

前記熱可塑性樹脂(16)の種類としては、ウレタン系樹脂、アクリル系樹脂、酢酸ビニル樹脂あるいは、前記各樹脂を混合した混合樹脂が使用可能である。   As the kind of the thermoplastic resin (16), urethane resin, acrylic resin, vinyl acetate resin, or a mixed resin obtained by mixing the above resins can be used.

前記熱発泡性粒子(17)は、熱可塑性樹脂からなる外殻内に液状ガスを内包してなる球状粒子からなっており、加熱転写時の温度よりも低い温度で発泡する。外殻に使用する樹脂としては、ポリスチレン樹脂、ポリオレフィン系樹脂、ポリウレタン系樹脂、ポリ塩化ビニル樹脂、前記各樹脂に染料を混練した着色樹脂、前記各樹脂に紫外光で励起され可視波長領域で発光する蛍光染料を混練した樹脂、前記樹脂に赤外光又は可視光で励起され赤外波長領域又は可視波長領域で発光する蛍光染料を混練した樹脂などが使用される。平均粒子径は未発泡時に10μm以下が好ましい。   The thermally foamable particles (17) are spherical particles formed by enclosing a liquid gas in an outer shell made of a thermoplastic resin, and foam at a temperature lower than the temperature at the time of heat transfer. As the resin used for the outer shell, polystyrene resin, polyolefin resin, polyurethane resin, polyvinyl chloride resin, colored resin in which each resin is kneaded with a dye, each resin is excited by ultraviolet light and emits light in the visible wavelength region. A resin kneaded with a fluorescent dye, a resin kneaded with a fluorescent dye excited with infrared light or visible light and emitting light in the infrared wavelength region or visible wavelength region, and the like are used. The average particle size is preferably 10 μm or less when unfoamed.

前記蛍光体(18)は、赤外波長領域又は可視波長領域で発光し、平均粒子径が1〜10μmの範囲のものが好ましい。1μm未満の場合は発光強度が低下することがあり、10μmを超えると場合によっては易接着層の表面から蛍光体粒子が飛び出てしまい、中間転写媒体を転写する時に種々の弊害がでる。   The phosphor (18) emits light in the infrared wavelength region or visible wavelength region, and preferably has an average particle diameter in the range of 1 to 10 μm. If the thickness is less than 1 μm, the emission intensity may decrease. If the thickness exceeds 10 μm, the phosphor particles may jump out from the surface of the easy-adhesion layer, which causes various problems when transferring the intermediate transfer medium.

前記易接着層(12、13)の形成方法は、前記熱可塑性樹脂(16)と熱発泡性粒子(17)を水中で分散しエマルジョン化したインキ、あるいは、前記熱可塑性樹脂(16)と熱発泡性粒子(17)と蛍光体(18)とを水中で分散しエマルジョン化したインキを用いて、公知のスクリーン印刷等の印刷法で基材層(11)上に形成する。厚さは、3〜20μmが好ましく、3μm未満であると接着性能が発現し難いなどの不都合が生じ、20μmを超えると形成が困難になるので良くない。   The easy-adhesion layers (12, 13) can be formed by an ink in which the thermoplastic resin (16) and the thermally foamable particles (17) are dispersed and emulsified in water, or the thermoplastic resin (16) and the heat. The foamable particles (17) and the phosphors (18) are formed on the base material layer (11) by a known printing method such as screen printing using an ink dispersed in water and emulsified. The thickness is preferably 3 to 20 μm, and if it is less than 3 μm, problems such as difficulty in developing adhesive performance occur, and if it exceeds 20 μm, formation becomes difficult.

図3は本発明の情報記録体に使用する中間転写媒体の一実施形態を示す側断面図であり、中間転写媒体(20)は、厚み方向に順に、支持基材層(21)、剥離層(22)、中間層(23)、受像層兼接着層(24)を積層した構成になっている。   FIG. 3 is a side sectional view showing an embodiment of an intermediate transfer medium used in the information recording medium of the present invention. The intermediate transfer medium (20) is composed of a supporting base layer (21) and a release layer in the thickness direction. (22), an intermediate layer (23) and an image receiving layer / adhesive layer (24) are laminated.

前記支持基材層(21)は、受像層兼接着層(24)に使用される材料より溶融温度又は軟化温度が高い材料からなっており、例えば、ポリエチレンテレフタレート、ポリエチレンナフタレート、ポリ塩化ビニル、ポリエステル、ポリカーボネート、ポリメタクリル酸メチル、ポリスチレン等の合成樹脂のフィルム、または紙、合成紙などを単独で又はそれらを組み合わせた複合体が使用可能である。   The support base layer (21) is made of a material having a higher melting temperature or softening temperature than the material used for the image receiving layer / adhesive layer (24). For example, polyethylene terephthalate, polyethylene naphthalate, polyvinyl chloride, A synthetic resin film such as polyester, polycarbonate, polymethyl methacrylate, polystyrene or the like, or a composite of paper, synthetic paper or the like alone or in combination thereof can be used.

前記剥離層(22)は、被転写体に転写するときは優れた剥離性を有し、転写後は保護層として機能する。使用する材料としては、アクリル系樹脂、塩化ゴム系樹脂、塩化ビニル・酢酸ビニル共重合樹脂、セルロース系樹脂、塩素化ポリプロピレン樹脂、あるいは前記樹脂にフッ化エチレンパウダー、ポリエチレンパウダー、動物系ワックス、植物系ワックス、鉱物系ワックス、石油系ワックス等の天然ワックス、合成炭化水素系ワックス、脂肪酸エステルとグリセライト系ワックス、水素化ワックス、合成ケトン系ワックス、アミン及びアマイド系ワックス、塩素化炭化水素系ワックス、合成動物ロウ系ワックス、アルファーオレフィン系ワックス等の合成ワックス、ステアリン酸亜鉛等の高級脂肪酸の金属塩などの耐摩擦剤、無機物の少なくとも1種類を添加した混合物が使用される。   The release layer (22) has excellent release properties when transferred to a transfer target, and functions as a protective layer after transfer. Materials used include acrylic resin, chlorinated rubber resin, vinyl chloride / vinyl acetate copolymer resin, cellulose resin, chlorinated polypropylene resin, or fluorinated ethylene powder, polyethylene powder, animal wax, plant Waxes, mineral waxes, natural waxes such as petroleum waxes, synthetic hydrocarbon waxes, fatty acid esters and glycerite waxes, hydrogenated waxes, synthetic ketone waxes, amine and amide waxes, chlorinated hydrocarbon waxes, Synthetic waxes such as synthetic animal waxes and alpha-olefin waxes, and anti-friction agents such as metal salts of higher fatty acids such as zinc stearate, and a mixture to which at least one of inorganic substances are added are used.

前記中間層(23)の種類としては、印刷層やOVD(Optical Variable Device)形成層などがある。前記OVD形成層はホログラム形成層と透過性薄膜層とからなり、ホログラム形成層はホログラム形成用樹脂層の表面に微細な凹凸パターンが設けられている。ホログラム形成用樹脂はエンボス成形性が良好で、プレスムラが生じ難く、明るい再生像が得られ、隣接層との接着性が良好な樹脂が良い。例えば、ポリカーボネート樹脂、ポリスチレン樹脂、ポリ塩化ビニル樹脂、不飽和ポリエステル樹脂、メラミン樹脂、エポキシ樹脂、ウレタン(メタ)アクリレート樹脂、ポリエステル(メタ)アクリレート樹脂、エポキシ(メタ)アクリレート樹脂、ポリオール(メタ)アクリレート樹脂、メラミン(メタ)アクリレート樹脂、トリアジン(メタ)アクリレート樹脂あるいは前記樹脂の混合物、ラジカル重合性不飽和基を有する樹脂などが使用可能であり、また、前記以外のものでも、ホログラム画像を形成可能な安定性を有する材料であれば使用可能である。透過性薄膜層はホログラム形成層の情報を透過するための透明材料であって、ホログラム形成層(屈折率n=1.3〜1.5)よりも屈折率の高いことが装飾性の向上に好ましい。さらに、透過性薄膜層は、複数の層を重ね合わせて形成してもよく、異なる屈折率の層の組み合わせ、高屈折率の層と低屈折率の層とを交互に積層した多層膜としてもよい。透過性薄膜層を形成する方法としては、真空蒸着法の他にスパッタリング法、イオンプレーティング法等の成膜手段が適用可能であり、膜厚としては10nm〜1000nmの範囲内にあることが好ましい。なお、ホログラムとしてはレリーフ型ホログラム、リップマンホログラムなどの体積位相型ホログラムなどがある。   Examples of the type of the intermediate layer (23) include a printed layer and an OVD (Optical Variable Device) forming layer. The OVD forming layer includes a hologram forming layer and a transmissive thin film layer, and the hologram forming layer is provided with a fine uneven pattern on the surface of the hologram forming resin layer. The resin for forming a hologram is preferably a resin having good embossing moldability, hardly causing press unevenness, obtaining a bright reproduced image, and having good adhesion to an adjacent layer. For example, polycarbonate resin, polystyrene resin, polyvinyl chloride resin, unsaturated polyester resin, melamine resin, epoxy resin, urethane (meth) acrylate resin, polyester (meth) acrylate resin, epoxy (meth) acrylate resin, polyol (meth) acrylate Resin, melamine (meth) acrylate resin, triazine (meth) acrylate resin or a mixture of the above resins, resins having a radical polymerizable unsaturated group, etc. can be used, and hologram images can be formed with other than the above Any material having excellent stability can be used. The transparent thin film layer is a transparent material for transmitting information of the hologram forming layer, and a higher refractive index than the hologram forming layer (refractive index n = 1.3 to 1.5) improves the decorativeness. preferable. Further, the transmissive thin film layer may be formed by superposing a plurality of layers, or may be a multilayer film in which layers of different refractive indexes are combined, or high refractive index layers and low refractive index layers are alternately laminated. Good. As a method for forming the transmissive thin film layer, film forming means such as sputtering and ion plating can be applied in addition to the vacuum deposition method, and the film thickness is preferably in the range of 10 nm to 1000 nm. . Note that the hologram includes volume phase holograms such as relief holograms and Lippmann holograms.

前記受像層兼接着層(24)は、熱可塑性樹脂からなっており、種類としては、塩化ビニル/酢酸ビニル共重合体樹脂、ポリエステル系樹脂、ポリアミド系樹脂、アクリル系樹脂等が使用される。   The image receiving layer / adhesive layer (24) is made of a thermoplastic resin, and as the kind, vinyl chloride / vinyl acetate copolymer resin, polyester resin, polyamide resin, acrylic resin, or the like is used.

図1(a)は本発明の情報記録体の一実施形態を示す拡大側断面図であり、情報記録体(1)は、前記中間転写媒体(20)及び前記被転写体(10)を用いて作成しており、厚み方向に順に、剥離層(22)、中間層(23)、受像層兼接着層(24)、熱可塑性樹脂(16)と加熱発泡済み粒子(19)からなる易接着層(14)、基材層(11)を積層した構成になっており、(b)は本発明の情報記録体の他の実施形態を示す拡大側断面図であり、情報記録体(2)は、前記中間転写媒体(20)及び前記被転写体(10´)を用いて作成しており、厚み方向に順に、剥離層(22)、中間層(23)、受像層兼接着層(24)、熱可塑性樹脂(16)と加熱発泡済み粒子(19)と蛍光体(18)からなる易接着層(15)、基材層(11)を積層した構成になっている。   FIG. 1A is an enlarged side sectional view showing an embodiment of an information recording body of the present invention. The information recording body 1 uses the intermediate transfer medium 20 and the transfer target 10. Easy adhesion consisting of release layer (22), intermediate layer (23), image receiving layer / adhesive layer (24), thermoplastic resin (16) and heat-foamed particles (19) in the thickness direction. The layer (14) and the base material layer (11) are laminated, (b) is an enlarged side sectional view showing another embodiment of the information recording body of the present invention, and the information recording body (2). Is formed using the intermediate transfer medium (20) and the transfer target (10 ′), and in the order of thickness, a release layer (22), an intermediate layer (23), and an image receiving layer / adhesive layer (24). ), An easily adhesive layer (15) comprising a thermoplastic resin (16), heat-foamed particles (19) and a phosphor (18), a base material It has become to the laminated structure (11).

図4(a)〜(c)は本発明の情報記録体の製造方法の一実施形態を示す説明図であり、図4(a)は、前記中間転写媒体(20)の受像層兼接着層(24)側を前記被転写媒体(10)の易接着層(12)上に重ねあわせ、中間転写媒体(20)側からで熱(T)及び応力(P)を加えて加熱、加圧する工程を示す図である。中間転写媒体(20)の受像層兼接着層(24)には前もって情報を記録しておく。図4(b)は、図4(a)の工程後、被転写媒体(10)の易接着層(12)中の熱発泡性粒子(17)が発泡し、体積が膨張してなる加熱発泡済み粒子(19)が生成すると共に、熱可塑性樹脂(16)が流動して易接着層(14)の受像層兼接着層(24)側の表面凹凸が無くなっている状態を示す図である。従って、受像層兼接着層(24)と易接着層(14)との密着が強固になる。図4(c)は、図4(b)の工程後、中間転写媒体(20)の支持基材層(21)のみを応力(P)で引き剥がし、剥離層(22)、中間層(23)、受像層兼接着層(24)を転写する工程を示す図である。   4A to 4C are explanatory views showing an embodiment of the method for producing an information recording body of the present invention. FIG. 4A is an image receiving layer / adhesive layer of the intermediate transfer medium (20). (24) A step of superimposing the side of the transfer medium (10) on the easy-adhesion layer (12) and applying heat (T) and stress (P) from the intermediate transfer medium (20) side to heat and pressurize. FIG. Information is recorded in advance on the image receiving / adhesive layer (24) of the intermediate transfer medium (20). FIG. 4B shows a thermal foaming process in which the thermally expandable particles (17) in the easy-adhesion layer (12) of the transfer medium (10) are foamed and the volume is expanded after the process of FIG. 4 (a). It is a figure which shows the state from which the surface unevenness | corrugation by the side of an image receiving layer and adhesive layer (24) of an easily bonding layer (14) is lose | eliminated as a finished particle (19) produces | generates and thermoplastic resin (16) flows. Accordingly, the adhesion between the image receiving layer / adhesive layer (24) and the easy-adhesive layer (14) is strengthened. In FIG. 4C, after the step of FIG. 4B, only the support base material layer (21) of the intermediate transfer medium (20) is peeled off by stress (P), and the release layer (22) and the intermediate layer (23 ) And a step of transferring the image receiving layer and adhesive layer (24).

さらに、図示はしていないが、図4(a)の工程で、表面に凹凸模様を有する加熱ロールを用いて、加熱、加圧すれば、情報記録体自身にエンボス模様を形成することができる。   Further, although not shown, an embossed pattern can be formed on the information recording body itself by heating and pressurizing using a heating roll having a concavo-convex pattern on the surface in the step of FIG. .

以下に、本発明の情報記録体を具体的な実施例に従って説明するが、本発明がこれらの実施例に限定されるものではない。
〈着色熱発泡性粒子の作成〉
エタノールに赤色染料「KAYASET RED SF−B」(日本化薬製)を5重量%で分散させ、その中に熱発泡性粒子(日本フィライト(株)、商品名:EXPANCEL、551−20)を浸漬させた後引き上げ、乾燥させ、平均粒径7μm、軟化温度が100℃の着色熱発泡性粒子を作成した。
〈易接着層(12)に使用するインキAの作成〉
前記の着色発泡性粒子を水系ウレタンエマルジョンに5重量%で分散させたインキAを作成した。
〈易接着層に使用するインキBの作成〉
水系ウレタンエマルジョン単体のインキBを作成した。
〈易接着層(12)に使用するインキCの作成〉
水系ウレタンエマルジョンに赤外蛍光顔料(平均粒子径 D50=2.4μm、D90=8.4μm)5重量%と、熱発泡性粒子(日本フィライト(株)、商品名:EXPANCEL、551−20)5重量%を分散させたインキCを作成した。
〈易接着層に使用するインキDの作成〉
水系ウレタンエマルジョンに赤外蛍光顔料(平均粒子径 D50=2.4μm、D90=8.4μm)を5重量%分散させたインキDを作成した。
〈スクリーン印刷版の作成〉
300線/インチのメッシュのポリエステル製クロスを650mm×650mmの枠に貼り、これに乳剤を塗布し、別途作成したポジフィルムを使用して露光し、公知の方法でスクリーン印刷版を作成した。
Hereinafter, the information recording medium of the present invention will be described according to specific examples, but the present invention is not limited to these examples.
<Creation of colored thermally foamable particles>
A red dye “KAYASET RED SF-B” (manufactured by Nippon Kayaku Co., Ltd.) is dispersed in ethanol at 5% by weight, and heat-expandable particles (Nippon Philite Co., Ltd., trade name: EXPANCEL, 551-20) are immersed therein. Then, it was pulled up and dried to produce colored thermally foamable particles having an average particle diameter of 7 μm and a softening temperature of 100 ° C.
<Preparation of ink A used for easy-adhesion layer (12)>
Ink A was prepared by dispersing the colored foamable particles in an aqueous urethane emulsion at 5% by weight.
<Creation of ink B used for easy adhesion layer>
Ink B of a water-based urethane emulsion alone was prepared.
<Preparation of ink C used for easy adhesion layer (12)>
Infrared fluorescent pigment (average particle size D50 = 2.4 μm, D90 = 8.4 μm) 5% by weight in water-based urethane emulsion and thermally foamable particles (Nippon Philite Co., Ltd., trade name: EXPANCEL, 551-20) 5 Ink C in which wt% was dispersed was prepared.
<Creation of ink D used for easy adhesion layer>
Ink D was prepared by dispersing 5% by weight of an infrared fluorescent pigment (average particle size D50 = 2.4 μm, D90 = 8.4 μm) in an aqueous urethane emulsion.
<Creation of screen printing version>
A 300-line / inch mesh polyester cloth was applied to a 650 mm × 650 mm frame, an emulsion was coated on the cloth, and exposed using a separately prepared positive film to prepare a screen printing plate by a known method.

基材層(11)として、180Kgベースの用紙(東海パルプ(株)、わらがみ)を使用して、最初に、前記用紙に前記作成したスクリーン印刷版を用いて、前記インキAで厚み5μmの易接着層(12)を形成し、90mm×55mmの大きさの被転写媒体(10)を作成した。引き続いて、中間転写媒体(20)として、支持基材層(21)の上に剥離層(22)、受像層兼接着層(24)を有する中間転写フィルムを使用し、その中間転写フィルムの受像層兼接着層(24)にカードプリンタCP300FX装置(凸版印刷株式会社製)を用いて、専用色リボンから画像情報を形成し、しかる後に前記装置の内蔵ヒー
トロールを使用して、表面温度は180℃で、転写速度は6mm/秒で、前記作成した被転写媒体(10)の易接着層(12)上に中間転写フィルムの剥離層と画像情報が形成された受像層兼接着層とを転写させて、本発明の情報記録体を作成した。
Using 180 Kg-based paper (Tokai Pulp Co., Ltd., straw) as the base material layer (11), first, using the screen printing plate prepared on the paper, the thickness of the ink A is 5 μm. The easy-adhesion layer (12) was formed, and a transfer medium (10) having a size of 90 mm × 55 mm was produced. Subsequently, as an intermediate transfer medium (20), an intermediate transfer film having a release layer (22) and an image receiving layer / adhesive layer (24) on a support substrate layer (21) is used. A card printer CP300FX device (manufactured by Toppan Printing Co., Ltd.) is used for the layer / adhesive layer (24) to form image information from a dedicated color ribbon, and then the surface temperature is 180 using the built-in heat roll of the device. The transfer speed is 6 mm / sec at 0 ° C., and the peel-off layer of the intermediate transfer film and the image-receiving layer / adhesive layer on which image information is formed are transferred onto the easy-adhesion layer (12) of the prepared transfer medium (10). Thus, an information recording body of the present invention was prepared.

実施例1において、インキCで厚み5μmの易接着層(12)を形成した90mm×55mmの大きさの被転写媒体(10)を用いた以外は、同様にして本発明の情報記録体を作成した。   In Example 1, the information recording medium of the present invention was prepared in the same manner except that the transfer medium (10) having a size of 90 mm × 55 mm in which the easy adhesion layer (12) having a thickness of 5 μm was formed with the ink C was used. did.

以下に、本発明の比較用の実施例を説明する。   In the following, comparative examples of the present invention will be described.

インキBで厚み5μmの易接着層を形成した90mm×55mmの大きさの被転写媒体を用いた以外は、実施例1と同様にして比較用の情報記録体を作成した。   A comparative information recording medium was prepared in the same manner as in Example 1 except that a transfer medium having a size of 90 mm × 55 mm in which an easy-adhesion layer having a thickness of 5 μm was formed with ink B was used.

インキDで厚み5μmの易接着層を形成した90mm×55mmの大きさの被転写媒体を用いた以外は、実施例1と同様にして比較用の情報記録体を作成した。   A comparative information recording medium was prepared in the same manner as in Example 1 except that a transfer medium having a size of 90 mm × 55 mm in which an easy-adhesion layer having a thickness of 5 μm was formed with ink D was used.

〈評価〉
実施例1の本発明の情報記録体及び実施例3の比較用の情報記録体を用いて、以下の方法で剥離テスト、改竄テストを実施し、評価した。さらに、実施例2の本発明の情報記録体及び実施例4の比較用の情報記録体を用いて、以下の方法で摩擦テストを実施し、評価した。その結果を表1、表2に示す。
(1)剥離テスト法
作成した各情報記録体の基材層と反対側の表面に粘着テープを貼った後に、粘着テープを引き剥がし、剥がれた状態を目視で評価した。
(2)改竄テスト法
メチルエチルケトン溶媒を用いて、作成した各情報記録体の剥離層、画像情報が形成された受像層兼接着層を除去した後、その上に再度、中間転写フィルムの剥離層と画像情報が形成された受像層兼接着層とを転写させて、改竄した情報記録体を作成し、元の情報記録体と比較、評価した。
(3)摩擦テスト法
作成した各情報記録体の基材層と反対側の表面を、学振式摩擦試験機で、摩擦布を用いて、9.8×104 Paの圧力で、1000回往復摩擦し、評価した。
<Evaluation>
Using the information recording material of the present invention of Example 1 and the information recording material for comparison of Example 3, a peeling test and a tampering test were performed and evaluated by the following methods. Furthermore, using the information recording material of the present invention of Example 2 and the information recording material for comparison of Example 4, a friction test was performed and evaluated by the following method. The results are shown in Tables 1 and 2.
(1) Peel test method After sticking an adhesive tape on the surface opposite to the base material layer of each created information recording body, the adhesive tape was peeled off, and the peeled state was visually evaluated.
(2) Tampering test method Using a methyl ethyl ketone solvent, the release layer of each information recording body and the image receiving layer / adhesive layer on which image information was formed were removed, and then the release layer of the intermediate transfer film was again formed thereon. The image receiving layer / adhesive layer on which the image information was formed was transferred to produce a falsified information recording body, which was compared with the original information recording body and evaluated.
(3) Friction test method The surface on the opposite side to the base material layer of each created information recording medium was subjected to 1000 times at a pressure of 9.8 × 10 4 Pa using a friction cloth with a Gakushin friction tester. Reciprocating friction was evaluated.

Figure 2009113269
Figure 2009113269

Figure 2009113269
表1に示すように、実施例1の本発明の情報記録体は、剥離テストの結果、全く剥離が無く、さらに、実施例1の本発明の情報記録体を用いて改竄した情報記録体は、一見して元の情報記録体と同様に見えたが、顕微鏡で観察したところ、加熱発泡済み粒子の消失や破壊が確認され、改竄跡が明瞭に判別できた。なた、一方、実施例3の比較用の情報記録体は、剥離テストの結果、受像層兼接着層と易接着層との層間で部分的な剥がれがあり、さらに、実施例3の比較用の情報記録体を用いて改竄した情報記録体は、元の情報記録体との明確な差は確認出来ず、改竄跡がわかりにくかった。
Figure 2009113269
As shown in Table 1, the information recording medium of the present invention of Example 1 was not peeled at all as a result of the peeling test, and the information recording body falsified using the information recording body of the present invention of Example 1 was At first glance, it looked the same as the original information recording body, but when observed with a microscope, the disappearance or destruction of the heat-foamed particles was confirmed, and the falsified mark could be clearly identified. On the other hand, as a result of the peel test, the information recording medium for comparison in Example 3 had partial peeling between the image receiving layer / adhesive layer and the easy-adhesive layer. The information recording body falsified using the information recording body of No. 1 could not confirm a clear difference from the original information recording body, and it was difficult to understand the falsification trace.

また、表2に示すように、実施例2の本発明の情報記録体は、摩擦テストの結果、各層の破壊は全く無かった。一方、実施例4の比較用の情報記録体は、摩擦テストの結果、剥離層、中間層、受像層兼接着層の一部で破壊が生じていた。   Further, as shown in Table 2, the information recording material of the present invention of Example 2 was not damaged at all as a result of the friction test. On the other hand, as a result of the friction test, the comparative information recording medium of Example 4 was broken in a part of the release layer, the intermediate layer, and the image receiving layer / adhesive layer.

(a)は本発明の情報記録体の一実施形態を示す拡大側断面図であり、(b)は情報記録体の他の実施形態を示す拡大側断面図である。(A) is an enlarged side sectional view showing an embodiment of the information recording body of the present invention, and (b) is an enlarged side sectional view showing another embodiment of the information recording body. (a)は本発明の情報記録体に使用する被転写媒体の一実施形態を示す拡大側断面図であり、(b)は情報記録体に使用する被転写媒体の他の実施形態を示す拡大側断面図である。(A) is an expanded side sectional view showing an embodiment of a transfer medium used for the information recording body of the present invention, and (b) is an enlargement showing another embodiment of the transfer medium used for the information recording body. It is a sectional side view. 本発明の情報記録体に使用する中間転写媒体の一実施形態を示す側断面図である。FIG. 3 is a side sectional view showing an embodiment of an intermediate transfer medium used for the information recording medium of the present invention. (a)〜(c)は本発明の情報記録体の製造方法の一実施形態を示す説明図である。(A)-(c) is explanatory drawing which shows one Embodiment of the manufacturing method of the information recording body of this invention.

符号の説明Explanation of symbols

1,2…情報記録体
10,10´…被転写媒体
11…基材層
12,13,14,15…易接着層
16…熱可塑性樹脂
17…熱発泡性粒子
18…蛍光体
19…加熱発泡済み粒子
20…中間転写媒体
21…支持基材層
22…剥離層
23…中間層
24…受像層兼接着層
T…熱
P…応力
DESCRIPTION OF SYMBOLS 1, 2 ... Information recording body 10, 10 '... Transfer medium 11 ... Base material layer 12, 13, 14, 15 ... Easy-adhesion layer 16 ... Thermoplastic resin 17 ... Thermally foamable particle 18 ... Phosphor 19 ... Heating foaming Finished particles 20 ... intermediate transfer medium 21 ... support base layer 22 ... peeling layer 23 ... intermediate layer 24 ... image receiving layer / adhesive layer T ... heat P ... stress

Claims (10)

支持基材層の片面に少なくとも、剥離層、情報が記録された受像層兼接着層を前記順序で有する中間転写媒体の剥離層から受像層兼接着層迄を、基材層の片面に熱可塑性樹脂と、熱発泡性粒子と、からなる易接着層を積層してなる被転写媒体の易接着層面に加熱転写してなる情報記録体であって、前記熱発泡性粒子が発泡してなる加熱発泡済み粒子が無色の粒子、着色された粒子、紫外光で励起され可視波長領域で発光する粒子、赤外光又は可視光で励起され赤外波長領域又は可視波長領域で発光する粒子のいずれか1種以上であることを特徴とする情報記録体。   At least one release layer on one side of the supporting base material layer, and an image receiving layer / adhesive layer on which information is recorded in the above order, from the release layer of the intermediate transfer medium to the image receiving layer / adhesive layer, thermoplastic on one side of the base material layer An information recording body obtained by heating and transferring to an easy-adhesion layer surface of a transfer medium formed by laminating an easy-adhesion layer comprising a resin and heat-expandable particles, wherein the heat-expandable particles are foamed. Either foamed particles are colorless particles, colored particles, particles that are excited by ultraviolet light and emit light in the visible wavelength region, or particles that are excited by infrared light or visible light and emit light in the infrared wavelength region or visible wavelength region An information recording body characterized by being one or more kinds. 前記被転写媒体の易接着層に蛍光体が含まれていることを特徴とする請求項1記載の情報記録体。   2. The information recording body according to claim 1, wherein a phosphor is contained in the easy-adhesion layer of the transfer medium. 前記蛍光体の平均粒子径が1〜10μmであることを特徴とする請求項2記載の情報記録体。   The information recording body according to claim 2, wherein the phosphor has an average particle diameter of 1 to 10 μm. 前記熱発泡性粒子の平均粒子径が未発泡時に10μm以下であることを特徴とする請求項1乃至請求項3のいずれか1項記載の情報記録体。   The information recording body according to any one of claims 1 to 3, wherein an average particle diameter of the thermally foamable particles is 10 µm or less when unexpanded. 請求項1乃至請求項4のいずれか1項記載の情報記録体の剥離層と受像層兼接着層との間に、回折格子構造体が形成されたOVD(Optical Variable Device)層を有することを特徴とする情報記録体。   An OVD (Optical Variable Device) layer in which a diffraction grating structure is formed is provided between the release layer of the information recording body according to any one of claims 1 to 4 and the image receiving layer / adhesion layer. Characteristic information recording medium. 請求項1乃至請求項5のいずれか1項記載の情報記録体に、さらにエンボス模様が施されていることを特徴とする情報記録体。   An information recording body according to any one of claims 1 to 5, further comprising an embossed pattern. 前記被転写媒体の易接着層中の熱発泡性粒子が加熱転写温度より低い温度で発泡することを特徴とする請求項1乃至請求項6のいずれか1項記載の情報記録体。   The information recording body according to any one of claims 1 to 6, wherein the thermally foamable particles in the easy-adhesion layer of the transfer medium are foamed at a temperature lower than the heat transfer temperature. 支持基材層の片面に少なくとも、剥離層、情報が記録された受像層兼接着層を前記順序で有する中間転写媒体の受像層兼接着層側を、基材層の片面に熱可塑性樹脂と、熱発泡性粒子と、からなる易接着層を積層してなる被転写媒体の易接着層面に重ね合わせ、中間転写媒体側から加熱、加圧して被転写媒体の易接着層中の熱発泡性粒子を発泡させ、加熱発泡済み粒子を生成させた状態で支持基材層を引き剥がすことを特徴とする情報記録体の製造方法。   At least the release layer on one side of the supporting base material layer, the image receiving layer / adhesive layer side of the intermediate transfer medium having the image receiving layer / adhesive layer in which information is recorded in the above order, the thermoplastic resin on one side of the base material layer, Heat-expandable particles in the easy-adhesion layer of the medium to be transferred by superimposing them on the surface of the easy-adhesion layer of the transfer medium formed by laminating an easily-adhesive layer comprising heat-expandable particles and heating and pressing from the intermediate transfer medium side A method for producing an information recording body, wherein the support base material layer is peeled off in a state where particles are heated and foamed particles are generated. 前記被転写媒体の易接着層中に蛍光体が含まれていることを特徴とする請求項8記載の情報記録体の製造方法。   9. The method for manufacturing an information recording body according to claim 8, wherein the easily adhesive layer of the transfer medium contains a phosphor. 表面に凹凸を有する加熱ロールで加熱、加圧することを特徴とする請求項8又は請求項9記載の情報記録体の製造方法。   The method for producing an information recording body according to claim 8 or 9, wherein the surface is heated and pressurized with a heating roll having irregularities on the surface.
JP2007287129A 2007-11-05 2007-11-05 Information recording body and its manufacturing method Pending JP2009113269A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007287129A JP2009113269A (en) 2007-11-05 2007-11-05 Information recording body and its manufacturing method

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007287129A JP2009113269A (en) 2007-11-05 2007-11-05 Information recording body and its manufacturing method

Publications (1)

Publication Number Publication Date
JP2009113269A true JP2009113269A (en) 2009-05-28

Family

ID=40780960

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2007287129A Pending JP2009113269A (en) 2007-11-05 2007-11-05 Information recording body and its manufacturing method

Country Status (1)

Country Link
JP (1) JP2009113269A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014076614A (en) * 2012-10-11 2014-05-01 Toppan Printing Co Ltd Adhesive transfer ribbon, personal authenticating medium using adhesive transfer ribbon, and method for manufacturing personal authenticating medium
WO2017057722A1 (en) * 2015-10-02 2017-04-06 凸版印刷株式会社 Counterfeit-preventing structure

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2014076614A (en) * 2012-10-11 2014-05-01 Toppan Printing Co Ltd Adhesive transfer ribbon, personal authenticating medium using adhesive transfer ribbon, and method for manufacturing personal authenticating medium
WO2017057722A1 (en) * 2015-10-02 2017-04-06 凸版印刷株式会社 Counterfeit-preventing structure
KR20180061184A (en) * 2015-10-02 2018-06-07 도판 인사츠 가부시키가이샤 Anti-fake structure
CN108136809A (en) * 2015-10-02 2018-06-08 凸版印刷株式会社 Anti-counterfeit structure body
JPWO2017057722A1 (en) * 2015-10-02 2018-09-20 凸版印刷株式会社 Anti-counterfeit structure
US10300732B2 (en) 2015-10-02 2019-05-28 Toppan Printing Co., Ltd. Anti-counterfeiting structure
CN108136809B (en) * 2015-10-02 2020-01-07 凸版印刷株式会社 Anti-counterfeiting structure
KR102563400B1 (en) * 2015-10-02 2023-08-03 도판 인사츠 가부시키가이샤 anti-counterfeit structure

Similar Documents

Publication Publication Date Title
JP2004127135A (en) Authentication identification card, and method of manufacturing authentication identification card
JP2004261978A (en) Certified recording medium, its creating method and certified recording medium issuing device
JP4870512B2 (en) Anti-counterfeit pressure-sensitive adhesive sheet and method for producing the same
JP4478350B2 (en) Intermediate transfer recording medium, manufacturing method thereof and image forming method
JP2002254840A (en) Method for forming image and intermediate transfer recording medium
JP7331997B2 (en) Hot stamping foil and printing with laminated optical decoration
JP2005319777A (en) Receiving-layer transfer material, transfer sheet, and image forming method using the same
JPH10297122A (en) Intermediate transfer sheet
JP4900150B2 (en) Brittle label and manufacturing method thereof
JP2009113269A (en) Information recording body and its manufacturing method
JP4816736B2 (en) Receiving layer transfer material and transfer sheet
WO2018216700A1 (en) Information recording body and individual certifying body
JP2006218847A (en) Receptive layer transfer material, transfer sheet, coloring material receiving sheet with relief layer, imaging method for using these material/sheets and imaging object
JPH11291646A (en) Intermediate transfer film
JPH11120319A (en) Image display body and information recording medium provided with prevention against forgery
JP5056352B2 (en) Information recording medium
JP4177580B2 (en) Intermediate transfer recording medium
JP4280122B2 (en) Decorative sheet and manufacturing method thereof
JP2000043458A (en) Material to be transferred and image display using it
JPH1035157A (en) Image display body and transfer sheet used for manufacture of image display
JP4765189B2 (en) Anti-counterfeit image-forming body and method for producing the same
JP6904058B2 (en) Transfer printing method
JP5278647B2 (en) Information recording medium
JP2008062415A (en) Information recorder
JP2000043434A (en) Intermediate transfer sheet