JP2009102076A - Bottle cap - Google Patents

Bottle cap Download PDF

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JP2009102076A
JP2009102076A JP2009000404A JP2009000404A JP2009102076A JP 2009102076 A JP2009102076 A JP 2009102076A JP 2009000404 A JP2009000404 A JP 2009000404A JP 2009000404 A JP2009000404 A JP 2009000404A JP 2009102076 A JP2009102076 A JP 2009102076A
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cap
bottle
outer cylinder
cylinder
inner cylinder
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JP2009000404A
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Japanese (ja)
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Masayuki Makita
正行 牧田
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BZI KK
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BZI KK
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Priority to JP2009000404A priority Critical patent/JP2009102076A/en
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Abstract

<P>PROBLEM TO BE SOLVED: To prevent swallowing a bottom cap accidentally by enhancing the property of airtightness all the more when sealing the bottom cap. <P>SOLUTION: Threaded sections 9a and 3e are formed, which are tightly fastened by being mutually threadedly engaged, on an inner tube 9 and the bottom cap 3 used as a raw material storing section of a slave cap 2, rotation-stop sections 3f and 7 are provided so as to mutually removably fit to the bottom cap 3 and an outer tube 6 of a master cap 1, and when turning the slave cap in the opening direction relative to the outer tube of the master cap, the bottom cap is made to fall off from the inner tube by being regulated to carry out following rotation with the inner tube by the rotation-stop section. A discharging groove 6e is formed in the hanging-down tube section 6b of the outer tube 6 to extend upward from its lower end to an intermediate part. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、粉末状又は液状の原料を収容する原料収容部を有し、開栓操作に伴い原料収容部の底蓋を脱落させて原料をボトル内に放出するボトルキャップに関する。   The present invention relates to a bottle cap that has a raw material container that contains a powdery or liquid raw material, and that releases the raw material into a bottle by dropping the bottom cover of the raw material container in accordance with the opening operation.

従来、この種のボトルキャップとして、例えば特許文献1(実公昭44−12957号公報)及び特許文献2(特許第3281730号公報)に記載のものがある。   Conventionally, as this kind of bottle cap, for example, there are those described in Patent Document 1 (Japanese Utility Model Publication No. 44-12957) and Patent Document 2 (Japanese Patent No. 3281730).

特許文献1に記載のものは、可撓性樹脂からなる円筒状のパッキング(外筒)と、原料収容部となる筒体(内筒)を有する蓋(キャップ)と、環状の突縁(鍔部)を有する押込栓(底蓋)とからなり、パッキングをボトルの口部内に嵌挿するとともに、押込栓を筒体の下面開口内に嵌挿して該筒体を密閉し、蓋をボトルの口部に螺合させて該口部を閉じる構造になっている。パッキングの下端部がすぼまっていて、蓋でボトルの口部を完全に閉じたとき、押込栓の環状突縁がパッキングの下端と係合するようになっている。蓋をボトルの口部に対して開く方向に回すと、筒体は蓋と共に上昇するが、押込栓はパッキングの下端で上昇を規制されるため、筒体から脱落し、筒体内に収容した粉末がボトル内に放出される。   Patent Document 1 describes a cylindrical packing (outer cylinder) made of a flexible resin, a lid (cap) having a cylindrical body (inner cylinder) serving as a raw material container, and an annular protruding edge (鍔). Part), and the packing is inserted into the mouth of the bottle, and the stopper is inserted into the bottom opening of the cylinder to seal the cylinder. The mouth is closed by screwing into the mouth. When the lower end of the packing is sunk and the mouth of the bottle is completely closed with the lid, the annular protruding edge of the push plug is engaged with the lower end of the packing. When the lid is turned in the opening direction with respect to the mouth of the bottle, the cylinder rises with the lid, but since the push-in stopper is restricted from rising at the lower end of the packing, the powder falls off the cylinder and is contained in the cylinder. Is released into the bottle.

また、特許文献2のものは、ボトルの口頚部外周に下部を抜け出し不能に嵌着固定した嵌合筒部の中途内周にフランジを延設し、該フランジ内周より支持筒部を一体に垂設してなる連結部材(外筒)と、頂壁の裏面中央部より収納筒部(内筒)を垂設したキャップと、その収納筒部下端に液密且つ離脱可能に嵌着させてその上部を原料収納部とする皿状の底蓋とを備え、また連結部材(外筒)の嵌合筒部の外周下部に第1螺条を周設するとともに、該第1螺条と空転域を介して上方に第2螺条を周設し、キャップの周壁内周下部に上記第1螺条と螺合する螺条を周設しており、キャップを連結部材(外筒)に対して開く方向に回して上昇させると、キャップの螺条が連結部材(外筒)の第1螺条から外れて空転する前に、底蓋の周縁上面が支持筒部の下端に係止されて脱落するようになっている。底蓋は、その底壁上面の周縁部に、キャップの収納筒部の内周下端部に嵌合するシール筒部を立設して液密性を保持するようになっている。
実公昭44−12957号公報(第1頁、第1図、第2図) 特許第3281730号公報(第2頁、第1図、第3図)
Further, in the case of Patent Document 2, a flange is extended to the inner periphery of a fitting tube portion that is fixedly fitted in and fixed to the outer periphery of the bottle neck of the bottle, and the support tube portion is integrated from the inner periphery of the flange. A connecting member (outer cylinder) that is suspended, a cap that has a storage cylinder (inner cylinder) suspended from the center of the rear surface of the top wall, and a liquid-tight and detachable fit to the lower end of the storage cylinder A dish-shaped bottom lid having the upper portion as a raw material storage portion, and a first screw thread is provided around the lower part of the outer periphery of the fitting tube portion of the connecting member (outer tube). A second screw thread is provided above the area, and a screw threaded to be engaged with the first screw thread is provided at the inner peripheral lower portion of the peripheral wall of the cap. The cap is connected to the connecting member (outer cylinder). When the cap is turned up and lifted, the upper surface of the peripheral edge of the bottom cover is supported before the cap screw is disengaged from the first screw of the connecting member (outer cylinder) and idles. So that the fall off is engaged with the lower end of the cylindrical portion. The bottom cover is provided with a seal cylinder portion that is fitted to the lower end portion of the inner periphery of the storage cylinder portion of the cap at the peripheral edge portion of the upper surface of the bottom wall to maintain liquid tightness.
Japanese Utility Model Publication No. 44-12957 (first page, FIG. 1, FIG. 2) Japanese Patent No. 3281730 (Page 2, FIGS. 1 and 3)

しかし、特許文献1に記載のものは、押込栓(底蓋)を原料収容部である筒体(内筒)に押し込んでいるものの、これらの間の気密性を確保することは難しく、ボトル内の湿気を含む空気が原料収容部である筒体(内筒)内に浸入し、粉末等の原料が酸素や湿気と接触することにより変質や腐敗等を招く。   However, although the thing of patent document 1 is pushing the pushing stopper (bottom lid) into the cylinder (inner cylinder) which is a raw material accommodating part, it is difficult to ensure the airtightness between these, The air containing the moisture penetrates into the cylinder (inner cylinder) which is the raw material container, and the raw materials such as powder come into contact with oxygen and moisture, thereby causing alteration and decay.

特許文献2に記載のものは、キャップの収納筒部と底蓋との間の液密性を確保するために、底蓋の上面に、キャップの収納筒部の内周下端部に嵌合するシール筒部を立設しているものの、これも気密性を確保することは難しく、ボトル内の湿気を含む空気が収容筒部内に浸入し、粉末等の原料が酸素と接触することにより変質や腐敗等を招く。   In order to ensure the liquid-tightness between the storage cylinder part of the cap and the bottom cover, the one described in Patent Document 2 is fitted on the lower end of the inner periphery of the storage cylinder part of the cap on the upper surface of the bottom cover. Although the seal cylinder part is erected, it is difficult to ensure airtightness, and air containing moisture in the bottle penetrates into the storage cylinder part. Invite corruption.

本発明の第1の課題は、原料収納部の下端開口を底蓋で封止したときの気密性が高く、原料収納部に収納した粉末等の変質や腐敗等を的確に防止できるようにするとともに、隙間による液体の残留が生じない構造にすることにある。
本発明の第2の課題は、底蓋を脱落後にキャップに懸垂できるようにして、自由に浮遊することによる弊害や誤飲を防止できるようにすることにある。
The first problem of the present invention is that airtightness is high when the lower end opening of the raw material storage part is sealed with a bottom lid, and it is possible to accurately prevent alteration or decay of the powder stored in the raw material storage part. At the same time, there is a structure in which no liquid remains due to the gap.
The second object of the present invention is to allow the bottom lid to be suspended from the cap after dropping, thereby preventing adverse effects and accidental ingestion due to free floating.

本発明は、ボトル50の口部50aに挿入する外筒6を備えた親キャップ1と、その外筒6に挿入して原料収納部となる内筒9を備えた子キャップ2と、その内筒9の下端開口を外筒6の外側で封止する底蓋3とからなり、親キャップ1をボトル50の口部50aに被せるとともに、子キャップ2を親キャップ1の外筒6に螺合させることにより、該外筒6の上端開口とともにボトル50の口部50aを封止でき、また子キャップ2を親キャップ1の外筒6に対し開く方向に回すことにより、底蓋3が外筒6によって内筒9から脱落され、内筒6内の原料がボトル50内に放出されるボトルキャップであって、
請求項1に係る発明は、上記第1の課題を達成するため次のような構造になっている。
ボトル50の口部50aに螺合する親キャップ1のキャップ本体5に、外筒6が、キャップ本体5の上下に突出するように一体に設けられ、ボトル50の口部50aの外側に突出する外筒6の上側部分が、子キャップ2を螺合させることにより封止される上端開口したネジ付き口部6a、キャップ本体5より垂下してボトル50の口部50aに挿入する外筒6の下側部分が下端開口した垂下筒部6bとなっている。この垂下筒部6bに、その内外を貫通して下端から途中まで上に延びる縦長の排出用切欠き6eが形成されている。
内筒9と底蓋3とに、互いに螺合して緊締するネジ部9a・3eを形成するとともに、底蓋3と親キャップ1の外筒6とに互いに係合する回り止め部3f・7を設け、子キャップ2を親キャップ1の外筒6に対し開く方向に回したときに、底蓋3が回り止め部3f・7により内筒9との追従回転を規制されて互いのネジ部9a・3eが外れ、内筒9から脱落するようになっている。
The present invention includes a parent cap 1 having an outer cylinder 6 to be inserted into a mouth 50a of a bottle 50, a child cap 2 having an inner cylinder 9 to be inserted into the outer cylinder 6 and serving as a raw material storage portion, It comprises a bottom lid 3 that seals the lower end opening of the tube 9 outside the outer tube 6, covers the parent cap 1 over the mouth 50 a of the bottle 50, and screwes the child cap 2 onto the outer tube 6 of the parent cap 1. By doing so, the mouth 50a of the bottle 50 can be sealed together with the upper end opening of the outer cylinder 6, and the bottom cap 3 is moved to the outer cylinder by turning the child cap 2 in the opening direction with respect to the outer cylinder 6 of the parent cap 1. 6 is a bottle cap which is dropped from the inner cylinder 9 by 6 and the raw material in the inner cylinder 6 is discharged into the bottle 50,
The invention according to claim 1 has the following structure in order to achieve the first object.
An outer cylinder 6 is integrally provided on the cap body 5 of the parent cap 1 that is screwed into the mouth part 50a of the bottle 50 so as to project up and down the cap body 5, and projects outside the mouth part 50a of the bottle 50. The upper portion of the outer cylinder 6 is sealed by screwing the child cap 2, and has a screwed mouth portion 6 a that is open at the upper end, and the outer tube 6 that hangs down from the cap body 5 and is inserted into the mouth portion 50 a of the bottle 50. The lower part is a hanging cylinder part 6b having a lower end opened. A vertical discharge notch 6e is formed in the hanging cylinder portion 6b and extends upward from the lower end to the middle through the inside and outside.
The inner cylinder 9 and the bottom cover 3 are formed with screw parts 9a and 3e that are screwed together to be fastened, and the rotation stoppers 3f and 7 that engage with the bottom cover 3 and the outer cylinder 6 of the parent cap 1 with each other. When the child cap 2 is rotated in the opening direction with respect to the outer cylinder 6 of the parent cap 1, the bottom lid 3 is restricted from following rotation with the inner cylinder 9 by the anti-rotation portions 3f and 7, so that each screw portion 9 a and 3 e come off and fall off from the inner cylinder 9.

請求項2に係る発明は、底蓋封止時の気密性を一層高くするため、底蓋3の周縁に、内筒9の下端部を圧入させることができる環状凹溝3bが形成され、該環状溝3bの内面に、内筒9の下端部のネジ部9aと螺合するネジ部3eが形成されている。   In the invention according to claim 2, in order to further improve the airtightness at the time of sealing the bottom cover, an annular groove 3b capable of press-fitting the lower end portion of the inner cylinder 9 is formed on the periphery of the bottom cover 3, On the inner surface of the annular groove 3b, a screw portion 3e that is screwed with the screw portion 9a at the lower end portion of the inner cylinder 9 is formed.

請求項3に係る発明は、上記第2の課題を達成するため、底蓋3が可撓性の連結片12にて親キャップ1の外筒6と連結され、内筒9から脱落したときに該連結片12にて外筒6に懸垂される。   In the invention according to claim 3, when the bottom cover 3 is connected to the outer cylinder 6 of the parent cap 1 by the flexible connecting piece 12 and falls off the inner cylinder 9 in order to achieve the second problem. The connecting piece 12 is suspended from the outer cylinder 6.

請求項4に係る発明は、上記請求項1〜3に係る発明において、外筒の内周面の中途と内筒の外周面の中途とにそれぞれ段部を形成し、これら段部が、子キャップで親キャップの上端開口を閉じたとき上下に対向するようにしたものである。   The invention according to claim 4 is the invention according to claims 1 to 3, wherein stepped portions are respectively formed in the middle of the inner peripheral surface of the outer cylinder and in the middle of the outer peripheral surface of the inner cylinder. When the upper end opening of the parent cap is closed with a cap, it faces the top and bottom.

請求項1に係る発明によると、底蓋は、そのネジ部を原料収納部である内筒のネジ部に螺合させて内筒の下端開口を緊締状態で封止するので、気密性が高い。このようにネジ部を螺合させて緊締しても、底蓋は、親キャップの外筒により内筒との追従回転を回り止め部によって規制されるので、開封時における内筒からの脱落は支障なく行われる。
また、親キャップの外筒の下側部分であって、親キャップのキャップ本体から垂下する垂下筒部に、その内外を貫通して下端から途中まで上に延びる縦長の排出用切欠きが形成されているので、外筒と子キャップの内筒との間が、この排出用切欠きを通じてボトル内と連通することになるため、外筒と子キャップの内筒との隙間の液体をこの排出用切欠きを通じて排出できる。
According to the first aspect of the present invention, the bottom lid is screwed into the screw portion of the inner cylinder, which is the raw material storage portion, and the lower end opening of the inner cylinder is sealed in a tight state, so that the airtightness is high. . Even if the threaded portion is screwed and tightened in this way, the bottom lid is restricted by the non-rotating portion from following rotation with the inner cylinder by the outer cylinder of the parent cap. It is done without hindrance.
In addition, a vertically long discharge notch extending through the inside and outside and extending upward from the lower end to the middle is formed in the hanging cylinder portion hanging from the cap main body of the parent cap, which is the lower portion of the outer cylinder of the parent cap. Therefore, the space between the outer cylinder and the inner cylinder of the child cap communicates with the inside of the bottle through this discharge notch. It can be discharged through the notch.

請求項2に係る発明によると、内筒の下端部を底蓋の周縁の環状溝に圧入させた状態で、該環状溝内で底蓋側のネジ部と内筒側のネジ部とを螺合させることができるので、気密性が一層高くなる。   According to the second aspect of the present invention, in the state where the lower end portion of the inner cylinder is press-fitted into the annular groove on the periphery of the bottom lid, the screw portion on the bottom lid side and the screw portion on the inner cylinder side are screwed in the annular groove. Since they can be combined, the airtightness is further increased.

請求項3に係る発明によると、底蓋が可撓性の連結片にて親キャップの外筒に連結され、内筒から脱落したときに親キャップの外筒に懸垂されるので、底蓋が内筒から脱落した後、底蓋の自由な浮遊を拘束できるとともに、開栓後の底蓋を親キャップの外筒に保持した状態に維持できるので、底蓋の誤飲を防止できる。   According to the invention of claim 3, the bottom cover is connected to the outer cylinder of the parent cap by the flexible connecting piece, and is suspended from the outer cylinder of the parent cap when it is dropped from the inner cylinder. After falling off from the inner cylinder, free floating of the bottom lid can be restrained, and the bottom lid after opening can be maintained in a state of being held by the outer cylinder of the parent cap, thereby preventing accidental ingestion of the bottom lid.

請求項4に係る発明によると、外筒の内周面の中途と内筒の外周面の中途とにそれぞれ段部を形成し、これら段部が、子キャップで親キャップの上端開口を閉じたとき上下に対向するので、ボトル内の液が外筒の内周面と内筒の外周面との間を浸透して上昇してくるのを堰止めできる。   According to the invention which concerns on Claim 4, the step part was each formed in the middle of the inner peripheral surface of the outer cylinder, and the middle part of the outer peripheral surface of the inner cylinder, and these step parts closed the upper end opening of the parent cap with the child cap. Since it is opposed to the upper and lower sides, it is possible to prevent the liquid in the bottle from penetrating and rising between the inner peripheral surface of the outer cylinder and the outer peripheral surface of the inner cylinder.

次に、本発明の実施の形態を図面に基づいて詳細に説明する。   Next, embodiments of the present invention will be described in detail with reference to the drawings.

図1〜図5は本発明の実施例1のボトルキャップを示し、図1及び図2は組み立て前の状態、図3は組み立てた状態、図4はボトルにセットした状態、図5は開封の動作状態である。このボトルキャップは、図1及び図2に示すように、それぞれ樹脂成型された親キャップ1と子キャップ2と底蓋3とからなる。   1 to 5 show a bottle cap according to a first embodiment of the present invention. FIGS. 1 and 2 are a state before assembly, FIG. 3 is an assembled state, FIG. 4 is a set state in a bottle, and FIG. It is an operating state. As shown in FIGS. 1 and 2, the bottle cap includes a parent cap 1, a child cap 2, and a bottom lid 3 that are resin-molded.

親キャップ1は、ペットボトル等のボトル50の口部50aに被せるキャップ本体5に、上下両端が開口した外筒6を一体に設けている。外筒6は、キャップ本体5の頂部5aを上下に一体に貫通しており、頂部5aより上側に突出した上部は、上端が開口する口部6aとなり、また頂部5aより下側に突出した下部は、キャップ本体5の胴部5bとの間に隙間を形成しながらその下端よりも下方に垂下して下端が開口する垂下筒部6bとなっている。この垂下筒部6bは、頂部5aの近くで段差をなして細くなってから、下端開口に向かって徐々に先細となっている。垂下筒部6bの下端には、底蓋3の回り止めのための矩形の凸部7が、一箇所又は対向する二箇所に設けられている。また、垂下筒部6bの内周面の中途には、肉厚を僅かに厚くする微小な段部6cが形成されている。   The parent cap 1 is integrally provided with an outer cylinder 6 whose upper and lower ends are open on a cap body 5 that covers a mouth portion 50a of a bottle 50 such as a plastic bottle. The outer cylinder 6 integrally penetrates the top part 5a of the cap body 5 vertically, and the upper part protruding upward from the top part 5a becomes a mouth part 6a whose upper end is open, and the lower part protruding downward from the top part 5a. Is a hanging cylinder portion 6b that hangs downward from its lower end and opens at its lower end while forming a gap with the body portion 5b of the cap body 5. The drooping cylinder portion 6b is tapered with a step near the top portion 5a, and then gradually tapers toward the lower end opening. At the lower end of the drooping cylinder portion 6b, rectangular convex portions 7 for preventing the bottom lid 3 from rotating are provided at one location or at two opposing locations. In addition, a minute step portion 6c that slightly increases the thickness is formed in the middle of the inner peripheral surface of the hanging cylinder portion 6b.

キャップ本体5の胴部5bの内周面には、図4に示すように、ボトル50の口部50aの雄ネジと螺合する雌ネジ5cが形成され、また外筒6の口部6aの外周面には雄ネジ6dが形成されている。胴部5bの外周面には、指を掛けて開ける際の滑り止め用ローレット5dが刻設されている。   As shown in FIG. 4, a female screw 5 c that engages with a male screw of the mouth part 50 a of the bottle 50 is formed on the inner peripheral surface of the body part 5 b of the cap body 5. A male screw 6d is formed on the outer peripheral surface. An anti-slip knurl 5d is formed on the outer peripheral surface of the body portion 5b when the finger is put on it.

また、外筒6の垂下筒部6bには、図21に示すように、その下端から途中まで上に延びる排出用溝6eが形成されている。   Further, as shown in FIG. 21, a discharge groove 6 e extending upward from the lower end to the middle is formed in the hanging cylinder portion 6 b of the outer cylinder 6.

子キャップ2は、原料及び圧力気体充填部(カプセル)となる内筒9を、キャップ本体8の頂部8aの下面から一体に突設するとともに、この内筒9の外周の至近位置において、肉薄の短い密閉リング10を一体に突設している。内筒9は、キャップ本体8の胴部8bとの間に隙間を形成しながらそれよりもはるかに長く突出している。内筒9は、外筒6よりも径がやや小さく、外筒6との間に僅かな隙間を形成して挿入できるようになっているが、長さは外筒6よりも若干長くなっている。内筒9の外周面の下端部には、ネジ山数の少ない雄ネジ9aが形成されている。内筒9は、内径については終端から下端まで同じであるが、外径は、内筒9の肉厚を徐々に薄くするように上端から下端に向かって徐々に小さくなっている。また、内筒9の外周面には、肉厚を僅かに薄くする微小な段部9cが形成されている。   The child cap 2 integrally protrudes from the lower surface of the top portion 8a of the cap body 8 with the inner cylinder 9 serving as a raw material and pressurized gas filling section (capsule), and is thin at a position close to the outer periphery of the inner cylinder 9. A short sealing ring 10 is integrally projected. The inner cylinder 9 protrudes much longer than that while forming a gap with the body portion 8b of the cap body 8. The inner cylinder 9 is slightly smaller in diameter than the outer cylinder 6 and can be inserted with a slight gap between the inner cylinder 6 but the length is slightly longer than the outer cylinder 6. Yes. A male screw 9 a having a small number of screw threads is formed at the lower end portion of the outer peripheral surface of the inner cylinder 9. The inner cylinder 9 has the same inner diameter from the terminal end to the lower end, but the outer diameter gradually decreases from the upper end to the lower end so that the thickness of the inner cylinder 9 is gradually reduced. Further, on the outer peripheral surface of the inner cylinder 9, a minute step portion 9 c that is slightly thinned is formed.

子キャップ2の胴部8bの環状の下周縁部分8cは、全周にわたる切り込み8dによりその上側の部分と分離可能になっている。この切り込み8dより上側において、胴部8bの内周面には、外筒6の口部6aの雄ネジ6dと螺合する雌ネジ8eが形成されている。図3に示すように、この雌ネジ8eを雄ネジ6cに螺合させ、更に環状の下周縁部分8cが雄ネジ6dの終端を強制的に越えるところまで子キャップ2を外筒6の口部6aに被せると、口部6aが気密かつ液密に封止される。このとき、子キャップ2は、その環状の下周縁部分8cが口部6aに対し回転不能に固定され、また内筒9の雄ネジ9aを有する下端部が、外筒6の垂下筒部6bの下端開口から突出し、内筒9の外周面中途の微小な段部9cと外筒6の内周面中途の微小な段部6cとが、近接して上下に対向する。更に、密閉リング10が外筒6の口部6a内に圧入するとともに、子キャップ2の頂部8aが外筒6の上端に圧接し、密閉リング10が子キャップ2の胴部8bの角部とで外筒6の口部6aを内外から挟持する状態となる。胴部8bの外周面には、指を掛けて開ける際の滑り止め用ローレット8fが刻設され、また頂部8aの上面には、開ける方向を指示する矢印8gが浮き出し形成されている。   An annular lower peripheral edge portion 8c of the trunk portion 8b of the child cap 2 can be separated from an upper portion thereof by a cut 8d extending over the entire circumference. On the inner peripheral surface of the body portion 8b above the notch 8d, a female screw 8e that is screwed with the male screw 6d of the mouth portion 6a of the outer cylinder 6 is formed. As shown in FIG. 3, the female screw 8e is screwed into the male screw 6c, and the child cap 2 is moved to the mouth of the outer cylinder 6 until the annular lower peripheral edge portion 8c forcibly exceeds the end of the male screw 6d. If it covers 6a, mouth part 6a will be sealed airtight and liquid-tight. At this time, the child cap 2 has an annular lower peripheral edge portion 8c fixed so as not to rotate with respect to the mouth portion 6a, and a lower end portion having a male screw 9a of the inner cylinder 9 is connected to the hanging cylinder portion 6b of the outer cylinder 6. The minute step portion 9c in the middle of the outer peripheral surface of the inner cylinder 9 and the minute step portion 6c in the middle of the inner peripheral surface of the outer cylinder 6 are close to each other and vertically face each other. Further, the sealing ring 10 is press-fitted into the mouth portion 6 a of the outer cylinder 6, the top portion 8 a of the child cap 2 is pressed against the upper end of the outer tube 6, and the sealing ring 10 is connected to the corner portion of the trunk portion 8 b of the child cap 2. Thus, the mouth portion 6a of the outer cylinder 6 is clamped from inside and outside. An anti-slip knurl 8f is formed on the outer peripheral surface of the body portion 8b, and an arrow 8g is provided on the top surface of the top portion 8a so as to indicate the opening direction.

底蓋3は、上面が凸面、下面が凹面となる押込部3aと、該押込部3aの周縁とで断面J状をなして環状凹溝3bを形成する周壁部3cと、押込部3aの凹面となっている下面の中央から下向きに突出する突起3dとを一体成型している。環状凹溝3b内、つまり周壁部3cの内周面には、ネジ山数の少ない雌ネジ3eが形成され、この雌ネジ3eと内筒9の下端部の雄ネジ9aとを螺合させて、内筒9の下端部を環状凹溝3b内に嵌め込むとともに、押込部3aを内筒9内に押し込むことにより、底蓋3は、圧力気体と原料11を充填した内筒9の下端開口を気密かつ液密に封止する。また周壁部3cには、外筒6に対する回り止めのための矩形の凹部3fが、一箇所又は対向する二箇所に設けられている。この凹部3fを外筒6の凸部7と嵌脱自在に嵌合させることにより、底蓋3は、外筒6に対し回り止めされる。   The bottom cover 3 includes a pressing portion 3a having a convex upper surface and a concave surface on the lower surface, a peripheral wall portion 3c having a J-shaped cross section with a peripheral edge of the pressing portion 3a, and a concave surface of the pressing portion 3a. A protrusion 3d protruding downward from the center of the lower surface is integrally molded. A female screw 3e with a small number of threads is formed in the annular groove 3b, that is, on the inner peripheral surface of the peripheral wall 3c. The female screw 3e and the male screw 9a at the lower end of the inner cylinder 9 are screwed together. The bottom lid 3 is fitted to the lower end of the inner cylinder 9 filled with the pressure gas and the raw material 11 by fitting the lower end of the inner cylinder 9 into the annular groove 3b and pushing the pushing part 3a into the inner cylinder 9. Is hermetically and liquid tightly sealed. Moreover, the rectangular recessed part 3f for the rotation prevention with respect to the outer cylinder 6 is provided in the peripheral wall part 3c in one place or two places which oppose. The bottom lid 3 is prevented from rotating with respect to the outer cylinder 6 by fitting the recess 3 f with the convex part 7 of the outer cylinder 6 so as to be detachable.

なお、底蓋3の回り止めのための凹部と凸部は、外筒6側を凹部、底蓋3側を凸部としてもよい。   In addition, the recessed part and convex part for rotation prevention of the bottom cover 3 are good also considering the outer cylinder 6 side as a recessed part, and making the bottom cover 3 side a convex part.

内筒9内に充填する原料11としては、緑茶、コーヒー、紅茶、濃縮ミネラル、海洋深層水抽出ミネラル、健康食品、薬剤、濃縮果汁、乳製品、アルコール、濃縮野菜、スープ原料、ビタミン類、糖類、薬草類、発酵菌などを、粉末や顆粒や錠剤や液体としたものが挙げられる。また、圧力気体としては、原料11の品質を安全に維持できる不活性ガスが良く、例えば窒素、ヘリウム、アルゴン、二酸化炭素、亜酸化窒素又はこれらの混合ガスが挙げられる。   The raw material 11 to be filled in the inner cylinder 9 includes green tea, coffee, black tea, concentrated minerals, deep sea water extracted minerals, health foods, drugs, concentrated fruit juices, dairy products, alcohol, concentrated vegetables, soup ingredients, vitamins, sugars , Herbs, fermenting bacteria, etc. in powder, granule, tablet or liquid. Moreover, as the pressure gas, an inert gas that can safely maintain the quality of the raw material 11 is good, and examples thereof include nitrogen, helium, argon, carbon dioxide, nitrous oxide, or a mixed gas thereof.

底蓋3は、可撓性の連結片12にて外筒6に連結されている。この連結片12の上端部は外筒6の外周面に、下端部は底蓋3の下面にそれぞれ固定され、底蓋3を内筒9から外したとき、連結片12は、ほぼ真っ直ぐな状態に復元して底蓋3を外筒6に対し懸垂状態とする。底蓋3は、連結片12と共に外筒6(親キャップ1)と一体に樹脂成型することが可能である。   The bottom lid 3 is connected to the outer cylinder 6 by a flexible connecting piece 12. The upper end of the connecting piece 12 is fixed to the outer peripheral surface of the outer cylinder 6, and the lower end is fixed to the lower surface of the bottom cover 3. When the bottom cover 3 is removed from the inner cylinder 9, the connecting piece 12 is in a substantially straight state. And the bottom cover 3 is suspended from the outer cylinder 6. The bottom cover 3 can be resin-molded integrally with the outer cylinder 6 (parent cap 1) together with the connecting piece 12.

この実施例1のボトルキャップは、親キャップ1と子キャップ2と底蓋3とを図3に示すように組み立て、内筒9内には、不活性ガス等の圧力気体と共に原料11を充填して底蓋3で封止するとともに、外筒6の口部6aは、子キャップ2のキャップ本体8で封止し、また底蓋3は、その凹部3fを外筒6の凸部7と嵌合させて外筒6に対し回り止め状態とする。そして、このように組み立てたボトルキャップを、図4に示すように、ペットボトル等のボトル50の口部50aに装着する場合、外筒6をボトル口部50a内に挿入し、親キャップ1のキャップ本体5の雌ネジ5cをボトル口部50aの雄ネジに螺合させて固く緊締することにより、該キャップ本体5にてボトル口部50aを封止する。   In the bottle cap of the first embodiment, the parent cap 1, the child cap 2 and the bottom lid 3 are assembled as shown in FIG. 3, and the inner cylinder 9 is filled with the raw material 11 together with a pressure gas such as an inert gas. Are sealed with the bottom lid 3, and the mouth portion 6 a of the outer cylinder 6 is sealed with the cap body 8 of the child cap 2, and the bottom lid 3 is fitted with the concave portion 3 f with the convex portion 7 of the outer cylinder 6. Combined with each other, the outer cylinder 6 is prevented from rotating. And when attaching the bottle cap assembled in this way to the mouth part 50a of the bottle 50 such as a plastic bottle as shown in FIG. 4, the outer cylinder 6 is inserted into the bottle mouth part 50a, and the parent cap 1 The bottle mouth part 50a is sealed with the cap body 5 by screwing the female screw 5c of the cap body 5 into the male screw of the bottle mouth part 50a and tightening it tightly.

このようにボトル50に装着された本ボトルキャップは、内筒9内に圧力気体が充填されているので、内筒9内への酸素や湿気の浸入を内圧により防止できるに加え、底蓋3は、内筒9の下端部を環状凹溝3bに嵌め込んで内筒9にネジ止めされているので、底蓋3に圧力気体による内圧がかかっていても、内筒9内からの圧力気体の漏れを確実に防止できる。   The bottle cap thus attached to the bottle 50 is filled with the pressure gas in the inner cylinder 9, so that intrusion of oxygen and moisture into the inner cylinder 9 can be prevented by the internal pressure, and the bottom lid 3 Since the lower end portion of the inner cylinder 9 is fitted in the annular groove 3b and screwed to the inner cylinder 9, even if the inner pressure of the pressure gas is applied to the bottom lid 3, the pressure gas from the inner cylinder 9 is applied. Can be reliably prevented.

外筒6と内筒9との間では、それらの中途において、外筒6の内周面の段部6cと内筒6の外周面の段部9cとが近接して対向するので、ボトル50内の液が外筒6の内周面と内筒9の外周面との間を浸透して上昇してくるのを堰止めできる。   Between the outer cylinder 6 and the inner cylinder 9, the step 6c on the inner peripheral surface of the outer cylinder 6 and the step 9c on the outer peripheral surface of the inner cylinder 6 are close to each other and face each other. It is possible to prevent the liquid inside from penetrating and rising between the inner peripheral surface of the outer cylinder 6 and the outer peripheral surface of the inner cylinder 9.

外筒6の口部6aと子キャップ2との間では、上記のように、子キャップ2の密閉リング10が外筒6内に圧入するとともに、子キャップ2の頂部8aが外筒6の上端に圧接し、密閉リング10が胴部8bの角部とで外筒6の口部6aを内外から挟持するので、外筒6の口部6aに対する子キャップ2の気密性及び液密性は非常に高い。   Between the mouth 6a of the outer cylinder 6 and the child cap 2, the sealing ring 10 of the child cap 2 is press-fitted into the outer cylinder 6 and the top 8a of the child cap 2 is the upper end of the outer cylinder 6 as described above. Since the sealing ring 10 clamps the mouth portion 6a of the outer cylinder 6 from the inside and outside with the corner portion of the body portion 8b, the air tightness and liquid tightness of the child cap 2 with respect to the mouth portion 6a of the outer cylinder 6 are extremely high. Very expensive.

一方、外筒6の垂下筒部6bには、図21に示したように、その内外を貫通して下端から途中まで上に延びる縦長の排出用切欠き6eが形成されているので、子キャップ2をその内筒9と共に抜き出してボトル50内の液体を外筒6の口部6aから注出する際、外筒6とボトル50の口部50aとの間に液体を残留させることなく、この排出用切欠き6eを通じて排出できる。   On the other hand, as shown in FIG. 21, the drooping cylinder portion 6b of the outer cylinder 6 is formed with a vertically long discharge notch 6e that penetrates the inside and outside and extends upward from the lower end to the middle. 2 is extracted together with the inner cylinder 9 and the liquid in the bottle 50 is poured out from the mouth part 6a of the outer cylinder 6 without leaving any liquid between the outer cylinder 6 and the mouth part 50a of the bottle 50. It can be discharged through the discharge notch 6e.

図4に示す装着状態で、子キャップ2を開けることに伴う動作について図5を参照して説明する。
同図(A)の状態から子キャップ2の胴部8bに指を掛けて矢印方向に回すと、胴部8bの環状の下周縁部分8cは、外筒6の口部6aに対し回転不能になっているので、同図(B)に示すように切り込み8dにおいて上下に分離し、下周縁部分8cはそのまま残るのに対し、それより上側の胴部8bは口部6aとの螺合により回転しながら上昇する。これに伴い内筒9も回転しながら上昇するが、底蓋3は、外筒6に対し回り止めされているので内筒9に追従して回転せず、子キャップ2を更に回して内筒9を更に上昇させると、内筒9の下端の雄ネジ9aと底蓋3の雌ネジ3eとの螺合が外れ、底蓋3は、内筒9の下端から解放される。
An operation associated with opening the child cap 2 in the mounting state shown in FIG. 4 will be described with reference to FIG.
When a finger is put on the trunk portion 8b of the child cap 2 and rotated in the direction of the arrow from the state shown in FIG. 9A, the annular lower peripheral edge portion 8c of the trunk portion 8b becomes unrotatable with respect to the mouth portion 6a of the outer cylinder 6. Therefore, as shown in FIG. 5B, it is separated vertically at the notch 8d and the lower peripheral edge portion 8c remains as it is, while the upper body portion 8b is rotated by screwing with the mouth portion 6a. While rising. Along with this, the inner cylinder 9 also rises while rotating, but the bottom cover 3 is prevented from rotating with respect to the outer cylinder 6 and therefore does not rotate following the inner cylinder 9 and the child cap 2 is further rotated to rotate the inner cylinder. When 9 is further raised, the male screw 9 a at the lower end of the inner cylinder 9 and the female screw 3 e of the bottom cover 3 are unscrewed, and the bottom cover 3 is released from the lower end of the inner cylinder 9.

なお、子キャップ2の胴部8bが切り込み8dにおいて上下に分離する力(ひねり)を子キャップ2に与えても、親キャップ1は、ボトル50の口部50aに対し回転しないように、しっかりと緊締されている。   It should be noted that even if a force (twist) is applied to the child cap 2 so that the body portion 8b of the child cap 2 is vertically separated at the notch 8d, the parent cap 1 is firmly fixed so as not to rotate with respect to the mouth portion 50a of the bottle 50. It is tightened.

内筒9の下端から解放された底蓋3は、内筒9内に充填されている圧力気体にて同図(C)に示すように押し下げられ、底蓋3の凹部3fと外筒6の下端の凸部7との嵌合が外れて、底蓋3は外筒6からも解放されて脱落する。これにより同図(D)に示すように、内筒9内の原料11が圧力気体と共にボトル50内に一気に噴出され、ボトル50内の液体と混合する。脱落した底蓋3は、連結片12がほぼ真っ直ぐな状態に復元することにより外筒6に懸垂される。   The bottom lid 3 released from the lower end of the inner cylinder 9 is pushed down by the pressure gas filled in the inner cylinder 9 as shown in FIG. The bottom lid 3 is released from the outer cylinder 6 and falls off when the fitting with the convex portion 7 at the lower end is released. As a result, as shown in FIG. 4D, the raw material 11 in the inner cylinder 9 is jetted into the bottle 50 together with the pressure gas, and mixed with the liquid in the bottle 50. The dropped bottom lid 3 is suspended from the outer cylinder 6 when the connecting piece 12 is restored to a substantially straight state.

ボトル50内の液体を飲むには、子キャップ2を外筒6の口部6aから外して内筒9を外筒6から抜き出し、口部6aを開ける。その際、必要に応じ、子キャップ2を外筒6の口部6aに対し再び閉めてボトル50自体を振り、原料11が液体によく混合してから、子キャップ2を外す。   To drink the liquid in the bottle 50, the child cap 2 is removed from the mouth 6a of the outer cylinder 6, the inner cylinder 9 is extracted from the outer cylinder 6, and the mouth 6a is opened. At that time, if necessary, the child cap 2 is closed again with respect to the mouth portion 6a of the outer cylinder 6 and the bottle 50 itself is shaken. After the raw material 11 is well mixed with the liquid, the child cap 2 is removed.

子キャップ2の胴部8bが切り込み8dにおいて上下に分離することで、底蓋3が脱落することを確認できるが、ボトル50が内部を透視できるようになっている場合には、底蓋3が脱落したことを目視確認できる。   It can be confirmed that the bottom lid 3 is dropped by separating the body portion 8b of the child cap 2 vertically at the cut 8d. However, when the bottle 50 can be seen through, the bottom lid 3 It can be visually confirmed that it has dropped out.

親キャップ1をボトル50から外せば、これと共に底蓋3も懸垂状態のまま一緒に取り出すことができるので、ボトル50のリサイクル性が良い。   If the parent cap 1 is removed from the bottle 50, the bottom lid 3 can be taken out together with this in the suspended state, so that the recyclability of the bottle 50 is good.

子キャップ2の胴部8bに切り込み8dを設け、その環状の下周縁部分8cを外筒6の口部6aに対し回転不能とすることで、子キャップ2の封止の緩みを防止できるとともに、切り込み8dで分離するまで子キャップ2を強制的に回さないと、底蓋3を脱落させて原料11の噴出を行えないという確認になるが、必ずしもこのような構造にする必要はない。   By providing a notch 8d in the body portion 8b of the child cap 2 and making the annular lower peripheral edge portion 8c non-rotatable with respect to the mouth portion 6a of the outer cylinder 6, it is possible to prevent the child cap 2 from being loosened, If the child cap 2 is not forcibly turned until it is separated by the notch 8d, it will be confirmed that the bottom lid 3 is dropped and the raw material 11 cannot be ejected, but such a structure is not necessarily required.

図6〜図8は本発明の実施例2のボトルキャップを示し、図6は組み立てた状態、図7はボトルにセットした状態、図8は開ける動作状態で、それぞれ第1実施例における図3、図4、図5に対応する。上記実施例1では、底蓋3を外筒6に連結して懸垂状態とするための連結片12を設けたが、実施例2ではこれを省略しただけで、その他については実施例1と同じである。   6 to 8 show a bottle cap according to a second embodiment of the present invention. FIG. 6 shows an assembled state, FIG. 7 shows a state in which the bottle is set, and FIG. 8 shows an opening state. This corresponds to FIGS. 4 and 5. In the first embodiment, the connecting piece 12 for connecting the bottom lid 3 to the outer cylinder 6 to be suspended is provided. However, in the second embodiment, this is omitted, and the rest is the same as the first embodiment. It is.

従って、実施例2では、底蓋3が外筒6に懸垂されることなく、ボトル50内の液中に沈降する。図9(A)は、子キャップ2を開く方向に回して原料11が噴出されるとともに、底蓋3が沈降していく状態、同図(B)は子キャップ2を再び閉める状態、同図(C)は、ボトル50を振って原料11の混合を行っている状態をそれぞれ示す。底蓋3は、突起3dを有するので、ボトル50内の液中に沈降する際にこの突起3dにて方向性を与えられる。   Therefore, in the second embodiment, the bottom lid 3 settles in the liquid in the bottle 50 without being suspended from the outer cylinder 6. 9A shows the state in which the raw material 11 is ejected by turning the child cap 2 in the opening direction, and the bottom cover 3 sinks. FIG. 9B shows the state in which the child cap 2 is closed again. (C) shows the state which is mixing the raw material 11 by shaking the bottle 50, respectively. Since the bottom lid 3 has the projection 3d, the projection 3d is given directionality when it settles in the liquid in the bottle 50.

図10〜図13は本発明の実施例3のボトルキャップを示し、図10は組み立てまでの断面図、図11は底蓋の斜視図、図12は回り止め部材の斜視図、図13は開封する動作状態の断面図である。この実施例3のボトルキャップは、図10(A)に示すように、親キャップ1と子キャップ2と底蓋3に加え回転止め部材4からなる。   10 to 13 show a bottle cap according to a third embodiment of the present invention, FIG. 10 is a sectional view up to assembly, FIG. 11 is a perspective view of a bottom cover, FIG. 12 is a perspective view of a detent member, and FIG. It is sectional drawing of the operation state to do. As shown in FIG. 10A, the bottle cap according to the third embodiment includes a rotation stopper member 4 in addition to the parent cap 1, the child cap 2, and the bottom lid 3.

実施例3における親キャップ1は、外筒6の下端に、実施例1における回り止め用の凸部7に代えて凹部7aを設けているが、その他については実施例1の親キャップと同じである。また、第3実施例における子キャップ2は、実施例1では内筒9の外周面の下端に設けた雄ネジ9aに代えて、内筒9の内周面の下端に雌ネジ9dを形成しているが、その他については実施例1の子キャップと同じである。   The parent cap 1 in the third embodiment is provided with a concave portion 7a at the lower end of the outer cylinder 6 in place of the rotation-preventing convex portion 7 in the first embodiment, but is otherwise the same as the parent cap of the first embodiment. is there. Further, the child cap 2 in the third embodiment has a female screw 9d formed at the lower end of the inner peripheral surface of the inner cylinder 9 in place of the male screw 9a provided at the lower end of the outer peripheral surface of the inner cylinder 9 in the first embodiment. However, the rest is the same as the child cap of the first embodiment.

実施例3における底蓋3は、実施例1のものとは大幅に異なり、図11に示すように押込部13aと鍔部13bとからなり、押込部13aの外周に、内筒9の雌ネジ9dと螺合する雄ネジ13cを形成し、鍔部13bの外周に環状溝13dを形成し、また鍔部13bの下面に、断面台形の十字状溝13eを形成している。   The bottom cover 3 in the third embodiment is significantly different from that in the first embodiment. As shown in FIG. 11, the bottom lid 3 is composed of a pressing portion 13a and a flange portion 13b, and a female screw of the inner cylinder 9 is formed on the outer periphery of the pressing portion 13a. A male screw 13c that is screwed with 9d is formed, an annular groove 13d is formed on the outer periphery of the flange portion 13b, and a cross-shaped groove 13e having a trapezoidal cross section is formed on the lower surface of the flange portion 13b.

底蓋3は、その雄ネジ13cを内筒9の雌ネジ9dに螺合させて押込部13aを内筒9に押し込むと、内筒9の下端開口を気密かつ液密に封止する。その際の螺合作業には、十字状溝13eを利用して底蓋3を回すことができる。底蓋3の鍔部13bの外径は、内筒9の下端の外径とほぼ等しいので、内筒9は底蓋3で封止したまま外筒6に挿入でき、しかも図10(B)に示すように、子キャップ2を外筒6の口部6aに被せて内筒9を外筒6に最大限に挿入すると、底蓋3は外筒6の下端開口から抜け出る。   The bottom lid 3 seals the lower end opening of the inner cylinder 9 in an airtight and liquid-tight manner when the male screw 13 c is screwed into the female thread 9 d of the inner cylinder 9 and the pushing portion 13 a is pushed into the inner cylinder 9. In the screwing operation at that time, the bottom lid 3 can be rotated using the cross-shaped groove 13e. Since the outer diameter of the flange 13b of the bottom cover 3 is substantially equal to the outer diameter of the lower end of the inner cylinder 9, the inner cylinder 9 can be inserted into the outer cylinder 6 while being sealed with the bottom cover 3, and FIG. As shown in FIG. 3, when the inner cap 9 is inserted into the outer tube 6 to the maximum by covering the child cap 2 over the mouth 6 a of the outer tube 6, the bottom cover 3 comes out of the lower end opening of the outer tube 6.

実施例3で加わった回り止め部材4は、図12に示すように、リング部14aの内側に、断面台形の十字状リブ14bを一体に設けるとともに、リング部14aの内周面に環状突部14cを形成し、リング部14aの対向する二箇所から回り止め用の矩形凸部14dを一体に突設している。そして、この回り止め部材4は、可撓性の連結片12にて外筒6に連結されている。この連結片12の上端部は外筒6の外周面に、下端部は回り止め部材4のリング部14aにそれぞれ固定され、連結片12は、ほぼ真っ直ぐな状態に復元すると回り止め部材4を外筒6に対し懸垂状態とする。回り止め部材4は、連結片12と共に外筒6(親キャップ1)と一体に樹脂成型することが可能である。   As shown in FIG. 12, the anti-rotation member 4 added in the third embodiment is provided with a cross-shaped trapezoidal cross-shaped rib 14b on the inner side of the ring portion 14a, and an annular protrusion on the inner peripheral surface of the ring portion 14a. 14c is formed, and a rectangular convex portion 14d for preventing rotation is integrally projected from two opposing portions of the ring portion 14a. The detent member 4 is connected to the outer cylinder 6 by a flexible connecting piece 12. The upper end of the connecting piece 12 is fixed to the outer peripheral surface of the outer cylinder 6, and the lower end is fixed to the ring portion 14a of the anti-rotation member 4. When the connecting piece 12 is restored to a substantially straight state, the anti-rotation member 4 is removed. The cylinder 6 is suspended. The anti-rotation member 4 can be resin-molded integrally with the outer cylinder 6 (parent cap 1) together with the connecting piece 12.

回り止め部材4は、親キャップ1と子キャップ2と底蓋3とを図10(B)に示すように組み合わせた後、同図(C)に示すように底蓋3に向かって押し付け、回り止め部材4の断面台形の十字状リブ14bを底蓋3の断面台形の十字状溝13eに強制的に嵌合させるとともに、回り止め部材4の内周の環状突部14を底蓋3の外周の環状溝13dに強制的に嵌合させ、更に回り止め部材4の凸部14dを外筒6の下端の凹部7aに嵌脱自在に嵌合させる。   The anti-rotation member 4 is formed by combining the parent cap 1, the child cap 2 and the bottom lid 3 as shown in FIG. 10 (B), and then pressing it toward the bottom lid 3 as shown in FIG. The cross-shaped rib 14b having the trapezoidal cross section of the stopper member 4 is forcibly fitted into the cross-shaped groove 13e having the trapezoidal cross section of the bottom cover 3, and the annular protrusion 14 on the inner periphery of the rotation preventing member 4 is The annular groove 13d is forcibly fitted, and the convex portion 14d of the rotation preventing member 4 is detachably fitted to the concave portion 7a at the lower end of the outer cylinder 6.

これにより回り止め部材4と底蓋3とは互いに外れないように合体され、しかも回り止め部材4は、底蓋3を抱持して外筒6に対し回り止め状態とする。   As a result, the anti-rotation member 4 and the bottom lid 3 are combined so as not to be separated from each other, and the anti-rotation member 4 holds the bottom lid 3 and is in a non-rotating state with respect to the outer cylinder 6.

実施例3のボトルキャップの場合、図13(A)に示すように、子キャップ2を矢印方向に回すと、その胴部8bの環状の下周縁部分8cを残して内筒9も回転しながら上昇するが、底蓋3は、回り止め部材4にて外筒6に対し回り止めされているので内筒9に追従して回転せず、子キャップ2を更に回して内筒9を更に上昇させると、同図(B)に示すように内筒9の下端の雌ネジ9dと底蓋3の雄ネジ13cとの螺合が外れ、底蓋3は、内筒9の下端から解放される。   In the case of the bottle cap of the third embodiment, as shown in FIG. 13A, when the child cap 2 is turned in the direction of the arrow, the inner cylinder 9 is also rotated while leaving the annular lower peripheral edge portion 8c of the trunk portion 8b. The bottom lid 3 is prevented from rotating with respect to the outer cylinder 6 by the anti-rotation member 4, and therefore does not rotate following the inner cylinder 9. The child cap 2 is further rotated to further raise the inner cylinder 9. Then, as shown in FIG. 5B, the screwing of the female screw 9d at the lower end of the inner cylinder 9 and the male screw 13c of the bottom cover 3 is released, and the bottom cover 3 is released from the lower end of the inner cylinder 9. .

内筒9の下端から解放された底蓋3は、内筒9内に充填されている圧力気体にて押し下げられ、これと一体に回り止め部材4も押し下げられて、その凸部14dが外筒6の下端の凹部7aから外れ、回り止め部材4が外筒6から解放されて底蓋3を保持したまま脱落する。これにより同図(C)に示すように、内筒9内の原料11が圧力気体と共に一気に噴出される。脱落した回り止め部材4は、連結片12がほぼ真っ直ぐな状態に復元することにより、底蓋3を保持したまま外筒6に懸垂される。   The bottom lid 3 released from the lower end of the inner cylinder 9 is pushed down by the pressure gas filled in the inner cylinder 9, and the rotation preventing member 4 is also pushed down together with this, so that the convex portion 14d becomes the outer cylinder. 6 is disengaged from the recess 7 a at the lower end of 6, and the rotation preventing member 4 is released from the outer cylinder 6 and falls off while holding the bottom cover 3. As a result, as shown in FIG. 5C, the raw material 11 in the inner cylinder 9 is ejected at a stretch together with the pressure gas. The fall-off preventing member 4 that has fallen is suspended from the outer cylinder 6 while holding the bottom cover 3 by restoring the connecting piece 12 to a substantially straight state.

実施例3のボトルキャップの場合、回り止め部材4を必要とするが、組み立ては、子キャップ2の内筒9内に原料11及び圧力気体を充填して底蓋3で封止した後、その封止した内筒9をそのまま外筒6に挿入して子キャップ2を外筒6の口部6aに被せ、回り止め部材4を底蓋3に向かって押し付けるだけで完了するので、特別な治具や反転機構等が不要であり、自動化が容易である。   In the case of the bottle cap of Example 3, the anti-rotation member 4 is required, but the assembly is performed after filling the inner cylinder 9 of the child cap 2 with the raw material 11 and the pressure gas and sealing with the bottom lid 3. The sealed inner cylinder 9 is inserted into the outer cylinder 6 as it is, the child cap 2 is put on the mouth portion 6a of the outer cylinder 6, and the anti-rotation member 4 is pressed toward the bottom cover 3 to complete the process. No tools or reversing mechanisms are required, and automation is easy.

図14〜図17は本発明の実施例4のボトルキャップを示し、図14及び図15は組み立て前の状態、図16は組み立てた状態、図17はボトルにセットした状態をそれぞれ示す。   14 to 17 show a bottle cap according to a fourth embodiment of the present invention. FIGS. 14 and 15 show a state before assembly, FIG. 16 shows an assembled state, and FIG. 17 shows a state set in a bottle.

実施例4のボトルキャップは、底蓋3を子キャップ2の内筒9の下端にネジ止めしないで、内筒9の下端開口を嵌合構造だけで気密かつ液密に封止できるようにしたもので、その他は上記の実施例と同様である。すなわち、底蓋3の環状凹溝3b内の雌ネジ3eを省略して、環状凹溝3bの断面を逆Ω状にする一方、内筒9の下端縁を外側に膨らむ突縁9eとする。そして、断面逆Ω状の環状凹溝3bと外側に膨らんだ突縁9eとを強制的に嵌合させ、つまり、内筒6の該突縁9eを含む下端部を断面逆Ω状の環状凹溝3bに圧入させて封止する。   In the bottle cap of Example 4, the bottom lid 3 is not screwed to the lower end of the inner cylinder 9 of the child cap 2, and the lower end opening of the inner cylinder 9 can be sealed airtight and liquid-tight only by the fitting structure. The others are the same as those in the above embodiment. That is, the internal thread 3e in the annular groove 3b of the bottom cover 3 is omitted, and the cross-section of the annular groove 3b is inverted Ω, while the lower edge of the inner cylinder 9 is a protruding edge 9e that bulges outward. Then, the annular concave groove 3b having a reverse Ω-shaped cross section and the protruding edge 9e bulging outward are forcibly fitted, that is, the lower end portion including the protruding edge 9e of the inner cylinder 6 is connected to the annular concave having an inverted Ω-shaped cross section. The groove 3b is press-fitted and sealed.

実施例4の場合には、底蓋3を内筒9の下端にネジ止めしていないので、外筒6に対して底蓋3を回り止めする必要はなく、子キャップ2を回して内筒9を上昇させていくと、底蓋3の周壁部3cが外筒6の下端に当接して底蓋3はそれ以上の上昇を拘束されるため、更に上昇していく内筒9から底蓋3が外れて脱落する。これが脱落すると、内筒9内の原料11が圧力気体と共に一気に噴出される。底蓋3はボトル内の液中に沈降する。   In the case of the fourth embodiment, since the bottom lid 3 is not screwed to the lower end of the inner cylinder 9, there is no need to prevent the bottom lid 3 from rotating around the outer cylinder 6, and the child cap 2 is turned to turn the inner cylinder 9 is raised, the peripheral wall portion 3c of the bottom cover 3 comes into contact with the lower end of the outer cylinder 6 and the bottom cover 3 is restrained from further rising. 3 comes off and falls off. When this falls off, the raw material 11 in the inner cylinder 9 is ejected at a stretch together with the pressure gas. The bottom lid 3 settles in the liquid in the bottle.

なお、実施例4の場合にも、上述した実施例の場合と同様に、底蓋3を連結片にて外筒5に連結してもよいこと勿論である。   In the case of the fourth embodiment as well, it is needless to say that the bottom cover 3 may be connected to the outer cylinder 5 with a connecting piece, as in the case of the above-described embodiment.

子キャップ2の胴部8bに、切り込み8dにより分離する環状の下周縁部分8cを設けない場合には、ボトル50にセットした状態で子キャップ2を不用意に回して開けないように、図18に示すように、子キャップ2の胴部8bと親キャップ1の胴部5bとを、透明又は半透明のシュリンクフィルム51にて包被する。このシュリンクフィルム51には、上側部分51aと下側部分51bとに上下に二分するための切り取り線51cと、上側部分51aを縦に切り裂くための切り裂き線51dとが設けられており、ボトルキャップの開封時には、切り裂き線51dで上側部分51aを切り裂いてから、子キャップ2の胴部8bに指を掛けてこれを回す。すると、シュリンクフィルム51が、切り取り線51cで上下に分離して、子キャップ2の胴部8bを包被していた上側部分51aは外れてしまうが、下側部分51bは、図19に示すように親キャップ1の胴部5bを包被したまま残る。このような状態になることで、当該ボトルキャップが開封されたことが分かる。これは、上記実施例1〜4のいずれにも適用できる。   When the body portion 8b of the child cap 2 is not provided with the annular lower peripheral edge portion 8c separated by the notch 8d, the child cap 2 is prevented from being unintentionally turned and opened in the state of being set in the bottle 50 as shown in FIG. As shown in FIG. 4, the trunk portion 8b of the child cap 2 and the trunk portion 5b of the parent cap 1 are covered with a transparent or translucent shrink film 51. The shrink film 51 is provided with a tear line 51c for vertically dividing the upper part 51a and the lower part 51b, and a tear line 51d for vertically tearing the upper part 51a. At the time of opening, after tearing the upper portion 51a along the tear line 51d, the finger is put on the trunk portion 8b of the child cap 2 and turned. Then, the shrink film 51 is separated vertically by the cut line 51c, and the upper portion 51a covering the trunk portion 8b of the child cap 2 is removed, but the lower portion 51b is as shown in FIG. The body portion 5b of the parent cap 1 remains covered. It turns out that the said bottle cap was opened by becoming such a state. This can be applied to any of Examples 1 to 4 described above.

上記の実施例では、内筒9内の原料11が酸素や湿気に接触して変質や腐敗等をしないようにするのに、内筒9内に圧力気体を封入したが、図20に示すように、脱酸素剤と除湿剤の両方又はいずれか一方21を内筒9内に封入してもよい。その場合、脱酸素剤又は除湿剤21を多孔質の容器22内に入れ、容器22ごと内筒9の奥端まで圧入する。その圧入に加えて、圧力気体も封入してもよい。   In the above embodiment, the pressure gas is sealed in the inner cylinder 9 so that the raw material 11 in the inner cylinder 9 does not deteriorate or decay due to contact with oxygen or moisture, but as shown in FIG. In addition, either or both of the oxygen absorber and the dehumidifier 21 may be enclosed in the inner cylinder 9. In that case, the oxygen scavenger or dehumidifier 21 is placed in the porous container 22 and the container 22 is press-fitted to the inner end of the inner cylinder 9. In addition to the press-fitting, a pressure gas may be enclosed.

図22に、本発明によるボトルキャップの組み立てから、圧力気体及び原料の充填、ボトルへの装着までを自動的に行う方法を例示する。
実施例1及び実施例2のボトルキャップの場合、図20(1)に示すように、親キャップ1を逆さにして底蓋3を外筒5にセットする。同図(2)に示すように、子キャップ2を逆さにして内筒9内に原料ホッパ52から原料11を定量投入する。
FIG. 22 illustrates a method for automatically performing from the assembly of the bottle cap according to the present invention to the filling of the pressure gas and the raw material and the mounting to the bottle.
In the case of the bottle caps of Example 1 and Example 2, as shown in FIG. 20 (1), the parent cap 1 is inverted and the bottom lid 3 is set on the outer cylinder 5. As shown in FIG. 2B, the child cap 2 is turned upside down, and the raw material 11 is quantitatively charged from the raw material hopper 52 into the inner cylinder 9.

同図(3)に示すように、親キャップ1及び子キャップ2を充填機53の圧力室54内に入れ、圧力室54内を真空ポンプ55に真空にした後、圧力気体供給装置56から圧力気体として窒素等の不活性ガスを供給する。   As shown in FIG. 3 (3), the parent cap 1 and the child cap 2 are placed in the pressure chamber 54 of the filling machine 53, the inside of the pressure chamber 54 is evacuated by the vacuum pump 55, and then the pressure is supplied from the pressure gas supply device 56. An inert gas such as nitrogen is supplied as a gas.

同図(4)に示すように、圧力室54内で底蓋3を治具57にて固定しておいたまま、子キャップ2をネジ込み装置58にて親キャップ1にネジ込んで、原料と圧力気体を充填した内筒9を封止した後、全体を反転させる。   As shown in FIG. 4 (4), the child cap 2 is screwed into the parent cap 1 by the screwing device 58 while the bottom lid 3 is fixed with the jig 57 in the pressure chamber 54, and the raw material is And the inner cylinder 9 filled with the pressure gas is sealed, and then the whole is inverted.

一方、同図(5)に示すように、ボトル50内にボトリングマシン59にて液体を充填しておく。そして、同図(6)に示すように、スクリューキャッパ60にて親キャップ1をボトル50の口部50aに螺合緊締する。螺合によらない場合には、同図(7)に示すように、プレスキャッパ61にて親キャップ1をボトル50の口部に強制的に嵌合させる。   On the other hand, as shown in FIG. 5 (5), the bottle 50 is filled with a liquid by a bottling machine 59. Then, as shown in FIG. 6 (6), the parent cap 1 is screwed and tightened to the mouth portion 50 a of the bottle 50 with the screw capper 60. When not using screwing, the parent cap 1 is forcibly fitted to the mouth of the bottle 50 by the press capper 61 as shown in FIG.

上述した実施例では、ボトル胴部に対し口部50aがすぼまったボトル50に適用した場合について説明したが、本発明によるボトルキャップは、図23及び図24に示すように、口部が胴部と同じような大きさの広口のボトルにも適用できる。   In the above-described embodiment, the case where the bottle portion 50a is applied to the bottle 50 having a narrowed mouth portion 50a has been described. However, the bottle cap according to the present invention has a mouth portion as shown in FIGS. It can also be applied to a wide-mouthed bottle that is the same size as the body.

本発明の実施例1のボトルキャップの組み立て前の状態で、(A)は斜視図、(B)は断面図である。In the state before the assembly of the bottle cap of Example 1 of this invention, (A) is a perspective view, (B) is sectional drawing. 同様の状態で、(A)は斜視図、(B)は断面図である。In the same state, (A) is a perspective view and (B) is a cross-sectional view. 同実施例の組み立てた状態で、(A)は正面図、(B)は断面図である。In the assembled state of the embodiment, (A) is a front view and (B) is a cross-sectional view. 同実施例のボトルにセットした状態の断面図である。It is sectional drawing of the state set to the bottle of the Example. 同実施例の開封の動作状態を(A)、(B)、(C)、(D)の順序で示す断面図である。It is sectional drawing which shows the operation state of opening of the Example in order of (A), (B), (C), (D). 本発明の実施例2のボトルキャップの組み立てた状態で、(A)は正面図、(B)は断面図である。In the state which assembled the bottle cap of Example 2 of this invention, (A) is a front view, (B) is sectional drawing. 同実施例のボトルにセットした状態の断面図である。It is sectional drawing of the state set to the bottle of the Example. 同実施例の開封の動作状態を(A)、(B)、(C)、(D)の順序で示す断面図である。It is sectional drawing which shows the operation state of opening of the Example in order of (A), (B), (C), (D). 開封よりボトル内の液体を飲用するまでの操作を(A)、(B)、(C)の順序で示す斜視図である。It is a perspective view which shows operation until it drinks the liquid in a bottle from opening in order of (A), (B), (C). 本発明の実施例3のボトルキャップについて、その組み立てまでを(A)、(B)、(C)の順序で示す断面図である。It is sectional drawing which shows to the assembly about the bottle cap of Example 3 of this invention in order of (A), (B), (C). 同実施例における底蓋の斜視図である。It is a perspective view of the bottom cover in the Example. 同実施例における回り止め部材の斜視図である。It is a perspective view of the detent | locking member in the Example. 同実施例の開封の動作状態を(A)、(B)、(C)の順序で示す断面図である。It is sectional drawing which shows the operation state of opening of the Example in order of (A), (B), (C). 本発明の実施例4のボトルキャップの組み立て前の状態で、(A)は斜視図、(B)は断面図である。In the state before the assembly of the bottle cap of Example 4 of this invention, (A) is a perspective view, (B) is sectional drawing. 同様の状態で、(A)は斜視図、(B)は断面図である。In the same state, (A) is a perspective view and (B) is a cross-sectional view. 同実施例の組み立てた状態で、(A)は斜視図、(B)は断面図である。In the assembled state of the embodiment, (A) is a perspective view and (B) is a cross-sectional view. 同実施例のボトルにセットした状態の断面図である。It is sectional drawing of the state set to the bottle of the Example. 本発明によるボトルキャップをシュリンクフィルムで包被した使用例を示す斜視図である。It is a perspective view which shows the usage example which covered the bottle cap by this invention with the shrink film. 同上においてシュリンクフィルムの一部を取り除いた状態の斜視図である。It is a perspective view of the state which removed a part of shrink film in the same as the above. 内筒内に脱酸素剤又は除湿剤を封入した実施例の断面図である。It is sectional drawing of the Example which enclosed the oxygen absorber or the dehumidifier in the inner cylinder. 外筒に排出用溝を設けてあることを示す断面図である。It is sectional drawing which shows that the groove | channel for discharge | emission is provided in the outer cylinder. 本発明によるボトルキャップの組み立てから、圧力気体及び原料の充填、ボトルへの装着までを自動的に行う方法の一例を示す説明図である。It is explanatory drawing which shows an example of the method of performing automatically from the assembly of the bottle cap by this invention to filling of pressure gas and a raw material, and mounting | wearing to a bottle. 広口のボトルに適用した実施例の斜視図である。It is a perspective view of the Example applied to the bottle of a wide mouth. 同上の断面図である。It is sectional drawing same as the above.

1 親キャップ
2 子キャップ
3 底蓋
3a 押込部
3b 環状凹溝
3c 周壁部
3d 突起
3e 雌ネジ
3f 凹部
4 回転止め部材
5 キャップ本体
5a 頂部
5b 胴部
5c 雌ネジ
5d ローレット
6 外筒
6a 口部
6b 垂下筒部
6c 段部
6d 雄ネジ
6e 排出用溝
7 凸部
7a 凹部
8 キャップ本体
8a 頂部
8b 胴部
8c 下周縁部分
8d 切り込み
8e 雌ネジ
8f ローレット
8g 矢印
9 内筒
9a 雄ネジ
9c 段部
9d 雌ネジ
9e 突縁
10 密閉リング
11 原料
12 連結片
13a 押込部
13b 鍔部
13c 雄ネジ
13b 鍔部
13e 十字状溝
14a リング部
14b 十字状リブ
14c 環状突部
14d 凸部
21 脱酸素剤又は除湿剤
22 容器
50 ボトル
50a ボトル口部
51 シュリンクフィルム
51a 上側部分
51b 下側部分
51c 切り取り線
51d 切り裂き線
52 原料ホッパ
53 充填機
54 圧力室
55 真空ポンプ
56 圧力気体供給装置
57 治具
58 ネジ込み装置
59 ボトリングマシン
60 スクリューキャッパ
61 プレスキャッパ
DESCRIPTION OF SYMBOLS 1 Parent cap 2 Child cap 3 Bottom cover 3a Pushing part 3b Annular groove 3c Circumferential wall part 3d Protrusion 3e Female thread 3f Recessed part 4 Anti-rotation member 5 Cap main body 5a Top part 5b Body part 5c Female screw 5d Knurl 6 Outer cylinder 6a Mouth part 6b Drooping cylinder part 6c Step part 6d Male thread 6e Discharge groove 7 Protrusion part 7a Concave part 8 Cap body 8a Top part 8b Body part 8c Lower peripheral edge part 8d Notch 8e Female thread 8f Knurl 8g Arrow 9 Inner cylinder 9a Male thread 9c Step part 9d Female Screw 9e Protruding edge 10 Sealing ring 11 Raw material 12 Connecting piece 13a Pushing portion 13b Hook portion 13c Male screw 13b Hook portion 13e Cross-shaped groove 14a Ring portion 14b Cross-shaped rib 14c Annular protrusion 14d Convex portion 21 Oxygen scavenger or dehumidifier 22 Container 50 Bottle 50a Bottle mouth part 51 Shrink film 51a Upper part 51b Lower part 51c Cut line 51d Ri tear line 52 feed hopper 53 filling machine 54 pressure chamber 55 a vacuum pump 56 pressure gas delivery system 57 jig 58 threaded device 59 bottling machine 60 screw capper 61 Puresukyappa

Claims (4)

ボトルの口部に挿入する外筒を備えた親キャップと、その外筒に挿入して原料収納部となる内筒を備えた子キャップと、その内筒の下端開口を前記外筒の外側で封止する底蓋とからなり、親キャップをボトルの口部に被せるとともに、子キャップを親キャップの外筒に螺合させることにより、該外筒の上端開口とともにボトルの口部を封止でき、また子キャップを親キャップの外筒に対し開く方向に回すことにより、底蓋が前記外筒によって内筒から脱落され、内筒内の原料がボトル内に放出されるボトルキャップにおいて、
ボトルの口部に螺合する前記親キャップのキャップ本体に、前記外筒が、キャップ本体の上下に突出するように一体に設けられ、ボトルの口部の外側に突出する外筒の上側部分が、前記子キャップを螺合させることにより封止される上端開口したネジ付き口部、キャップ本体より垂下してボトルの口部に挿入する外筒の下側部分が下端開口した垂下筒部となっており、この垂下筒部に、その内外を貫通して下端から途中まで上に延びる縦長の排出用切欠きが形成され、
また、前記内筒と前記底蓋とに、互いに螺合して緊締するネジ部を形成するとともに、底蓋と親キャップの外筒とに互いに係合する回り止め部を設け、子キャップを親キャップの外筒に対し開く方向に回したときに、底蓋が回り止め部により内筒との追従回転を規制されて互いのネジ部が外れ、内筒から脱落するようになっていることを特徴とするボトルキャップ。
A parent cap having an outer cylinder to be inserted into the mouth of the bottle, a child cap having an inner cylinder to be inserted into the outer cylinder and serving as a raw material storage section, and a lower end opening of the inner cylinder at the outer side of the outer cylinder It consists of a bottom lid to be sealed, and the bottle cap can be sealed together with the upper end opening of the outer cylinder by covering the bottle cap with the parent cap and screwing the child cap onto the outer cylinder of the parent cap. In the bottle cap in which the bottom cap is removed from the inner cylinder by the outer cylinder by turning the child cap in the opening direction with respect to the outer cylinder of the parent cap, and the raw material in the inner cylinder is discharged into the bottle.
The outer cylinder is integrally provided on the cap main body of the parent cap that is screwed into the mouth of the bottle so as to protrude upward and downward of the cap main body, and the upper portion of the outer cylinder that protrudes outside the mouth of the bottle , A screwed mouth portion having an upper end opening that is sealed by screwing the child cap, and a lower cylinder portion having a lower end opened at a lower portion of the outer cylinder that is suspended from the cap body and inserted into the mouth portion of the bottle. In this hanging cylinder part, a vertically long discharge notch extending through the inside and outside and extending upward from the lower end to the middle is formed.
In addition, the inner cylinder and the bottom lid are formed with threaded portions that are screwed together and tightened, and a rotation stopper portion that engages with the bottom lid and the outer cylinder of the parent cap is provided so that the child cap can be When the cap is rotated in the opening direction with respect to the outer cylinder, the bottom lid is restricted from following and rotating with the inner cylinder by the anti-rotation part, so that the screw parts of each other come off and fall off from the inner cylinder. Characteristic bottle cap.
底蓋の周縁に、内筒の下端部を圧入させることができる環状凹溝が形成され、該環状溝の内面に、内筒の下端部のネジ部と螺合するネジ部が形成されていることを特徴とする請求項1に記載のボトルキャップ。   An annular concave groove capable of press-fitting the lower end portion of the inner cylinder is formed on the periphery of the bottom lid, and a screw portion that is screwed with a screw portion of the lower end portion of the inner cylinder is formed on the inner surface of the annular groove. The bottle cap according to claim 1. 底蓋が可撓性の連結片にて親キャップの外筒と連結され、内筒から脱落したときに該連結片にて外筒に懸垂されることを特徴とする請求項1又は2に記載のボトルキャップ。   The bottom cover is connected to the outer cylinder of the parent cap by a flexible connecting piece, and is suspended from the outer cylinder by the connecting piece when dropped from the inner cylinder. Bottle cap. 外筒の内周面の中途と内筒の外周面の中途とにそれぞれ段部を形成し、これら段部が、子キャップで親キャップの上端開口を閉じたとき上下に対向するようにしたことを特徴とする請求項1〜3のいずれかに記載のボトルキャップ。   Steps were formed in the middle of the inner peripheral surface of the outer cylinder and in the middle of the outer peripheral surface of the inner cylinder, and these stepped parts faced up and down when the upper end opening of the parent cap was closed with the child cap. The bottle cap according to any one of claims 1 to 3.
JP2009000404A 2009-01-05 2009-01-05 Bottle cap Pending JP2009102076A (en)

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Cited By (1)

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Publication number Priority date Publication date Assignee Title
JP2014145631A (en) * 2013-01-28 2014-08-14 Ushio Inc Reagent solution kit for fluorometry

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JPS5346960A (en) * 1976-10-12 1978-04-27 Abic Ltd Biss22furanizylether and its preparation
JPS5841336A (en) * 1981-09-04 1983-03-10 Toa Medical Electronics Co Ltd Particle analyzer
JPH03126879A (en) * 1989-10-09 1991-05-30 Sumitomo Metal Ind Ltd Production of cold rolled steel sheet excellent in chemical conversion treating property
JPH10273161A (en) * 1997-03-26 1998-10-13 Mitsubishi Materials Corp Container cap and container
JP3281730B2 (en) * 1994-09-28 2002-05-13 株式会社吉野工業所 Two-part mixing container

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Publication number Priority date Publication date Assignee Title
JPS5346960A (en) * 1976-10-12 1978-04-27 Abic Ltd Biss22furanizylether and its preparation
JPS5841336A (en) * 1981-09-04 1983-03-10 Toa Medical Electronics Co Ltd Particle analyzer
JPH03126879A (en) * 1989-10-09 1991-05-30 Sumitomo Metal Ind Ltd Production of cold rolled steel sheet excellent in chemical conversion treating property
JP3281730B2 (en) * 1994-09-28 2002-05-13 株式会社吉野工業所 Two-part mixing container
JPH10273161A (en) * 1997-03-26 1998-10-13 Mitsubishi Materials Corp Container cap and container

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JP2014145631A (en) * 2013-01-28 2014-08-14 Ushio Inc Reagent solution kit for fluorometry

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