JP2009097016A5 - - Google Patents

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JP2009097016A5
JP2009097016A5 JP2008275027A JP2008275027A JP2009097016A5 JP 2009097016 A5 JP2009097016 A5 JP 2009097016A5 JP 2008275027 A JP2008275027 A JP 2008275027A JP 2008275027 A JP2008275027 A JP 2008275027A JP 2009097016 A5 JP2009097016 A5 JP 2009097016A5
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group
monomer
polymer
electron withdrawing
polymer according
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JP2008275027A
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Japanese (ja)
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JP5283479B2 (en
JP2009097016A (en
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Priority claimed from GBGB0225869.7A external-priority patent/GB0225869D0/en
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Claims (16)

式（Ｉ）の選択的に置換された第１繰返し単位を含むポリマーであって、
ここで、Ａｒは
（ａ）少なくとも１つの電子誘引基で置換される芳香族炭化水素、又は
（ｂ）電子誘引ヘテロアリール
を含む（但し、フルオリン原子、フルオロアルキル、フルオロアリール及びフルオロヘテロアリールから選択される少なくとも１つの電子誘引基で置換されるフェニル又はオリゴフェニルではない）ポリマー。 A polymer comprising a selectively substituted first repeat unit of formula (I), comprising:
Wherein Ar includes (a) an aromatic hydrocarbon substituted with at least one electron withdrawing group, or (b) includes an electron withdrawing heteroaryl, provided that they are selected from fluorin atoms, fluoroalkyl, fluoroaryl and fluoroheteroaryl Polymer that is not phenyl or oligophenyl substituted with at least one electron-withdrawing group . 式（ＩＩ）を有する繰返し単位を含む請求項１に記載のポリマーであって、
ここで、各Ａｒは、
（ｃ）少なくとも１つの電子誘引基で置換される芳香族炭化水素、又は
（ｄ）電子誘引ヘテロアリール
からそれぞれ独立して選択される（但し、フルオリン原子、フルオロアルキル、フルオロアリール及びフルオロヘテロアリールから選択される少なくとも１つの電子誘引基で置換されるフェニル又はオリゴフェニルではない）ポリマー。 A polymer according to claim 1, comprising repeat units having the formula (II),
Here, each Ar is
(C) an aromatic hydrocarbon substituted with at least one electron withdrawing group, or (d) each independently selected from electron withdrawing heteroaryl (provided from fluorin atom, fluoroalkyl, fluoroaryl and fluoroheteroaryl) Polymers that are not phenyl or oligophenyl substituted with at least one selected electron withdrawing group . 各Ａｒは式（ＩＩＩ）の単位から独立して選択される請求項１又は２に記載のポリマーであって、
ここで、ｎは１〜３であり、Ｒ1〜Ｒ5の少なくとも１つは電子誘引基になるように、
水素、
アルキル、アルコキシ、アリールアルキル及びヘテロアリールアルキルから選択される溶解性基、及び
電子誘引基
から独立して選択されるポリマー。 A polymer according to claim 1 or 2, wherein each Ar is independently selected from units of formula (III),
Here, n is 1 to 3, and at least one of R 1 to R 5 is an electron withdrawing group.
hydrogen,
A polymer independently selected from a soluble group selected from alkyl, alkoxy, arylalkyl and heteroarylalkyl, and an electron withdrawing group. Ａｒは少なくとも１つの電子誘引基で置換されたフェニル又はオリゴフェニルであり、少なくとも１つの電子誘引基は、フルオリン、シアノ及びニトロからなる群より選択される請求項１ないし３のいずれかに記載のポリマー。 4. Ar according to any of claims 1 to 3, wherein Ar is phenyl or oligophenyl substituted with at least one electron withdrawing group, wherein the at least one electron withdrawing group is selected from the group consisting of fluorin, cyano and nitro. polymer. 電子誘引ヘテロアリールが選択的に置換されたピリジン及びトリアジンから選択される請求項１又は２に記載のポリマー。 3. A polymer according to claim 1 or 2, wherein the electron withdrawing heteroaryl is selected from selectively substituted pyridines and triazines. 第２の繰返し単位を含む請求項１ないし５のいずれかに記載のポリマー。 The polymer according to any one of claims 1 to 5 , comprising a second repeating unit. 第２繰返し単位がトリアリールアミン及び複素環式芳香族化合物から選択される請求項１ないし６のいずれかに記載のポリマー。 The polymer according to any one of claims 1 to 6 , wherein the second repeating unit is selected from a triarylamine and a heterocyclic aromatic compound. 電子を輸送することができる請求項１ないし７のいずれかに記載のポリマー。 The polymer according to any one of claims 1 to 7 , which can transport electrons. 正孔輸送及び／又は発光することができる少なくとも１つの区域を含む請求項８に記載のポリマー。 9. A polymer according to claim 8 , comprising at least one zone capable of hole transport and / or light emission. 請求項１ないし９のいずれかに記載のポリマーを含む光学装置。 Optical device comprising a polymer according to any one of claims 1 to 9. 電子冷光放射性装置である請求項１０に記載の光学装置。 The optical device according to claim 10 , which is an electronic cold light emitting device. 第１のタイプの電荷輸送体を注入する第１電極、
第２のタイプの電荷輸送体を注入する第２電極、及び
第１及び第２電極の間に請求項１ないし４のいずれかに記載のポリマーから構成される発光層、
を含む電子冷光放射性装置。 A first electrode for injecting a first type of charge transporter;
A second electrode for injecting a second type of charge transporter, and a light emitting layer composed of the polymer according to any one of claims 1 to 4 between the first and second electrodes,
An electronic cold-emitting device comprising: モノマーを重合するための条件下において、第１モノマーを第１モノマーと同じか異なる第２モノマーと反応させる工程を含むポリマーの製造方法であって、
前記第１モノマーは式（ＩＶ）の選択的に置換された化合物を含むものである方法
（ここで、各Ｐは独立して重合基を表し、Ａｒは請求項１ないし５のいずれかで定義される）。 A process for producing a polymer comprising reacting a first monomer with a second monomer that is the same as or different from the first monomer under conditions for polymerizing the monomer ,
The method wherein the first monomer comprises a selectively substituted compound of formula (IV)
(Here, each P independently represents a polymerized group, and Ar is defined in any one of claims 1 to 5) . モノマーを重合するための条件下において、第１モノマーを第１モノマーと同じか異なる第２モノマーと反応させる工程を含むポリマーの製造方法であって、A method for producing a polymer comprising reacting a first monomer with a second monomer that is the same as or different from the first monomer under conditions for polymerizing the monomer,
前記第１モノマーは式（Ｖ）の選択的に置換された化合物を含むものである方法The method wherein the first monomer comprises a selectively substituted compound of formula (V)
（ここで、各Ｐは独立して重合基を表す）。(Here, each P independently represents a polymeric group). 各Ｐが、ボロン酸基、ボロンエステル基及びボラン基並びに反応性ハロゲン基から選択される反応性ボロン誘導基から独立して選択される請求項１３又は１４に記載のポリマーの製造方法。The method for producing a polymer according to claim 13 or 14, wherein each P is independently selected from a reactive boron derivative group selected from a boronic acid group, a boron ester group and a borane group, and a reactive halogen group. （ａ）各Ｐが、ボロン酸基、ボロンエステル基及びボラン基から選ばれるボロン誘導官能基であるモノマー、並びに少なくとも２つの反応性ハロゲン官能基を有する芳香族モノマー、又は
（ｂ）各Ｐが、反応性ハロゲン官能基であるモノマー、並びに、ボロン酸基、ボロンエステル基及びボラン基から選択される少なくとも２つのボロン誘導官能基を有する芳香族モノマー、又は
（ｃ）１つのＰが、反応性ハロゲン官能基であり、１つのＰがボロン酸基、ボロンエステル基及びボラン基から選択されるボロン誘導官能基であるモノマー、
の反応混合物の重合を含み、
ここで、反応混合物は芳香族モノマーの重合を触媒するに適当な触媒量の触媒、並びにボロン誘導官能基をボロネートアニオン基に転換するに十分な量の塩基を含む請求項１５に記載のポリマーの製造方法。 (A) a monomer in which each P is a boron-derived functional group selected from a boronic acid group, a boron ester group and a borane group, and an aromatic monomer having at least two reactive halogen functional groups, or (b) each P is , the monomer is a reactive halide functional group, and a boronic acid group, an aromatic monomer having at least two boron derivative functional groups selected from boronic ester group and a borane group, or (c) 1 one P is a reactive A monomer that is a halogen functional group and one P is a boron-derived functional group selected from a boronic acid group, a boron ester group and a borane group;
Polymerization of the reaction mixture of
16. The polymer of claim 15 , wherein the reaction mixture comprises a catalytic amount of a catalyst suitable to catalyze the polymerization of an aromatic monomer, and a sufficient amount of base to convert a boron-derived functional group to a boronate anion group. Manufacturing method.
JP2008275027A 2002-11-06 2008-10-27 polymer Expired - Fee Related JP5283479B2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0225869.7 2002-11-06
GBGB0225869.7A GB0225869D0 (en) 2002-11-06 2002-11-06 Polymer

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US (2) US7494720B2 (en)
EP (2) EP2363423A1 (en)
JP (2) JP4293991B2 (en)
KR (1) KR100604500B1 (en)
CN (3) CN101870765B (en)
AT (1) ATE554121T1 (en)
AU (1) AU2003285484A1 (en)
GB (1) GB0225869D0 (en)
WO (1) WO2004041902A2 (en)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0225869D0 (en) * 2002-11-06 2002-12-11 Cambridge Display Tech Ltd Polymer
JP4940658B2 (en) 2003-07-08 2012-05-30 コニカミノルタホールディングス株式会社 Organic electroluminescence device
US8052894B2 (en) * 2004-12-03 2011-11-08 Sumitomo Chemical Company, Limited Salicylate substituted conjugated polymers and devices
KR101249640B1 (en) * 2004-12-06 2013-04-01 에스케이이노베이션 주식회사 Electroluminescent Polymers having 9-fluoren-2-yl-9-aryl-2,7-fluorenyl Unit and the Electroluminescent Device Prepared Using the Same
US20060121314A1 (en) * 2004-12-06 2006-06-08 Sk Corporation Electroluminescent polymer having 9-fluoren-2-yl-9-aryl-2,7-fluorenyl unit and electroluminescent device manufactured using the same
GB2440934B (en) 2006-04-28 2009-12-16 Cdt Oxford Ltd Opto-electrical polymers and devices
KR20090034398A (en) 2006-08-01 2009-04-07 스미또모 가가꾸 가부시키가이샤 Polymer compound and polymer light-emitting device
KR20090053949A (en) * 2006-09-13 2009-05-28 스미또모 가가꾸 가부시키가이샤 Polymer compound and polymer light-emitting device
CN101836306B (en) * 2007-10-24 2013-09-18 默克专利有限公司 Optoelectronic device
GB2454890B (en) * 2007-11-21 2010-08-25 Limited Cambridge Display Technology Light-emitting device and materials therefor
CN101591219B (en) * 2008-05-29 2012-08-08 中国科学院化学研究所 Functional polyfluorene compound and intermediate and application thereof
DE102008045663A1 (en) * 2008-09-03 2010-03-04 Merck Patent Gmbh Fluorine-bridged associates for opto-electronic applications
DE102009034194A1 (en) 2009-07-22 2011-01-27 Merck Patent Gmbh Materials for electronic devices
US20110077373A1 (en) * 2009-09-29 2011-03-31 General Electric Company Polymer and optoelectronic device comprising the same
TWI401274B (en) * 2009-10-16 2013-07-11 Univ Nat Taiwan Science Tech Novel high polymer and copolymer and method of making the same
KR101663185B1 (en) * 2009-11-20 2016-10-06 삼성전자주식회사 Fluoro group-containing polymer, organic light emitting device comprising the polymer and method for manufacturing the device
JP5710993B2 (en) 2010-01-28 2015-04-30 住友化学株式会社 Polymer compound and light emitting device using the same
EP2530100B1 (en) * 2010-01-28 2015-10-21 Sumitomo Chemical Co., Ltd Polymer compound and light-emitting device using same
DE102010033080A1 (en) 2010-08-02 2012-02-02 Merck Patent Gmbh Polymers with structural units that have electron transport properties
JP5750247B2 (en) * 2010-08-31 2015-07-15 住友化学株式会社 Organic thin film transistor and manufacturing method thereof
GB2483269A (en) * 2010-09-02 2012-03-07 Cambridge Display Tech Ltd Organic Electroluminescent Device containing Fluorinated Compounds
JP5883570B2 (en) * 2011-03-25 2016-03-15 国立大学法人横浜国立大学 Laminated structure
WO2013047106A1 (en) * 2011-09-30 2013-04-04 三菱瓦斯化学株式会社 Resin having fluorene structure and underlayer film-forming material for lithography

Family Cites Families (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB8909011D0 (en) 1989-04-20 1989-06-07 Friend Richard H Electroluminescent devices
WO1994029883A1 (en) 1993-06-10 1994-12-22 Cambridge Display Technology Limited Polymers for optical devices
US5523555A (en) 1994-09-14 1996-06-04 Cambridge Display Technology Photodetector device having a semiconductive conjugated polymer
GB9423692D0 (en) 1994-11-23 1995-01-11 Philips Electronics Uk Ltd A photoresponsive device
JP3865406B2 (en) * 1995-07-28 2007-01-10 住友化学株式会社 2,7-Aryl-9-substituted fluorene and 9-substituted fluorene oligomers and polymers
KR0176331B1 (en) 1996-05-16 1999-04-01 박원훈 Floren based shift copolymer for electroluminescent device and electroluminescent device using same as light emitting material
JP3824385B2 (en) 1996-08-02 2006-09-20 三井化学株式会社 Organic electroluminescence device
US6309763B1 (en) 1997-05-21 2001-10-30 The Dow Chemical Company Fluorene-containing polymers and electroluminescent devices therefrom
US5777070A (en) 1997-10-23 1998-07-07 The Dow Chemical Company Process for preparing conjugated polymers
KR100697861B1 (en) 1998-03-13 2007-03-22 캠브리지 디스플레이 테크놀로지 리미티드 Electroluminescent devices
GB9805476D0 (en) 1998-03-13 1998-05-13 Cambridge Display Tech Ltd Electroluminescent devices
DE19846768A1 (en) * 1998-10-10 2000-04-20 Aventis Res & Tech Gmbh & Co A conjugated polymer useful as an organic semiconductor, an electroluminescence material, and for display elements in television monitor and illumination technology contains fluorene building units
DE19846766A1 (en) * 1998-10-10 2000-04-20 Aventis Res & Tech Gmbh & Co A conjugated fluorene-based polymer useful as an organic semiconductor, electroluminescence material, and for display elements
DE69924155T2 (en) * 1999-02-04 2006-04-13 Dow Global Technologies, Inc., Midland FLUORES-COPOLYMERS AND DEVICES MANUFACTURED THEREFROM
WO2000053656A1 (en) 1999-03-05 2000-09-14 Cambridge Display Technology Limited Polymer preparation
WO2001062822A1 (en) 2000-02-25 2001-08-30 Cambridge Display Technology Limited Electro-luminiscent polymers, their preparation and uses
KR100354500B1 (en) * 2000-09-05 2002-09-30 한화석유화학 주식회사 Fluorene based polymers and light emitting diodes fabricated with the same as light emitting material
EP1220341B1 (en) * 2000-12-28 2008-07-02 Kabushiki Kaisha Toshiba Organic electroluminescent device and display apparatus
JP3972588B2 (en) * 2001-02-26 2007-09-05 淳二 城戸 Organic electroluminescence device
CN1216928C (en) * 2001-03-24 2005-08-31 科文有机半导体有限公司 Conjugated polymerts cotg. spirobifluorene units and fluourene units, and use thereof
GB0111549D0 (en) * 2001-05-11 2001-07-04 Cambridge Display Tech Ltd Polymers, their preparation and uses
KR100453809B1 (en) * 2001-07-21 2004-10-20 한국전자통신연구원 Spirobifluorene compounds, electroluminescence polymer and electroluminescence element having the same
EP1416028A1 (en) * 2002-10-30 2004-05-06 Covion Organic Semiconductors GmbH New method for the production of monomers useful in the manufacture of semiconductive polymers
GB0225869D0 (en) * 2002-11-06 2002-12-11 Cambridge Display Tech Ltd Polymer

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