JP2009078485A - Shaft body and writing utensil using the shaft body - Google Patents

Shaft body and writing utensil using the shaft body Download PDF

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JP2009078485A
JP2009078485A JP2007250718A JP2007250718A JP2009078485A JP 2009078485 A JP2009078485 A JP 2009078485A JP 2007250718 A JP2007250718 A JP 2007250718A JP 2007250718 A JP2007250718 A JP 2007250718A JP 2009078485 A JP2009078485 A JP 2009078485A
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shaft
resin
laser light
shaft body
shaft tube
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JP5364987B2 (en
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Naoto Yoshihara
直人 吉原
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Pentel Co Ltd
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Pentel Co Ltd
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<P>PROBLEM TO BE SOLVED: To prevent the separation of joint portion of a shaft tube and the generation of looseness caused by the swelling with sweat in the shaft body formed with two or more shaft tubes each being inserted to and contacted with the other. <P>SOLUTION: In a shaft body formed with two or more shaft tubes each being inserted to and contacted with the other, at least one shaft tube is made of non-permeable resin which is opaque to a laser beam, and at least one shaft tube contacting the shaft tube is made of a permeable resin which is penetrable by a laser beam, and the contacting portion of these shaft tubes are welded and joined by the irradiation of a laser beam. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、軸体、特に把持部を設けた軸体の接合に関するものであり、その軸体の1例としては、ボールペンやシャープペンシルなどの筆記具や、口紅やアイライナーなど細長い容器、釣り竿、ドアノブ、ドライバーなどの工具類が挙げられる。   The present invention relates to the joining of a shaft body, particularly a shaft body provided with a gripping part, and examples of the shaft body include writing instruments such as ballpoint pens and mechanical pencils, elongated containers such as lipsticks and eyeliners, fishing rods, Examples include tools such as door knobs and drivers.

軸体を形成する軸筒の接合には係止用の凹凸部を設けた嵌合、ネジ、接着、熱溶着、超音波溶着と言った様々な手段があり、これらは接合の目的や強度、また工数やコストの観点から様々な発明がなされている。
実開昭59−122286号公報(凹凸部を設けた嵌合:三菱) 実開昭59−122285号公報(ネジ:三菱) 実開平3−29453号公報(熱溶着:ぺんてる) 実開平3−103780号公報(超音波溶着:三菱)
There are various means such as fitting, screws, bonding, thermal welding, ultrasonic welding, which are provided with concave and convex portions for locking, for joining the shaft cylinders forming the shaft body, and these are the purpose and strength of joining, Various inventions have been made from the viewpoint of man-hours and costs.
Japanese Utility Model Publication No. 59-122286 (Fitting with uneven portions: Mitsubishi) Japanese Utility Model Publication No.59-122285 (Screw: Mitsubishi) Japanese Utility Model Publication No. 3-29453 (thermal welding: Pentel) Japanese Utility Model Publication No. 3-103780 (ultrasonic welding: Mitsubishi)

しかし、材料の特性や構造上の制約によって十分な接合強度が得られない場合には、軸体の使用時に接合部が外れたり、剥がれたりして使用できなくなってしまう。特に、把持部等に弾性樹脂を使用する場合には、弾性樹脂内に含有される油分が接着剤の硬化を阻害したり、接着成分の活性を弱めるため、例えば、プライマーを使用しても強固な接合が難しく、把持部のズレや膨潤によるゆるみが発生するといった問題があった。また、強力な接着剤の使用は樹脂をその成分中に含まれる有機溶剤で樹脂が溶解するため、外観に凹みが発せするなど問題が発生してしまう。
また、熱溶着の場合は、外面にヒートシールなどを巻きつけることから、その外面に溶着痕が残る問題がある。
さらに、超音波溶着の場合は、弾性樹脂に振動が吸収されるため、樹脂同士の溶解が発生しにくく十分な溶着強度が得られない。ここで、超音波の出力を高くしてしまうと接着面以外の部分にも熱が伝わってしまい外観不良が発生したり、接着対象となる硬質の樹脂材料に破損が生じたりするといった問題があった。
However, if sufficient joint strength cannot be obtained due to material characteristics and structural restrictions, the joint portion may be detached or peeled off when the shaft is used, making it unusable. In particular, when an elastic resin is used for the gripping part or the like, the oil contained in the elastic resin inhibits the curing of the adhesive or weakens the activity of the adhesive component. There was a problem that smooth joining was difficult and loosening due to displacement or swelling of the gripping part occurred. In addition, the use of a strong adhesive causes problems such as the appearance of dents because the resin dissolves in the organic solvent contained in the component.
Further, in the case of heat welding, since a heat seal or the like is wound around the outer surface, there is a problem that a welding mark remains on the outer surface.
Further, in the case of ultrasonic welding, since vibration is absorbed by the elastic resin, it is difficult for the resins to be dissolved, and a sufficient welding strength cannot be obtained. Here, if the output of the ultrasonic wave is increased, heat is transmitted to parts other than the bonding surface, resulting in a defective appearance and damage to the hard resin material to be bonded. It was.

そこで、本発明は、2つ以上の軸筒の一方を他方に挿入し当接して形成される軸体において、軸筒の少なくとも一つはレーザー光に対して透過性のない非透過性樹脂を材料とし、それに当接する軸筒の少なくとも一つはレーザー光に対して透過性のある透過性樹脂を材料とし、軸筒同士の当接部をレーザー光の照射によって溶着し、接合したことを第1の要旨とし、前記樹脂の少なくとも一つに弾性樹脂を使用したことを第2の要旨とする。さらに、前記弾性樹脂を使用した軸筒が把持部であることを第3の要旨とし、軸体を筆記具に使用したことを第4の要旨とするものである。   Therefore, the present invention provides a shaft body formed by inserting and abutting one of two or more shaft cylinders into the other, and at least one of the shaft cylinders is made of an impermeable resin that is not transmissive to laser light. The material, and at least one of the shaft cylinders in contact with it is made of a transparent resin that is transmissive to the laser light, and the contact portion between the shaft cylinders is welded and joined by laser light irradiation. The second gist is that an elastic resin is used as at least one of the resins. Further, a third gist is that the shaft cylinder using the elastic resin is a gripping portion, and a fourth gist is that the shaft body is used for a writing instrument.

軸体は2つ以上の軸筒の一方を他方に挿入し当接して形成されればよい。軸筒は、少なくとも一つはレーザー光に対して透過性のない非透過性樹脂を材料とし、それに当接する軸筒の少なくとも一つはレーザー光に対して透過性のある透過性樹脂を材料とする。その他の軸筒は樹脂、木材、石材など軸体として使用できるものであればよく、特に限定されない。また、これらの材質は1種または、2種以上の混合物であってもよい。   The shaft body may be formed by inserting one of two or more shaft cylinders into the other and contacting. At least one of the shaft cylinders is made of a non-transparent resin that is not transmissive to laser light, and at least one of the shaft cylinders that contacts the shaft cylinder is made of a transmissive resin that is transmissive to laser light. To do. Other shaft cylinders are not particularly limited as long as they can be used as a shaft body such as resin, wood, and stone. These materials may be one kind or a mixture of two or more kinds.

レーザー溶着方法では、透過性樹脂材内を透過したレーザー光が非透過性樹脂材の当接面に到達して吸収され、この当接面に吸収されたレーザー光がエネルギーとして蓄積される。その結果、非透過性樹脂材の当接面が加熱溶融されるとともに、この非透過性樹脂材の当接面からの熱伝達により透過性樹脂材の当接面が加熱溶融される。この状態で、透過性樹脂材と非透過性樹脂材の当接面同士を圧着させれば、両者を一体的に接合することができる。こうして得られた接合部は、接合面同士が溶融されて接合されており、該接合面同士の間では両成形部材を構成する両樹脂が溶融して互いに入り込み絡まった状態が形成されているため、強固な接合状態を構成して高い接合強度及び耐圧強度を有している。その為、軸筒同士の当接部はレーザーを照射した際に完全に溶着するよう密接している必要がある。密接させる手段としては、外部から圧力をかける、軸筒同士を螺合する、圧入する、部分的な凹凸によって嵌合する、軸筒の一方に弾性樹脂を用いてその弾性によって圧接するといった方法があげられるが、レーザーを照射する軸筒同士の当接部が圧接していればよく、特に限定されない。接合の界面(接合面)のみで溶融が発生する為、表面が犯されることはなく、外観上の問題は発生しない。   In the laser welding method, the laser light transmitted through the transparent resin material reaches the contact surface of the non-transparent resin material and is absorbed, and the laser light absorbed on the contact surface is accumulated as energy. As a result, the contact surface of the non-permeable resin material is heated and melted, and the contact surface of the transparent resin material is heated and melted by heat transfer from the contact surface of the non-permeable resin material. In this state, if the contact surfaces of the permeable resin material and the non-permeable resin material are pressure-bonded to each other, they can be joined together. In the joint portion thus obtained, the joining surfaces are melted and joined, and between the joining surfaces, both resins constituting both molded members are melted and are intertwined with each other. It has a strong bonding state and a high pressure strength by constituting a strong bonding state. For this reason, the contact portions of the shaft tubes need to be in close contact with each other when they are irradiated with laser. As means for close contact, there are methods such as applying pressure from the outside, screwing the shaft cylinders together, press-fitting, fitting by partial unevenness, and press-contacting one of the shaft cylinders by the elasticity using an elastic resin. However, there is no particular limitation as long as the abutting portions of the shaft cylinders that irradiate the laser are in pressure contact with each other. Since melting occurs only at the bonding interface (bonding surface), the surface is not violated, and no appearance problem occurs.

上記透過性樹脂材に用いる樹脂及び/または弾性樹の種類としては、加熱源としてのレーザ光を所定の透過率以上で透過させうるものであれば特に限定されない。樹脂としてはポリ塩化ビニル(PVC)、ポリ塩化ビニリデン(PVDC)、ポリエチレン樹脂(PE)、ポリプロピレン樹脂(PP)、ポリスチレン樹脂(PS)、アクリロニトリルスチレン樹脂(AS)、アクリロニトリルスチレンブタジエン樹脂(ABS)、メタクリル樹脂(PMMA)、ポリアセタール樹脂(POM)、ナイロン6樹脂(PA6)やナイロン66樹脂(PA66)等のポリアミド樹脂(PA)、ポリカーボネート樹脂(PC)、ポリエチレンテレンテレフタレート樹脂(PET)、ポリブチレンテレフタレート(PBT)、四フッ化エチレン樹脂(PTFE)、弾性樹脂としてはアクリル樹脂やシリコーン樹脂、フッ素樹脂、塩化ビニル、ウレタン樹脂、ポリウレタン樹脂、ポリエチレン樹脂、エラストマーゲル、ポリエチレンゲル、ウレタンゴム、エチレンアクリルゴム、エピクロルヒドリンゴム、アクリルゴム、エチレンプロピレンゴム、クロロプレンゴム、天然ゴム、イソプレンゴム、塩素化ポリエチレン、ニトリルゴム、スチレン系エラストマー、オレフィン系エラストマー、エステル系エラストマー、ウレタン系エラストマーなどが挙げられるが、形状が維持できるものであれば特に限定されない。これら樹脂及び/または弾性樹脂は1種または2種以上の混合物であってもよい。   The type of resin and / or elastic tree used for the transparent resin material is not particularly limited as long as it can transmit laser light as a heating source at a predetermined transmittance or higher. As the resin, polyvinyl chloride (PVC), polyvinylidene chloride (PVDC), polyethylene resin (PE), polypropylene resin (PP), polystyrene resin (PS), acrylonitrile styrene resin (AS), acrylonitrile styrene butadiene resin (ABS), Methacrylic resin (PMMA), polyacetal resin (POM), polyamide resin (PA) such as nylon 6 resin (PA6) and nylon 66 resin (PA66), polycarbonate resin (PC), polyethylene terephthalate resin (PET), polybutylene terephthalate (PBT), ethylene tetrafluoride resin (PTFE), elastic resins include acrylic resin, silicone resin, fluorine resin, vinyl chloride, urethane resin, polyurethane resin, polyethylene resin, elastomer gel, Reethylene gel, urethane rubber, ethylene acrylic rubber, epichlorohydrin rubber, acrylic rubber, ethylene propylene rubber, chloroprene rubber, natural rubber, isoprene rubber, chlorinated polyethylene, nitrile rubber, styrene elastomer, olefin elastomer, ester elastomer, urethane Although an elastomer etc. are mentioned, if a shape can be maintained, it will not specifically limit. These resins and / or elastic resins may be one kind or a mixture of two or more kinds.

弾性樹脂の硬度は、ショアーAで0度から90度もしくは、アスカーCで0度から90度までの硬度範囲の中で適宜選択すればよく、特に限定されるものではない。ただし、ショアーAで60度、アスカーCで80度以上の弾性樹脂は硬くなり、表面のベタツキや膨潤も少なくなることから、ショアーAで60度以下、アスカーCで80度以下の弾性樹脂であることが望ましい。   The hardness of the elastic resin may be appropriately selected within a hardness range of 0 to 90 degrees for Shore A or 0 to 90 degrees for Asker C, and is not particularly limited. However, an elastic resin of 60 degrees or less on Shore A and 80 degrees or more on Asker C becomes hard and less sticky or swells on the surface. Therefore, it is an elastic resin of 60 degrees or less on Shore A and 80 degrees or less on Asker C. It is desirable.

上記非透過性樹脂材に用いる樹脂及び/または弾性樹脂の種類としては、加熱源としてのレーザ光を透過させずに吸収しうるものであれば特に限定されない。樹脂としてはポリ塩化ビニル(PVC)、ポリ塩化ビニリデン(PVDC)、ポリエチレン樹脂(PE)、ポリプロピレン樹脂(PP)、ポリスチレン樹脂(PS)、アクリロニトリルスチレン樹脂(AS)、アクリロニトリルスチレンブタジエン樹脂(ABS)、メタクリル樹脂(PMMA)、ポリアセタール樹脂(POM)、ナイロン6樹脂(PA6)やナイロン66樹脂(PA66)等のポリアミド樹脂(PA)、ポリカーボネート樹脂(PC)、ポリエチレンテレンテレフタレート樹脂(PET)、ポリブチレンテレフタレート(PBT)、四フッ化エチレン樹脂(PTFE)、弾性樹脂としてはアクリル樹脂やシリコーン樹脂、フッ素樹脂、塩化ビニル、ウレタン樹脂、ポリウレタン樹脂、ポリエチレン樹脂、エラストマーゲル、ポリエチレンゲル、ウレタンゴム、エチレンアクリルゴム、エピクロルヒドリンゴム、アクリルゴム、エチレンプロピレンゴム、クロロプレンゴム、天然ゴム、イソプレンゴム、塩素化ポリエチレン、ニトリルゴム、スチレン系エラストマー、オレフィン系エラストマー、エステル系エラストマー、ウレタン系エラストマーなどが挙げられ、樹脂及び/または弾性樹脂にレーザー光に対して十分な吸収性を示すカーボンブラック、染料や顔料等の所定の着色材を混入したものを挙げることができる。また、レーザー光に対して、十分な吸収性を示すものであれば、有機系着色材を用いてもよい。このような着色材として、たとえば、銅フタロジアニン系顔料等をあげることができる。   The type of resin and / or elastic resin used for the non-transparent resin material is not particularly limited as long as it can absorb laser light as a heating source without transmitting it. As the resin, polyvinyl chloride (PVC), polyvinylidene chloride (PVDC), polyethylene resin (PE), polypropylene resin (PP), polystyrene resin (PS), acrylonitrile styrene resin (AS), acrylonitrile styrene butadiene resin (ABS), Methacrylic resin (PMMA), polyacetal resin (POM), polyamide resin (PA) such as nylon 6 resin (PA6) and nylon 66 resin (PA66), polycarbonate resin (PC), polyethylene terephthalate resin (PET), polybutylene terephthalate (PBT), ethylene tetrafluoride resin (PTFE), elastic resins include acrylic resin, silicone resin, fluorine resin, vinyl chloride, urethane resin, polyurethane resin, polyethylene resin, elastomer gel, Reethylene gel, urethane rubber, ethylene acrylic rubber, epichlorohydrin rubber, acrylic rubber, ethylene propylene rubber, chloroprene rubber, natural rubber, isoprene rubber, chlorinated polyethylene, nitrile rubber, styrene elastomer, olefin elastomer, ester elastomer, urethane Examples thereof include elastomers, and examples thereof include those in which a predetermined colorant such as carbon black, dye, pigment, or the like, which has sufficient absorbability for laser light, is mixed in a resin and / or elastic resin. In addition, an organic coloring material may be used as long as it exhibits sufficient absorbability with respect to laser light. Examples of such a coloring material include copper phthalodianine pigments.

上記透過性樹脂材に用いる樹脂と上記非透過性樹脂材に用いる樹脂との組合せについては、互いに相溶性のあるもの同士の組合せとされる。同種の樹脂同士の組合せの他、ナイロン6とナイロン66との組合せ、PETとPCとの組合せやPCとPBTとの組合せ、また、スチレン系エラストマーとポリプロピレン樹脂(PP)との組合せの様な樹脂と弾性樹脂の組合せ、オレフィン系エラストマーとウレタンゴムとの組合せの様な弾性樹脂同士の組合せが挙げられるが、相溶性のある樹脂同士の組合せであればよく特に限定されない。   The combination of the resin used for the permeable resin material and the resin used for the non-permeable resin material is a combination of those compatible with each other. Resins such as combinations of nylon 6 and nylon 66, combinations of PET and PC, combinations of PC and PBT, and combinations of styrene elastomer and polypropylene resin (PP) in addition to combinations of resins of the same type And a combination of elastic resins, and a combination of elastic resins such as a combination of an olefin elastomer and urethane rubber, but any combination of compatible resins may be used.

加熱源として用いるレーザー光の種類としては、レーザ光を透過させる透過性樹脂材の吸収スペクトルや板厚(透過長)等との関係で、透過性樹脂材内での透過率が所定値以上となるような波長を有するものが適宜選定される。例えば、YAG:Nd3+レーザ(レーザ光の波長:1060nm)や半導体レーザ(レーザ光の波長:500〜1000nm)を用いることができる。なお、レーザーの出力、照射密度や加工速度(移動速度)等の照射条件は、樹脂の種類、透過性樹脂材の吸収能力等に応じて適宜設定可能である。レーザー光の出力が低いと樹脂材料の接合面を互いに溶融させることが困難となり、出力が高いと樹脂材料が蒸発したり、変質し強度が低下する問題が生じるようになる。 The type of laser light used as a heating source is such that the transmittance in the transparent resin material is a predetermined value or more in relation to the absorption spectrum or plate thickness (transmission length) of the transparent resin material that transmits the laser light. Those having such wavelengths are appropriately selected. For example, a YAG: Nd 3+ laser (laser light wavelength: 1060 nm) or a semiconductor laser (laser light wavelength: 500 to 1000 nm) can be used. Irradiation conditions such as laser output, irradiation density and processing speed (moving speed) can be set as appropriate according to the type of resin, the absorption capacity of the permeable resin material, and the like. If the output of the laser beam is low, it becomes difficult to melt the joint surfaces of the resin materials, and if the output is high, the resin material evaporates or changes in quality and the strength is lowered.

微細な固体4は軸体と把持部との間及び/または把持部に設けられた空間に配されている。微細な固体4の具体的な例としては、ステンレス、洋白、ジルコニア、ルビーボール等の硬球、ダイヤモンド、ルビー、サファイヤ、めのう、水晶等の鉱石、御影石、大理石等の岩石、ポリエチレン、ポリエチレンテレフタラート、塩化ビニル、ABS、AS、PMMA、ポリプロピレン、ポリカーボネート等の樹脂やその発泡体、アクリル樹脂、シリコーン樹脂、フッ素樹脂、ウレタン樹脂、ポリウレタン樹脂、ジメチル系シリコーン、メチルビニル系シリコーン、メチルフェニルビニル系シリコーン、メチルフルオロアルキル系シリコーン(フロロシリコーン)、フロロ−ジメチル共重合シリコーン、ウレタンゴム、エチレンアクリルゴム、エピクロルヒドリンゴム、アクリルゴム、エチレンプロピレンゴム、クロロプレンゴム、天然ゴム、イソプレンゴム、塩素化ポリエチレン、ニトリルゴム、スチレン系エラストマー、オレフィン系エラストマー、エステル系エラストマー、ウレタン系エラストマー等の弾性樹脂、ナイロン、絹、綿等の繊維、ガラスなどが挙げられるが、微細な固体が形成できればよく特に限定はされない。また、これらの微細な固体は1種または2種以上の混合物であってもよい。   The fine solid 4 is disposed between the shaft body and the grip portion and / or in a space provided in the grip portion. Specific examples of the fine solid 4 include hard balls such as stainless steel, white and white, zirconia and ruby balls, ores such as diamond, ruby, sapphire, agate and quartz, rocks such as granite and marble, polyethylene, polyethylene terephthalate , Vinyl chloride, ABS, AS, PMMA, polypropylene, polycarbonate and other resins and their foams, acrylic resin, silicone resin, fluororesin, urethane resin, polyurethane resin, dimethyl silicone, methyl vinyl silicone, methyl phenyl vinyl silicone , Methyl fluoroalkyl silicone (fluorosilicone), fluoro-dimethyl copolymer silicone, urethane rubber, ethylene acrylic rubber, epichlorohydrin rubber, acrylic rubber, ethylene propylene rubber, chloroprene rubber, natural rubber , Isoprene rubber, chlorinated polyethylene, nitrile rubber, styrene elastomer, olefin elastomer, ester elastomer, urethane elastomer and other elastic resins, nylon, silk, cotton and other fibers, glass, etc. There is no particular limitation as long as it can be formed. These fine solids may be one kind or a mixture of two or more kinds.

微細な固体4の形状は粒子状、繊維状、不定形状等様々な形状の固体が利用できる。硬球などの真球に近い形状の微細な固体を配した場合には、把持した際の変形が速く、また、放した時の形状復元も速い。岩石やガラスを粉砕した不定形の微細な固体を配した場合には、把持した際の変形は遅いが腰がある把持感があり、また、放した時にも形状をある程度記憶している。微細な固体の大きさは空間の大きさによって異なるが、空間の最小の幅より小さければよく、特に限定されない。また、これらの微細な固体の大きさは1種または2種以上の混合物であってもよい。   As the shape of the fine solid 4, various shapes of solid such as particles, fibers, and irregular shapes can be used. When a fine solid having a shape close to a true sphere, such as a hard sphere, is arranged, the deformation is fast when gripped, and the shape is restored quickly when released. When an irregularly shaped fine solid obtained by pulverizing rocks or glass is arranged, the gripping is slow, but there is a feeling of gripping, and the shape is remembered to some extent when released. The size of the fine solid varies depending on the size of the space, but is not particularly limited as long as it is smaller than the minimum width of the space. Further, the size of these fine solids may be one kind or a mixture of two or more kinds.

軸体と把持部との間及び/または把持部内部に設けられた空間には微細な固体4の他に、微細な固体の流動性、形状保持性を補助するために弾性樹脂やゲル状物質や粘稠物などの補助材5を配してもよい。粘稠物としては、KF96(信越化学工業(株)製)といったシリコーンオイルやtsk5370(Ge東芝シリコーン(株)製)といったシリコーンオイルコンパウンド、レチナックス グリース CL(昭和シェル石油(株)製)といった石油系グリースがあげられる。ゲル状物質としてはKE−1052、sifel827(信越化学工業(株)製)、アルファゲル((株)ジェルテック製)、SilGel612(旭化成ワッカーシリコーン(株)製)といったシリコーンゲル、人肌のゲル((株)エクシールコーポレーション製)といったウレタンゲルなどが挙げられる。   In addition to the fine solid 4 in the space provided between the shaft body and the grip part and / or inside the grip part, an elastic resin or gel-like substance is used to assist the fluidity and shape retention of the fine solid. Auxiliary material 5 such as or a viscous material may be provided. Examples of viscous materials include silicone oils such as KF96 (manufactured by Shin-Etsu Chemical Co., Ltd.), silicone oil compounds such as tsk5370 (manufactured by Ge Toshiba Silicone), and petroleum-based oils such as Retinax Grease CL (manufactured by Showa Shell Sekiyu KK). Grease. As gel-like substances, silicone gels such as KE-1052, sifel 827 (manufactured by Shin-Etsu Chemical Co., Ltd.), alpha gel (manufactured by Geltech Co., Ltd.), SilGel612 (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.), human skin gel ( Urethane gels such as those manufactured by Exeal Corporation are available.

本発明は、2つ以上の軸筒の一方を他方に挿入し当接して形成される軸体において、軸筒の少なくとも一つはレーザー光に対して透過性のない非透過性樹脂を材料とし、それに当接する軸筒の少なくとも一つはレーザー光に対して透過性のある透過性樹脂を材料とし、軸筒同士の当接部をレーザー光の照射によって溶着し、接合したことで強固な接合を実現している。従来プライマーを使用する必要があり強固な接合が困難であった弾性樹脂の場合でも、両樹脂が溶融して互いに入り込み絡まった状態が形成されるため、強固な接合状態を構成し、高い接合強度及び耐圧強度を有している。特に把持部として使用されることが多い弾性時樹脂は汗による膨潤によるゆるみが発生する問題があったが、両樹脂が溶融して強固な溶着が実現されるため、解消される。また、溶着によって密閉構造を作り出すことが出来るので、非透過性樹脂及び/または透過性樹脂の間に設けた空間に微細な固体及び/または粘稠物を配しても漏れ出すことがない封入が可能である。   According to the present invention, in a shaft body formed by inserting and abutting one of two or more shaft cylinders into the other, at least one of the shaft cylinders is made of a non-transparent resin that is not transparent to laser light. In addition, at least one of the shaft cylinders that abut on it is made of a transparent resin that is transmissive to laser light, and the abutting portions of the shaft cylinders are welded and bonded together by laser light irradiation, thereby providing strong bonding Is realized. Even in the case of an elastic resin that has conventionally required the use of a primer and difficult to join firmly, both resins melt and enter each other to form an entangled state. And withstand pressure strength. In particular, the elastic resin often used as a gripping part has a problem of loosening due to swelling due to sweat. However, since both resins are melted to realize a strong welding, the problem is solved. In addition, since a sealed structure can be created by welding, the enclosure does not leak even if a fine solid and / or viscous material is placed in the space provided between the impermeable resin and / or the permeable resin. Is possible.

本発明は、レーザー光に対して透過性のない非透過性樹脂で成形した軸筒と、レーザー光に対して透過性のある透過性樹脂で成形した軸筒同士の当接部をレーザー光の照射によって溶着することを最も主要な特徴とする。これまで使用に耐える強度や高い耐久性が得られなかった弾性樹脂の溶着を可能にした。更に強固な溶着を用いた密閉構造を創意工夫することよって、これまでにない触感の軸体を実現した。   In the present invention, a contact portion between a shaft tube formed of a non-transparent resin that is not transmissive to laser light and a shaft tube formed of a transmissive resin that is transmissive to laser light is used for the laser light. The main feature is welding by irradiation. We have made it possible to weld elastic resin, which has not been able to obtain strength and durability that can withstand use. Furthermore, a shaft body with an unprecedented tactile sensation has been realized by creatively inventing a sealed structure using strong welding.

実施例1
図1は、本発明を筆記具の軸体に使用した実施例1の部品図である。図2は図1のa−A’線断面図である。また、参照符号1は軸筒1、参照符号2は軸筒2、参照符号3は溶着部である。
Example 1
FIG. 1 is a component diagram of Example 1 in which the present invention is used for a shaft of a writing instrument. 2 is a cross-sectional view taken along the line AA ′ of FIG. Reference numeral 1 is a shaft cylinder 1, reference numeral 2 is a shaft cylinder 2, and reference numeral 3 is a welded portion.

レーザー光に対して透過性のあるエラストマー(アクティマーAE−2040S、リケンテクノス(株)製、ショアーA硬度:40°)を用いて射出成形した軸筒1に、レーザー吸収材料としてカーボンブラックを0.5重量%配合したポリエチレンを用いて射出成形した軸筒2を挿入した。軸筒2の両端を固定し、径方向に回転する装置に取り付け、回転させながら溶着部3の部分に半導体レーザー装置(波長940nm、出力40W)でレーザー光を一周照射し、軸筒1と軸筒2を溶着部3全周で溶着した。軸筒1と軸筒2は完全に溶融して外れることはなく、汗等で膨潤してもゆるみは発生しなかった。   Carbon black as a laser-absorbing material is added to the shaft cylinder 1 injection molded using an elastomer (actimer AE-2040S, manufactured by Riken Technos Co., Ltd., Shore A hardness: 40 °) that is transmissive to laser light. A shaft cylinder 2 injection-molded using 5% by weight of polyethylene was inserted. Both ends of the shaft tube 2 are fixed and attached to a device that rotates in the radial direction. While rotating, the laser beam is irradiated around the welded portion 3 with a semiconductor laser device (wavelength 940 nm, output 40 W). The cylinder 2 was welded around the entire circumference of the welded part 3. The shaft tube 1 and the shaft tube 2 were not completely melted and detached, and no loosening occurred even when swollen with sweat or the like.

実施例2
図3は、本発明を筆記具の軸体に使用した実施例2の部品図である。図4は図3のa−A’線断面図である。また、参照符号1は軸筒1、参照符号2は軸筒2、参照符号3は溶着部、参照符号4は微細な固体、参照符号5は補助材である。軸筒1と軸筒2の間には空間部があり、軸筒1と軸筒2の当接部二箇所を全周溶着し溶着部3とすることによって空間7は封止され、その空間7の内部に微細な固体4、補助材5が封入されている。
Example 2
FIG. 3 is a component diagram of Example 2 in which the present invention is used for a writing instrument shaft. 4 is a cross-sectional view taken along line aA ′ of FIG. Reference numeral 1 is a shaft cylinder 1, reference numeral 2 is a shaft cylinder 2, reference numeral 3 is a welded portion, reference numeral 4 is a fine solid, and reference numeral 5 is an auxiliary material. There is a space between the shaft tube 1 and the shaft tube 2, and the space 7 is sealed by welding the two contact portions of the shaft tube 1 and the shaft tube 2 all around to form the welded portion 3. 7 is filled with a fine solid 4 and an auxiliary material 5.

レーザー光に対して透過性のあるエラストマー(ラバロンMJ5302C、三菱化学(株)製、ショアーA硬度:50度)を用いて射出成形した軸筒1に、レーザー吸収材料(LAW−1800、オリヱント化学工業(株)製)を混合したポリプロピレンを用いて射出成形した軸筒2を挿入した。軸筒1と軸筒2の間に形成される空間に微細な固体4としてガラスビーズ(ユニビーズUB−1921LN、(株)ユニオン製)を配し、隙間にシリコーンゲル(KE−1052、信越化学工業(株)製)を充填した。軸筒2の両端を固定し、径方向に回転する装置に取り付け、回転させながら半導体レーザー装置(波長940nm、出力40W)でレーザー光を照射し軸筒1と軸筒2を2箇所で溶着した。軸筒1と軸筒2は完全に溶融して外れることはなく、汗等で膨潤してもゆるみは発生しなかった。また、空間に配されたガラスビーズやシリコーンゲルは溶着によって封入されているため外部に漏れ出すことはない。ガラスビーズは握った時の圧力で適度に位置を変え、その移動はシリコーンゲルによってより柔らかな変化となる。このため把持部2は握った指の形状に変形し、持ちやすさ、滑りにくさといった効果を発揮する。内部のガラスビーズそのものは硬くシリコーンゲルによる弾力があるため、しっかり握った際にも変形しすぎず、腰のある良好な感触が得られる。   A laser-absorbing material (LAW-1800, Orient Chemical Industry Co., Ltd.) is injected into the shaft cylinder 1 which is injection-molded using an elastomer (Lavalon MJ5302C, manufactured by Mitsubishi Chemical Corporation, Shore A hardness: 50 degrees). A shaft cylinder 2 injection-molded using polypropylene mixed with (made by Co., Ltd.) was inserted. Glass beads (Unibeads UB-1921LN, manufactured by Union Co., Ltd.) are arranged as a fine solid 4 in the space formed between the shaft tube 1 and the shaft tube 2, and silicone gel (KE-1052, Shin-Etsu Chemical Co., Ltd.) is placed in the gap. Product). Both ends of the shaft tube 2 are fixed, attached to a device rotating in the radial direction, and irradiated with laser light with a semiconductor laser device (wavelength 940 nm, output 40 W) while rotating, the shaft tube 1 and the shaft tube 2 are welded at two locations. . The shaft tube 1 and the shaft tube 2 were not completely melted and detached, and no loosening occurred even when swollen with sweat or the like. Further, since glass beads and silicone gel arranged in the space are sealed by welding, they do not leak to the outside. The glass beads change their position appropriately according to the pressure when grasped, and the movement is made softer by the silicone gel. For this reason, the grasping part 2 is deformed into the shape of a grasped finger and exhibits effects such as ease of holding and difficulty in sliding. The inner glass beads themselves are hard and elastic due to the silicone gel, so that they do not deform too much when grasped firmly, and a good feeling with a waist is obtained.

実施例3
図5は、本発明を筆記具の軸体に使用した実施例3の部品図である。図6は図5のa−A’線断面図である。また、参照符号1は軸筒1、参照符号2は軸筒2、参照符号3は溶着部、参照符号4は微細な固体、参照符号5は補助材、参照符号6は軸筒3、参照符号7は空間である。軸筒1は袋状に成形され、フタの役割を担う軸筒2との当接部を全周溶着し溶着部3とすることによって封止された空間7が形成され、その空間7の内部に微細な固体4、補助材5が封入されている。
Example 3
FIG. 5 is a component diagram of Example 3 in which the present invention is used for a shaft of a writing instrument. 6 is a cross-sectional view taken along line AA ′ of FIG. Reference numeral 1 is a shaft cylinder 1, reference numeral 2 is a shaft cylinder 2, reference numeral 3 is a welded portion, reference numeral 4 is a fine solid, reference numeral 5 is an auxiliary material, reference numeral 6 is a shaft cylinder 3, and reference numeral. 7 is a space. The shaft tube 1 is formed in a bag shape, and a sealed space 7 is formed by welding the contact portion with the shaft tube 2 serving as a lid all around to form a weld portion 3. A fine solid 4 and an auxiliary material 5 are enclosed.

ポリプロピレンを用いて射出成形した軸筒3にレーザー光に対して透過性のあるエラストマー(ラバロンMJ6302C、三菱化学(株)製、ショアーA硬度:60度)を用いて袋状の軸筒1を2色成形した。軸筒1に形成される空間に微細な固体4としてガラスビーズ(ユニビーズUB−1921LN、(株)ユニオン製)を配し、隙間にシリコーンゲル(KE−1052、信越化学工業(株)製)を充填した。レーザー吸収材料(LAW−1800、オリヱント化学工業(株)製)を混合したポリプロピレンを用いて射出成形した軸筒2を軸筒1と軸筒3の間に挿入した。軸筒2と軸筒3は凹凸によって嵌合されている。軸筒3の両端を固定し、径方向に回転する装置に取り付け、回転させながら半導体レーザー装置(波長940nm、出力40W)でレーザー光を照射し軸筒1と軸筒2を溶着した。軸筒1と軸筒2は完全に溶融して外れることはなく、汗等で膨潤してもゆるみは発生しなかった。また、空間に配されたガラスビーズやシリコーンゲルは溶着によって封入されているため外部に漏れ出すことはない。ガラスビーズは握った時の圧力で適度に位置を変え、その移動はシリコーンゲルによってより柔らかな変化となる。このため把持部2は握った指の形状に変形し、持ちやすさ、滑りにくさといった効果を発揮する。内部のガラスビーズそのものは硬くシリコーンゲルによる弾力があるため、しっかり握った際にも変形しすぎず、腰のある良好な感触が得られる。   A bag-shaped shaft tube 1 is formed by using an elastomer (Lavalon MJ6302C, manufactured by Mitsubishi Chemical Co., Ltd., Shore A hardness: 60 degrees) that is transparent to laser light on a shaft tube 3 that is injection-molded using polypropylene. Color molded. Glass beads (Unibeads UB-1921LN, manufactured by Union Co., Ltd.) are arranged as fine solids 4 in the space formed in the shaft tube 1, and silicone gel (KE-1052, manufactured by Shin-Etsu Chemical Co., Ltd.) is placed in the gap. Filled. A shaft cylinder 2 injection-molded using polypropylene mixed with a laser absorbing material (LAW-1800, manufactured by Orient Chemical Industry Co., Ltd.) was inserted between the shaft cylinder 1 and the shaft cylinder 3. The shaft tube 2 and the shaft tube 3 are fitted by unevenness. Both ends of the shaft tube 3 were fixed, attached to a device rotating in the radial direction, and irradiated with laser light with a semiconductor laser device (wavelength 940 nm, output 40 W) while rotating, the shaft tube 1 and the shaft tube 2 were welded. The shaft tube 1 and the shaft tube 2 were not completely melted and detached, and no loosening occurred even when swollen with sweat or the like. Further, since glass beads and silicone gel arranged in the space are sealed by welding, they do not leak to the outside. The glass beads change their position appropriately according to the pressure when grasped, and the movement is made softer by the silicone gel. For this reason, the grasping part 2 is deformed into the shape of a grasped finger and exhibits effects such as ease of holding and difficulty in sliding. The inner glass beads themselves are hard and elastic due to the silicone gel, so that they do not deform too much when grasped firmly, and a good feeling with a waist is obtained.

実施例4
図8は、本発明を筆記具の軸体に使用した実施例4の部品図である。図9は図8のa−A’線断面図である。また、参照符号1は軸筒1、参照符号2は軸筒2、参照符号3は溶着部、参照符号4は微細な固体、参照符号5は補助材、参照符号6は軸筒3、参照符号7は空間、参照符号8は軸筒2に設けられた貫通孔である。軸筒1は袋状に成形され、フタの役割を担う軸筒2との当接部を全周溶着し溶着部3とすることによって形成された空間7に微細な固体4、並びに、補助材5が配されている。
Example 4
FIG. 8 is a component diagram of Example 4 in which the present invention is used for a writing instrument shaft. 9 is a cross-sectional view taken along the line AA ′ of FIG. Reference numeral 1 is a shaft cylinder 1, reference numeral 2 is a shaft cylinder 2, reference numeral 3 is a welded portion, reference numeral 4 is a fine solid, reference numeral 5 is an auxiliary material, reference numeral 6 is a shaft cylinder 3, and reference numeral. Reference numeral 7 denotes a space, and reference numeral 8 denotes a through hole provided in the shaft cylinder 2. The shaft cylinder 1 is formed into a bag shape, and a fine solid 4 and an auxiliary material are formed in a space 7 formed by welding the contact portion with the shaft cylinder 2 serving as a lid all around to form a weld portion 3. 5 is arranged.

ポリプロピレンを用いて射出成形した軸筒3にレーザー光に対して透過性のあるエラストマー(ラバロンMJ6302C、三菱化学(株)製、ショアーA硬度:60度)を用いて袋状の軸筒1を2色成形した。軸筒1に形成される空間7に微細な固体4としてガラスビーズ(ユニビーズUB−1921LN、(株)ユニオン製)を配した。レーザー吸収材料(LAW−1800、オリヱント化学工業(株)製)を混合したポリプロピレンを用いて射出成形した軸筒2を軸筒1と軸筒3の間に挿入した。軸筒2と軸筒3は凹凸によって嵌合されている。軸筒3の両端を固定し、径方向に回転する装置に取り付け、回転させながら半導体レーザー装置(波長940nm、出力40W)でレーザー光を照射し軸筒1と軸筒2を溶着した。微細な固体4が配された空間7の隙間にシリコーンゲル(SilGel612(旭化成ワッカーシリコーン(株)製)を貫通孔8を通じて外部より充填した。軸筒1と軸筒2は完全に溶融して外れることはなく、汗等で膨潤してもゆるみは発生しなかった。また、空間7に配されたガラスビーズやシリコーンゲルは軸筒1と軸筒2が溶着されているため外部に漏れ出すことはない。貫通孔8はガラスビーズより小さいため、空間内のガラスビーズが外部に出てくることはない。シリコーンゲルは圧力によって変形するがその変形量に限界があり、また、圧力がかかっても狭い貫通孔8から漏れ出すより空間7の内部で移動する方が変形しやすいため、外に漏れ出すことはない。更に、圧力によって移動したガラスビーズが貫通孔8を塞いでしまうのでシリコーンゲルは外部に漏れ出す前に止まっている。ガラスビーズは握った時の圧力で適度に位置を変え、その移動はシリコーンゲルによってより柔らかな変化となる。このため把持部2は握った指の形状に変形し、持ちやすさ、滑りにくさといった効果を発揮する。内部のガラスビーズそのものは硬くシリコーンゲルによる弾力があるため、しっかり握った際にも変形しすぎず、腰のある良好な感触が得られる。   A bag-shaped shaft tube 1 is formed by using an elastomer (Lavalon MJ6302C, manufactured by Mitsubishi Chemical Co., Ltd., Shore A hardness: 60 degrees) that is transparent to laser light on a shaft tube 3 that is injection-molded using polypropylene. Color molded. Glass beads (Unibeads UB-1921LN, manufactured by Union Co., Ltd.) were arranged as fine solids 4 in the space 7 formed in the shaft tube 1. A shaft cylinder 2 injection-molded using polypropylene mixed with a laser absorbing material (LAW-1800, manufactured by Orient Chemical Industry Co., Ltd.) was inserted between the shaft cylinder 1 and the shaft cylinder 3. The shaft tube 2 and the shaft tube 3 are fitted by unevenness. Both ends of the shaft tube 3 were fixed, attached to a device rotating in the radial direction, and irradiated with laser light with a semiconductor laser device (wavelength 940 nm, output 40 W) while rotating, the shaft tube 1 and the shaft tube 2 were welded. Silicone gel (SilGel612 (manufactured by Asahi Kasei Wacker Silicone Co., Ltd.)) was filled from the outside through the through-hole 8 in the space 7 in which the fine solid 4 was disposed. No loosening occurred even when swollen with sweat, etc. Further, the glass beads and silicone gel arranged in the space 7 leaked to the outside because the shaft tube 1 and the shaft tube 2 are welded. Since the through-hole 8 is smaller than the glass bead, the glass bead in the space does not come out to the outside.The silicone gel is deformed by pressure, but the deformation amount is limited, and the pressure is applied. However, the glass beads that have moved due to pressure do not block the through-holes 8 because they move more easily inside the space 7 than the leaks from the narrow through-holes 8. Therefore, the silicone gel is stopped before it leaks to the outside, and the glass beads change their position appropriately according to the pressure when grasped, and the movement is softened by the silicone gel. It is deformed into the shape of a finger and is easy to hold and difficult to slide.The inner glass beads themselves are hard and elastic with silicone gel, so they do not deform too much when gripped firmly and have a waist A good feel is obtained.

比較例1
実施例1の軸筒1の固定を接着剤を用いて行った。しかし、軸筒1のエラストマーは材料内に油分を含む弾性樹脂で難接着物であり、汗等で膨潤すると接着した箇所がはく離し、ゆるんでしまった。
Comparative Example 1
The shaft cylinder 1 of Example 1 was fixed using an adhesive. However, the elastomer of the shaft cylinder 1 is an elastic resin containing an oil component in the material and is a difficult-to-adhere substance. When swollen with sweat or the like, the adhered portion is peeled off and loosened.

比較例2
実施例2の溶着を熱溶着機を用いて行った。熱溶着は材料を通して熱エネルギーを伝え界面を溶着する方法である。しかし、軸筒1に熱の発生源を当接して熱を伝えるため、溶着するまでに軸筒1の表面が熱で溶解し、外観が汚れてしまった。
Comparative Example 2
The welding in Example 2 was performed using a heat welding machine. Thermal welding is a method of transferring thermal energy through a material and welding the interface. However, since the heat generation source is brought into contact with the shaft tube 1 to transmit heat, the surface of the shaft tube 1 is melted by heat until it is welded, and the appearance is soiled.

比較例3
実施例3の溶着を超音波溶着機を用いて行った。超音波溶着は材料を通して振動を伝え界面を溶着する方法である。しかし、軸筒1のエラストマーは弾性材料であり振動が減衰してしまうため溶着が不完全になり、使用中に外れてしまった。
Comparative Example 3
The welding of Example 3 was performed using an ultrasonic welding machine. Ultrasonic welding is a method in which vibration is transmitted through a material and the interface is welded. However, since the elastomer of the shaft tube 1 is an elastic material and the vibration is attenuated, the welding is incomplete, and it is detached during use.

本発明は、2つ以上の軸筒で一方を他方に挿入し当接して形成される軸体に関するものである。その軸体の例としては、シャープペンシルやボールペン、修正ペンなどの筆記具、カッターや彫刻刀、ドライバーなどの工具類、PDA(パーソナル デジタル アシスタンス)や電子手帳に使用される入力ペン、自転車のハンドルなど多岐にわたる。   The present invention relates to a shaft body formed by inserting and abutting one of two or more shaft cylinders into the other. Examples of shafts include writing instruments such as mechanical pencils, ballpoint pens, correction pens, tools such as cutters and engraving swords, drivers, input pens used in PDAs (personal digital assistance) and electronic notebooks, bicycle handles, etc. Wide range.

本発明を筆記具の軸体に使用した実施例1の部品図である。It is component drawing of Example 1 which used this invention for the shaft of a writing instrument. 図1のa−A’線断面図である。It is the a-A 'line sectional view of Drawing 1. 本発明を筆記具の軸体に使用した実施例2の部品図である。It is component drawing of Example 2 which used this invention for the shaft of a writing instrument. 図3のa−A’線断面図である。FIG. 4 is a sectional view taken along line a-A ′ of FIG. 3. 本発明を筆記具の軸体に使用した実施例3の部品図である。It is component drawing of Example 3 which used this invention for the shaft of a writing instrument. 図5のa−A’線断面図である。FIG. 6 is a sectional view taken along line a-A ′ of FIG. 5. 図5の要部拡大図である。It is a principal part enlarged view of FIG. 本発明を筆記具の軸体に使用した実施例4の部品図である。It is component drawing of Example 4 which used this invention for the shaft of a writing instrument. 図8のa−A’線断面図である。FIG. 9 is a sectional view taken along line a-A ′ of FIG. 8. 図8の要部拡大図である。It is a principal part enlarged view of FIG.

符号の説明Explanation of symbols

1 軸筒
2 軸筒
3 溶着部
4 微細な固体
5 補助材
6 軸筒
7 空間
8 貫通孔
DESCRIPTION OF SYMBOLS 1 Shaft cylinder 2 Shaft cylinder 3 Welding part 4 Fine solid 5 Auxiliary material 6 Shaft cylinder 7 Space 8 Through-hole

Claims (7)

2つ以上の軸筒で一方を他方に挿入し当接して形成される軸体において、軸筒の少なくとも一つはレーザー光に対して透過性のない非透過性樹脂を材料とし、それに当接する軸筒の少なくとも一つはレーザー光に対して透過性のある透過性樹脂を材料とし、軸筒同士の当接部をレーザー光の照射によって溶着し、接合したことを特徴とする軸体。 In a shaft body formed by inserting and abutting one of the two or more shaft cylinders into the other, at least one of the shaft cylinders is made of a non-transparent resin that is not transmissive to laser light and abuts on the material A shaft body characterized in that at least one of the shaft cylinders is made of a transparent resin that is transmissive to laser light, and abutting portions of the shaft cylinders are welded and joined by laser light irradiation. 前記樹脂の少なくとも一つに弾性樹脂を使用したことを特徴とする請求項1に記載の軸体。 2. The shaft body according to claim 1, wherein an elastic resin is used for at least one of the resins. 前記弾性樹脂を使用した軸筒が把持部であることを特徴とする請求項2に記載の軸体。 The shaft body according to claim 2, wherein the shaft cylinder using the elastic resin is a grip portion. 前記軸筒同士の当接部をレーザー光の照射によって溶着し、接合することで、前記軸筒同士の間及び/または前記軸筒内部に設けられる空間に微細な固体及び/または弾性樹脂及び/または粘稠物を配したことを特徴とする請求項1〜3の何れかに記載の軸体。 By welding and joining the abutting portions of the shaft cylinders by laser light irradiation, a fine solid and / or elastic resin and / or a space provided between the shaft cylinders and / or in the space inside the shaft cylinder, and / or Or the viscous body was arranged, The shaft body in any one of Claims 1-3 characterized by the above-mentioned. 前記空間に配する微細な固体が粒子状及び/または繊維状であることを特徴とする請求項1〜4の何れかに記載の軸体。 The shaft according to any one of claims 1 to 4, wherein the fine solid disposed in the space is in the form of particles and / or fibers. 前記空間に配する粘稠物がゲル状物質であることを特徴とする請求項1〜6の何れかに記載の軸体。 The shaft according to any one of claims 1 to 6, wherein the viscous material arranged in the space is a gel material. 請求項1〜6に記載の軸体を使用した筆記具。 A writing instrument using the shaft body according to claim 1.
JP2007250718A 2007-09-27 2007-09-27 Shaft body and writing instrument using the shaft body Expired - Fee Related JP5364987B2 (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010274542A (en) * 2009-05-29 2010-12-09 Pentel Corp Shaft body and mechanical pencil using the same
JP2011240609A (en) * 2010-05-19 2011-12-01 Mitsubishi Pencil Co Ltd Writing utensil
JP2012034749A (en) * 2010-08-04 2012-02-23 Tokiwa Corp Cosmetic applicator
JP2013166383A (en) * 2013-04-26 2013-08-29 Mitsubishi Pencil Co Ltd Method of assembling writing utensil

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07299984A (en) * 1994-04-28 1995-11-14 Mitsubishi Pencil Co Ltd Writing implement
JP2002507509A (en) * 1998-03-26 2002-03-12 ビック コーポレイション Writing instrument with finger grip device
JP2004291612A (en) * 2003-02-05 2004-10-21 Mitsubishi Pencil Co Ltd Grip structure of writing instrument or coating implement, and writing instrument or coating implement equipped with the grip structure
JP2005199594A (en) * 2004-01-16 2005-07-28 Pentel Corp Barrel body
JP2005305906A (en) * 2004-04-23 2005-11-04 Denso Corp Laser welding method for resin materials

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07299984A (en) * 1994-04-28 1995-11-14 Mitsubishi Pencil Co Ltd Writing implement
JP2002507509A (en) * 1998-03-26 2002-03-12 ビック コーポレイション Writing instrument with finger grip device
JP2004291612A (en) * 2003-02-05 2004-10-21 Mitsubishi Pencil Co Ltd Grip structure of writing instrument or coating implement, and writing instrument or coating implement equipped with the grip structure
JP2005199594A (en) * 2004-01-16 2005-07-28 Pentel Corp Barrel body
JP2005305906A (en) * 2004-04-23 2005-11-04 Denso Corp Laser welding method for resin materials

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2010274542A (en) * 2009-05-29 2010-12-09 Pentel Corp Shaft body and mechanical pencil using the same
JP2011240609A (en) * 2010-05-19 2011-12-01 Mitsubishi Pencil Co Ltd Writing utensil
JP2012034749A (en) * 2010-08-04 2012-02-23 Tokiwa Corp Cosmetic applicator
JP2013166383A (en) * 2013-04-26 2013-08-29 Mitsubishi Pencil Co Ltd Method of assembling writing utensil

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