JP2009061680A - Reinforced floor material and method of manufacturing the same - Google Patents

Reinforced floor material and method of manufacturing the same Download PDF

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JP2009061680A
JP2009061680A JP2007231649A JP2007231649A JP2009061680A JP 2009061680 A JP2009061680 A JP 2009061680A JP 2007231649 A JP2007231649 A JP 2007231649A JP 2007231649 A JP2007231649 A JP 2007231649A JP 2009061680 A JP2009061680 A JP 2009061680A
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moisture
thermosetting resin
proof sheet
sheet
resin adhesive
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Masaki Fukui
雅基 福井
Morihei Yasui
森平 安井
Terukazu Inoue
輝一 井上
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Daiken Trade and Industry Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a reinforced floor material having superior damp-proofing property and crack resistance and hardly causing inside delamination due to the load of casters or the like. <P>SOLUTION: The reinforced floor material is formed by laminating a damp-proofing sheet like material 2 on the surface of a woody fiber board 1a forming a surface layer part of a woody base material 1 to adhere through a thermosetting resin adhesive 4b and further integrally laminating a decorative veneer 3 on the damp-proofing sheet like material 2 to adhere through a thermosetting resin adhesive 4a having elasticity and thereby, the occurrence of delamination between papers or inside the decorative veneer 3 is prevented even when the load due to the casters of wagons or the like is applied on the floor material. The damp-proofing sheet like material 2 has a three layer structure formed by integrally providing a thermosetting resin sheet 2c having heat resistant and damp-proofing property as a core layer and thermosetting resin-impregnated hardened paper layers 2a formed on the front and back surfaces of the core layer. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、防湿性及び耐傷性に優れた強化床材とその製造方法に関するものである。   The present invention relates to a reinforced flooring material excellent in moisture resistance and scratch resistance and a method for producing the same.

従来から、床材や化粧板等に防湿性を付与するには、例えば、特許文献1に記載されているように、ポリエチレン等の防湿性を有する熱可塑性樹脂フィルムの表裏面に紙を重ね合わせてこの熱可塑性樹脂フィルムの熱融着により一体化してなるポリサンド紙と称される防湿シートを使用し、この防湿シートを介して木質基材の表面に化粧単板を積層、接着することが行われている。   Conventionally, in order to impart moisture resistance to a flooring material or a decorative board, for example, as described in Patent Document 1, paper is superimposed on the front and back surfaces of a moisture-proof thermoplastic resin film such as polyethylene. Using a moisture-proof sheet called poly-sand paper that is integrated by thermal fusion of the thermoplastic resin film, a decorative veneer is laminated and bonded to the surface of the wooden substrate via this moisture-proof sheet. It has been broken.

また、特許文献2には、パーティクルボードや合板等の基材の表面に熱硬化性樹脂含浸紙の積層体を一体に接着してなる化粧板において、上記熱硬化性樹脂含浸紙の積層体の任意の層間に水蒸気透過度の低い樹脂フィルムを介在させることにより、防湿機能を発揮させるように構成した防湿性積層体が記載されている。   Further, in Patent Document 2, in a decorative board in which a laminate of thermosetting resin-impregnated paper is integrally bonded to the surface of a substrate such as particle board or plywood, the laminate of the thermosetting resin-impregnated paper is described. A moisture-proof laminate is described that is configured to exert a moisture-proof function by interposing a resin film having a low water vapor permeability between arbitrary layers.

特開平10−211674号公報Japanese Patent Application Laid-Open No. 10-2111674 特開昭61−160248号公報JP-A 61-160248

しかしながら、上記特許文献1に記載の床材や化粧板によれば、木質基材の表面と化粧単板の裏面とにそれぞれ接着する上記防湿シートの表裏紙の厚さが10〜20μm程度の極めて薄い場合には問題はないが、20μm以上の紙になると、薄葉紙であっても接着剤が浸透していない層が発生し、紙間剥離が生じやすくなるといった問題点がある。特に、床材に耐磨耗性、耐傷性を付与するために木質基材の少なくとも表層部を比重が0.4 〜1.0 の硬質木質繊維板によって形成し、この硬質木質繊維板の表面に上記防湿シートを介して化粧単板を貼着してなる場合において、この床材上でワゴン等のキャスターによる荷重がかかると、接着剤が浸透していない上記層で紙間剥離が発生し、表面の化粧突板が剥離してしまうといった問題点があった。   However, according to the flooring and decorative plate described in Patent Document 1, the thickness of the front and back paper of the moisture-proof sheet that adheres to the surface of the wooden substrate and the back surface of the decorative veneer is about 10 to 20 μm. If it is thin, there is no problem, but if it is 20 μm or more, there is a problem that even if it is thin paper, a layer into which the adhesive does not permeate is generated, and separation between papers is likely to occur. In particular, in order to impart abrasion resistance and scratch resistance to the flooring material, at least the surface layer portion of the wood base material is formed of a hard wood fiber board having a specific gravity of 0.4 to 1.0, and the moisture-proof sheet is formed on the surface of the hard wood fiber board. When a veneer veneer is applied to the flooring material and a load is applied by a caster such as a wagon on the flooring, peeling between papers occurs in the above layer where the adhesive does not penetrate, and the surface makeup is applied. There was a problem that the veneer peeled off.

なお、上記防湿シートの表裏紙間に介在させている熱可塑性樹脂フィルムを溶融させて表裏紙と一体的に熱融着させると防湿性能が低下することになるので、、通常は冷圧貼着されるのが一般的であり、この場合、使用される接着剤中に含まれる水分を飛ばす必要があるため、接着剤の塗布量をできる限り少なくし、また、熱圧プレスを行う場合においても水分によるパンクの発生を防止するために接着剤の塗布量を極力絞るのが一般的であり、従って、上述したように、20μm以上の厚みを有する紙になると、薄葉紙であっても接着剤が浸透していない層が発生することになる。   In addition, since the moisture-proof performance will be reduced if the thermoplastic resin film interposed between the front and back paper of the moisture-proof sheet is melted and heat-sealed integrally with the front and back paper, usually cold pressure sticking In this case, since it is necessary to blow off the moisture contained in the adhesive used, the amount of adhesive applied should be as small as possible, and also when performing hot press In order to prevent the occurrence of puncture due to moisture, it is common to reduce the amount of adhesive applied as much as possible. Therefore, as described above, when the paper has a thickness of 20 μm or more, even if it is thin paper, A non-penetrating layer will occur.

このような問題点をなくするために、防湿シートの表裏紙に紙間強化紙といった紙を使用し、この紙に予め、ラテックスやアクリルエマルジョン等の熱可塑性樹脂を含浸させておくことにより、紙間剥離を防ぐ試みもなされているが、木質基材が比較的柔らかい合板である場合には、この木質基材上に該防湿シートを介して化粧突板を貼着してなる床材として一定の効果を奏することができるものの、上述したように木質基材の表層部が硬質木質繊維板によって形成されている場合には、この木質基材上に上記防湿シートを介して化粧突板を積層接着してなる床材の該化粧突板上にワゴン等のキャスターによる荷重がかかると、防湿シートに剪断破壊力が激しく作用して、紙間強化紙程度の強度では紙間剥離を防ぐことが困難である。   In order to eliminate such problems, paper such as inter-paper reinforced paper is used for the front and back of the moisture-proof sheet, and the paper is impregnated with a thermoplastic resin such as latex or acrylic emulsion in advance. Attempts to prevent interlaminar peeling have also been made, but when the wooden base material is a relatively soft plywood, the flooring material is formed by sticking a decorative veneer on the wooden base material via the moisture-proof sheet. Although the effect can be achieved, as described above, when the surface portion of the wood base material is formed of a hard wood fiber board, the decorative veneer is laminated and bonded to the wood base material via the moisture-proof sheet. When a load of casters such as a wagon is applied on the decorative veneer of the flooring material, a shear breaking force acts violently on the moisture-proof sheet, and it is difficult to prevent separation between papers at the strength of paper-reinforced paper. .

一方、上記特許文献2によれば、熱硬化性樹脂含浸紙の積層体の任意の層間に水蒸気透過度の低い樹脂フィルムを中間層として介在させているので、この中間層によって防湿効果が期待できるると共に、紙間剥離の発生をなくすることができるが、熱硬化性樹脂含浸紙の積層体の任意の層間に上記水蒸気透過度の低い樹脂フィルムを中間層として介在させる際に、この樹脂フィルムに表面処理を施しておく必要があって生産性の低下を招くばかりでなく、硬質の木質基材にこの熱硬化性樹脂含浸紙の積層体を介して化粧突板を積層、一体化してなる床材を構成した場合、中間層にクッション的な機能を発揮する層が全く存在しないために、キャスターによる連続的な荷重が作用すると、化粧突板の内部層で剪断破壊が生じるといった問題点があった。   On the other hand, according to Patent Document 2, since a resin film having a low water vapor permeability is interposed as an intermediate layer between arbitrary layers of the laminate of thermosetting resin-impregnated paper, a moisture-proof effect can be expected by this intermediate layer. In addition, the occurrence of peeling between papers can be eliminated, but when the resin film having a low water vapor permeability is interposed as an intermediate layer between arbitrary layers of the laminate of the thermosetting resin-impregnated paper, this resin film In addition to causing a decrease in productivity, it is necessary to perform surface treatment on the floor, and a decorative veneer is laminated and integrated on a hard wooden base material through a laminate of this thermosetting resin-impregnated paper. When the material is configured, there is no layer that exhibits a cushioning function in the intermediate layer. Therefore, when a continuous load is applied by a caster, shear failure occurs in the inner layer of the decorative veneer. Was Tsu.

本発明はこのような問題点に鑑みてなされたもので、その目的とするところは、優れた防湿性を維持しつつ、キャスター等の使用に対しても充分な耐傷性と強度を発揮することができると共に紙間剥離や単板の剪断破壊が生じ難い強化床材とこの強化床材の製造方法を提供するにある。   The present invention has been made in view of such problems, and its purpose is to exhibit sufficient scratch resistance and strength even for the use of casters, etc. while maintaining excellent moisture resistance. It is another object of the present invention to provide a reinforced floor material that can be easily peeled off and shear breakage of a single plate and a method for producing the reinforced floor material.

上記目的を達成するために、本発明の強化床材は、請求項1に記載したように、少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材と、耐熱性及び防湿性を有する熱可塑性樹脂シートの表裏面に熱硬化性樹脂を含浸硬化させている上下紙層を重ね合わせてこれらの上下紙層を上記熱可塑性樹脂シートに一体に熱溶着してなる防湿シート状物と、化粧突板とを順次、積層一体化してなる構造を有している。   In order to achieve the above object, the reinforced flooring material of the present invention, as described in claim 1, has a wood base material comprising at least a hard wood fiberboard having a specific gravity of 0.4 to 1.0, heat resistance and moisture resistance. A moisture-proof sheet-like material obtained by superimposing upper and lower paper layers impregnated and cured with a thermosetting resin on the front and back surfaces of a thermoplastic resin sheet having heat resistance and integrally welding these upper and lower paper layers to the thermoplastic resin sheet. And a decorative veneer are sequentially laminated and integrated.

このように構成した強化床材において、請求項2に係る発明は、上記防湿シート状物の上側紙層の表面を化粧単板の裏面に、下側紙層の裏面を木質基材の表面にそれぞれ熱硬化性樹脂接着剤によって一体に接着していると共に接着時にこれらの熱硬化性樹脂接着剤を上下紙層に含浸硬化させてなり、さらに、上記上側紙層は30〜50μmの厚みを有していると共にこの上側紙層と上記化粧単板とを接着させている上記熱硬化性樹脂接着剤は弾性を有する接着剤であって、この接着剤を上側紙層の全体に亘って含浸硬化させていることを特徴とする。   In the reinforced flooring material configured as described above, the invention according to claim 2 is directed to the surface of the upper paper layer of the moisture-proof sheet-like material on the back surface of the decorative veneer and the back surface of the lower paper layer on the surface of the wooden substrate. They are bonded together by thermosetting resin adhesives, and these upper and lower paper layers are impregnated and cured at the time of bonding, and the upper paper layer has a thickness of 30 to 50 μm. The thermosetting resin adhesive that bonds the upper paper layer to the decorative veneer is an elastic adhesive, and the adhesive is impregnated and cured throughout the upper paper layer. It is characterized by letting

請求項3に係る発明は、上記強化床材の製造方法であって、少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材の表面に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して木質基材の表面に、耐熱性及び防湿性を有する熱可塑性樹脂シートの表裏面に上下紙層を重ね合わせて一体に熱溶着してなる防湿シート状物を載置し、さらに、この防湿シート状物上に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して防湿シート状物の表面に化粧突板を積み重ねることによって、木質基材と防湿シート状物と化粧突板とからなる積層体を形成し、この積層体を熱圧することによって防湿シート状物の上下紙層にそれぞれ上記熱硬化性樹脂接着剤を含浸硬化させると共にこれらの熱硬化性樹脂接着剤によって木質基材の表面に防湿シート状物を介して化粧突板を積層一体化させることを特徴とする。   The invention according to claim 3 is a method for producing the above-mentioned reinforced flooring, wherein at least the surface layer portion is coated with a thermosetting resin adhesive on the surface of a wood base material made of a hard wood fiber board having a specific gravity of 0.4 to 1.0. A moisture-proof sheet formed by superimposing upper and lower paper layers on the front and back surfaces of a thermoplastic resin sheet having heat resistance and moisture resistance on the surface of a wooden substrate via this thermosetting resin adhesive and integrally heat-welding them. By placing a product, and further applying a thermosetting resin adhesive on the moisture proof sheet, and then stacking a decorative veneer on the surface of the moisture proof sheet via the thermosetting resin adhesive, A laminate composed of a wooden substrate, a moisture-proof sheet and a decorative veneer is formed, and the laminate is heated and pressed to impregnate and cure the thermosetting resin adhesive on the upper and lower paper layers of the moisture-proof sheet, respectively. These thermosetting resin contacts And characterized in that integrally laminating a decorative sliced veneer through the moisture-proof sheet on the surface of the wood substrate by agents.

請求項4に係る発明は、上記製造方法とは別な強化床材の製造方法であって、少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材の表面に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して木質基材の表面に、耐熱性及び防湿性を有する熱可塑性樹脂シートの表裏面に上下紙層を重ね合わせて一体に熱溶着してなる防湿シート状物を載置することにより木質基材と防湿シート状物とからなる中間積層体を形成し、この中間積層体を熱圧することによって防湿シート状物の下側紙層に上記熱硬化性樹脂接着剤を全体に亘って含浸硬化させると共に木質基材表面に防湿シート状物を一体に接着させる第一熱圧工程と、この中間積層体上に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して中間積層体に化粧突板を載置することにより最終積層体を形成し、この最終積層体を熱圧することによって防湿シート状物の上側紙層に中間積層体上に塗布した上記熱硬化性樹脂接着剤を含浸硬化させると共に防湿シート状物上に化粧突板を一体に接着させる第二熱圧工程とからなることを特徴とする。   The invention according to claim 4 is a method for manufacturing a reinforced flooring material different from the above manufacturing method, wherein at least the surface layer part has a thermosetting resin on the surface of a wooden base material made of a hard wood fiberboard having a specific gravity of 0.4 to 1.0. After the adhesive is applied, the upper and lower paper layers are superposed on the front and back surfaces of the thermoplastic resin sheet with heat resistance and moisture resistance on the surface of the wooden substrate via this thermosetting resin adhesive. An intermediate laminate composed of a wooden substrate and a moisture proof sheet is formed by placing the moisture proof sheet, and the intermediate laminate is hot-pressed on the lower paper layer of the moisture proof sheet. The thermosetting resin adhesive is impregnated and cured throughout the thermosetting resin adhesive, and the moisture-proof sheet-like material is integrally bonded to the surface of the wooden substrate, and the thermosetting resin adhesive is applied on the intermediate laminate. After applying, through this thermosetting resin adhesive The above-mentioned thermosetting resin adhesion applied on the intermediate laminate to the upper paper layer of the moisture-proof sheet by forming a final laminate by placing a decorative veneer on the interlaminate and then heat-pressing this final laminate And a second hot-pressing step in which the decorative veneer is integrally bonded onto the moisture-proof sheet-like material while impregnating and curing the agent.

請求項1に係る発明によれば、木質基材の少なくとも表層部を比重が0.4 〜1.0 の硬質木質繊維板によって形成しているので、この木質基材上に防湿シート状物を介して化粧突板を一体に積層してなる床材に落下物や家具の移動による凹み等の発生を防止するための強度を付与しておくことができるばかりでなく、木質基材と化粧突板との間に介在する上記防湿シート状物における熱可塑性樹脂シートによって表面から木質基材内に湿気が浸入するのを防止することができて寸法安定性を保持し得るものであり、その上、上記熱可塑性樹脂シートの表裏面に一体に熱融着されてこの熱可塑性樹脂シートと共に防湿シート状物を形成している上下紙層には、全体に亘って熱硬化性樹脂を含浸硬化させているので、床材に優れた耐傷性を付与することができると共に、上記木質基材の表層部に硬質木質繊維板を使用したことによってこの防湿シート状物に剪断破壊力が集中的に作用しても、紙間剥離や化粧突板の剪断破壊を防ぐことができる。   According to the first aspect of the present invention, at least the surface layer portion of the wood base material is formed of the hard wood fiber board having a specific gravity of 0.4 to 1.0, and thus the decorative veneer is disposed on the wood base material via the moisture-proof sheet-like material. In addition to being able to give strength to prevent the occurrence of dents due to falling objects and movement of furniture on the flooring that is laminated integrally, it is interposed between the wooden substrate and the decorative veneer It is possible to prevent moisture from entering from the surface into the wooden substrate by the thermoplastic resin sheet in the moisture-proof sheet, and to maintain dimensional stability. In addition, the thermoplastic resin sheet The upper and lower paper layers, which are integrally heat-sealed on the front and back surfaces of this sheet and form a moisture-proof sheet-like material together with this thermoplastic resin sheet, are impregnated and cured throughout, so that flooring To provide excellent scratch resistance In addition, the use of a hard wood fiberboard for the surface layer of the wood base material prevents the paper from peeling and shearing breakage of the decorative veneer even if shearing force acts on the moisture-proof sheet. be able to.

さらに、防湿シート状物における一定厚みを有する上下紙層に含浸させる熱硬化性樹脂接着剤の硬さと防湿シート状物の芯材に使用される樹脂シートの硬さを任意に選択することによって様々な要求に応じた強化床材を提供することができ、その上、上記樹脂シートが耐熱性を有する熱可塑性樹脂からなるため、その表裏面に重ね合わせた紙層に熱可塑性樹脂を含浸させるための熱圧プレスを行った場合でも、樹脂シートの防湿性能を劣化させることなく安定した生産が可能となる。   Furthermore, by arbitrarily selecting the hardness of the thermosetting resin adhesive impregnated in the upper and lower paper layers having a certain thickness in the moisture-proof sheet and the hardness of the resin sheet used for the core of the moisture-proof sheet In addition, the resin sheet is made of a thermoplastic resin having heat resistance, so that the paper layer superimposed on the front and back surfaces is impregnated with the thermoplastic resin. Even when the hot pressing is performed, stable production is possible without deteriorating the moisture-proof performance of the resin sheet.

また、請求項2に係る発明によれば、上記防湿シート状物の上側紙層と上記化粧単板とを接着させている上記熱硬化性樹脂接着剤は弾性を有する接着剤であって、この接着剤を上側紙層の全体に亘って含浸硬化させているので、ワゴン等のキャスターによる荷重がかかっても、その荷重を弾性的に吸収して紙層及び化粧突板のどの部分においても、紙間剥離や層間剥離が生じるのを防止することができる。   According to the invention according to claim 2, the thermosetting resin adhesive that bonds the upper paper layer of the moisture-proof sheet and the decorative veneer is an elastic adhesive, Since the adhesive is impregnated and cured over the entire upper paper layer, even if a load is applied by a caster such as a wagon, the load is elastically absorbed and the paper layer and the decorative veneer are not affected by the paper. It is possible to prevent interlaminar peeling and delamination.

上記強化床材の製造方法としては、請求項3に記載したように、少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材の表面に熱硬化性樹脂接着剤を介して、熱可塑性樹脂シートの表裏面に上下紙層を重ね合わせて一体に熱溶着してなる防湿シート状物を重ねると共に、この防湿シート状物上に熱硬化性樹脂接着剤を介して化粧突板を積み重ね、この積層体を熱圧プレスするものであるから、熱硬化性樹脂接着剤を防湿シート状物の上下紙層に含浸硬化させて紙間剥離が生じ難い紙層に形成することができると同時に、熱硬化性樹脂接着剤を介して木質基材と防湿シート状物と化粧突板とが強固に積層一体化してなる防湿性及び耐傷性に優れた強化床材を能率よく製造することができる。   As a manufacturing method of the reinforced flooring, as described in claim 3, at least the surface layer part has a specific gravity of 0.4 to 1.0 on the surface of a wooden base material made of hard wooden fiberboard, through a thermosetting resin adhesive, The top and bottom paper layers are stacked on the front and back surfaces of the thermoplastic resin sheet, and a moisture-proof sheet-like material that is integrally heat-welded is stacked, and a decorative veneer is stacked on the moisture-proof sheet-like material via a thermosetting resin adhesive. Since the laminate is hot-pressed, the thermosetting resin adhesive can be impregnated and cured in the upper and lower paper layers of the moisture-proof sheet to form a paper layer in which separation between papers hardly occurs. In addition, it is possible to efficiently produce a reinforced flooring material excellent in moisture resistance and scratch resistance, in which a wooden base material, a moisture-proof sheet-like material, and a decorative veneer are firmly laminated and integrated through a thermosetting resin adhesive.

なお、このように、木質基材と防湿シート状物と化粧突板との積層体を熱圧プレスによって同時に一体に固着する方法によることなく、請求項4に記載したように、まず、少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材の表面に熱硬化性樹脂接着剤を介して上記防湿シート状物を載置することにより中間積層体を形成し、この中間積層体を熱圧することによって防湿シート状物の下側紙層に上記熱硬化性樹脂接着剤を全体に亘って含浸硬化させると共に木質基材表面に防湿シート状物を一体に接着させる第一熱圧工程と、この中間積層体上に熱硬化性樹脂接着剤を介して化粧突板を載置することにより最終積層体を形成し、この最終積層体を熱圧することによって防湿シート状物の上側紙層に中間積層体上に塗布した上記熱硬化性樹脂接着剤を含浸硬化させると共に防湿シート状物上に化粧突板とを一体に接着させる第二熱圧工程とによって、強化床材を製造してもよい。   In addition, as described in claim 4, first, at least the surface layer portion is not based on the method in which the laminated body of the wooden base material, the moisture-proof sheet-like material, and the decorative veneer is fixed integrally at the same time by hot pressing. Is formed by placing the moisture-proof sheet-like material on the surface of a wood substrate made of a hard wood fiber board having a specific gravity of 0.4 to 1.0 via a thermosetting resin adhesive. A first hot-pressing step in which the lower paper layer of the moisture-proof sheet-like material is impregnated and cured with the thermosetting resin adhesive, and the moisture-proof sheet-like material is integrally bonded to the surface of the wooden substrate by hot pressing; The final laminate is formed by placing a decorative veneer on the intermediate laminate via a thermosetting resin adhesive, and the intermediate laminate is formed on the upper paper layer of the moisture-proof sheet by hot pressing the final laminate. After coating on the laminate By a second hot pressing step to bond together a decorative sliced veneer in the moisture-proof sheet on with impregnated cured thermosetting resin adhesive, may be produced reinforcing flooring.

次に、本発明の具体的の実施の形態を図面に基づいて説明すると、図1は強化床材Aの簡略縦断面図であって、強化床材Aは、一定厚みを有する木質基材1の表面(上面)に防湿シート状物2を介して化粧突板3を積層、一体化してなる構造を有している。   Next, a specific embodiment of the present invention will be described with reference to the drawings. FIG. 1 is a simplified longitudinal sectional view of a reinforced flooring A, and the reinforced flooring A is a wooden substrate 1 having a certain thickness. The decorative veneer 3 is laminated and integrated on the surface (upper surface) of the decorative veneer 3 via the moisture-proof sheet-like material 2.

詳しくは、上記木質基材1としては合板やパーティクルボード、OSB等の木質板状体1bの表面に比重が0.4 〜1.0 の硬質な木質繊維板1aを貼着してなる板材が使用されるが、基材全体を木質繊維板によって形成しておいてもよく、要するに、少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板1aからなる木質基材1であればよい。   Specifically, as the above-mentioned wood base material 1, a board material is used in which a hard wood fiber board 1 a having a specific gravity of 0.4 to 1.0 is attached to the surface of a wood board 1 b such as plywood, particle board, OSB or the like. In addition, the entire base material may be formed of a wood fiber board. In short, the wood base material 1 may be formed of the hard wood fiber board 1a having at least a surface layer portion having a specific gravity of 0.4 to 1.0.

上記のような硬質木質繊維板1aとしては、一般的な中比重木質繊維板(以下、MDFとする)やハードボード(以下、HDFとする)のうち、上述したように比重が0.4 〜1.0の木質繊維板を使用する。なお、比重が0.4 以下の木質繊維板は、化粧突板3の表面から衝撃を受けた場合には凹みや傷が生じやすくなって表面の耐傷性の高い床材を得ることができなく、また、比重が1.0 を越えるHDFを使用した場合には、湿気によって厚さ方向の膨潤が大きくなるため、好ましくない。   The hard wood fiber board 1a as described above has a specific gravity of 0.4 to 1.0 as described above, among general medium specific gravity wood fiber boards (hereinafter referred to as MDF) and hard boards (hereinafter referred to as HDF). Use wood fiberboard. It should be noted that the wood fiberboard having a specific gravity of 0.4 or less cannot easily obtain a flooring material having high surface scratch resistance because it tends to cause dents and scratches when impacted from the surface of the decorative veneer 3, When an HDF having a specific gravity exceeding 1.0 is used, it is not preferable because swelling in the thickness direction increases due to moisture.

また、木質繊維板は、使用している接合剤の種類により、例えば、該結合剤としてユリアメラミン樹脂を使用したものをUタイプ、メラミン樹脂を使用したものをMタイプ、フェノール樹脂を使用したものをPタイプとしているが、どのようなタイプであっても使用することができる。しかしながら、特に、床材の用途に使用する場合には、上記タイプのうち、Uタイプのものは耐水性に劣り、湿気に対して膨れやすいために使用を避けるべきである。さらに、結合剤としてイソシアネー化合物やポリオール化合物等の結合剤を使用した硬質木質繊維板も採用できる。なお、好適にはワックス等の撥水剤が内添されている硬質木質繊維板を使用することが望ましい。   In addition, wood fiberboards, for example, those using urea melamine resin as the binder, U type, those using melamine resin, M type, using phenolic resin, depending on the type of bonding agent used Is a P type, but any type can be used. However, in particular, when used for flooring applications, among the above types, the U type should be avoided because it is poor in water resistance and easily swells against moisture. Furthermore, a hard wood fiber board using a binder such as an isocyanate compound or a polyol compound as a binder can also be employed. It is preferable to use a hard wood fiber board in which a water repellent such as wax is added.

さらにまた、上記MDFやHDFは、使用している木質繊維の種類により、針葉樹系と広葉樹系とに分けられるが、一般的には針葉樹系の木質繊維に比べて広葉樹系の木質繊維は水分に対する寸法安定性に優れているため、広葉樹系の木質繊維からなるMDFやHDFを使用することが望ましい。   Furthermore, the MDF and HDF are classified into softwood and hardwood depending on the type of wood fiber used, but generally hardwood wood fiber is more resistant to moisture than softwood wood fiber. Because of excellent dimensional stability, it is desirable to use MDF or HDF made of hardwood wood fibers.

木質基材1の表面に防湿シート状物2を介して積層、一体化してなる上記化粧突板3としては、天然木質材からなる厚さが0.15〜1.0 mmの薄い木質化粧突板を使用するが、その樹種は限定されることなく、また、乾燥単板でもよいし、いわゆる濡れ単板であってもよい。但し、後述するように、本発明の強化床材を製造するには、木質基材1上に防湿シート状物2を介してこの化粧突板3を接着するための熱硬化性樹脂接着剤4aの塗布量を多く必要とするため、化粧突板3の表面へのこの熱硬化性樹脂接着剤4aの染み上がりが起こりやすくなるので、好適には0.35〜0.6 mm厚程度の化粧突板3が使用される。なお、この化粧突板3の表面に溝加工や浮造り加工、或いは、着色や塗装を施してもよい。   As the decorative veneer 3 formed by laminating and integrating the moisture-proof sheet-like material 2 on the surface of the wooden substrate 1, a thin wooden veneer having a thickness of 0.15 to 1.0 mm made of natural wooden material is used. The tree species is not limited and may be a dry veneer or a so-called wet veneer. However, as will be described later, in order to produce the reinforced flooring of the present invention, the thermosetting resin adhesive 4a for bonding the decorative veneer 3 to the wooden substrate 1 through the moisture-proof sheet-like material 2 is used. Since a large amount of coating is required, the surface of the decorative veneer 3 is likely to seep out of the thermosetting resin adhesive 4a. Therefore, the decorative veneer 3 having a thickness of about 0.35 to 0.6 mm is preferably used. . It should be noted that the surface of the decorative veneer 3 may be grooved, floated, colored or painted.

化粧突板3を木質基材1の硬質木質繊維板1aの表面に一体に積層接着させる上記防湿シート状物2としては、上側紙層2aと下側紙層2bとの間に耐熱性及び防湿性を有する熱可塑性樹脂からなる樹脂シート2cを芯層となるようにサンドイッチ状に介在させてなる三層構造のシート状物を熱圧することによって、熱可塑性樹脂シート2cの表裏面を上下紙層2a、2bに一体に融着させてなる構造を有するが、別な製造方法として、上下紙層2a、2b間に成形機のノズルから半溶融状態の熱可塑性樹脂シート2cを送り込んで上下紙層2a、2bの対向面をこの熱可塑性樹脂シート2cの表裏面にそれぞれ圧着させることにより、積層一体化させてもよい。   As the moisture-proof sheet-like material 2 in which the decorative projecting board 3 is integrally laminated and adhered to the surface of the hard wood fiber board 1a of the wood substrate 1, heat resistance and moisture resistance are provided between the upper paper layer 2a and the lower paper layer 2b. The upper and lower paper layers 2a are attached to the front and back surfaces of the thermoplastic resin sheet 2c by hot-pressing a sheet-like material having a three-layer structure in which a resin sheet 2c made of a thermoplastic resin having a core layer is interposed in a sandwich shape. , 2b has a structure that is integrally fused, but as another manufacturing method, a thermoplastic resin sheet 2c in a semi-molten state is fed between the upper and lower paper layers 2a and 2b from the nozzle of the molding machine, and the upper and lower paper layers 2a 2b may be laminated and integrated by pressing the opposite surfaces of 2b to the front and back surfaces of the thermoplastic resin sheet 2c, respectively.

この防湿シート状物2は上記木質基材1の木質繊維板1a上に重ね合わせる下側紙層2bを熱硬化性樹脂接着剤4bによって一体に接着させていると共に上側紙層2aの上面を化粧突板3の下面に熱硬化性樹脂接着剤4aによって一体に接着させることにより、木質基材1の木質繊維板1a上に防湿シート状物2を介して化粧突板3が一体に積層接着していると共に、防湿シート状物2の上下紙層2a、2bには、上記熱硬化性樹脂接着剤4a、4bがそれぞれ全体(全層)に亘って含浸硬化している強化床材Aを構成している。   The moisture-proof sheet-like material 2 has a lower paper layer 2b superimposed on a wood fiber board 1a of the above-mentioned wood substrate 1 and is integrally bonded with a thermosetting resin adhesive 4b, and the upper surface of the upper paper layer 2a is decorated. The decorative veneer 3 is integrally laminated and bonded to the lower surface of the veneer 3 with the thermosetting resin adhesive 4a on the wood fiber board 1a of the wood substrate 1 via the moisture-proof sheet-like material 2. At the same time, the upper and lower paper layers 2a and 2b of the moisture-proof sheet-like material 2 constitute a reinforced floor material A in which the thermosetting resin adhesives 4a and 4b are impregnated and cured over the whole (all layers). Yes.

上記熱可塑性樹脂シート2cとしては、一般的には低密度ポリエチレンシートを採用しているが、本発明においては、低密度ポリエチレンシートよりも耐熱性が高く、110 ℃以上の軟化温度特性を有する高密度ポリエチレンや架橋ポリエチレンシート、高密度架橋ポリエチレンシート、ポリエチレンテレフタレートシート等の耐熱性樹脂シートが好適に使用される。因みに、高密度ポリエチレン樹脂とは密度が0.94程度以上のものをさす。   As the thermoplastic resin sheet 2c, a low-density polyethylene sheet is generally employed. However, in the present invention, the thermoplastic resin sheet 2c has a higher heat resistance than a low-density polyethylene sheet and has a softening temperature characteristic of 110 ° C. or higher. A heat-resistant resin sheet such as a density polyethylene, a crosslinked polyethylene sheet, a high-density crosslinked polyethylene sheet, or a polyethylene terephthalate sheet is preferably used. Incidentally, high density polyethylene resin refers to those with a density of about 0.94 or more.

この熱可塑性樹脂シート2cの表裏面に層着している上記上下紙層2a、2bとしては、20〜50g/m2 程度のクラフト紙、薄葉紙、チタン紙等が用いられる。さらに好適には、ラテックスや合成樹脂等を含浸硬化させた紙間強化シート状物が使用される。ただし、この紙間強化シート状物は、上記熱硬化性樹脂接着剤4a、4bの浸透を妨げない程度に紙間強化されている必要がある。 As the upper and lower paper layers 2a and 2b layered on the front and back surfaces of the thermoplastic resin sheet 2c, kraft paper, thin paper, titanium paper or the like of about 20 to 50 g / m 2 is used. More preferably, a paper-reinforced sheet-like material impregnated and cured with latex or synthetic resin is used. However, the inter-paper reinforcing sheet needs to be inter-paper reinforced so as not to prevent the penetration of the thermosetting resin adhesives 4a and 4b.

防湿シート状物2の上下紙層2a、2bに含浸硬化すると共に、この防湿シート状物2を介して木質基材1の木質繊維板1a上に化粧突板3を一体に積層、接着させている上記熱硬化性樹脂接着剤4a、4bとしては、熱硬化特性を有していればどのような樹脂でも使用が可能であり、例えば、尿素メラミン系樹脂、尿素系樹脂、ポリエステル系樹脂、酢酸ビニル系樹脂やラテックス系樹脂にメラミン系樹脂やイソシアネート系樹脂を添加した接着剤等が好適に使用できる。   The upper and lower paper layers 2a, 2b of the moisture-proof sheet 2 are impregnated and cured, and the decorative veneer 3 is integrally laminated and bonded onto the wood fiber board 1a of the wooden substrate 1 through the moisture-proof sheet 2. As the thermosetting resin adhesives 4a and 4b, any resin having thermosetting properties can be used. For example, urea melamine resin, urea resin, polyester resin, vinyl acetate An adhesive obtained by adding a melamine resin or an isocyanate resin to a polymer resin or a latex resin can be suitably used.

木質基材1の表層部を形成している木質繊維板1a上に防湿シート状物2の下側紙層2bを接着させる熱硬化性樹脂接着剤4bとしては、耐傷性を向上させるために、比較的硬めの尿素メラミン系樹脂を用いることができ、耐キャスター性を向上させるためには、弾性を有するアクリル系樹脂、或いは、酢酸ビニル系樹脂やラテックス系樹脂にメラミン系樹脂やイソシアネート系樹脂等の熱硬化剤を添加した接着剤を使用することが好ましい。   In order to improve the scratch resistance, the thermosetting resin adhesive 4b for adhering the lower paper layer 2b of the moisture-proof sheet 2 to the wood fiber board 1a forming the surface layer portion of the wood substrate 1 Relatively hard urea melamine resin can be used, and in order to improve caster resistance, elastic acrylic resin, vinyl acetate resin or latex resin, melamine resin or isocyanate resin, etc. It is preferable to use an adhesive to which a thermosetting agent is added.

さらに、防湿シート状物2の上側紙層2aと化粧突板3とを接着させる熱硬化性樹脂接着剤4aとしては、化粧突板3の耐クラック性能と耐キャスター性能を向上させるために、弾性を有する熱硬化性樹脂接着剤を使用することが好ましく、特に、アクリル系樹脂、酢酸ビニル系樹脂やラテックス系樹脂にメラミン系樹脂やイソシアネート系樹脂等の熱硬化剤を添加した上記接着剤が好適に使用される。この場合、この熱硬化性樹脂接着剤4aと、上記木質繊維板1a上に防湿シート状物2の下側紙層2bを接着させている熱硬化性樹脂接着剤4bとは同じ組成の接着剤であってもよく、別な組成の接着剤であってもよい。   Furthermore, the thermosetting resin adhesive 4a for bonding the upper paper layer 2a of the moisture-proof sheet 2 and the decorative veneer 3 has elasticity in order to improve the crack resistance and caster resistance of the decorative veneer 3. It is preferable to use a thermosetting resin adhesive, and in particular, the above-mentioned adhesive in which a thermosetting agent such as a melamine resin or an isocyanate resin is added to an acrylic resin, a vinyl acetate resin or a latex resin is preferably used. Is done. In this case, the thermosetting resin adhesive 4a and the thermosetting resin adhesive 4b in which the lower paper layer 2b of the moisture-proof sheet 2 is bonded onto the wood fiber board 1a have the same composition. Or an adhesive having a different composition.

次に、上記のように構成した強化床材Aの製造方法について述べる。図2は、その一実施例であって、同図(イ)に示すように、表層部に比重0.4 〜1.0 の木質繊維板1aを一体に設けている木質基材1の表面にロールコータによって熱硬化性樹脂接着剤4bを全面に亘って均一に塗布したのち、熱可塑性樹脂シート2cを芯層としてこの熱可塑性樹脂シート2cの表裏面に紙層2a、2bを一体に設けてなる防湿シート状物2を重ねる。さらに、この防湿シート状物2の上側紙層2a上にロールコータによって熱硬化性樹脂接着剤4aを塗布したのち、この熱硬化性樹脂接着剤4aを介して防湿シート状物2上に化粧突板3を積み重ねることによって、木質基材1と防湿シート状物2と化粧突板3とからなる積層体A'を得る。この際、防湿シート状物2上に塗布した熱硬化性樹脂接着剤4aについては化粧突板3を重ねる前に短時間、養生をおいてその水分を少し揮発させておくことが好ましい。   Next, the manufacturing method of the reinforced flooring A comprised as mentioned above is described. FIG. 2 shows an embodiment of the present invention. As shown in FIG. 2A, a roll coater is used on the surface of a wood substrate 1 in which a wood fiber board 1a having a specific gravity of 0.4 to 1.0 is integrally provided on the surface layer portion. A moisture-proof sheet in which the thermosetting resin adhesive 4b is uniformly applied over the entire surface, and the thermoplastic resin sheet 2c is used as a core layer, and the paper layers 2a and 2b are integrally provided on the front and back surfaces of the thermoplastic resin sheet 2c. Layer 2 is stacked. Further, a thermosetting resin adhesive 4a is applied onto the upper paper layer 2a of the moisture-proof sheet-like material 2 by a roll coater, and then a decorative veneer is placed on the moisture-proof sheet-like material 2 via the thermosetting resin adhesive 4a. By stacking 3, a laminate A ′ composed of the wooden substrate 1, the moisture-proof sheet-like material 2, and the decorative veneer 3 is obtained. At this time, it is preferable that the thermosetting resin adhesive 4a applied on the moisture-proof sheet-like material 2 is cured for a short period of time before the decorative veneer 3 is stacked, and the water is volatilized slightly.

木質基材1の木質繊維板1aの表面と、防湿シート状物2の上側紙層2aにそれぞれ塗布する上記熱硬化性樹脂接着剤4a、4bの塗布量は、防湿シート状物2の上下紙層2a、2bの紙厚によって異なるが、上下紙層2a、2b内に全体に亘って含浸させ、且つ、木質基材1の木質繊維板1aとの接着及び化粧突板3との接着が全面的に確実に行わせるために、上下紙層2a、2bが30g/m2 の薄葉紙からなる場合には75g/m2 程度、上下紙層2a、2bが50g/m2 のクラフト紙からなる場合には130 g/m2 程度の接着剤を塗布する必要がある。 The amount of the thermosetting resin adhesives 4a and 4b applied to the surface of the wood fiber board 1a of the wood substrate 1 and the upper paper layer 2a of the moisture-proof sheet 2 is respectively the upper and lower papers of the moisture-proof sheet 2 Although depending on the paper thickness of the layers 2a and 2b, the upper and lower paper layers 2a and 2b are impregnated throughout, and the adhesion to the wood fiber board 1a and the adhesion to the decorative veneer 3 are entirely performed. in order to reliably performed, the upper and lower paper layers 2a, 2b is 75 g / m 2 approximately when consisting of tissue paper of 30 g / m 2, the upper and lower paper layers 2a, if 2b consists kraft paper 50 g / m 2 It is necessary to apply an adhesive of about 130 g / m 2 .

次いで、この積層体A'を熱圧プレス機の上下プレス盤間に挿入して温度100 〜130 ℃、圧力0.3 〜1.5 MPaの熱圧条件でもって30〜90秒間、熱圧プレスする。この際、木質基材1の木質繊維板1aの表面、及び、防湿シート状物2の上側紙層2a上に塗布している熱硬化性樹脂接着剤4a、4bの塗布量が多いため、含まれている水分によってパンクが発生するのを防止するために、熱圧プレスを2段階に分けて行うことが望ましい。即ち、最初に温度100 〜130 ℃、圧力0.3 〜0.5 MPa、熱圧時間10〜30秒程度のプレススケジュールでもって積層体A'を熱圧プレスすることにより、熱硬化性樹脂接着剤4a、4bに含まれている水分を水蒸気として飛ばしたのち、温度100 〜130 ℃、圧力0.8 〜1.5 MPa、熱圧時間30〜60秒程度のプレススケジュールでもって熱圧処理を行う。   Next, this laminate A ′ is inserted between the upper and lower presses of the hot press machine and hot pressed for 30 to 90 seconds under hot pressure conditions of a temperature of 100 to 130 ° C. and a pressure of 0.3 to 1.5 MPa. At this time, the amount of the thermosetting resin adhesive 4a, 4b applied on the surface of the wood fiber board 1a of the wood substrate 1 and the upper paper layer 2a of the moisture-proof sheet-like material 2 is large. In order to prevent the occurrence of puncture due to the water content, it is desirable to perform the hot press in two stages. That is, the thermosetting resin adhesives 4a and 4b are obtained by first hot pressing the laminate A ′ with a press schedule of a temperature of 100 to 130 ° C., a pressure of 0.3 to 0.5 MPa, and a hot pressing time of about 10 to 30 seconds. After the moisture contained in the water is blown out as water vapor, the hot-pressure treatment is performed with a press schedule of a temperature of 100 to 130 ° C., a pressure of 0.8 to 1.5 MPa, and a hot press time of about 30 to 60 seconds.

この熱圧プレスによって熱硬化性樹脂接着剤4a、4bが防湿シート状物2の上下紙層2a、2bに全体(全層)に亘って含浸したのち硬化すると共にこれらの熱硬化性樹脂接着剤4a、4bによって木質基材1の木質繊維板1aの表面に防湿シート状物2を介して化粧突板3が積層接着して図2(ロ)に示すように強化床材Aを得る。この強化床材Aはこのまま床材として使用してもよいが、その表面に浮造り加工や塗装等の化粧処理を施してもよい。   With this hot press, the thermosetting resin adhesives 4a and 4b are impregnated over the whole (all layers) of the upper and lower paper layers 2a and 2b of the moisture-proof sheet 2 and then cured. The decorative veneer 3 is laminated and bonded to the surface of the wood fiber board 1a of the wood substrate 1 through the moisture-proof sheet-like material 2 by 4a and 4b to obtain a reinforced flooring A as shown in FIG. Although this reinforced flooring A may be used as it is as a flooring, it may be subjected to a makeup process such as floating or painting on the surface.

このような化粧処理において、着色を施す場合に、その着色剤としては特に限定されないが、有機顔料や無機顔料等の顔料系着色剤や、染料系の着色剤が好適に使用される。また、塗装により化粧処理の場合においてもその塗装材料は特に限定されないが、熱硬化性樹脂や紫外線硬化性樹脂、電子線硬化性樹脂等の様々な塗料を使用することができる。床用の塗装用塗料としては、好適にはVOCの問題が少ない無溶剤系の紫外線硬化型アクリレート系樹脂が好適に使用することができる。   When coloring is performed in such a cosmetic treatment, the colorant is not particularly limited, but pigment-based colorants such as organic pigments and inorganic pigments, and dye-based colorants are preferably used. Also, in the case of cosmetic treatment by painting, the coating material is not particularly limited, but various paints such as a thermosetting resin, an ultraviolet curable resin, and an electron beam curable resin can be used. As the floor coating material, a solvent-free ultraviolet curable acrylate resin with few VOC problems can be preferably used.

図3は本発明強化床材Aの別な製造方法を示すもので、まず、同図(イ)に示すように表層部に比重0.4 〜1.0 の木質繊維板1aを一体に設けている木質基材1の表面にロールコータによって熱硬化性樹脂接着剤4bを全面に亘って均一に塗布したのち、熱可塑性樹脂シート2cを芯層としてこの熱可塑性樹脂シート2cの表裏面に紙層2a、2bを熱融着により一体に設けてなる防湿シート状物2を重ねることにより、木質基材1と防湿シート状物2とからなる中間積層体A1を得る。   FIG. 3 shows another method for producing the reinforced flooring A of the present invention. First, as shown in FIG. 3 (a), a wood base having a wood fiber board 1a having a specific gravity of 0.4 to 1.0 integrally formed on the surface layer portion. After the thermosetting resin adhesive 4b is uniformly applied over the entire surface of the material 1 by a roll coater, the paper layers 2a and 2b are formed on the front and back surfaces of the thermoplastic resin sheet 2c using the thermoplastic resin sheet 2c as a core layer. By stacking the moisture-proof sheet-like material 2 integrally formed by heat-sealing, an intermediate laminate A1 composed of the wooden substrate 1 and the moisture-proof sheet-like material 2 is obtained.

次いで、この中間積層体A1を熱圧プレス機の上下プレス盤間に挿入して上記実施例における強化床材Aの製造時と同じプレススケジュールの条件でもって熱圧プレスすることにより、熱硬化性樹脂接着剤4bを溶融させて防湿シート状物2の下側紙層2bに全体(全層)に亘って含浸させたのち硬化させると共にこの熱硬化性樹脂接着剤4bによって木質基材1の木質繊維板1aの表面に防湿シート状物2を一体に積層接着する。この熱圧による木質基材1と防湿シート状物2との接着処理を第1熱圧工程とする。   Next, the intermediate laminate A1 is inserted between the upper and lower presses of the hot press machine and hot pressed under the same press schedule conditions as in the production of the reinforced flooring A in the above embodiment, thereby providing thermosetting. The resin adhesive 4b is melted and impregnated over the whole (all layers) of the lower paper layer 2b of the moisture-proof sheet material 2 and then cured, and the wood substrate 1 is made of wood with this thermosetting resin adhesive 4b. A moisture-proof sheet-like material 2 is integrally laminated and bonded to the surface of the fiber board 1a. The adhesion treatment between the wooden base material 1 and the moisture-proof sheet-like material 2 by this heat pressure is defined as a first heat pressure step.

しかるのち、図3(ロ)に示すようにこの中間積層体A1における防湿シート状物2の上側紙層2a上にロールコータによって熱硬化性樹脂接着剤4aを全面に亘って均一に塗布し、この熱硬化性樹脂接着剤4aを介して化粧突板3を防湿シート状物2上に重ね合わせることにより最終積層体A'' を形成する。この場合、熱硬化性樹脂接着剤4aについては化粧突板3を載置する前に短時間の養生をおいてその水分を少し揮発させておくことが好ましい。   Thereafter, as shown in FIG. 3 (b), a thermosetting resin adhesive 4a is uniformly applied over the entire surface by a roll coater on the upper paper layer 2a of the moisture-proof sheet 2 in the intermediate laminate A1. The final laminate A ″ is formed by superimposing the decorative veneer 3 on the moisture-proof sheet-like material 2 through the thermosetting resin adhesive 4a. In this case, the thermosetting resin adhesive 4a is preferably cured for a short period of time before the decorative veneer 3 is placed, so that the water is volatilized slightly.

こうして得られた最終積層体A'' を、上記中間積層体A1に対する熱圧プレスを第1熱圧工程として、第2熱圧工程を行うことにより図3(ハ)に示すように強化床材Aを得る。この際、第2熱圧工程も上記と同様に、最終積層体A'' を熱圧プレス機の上下プレス盤間に挿入して上記実施例における強化床材Aの製造時と同じプレススケジュールの条件でもって熱圧プレスすることにより、熱硬化性樹脂接着剤4aを防湿シート状物2の上側紙層2aに全体に亘って含浸させたのち硬化させると共にこの熱硬化性樹脂接着剤4aによって防湿シート状物2に化粧突板3を一体に接着させる。   The final laminate A ″ thus obtained is subjected to a second hot-pressing process using the hot-pressing process for the intermediate laminate A1 as a first hot-pressing step, thereby performing a reinforced flooring as shown in FIG. Get A. At this time, in the second hot-pressing process, as in the above, the final laminate A ″ is inserted between the upper and lower press panels of the hot-pressing machine, and the press schedule is the same as that for manufacturing the reinforced flooring A in the above embodiment. By thermo-pressing under conditions, the thermosetting resin adhesive 4a is completely impregnated into the upper paper layer 2a of the moisture-proof sheet 2 and then cured, and the thermosetting resin adhesive 4a prevents moisture. The decorative veneer 3 is integrally bonded to the sheet-like material 2.

得られた強化床材Aは、上記製造方法によって得られた強化床材Aと略同一の物性を有し、その化粧突板3の表面に上記同様に任意の化粧加工を施して優れた外観と安定した品質を有する強化床材を得ることができる。次に、本発明の具体的な実施例を示す。   The obtained reinforced flooring A has substantially the same physical properties as the reinforced flooring A obtained by the above manufacturing method, and the surface of the decorative veneer 3 is subjected to any cosmetic processing in the same manner as described above and has an excellent appearance. A reinforced flooring material having stable quality can be obtained. Next, specific examples of the present invention will be described.

〔実施例〕
まず、2.7 mm厚みで比重が0.8 の木質繊維板を、9mmの厚みで5層構成のラワン合板の表面に貼着することによって複合木質基材を作製した。この複合木質基材の表面に尿素メラミン系樹脂100 重量部に対してラテックス系樹脂を15重量部添加してなる樹脂率50%の熱硬化性樹脂接着剤をロールコータによって75g/m2 塗布した。次いで、軟化点130 ℃の高密度ポリエチレン樹脂シートの表裏面に30g/m2 の薄葉紙をサンドイッチ状に重ね合わせて該高密度ポリエチレン樹脂シートの表裏面を薄葉紙に熱融着させることにより作製された3層構造のポリサンド紙(防湿シート状物)を上記熱硬化性樹脂接着剤の層上に重ねたのち、このポリサンド紙上に尿素メラミン系樹脂100 重量部に対してラテックス系樹脂を50重量部添加してなる樹脂率50%の熱硬化性樹脂接着剤をロールコータによって75g/m2 塗布した。この状態で60秒間、常温下で放置した。
〔Example〕
First, a wood fiber board having a thickness of 2.7 mm and a specific gravity of 0.8 was attached to the surface of a lauan plywood having a thickness of 9 mm and a five-layer structure to prepare a composite wood substrate. A thermosetting resin adhesive having a resin rate of 50%, which is obtained by adding 15 parts by weight of a latex resin to 100 parts by weight of urea melamine resin, was applied to the surface of the composite wood substrate by a roll coater at 75 g / m 2 . . Subsequently, 30 g / m 2 of thin paper was superimposed on the front and back surfaces of the high-density polyethylene resin sheet having a softening point of 130 ° C. in a sandwich shape, and the front and back surfaces of the high-density polyethylene resin sheet were heat-sealed to the thin paper. After three-layer poly sand paper (moisture-proof sheet-like material) is layered on the thermosetting resin adhesive layer, 50 parts by weight of latex resin is added to 100 parts by weight of urea melamine resin on this poly sand paper. A thermosetting resin adhesive having a resin ratio of 50% was applied by a roll coater at 75 g / m 2 . This state was left at room temperature for 60 seconds.

しかるのち、この熱硬化性樹脂接着剤の層上に化粧突板を載置し、直ちに平板熱圧プレス機により、120 ℃、0.5 MPaの熱圧を15秒間行い、続いて120 ℃、0.8 MPaの熱圧を45秒間行うプレススケジュールでもって熱圧プレスすることにより強化床材を得た。こうして得られた強化床材における化粧突板の表面に顔料系の水系着色剤で着色したのちドライヤーで乾燥し、アクリレート系の紫外線硬化型樹脂で透明塗膜層を表面に形成した。この強化床材に対して耐キャスター試験を行った。この耐キャスター試験とは25kgの重りを載せた直径30cm程度の鉄輪キャスターを強化床材の同一表面箇所で500 回往復運動させ、試験後の表面状態を観測する試験である。この試験結果、紙間剥離や化粧突板内での層間剥離は全く生じていなかった。   After that, a decorative veneer was placed on the thermosetting resin adhesive layer, and immediately subjected to 120 ° C. and 0.5 MPa hot pressure for 15 seconds by a flat plate hot press machine, followed by 120 ° C. and 0.8 MPa. Reinforced flooring was obtained by hot pressing with a press schedule for 45 seconds. The surface of the decorative veneer in the thus obtained reinforced flooring was colored with a pigment-based water-based colorant, dried with a dryer, and a transparent coating layer was formed on the surface with an acrylate-based ultraviolet curable resin. A caster resistance test was performed on the reinforced flooring. This caster resistance test is a test in which a steel wheel caster with a diameter of about 30 cm on which a 25 kg weight is placed is reciprocated 500 times on the same surface of the reinforced flooring and the surface condition after the test is observed. As a result of this test, no delamination between sheets or delamination within the decorative veneer occurred.

〔比較例〕
まず、2.7 mm厚みで比重が0.8 の木質繊維板を、9mmの厚みで5層構成のラワン合板の表面に貼着することによって複合木質基材を作製した。この複合木質基材の表面に尿素メラミン系樹脂100 重量部に対してラテックス系樹脂を15重量部添加してなる樹脂率50%の熱硬化性樹脂接着剤をロールコータによって50g/m2 塗布した。次いで、軟化点130 ℃の高密度ポリエチレン樹脂シートの表裏面に30g/m2 の薄葉紙をサンドイッチ状に重ね合わせて該高密度ポリエチレン樹脂シートの表裏面を薄葉紙に熱融着させることにより作製された3層構造のポリサンド紙(防湿シート状物)を上記熱硬化性樹脂接着剤の層上に重ねたのち、このポリサンド紙上に尿素メラミン系樹脂100 重量部に対してラテックス系樹脂を50重量部添加してなる樹脂率50%の熱硬化性樹脂接着剤をロールコータによって50g/m2 塗布した。
[Comparative example]
First, a wood fiber board having a thickness of 2.7 mm and a specific gravity of 0.8 was attached to the surface of a lauan plywood having a thickness of 9 mm and a five-layer structure to prepare a composite wood substrate. 50 g / m 2 of a thermosetting resin adhesive having a resin ratio of 50% obtained by adding 15 parts by weight of a latex resin to 100 parts by weight of urea melamine resin was applied to the surface of this composite wood substrate by a roll coater. . Subsequently, 30 g / m 2 of thin paper was superimposed on the front and back surfaces of the high-density polyethylene resin sheet having a softening point of 130 ° C. in a sandwich shape, and the front and back surfaces of the high-density polyethylene resin sheet were heat-sealed to the thin paper. After three-layer poly sand paper (moisture-proof sheet-like material) is layered on the thermosetting resin adhesive layer, 50 parts by weight of latex resin is added to 100 parts by weight of urea melamine resin on this poly sand paper. A thermosetting resin adhesive having a resin ratio of 50% was applied by a roll coater at 50 g / m 2 .

しかるのち、この熱硬化性樹脂接着剤の層上に化粧突板を載置し、直ちに平板熱圧プレス機により、120 ℃、0.8 MPaの熱圧を60秒間行うことによって強化床材を得た。こうして得られた強化床材における化粧突板の表面に顔料系の水系着色剤で着色したのちドライヤーで乾燥し、アクリレート系の紫外線硬化型樹脂で透明塗膜層を表面に形成した。この強化床材に対して上記実施例と同じ耐キャスター試験を行った。その結果、この強化床材におけるボリサンド紙の下側紙層の熱硬化性樹脂接着剤の含浸されていない部分で紙間剥離が確認された。   Thereafter, a decorative veneer was placed on the thermosetting resin adhesive layer, and a reinforced flooring was obtained by immediately applying a hot pressure of 120 ° C. and 0.8 MPa for 60 seconds with a flat plate hot press machine. The surface of the decorative veneer in the thus obtained reinforced flooring was colored with a pigment-based water-based colorant, dried with a dryer, and a transparent coating layer was formed on the surface with an acrylate-based ultraviolet curable resin. The same caster resistance test as that of the above example was performed on this reinforced flooring. As a result, separation between papers was confirmed at a portion of the reinforced flooring material that was not impregnated with the thermosetting resin adhesive in the lower paper layer of the Bolly sand paper.

強化床材の簡略縦断面図。The simplified longitudinal cross-sectional view of a reinforced flooring. 強化床材の製造方法を示す簡略工程図。The simplified process drawing which shows the manufacturing method of a reinforced flooring. 強化床材の別な製造方法を示す簡略工程図。The simplified process drawing which shows another manufacturing method of a reinforced flooring.

符号の説明Explanation of symbols

A 強化床材
1 木質基材
1a 木質繊維板
2 防湿シート状物
2a、2b 上下紙層
2c 熱可塑性樹脂シート
3 化粧突板
4a、4b 熱硬化性樹脂接着剤
A Reinforced flooring 1 Wood base
1a Wood fiber board 2 Moisture-proof sheet
2a, 2b Top and bottom paper layers
2c thermoplastic resin sheet 3 decorative veneer
4a, 4b Thermosetting resin adhesive

Claims (4)

少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材と、耐熱性及び防湿性を有する熱可塑性樹脂シートの表裏面に熱硬化性樹脂を含浸硬化させている上下紙層を重ね合わせてこれらの上下紙層を上記熱可塑性樹脂シートに一体に熱溶着してなる防湿シート状物と、化粧突板とを順次、積層一体化してなることを特徴とする強化床材。   At least the surface layer part is made of a hard wood fiberboard having a specific gravity of 0.4 to 1.0, and upper and lower paper layers impregnated and cured with a thermosetting resin on the front and back surfaces of a thermoplastic resin sheet having heat resistance and moisture resistance. In addition, a reinforced flooring material comprising a moisture-proof sheet-like product obtained by integrally heat-sealing these upper and lower paper layers with the thermoplastic resin sheet and a decorative projecting board, which are sequentially laminated and integrated. 防湿シート状物の上側紙層の表面を化粧単板の裏面に、下側紙層の裏面を木質基材の表面にそれぞれ熱硬化性樹脂接着剤によって一体に接着していると共に接着時にこれらの熱硬化性樹脂接着剤を上下紙層に含浸硬化させてなり、さらに、上記上側紙層は30〜50μmの厚みを有していると共にこの上側紙層と上記化粧単板とを接着させている上記熱硬化性樹脂接着剤は弾性を有する接着剤であって、この接着剤を上側紙層の全体に亘って含浸硬化させていることを特徴とする請求項1に記載の強化床材。   The surface of the upper paper layer of the moisture-proof sheet is adhered to the back surface of the decorative veneer, and the back surface of the lower paper layer is integrally bonded to the surface of the wooden substrate with a thermosetting resin adhesive. The upper and lower paper layers are impregnated and cured with a thermosetting resin adhesive, and the upper paper layer has a thickness of 30 to 50 μm and is bonded to the decorative veneer. The reinforced flooring material according to claim 1, wherein the thermosetting resin adhesive is an adhesive having elasticity, and the adhesive is impregnated and cured over the entire upper paper layer. 少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材の表面に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して木質基材の表面に、耐熱性及び防湿性を有する熱可塑性樹脂シートの表裏面に上下紙層を重ね合わせて一体に熱溶着してなる防湿シート状物を載置し、さらに、この防湿シート状物上に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して防湿シート状物の表面に化粧突板を積み重ねることによって、木質基材と防湿シート状物と化粧突板とからなる積層体を形成し、この積層体を熱圧することによって防湿シート状物の上下紙層にそれぞれ上記熱硬化性樹脂接着剤を含浸硬化させると共にこれらの熱硬化性樹脂接着剤によって木質基材の表面に防湿シート状物を介して化粧突板を積層一体化させることを特徴とする強化床材の製造方法。   After applying a thermosetting resin adhesive to the surface of a wood substrate made of hard wood fiberboard with a specific gravity of 0.4 to 1.0 at least in the surface layer, heat resistance is applied to the surface of the wood substrate through this thermosetting resin adhesive. A moisture-proof sheet-like material obtained by superimposing upper and lower paper layers on the front and back surfaces of a thermoplastic resin sheet having heat resistance and moisture-proof and integrally heat-sealing is further mounted on the moisture-proof sheet-like material. After applying the adhesive, the decorative veneer is stacked on the surface of the moisture-proof sheet through this thermosetting resin adhesive to form a laminate composed of the wooden substrate, the moisture-proof sheet, and the decorative veneer. The laminate is heated and pressed so that the upper and lower paper layers of the moisture-proof sheet are impregnated and cured with the thermosetting resin adhesive, and the moisture-proof sheet is applied to the surface of the wooden substrate by these thermosetting resin adhesives. Through makeup Method for producing a reinforcing flooring for causing integrally laminated plate. 少なくとも表層部が比重0.4 〜1.0 の硬質木質繊維板からなる木質基材の表面に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して木質基材の表面に、耐熱性及び防湿性を有する熱可塑性樹脂シートの表裏面に上下紙層を重ね合わせて一体に熱溶着してなる防湿シート状物を載置することにより木質基材と防湿シート状物とからなる中間積層体を形成し、この中間積層体を熱圧することによって防湿シート状物の下側紙層に上記熱硬化性樹脂接着剤を全体に亘って含浸硬化させると共に木質基材表面に防湿シート状物を一体に接着させる第一熱圧工程と、この中間積層体上に熱硬化性樹脂接着剤を塗布したのち、この熱硬化性樹脂接着剤を介して中間積層体に化粧突板を載置することにより最終積層体を形成し、この最終積層体を熱圧することによって防湿シート状物の上側紙層に中間積層体上に塗布した上記熱硬化性樹脂接着剤を含浸硬化させると共に防湿シート状物上に化粧突板を一体に接着させる第二熱圧工程とからなることを特徴とする強化床材の製造方法。   After applying a thermosetting resin adhesive to the surface of a wood substrate made of hard wood fiberboard with a specific gravity of 0.4 to 1.0 at least in the surface layer, heat resistance is applied to the surface of the wood substrate through this thermosetting resin adhesive. Between a wooden substrate and a moisture-proof sheet by placing a moisture-proof sheet in which the upper and lower paper layers are superposed on the front and back surfaces of the thermoplastic and moisture-proof thermoplastic resin sheet By forming a laminate and heat-pressing the intermediate laminate, the lower paper layer of the moisture-proof sheet is impregnated and cured over the entire surface and the moisture-proof sheet on the surface of the wooden substrate. A first heat-pressure step for bonding the two pieces together, and applying a thermosetting resin adhesive on the intermediate laminate, and then placing a decorative veneer on the intermediate laminate via the thermosetting resin adhesive To form the final laminate. The second heat is applied to the upper paper layer of the moisture-proof sheet by impregnating and curing the thermosetting resin adhesive applied on the intermediate laminate, and the decorative veneer is integrally bonded to the moisture-proof sheet. A method for producing a reinforced floor material, comprising a pressing step.
JP2007231649A 2007-09-06 2007-09-06 Reinforced floor material and method of manufacturing the same Pending JP2009061680A (en)

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101851999A (en) * 2010-06-11 2010-10-06 三林合板(南通)有限公司 Composite floor decorative material
JP2011226198A (en) * 2010-04-22 2011-11-10 Panasonic Electric Works Co Ltd Wood floor material
JP2011226199A (en) * 2010-04-22 2011-11-10 Panasonic Electric Works Co Ltd Method of manufacturing direct bonding floor material
CN102284991A (en) * 2011-09-01 2011-12-21 内蒙古农业大学 Medium-density fiberboard made of willow timber fiber reinforced sand willow timber and preparation method of same
CN102303348A (en) * 2011-09-01 2012-01-04 内蒙古农业大学 Reed fiber reinforced salix mongolica medium-density fiber board and preparation method thereof
CN102912952A (en) * 2012-10-16 2013-02-06 张家港市盛港绿色防火建材有限公司 Embossed wood grain board and manufacturing process thereof
WO2015135231A1 (en) * 2014-03-10 2015-09-17 浙江鑫拓竹业科技有限公司 Recombinant wood flooring
CN106042533A (en) * 2016-06-28 2016-10-26 浙江裕华木业有限公司 Recombined decoration board and manufacturing method thereof
JP2020168818A (en) * 2019-04-04 2020-10-15 冨士ファニチア株式会社 Decorative composite board, and manufacturing method of decorative composite board subjected to drawing processing
CN115023327A (en) * 2020-02-19 2022-09-06 尤尼伍德株式会社 Structural veneer laminate and method for making same

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02301405A (en) * 1989-05-16 1990-12-13 Kobunshi Giken Kk Plate for concrete frame and its manufacture
JPH09314520A (en) * 1996-05-27 1997-12-09 Dantani Plywood Co Ltd Woody decorative board
JPH10219985A (en) * 1997-02-05 1998-08-18 Mitsubishi Chem Mkv Co Wooden floor material
JPH11333985A (en) * 1998-05-27 1999-12-07 Dainippon Printing Co Ltd Warpage preventing decorative material
JP2000274054A (en) * 1999-03-25 2000-10-03 Nippon Paper Industries Co Ltd Moisture-proof floor material
JP2003211420A (en) * 2002-01-28 2003-07-29 Matsushita Electric Works Ltd Method for producing floor material
JP2007031958A (en) * 2005-07-22 2007-02-08 Matsushita Electric Works Ltd Construction plate

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH02301405A (en) * 1989-05-16 1990-12-13 Kobunshi Giken Kk Plate for concrete frame and its manufacture
JPH09314520A (en) * 1996-05-27 1997-12-09 Dantani Plywood Co Ltd Woody decorative board
JPH10219985A (en) * 1997-02-05 1998-08-18 Mitsubishi Chem Mkv Co Wooden floor material
JPH11333985A (en) * 1998-05-27 1999-12-07 Dainippon Printing Co Ltd Warpage preventing decorative material
JP2000274054A (en) * 1999-03-25 2000-10-03 Nippon Paper Industries Co Ltd Moisture-proof floor material
JP2003211420A (en) * 2002-01-28 2003-07-29 Matsushita Electric Works Ltd Method for producing floor material
JP2007031958A (en) * 2005-07-22 2007-02-08 Matsushita Electric Works Ltd Construction plate

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2011226198A (en) * 2010-04-22 2011-11-10 Panasonic Electric Works Co Ltd Wood floor material
JP2011226199A (en) * 2010-04-22 2011-11-10 Panasonic Electric Works Co Ltd Method of manufacturing direct bonding floor material
CN101851999A (en) * 2010-06-11 2010-10-06 三林合板(南通)有限公司 Composite floor decorative material
CN102284991A (en) * 2011-09-01 2011-12-21 内蒙古农业大学 Medium-density fiberboard made of willow timber fiber reinforced sand willow timber and preparation method of same
CN102303348A (en) * 2011-09-01 2012-01-04 内蒙古农业大学 Reed fiber reinforced salix mongolica medium-density fiber board and preparation method thereof
CN102912952A (en) * 2012-10-16 2013-02-06 张家港市盛港绿色防火建材有限公司 Embossed wood grain board and manufacturing process thereof
WO2015135231A1 (en) * 2014-03-10 2015-09-17 浙江鑫拓竹业科技有限公司 Recombinant wood flooring
CN106042533A (en) * 2016-06-28 2016-10-26 浙江裕华木业有限公司 Recombined decoration board and manufacturing method thereof
JP2020168818A (en) * 2019-04-04 2020-10-15 冨士ファニチア株式会社 Decorative composite board, and manufacturing method of decorative composite board subjected to drawing processing
JP7208626B2 (en) 2019-04-04 2023-01-19 冨士ファニチア株式会社 Decorative composite board and method for manufacturing drawn decorative composite board
CN115023327A (en) * 2020-02-19 2022-09-06 尤尼伍德株式会社 Structural veneer laminate and method for making same

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