JP2009012041A - Warm-forming method and warm-formed article manufactured by the method - Google Patents

Warm-forming method and warm-formed article manufactured by the method Download PDF

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JP2009012041A
JP2009012041A JP2007176911A JP2007176911A JP2009012041A JP 2009012041 A JP2009012041 A JP 2009012041A JP 2007176911 A JP2007176911 A JP 2007176911A JP 2007176911 A JP2007176911 A JP 2007176911A JP 2009012041 A JP2009012041 A JP 2009012041A
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JP5266676B2 (en
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Mitsuhiro Tamaoki
充宏 玉置
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Sumitomo Light Metal Industries Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To obtain a warm-formed article having high strength by using an Al-Mg alloy having high strength. <P>SOLUTION: An Al-Mg alloy plate 6 having high strength is placed on a wrinkle presser 3 while keeping a space 7 between a die 2 and the wrinkle presser 3, and heated to the temperature range not reaching an O material. Since the plate is formed by a punch 4 while being held by the die 2 and the wrinkle presser 3, expansion is not prevented by the space and any distortion is not generated even when the Al-Mg alloy plate 6 is expanded when the plate is heated. Further, since the heating is performed for a short time, the degradation of the strength is minimum, and a warm-formed article having high strength can be obtained. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本願発明は、Al合金、特にAl−Mg合金の温間成形加工方法と該温間成形成形加工方法により製造される成形加工品に関する。   The present invention relates to a warm forming method of an Al alloy, particularly an Al-Mg alloy, and a formed product manufactured by the warm forming method.

従来、高強度のAl合金の成形加工品を得ようとする場合には、成形加工品の形状を複雑にする、成形加工後に熱処理を施す、又は成形素材にAl−Mg合金等の強度の高いものを使用する等の成形加工方法がある。   Conventionally, when trying to obtain a molded product of high-strength Al alloy, the shape of the molded product is complicated, heat treatment is performed after molding, or the molding material has high strength such as Al-Mg alloy There are molding methods such as using materials.

しかしながら、上記成形加工方法において、成形加工品の形状を複雑にして強度を高めようとすると、該成形加工品の外観が制約されるものとなる。
また、成形加工後に熱処理を施すものであっては、成形加工に使用できるAl合金が限定される上、成形加工後の熱処理によって歪みが発生することがある。その結果成形加工品の歩留まりが低下し、熱処理工程の付加により成形加工品の製造コストが上昇する。さらに成形加工品に対する熱処理により得られる強度は調質の半硬程度が限界である。
そして、成形素材にAl−Mg合金等の高強度のAl合金を使用する場合、冷間成形加工では成形素材の展伸性が期待できず、複雑な形状や深い絞り成形を施すには限界がある。その上、成形加工中に成形加工品や金型が破損し易いものである。
However, in the above molding method, if the shape of the molded product is complicated to increase the strength, the appearance of the molded product is restricted.
In addition, in the case where heat treatment is performed after the forming process, Al alloys that can be used for the forming process are limited, and distortion may occur due to the heat treatment after the forming process. As a result, the yield of the molded product decreases, and the manufacturing cost of the molded product increases due to the addition of the heat treatment step. Further, the strength obtained by heat treatment of the molded product is limited to the semi-hardness of the tempering.
And when using a high-strength Al alloy such as an Al-Mg alloy as the molding material, the cold forming process cannot expect the extensibility of the molding material, and there are limits to applying complex shapes and deep drawing. is there. In addition, the molded product and the mold are easily damaged during the molding process.

そこで、成形素材にAl−Mg合金等の高強度のAl合金を使用した上で、成形加工中に成形素材をO材に至らない温間温度域で加熱する成形加工方法(特許文献1、2及び3参照)が提案されている。   Therefore, after using a high-strength Al alloy such as an Al—Mg alloy as a forming material, a forming method in which the forming material is heated in a warm temperature range that does not reach the O material during the forming process (Patent Documents 1 and 2). And 3) have been proposed.

ところが、例えばダイス、しわ押さえとポンチからなる絞り成形加工では、ダイスとしわ押さえにより成形素材の周縁を挟持しながら加熱するものである。その結果、Al合金の成形素材は、その大きな線膨張係数に起因して、ダイスとしわ押さえによって挟持される周縁に成形加工品の変形につながる歪みを発生させることがある。   However, in the drawing forming process including, for example, a die, a wrinkle presser and a punch, heating is performed while sandwiching the periphery of the molding material by the die and the wrinkle presser. As a result, due to the large linear expansion coefficient, the Al alloy molding material may generate strain that leads to deformation of the molded product at the periphery held by the die and the wrinkle retainer.

特開平4−158937号公報JP-A-4-158937 特開平7−310137号公報JP 7-310137 A 特開2006−205244号公報JP 2006-205244 A

本願発明は、高強度のAl合金の成形素材を用いて温間成形加工を行うに当たり、強度の低下を最小限とするとともに、成形加工品の変形を防止して、高強度の成形加工品が得られるようにする。   The invention of the present application minimizes a decrease in strength when performing warm forming using a high-strength Al alloy molding material, and prevents deformation of the molded product, so that a high-strength molded product is obtained. To be obtained.

上記課題を解決するため、第1の特徴として、互いに当接自在となりヒーターを内蔵するダイス、しわ押さえ及びポンチを具備する温間成形加工装置において、
温間成形加工装置の互いに離隔しているダイスとしわ押さえ間において、一方のダイス又はしわ押さえとの間に空隙を有しながら、他方のしわ押さえ又はダイス上にAl−Mg合金の成形素材を載置する工程と、
該温間成形加工装置内を加熱することで成形素材をO材に至らない180〜350℃の温度域まで加熱する工程と、
該成形素材をダイスとしわ押さえにより挟持する工程と、
上記ダイスとしわ押さえにより挟持された成形素材をポンチによって成形してなる工程と
からなるものである。
In order to solve the above problems, as a first feature, in a warm forming apparatus including a die, a crease presser, and a punch that are in contact with each other and have a built-in heater,
Between the dice and the crease presser that are separated from each other in the warm forming processing device, while having a gap between the dies and the crease presser, a molding material of Al-Mg alloy is formed on the other crease presser or die. A process of placing;
A step of heating the molding material to a temperature range of 180 to 350 ° C. that does not reach O material by heating the inside of the warm molding processing apparatus;
Sandwiching the molding material with a die and a crease press;
And forming a molding material sandwiched between the die and the wrinkle presser by a punch.

以上のように、線膨張係数の大きい成形素材であるAl−Mg合金が加熱中に大きく膨張しても、該成形素材の膨張はダイスとしわ押さえとの間に形成される空隙で許容されるので、前記Al−Mg合金において成形加工品の歪みの発生を防止できる。   As described above, even if the Al—Mg alloy, which is a molding material having a large linear expansion coefficient, expands greatly during heating, the expansion of the molding material is allowed by the gap formed between the die and the wrinkle retainer. Therefore, generation | occurrence | production of the distortion of a molded product can be prevented in the said Al-Mg alloy.

そして、成形素材であるAl−Mg合金は加熱によってO材に至らない180〜350℃の温度域となるので、Al−Mg合金の展伸性は常温と比較して数倍にまで向上する。その結果、成形加工は容易になり、複雑な形状や深い絞り成形が可能になる。更に上記温間温度域であるので成形加工品においてはO材に至ることはなく、強度を十分に確保することができる。
ここで、成形素材に対する加熱は、Al−Mg合金において、より好ましくは230〜350℃の温度域とするものである。なお、本願発明はAl−Mg合金についてのものであるが、該成形素材が1000系の場合は180〜300℃、3000系の場合は200〜330℃、また6000系の場合は180〜330℃が好ましいものである。
And since the Al-Mg alloy which is a forming material is in a temperature range of 180 to 350 ° C. which does not reach the O material by heating, the extensibility of the Al—Mg alloy is improved several times compared to normal temperature. As a result, the molding process becomes easy, and a complicated shape and deep drawing can be performed. Furthermore, since it is in the warm temperature range, the molded product does not reach the O material, and a sufficient strength can be ensured.
Here, the heating with respect to the forming material is preferably performed in a temperature range of 230 to 350 ° C. in the Al—Mg alloy. The present invention relates to an Al—Mg alloy. When the molding material is 1000 series, it is 180 to 300 ° C., 3000 series is 200 to 330 ° C., and 6000 series is 180 to 330 ° C. Is preferred.

更に、第1の特徴を踏まえて、第2の特徴として、上記温間成形加工装置内の加熱開始から成形加工品の取り出しまでの時間を2〜30秒とするものである。   Further, based on the first feature, as a second feature, the time from the start of heating in the warm molding apparatus to the removal of the molded product is set to 2 to 30 seconds.

以上のように、上記温間成形加工装置内のAl−Mg合金に対する加熱は必要最小限となるので、過剰な加熱により発生する焼き鈍しによって成形加工品の強度が低下することを防止できる。その上、成形加工の作業時間は短くなるので成形素材の温度低下は最小限となって成形加工中での成形素材の展伸性を十分に確保できるので、複雑な形状や深い絞り成形が可能になる。
ここで、温間成形加工装置内の加熱開始から成形加工品の取り出しまでの時間を2秒未満であると、特に成形素材の温度分布にムラが生じ易く成形加工に際しての成形素材の全面で十分な展伸性を確保できなくなるおそれがある。一方前記時間を30秒以上とすると、成形加工品が軟化して変形するおそれがある。
As described above, since the heating of the Al—Mg alloy in the warm forming apparatus is the minimum necessary, it is possible to prevent the strength of the formed product from being lowered due to the annealing generated by excessive heating. In addition, the working time of the molding process is shortened, so the temperature drop of the molding material is minimized, and the extensibility of the molding material during the molding process can be secured sufficiently, enabling complex shapes and deep drawing become.
Here, if the time from the start of heating in the warm molding apparatus to the removal of the molded product is less than 2 seconds, unevenness in the temperature distribution of the molding material is likely to occur, and the entire surface of the molding material is sufficient during the molding process. May not be able to ensure proper extensibility. On the other hand, if the time is 30 seconds or more, the molded product may be softened and deformed.

ここで、成形素材への加熱は、Al−Mg合金がO材に至らない温度域に達すれば足りるものである。そのため温間成形加工装置内での加熱だけでなく、誘導加熱やホットプレスを利用することで予め加熱を行うことで、成形加工装置内での加熱時間を短時間とし、成形加工の作業時間を短縮させることができる。   Here, the heating to the forming material is sufficient if the temperature reaches a temperature range where the Al—Mg alloy does not reach the O material. Therefore, not only heating in the warm forming apparatus, but also heating in advance by using induction heating or hot press, the heating time in the forming apparatus is shortened, and the working time of the forming process is reduced. It can be shortened.

そして、第1及び第2の特徴を踏まえて、第3の特徴として、上記成形素材におけるMgの含有量を3〜10mass%とするものである。   And based on the 1st and 2nd characteristics, content of Mg in the said shaping | molding raw material shall be 3-10 mass% as a 3rd characteristic.

以上のように、成形素材であるAl−Mg合金中のMgの含有量を3〜10mass%とすることで、強度を十分に確保した成形加工品を得ることができる。なお、成形素材中に含有するMgの含有量が3mass%未満であると成形加工品の強度を十分に確保することができない。またMgの含有量が10mass%を超えると、成形素材中でのMgの偏析により鋳造割れが発生して造塊が困難となって成形素材とすることができない。   As described above, when the content of Mg in the Al—Mg alloy, which is a molding material, is 3 to 10 mass%, a molded product with sufficient strength can be obtained. If the content of Mg contained in the molding material is less than 3 mass%, the strength of the molded product cannot be sufficiently ensured. On the other hand, if the Mg content exceeds 10 mass%, casting cracks occur due to segregation of Mg in the molding material, and ingot formation becomes difficult, making it impossible to obtain a molding material.

ところで、前記成形素材であるAl−Mg合金に対する調質も、成形加工品の強度を十分に確保するため、加工硬化の場合ならばH14、H16又はH18、加工硬化後に適度に軟化処理する場合ならばH24、H26又はH28、及び加工硬化後安定化処理する場合ならばH34、H36又はH38とすることが好ましい。   By the way, the tempering for the Al—Mg alloy as the molding material is also H14, H16 or H18 in the case of work hardening in order to sufficiently secure the strength of the molded product, and in the case of moderate softening after work hardening. For example, H24, H26 or H28, and H34, H36 or H38 in the case of stabilizing after work hardening are preferable.

本願発明は、成形素材に高強度のAl合金を使用して、温間成形加工による変形や強度の低下を防止するとともに、複雑な形状や深い絞り成形加工を可能にすることができるとともに、その成形加工品は変形のない高い強度を有するものとすることができる優れた効果を有する。   The present invention uses a high-strength Al alloy as a molding material to prevent deformation and a decrease in strength due to warm forming, as well as enable complex shapes and deep drawing, The molded product has an excellent effect that it can have a high strength without deformation.

以下において、本願発明の実施例について説明する。
なお、この実施例は、本願発明の好ましい一実施態様を説明するためのものであって、これにより本願発明が制限されるものでない。
Examples of the present invention will be described below.
In addition, this Example is for demonstrating one preferable embodiment of this invention, Comprising: This invention is not restrict | limited by this.

そこで、実施例として本願発明の温間成形加工方法に基づいて成形加工品8の製造を行った。ここで、本願発明の温間成形加工方法を実施する温間成形加工装置1は、図1で示すように、ヒーター5を内蔵するしわ押さえ3の上方にヒーター5を内蔵するダイス2を当接自在に配置するとともに、前記ダイス2としわ押さえ3とが当接して挟持する成形素材であるAl−Mg合金板6に対して所定形状に成形加工するヒーター5を内蔵するポンチ4をダイス2及びしわ押さえ3の内で下方より上下方向に移動自在に配設してなるものである。ここで、前記温間成形加工装置1ではしわ押さえ3の上方にダイス2を配置するものであるが、ダイス2の上方にしわ押さえ3を配置するものであってもよい。また、ポンチ4は下方から上下方向に移動自在となるように配設されているが、逆に上方から上下方向に移動自在となるものであってもよい。更に、ダイス2及びしわ押さえ3により挟持する成形素材のAl−Mg合金板6に対してポンチ4が移動自在となるが、逆にポンチ4に対してダイス2及びしわ押さえ3により挟持する成形素材のAl−Mg合金板6が移動自在となるものであってもよい。   Therefore, as an example, the molded product 8 was manufactured based on the warm molding method of the present invention. Here, as shown in FIG. 1, the warm forming apparatus 1 that performs the warm forming method of the present invention abuts the die 2 containing the heater 5 above the wrinkle presser 3 containing the heater 5. A punch 4 that includes a heater 5 that is molded into a predetermined shape with respect to an Al-Mg alloy plate 6 that is a molding material that is placed between the die 2 and the wrinkle presser 3 in contact with the die 2 and the die 2 and The wrinkle presser 3 is arranged so as to be movable in the vertical direction from below. Here, although the die 2 is disposed above the wrinkle retainer 3 in the warm forming apparatus 1, the wrinkle retainer 3 may be disposed above the die 2. The punch 4 is arranged so as to be movable in the vertical direction from below, but may be movable in the vertical direction from above. Further, the punch 4 is movable with respect to the Al—Mg alloy plate 6 of the molding material sandwiched by the die 2 and the wrinkle presser 3, but conversely, the molding material sandwiched by the die 2 and the wrinkle presser 3 with respect to the punch 4. The Al—Mg alloy plate 6 may be movable.

なお、前記成形加工品8の取り出しを円滑かつ確実に行えるようにするためには、温間成形加工装置1のダイス2、しわ押さえ3及びポンチ4の表面を平滑することが必要となる。そのため、該ダイス2、しわ押さえ3及びポンチ4の表面に対して、耐熱性及び潤滑性を有するクロムメッキ、窒化処理又はDLC(ダイヤモンドライクカーボン)処理等の表面処理を施すことが好ましい。   In addition, in order to be able to take out the molded product 8 smoothly and reliably, it is necessary to smooth the surfaces of the die 2, the wrinkle presser 3 and the punch 4 of the warm forming apparatus 1. Therefore, it is preferable to perform surface treatment such as chromium plating, nitriding treatment or DLC (diamond-like carbon) treatment having heat resistance and lubricity on the surfaces of the die 2, the wrinkle presser 3 and the punch 4.

そして、上記成形素材のAl−Mg合金板6には、厚さ0.8mmのJIS 5182−H18(Mg:4.5mass%)を使用し、高さ50mm×幅60mm×長さ80mmの角筒形状の絞り成形加工品8を製造した。   The Al-Mg alloy plate 6 of the molding material is JIS 5182-H18 (Mg: 4.5 mass%) having a thickness of 0.8 mm, and is a square tube having a height of 50 mm, a width of 60 mm, and a length of 80 mm. A drawn molded article 8 having a shape was manufactured.

即ち、上記温間成形加工装置1内で、
まず、互いに離隔しているダイス2としわ押さえ3間において〔図2(イ)参照〕、該ダイス2との間に空隙7を有しながら上記Al−Mg合金板6をしわ押さえ3上に載置した〔図2(ロ)参照〕。
次に、該温間成形加工装置1を構成する該ダイス2、しわ押さえ3、及びポンチ4を内蔵するヒーター5により200〜300℃まで加熱するとともに、該Al−Mg合金板6は270±20℃の温度域まで加熱した。
その後、前記Al−Mg合金板6をダイス2としわ押さえ3により挟持した。その結果ダイス2としわ押さえ3、及び該ダイス2としわ押さえ3により挟持されるAl−Mg合金板6の温度分布は均一となった。
その上で、上記ダイス2としわ押さえ3により挟持されたAl−Mg合金板6に対してポンチ4を上方に移動させることで成形し〔図2(ハ)参照〕、変形のない所定形状の成形加工品8が得られた〔図2(ニ)参照〕。
なお、上記温間成形加工方法において、温間成形加工装置1内の加熱開始から成形加工品8の取り出しまでの時間は30秒以内であった。
That is, in the warm forming apparatus 1,
First, between the dice 2 and the wrinkle presser 3 that are spaced apart from each other (see FIG. 2A), the Al-Mg alloy plate 6 is placed on the wrinkle presser 3 while having a gap 7 between the die 2 and the wrinkle presser 3. It was mounted (see FIG. 2 (B)).
Next, while heating to 200-300 degreeC with the heater 5 which contains this die | dye 2, the wrinkle presser 3, and the punch 4 which comprise this warm forming apparatus 1, this Al-Mg alloy plate 6 is 270 +/- 20. Heated to a temperature range of ° C.
Thereafter, the Al—Mg alloy plate 6 was sandwiched between the die 2 and the wrinkle presser 3. As a result, the temperature distribution of the die 2 and the wrinkle retainer 3 and the Al—Mg alloy plate 6 sandwiched between the die 2 and the wrinkle retainer 3 became uniform.
Thereafter, the punch 4 is moved upward with respect to the Al-Mg alloy plate 6 sandwiched between the die 2 and the wrinkle presser 3 (see FIG. 2 (c)), and a predetermined shape without deformation is formed. A molded product 8 was obtained [see FIG. 2 (d)].
In the warm molding method, the time from the start of heating in the warm molding apparatus 1 to the removal of the molded product 8 was within 30 seconds.

そこで、本願発明の温間成形加工方法により得られた上記成形加工品8に対して、JISに規定する引張試験を行い耐力を測定した。その結果、該成形加工品8の耐力は250〜300N/mmであって、成形加工前のAl−Mg合金板6の耐力と比較しても耐力の低下は10%以内に収めることができた。 Therefore, a tensile test specified in JIS was performed on the molded product 8 obtained by the warm molding method of the present invention, and the yield strength was measured. As a result, the yield strength of the molded product 8 is 250 to 300 N / mm 2 , and the decrease in the yield strength can be kept within 10% even when compared to the yield strength of the Al—Mg alloy plate 6 before the molding process. It was.

一方、上記実施例と同形状の絞り成形加工品を、冷間成形加工により製造しようとすると、成形素材であるAl合金の材料、調質は1100−H24或いは5052−H32が限界となる。
そこで、本願発明の実施例に対する比較例として成形素材のAl合金板に1050−H24及び5052−H32を使用して、本願発明の温間成形加工方法に基づいて上記実施例と同形状の絞り高さ50mmの成形加工品を製造した。その結果、成形加工品の耐力は、1050−H24では100N/mm、5052−H32では150N/mmとなって強度は低く、成形加工前の成形素材との耐力の比較においても著しく低下することが確認された。
On the other hand, when a drawn product having the same shape as the above embodiment is manufactured by cold forming, 1100-H24 or 5052-H32 is the limit for the material and tempering of the Al alloy as the forming material.
Therefore, as a comparative example with respect to the embodiment of the present invention, 1050-H24 and 5052-H32 are used for the Al alloy plate of the forming material, and the drawing height of the same shape as the above embodiment is based on the warm forming method of the present invention. A molded product having a thickness of 50 mm was produced. As a result, strength of the molded article, the strength becomes 1050-H24 in 100N / mm 2, 5052-H32 in 150 N / mm 2 is low, significantly reduced even in comparison with strength of the molding material before molding It was confirmed.

従って、本願発明の温間成形加工方法により製造される成形加工品8において、成形素材に1050−H24及び5052−H32のAl合金板を使用して温間成形加工して製造した成形加工品と同一の強度を確保できれば足りるとすると、本願発明では成形素材のAl−Mg合金板6の板厚を2/3〜1/2程度まで薄くすることができる。その結果本願発明の成形加工品8は軽量化が可能になるとともに、製造コストの削減を図ることができるものとなる。   Therefore, in the molded product 8 produced by the warm molding method of the present invention, a molded product produced by warm molding using 1050-H24 and 5052-H32 Al alloy plates as the molding material, and If it is sufficient if the same strength can be ensured, in the present invention, the thickness of the Al—Mg alloy plate 6 as a forming material can be reduced to about 2/3 to 1/2. As a result, the molded product 8 of the present invention can be reduced in weight, and the manufacturing cost can be reduced.

本願発明は、高強度のAl−Mg合金を使用する温間成形加工において広く適用することができる。   The present invention can be widely applied in warm forming using a high-strength Al—Mg alloy.

本願発明の温間成形加工方法に供する温間成形加工装置の構成を示す模式図である。It is a schematic diagram which shows the structure of the warm forming apparatus provided to the warm forming method of this invention. 本願発明の温間成形加工方法による成形加工品の製造工程を示した模式図である。It is the schematic diagram which showed the manufacturing process of the molded product by the warm forming method of this invention.

符号の説明Explanation of symbols

1 温間成形加工装置
2 ダイス
3 しわ押さえ
4 ポンチ
5 ヒーター
6 Al−Mg合金板
7 空隙
8 成形加工品
DESCRIPTION OF SYMBOLS 1 Warm forming apparatus 2 Dice 3 Wrinkle holding | suppressing 4 Punch 5 Heater 6 Al-Mg alloy board 7 Cavity 8 Molding processed goods

Claims (4)

互いに当接自在となりヒーターを内蔵するダイス、しわ押さえ及びポンチを具備する温間成形加工装置において、
温間成形加工装置の互いに離隔しているダイスとしわ押さえ間において、一方のダイス又はしわ押さえとの間に空隙を有しながら、他方のしわ押さえ又はダイス上にAl−Mg合金の成形素材を載置する工程と、
該温間成形加工装置内を加熱することで成形素材をO材に至らない180〜350℃の温度域まで加熱する工程と、
該成形素材をダイスとしわ押さえにより挟持する工程と、
上記ダイスとしわ押さえにより挟持された成形素材をポンチによって成形してなる工程と
からなることを特徴とする温間成形加工方法。
In a warm forming apparatus equipped with a die, a wrinkle presser and a punch that can come into contact with each other and have a built-in heater,
Between the dice and the crease presser that are separated from each other in the warm forming processing device, while having a gap between the dies and the crease presser, a molding material of Al-Mg alloy is formed on the other crease presser or die. A process of placing;
A step of heating the molding material to a temperature range of 180 to 350 ° C. that does not reach O material by heating the inside of the warm molding processing apparatus;
Sandwiching the molding material with a die and a crease press;
A warm forming method comprising: forming a molding material sandwiched between the die and the wrinkle press with a punch.
上記温間成形加工装置内の加熱開始から成形加工品の取り出しまでの時間を2〜30秒とすることを特徴とする請求項1記載の温間成形加工方法。 2. The warm forming method according to claim 1, wherein the time from the start of heating in the warm forming apparatus to the removal of the formed product is 2 to 30 seconds. 上記成形素材におけるMgの含有量を3〜10mass%とすることを特徴とする請求項1又は2記載の温間成形加工方法。 The warm forming method according to claim 1 or 2, wherein the content of Mg in the molding material is 3 to 10 mass%. 上記請求項1乃至3記載の温間成形加工方法により製造されることを特徴とする成形加工品。 A molded article manufactured by the warm molding method according to any one of claims 1 to 3.
JP2007176911A 2007-07-05 2007-07-05 Warm forming method and molded product produced by the warm forming method Expired - Fee Related JP5266676B2 (en)

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JP2016112606A (en) * 2014-12-17 2016-06-23 新日鐵住金株式会社 Warm molding method

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