JP2009001630A5 - - Google Patents

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JP2009001630A5
JP2009001630A5 JP2007162319A JP2007162319A JP2009001630A5 JP 2009001630 A5 JP2009001630 A5 JP 2009001630A5 JP 2007162319 A JP2007162319 A JP 2007162319A JP 2007162319 A JP2007162319 A JP 2007162319A JP 2009001630 A5 JP2009001630 A5 JP 2009001630A5
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formula
optionally substituted
hydrocarbon group
integer
shows
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(式(2)中、R1は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、nは5以上、600以下のいずれかの整数を示す。) (In formula (2), R 1, a optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon group indicates, n represents 5 or more, 600 or less of any integer the shows be.)

(式(3)中、R2は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、mは5以上、600以下のいずれかの整数を示す。)
Yは式(2)、式(3)、又は式(4)を示す。
(In the formula (3), R 2 is an optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon group indicates, m is 5 or more, 600 or less of any integer the shows be.)
Y represents Formula (2), Formula (3), or Formula (4).

(式(5)、R1は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、nは5以上、600以下のいずれかの整数を示す。) (Formula (5), R 1 is, indicates an optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon radical, n is 5 or more, 600 one of the following integer It shows you.)

(式(6)中、R2は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、mは5以上、600以下のいずれかの整数を示す。)に関する。 (In the formula (6), R 2 is a optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon group indicates, m is 5 or more, 600 or less of any integer the shows be.) about.

式(2)中のn、式(3)中のmは重合度を示し、それぞれ5以上600以下のいずれかの整数を示す。このような重合度を有するポリエステルブロックセグメント又はポリアミドブロックセグメントにより、式(1)で表される高分子化合物に、優れた機械特性、化学的特性、加工特性を付与することができる。 N in formula (2), the m in formula (3) indicates the degree of polymerization, shows the integer of 5 or more and 600 or less, respectively. The polyester block segments or polyamide block segment having a degree of polymerization such as this, the polymer compound represented by formula (1) can be excellent mechanical properties, chemical properties, processing properties imparting.

このような重縮合工程において得られる式(5)で表されるポリエステルの重合度、nは5以上600以下である。分子量としては、1,1,1,3,3,3−ヘキサフルオロ−2−プロパノール(HFIP)に溶解させたゲル浸透クロマトグラフィー(GPC)法による分子量測定で、ピークトップ分子量が1000〜140000を挙げることができる。 The degree of polymerization of the polyester represented by the obtained equation in such a polycondensation step (5), n is 5 or more and 600 or less. The molecular weight was measured by gel permeation chromatography (GPC) dissolved in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), and the peak top molecular weight was 1000 to 140000. Can be mentioned.

このような重縮合工程において得られる式(6)で表されるポリアミドの重合度、mは5以上600以下である。分子量としては、1,1,1,3,3,3−ヘキサフルオロ−2−プロパノール(HFIP)に溶解させたゲル浸透クロマトグラフィー(GPC)法による分子量測定で、ピークトップ分子量が1000〜140000を挙げることができる。 Polymerization degree of the polyamide represented by the obtained equation in such a polycondensation step (6), m is 5 or more and 600 or less. The molecular weight was measured by gel permeation chromatography (GPC) dissolved in 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP), and the peak top molecular weight was 1000 to 140000. Can be mentioned.

Claims (5)

式(1)で表される高分子化合物。
Figure 2009001630
[式中、Xは式(2)又は式(3)を示し、
Figure 2009001630
(式(2)中、R1は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、nは5以上、600以下のいずれかの整数を示す。)
Figure 2009001630
(式(3)中、R2は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、mは5以上、600以下のいずれかの整数を示す。)
Yは式(2)、式(3)、又は式(4)を示す。
Figure 2009001630
(式(4)中、ZはYを示す。)]
The high molecular compound represented by Formula (1).
Figure 2009001630
[Wherein X represents formula (2) or formula (3);
Figure 2009001630
(In the formula (2), R 1 is an optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon group indicates, n represents 5 or more, 600 or less of any integer the shows be.)
Figure 2009001630
(In the formula (3), R 2 is an optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon group indicates, m is 5 or more, 600 or less of any integer the shows be.)
Y represents formula (2), formula (3), or formula (4).
Figure 2009001630
(In formula (4), Z represents Y.)]
式(2)中、R1がn−ブチレン基を示すことを特徴とする請求項1記載の高分子化合物。 The polymer compound according to claim 1 , wherein R 1 in the formula (2) represents an n-butylene group. 請求項1又は2記載の高分子化合物の製造方法であって、式(5)で表されるポリエステル又は式(6)で表されるポリアミドを溶融し、オルガノアルコキシシラン又はオルガノアルコキシシランの加水分解物を加えて反応させることを特徴とする高分子化合物の製造方法。
Figure 2009001630
(式(5)、R1は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、nは5以上、600以下のいずれかの整数を示す。)
Figure 2009001630
(式(6)中、R2は、置換されていてもよい芳香族炭化水素基又は置換されていてもよい脂肪族炭化水素基を示し、mは5以上、600以下のいずれかの整数を示す。)
It is a manufacturing method of the high molecular compound of Claim 1 or 2, Comprising: The polyester represented by Formula (5) or the polyamide represented by Formula (6) is melted, and hydrolysis of organoalkoxysilane or organoalkoxysilane is carried out. A method for producing a polymer compound, which comprises reacting a product.
Figure 2009001630
(Formula (5), R 1 is, indicates an optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon radical, n is 5 or more, 600 one of the following integer It shows you.)
Figure 2009001630
(In the formula (6), R 2 is a optionally substituted aromatic hydrocarbon group or an optionally substituted aliphatic hydrocarbon group indicates, m is 5 or more, 600 or less of any integer the shows be.)
式(5)中、R1がn−ブチレン基を示す化合物を用いることを特徴とする請求項3記載の高分子化合物の製造方法。 The method for producing a polymer compound according to claim 3, wherein a compound in which R 1 represents an n-butylene group in formula (5) is used. 請求項1又は2記載の高分子化合物を含む成形品用組成物。   A composition for a molded article comprising the polymer compound according to claim 1.
JP2007162319A 2007-06-20 2007-06-20 Polymeric compound and its manufacturing method, and molded product composition Pending JP2009001630A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007162319A JP2009001630A (en) 2007-06-20 2007-06-20 Polymeric compound and its manufacturing method, and molded product composition

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Application Number Priority Date Filing Date Title
JP2007162319A JP2009001630A (en) 2007-06-20 2007-06-20 Polymeric compound and its manufacturing method, and molded product composition

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JP2009001630A JP2009001630A (en) 2009-01-08
JP2009001630A5 true JP2009001630A5 (en) 2010-08-05

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2002382C2 (en) 2008-12-30 2010-07-01 Furanix Technologies Bv A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and such (co)polymers.
JP5356055B2 (en) * 2009-02-05 2013-12-04 日産自動車株式会社 Rolling sliding member
JP5812791B2 (en) * 2011-03-28 2015-11-17 キヤノン株式会社 Printer, copier
JP2013006963A (en) * 2011-06-24 2013-01-10 Unitika Ltd Polyamide and molded article thereof
JP5955205B2 (en) * 2012-01-23 2016-07-20 キヤノン株式会社 Chemical sealing film
WO2013149180A1 (en) * 2012-03-30 2013-10-03 E. I. Du Pont De Nemours And Company Furan based polyamides
WO2014205358A1 (en) * 2013-06-21 2014-12-24 Bret Ja Chisholm Polyamide copolymers having 2,5-furan dicarboxamide units
JP6149793B2 (en) * 2014-04-25 2017-06-21 株式会社デンソー Molded products using polyamide compounds
BR112017022224B1 (en) 2015-04-14 2022-05-03 E I Du Pont De Nemours Integrated process to produce 2,5-furanedicarboxylic acid and/or a derivative thereof

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DE3008138A1 (en) * 1980-03-04 1981-09-10 Wacker-Chemie GmbH, 8000 München METHOD FOR PRODUCING SILICONE MODIFIED RESINS
CH697009A5 (en) * 2004-07-08 2008-03-14 Zeev Ofer Crystallized polyethylene terephthalate, which contains silicon, and process for its preparation.
JP4881127B2 (en) * 2005-11-07 2012-02-22 キヤノン株式会社 Polymer compound and synthesis method thereof

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