JP2009000060A - Acidic oil-in-water emulsified food - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide an acidic oil-in-water emulsified food having a stably emulsified condition even after thawed and excellent in freezing resistance. <P>SOLUTION: The acidic oil-in-water emulsified food is obtained by blending dried albumen, chemically-modified starch and/or treated starch composed of moist heat-treated starch, preferably etherified starch, and subjecting the dried albumen to desugaring treatment and heat storage treatment at ≥65°C preferably ≥68°C. The syneresis ratio of heat-coagulated material in dried-albumen aqueous solution (7 pts.mass of pure water based on 1 pt.mass of the dried albumen) is ≤4 wt.%, preferably ≤3.3 wt.%. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

The present invention relates to an acidic oil-in-water emulsified food having a stable emulsified state after thawing and excellent in freezing resistance.

Acidic oil-in-water emulsified foods such as mayonnaise and semi-solid emulsified dressings are a type of seasoning that is widely used in everyday eating habits. As a representative food using the emulsified food, there is a salad, but in recent years its use has been expanded, and it is also used in fields such as confectionery, bread making, and frozen food. Also, in the field of prepared foods, some prepared foods using the emulsified food are stored frozen and then thawed or warmed. What is frozen in this way is desired to be in a good state after thawing, and the emulsified food preferably has a stable emulsified state after thawing.

As the acidic oil-in-water emulsified food having freeze resistance, for example, Japanese Patent Application Laid-Open No. 61-141861 (Patent Document 1) proposes an emulsified food obtained by blending dried egg white and heat-treating it. As dry egg white that is widely distributed for food use, the raw liquid egg white is adjusted to a pH (weak acidity) optimal for desugaring treatment, then desugared and spray-dried, and the resulting neutral drying is obtained. For example, there is a product name “dried egg white K type” manufactured by QP Corporation.

Then, this inventor manufactured acidic oil-in-water type emulsified food using the said commercially available dried egg white, and tested whether the said product had freezing tolerance. However, it was difficult to say that the obtained emulsified food has freezing resistance.

JP-A-61-141861

Therefore, an object of the present invention is to provide an acidic oil-in-water emulsified food that has a stable emulsified state even after thawing and has excellent freezing resistance.

The present inventors have intensively studied various compounding raw materials that can be used for acidic oil-in-water type emulsified foods. As a result, if the processed starch and a specific dried egg white are blended, the present invention has been found to be an acidic oil-in-water emulsified food that has a surprisingly stable emulsified state even after thawing and has excellent freezing resistance. It came to do.

That is, the present invention
(1) Dry egg white is blended with modified starch and / or treated starch that is heat-moisture-treated starch, the dried egg white is desugared and heat-treated at 65 ° C. or higher, and a dried egg white aqueous solution (dried Acidic oil-in-water emulsified food with a water separation rate of 4% or less of heated coagulated product of 1 part of egg white and 7 parts of fresh water,
(2) The acidic oil-in-water emulsified food according to (1), wherein the dried egg white is heat-treated at 68 ° C. or higher,
(3) The acid oil-in-water emulsified food according to (1) or (2), wherein the dried egg white has a water separation rate of 3.3% or less,
(4) The acidic oil-in-water emulsion food according to any one of (1) to (3), wherein the treated starch is an etherified starch,
(5) The acidic oil-in-water emulsified food according to any one of (1) to (4), wherein the blended amount of dried egg white is 0.1 to 10% of the product,
(6) The acidic oil-in-water emulsified food according to any one of (1) to (5), wherein the compounding amount of the treated starch is 0.3 to 8% of the product,
It is.

According to the present invention, since an acidic oil-in-water emulsified food having a stable emulsified state even after thawing can be provided, an increase in demand for acidic oil-in-water emulsified foods to food accompanied by freezing is expected.

The present invention will be described in detail below. In the present invention, “%” means “mass%” and “part” means “part by mass”.

In the present invention, the acidic oil-in-water emulsified food means that edible fats and oils are dispersed almost uniformly in the water phase as oil droplets to maintain the oil-in-water emulsified state, and the pH is 4. It is an acidic emulsified food with a viscosity adjusted to 6 or less and a viscosity of 30 Pa · s or more. Such acidic oil-in-water emulsified foods are generally referred to as mayonnaise, mayonnaise or semi-solid emulsified dressing.

In the acidic oil-in-water emulsified food according to the present invention, the dried egg white is mixed with a modified starch and / or a processed starch that is a heat-moisture-treated starch, and the dried egg white is subjected to a desugaring treatment and a heat storage treatment at 65 ° C. or higher. And the water separation rate of the heated coagulum of the dried egg white aqueous solution (7 parts of fresh water relative to 1 part of dried egg white) is 4% or less, thereby having a stable emulsified state even after thawing. An acidic oil-in-water emulsified food with excellent freezing resistance.

Here, the dried egg white is a liquid egg white dried by any drying method such as spray drying (spray drying), stationary drying (pan drying), freeze drying (freeze drying), etc., and then subjected to heat storage treatment. It has been applied. According to the present invention, the dried egg white is further subjected to a heat storage treatment at 65 ° C. or higher, preferably 68 ° C. or higher, more preferably 70 ° C. or higher, and 1 part of the obtained dried egg white is added to 7 parts of fresh water. The water separation rate is 4% or less, preferably 3.3% or less, more preferably 3.0% or less, when the thermocoagulated product of the dissolved dried egg white aqueous solution is measured by the method described later.

If the heat storage treatment is not performed or the heat storage treatment is lower than the above temperature, even if the water separation rate condition is satisfied and the treated starch described later is used in combination, the acidic oil-in-water type as shown in the test example described later The emulsified food tends to have a stable emulsified state in which oil separation is observed in the state after thawing. On the other hand, if the water separation rate is higher than the above value, even if the heat storage treatment conditions are satisfied and the treated starch described later is used in combination, oil separation after thawing is observed and it is difficult to have a stable emulsified state, which is not preferable. Because.

The water separation rate is a value measured by the following procedure. That is, 7 parts of fresh water is added to 1 part of dried egg white and dissolved, filled and sealed in a nylon casing having a folding diameter of 60 mm, and heated at 80 ° C. for 40 minutes to produce a heated coagulum. Next, after the casing-packed heated coagulum is stored at 5 ° C. for 24 hours, it is allowed to stand at room temperature (20 ° C.) for 3 hours to bring the temperature of the heated coagulated product to 20 ° C. Next, the heated coagulum is taken out of the casing and cut into a thickness of 3 cm perpendicular to the length direction. Next, the heated coagulated material cut on 5 sheets of 110 mm diameter filter paper (qualitative filter paper No. 2) was placed so that one of the cut surfaces became the bottom surface, and then room temperature (20 ° C. for 1 hour). The water separation rate was determined from the following formula from the change in mass of the heated coagulated product before and after leaving.

Water separation rate (%) = (mass of heated coagulated product before standing-mass of heated coagulated product after standing) × 100 / (mass of heated coagulated product before standing)

The method for producing dried egg white that satisfies the conditions for the heat storage treatment and the water separation rate will be described in detail below. The dried egg white of the present invention may be any as long as it satisfies the above two conditions, and is not limited to the following method.

First, liquid egg white used for dry egg white is prepared. As the liquid egg white, for example, a raw liquid egg white obtained by splitting the egg and separating it from the yolk, a thing subjected to processing such as filtration, sterilization, freezing, concentration, etc., as well as a process for removing components in the egg white, for example, Examples include those subjected to a desugaring process for removing sugar and a process for removing lysozyme, but among these liquid egg whites, it is important to use liquid egg whites subjected to desugaring process. If the desugaring process is not performed, the amino group in egg white protein and free sugar cause a Maillard reaction during the heat storage process, resulting in deterioration of quality such as browning and unpleasant odor. This is because oil separation is observed after thawing, and even if it is obtained, an acidic oil-in-water emulsified food excellent in freezing resistance as the object of the present invention cannot be obtained. The desugaring treatment may be performed by a conventional method using yeast, enzyme, bacteria, etc., and is preferably performed so that the free sugar content in the liquid egg white is preferably 0.1% or less.

In general, when liquid egg white is desugared by methods such as yeast desugaring and enzymatic desugaring, the appropriate pH of these yeasts and enzymes is weakly acidic to neutral, and an acid agent such as an organic acid is added. Since the pH of the liquid egg white is changed from weakly acidic to neutral, the resulting dried egg white also has a pH of around 7. However, the water separation rate of the obtained dried egg white exceeds 4%, and the acidic oil-in-water emulsified food using the dried egg white is not preferable because oil separation is observed after thawing.

On the other hand, in order to set the water separation rate of dried egg white to 4% or less, for example, an acid agent such as an organic acid is not added during the desugaring treatment, or the addition is suppressed to a very small amount, and spray drying is performed. The pH after the drying treatment is 9 or more, preferably 9.5 or more, more preferably 10 or more. Specifically, depending on the pH of the liquid egg white to be used and the drying method, a liquid having a pH of about 9.9 to 10.1 is obtained when the yeast is desugared without adding an acid agent such as an organic acid. A dried egg white can be obtained. Further, in the present invention, it is preferable not to add an acid agent such as an organic acid because a higher pH after the drying treatment tends to obtain a lower water separation rate. However, for the purpose of increasing the desugaring treatment efficiency, it is preferable. For example, when an organic acid such as citric acid is used as the acid agent, the amount of organic acid added at the time of desugaring is 1000 mg or less, preferably 500 mg or less, more preferably 200 mg or less, and still more preferably, with respect to 1 kg of liquid egg white. 100 mg or less.

There is a tendency that the pH after the desugaring treatment is somewhat lower than the pH of the liquid egg white before the desugaring treatment. For example, depending on the pH of the liquid egg white before the desugaring treatment, the pH is reduced by about 0.1 to 2.5 when the desugaring treatment is performed with yeast. On the other hand, compared with the pH of the liquid egg white before the drying process, which is the liquid egg white after the desugaring process, the pH after the drying process tends to slightly increase. For example, although it depends on the drying conditions, when it is dried with hot air of 150 to 200 ° C., which is a normal spray drying condition, the pH increases by about 1 to 3. Therefore, in consideration of these, the pH of the dried liquid egg white after the drying treatment may be adjusted to the above range.

In addition, in order to adjust the pH of the dried liquid egg white product to the specific range, a small amount of an alkaline agent such as trisodium phosphate may be added. Since so-called boiled food that is heat-denatured and insolubilized is likely to occur, it is necessary to carry out fine adjustment so as not to generate boiled food. The following is preferred.

The drying treatment is not particularly limited. For example, the moisture content of the dried product is preferably 12% or less by various methods such as spray drying (spray drying), stationary drying (pan drying), freeze drying (freeze drying), and the like. More preferably, it may be carried out in accordance with an ordinary method so as to be 10% or less.

In the case of a liquid product such as liquid egg white, the pH is as it is, and in the case of a dry product, 7 parts of fresh water added to 1 part of the dried product and dissolved are measured with a pH meter. Value. The moisture content of the dried product is a value measured by an infrared moisture meter (Kett Science Laboratory, FD-600).

Next, the dried egg white product is subjected to a heat storage treatment at 65 ° C. or higher, preferably 68 ° C. or higher, more preferably 70 ° C. or higher. The dried liquid egg white obtained by the above method satisfies the condition of a water separation rate of 4% or less. However, if the heat storage treatment is not performed or the heat storage treatment is lower than the above temperature, the condition of the water separation rate is satisfied. Satisfactory, even if the treated starch described later is used in combination, as shown in the test examples described later, the acidic oil-in-water emulsified food is preferably less likely to have a stable emulsified state because oil separation is observed in the state after thawing. Because there is no. Moreover, although it depends on the method of heat storage treatment described later, the water separation rate is further reduced by about 0.1 to 1 depending on the heat storage treatment conditions.

As a method of heat storage treatment, a dried liquid egg white product was enclosed in a container, or the dried product was spread on a flat container such as a bat to a thickness of about 1 mm to 10 cm, and this was set to the predetermined temperature. It is good to store it in a thermostat, dryer, heat storage, etc. In particular, the method of performing the thermal storage treatment while removing carbon dioxide further reduces the water separation rate, the water separation rate of the obtained dried egg white becomes 3% or less, and the acidic oil-in-water emulsified food using the dried egg white is It is preferable because of its excellent freezing resistance. Specifically, the concentration of carbon dioxide in the dried egg white is preferably 1% or less, more preferably 0.8% or less.

The concentration of carbon dioxide in the dried egg white is determined by sealing 25 g of dried egg white in a 250 mL vial and storing it in a thermostat at 75 ° C. for 24 hours, and then removing it from the thermostat within 1 minute. This is a value obtained by measuring the carbon dioxide concentration with a carbon dioxide concentration meter (Check Point O ₂ / CO ₂ manufactured by PBI-Dansensor).

As a method of performing the heat storage treatment while removing carbon dioxide, for example, in the case of spreading a liquid egg white dried product in a container such as a vat and storing it, 1) a constant temperature oven and a dryer in which heated air is ventilated Store in a heat storage. 2) A thermostat having carbon dioxide permeability, such as a pouch made of a polyethylene film having a thickness of preferably 20 to 80 μm, more preferably 30 to 70 μm, and a heated air ventilated. Store in a dryer or heat storage. 3) The dried product is sealed in a container together with a carbon dioxide absorbent, specifically, a carbon dioxide absorbent having an absorption capacity of 200 to 600 mL with respect to 1 kg of dried product, and subjected to heat storage treatment. Or the method of combining said 2) and 3) etc. are mentioned.

In the present invention, only the lower limit of the temperature of the heat storage treatment is specified, but if the heat storage temperature is too high, boiling may occur, and it is preferably 100 ° C. or less, more preferably 90 ° C. or less. Moreover, although the process days of a heat storage process are not prescribed | regulated, Preferably it is 1-30 days, More preferably, it is 2-20 days. When the number of days for the heat storage treatment is shorter than the above range, the effect of the heat storage treatment is not expressed, and oil separation is observed in the state after thawing, while when it is longer than the above range, not only the productivity is inferior, This is because the effects of the brewing process tend to be difficult to express any more.

The amount of the dried egg white mentioned above is preferably 0.1 to 10%, preferably 0.5 to 8% based on the product, although it depends on the amount of the modified starch and / or the heat-treated starch, which will be described later. More preferred. If the blending amount is less than the above range, oil separation is observed in the state after thawing even if the processed starch described later is used in combination, and it tends to be difficult to have a stable emulsified state. This is because it is difficult to obtain an emulsified food having a good texture.

The acidic oil-in-water emulsified food of the present invention is a blend of processed starch that is a modified starch and / or a wet heat-treated starch in addition to the above-described dried egg white. The treated starch is obtained by subjecting raw raw starch to some kind of treatment. Among the modified starches that are modified starch and / or wet-heat treated starch, modified starch is a starch that is used as a thickener that has been subjected to chemical treatment and is particularly limited as long as it is used for food. is not. For example, acetylated adipic acid cross-linked starch that is esterified by allowing acetic anhydride and adipic anhydride to act on starch, and esterifying by reacting starch with phosphorus oxychloride or sodium trimetaphosphate and then acetic anhydride or vinyl acetate. Cross-linked acetylated phosphate starch, acetylated oxidized starch that is esterified with sodium hypochlorite and acetic anhydride on starch, octenyl succinic acid starch sodium that is esterified with octenyl succinic anhydride on starch, acetic anhydride on starch Or starch acetate that is esterified by the action of vinyl acetate, oxidized starch that acts sodium hypochlorite on starch, hydroxypropyl starch that is etherified by acting propylene oxide on starch, or etherified by acting propylene oxide on starch In addition, phosphorus oxychloride or tri Hydroxypropylated phosphate cross-linked starch that reacts with sodium taphosphate and esterifies starch by reacting phosphorus oxychloride or sodium trimetaphosphate with starch, and then reacts with orthophosphoric acid or its potassium salt, sodium salt, sodium tripolyphosphate Phosphoric acid monoesterified phosphate cross-linked starch, phosphoric acid starch that is esterified with orthophosphoric acid or its potassium salt, sodium salt, sodium tripolyphosphate acting on starch, starch phosphochloride or sodium trimetaphosphate acting on starch And phosphoric acid cross-linked starch.

Further, the wet heat-treated starch used in the present invention is not particularly limited as long as it is commercially available as “wet heat-treated starch”. For example, starch particles containing water that does not gelatinize even when the starch is heated. Is obtained by heating to about 100-125 ° C. in a sealed container at a relative humidity of 100%, or starch is placed in the container in the first stage, sealed and decompressed, and the raw steam is stored in the second stage. It is manufactured by a reduced pressure and heating method, which is a system for introducing and humidifying and heating.

In the present invention, it is preferable to use one or two or more kinds of these treated starches. Among them, when an etherified starch such as hydroxypropyl starch or hydroxypropylated phosphoric acid crosslinked starch is used, it is used in combination with the above-mentioned dried egg white. Thus, an acidic oil-in-water emulsified food product having a more stable emulsified state after thawing can be obtained. Moreover, although the compounding quantity of these process starch is based also on the compounding quantity of the above-mentioned dry egg white, 0.3-8% is preferable and 0.5-6% is more preferable. If the blending amount is less than the above range, even if the above-mentioned dry egg white is used in combination, oil separation is observed in the state after thawing, and it tends not to have a stable emulsified state. This is because the texture tends to be heavy, which is not preferable.

The acidic oil-in-water emulsified food of the present invention is an acidic oil-in-water emulsified food within the range that does not impair the effects of the present invention, in addition to blending the above-described dried egg white and modified starch and / or heat-treated starch. Various raw materials that are usually used can be appropriately selected and contained. For example, rapeseed oil, corn oil, cottonseed oil, safflower oil, olive oil, safflower oil, soybean oil, palm oil, fish oil, egg yolk oil and other animal and vegetable oils and their refined oils, and MCT (medium chain fatty acid triglycerides), diglycerides, etc. Edible fats and oils such as fats and oils obtained by chemical or enzymatic treatment, xanthan gum, tamarind seed gum, locust bean gum, gellan gum, guar gum, gum arabic, silum seed gum, etc., starch degradation products, dextrin, Sugars such as dextrin alcohol, oligosaccharides, oligosaccharide alcohols, vinegar, citric acid, lactic acid, lemon juice and other sour materials, sodium glutamate, salt, sugar and other seasonings, egg yolk, phospholipase A treated egg yolk, whole egg, liquid Egg white, lecithin, glycerin fatty acid ester, polyg Serine fatty acid esters, sucrose fatty acid esters, sorbitan fatty acid esters, emulsifying materials such as octenyl starches, extracts, plants and animals, mustard flour, spices such as pepper, as well as various proteins and their degradation products thereof.

In addition, the production method of the present invention can be produced in accordance with the ordinary method of acidic oil-in-water emulsified foods, except that the above-mentioned dried egg white and modified starch and / or treated starch which is wet-heat treated starch are blended as one raw material. Well, for example, coarsely emulsified by adding the oil phase raw material while stirring the water phase raw material mixed with the above-mentioned dried egg white and the modified starch and / or the processed starch which is the heat-treated starch with a mixer etc. Next, after finishing emulsification with a colloid mill, a high-pressure homogenizer, etc., it is filled and sealed in a bottle container or a glass container. If the treated starch has cold water swellability, it can be used as it is, but if not, a starch obtained by gelatinizing the treated starch in an aqueous medium such as fresh water may be used.

Hereinafter, the acidic oil-in-water emulsified food of the present invention will be specifically described based on Examples, Comparative Examples, and Test Examples. The present invention is not limited to these.

[Example 1]
<Preparation of dried egg white>
2 kg of baker's yeast was added to 1000 kg of liquid egg white obtained by splitting the eggs with shells and desugared at 35 ° C. for 4 hours. Next, this desugared liquid egg white was spray-dried at 170 ° C. to obtain a dried liquid egg white product (pH 10.0, water content 7%). Each 10 kg of this dried product is filled and sealed in a polyethylene bag with a thickness of 60 μm, and these packages are stored in a heat storage room with a temperature of 75 ° C. in which the heated air is ventilated and stored at 75 ° C. for 14 days. The dried egg white was obtained. In addition, when carrying out the heat storage process, the packaging bodies were arranged on the shelf made of a wire mesh in the heat storage room without overlapping each bag. Moreover, the water separation rate of the obtained dried egg white was 2.5%, and the carbon dioxide concentration was 0.6%. The water separation rate was determined by the method described in paragraphs [0015] to [0016] and the carbon dioxide concentration was described in paragraph [0027], and the following examples and comparative examples were similarly performed.

<Preparation of acidic oil-in-water emulsified food>
An acidic oil-in-water emulsified food product having a finish of 100 kg was produced at the blending ratio shown below. That is, the modified starch is dispersed in fresh water, gelatinized by heating, and then cooled to prepare a gelatinized starch solution. The obtained gelatinized starch solution and the aqueous phase raw material other than vegetable oil are uniformly mixed with a mixer to prepare an aqueous phase portion, and then the vegetable oil is gradually added while stirring the aqueous phase portion to obtain a crude emulsion. Made. Next, the obtained coarse emulsion was finish-emulsified with a colloid mill, and 150 g was filled and sealed in a 200 mL capacity nylon plastic bag (15 μm nylon, 60 μm PE from the outside). In addition, hydroxypropyl starch was used for the compounded modified starch.

<Combination ratio>
Vegetable oil 55%
Vinegar (acidity 5%) 10%
Dry egg white 1.5%
Salt 1.5%
Chemical starch 1%
Sterilized egg yolk 1%
1% sugar
Pepper powder 0.5%
Sodium glutamate 0.3%
Shimizu Residues ――――――――――――――――――――――――
Total 100%

[Comparative Example 1]
<Preparation of dried egg white>
Dried egg white was prepared in the same manner as in Example 1 except that the liquid egg white was directly spray dried without desugaring.

<Preparation of acidic oil-in-water emulsified food>
When an acidic oil-in-water emulsified food was prepared in the same manner with the same proportion of acidic oil-in-water emulsified food as in Example 1, oil separation occurred at the stage of final emulsification in the colloid mill, and the emulsified food was It was not obtained.

[Comparative Example 2]
<Preparation of dried egg white>
In the preparation of the dried egg white of Example 1, the dried egg white was prepared in the same manner except that the liquid egg white was directly spray-dried without desugaring and heat-treated for 1 day.

<Preparation of acidic oil-in-water emulsified food>
A container-packed acidic oil-in-water emulsified food was prepared in the same manner at the same proportion of acidic oil-in-water emulsified food as in Example 1. When dry egg white that had been subjected to heat storage treatment for 2 days or more was used, as in Comparative Example 1, oil separation occurred at the stage of final emulsification in a colloid mill, and no emulsified food was obtained.

[Test Example 1]
From Example 1 and Comparative Examples 1 and 2, the influence on the emulsification of the acidic oil-in-water emulsified food by the presence or absence of the desugaring treatment of the dried egg yolk and the influence on the freezing tolerance were examined. The effect on emulsification is the state at the stage of final emulsification, and the effect on freezing tolerance is stored frozen at -20 ° C, -25 ° C and -30 ° C for 2 weeks, and the state after thawing is determined. Each was visually observed and evaluated.

From Table 1, the acid oil-in-water type emulsified food using dried egg white that has not been subjected to desugaring treatment is freezing resistant even if the finished emulsified state is oil-separated (Comparative Example 1) or evenly emulsified. (Comparative Example 2). On the other hand, the emulsified food (Example 1) using the dried egg white subjected to the desugaring treatment was uniformly emulsified in the finished emulsified state and was excellent in freezing resistance. From this, it is understood that dried egg white subjected to a desugaring process must be used in order to obtain an acidic oil-in-water emulsified food having freezing resistance. In Comparative Example 1, since the finished emulsified state was oil-separated, a test related to freezing resistance was not performed.

[Example 2]
<Preparation of dried egg white>
In the preparation of the dried egg white of Example 1, a 100 μm polyethylene bag was used in place of the 60 μm thick polyethylene bag, and it was further placed in a kraft bag and subjected to heat storage treatment in a state where the heated air in the cabinet was not ventilated. A dried egg white was prepared in the same manner except that. The obtained dried egg white had a water separation rate of 3.3% and a carbon dioxide concentration of 1.8%.

In addition, preparation of the acidic oil-in-water type emulsified foods of Examples 3 to 4 and Comparative Examples 3 to 4 including this example is the same method with the blending ratio of the acidic oil-in-water type emulsified foods as in Example 1. An acid oil-in-water emulsified food was prepared in a container. All of the obtained acidic oil-in-water emulsified foods were finished and the emulsified state was uniformly emulsified, which was good.

[Example 3]
<Preparation of dried egg white>
In the preparation of the dried egg white of Example 1, a 100 μm polyethylene bag was used in place of the 60 μm thick polyethylene bag, and heat was further put in a kraft bag and the heated air in the chamber was not ventilated at a chamber temperature of 68 ° C. Dried egg white was prepared in the same manner except that heat storage was performed in the warehouse. The obtained dried egg white had a water separation rate of 3.3% and a carbon dioxide concentration of 2.0%.

[Example 4]
<Preparation of dried egg white>
In the preparation of the dried egg white of Example 1, a 100 μm polyethylene bag was used in place of the 60 μm thick polyethylene bag, and it was further placed in a kraft bag and the heated air in the chamber was not ventilated at a temperature of 65 ° C. Dried egg white was prepared in the same manner except that heat storage was performed in the warehouse. The obtained dried egg white had a water separation rate of 3.4% and a carbon dioxide concentration of 2.2%.

[Comparative Example 3]
<Preparation of dried egg white>
In the preparation of the dried egg white of Example 1, a 100 μm polyethylene bag was used instead of the 60 μm thick polyethylene bag, and the heat was further put in a kraft bag and the heated air in the chamber was not ventilated at a temperature of 60 ° C. Dried egg white was prepared in the same manner except that heat storage was performed in the warehouse. The obtained dried egg white had a water separation rate of 3.5% and a carbon dioxide concentration of 2.3%.

[Comparative Example 4]
<Preparation of dried egg white>
350 g of 10% citric acid solution and 20 g of baker's yeast were added to 10 kg of liquid egg white obtained by splitting the eggs with shells, and desugared at 35 ° C. for 4 hours. Next, this desugared liquid egg white was spray dried at 170 ° C. to obtain a dried liquid egg white product (pH 7.3, water content 7%). Each 1 kg of the dried product is filled and sealed in a polyethylene bag having a thickness of 60 μm, and these packages are stored in a thermostat at 75 ° C., and are heated at 75 ° C. for 14 days while periodically ventilating the heated air in the thermostat. Processing was performed to obtain dried egg white. In addition, the water separation rate of the obtained dried egg white was 6.1%, and the carbon dioxide concentration was 0.1%.

[Test Example 2]
The dried egg white that has been desugared is further subjected to heat treatment at 65 ° C. or higher, and a dried egg white having a water separation rate of 4% or less of the heated coagulum of the dried egg white aqueous solution (7 parts of fresh water relative to 1 part of dried egg white). To demonstrate that the acidic oil-in-water emulsified food obtained does not have excellent refrigeration resistance even if used in combination with dried egg white and modified starch and / or treated starch that is wet-heat treated starch, The freezing tolerance test of each acidic oil-in-water emulsified food obtained in Examples 1 to 4 and Comparative Examples 3 to 4 was evaluated in the same manner as in Test Example 1.

From Table 2, in an acidic oil-in-water emulsified food using desugared dried egg white, an emulsified food using a dried egg white having a heat storage temperature of less than 65 ° C. even if the water separation rate is 4% or less. (Comparative Example 3) or even if the dried egg white is subjected to heat storage at 65 ° C. or higher, the emulsified food (Comparative Example 4) using a water separation rate of more than 4% has no freezing resistance Met. On the other hand, it is understood that the emulsified foods (Examples 1 to 4) using dried egg white that has been subjected to heat storage at 65 ° C. or higher and a water separation rate of 4% or less are excellent in freezing resistance. The

Moreover, from the result of the freezing tolerance of Examples 1 to 4, the heat storage temperature is preferably 68 ° C or higher, more preferably 70 ° C or higher, and the water separation rate is preferably 3.3% or lower, more preferably 3.0% or lower. It is understood that the acidic oil-in-water emulsified food using the dried egg white has better freezing resistance.

[Test Example 3]
The presence or absence of a modified starch and / or a heat-treated starch blended in an acidic oil-in-water emulsified food was examined and the effect of its type on freezing resistance. That is, in the preparation of the acidic oil-in-water type emulsified food of Example 1, the same amount (1%) of different types of treated starches shown in the following table were blended (1%) or not, and the freezing tolerance test of the emulsified food was tested. Evaluation was performed in the same manner as in Example 1. In addition, what mix | blended hydroxypropyl starch in the following table | surface is the acidic oil-in-water type emulsified food obtained in Example 1. FIG.

Table 3 shows that, in an acidic oil-in-water type emulsified food, a modified starch and / or a heat-moisture-treated product, even if the product is desugared and heat-treated at 65 ° C. or higher and blended with dried egg white having a water separation rate of 4% or less It is understood that if the treated starch which is starch is not used in combination, a product having excellent freezing resistance cannot be obtained. In particular, emulsified foods using etherified starch (hydroxypropyl starch, hydroxypropylated phosphoric acid cross-linked starch) were excellent in freezing resistance.

[Test Example 4]
The effect on the freezing tolerance of the blended amount of dried egg white mixed with acid oil-in-water emulsified food and modified starch and / or heat-treated starch was examined. That is, in the preparation of the acidic oil-in-water emulsified food of Example 1, the blended amounts of dry egg white and the modified starch and / or the heat-treated starch that are the heat-treated starch shown in the following table are blended, and the freezing tolerance test of the emulsified food Were evaluated in the same manner as in Test Example 1.

From Table 4, it is understood that the acidic oil-in-water emulsified food having a dry egg white content of 0.1 to 10% and a processed starch content of 0.3 to 8% is excellent in freezing resistance. Is done. In particular, the emulsified food having a dry egg white content of 0.5 to 8% and a processed starch content of 0.5 to 6% was excellent in freezing resistance.

Claims (6)

The dried egg white is blended with a modified starch and / or a processed starch that is a heat-treated starch, the dried egg white is subjected to a desugaring process and a heat storage process at 65 ° C. or higher, and a dried egg white aqueous solution (1 part dried egg white) An acidic oil-in-water emulsified food characterized in that the water separation rate of the heated coagulated product of 7 parts of fresh water is 4% or less. The acidic oil-in-water emulsified food according to claim 1, wherein the dried egg white is heat-treated at 68 ° C or higher. The acidic oil-in-water emulsified food according to claim 1 or 2, wherein the dried egg white has a water separation rate of 3.3% or less. The acidic oil-in-water emulsified food according to any one of claims 1 to 3, wherein the treated starch is an etherified starch. The acidic oil-in-water emulsified food according to any one of claims 1 to 4, wherein the blended amount of dried egg white is 0.1 to 10% based on the product. The acidic oil-in-water emulsified food according to any one of claims 1 to 5, wherein the amount of the treated starch is 0.3 to 8% based on the product.