JP2008279325A - Method for improving quality of water in water tank and water quality improver therefor - Google Patents
Method for improving quality of water in water tank and water quality improver therefor Download PDFInfo
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- JP2008279325A JP2008279325A JP2007123864A JP2007123864A JP2008279325A JP 2008279325 A JP2008279325 A JP 2008279325A JP 2007123864 A JP2007123864 A JP 2007123864A JP 2007123864 A JP2007123864 A JP 2007123864A JP 2008279325 A JP2008279325 A JP 2008279325A
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 457
- 238000000034 method Methods 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 claims abstract description 119
- 239000011941 photocatalyst Substances 0.000 claims abstract description 49
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 47
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 47
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 44
- 229940070527 tourmaline Drugs 0.000 claims abstract description 44
- 239000011032 tourmaline Substances 0.000 claims abstract description 44
- 238000007667 floating Methods 0.000 claims abstract description 19
- 230000005012 migration Effects 0.000 claims abstract description 5
- 238000013508 migration Methods 0.000 claims abstract description 5
- 230000006872 improvement Effects 0.000 claims description 85
- 238000003860 storage Methods 0.000 claims description 34
- 230000002093 peripheral effect Effects 0.000 claims description 22
- 239000000919 ceramic Substances 0.000 claims description 6
- 230000008859 change Effects 0.000 claims description 5
- 230000005540 biological transmission Effects 0.000 claims description 3
- 238000000638 solvent extraction Methods 0.000 claims 1
- 239000005416 organic matter Substances 0.000 abstract description 5
- 230000003213 activating effect Effects 0.000 abstract description 3
- 230000000694 effects Effects 0.000 description 16
- 238000000746 purification Methods 0.000 description 7
- 230000009471 action Effects 0.000 description 6
- 238000009826 distribution Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 230000029553 photosynthesis Effects 0.000 description 3
- 238000010672 photosynthesis Methods 0.000 description 3
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 229920006248 expandable polystyrene Polymers 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- -1 hydroxide ions Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000005339 levitation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000001089 mineralizing effect Effects 0.000 description 1
- 230000021962 pH elevation Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
- C02F1/32—Treatment of water, waste water, or sewage by irradiation with ultraviolet light
- C02F1/325—Irradiation devices or lamp constructions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/32—Details relating to UV-irradiation devices
- C02F2201/322—Lamp arrangement
- C02F2201/3225—Lamps immersed in an open channel, containing the liquid to be treated
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/32—Details relating to UV-irradiation devices
- C02F2201/322—Lamp arrangement
- C02F2201/3227—Units with two or more lamps
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Physical Water Treatments (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Catalysts (AREA)
Abstract
Description
本発明は、ビル、マンション、ホテル、集合住宅等に設けられている受水槽や給水槽や高架水槽など水槽内の水の水質改良方法とそのための水質改良器に関する。特に、本発明は、水を活性化するトルマリンや紫外線が当ると有機物を分解除去して浄化する酸化チタン系光触媒を利用して水槽内に貯留している水質改良をせんとするものである。 The present invention relates to a method for improving the quality of water in a water tank, a water tank, an elevated water tank, and the like, and a water quality improver therefor provided in buildings, condominiums, hotels, apartment houses and the like. In particular, the present invention is intended to improve the quality of water stored in a water tank using a titanium oxide-based photocatalyst that decomposes and removes organic matter when it is exposed to water or UV light.
従来より、トルマリンや酸化チタン系光触媒には、水を浄化したり水質改良したりする機能を有することは知られている。すなわち、トルマリンは、一般に電気石と称されているように永久電極を有し、0.06ミリアンペアの微弱電流を発生し続けている。この特性により水を電気分解したり、水のクラスターを分解して水を活性化したり、吸着、反発作用により脱臭効果や抗菌効果を発揮したりする。またトルマリン鉱石の界面活性効果により水分中の汚れを分離したり、弱アルカリ化によって水質調整したり、トルマリン鉱石からのミネラルの溶質作用により水をミネラル化したりするなどの水質改良をすることが知られている。 Conventionally, it has been known that tourmaline and titanium oxide photocatalysts have a function of purifying water and improving water quality. That is, tourmaline has a permanent electrode as generally called tourmaline, and continues to generate a weak current of 0.06 milliamperes. This property electrolyzes water, decomposes water clusters to activate water, and exhibits deodorizing and antibacterial effects by adsorption and repulsion. It is also known to improve water quality by separating dirt in moisture by surface-active effects of tourmaline ore, adjusting water quality by weak alkalinization, and mineralizing water by solute action of minerals from tourmaline ore. It has been.
また、酸化チタン系光触媒は、光(紫外線)が当るとその表面から電子が飛び出し、このとき電子が抜けた穴(正孔)は、プラスの電荷を帯びており、強力な酸化力をもち、水中にある水酸化イオンなどから電子を奪い、非常に不安定な状態のOH
ラジカルになる。当該OHラジカルは強力な酸化力を持つため、近くの有機物から電子を奪い自分自身が安定になろうとする。電子を奪われた有機物は結合を分断され、分解して二酸化炭素や水となって大気中に発散していく。このようにして酸化チタン系光触媒は、その強力な酸化力により、水中に融解している有機物を分解、除去して浄水する効果が生ずるのである。
In addition, titanium oxide photocatalysts emit electrons from the surface when exposed to light (ultraviolet rays), and the holes (holes) from which the electrons have escaped have a positive charge and have a strong oxidizing power. OH deprived of electrons from hydroxide ions in the water, very unstable state
Become a radical. Since the OH radical has a strong oxidizing power, it takes electrons from nearby organic substances and tries to stabilize itself. Organic matter that has been deprived of electrons breaks the bond, breaks down into carbon dioxide and water, and diffuses into the atmosphere. Thus, the titanium oxide photocatalyst has the effect of decomposing and removing the organic matter melted in the water and purifying the water by its strong oxidizing power.
このようなトルマリンや酸化チタン系光触媒の機能を利用して、水を活性化したり、浄化したり、水質改良する装置は、従来から種々開発されている。例えば、 Various devices for activating, purifying, and improving the quality of water using the functions of such tourmaline and titanium oxide photocatalyst have been developed. For example,
(イ)トルマリンを利用したものとしては、特許第3283231号「洗車機用水質改良装置」、特開2000−202463号「水又は温水の対流浄化・活性化装置」、(ロ)光触媒を利用したものとしては、特開2005−254100号「水質の浄化に用いる光触媒」、特開2000−244694号「酸化チタン光触媒コーティングを備える回転部材を用いる水質汚染浄化装置」、(ハ)トルマリンと酸化チタン系光触媒とからなる水質改良材を利用したものとして特開2005−13974号「水質改良器」、
特開2004−243294号「水質改良装置」などがそれである。
(A) As a thing using tourmaline, patent 3283231 "water quality improvement apparatus for car wash machines", Unexamined-Japanese-Patent No. 2000-202463 "convection purification / activation apparatus of water or warm water", (b) Photocatalyst was utilized. JP 2005-254100 “Photocatalyst used for water purification”, JP 2000-244694 “Water pollution purification device using rotating member equipped with titanium oxide photocatalyst coating”, (ha) tourmaline and titanium oxide system As a thing using the water quality improvement material which consists of a photocatalyst, Unexamined-Japanese-Patent No. 2005-13974 "water quality improvement device",
Japanese Patent Application Laid-Open No. 2004-243294 “Water quality improvement device” is one example.
本発明は、水槽内に収納されている水の水質をトルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材を用いて改良せんとするものである。当該水質改良材のトルマリンおよび/または酸化チタン系光触媒は、前述したようにその物性そのもので自然に水質改良をするものである。このようにトルマリンおよび/または酸化チタン系光触媒は、人工的にエネルギーを供給しなくても良いので、経済的であるという長所があるが、その効果がまろやかで弱く貯溜している水全体の水質改良をするには、時間がかかる欠点がある。そのため、従来例においても水を効率よく品質改良するための工夫がなされている。 The present invention is intended to improve the quality of water stored in a water tank using a water quality improving material mainly composed of tourmaline and / or a titanium oxide photocatalyst. The tourmaline and / or titanium oxide photocatalyst of the water quality improving material naturally improves the water quality by its physical properties as described above. Thus, tourmaline and / or titanium oxide-based photocatalysts do not have to supply energy artificially, so they have the advantage of being economical, but their effects are mild and weak, and the quality of the entire stored water is low. The improvement has the disadvantage of taking time. Therefore, the device for improving the quality of water efficiently is also made in the conventional example.
例えば前記特許文献1、特許文献2の場合は、トルマリンを収納した容器を流水通路に設けてトルマリンと流水とを積極的に接触させようとしており、特許文献3は、水に対流と攪拌を意識的に起こすように構成することにより水圧と接触効率の良さにより水質改良効果を高めるようにしている。また、特許文献4,5の場合は、水槽内の水を浄化するためトルマリンと酸化チタン系光触媒を組み合わせることによる相乗作用により、少しでも水質改良効果をあげようとしている。しかし、流水通路での水質改良材との接触は、瞬間的な接触にすぎず水質改良を確実におこなうには充分ではない。意識的に水に対流と攪拌を起こして接触効率を高めようとすれば、そのためのエネルギー供給が必要となり経済的負担が高くなる。また、特許文献5,6の場合のようにトルマリンと酸化チタン系光触媒を単に組み合わせただけでは水質改良の効率がそれほど良くなるわけではなく満足できるものではない。 For example, in the case of Patent Document 1 and Patent Document 2, a container containing tourmaline is provided in a running water passage to actively contact tourmaline and running water, and Patent Document 3 considers convection and agitation in water. By improving the water quality and the contact efficiency, the water quality improvement effect is enhanced. In the case of Patent Documents 4 and 5, a water quality improvement effect is intended to be achieved by a synergistic effect by combining tourmaline and a titanium oxide photocatalyst to purify the water in the water tank. However, the contact with the water quality improving material in the flowing water passage is only a momentary contact and is not sufficient to surely improve the water quality. If the convection and agitation are consciously caused in the water to increase the contact efficiency, an energy supply for that purpose is required and the economic burden increases. Further, simply combining tourmaline and a titanium oxide photocatalyst as in Patent Documents 5 and 6 does not improve the water quality improvement efficiency, and is not satisfactory.
本発明は、水槽内で貯留状態となっている水の水質改良を効率的におこなうための技術である。水が水槽内に貯留しているときは、ほとんど動くことがなく水が流入する時と流出してくる時に多少対流が起るだけである。このような滞留状態で動かない水全体の水質を効率よく改良するのは難しい。なぜなら水質改良材であるトルマリンも酸化チタン系光触媒も水と接触する表面か接触しそうな表面近傍だけで水質改良作用を起すものであり、離れたところにある水の水質改良作用は起らないからである。また、トルマリンも酸化チタン系光触媒も水質改良作用はまろやかで強くはないので、水槽内に水質改良材を入れただけでは滞留している水全体を効率良く水質改良するのには時間がかかる難点がある。 The present invention is a technique for efficiently improving the quality of water stored in a water tank. When water is stored in the aquarium, there is almost no movement and only a slight convection occurs when water flows in and out. It is difficult to efficiently improve the quality of the whole water that does not move in such a staying state. Because the tourmaline and titanium oxide photocatalyst, which are water quality improvers, only improve the water quality on the surface that is in contact with water or in the vicinity of the surface that is likely to come into contact with it. It is. In addition, since tourmaline and titanium oxide photocatalysts are not mellow and strong in water quality improvement, it is difficult to improve the water quality of all the remaining water efficiently by simply placing a water quality improvement material in the tank. There is.
本発明は、このような技術的課題を解消するために、水質改良材を水中に浮遊させ、当該水質改良材が自動的に動き回るように構成することにより、水と水質改良材とが効率的に接触するようにし、これによって水槽内の水質改良効果を高めるようにしたものである。 In order to solve such technical problems, the present invention makes it possible to efficiently make water and the water quality improving material by floating the water quality improving material in water and automatically moving the water quality improving material around. This improves the water quality improvement effect in the aquarium.
特許を受けようとする第1発明は、トルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材と、当該水質改良材を水中浮遊させることのできる浮力を有する浮力体を備えた水質改良器を、水槽内に収納されている水中に浮遊させ、水の対流と水質改良器の回遊により水質改良材と水との接触が良好になるようにしたことを特徴とする水質改良方法である。 The first invention to be patented is a water quality improver comprising a water quality improving material mainly composed of tourmaline and / or a titanium oxide photocatalyst, and a buoyant body having a buoyancy capable of floating the water quality improving material in water. The water quality improvement method is characterized in that the water quality improvement material and the water are in good contact with each other by floating the water in the water stored in the aquarium and migrating the water quality improvement device.
当該第1発明は、水槽内に収納されている水の水質改良方法である。本発明の第1の特徴は、水質改良器に浮力体を備えたことであり、第2に、水質改良材としてトルマリンおよび/または酸化チタン系光触媒を主体としたものを用いた点にある。水質改良器に浮力体を備えたことにより水質改良材を水槽内に収納されている水中に浮遊させ、水の対流と水質改良器の回遊により水質改良材と水とが接触する機会が多くなるようにして、滞留中の水全体を効率的に水質改良するようにした水質改良方法である。
The first invention is a method for improving the quality of water stored in a water tank. The first feature of the present invention is that the water quality improver is provided with a buoyant body, and secondly, a water quality improving material mainly composed of tourmaline and / or a titanium oxide photocatalyst is used. Since the water quality improver is equipped with a buoyant body, the water quality improver is suspended in the water stored in the aquarium, and the opportunity for the water quality improver to come into contact with water due to the convection of the water and the migration of the water quality improver increases. In this way, the water quality improving method is designed to efficiently improve the water quality of the entire staying water.
特許を受けようとする第2発明は、一部に窓部を設け、その窓部に可視光線を遮断し紫外線だけを透過させる紫外線透過フィルターを取付けてなる水槽と、トルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材と、当該水質改良材を水中浮遊させることのできる浮力を有する浮力体とを備えた水質改良器とを用意し、当該水槽内に収納されている水中に水質改良器を浮遊させ、
水の対流と水質改良器の回遊により水と水質改良材との接触を良好にするとともに、水槽内に透過した紫外線により水質改良器の酸化チタン系光触媒を活性化するようにしたことを特徴とする水質改良方法である。
The second invention to be patented is a water tank in which a window part is provided, and an ultraviolet light transmission filter that blocks visible light and transmits only ultraviolet light, and a tourmaline and / or titanium oxide system. A water quality improvement device comprising a water quality improvement material mainly composed of a photocatalyst and a buoyancy body capable of floating the water quality improvement material in water is prepared, and the water quality improvement is performed in the water stored in the water tank. Float the vessel,
It is characterized in that the contact between water and the water quality improvement material is improved by the convection of water and the migration of the water quality improvement device, and the titanium oxide photocatalyst of the water quality improvement device is activated by the ultraviolet rays transmitted into the water tank. This is a method for improving water quality.
当該第2発明は、第1発明の水質改良法を強化した水質改良方法である。本発明の場合、水質改良材の一種である酸化チタン系光触媒の有機物を分解、除去して浄水する効果を高めるためには、光(紫外線)が必要である。しかし、ビル、マンション、ホテル、集合住宅等に設けられている受水槽や給水槽や高架水槽など清涼な水の場合には、水槽内に光が入り込まないように暗室にすることが要請されている。なぜなら水に光が照射されると光合成作用が起るなど水質が劣化しやすくなるからである。ところが、水質改良材である酸化チタン系光触媒は、光がないと光触媒作用がおきないものである。そのため水質改良材として酸化チタン系光触媒を使用する場合、水槽内を暗室にしていては、その浄化作用を十分に発揮させることができない。そこで、水槽の一部に窓部を設け、その窓部に可視光線を遮断し紫外線だけを透過させる紫外線透過フィルターを取付けて、水中での光合成作用を防止しながら酸化チタン系光触媒の光触媒作用を活性化させ、水の浄化を促進しようとするものである。 The said 2nd invention is the water quality improvement method which strengthened the water quality improvement method of 1st invention. In the case of the present invention, light (ultraviolet rays) is necessary to enhance the effect of decomposing and removing the organic substance of the titanium oxide photocatalyst, which is a kind of water quality improving material, to purify the water. However, in the case of cool water such as water tanks, water tanks, and elevated water tanks installed in buildings, condominiums, hotels, apartment buildings, etc., it is requested to make a dark room so that light does not enter the tank. Yes. This is because when water is irradiated with light, the water quality tends to deteriorate, for example, a photosynthesis action occurs. However, the titanium oxide photocatalyst, which is a water quality improving material, does not exhibit photocatalytic action without light. Therefore, when a titanium oxide photocatalyst is used as a water quality improving material, the purification action cannot be sufficiently exhibited if the inside of the water tank is a dark room. Therefore, a window is provided in a part of the water tank, and an ultraviolet transmissive filter that blocks visible light and transmits only ultraviolet rays is attached to the window, thereby preventing the photosynthesis of the titanium oxide photocatalyst while preventing photosynthesis in water. It is intended to activate and promote water purification.
特許を受けようとする第3発明は、トルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材と、当該水中を浮遊することのできる浮力を有する浮力体とを備えた水質改良器である。 The third invention to be patented is a water quality improver comprising a water quality improving material mainly composed of tourmaline and / or a titanium oxide photocatalyst, and a buoyant body having a buoyancy capable of floating in the water. .
当該第3発明は、第1発明又は第2発明に係る水質改良方法を実現するのに用いる水質改良器の基本発明である。水質改良材については第6発明の項で詳細に説明するので、ここでの説明は省略する。浮力体は、(a)空洞体の中に空気など水より軽い気体を封入してある場合)(b)発砲スチロールを使用する場合、(c)発砲スチロールと気体を用いて、浮力を発生させてる浮力体であれば、いずれでも良い。 The third invention is a basic invention of a water quality improver used to realize the water quality improvement method according to the first invention or the second invention. Since the water quality improving material will be described in detail in the section of the sixth invention, the description thereof is omitted here. The buoyant body is (a) a gas that is lighter than water, such as air, is enclosed in a hollow body) (b) when using a foamed polystyrene, (c) using the foamed polystyrene and gas to generate buoyancy Any buoyant body can be used.
特許を受けようとする第4発明は、水中を浮遊することのできる浮力を有する球形の浮力体の外周に、網状体又は多数の透水孔を有する透水材にて、より径が大きい球形状の透水性外周壁を形成して、前記浮力体の外周と透水性外周壁との間に水質改良材収納空間を形成し、当該水質改良材収納空間を区分して複数の水質改良材収納室を区画形成するようにし、当該区画された複数の水質改良材収納室内に、トルマリンおよび/または酸化チタン系光触媒を主体とする球形の水質改良材を適度の余裕空間が生ずる量を収納し、姿勢が変化すると重力によって水質改良材が水質改良材収納室内を遊動自在なるようになし、前記透水性外周壁の適所には突起部を形成し、水流や水圧の変化によっても姿勢を変化させることができるようにしたことを特徴とする水質改良器である。 The fourth invention to be patented is a spherical material having a larger diameter with a net or a water-permeable material having a large number of water-permeable holes on the outer periphery of a spherical buoyant material having a buoyancy capable of floating in water. A water permeable outer peripheral wall is formed, a water quality improving material storage space is formed between the outer periphery of the buoyant body and the water permeable outer peripheral wall, and a plurality of water quality improving material storage chambers are formed by dividing the water quality improving material storage space. A compartment is formed, and a plurality of water quality improvement material storage chambers are partitioned, and a spherical water quality improvement material mainly composed of tourmaline and / or a titanium oxide-based photocatalyst is stored in such an amount that an appropriate margin space is generated. If it changes, the water quality improving material can freely move in the water quality improving material storage chamber due to gravity, and a protrusion is formed at an appropriate position of the water permeable outer peripheral wall, so that the posture can be changed by changing the water flow or water pressure. What I did A water quality improvement device according to claim.
当該第4発明は、水質改良器の具体的実施態様例である。全体形状が球形で、その中心部に浮力体が設けられており、その外周に球形の透水性外周壁により水質改良材収納空間を形成し、当該水質改良材収納空間を区分して複数の水質改良材収納室を区画形成している。当該水質改良材収納室内には、球形の水質改良材を適度の余裕空間が生ずる量が収納してあり、姿勢が変化すると重力によって収納された水質改良材が水質改良材収納室内を遊動自在なるように構成されている。しかも前記透水性外周壁の適所には突起部を形成し、水流や水圧の変化によっても球形の水質改良器が回転して姿勢を変化させることができるようにした水質改良器である。このように本発明に係る水質改良器は、わずかな水流や水圧の変化によって水中を常に回転移動するので、水と水質改良材との接触範囲が広く良好となり、水槽内に滞留中の水であっても水質改良効果を高めることができるものである。 The fourth invention is a specific embodiment example of the water quality improver. The overall shape is spherical, and a buoyant body is provided in the center, and a water quality improvement material storage space is formed on the outer periphery by a spherical permeable outer peripheral wall, and the water quality improvement material storage space is divided into a plurality of water qualities. The improvement material storage chamber is partitioned. In the water quality improvement material storage chamber, a spherical water quality improvement material is stored in such an amount that a moderate margin space is generated. When the posture changes, the water quality improvement material stored by gravity becomes free to move in the water quality improvement material storage chamber. It is configured as follows. In addition, the water quality improver is configured such that a protrusion is formed at an appropriate position of the water permeable outer peripheral wall so that the spherical water quality improver can rotate and change its posture even when the water flow or water pressure changes. As described above, the water quality improver according to the present invention constantly rotates in the water by a slight change in water flow or water pressure, so that the contact range between the water and the water quality improving material is wide and good, and the water staying in the water tank Even if it exists, the water quality improvement effect can be heightened.
特許を受けようとする第5発明は、水中を浮遊することのできる浮力を有する浮力体から又は浮力体に装着した取付け枠から複数本の索条を垂下させ、当該索条のそれぞれにトルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材の塊体または球形体を複数個取付けたことを特徴とする水質改良器である。 According to a fifth aspect of the invention to receive a patent, a plurality of ropes are suspended from a buoyancy body having a buoyancy capable of floating in water or from a mounting frame attached to the buoyancy body. A water quality improver comprising a plurality of masses or spheres of a water quality improvement material mainly comprising a titanium oxide photocatalyst.
当該第5発明は、水質改良器の第二実施態様例である。当該水質改良器は、上部に浮力を有する浮力体を設け、その浮力体から直接または浮力体に装着した取り付け枠から複数本の索条を垂下させる。その索条のそれぞれに水質改良材の塊体又は球形体を複数個取り付けてなるものである。この発明にかかる水質改良器は、水中の広い範囲で水と水質改良材との接触が実現し、効率よく水槽内の水を水質改良させることができる。 The fifth invention is a second embodiment of the water quality improver. The water quality improver is provided with a buoyancy body having buoyancy at the top, and a plurality of ropes are suspended directly from the buoyancy body or from an attachment frame attached to the buoyancy body. A plurality of water quality improving material blocks or spheres are attached to each of the ropes. The water quality improver according to the present invention achieves contact between water and the water quality improving material in a wide range of water, and can efficiently improve the water quality in the water tank.
特許を受けようとする第6発明は、水質改良材が、トルマリンおよび/または酸化チタン系光触媒を主体とするセラミックの塊体または球形体であることを特徴とする水質改良器である。 A sixth invention to be patented is a water quality improver characterized in that the water quality improving material is a ceramic lump or spherical body mainly composed of tourmaline and / or a titanium oxide photocatalyst.
第6発明は、本発明に係る水質改良材の種類を特定したものである。それは、(a)トルマリンの原石をそのまま球形や粒状に整形加工して使用する場合、(b)当該トルマリンを粉末化したものを主体として、これに連結材を混合し整形したうえ、焼成してトルマリンセラミックにしたものを使用する場合、(c)酸化チタン系光触媒を整形補助材と混合したものを成形し、焼成してセラミック状の塊体や球形状にしたものを使用する場合、(d)粉末状のトルマリンと酸化チタン系光触媒と連結材を混合し成形したうえ、焼成してセラミック化したものを使用する場合、(e)トルマリンと酸化チタン系光触媒を主体とし、これに麦飯石、その他の水質改良効果のある材料を混合したものを原料として水質改良材を成形したものの全てを含むものである。 6th invention specifies the kind of water quality improvement material which concerns on this invention. When (a) the tourmaline ore is used after being shaped into a spherical or granular form as it is, (b) the tourmaline powdered as a main component, and after mixing and shaping the connecting material, firing it When using tourmaline ceramics, (c) When using a mixture of a titanium oxide photocatalyst and a shaping aid, and firing to form a ceramic lump or sphere, (d ) When powdered tourmaline, titanium oxide photocatalyst and connecting material are mixed and molded, and then fired and ceramicized, (e) tourmaline and titanium oxide photocatalyst are mainly used. It includes all of the water quality improving materials formed from a mixture of other water quality improving materials.
本発明は、エネルギーを供給しなくてもトルマリンと酸化チタン系光触媒が有する水質浄化作用に着目して、これを水質改良材として採用し、この浄化作用を効率よく発揮させるために、水と水質改良材との接触を常に良好にするように工夫した水質改良方法である。本発明の場合水槽の中に貯溜されている水中に水質改良器を浮遊させておくだけで水質改良がおこなわれるので、便利である。
The present invention focuses on the water purification effect of tourmaline and titanium oxide photocatalysts without supplying energy, and adopts this as a water quality improving material, and in order to efficiently exhibit this purification action, water and water quality It is a water quality improvement method devised so that the contact with the improvement material is always good. In the case of the present invention, the water quality is improved simply by floating the water quality improver in the water stored in the water tank, which is convenient.
特にトルマリンを用いて水質改良した場合には水槽から水を配水する管の赤錆を除去し配管を清掃する効果も生じる。
In particular, when the water quality is improved using tourmaline, the effect of removing red rust from the pipe that distributes water from the water tank and cleaning the pipe is also produced.
第2発明は、更に酸化チタン系光触媒をより活性化するため水槽の一部に窓を設けて、紫外線だけを通過させる紫外線フィルターを設けた点が大きな特徴である。
The second invention is further characterized in that in order to further activate the titanium oxide photocatalyst, a window is provided in a part of the water tank and an ultraviolet filter that allows only ultraviolet rays to pass through is provided.
第3発明〜第6発明の水質改良器の特徴は、第1に浮力体を設けて、水質改良材を浮遊させるようにすることであり、第2に水質改良材と水を少しでも広く且つ効率的に良くなるように工夫した点にある。第3発明の場合は、球形にしてさらにそれが回転し易い構造にすることにより水との新しい接触が起こりやすくして、効率的な水質改良をするようにしたものである。また、第4発明は、垂下索条に水質改良材を水中に広く展開するように配設し、それが揺動することにより広く効率的に水と接触し、効率よく水質改良する効果がある。 The features of the water quality improvers of the third to sixth inventions are to firstly provide a buoyant body to float the water quality improving material, and secondly to make the water quality improving material and water as wide as possible and It is in the point devised so that it may improve efficiently. In the case of the third aspect of the invention, a spherical contact structure is formed so that it can be easily rotated, so that new contact with water is likely to occur, thereby improving the water quality efficiently. Further, the fourth aspect of the present invention has an effect of efficiently improving the water quality by arranging the water quality improving material on the hanging rope so as to spread widely in the water and swinging it widely and efficiently. .
一部に窓部を設け、その窓部に可視光線を遮断し紫外線だけを透過させる紫外線透過フィルターを取付けてなる水槽と、トルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材と、当該水中を浮遊することのできる浮力を有する浮力体とを備えた水質改良器を用意し、その水質改良器を、水槽内に収納されている水中に浮遊させ、水の対流と水質改良器の回遊により水と水質改良材との接触を良好にするとともに、水槽内に透過した紫外線により水質改良器の酸化チタン系光触媒を活性化して効率よく水質改良をするようにしたことを特徴とする水質改良方法である。 A water tank having a window part in a part, and an ultraviolet light transmission filter that blocks visible light and transmits only ultraviolet light, and a water quality improvement material mainly composed of tourmaline and / or a titanium oxide photocatalyst, Prepare a water quality improver equipped with a buoyant body with buoyancy that can float in the water, float the water quality improver in the water stored in the aquarium, and move the water convection and the water quality improver The water quality improvement is characterized by improving the water quality efficiently by improving the contact between water and the water quality improvement material by activating the titanium oxide photocatalyst of the water quality improvement device with the ultraviolet rays transmitted through the water tank. Is the method.
以下、本発明にかかる水質改良方法と水質改良器を図示実施例に基づいて説明する。図1は、第1発明に係る水質改良方法を示す縦断説明図であり、図2は、第2発明に係る水質改良方法を示す縦断説明図である。図3は、水質改良器の一実施例を示す斜視図であり、図4は、図3に示す水質改良器の透水性外周壁をはずした状態でその区分された水質改良材収納室に水質改良材が収納されている状態を示す斜視図である。図5は、図3に示す水質改良器の構造を示す縦断説明図である。図6は、図3に示す水質改良器の区分された水質改良材収納室を示す一部切欠した説明図である。図7は、水質改良器の他実施例を示す斜視図である。図8は、実施例1の水質改良器を水中に沈めた場合に当該水質改良器に働く力について示す説明図であり、図9は、実施例1に係る球形の水質改良器の外部に設置された突起部により右方向に回転した場合の水質改良器周りの流線である。 Hereinafter, a water quality improving method and a water quality improving device according to the present invention will be described based on illustrated embodiments. FIG. 1 is a longitudinal explanatory view showing a water quality improving method according to the first invention, and FIG. 2 is a longitudinal explanatory view showing a water quality improving method according to the second invention. FIG. 3 is a perspective view showing an embodiment of the water quality improver, and FIG. 4 shows the water quality in the partitioned water quality improver storage chamber with the water permeable outer peripheral wall of the water quality improver shown in FIG. 3 removed. It is a perspective view which shows the state in which the improvement material is accommodated. FIG. 5 is a longitudinal explanatory view showing the structure of the water quality improver shown in FIG. 3. FIG. 6 is a partially cutaway explanatory view showing the water quality improvement material storage chamber into which the water quality improvement device shown in FIG. 3 is divided. FIG. 7 is a perspective view showing another embodiment of the water quality improver. FIG. 8 is an explanatory diagram showing the force acting on the water quality improver when the water quality improver of Example 1 is submerged in water, and FIG. 9 is installed outside the spherical water quality improver according to Example 1. It is a streamline around the water quality improver when it is rotated rightward by the projected portion.
図1は、第1発明に係る水質改良方法を示す縦断説明図である。図中1は水槽であり、2はその水槽1内に貯溜されている水であり、3は水槽1への水の供給口で4は水槽1から水を配水する配水口である。水中に浮遊する球形体は、第4発明に係る水質改良器5aである。当該球形の水質改良器5aは、常時浮遊しながら不規則に回転し姿勢が変化するようになっている。
FIG. 1 is a longitudinal explanatory view showing a water quality improvement method according to the first invention. In the figure, 1 is a water tank, 2 is water stored in the water tank 1, 3 is a water supply port to the water tank 1, and 4 is a water distribution port for distributing water from the water tank 1. The spherical body floating in water is the water quality improver 5a according to the fourth invention. The spherical water quality improver 5a rotates irregularly while constantly floating and changes its posture.
図2は、第2発明に係る水質改良方法を示す縦断説明図である。図中1は水槽であり2は、その水槽内に貯蔵されている水であり、3は水槽への水の供給口で、4は水槽から水を配水する配水口である。図1との相違点は、水槽1の天井面に装着されている入り口のキャップ6に、窓7が形成されており、その窓には、紫外線だけを通過させることのできる紫外線フィルター8が取り付けられている。尚、図中13は水槽1の外部に設けた室内照明用のランプである。水槽1内の貯溜水に浮かんでいるのは、第5発明に係る水質改良器5bである。当該水質改良器5bは、水中を浮遊することのできる球形の浮力体9の周囲に装着した取付け枠10から複数本の索条11,11、…を垂下させ、当該索条11,11、…のそれぞれにトルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材12,12,12、…の塊体または球形体を各複数個づつ取付けてなるものである。この水質改良器5bの場合には、水質改良材12,12,12、…が水深の浅いところから深いところまで広く分散して広い範囲で水とよく接触するので、水質改良効果が効率的であり、貯溜水全体を品質改良するのに適している。しかも対流が起これば水質改良器5b自体が移動するし、垂下した策条11,11,11、…尚、が揺動するので、水質改良効果がより良好となる。
FIG. 2 is a longitudinal explanatory view showing a water quality improvement method according to the second invention. In the figure, 1 is a water tank, 2 is water stored in the water tank, 3 is a water supply port to the water tank, and 4 is a water distribution port for distributing water from the water tank. The difference from FIG. 1 is that a window 7 is formed in an entrance cap 6 attached to the ceiling surface of the water tank 1, and an ultraviolet filter 8 that allows only ultraviolet rays to pass through is attached to the window 7. It has been. In the figure, reference numeral 13 denotes a lamp for indoor lighting provided outside the water tank 1. Floating in the stored water in the water tank 1 is a water quality improver 5b according to the fifth invention. The water quality improver 5b hangs a plurality of ropes 11, 11,... From a mounting frame 10 mounted around a spherical buoyancy body 9 that can float in water, and the ropes 11, 11,. , And a plurality of lumps or spheres of water quality improving materials 12, 12, 12,... Mainly composed of tourmaline and / or titanium oxide photocatalysts. In the case of the water quality improver 5b, the water quality improving materials 12, 12, 12,... Are widely dispersed from a shallow depth to a deep location and are in good contact with water in a wide range, so that the water quality improving effect is efficient. Yes, it is suitable for improving the quality of the entire stored water. In addition, if convection occurs, the water quality improver 5b itself moves and the suspended measures 11, 11, 11,... Swing, so that the water quality improving effect becomes better.
図3〜図6は、水質改良器5aの構造を詳細に示す図面である。図示実施例は、図3に示すようにその外周壁が透水材14として金網でできており、その表面に野球のボールの縫い目のような突起部15が形成されている。その内部構造は、図5に示したように、球形の外周壁16を有しその中央部に空気17が封入されてなる浮力体9が形成されており、その浮力体9の外周に、網状体又は多数の透水孔を有する透水材14にて、より径が大きい球形状の透水性外周壁18を形成してあり、前記浮力体9の外周壁16と透水性外周壁18との間に水質改良材収納空間19を形成する。当該水質改良材収納空間19は、図6に示すようにほぼ均一な形状と面積に区分されていて複数の水質改良材収納室20,20,20、…が区画形成されている。図6はその複数に区画された水質改良材収納室20,20,20、…の様子を示した要部切欠の斜視図である。当該区画された複数の水質改良材収納室内20,20,20、…には、トルマリンおよび/または酸化チタン系光触媒を主体とする球形の水質改良材12,12,12、…を適度の余裕空間が生ずる量づつ収納してある(図5、図4)。
3-6 is drawing which shows the structure of the water quality improvement device 5a in detail. In the illustrated embodiment, as shown in FIG. 3, the outer peripheral wall is made of a wire mesh as a water permeable material 14, and a projection 15 like a baseball ball seam is formed on the surface thereof. As shown in FIG. 5, the internal structure is formed with a buoyant body 9 having a spherical outer peripheral wall 16 in which air 17 is sealed at the center, and a net-like structure is formed on the outer periphery of the buoyant body 9. A permeable outer peripheral wall 18 having a larger diameter is formed by a body or a water permeable material 14 having a large number of water permeable holes, and between the outer peripheral wall 16 and the permeable outer peripheral wall 18 of the buoyancy body 9. A water quality improving material storage space 19 is formed. As shown in FIG. 6, the water quality improving material storage space 19 is divided into a substantially uniform shape and area, and a plurality of water quality improving material storage chambers 20, 20, 20,. FIG. 6 is a perspective view of a main part cutout showing the state of the water quality improving material storage chambers 20, 20, 20,. In the partitioned water quality improvement material storage chambers 20, 20, 20,..., Spherical water quality improvement materials 12, 12, 12,... Mainly composed of tourmaline and / or a titanium oxide photocatalyst are provided. Is stored in an amount such that the amount of occurrence occurs (FIGS. 5 and 4).
図示実施例1に係る水質改良器5aを具体的に試作し、それが水面又は水中を遊動自在隣、水質改良材12と水との接触を良好にする機能を有することを確認し、その理由について説明する。
The water quality improver 5a according to the first embodiment shown in the figure is specifically prototyped, and it is confirmed that it has a function of improving the contact between the water quality improvement material 12 and the water, next to the water surface or underwater freely, and the reason. Will be described.
試作品として製造した水質改良品5aは、図5に示すように、合成樹脂製など非通気性材料により製造された、直径が20cmの球形体の中に空気などの気体を封入することにより構成された浮力体9を形成している。その浮力体9の外周に直径が24.6cmの球形状の透水性外周壁18が形成してある。当該実施例では透水性外周壁18は、金網製とした。従って当該浮力体9の外周と透水性外周壁18との間には、2.3cmの間隔をもった水質改良材収納空間19が形成されている。当該水質改良材収納空間19は、図6に示すように8つの区分された水質改良材収納室20,20,20、…が区画形成されており、当該水質改良材収納室20,20,20、…内には、図4に示すように直径が2cmの球形状のセラミックに加工した水質改良材12,12,12、…が収納されている。
As shown in FIG. 5, the water quality improvement product 5a manufactured as a prototype is configured by enclosing a gas such as air in a spherical body having a diameter of 20 cm manufactured using a non-breathable material such as a synthetic resin. The formed buoyancy body 9 is formed. A spherical water-permeable outer peripheral wall 18 having a diameter of 24.6 cm is formed on the outer periphery of the buoyancy body 9. In this embodiment, the water permeable outer peripheral wall 18 is made of wire mesh. Accordingly, a water quality improving material storage space 19 having a distance of 2.3 cm is formed between the outer periphery of the buoyancy body 9 and the water permeable outer peripheral wall 18. As shown in FIG. 6, the water quality improvement material storage space 19 is divided into eight divided water quality improvement material storage chambers 20, 20, 20,. ,... Contain water quality improving materials 12, 12, 12,... Processed into a spherical ceramic having a diameter of 2 cm as shown in FIG.
当該試作品の水質改良品5aが浮遊する浮力は、浮力体9によって得られ、これを沈めようとする重力は、収納される水質改良材12,12,12、…の総重量と透水性外周壁18の総重量との総和により得られる。また、水質改良材12,12,12、…を水中に沈めた場合、この水質改良材12,12,12、…が押しのける体積によっても浮力が生ずる。こんように実施例1の水質改良器5aを水中に沈めた場合に当該水質改良器5aに働く力については、図8に示す通りとなる。
The buoyancy at which the water quality improvement product 5a of the prototype is floated is obtained by the buoyancy body 9, and the gravity to sink it is the total weight of the water quality improvement materials 12, 12, 12,. It is obtained by summing up with the total weight of the wall 18. Further, when the water quality improving materials 12, 12, 12,... Are submerged in water, buoyancy is also generated by the volume that the water quality improving materials 12, 12, 12,. FIG. 8 shows the force acting on the water quality improver 5a when the water quality improver 5a of Example 1 is submerged in the water.
図8に示すように、球形体による浮力をF1とし、これを沈めようとする水質改良材12,12,12、…の総重量をF2となし、この水質改良材,12,12、…により生じる総浮力をF3とする。但し、解析を簡素化するため、近似的に透水性外周壁の総重量は、F1,F2,F3と比較して、無視すべきものとする。
球形体9による浮力F1は、数式(1)で求められる。
As shown in FIG. 8, the buoyancy by spherical bodies and F 1, the water quality improving materials 12, 12, 12 when you Shizumeyo this, ... the total weight of F 2 ungated, this water quality improvement agent, 12, 12, ... the total buoyancy caused by the F 3. However, in order to simplify the analysis, the total weight of the water permeable outer peripheral wall should be ignored in comparison with F 1 , F 2 , and F 3 .
The buoyancy F 1 due to the spherical body 9 can be obtained by Expression (1).
実施例1で記載されている試作品の水質改良器5aについて、上記の数式(1)〜(5)に基づいてその浮力について、検証する。
直径が20cmの合成樹脂製の球体として浮力体9を形成し、中に空気を封入すると、約6kg強の浮力が得られる。この場合r1=10cmである。また、水質改良材12の直径は、2cmとすると、d=2cmとなる。この数値を数式(1)
に代入すると、次の結果が得られる。
F1=4188.79g
このときの水質改良材収納空間19に充填される水質改良材12の個数を求めてみると、数式(2)より、次のようになる。
n=484個
従って、この数値を使うと、数式(3)〜(5)より、次の値が求となる。
F2=4054.75g
F3=2027.35g
F=2161.42g
従って、この場合得られる浮力は、F1+F3=6216.42gとなる。
The buoyancy of the prototype water quality improver 5a described in Example 1 is verified based on the above formulas (1) to (5).
When the buoyancy body 9 is formed as a synthetic resin sphere having a diameter of 20 cm and air is enclosed therein, a buoyancy of about 6 kg or more is obtained. In this case, r1 = 10 cm. Moreover, if the diameter of the water quality improving material 12 is 2 cm, d = 2 cm. This numerical value is expressed by Equation (1)
Substituting into yields the following result:
F 1 = 4188.79 g
When the number of the water quality improving materials 12 filled in the water quality improving material storage space 19 at this time is determined, the following is obtained from the formula (2).
n = 484 Therefore, when this numerical value is used, the following values are obtained from the equations (3) to (5).
F 2 = 4054.75 g
F 3 = 2027.35 g
F = 2161.42g
Therefore, the buoyancy obtained in this case is F 1 + F 3 = 6216.42 g.
つまり、実施例1の浮力は6Kg強であり、充填される水質改良材12,12,12、…の個数は、484個である。この状態で、F=2162.42gであることから、理論的には、水質改良器5aは、その一部を水面上に表して浮遊することになるが、本解析では、透水性外周壁18の総重量を無視している。従って、この重量を考慮すれば、水質改良器5bが、図1の状態で、水面若しくは水中で浮遊させることができるのは明らかである。 That is, the buoyancy of Example 1 is slightly over 6 kg, and the number of the water quality improving materials 12, 12, 12,. In this state, since F = 2216.42 g, theoretically, the water quality improver 5a floats with a part of it appearing on the water surface. Ignoring the total weight of the. Therefore, considering this weight, it is clear that the water quality improver 5b can be floated on the water surface or in the water in the state of FIG.
更に図示実施例1の場合、当該水質改良材収納空間19は、図6に示すように8つの区分された水質改良材収納室20,20,20、…が区画形成されている。当該水質改良材収納室20,20,20、…内には、直径が2cmの球形状のセラミックに加工した水質改良材12,12,12、…を全容積の70〜80%が埋まる程度(適度の余裕空間が生ずる量づつ)収納してある。従って、収納されている水質改良材12,12,12、…は、姿勢が変化すると重力によって水質改良材12,12,12、…の一部が移動して、重心を変化させるので、回転してその姿勢を変える。このように8つの水質改良材収納室20,20,20、…内で遊動自在なるように構成されているので、安定した姿勢を保ちにくく、ちょっとした刺激によってつねに姿勢を変えようとする。更に、当該透水性外周壁18の外周壁の適所には突起部15を形成し、水流や水圧の変化によっても姿勢を変化させることができるように形成したので、一定の姿勢を保持することが難しく常に水中を移動したり回転したりするので、その分だけ水質改良材12,12,12、…が水と接触する効率が良好となる(図1)。 Further, in the case of the illustrated embodiment 1, the water quality improving material storage space 19 is divided into eight water quality improving material storage chambers 20, 20, 20,... As shown in FIG. The water quality improvement material storage chambers 20, 20, 20,... Are filled with 70 to 80% of the total volume of the water quality improvement materials 12, 12, 12,... Processed into a spherical ceramic having a diameter of 2 cm ( It is stored in an amount that creates a moderate margin). Accordingly, the stored water quality improving materials 12, 12, 12,... Rotate because part of the water quality improving materials 12, 12, 12,... Change its posture. Thus, since it is configured to be freely movable in the eight water quality improvement material storage chambers 20, 20, 20,..., It is difficult to maintain a stable posture, and the posture is always changed by a slight stimulus. Furthermore, since the protrusion 15 is formed at an appropriate position on the outer peripheral wall of the water permeable outer peripheral wall 18 so that the posture can be changed by a change in water flow or water pressure, a certain posture can be maintained. Since it is difficult and always moves and rotates in the water, the water quality improving material 12, 12, 12,...
水質改良材12,12,12、…であるトルマリンおよび/または酸化チタン系光触媒は、有機質を分解したり、界面活性効果を発揮させたり、水の電気分解をしたり遠赤外線を放射したり、様々な作用を有していて、水を浄化したり、活性化したりすることが知られているが、そのような作用効果はトルマリンおよび/または酸化チタン系光触媒に接触した水か、その近傍でしか起こりにくい。水が静止していて動かない場合には、より離れた場所にある水の水質改良は難しく、時間がかかる。本発明のように水槽1に水を貯溜しておき、必要に応じて配水する場合に、貯溜水を効率的に水質改良する要請に応えるには、水2と水質改良材12,12,12、…との接触効率を高めることによって、実用性を確保できるようにしたものである。
The tourmaline and / or titanium oxide photocatalyst, which is a water quality improver 12, 12, 12,... Decomposes organic matter, exerts a surface active effect, electrolyzes water, emits far infrared rays, It is known to purify and activate water with various actions, but such action and effect can be achieved in or near water in contact with tourmaline and / or titanium oxide photocatalysts. Only difficult to happen. If the water is stationary and does not move, it is difficult and time-consuming to improve the quality of the water at a further distance. In the case where water is stored in the water tank 1 as in the present invention and distributed as needed, the water 2 and the water quality improvers 12, 12, 12 are used to meet the demand for improving the water quality of the stored water efficiently. The practicality can be secured by increasing the contact efficiency with.
更に、実施例1に示す水質改良器5aは、透水性外周壁18の適所に突起部15を形成し、水流や水圧の変化によっても姿勢を変化させることができるように構成してある。具体的には図3に示すように、野球のボールの縫い目上に突起部15を突設形成している。この突起部15が自由浮揚を促進することを、以下解析する。
Further, the water quality improver 5a shown in the first embodiment is configured such that the protrusions 15 are formed at appropriate positions on the water-permeable outer peripheral wall 18 so that the posture can be changed by changing the water flow or the water pressure. Specifically, as shown in FIG. 3, a projection 15 is formed to project on the seam of a baseball. It will be analyzed below that this protrusion 15 promotes free levitation.
図9は、球形の水質改良器5aの外部に設置された突起部15により右方向に回転した場合の水質改良器5a周りの流線である。このように球体が回転すると、流速が流れの一方の側で速く、反対側で遅くて物体を回る閉曲線に沿って流速を積分した値が0でない場合には、早いほうに揚力が作用する。この傾向は、速い側では流感が補足なり、圧力が小さくなるのに反して、遅い側では流管が太くなり、圧力が大きくなることによる。これは、マグナス(Magnus)効果と呼ばれ、流れの中で球などを回転させると、表面が流れの方向に回っている側に地からが作用し、その方向に球体が運動する現象となる。本発明に係る水質改良器5aは、前記のように野球ボール状突起を有している。この突起が非軸対象形となっていないため、流速のある流体中では、流線の様々な粗密により、種々な回転をなし、この回転により得られた力により様々な方向に浮遊することを可能とする。故に、本発明による水質改良器5aは、遊動自在となり、水質改良材と水との接触を良好ならしめることができるのである。 FIG. 9 is a streamline around the water quality improver 5a when rotated in the right direction by the protrusion 15 installed outside the spherical water quality improver 5a. When the sphere rotates in this way, if the value obtained by integrating the flow velocity along the closed curve around the object is fast on one side of the flow and slow on the other side, lift is applied earlier. This tendency is due to the fact that the flow feeling is supplemented on the fast side and the pressure becomes small, whereas the flow pipe becomes thick and the pressure becomes large on the slow side. This is called the Magnus effect. When a sphere or the like is rotated in the flow, the surface acts on the side where the surface is rotating in the flow direction, and the sphere moves in that direction. . As described above, the water quality improver 5a according to the present invention has a baseball ball-like protrusion. Since these protrusions are not non-axially shaped, in a fluid with a high flow velocity, various rotations occur due to various coarseness of streamlines, and it is possible to float in various directions due to the force obtained by this rotation. Make it possible. Therefore, the water quality improver 5a according to the present invention is free to move, and the contact between the water quality improving material and water can be improved.
実施例2は、図7に示したような垂下数式の水質改良器5bの実施例図7に示したとおり上部に水中を浮遊することのできる浮力を有する球形の浮力体9を設けておき、この周辺に取付け枠10を装着しておき、この取り付け枠10から複数本の索条11,11,11、…を垂下させ、当該索条11,11,11、…のそれぞれにトルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材12,12,12、…の塊体または球形体を複数個取付けてなる水質改良器5bである。この水質改良器5bは、水槽の浅いところから深いところまで、水質改良材12,12,12、…を拡散して配設することにより、水との接触効率を高めるようにしたことが特徴である。しかも本発明に係る水質改良器5bは、構造が簡単で製造し易く、しかも浮力体により水槽内を回遊自在にできるので、水槽全体の水質改良効率が相当に高く実用性がある。 Example 2 is an example of a water quality improver 5b of a drooping formula as shown in FIG. 7 A spherical buoyant body 9 having a buoyancy capable of floating in water as shown in FIG. A mounting frame 10 is attached to the periphery, and a plurality of ropes 11, 11, 11,... Are suspended from the mounting frame 10, and tourmaline and / or each of the ropes 11, 11, 11,. This is a water quality improver 5b in which a plurality of lumps or spherical bodies of water quality improving materials 12, 12, 12,... Mainly composed of a titanium oxide photocatalyst are attached. This water quality improver 5b is characterized in that the contact efficiency with water is improved by diffusing and arranging the water quality improving materials 12, 12, 12,... From the shallow part to the deep part of the water tank. is there. Moreover, the water quality improver 5b according to the present invention has a simple structure, is easy to manufacture, and can be freely moved in the water tank by a buoyant body, so that the water quality improvement efficiency of the entire water tank is considerably high and has practicality.
1:水槽
2:水
3:供給口
4:配水口
5a:水質改良器
5b:水質改良器
6:キャップ
7:窓
8:紫外線フィルター
9:浮力体
10:取り付け枠
11:索条
12:水質改良材
13:室内照明用のランプ
14:透水材
15:突起部
16:外周壁
17:空気
18:透水性外周壁
19:水質改良材収納空間
20:水質改良材収納室
1: Water tank 2: Water 3: Supply port 4: Water distribution port 5a: Water quality improver 5b: Water quality improver 6: Cap 7: Window 8: Ultraviolet filter 9: Buoyant body 10: Mounting frame 11: Strip 12: Water quality improvement Material 13: Lamp for indoor lighting 14: Water permeable material 15: Projection 16: Outer wall 17: Air 18: Water permeable outer wall 19: Water quality improving material storage space 20: Water quality improving material storage room
Claims (6)
トルマリンおよび/または酸化チタン系光触媒を主体とする水質改良材と、当該水質改良材を水中浮遊させることのできる浮力を有する浮力体とを備えた水質改良器とを用意し、
当該水槽内に収納されている水中に水質改良器を浮遊させ、
水の対流と水質改良器の回遊により水と水質改良材との接触を良好にするとともに、
水槽内に透過した紫外線により水質改良器の酸化チタン系光触媒を活性化するようにしたことを特徴とする水質改良方法。 A water tank in which a window is provided in a part, and an ultraviolet transmission filter that blocks visible light and transmits only ultraviolet rays is attached to the window,
A water quality improver comprising a water quality improving material mainly composed of tourmaline and / or a titanium oxide photocatalyst, and a buoyant body having a buoyancy capable of floating the water quality improving material in water,
Float a water quality improver in the water stored in the tank,
With good convection of water and migration of the water quality improver, good contact between the water and the water quality improving material,
A method for improving water quality, wherein a titanium oxide photocatalyst of a water quality improver is activated by ultraviolet rays transmitted through a water tank.
当該区画された複数の水質改良材収納室内に、トルマリンおよび/または酸化チタン系光触媒を主体とする球形の水質改良材を適度の余裕空間が生ずる量を収納し、姿勢が変化すると重力によって水質改良材が水質改良材収納室内を遊動自在なるようになし、
前記透水性外周壁の適所には突起部を形成し、水流や水圧の変化によっても姿勢を変化させることができるようにしたことを特徴とする水質改良器。 A spherical permeable outer peripheral wall having a larger diameter is formed on the outer periphery of a spherical buoyant body having a buoyancy capable of floating in water, with a net-like body or a water-permeable material having a large number of water-permeable holes, and the buoyancy Forming a water quality improvement material storage space between the outer periphery of the body and the water permeable outer peripheral wall, dividing the water quality improvement material storage space and partitioning a plurality of water quality improvement material storage chambers;
A plurality of water quality improvement material storage chambers are divided into spherical water quality improvement materials mainly composed of tourmaline and / or titanium oxide photocatalysts. The material is made freely movable in the water quality improvement material storage room,
A water quality improver characterized in that a protrusion is formed at an appropriate position of the water permeable outer peripheral wall so that the posture can be changed by a change in water flow or water pressure.
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Cited By (2)
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JP2013031812A (en) * | 2011-08-02 | 2013-02-14 | Shinyo:Kk | Water activator |
CN105692778A (en) * | 2016-03-07 | 2016-06-22 | 圆融健康科技(深圳)有限公司 | Intelligent DUV (deep-ultraviolet) water sterilization device and intelligent DUV sterilization system |
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CN104128171B (en) * | 2014-07-02 | 2016-09-21 | 昆明理工大学 | A kind of composite of titanium dioxide and Linesless charcoal and preparation method thereof |
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JP4882859B2 (en) | 2012-02-22 |
WO2008136532A1 (en) | 2008-11-13 |
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