JP2008274506A - Japanese paper taking health and sanitation into account - Google Patents

Japanese paper taking health and sanitation into account Download PDF

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JP2008274506A
JP2008274506A JP2007142527A JP2007142527A JP2008274506A JP 2008274506 A JP2008274506 A JP 2008274506A JP 2007142527 A JP2007142527 A JP 2007142527A JP 2007142527 A JP2007142527 A JP 2007142527A JP 2008274506 A JP2008274506 A JP 2008274506A
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japanese paper
paper
powder
japanese
propolis
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Hayashi Nagataki
林 長瀧
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a Japanese paper taking health and sanitation into account for precaution of sick house syndrome, expected to have effective action for long time while adding effect to the Japanese paper by using a natural material. <P>SOLUTION: The Japanese paper can be modified to have potentials of adsorption, humidity conditioning, air purification, deodorant, antibacterial, sterilising and preservative efficacy by dispersing powder of both "Bakuhanseki" 17 (quartz porphyry or granite porphyry), which is a natural porous ore, and powder of propolis chunk 18 which is a natural material, on the surface and inside of the Japanese paper. The prolongment of these effects can be expected. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は、壁紙、障子、インテリア用品等に用いられる和紙に、麦飯石粉末とプロポリス原塊粉末を分散させることによって健康及び衛生面を考慮した和紙に関する。  The present invention relates to Japanese paper considering health and hygiene by dispersing barley stone powder and propolis bulk powder in Japanese paper used for wallpaper, shoji, interior goods, and the like.

近年、一般住宅やオフィスビル等の建築物は省エネルギー効果対策が進み、気密性や断熱性を高めている。その結果、不完全な換気で室内に湿気が留まり、結露が生じるために建築物が腐食しやすくなる。また、ダニやカビが発生しやすい環境にあるため、それらの死骸がハウスダストとなり室内に漂い人体の健康に悪影響を及ぼす原因となる。そこで、建築材料には防腐剤や防カビ剤等が使用されている。  In recent years, buildings such as ordinary houses and office buildings have been improved in energy saving effect and have improved airtightness and heat insulation. As a result, dampness remains in the room due to incomplete ventilation, and dew formation occurs, so that the building is easily corroded. In addition, because of the environment where ticks and molds are likely to be generated, these dead bodies become house dust and drift inside the room, which can adversely affect human health. Therefore, antiseptics, fungicides and the like are used for building materials.

しかしながら、建築材料に防腐剤や防カビ剤等を使用することにより、それらに含有されているホルムアルデヒド、トルエン、キシレン、アセトアルデヒド等の有害な揮発性有機化合物(以下、有害化学物質という)が室内の大気中に放散され、頭痛等の自立神経障害やうつ状態等の精神障害、呼吸困難等の呼吸器障害、発疹等の皮膚障害等といった様々な症状が現れるシックハウス症候群が大きな社会問題となっている。  However, by using preservatives and fungicides for building materials, harmful volatile organic compounds such as formaldehyde, toluene, xylene, and acetaldehyde (hereinafter referred to as hazardous chemical substances) contained in the building Sick house syndrome, which is diffused into the atmosphere and manifests various symptoms such as mental disorders such as headaches, mental disorders such as depression, respiratory disorders such as breathing difficulties, skin disorders such as rash, etc. is a major social problem .

シックハウス症候群対策には、室内の有害化学物質の濃度を低減させることが有効であるため、最近では建築物に有害化学物質の含有量が少ない建築材料が使用されるようになった。  As countermeasures against sick house syndrome, it is effective to reduce the concentration of harmful chemical substances in the room, and recently, building materials with a low content of harmful chemical substances have been used in buildings.

けれども、有害化学物質は建築材料のみからではなく、室内の家具やカーテン、芳香剤、防虫剤等の多種多様な化学製品から大気中に放散されるているのが現状である。  However, at present, harmful chemical substances are released into the atmosphere not only from building materials but also from a wide variety of chemical products such as indoor furniture, curtains, fragrances and insect repellents.

そこで、多孔質物質である炭化物を用いて室内の有害化学物質を吸着させて大気中への再放散を防ぐ方法が取られている。例えば、特許文献1では活性炭を熱融着粉体及び熱融着繊維を介して内部に固定させたシートや、特許文献2では内装紙の裏面に炭化物を積層させた壁紙に関する技術が提案されている。
特開2004−313860号公報 特開2005−060867号公報
In view of this, a method has been adopted in which harmful chemical substances in the room are adsorbed using carbide, which is a porous substance, to prevent re-emission into the atmosphere. For example, Patent Document 1 proposes a technique related to a sheet in which activated carbon is fixed inside through heat-bonding powder and heat-bonding fibers, and Patent Document 2 proposes a technique related to wallpaper in which carbide is laminated on the back surface of interior paper. Yes.
JP 2004-313860 A JP-A-2005-060867

しかしながら、有害化学物質の吸着材料として炭化物を用いても、炭化物自体が吸着物質の分解作用という特性を保有していないので、すぐに炭化物の孔が飽和状態になり目詰まりをしてしまうため、その効果を長く続かせることが難しい。  However, even if carbide is used as an adsorbing material for harmful chemical substances, the carbide itself does not possess the property of decomposition of the adsorbing substance, so the pores of the carbide immediately become saturated and clogged. It is difficult to keep the effect for a long time.

本発明の目的は、シックハウス症候群対策を行うためのものであり、上述の課題を鑑みて、混紙材が天然のものでありつつ効果の長期化が期待できる素材を選定して、これらを和紙の表面のみならず内部にまで分散させることにより、和紙本来の持つ効果を向上させ、さらに新たな効果も付加させて健康及び衛生面を考慮した和紙を提供することにある。  An object of the present invention is to take measures against sick house syndrome, and in view of the above-mentioned problems, a material that can be expected to have a long-lasting effect while selecting a natural paper mixed material is selected, and these are made in Japanese paper. It is to provide Japanese paper considering health and hygiene aspects by improving the original effect of Japanese paper by dispersing it not only on the surface but also inside.

天然の多孔質鉱石である麦飯石と天然素材であるプロポリス原塊の必ず両者を、和紙への混入材料(以下、混紙材という)として用いて、それを和紙の表面及び内部へ分散させることによって和紙本来が保有している吸着、調湿効果を向上させつつ大気浄化、消臭、抗菌、殺菌、防腐効果を付加させたことを特徴とする。  Be sure to use both natural porcelain ore and natural propolis block as materials mixed in Japanese paper (hereinafter referred to as mixed paper material) and disperse it on the surface and inside of Japanese paper. It is characterized by adding air purification, deodorization, antibacterial, sterilization, and antiseptic effects while improving the adsorption and humidity control effects inherent in Japanese paper.

さらに、混紙材である麦飯石とプロポリス原塊が粉末で、プロポリス原塊粉末の粒径は麦飯石粉末の粒径以上であることを特徴とする。  Furthermore, the barley stone and the propolis raw mass which are mixed paper materials are powders, and the particle size of the propolis raw bulk powder is equal to or larger than the particle size of the barley stone powder.

また、混紙材を和紙の表面及び内部へ分散させるため、叩解工程にてビーターに和紙の原材料と水を入れて叩解した後に、紙用糊と混紙材を加えて攪拌させて調整した溶液(以下、混紙溶液)から抄造することを特徴とする。尚、混紙溶液中における混紙材の割合は、和紙の原材料に対して麦飯石粉末が0.1〜10%重量、プロポリス原塊粉末が0.1〜5%重量であることが好ましい。  In addition, in order to disperse the mixed paper material on the surface and the inside of the Japanese paper, after adding the Japanese paper raw material and water to the beater in the beating process, the solution was adjusted by adding the paper paste and the mixed paper material and stirring. (Hereinafter referred to as a mixed paper solution). In addition, the ratio of the mixed paper material in the mixed paper solution is preferably 0.1 to 10% by weight of the barleystone powder and 0.1 to 5% by weight of the propolis raw powder with respect to the raw material of the Japanese paper.

本発明によれば、麦飯石粉末とプロポリス粉末を和紙の表面及び内部に容易に分散させることができ、それらの性質により室内に放散されている有害化学物質を吸着・分解して再放散を防止する大気浄化効果、臭いを吸着・分解する消臭効果、埃を吸収する吸着効果、湿気を吸放出し湿度を一定に保つ調湿効果、バクテリア、大腸菌等を吸着・分解する抗菌効果、殺菌効果、防腐効果を望める。加えて、これらの効果の長期化も望めるようになる。  According to the present invention, barley stone powder and propolis powder can be easily dispersed on the surface and inside of Japanese paper, and the harmful chemical substances diffused indoors due to their properties are adsorbed and decomposed to prevent re-emission. Cleansing effect, deodorization effect that absorbs and decomposes odor, adsorption effect that absorbs dust, humidity control effect that absorbs and releases moisture and keeps humidity constant, antibacterial effect that absorbs and decomposes bacteria, Escherichia coli, etc., bactericidal effect Can expect antiseptic effect. In addition, it is hoped that these effects will be prolonged.

また、本発明の和紙自体が天然の材料から抄造されており自らが有害化学物質を含有していないので、室内の壁紙や障子、インテリア用品等に用いるのにも適しているし、廃棄の際に燃やしたとしても環境を汚すことはない。  In addition, the Japanese paper of the present invention itself is made from natural materials and does not contain any harmful chemical substances. Therefore, it is suitable for use in indoor wallpaper, shoji, interior goods, etc. Even if burned, it will not pollute the environment.

以下、本発明の実施の形態を図面に基づき詳細に説明する。  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

図1〜図2は本発明の実施の形態に係り、図1はその横断面図、図2は製造工程のフローチャートである。  1 to 2 relate to an embodiment of the present invention, FIG. 1 is a cross-sectional view thereof, and FIG. 2 is a flowchart of a manufacturing process.

和紙16には湿度の高い時に湿気を吸収し、また低い時には蓄えていた湿気を放出する調湿効果、埃を吸収する吸着効果があり、それ自体がコウゾ、三椏、ケナフ等の天然素材を原材料としているため壁紙、障子、インテリア用品等に和紙を用いることはシックハウス症候群対策において有効である。  Washi 16 absorbs moisture when the humidity is high, and releases moisture stored when the humidity is low, and has an adsorption effect that absorbs dust. It itself is made from natural materials such as Kozo, Mitsugi, and Kenaf. Therefore, using Japanese paper for wallpaper, shoji, interior goods, etc. is effective in preventing sick house syndrome.

また、天然の鉱石である麦飯石17は、多孔質のため表面積が非常に広く、いくら小さく砕いても多孔性を持ち続けるという性質がある。麦飯石1gの孔の総表面積は数百mにもなり、同じような構造の同質量の活性炭に比べて約2万倍にもなるため吸着能力が非常に強い。また、大きく活性炭と異なる点は、単に物を吸着するだけではなく、有害化学物質、化学合成物、バクテリア、カドニウム、シアン、大腸菌、水銀、塩素、アンモニア等の分解・除去能力も保有していることが明らかになっている。このため、麦飯石の孔は飽和状態になり難いので、麦飯石17の吸着能力の低下は緩やかである。以上の性質により、麦飯石17には室内に放散されている有害化学物質を吸着・分解して再放散を防止する大気浄化効果、室内の臭いを吸着・分解する消臭効果、バクテリア、大腸菌等を吸着・分解する抗菌効果、湿気を吸放出し湿度を一定に保つ調湿効果が期待できる。また、これらの効果の長期化も期待することができる。Moreover, the barleystone 17 which is a natural ore has a property that it has a very large surface area because of its porosity, and continues to have porosity even if it is crushed to a small extent. The total surface area of 1 g of barley stone is as high as several hundred m 2, which is about 20,000 times that of activated carbon having the same structure and the same mass, so the adsorption capacity is very strong. Also, the main difference from activated carbon is not only adsorption of substances, but also possesses the ability to decompose and remove harmful chemical substances, chemical compounds, bacteria, cadmium, cyanide, E. coli, mercury, chlorine, ammonia, etc. It has become clear. For this reason, since the pores of the barley stone are unlikely to become saturated, the decrease in the adsorption capacity of the barley stone 17 is gradual. Due to the above properties, the barley stone 17 adsorbs and decomposes harmful chemical substances that are diffused indoors to prevent re-emission, air purification effects that absorb and decompose indoor odors, bacteria, Escherichia coli, etc. Antibacterial effect that adsorbs and decomposes moisture, and humidity control effect that keeps humidity constant by absorbing and releasing moisture can be expected. In addition, prolongation of these effects can be expected.

一方で、プロポリス原塊18は、ミツバチが自然界の様々な樹木から集めた樹脂等を自らの内分泌液である唾液とともに噛み砕いて作られたものであり、フラボノイドを主成分として含有しているためにバクテリア等の殺菌や抗菌、防腐効果を保有している天然素材である。  On the other hand, the propolis block 18 is made by chewing resin collected from various trees in nature with saliva, which is its endocrine solution, and containing flavonoids as the main component. It is a natural material possessing bactericidal, antibacterial and antiseptic effects such as bacteria.

上述の麦飯石17とプロポリス原塊18の必ず両方を和紙16への混紙材にすることによって、それぞれ3者の効果を充分に発揮しながら、その相乗効果により和紙に吸着、調湿、大気浄化、抗菌、殺菌、防腐効果を保持させることができる。例えば、和紙に麦飯石を分散させることによって、和紙本来の持つ吸着、調湿効果が向上するし、麦飯石とプロポリス原塊の両者を混紙材として用いることにより抗菌効果を向上させることができる。  By making both the above-mentioned barley stone 17 and the propolis bulk block 18 into a mixed paper material for the Japanese paper 16, each of the three effects can be fully exerted, and the synergistic effects can be adsorbed on the Japanese paper, humidity control, and air. Purifying, antibacterial, bactericidal and antiseptic effects can be retained. For example, by dispersing barley-stone in Japanese paper, the adsorption and humidity control effects inherent in Japanese paper are improved, and the antibacterial effect can be improved by using both barley-stone and propolis bulk as a mixed paper material. .

従来の和紙の製造工程は、和紙の原材料を煮沸することによって繊維質にし易くする煮熟工程、ビーターにて煮熟された原材料と水を入れて叩解する叩解工程、抄紙機にかけて紙を漉く抄紙工程、ポンプによって厚さ調整をする圧縮工程、プレスして水分調整を行い乾燥させる乾燥工程の順番にて行われる。  The traditional Japanese paper manufacturing process consists of a ripening process that makes the Japanese paper raw material boiled easily, a beating process in which the raw material cooked in a beater and water are beaten, and a paper machine is used for papermaking. The process is performed in the order of a compression process in which the thickness is adjusted by a pump, and a drying process in which the moisture is adjusted by pressing and dried.

本発明の和紙は、図2に示すように叩解工程にてビーターに和紙の原材料と水を入れて叩解した後に、紙用糊と混紙材を加えて攪拌させて調整した混紙溶液を生成する工程(以下、混紙溶液生成工程という)を従来の和紙の製造工程に加える。この工程で生成された混紙溶液をタンクに溜めて抄紙機にかけることにより図1に示すような表面及び内部にまで混紙材を分散させた和紙を抄造することが非常に容易になる。  As shown in FIG. 2, the Japanese paper of the present invention produces a mixed paper solution prepared by adding a paper paste and a mixed paper material and stirring the beater after adding the Japanese paper raw material and water to the beater in the beating process. To the conventional Japanese paper manufacturing process (hereinafter referred to as a mixed paper solution generation process). By collecting the mixed paper solution generated in this process in a tank and applying it to a paper machine, it becomes very easy to make a Japanese paper in which the mixed paper material is dispersed to the surface and inside as shown in FIG.

尚、混紙溶液生成工程での混紙材である麦飯石17とプロポリス原塊18は粉末でなければならない。混紙材を粉末にすることによって混紙溶液中に容易に分散させることができるし、紙用糊をバインダーとさせることができるので混紙溶液中での沈殿の防止にもなる。また、この時に注意すべきことは、多孔質である麦飯石粉末の孔の中にプロポリス原塊粉末が入り込むことにより目詰まりをすることを防止するため、プロポリス原塊粉末の粒径は麦飯石粉末の粒径以上でなければならない。加えて、混紙溶液中における混紙材の割合は、和紙の原材料に対して麦飯石粉末が0.1〜10%重量、プロポリス原塊粉末が0.1〜5%重量であることが好ましい。混紙材の割合をこれ以上増やしてしまうと和紙の風合を損なうばかりか、抄造することさえも困難になってしまう。  In addition, the barley stone 17 and the propolis original lump 18 which are mixed paper materials in a mixed paper solution production | generation process must be a powder. By making the mixed paper material into powder, it can be easily dispersed in the mixed paper solution, and the paper paste can be used as a binder, so that precipitation in the mixed paper solution can be prevented. In addition, it should be noted at this time that the particle size of the propolis bulk powder is to prevent clogging due to the propolis bulk powder entering the pores of the porous barley stone powder. Must be greater than the particle size of the powder. In addition, the ratio of the mixed paper material in the mixed paper solution is preferably 0.1 to 10% by weight of the barley stone powder and 0.1 to 5% by weight of the propolis raw powder with respect to the raw material of the Japanese paper. . If the ratio of the mixed paper material is increased further, the texture of the Japanese paper will be impaired, and even papermaking will be difficult.

本発明の実施の形態を示す和紙の横断面図  Cross-sectional view of Japanese paper showing an embodiment of the present invention 図1における和紙の製造工程のフローチャート  Flow chart of the Japanese paper manufacturing process in FIG.

符号の説明Explanation of symbols

16 和紙
17 麦飯石
18 プロポリス原塊
16 Japanese paper 17 Barley rice stone 18 Propolis block

Claims (5)

天然の多孔質鉱石である麦飯石と天然素材であるプロポリス原塊の必ず両者を、混紙材として用いて、それを和紙の表面及び内部へ分散させることによって和紙本来が保有している吸着、調湿効果を向上させつつ大気浄化、消臭、抗菌、殺菌、防腐効果を付加させたこと特徴とする和紙。  Adsorption that the original Japanese paper possesses by using both the natural porcelain ore and the natural raw material propolis block as a mixed paper material and dispersing it on the surface and inside of the Japanese paper, Japanese paper characterized by the addition of air purification, deodorization, antibacterial, sterilization and antiseptic effects while improving the humidity control effect. 混紙材の麦飯石とプロポリス原塊が粉末であることを特徴とする請求項1記載の和紙。  The Japanese paper according to claim 1, wherein the mixed paper material barley-stone and propolis ingot are powder. プロポリス原塊粉末粒径は麦飯石粉末の粒径以上であることを特徴とする請求項1〜請求項2記載の和紙。  The Japanese paper according to claim 1, wherein the propolis bulk powder particle size is equal to or greater than the particle size of the barley stone powder. 叩解工程にてビーターに和紙の原材料と水を入れて叩解した後に、紙用糊と混紙材を加えて攪拌させて調整した溶液から抄造することを特徴とする請求項1〜請求項3記載の和紙。  The paper is made from a solution prepared by adding a paper paste and a mixed paper material and stirring the mixture after beating the raw material of Japanese paper and water in a beater in the beating step. Japanese paper. 混紙材の割合は、和紙の原材料に対して麦飯石粉末が0.1〜10%重量、プロポリス原塊粉末が0.1〜5%重量であることを特徴とする請求項1〜請求項4記載の和紙。  The ratio of the mixed paper material is 0.1 to 10% by weight of the barleystone powder and 0.1 to 5% by weight of the propolis bulk powder with respect to the raw material of the Japanese paper. 4 Japanese paper.
JP2007142527A 2007-04-26 2007-04-26 Japanese paper taking health and sanitation into account Pending JP2008274506A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102673061A (en) * 2012-05-18 2012-09-19 王甦之 Double-layer food-grade stone paper and manufacturing method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102673061A (en) * 2012-05-18 2012-09-19 王甦之 Double-layer food-grade stone paper and manufacturing method thereof

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