JP2008264768A - Treatment method of incineration ash and treatment equipment of incineration ash - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a treatment method of incineration ash capable of reducing a treatment cost for reuse as a cement raw material or the like and efficiently removing chlorine contained in the incineration ash such as main ash and fly ash discharged from an incinerator, and treatment equipment of incineration ash. <P>SOLUTION: The treatment method of the incineration ash for cleaning the incineration ash comprises: a first process of cleaning incineration main ash separated and recovered from the incineration ash while separating unburned matters and inappropriate matters; and a second process of classifying the incineration main ash separated and cleaned in the first process. The incineration main ash separated and recovered from the incineration ash is fed to the first process without being cleaned beforehand. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

  The present invention relates to a processing facility for processing a granular processing object mixed with a coarse material, and more particularly, to a processing method for incineration ash for cleaning incineration ash and a processing facility for incineration ash.

  When resources such as ash and soil mixed with metal, glass (stones, glass pieces, etc.) and organic materials (rubber, plastic, paper, fiber, wood pieces, etc.) are reused. In addition, it is necessary to separate and remove coarse substances and to remove various water-soluble components and heavy substances such as heavy metals that impede resource recycling.

  For example, when purifying and reusing contaminated soil where miscellaneous waste has been illegally dumped, the soil is excavated to separate and remove coarse materials such as metals, glass, and organic materials, and adhere to soil and sand. It is necessary to remove harmful components such as heavy metals.

  Incineration ash, such as incineration main ash and fly ash, is generally landfilled at the final disposal site, or disposed of in a melting furnace at a high temperature and then reduced to chemically stable slag. In view of problems such as saturation of the capacity of the final disposal site, it is considered to be reused as a raw material for cement.

  In general, when incineration residues such as incineration ash generated in municipal waste incineration facilities are reused as raw materials for cement, it is first necessary to separate and remove coarse materials such as metals, glass, and organic materials from the incineration residues. .

  Furthermore, when the incineration ash is preheated with a preheating device and then baked in a rotary kiln, etc., there is a problem that the device is corroded by the chlorine component contained in the incineration ash, so the incineration ash is washed with water in advance to remove chlorine. There is a need to.

  In addition, when incinerated ash is used as a raw material for ordinary Portland cement, which accounts for about 70% of domestic cement consumption, it is necessary to remove chlorine in order to prevent corrosion of reinforcing bars in concrete.

Patent Document 1 discloses a recovery process for recovering incineration ash discharged from a municipal waste incinerator into separate receiving tanks for main ash and fly ash, pulverizing the main ash in the main ash receiving tank of the recovery process, A pulverization step for obtaining pulverized particles having a diameter of 200 μm or less, a dedioxin step for decomposing dioxins by treating fly ash in the fly ash receiving tank of the recovery step at a temperature of 300 to 450 ° C. in a reducing atmosphere, and There has been proposed a method for treating incinerated ash that includes a washing step in which the main ash obtained from the pulverization step and the fly ash obtained from the dedioxin step are washed with water and the solid content with reduced chlorine components is recovered.
JP 2003-103232 A

  However, the method described in Patent Document 1 has a problem that the efficiency is poor because the main ash obtained from the pulverization step and the fly ash obtained from the dedioxin step are mixed and simultaneously washed with water.

  In general, the chlorine concentration in the incinerated main ash is about 1%, whereas the chlorine concentration in the fly ash is as high as 8 to over 10%, and it is inefficient to wash these together. Not only is a large amount of washing water required, but a large-scale biological treatment tank is required to purify a large amount of washing wastewater by collecting fly ash that does not contain organic components and main ash that contains organic components. It becomes.

  In addition, most cleaning equipment is not intended for miscellaneous solids such as leftovers, paper, wood chips, fibers, vinyl, and other unburned materials contained in incinerator main ash, glass, and metals. There was also a problem that it must be removed efficiently.

  In this way, the necessity of efficiently removing obstacle substances mixed in the processing object by washing the granular processing object mixed with a coarse material is not limited to incineration ash, and miscellaneous waste is illegal. Common to dumped contaminated soil particles.

  This invention is made | formed in view of the conventional problem mentioned above, reduces the processing cost for reusing as a cement raw material etc., and incinerated ash, such as main ash and fly ash discharged | emitted from an incinerator. It aims at providing the processing method of the incineration ash which can remove the chlorine contained efficiently, the processing equipment of the incineration ash, and the processing apparatus of the granular processing object mixed with the coarse thing.

  In order to achieve the above object, the characteristic configuration of the incineration ash processing method according to the present invention is the incineration ash processing method for cleaning the incineration ash as described in claim 1 of the claims. The first step of cleaning the incinerated main ash separated and recovered from the incinerated ash while separating unburned and unsuitable materials, and the second step of classifying the incinerated main ash separated and washed in the first step It is in.

  In the first step, the incinerated main ash is washed, and unburned materials and unsuitable materials are separated and removed at the same time. In the second step, only the incinerated main ash is appropriately washed. Accordingly, unburned materials and unsuitable materials are not mixed in the second step, and the classification process can be smoothly performed.

  In addition to the first feature configuration described above, the second feature configuration according to claim 2 is the same as the first feature configuration described above, but the incineration main ash separated and recovered from the incineration ash is not cleaned in advance. The point is that it is put into one process.

  In the third feature configuration, in addition to the first or second feature configuration described above, the first step is to put incinerated main ash into a cleaning tank filled with cleaning water. Then, the floating substance separation process for separating unburned substances floating in the washing water, the unsuitable substance removal process for removing unsuitable substances that settle in the washing water, and the incineration main ash from which the floating substances and unsuitable substances have been removed And a transporting process for transporting to the classifying process.

  In the fourth feature configuration, as described in claim 4, the first step is performed while cleaning the incinerated main ash charged in the pulsation washing tank in which the filled washing water pulsates up and down, and the specific gravity difference Floating substance separation process that floats unburned material contained in the incineration main ash and transports it with the upper washing water, unsuitable substance removal process that accepts and transports unsuitable substances that settle in the washing water due to the difference in specific gravity, and It is in the point provided with the conveyance process which conveys the incineration main ash which settles to a subsequent classification process.

  The fifth characteristic configuration is the incineration ash treatment method for cleaning the incineration ash as described in claim 5, wherein the incineration main ash separated and recovered from the incineration ash is treated with unburned or unsuitable materials. A cleaning process for cleaning while separating, a classification process for classifying the incinerated main ash after the cleaning process based on a standard particle size set in advance in multiple stages, and a reinspection of the incinerated main ash on the small diameter side after the classification process A re-washing step, and the classification step and the re-washing step are repeated in order from the largest to the smallest particle size of the incinerated main ash after the washing step.

  The inventor of the present application has conducted extensive research and found that the incinerated main ash has a different chlorine content depending on the particle size, and the smaller the particle size, the higher the chlorine content. That is, as shown in FIG. 4, the chlorine content varies greatly depending on the particle size of the incinerated main ash, the coarse ash having a particle size of 2 mm or more based on the chlorine content, and the particle size of 0.15 mm to 2 mm. It was classified into fine ash and fine ash with a diameter smaller than 0.15 mm, and new knowledge was obtained that dechlorination could be performed efficiently by changing the cleaning conditions. According to the above-described configuration, the incinerated ash is classified in multiple stages based on the reference particle size set in multiple stages based on the chlorine content, so that large-diameter particles having a relatively small chlorine content are washed in a small amount. Incinerated ash with a large chlorine content and a small particle size can be washed in multiple stages while being sufficiently dechlorinated with water. In addition, the main ash for incineration is washed, and the incineration fly ash with a high chlorine content is not washed at the same time, so the dechlorination treatment can be performed effectively with a small amount of washing water, reducing the treatment cost. Can do it.

  In addition to the fifth feature configuration described above, the sixth feature configuration is the same as the fifth feature configuration described above, wherein the cleaning step is performed by injecting incinerated main ash into a cleaning tank filled with cleaning water, and A floating substance separation process for separating unburned substances, an unsuitable substance removal process for removing unsuitable substances that settle, a conveying process for conveying the incinerated main ash from which floating substances and unsuitable substances have been removed to a subsequent classification process, A cleaning water replenishing step of replenishing the cleaning tank with cleaning water is provided.

  The main ash from which unburned materials such as paper and wood chips contained in the incinerated main ash put into the cleaning tank are removed in the floating substance separation process, and large-diameter metals and glass are removed in the unsuitable substance removal process It is washed in the inside, and is conveyed to the subsequent classification step together with the washing water in the conveyance step. By draining a part of the washing water in the tank in the transport process and replenishing the washing water in the washing water replenishment process, it is possible to avoid the concentration of the chlorine reaching saturation due to the dissolved chlorine in the washing tank. Thus, the cleaning performance can be maintained.

  In addition to the sixth feature configuration described above, the seventh feature configuration is crushed after removing the metal from the unsuitable matter removed in the unsuitable matter removing step, as described in claim 7. It exists in the point which throws in to-be-crushed processed material in the said washing | cleaning process.

  According to the above-mentioned composition, the recycle rate of the incineration main ash can be raised by crushing the unsuitable thing and throwing it into the washing process.

  The first characteristic configuration of the incineration ash treatment facility according to the present invention is the incineration ash treatment facility for cleaning the incineration ash as described in claim 8, wherein the incineration main ash separated and recovered from the incineration ash In the point which comprises the washing | cleaning apparatus which isolate | separates unburned material and unsuitable thing, and the classification apparatus which classifies the incinerator main ash after washing | cleaning.

  In the second characteristic configuration, as described in claim 9, the cleaning device is filled with cleaning water, has a tubular pulsating cleaning tank in which an upper part is branched into two and a lower part is connected, and the pulsating A pulsation generator that pulsates the cleaning water in the cleaning tank, and the upper cleaning water by floating unburned substances contained in the incinerated main ash due to the difference in specific gravity while cleaning the incinerated main ash charged into the pulsating cleaning tank And a discharge device for carrying out, a conveyor device for receiving and carrying out unsuitable objects that settle in the washing water due to the difference in specific gravity, and a conveyor device for carrying the incinerated main ash settling to the bottom to the subsequent classification process. .

  The third characteristic configuration is an incineration ash treatment facility for cleaning incineration ash as described in claim 10, wherein the incineration main ash separated and recovered from the incineration ash is treated with unburned or unsuitable materials. Installed in the rear stage of each classifier, and a classifier that classifies the incinerated main ash after cleaning based on the standard particle size set in multiple stages in order from large to small. A plurality of re-cleaning devices for re-cleaning the incinerated main ash classified to the small diameter side and a dehydrating device for dehydrating the incinerated main ash re-washed by the re-cleaning device are provided.

  According to the configuration described above, the incinerated main ash is rewashed in multiple stages as the main ash having a higher chlorine content, so that the main ash having a larger particle size can be efficiently cleaned from the main ash having a smaller particle size. It is possible to increase the reuse rate.

  In the fourth feature configuration, as described in claim 11, in addition to any one of the first to third feature configurations described above, the cleaning device includes a cleaning tank filled with cleaning water, An oscillating mechanism for pulsating the washing water filled in the washing tank, a floating substance separation mechanism for separating unburned substances floating from the incinerated main ash charged in the washing tank, and an unsuitable thing for removing unsuitable substances that settle. Jig sorting equipped with a removal mechanism, a transport mechanism that transports the incinerated main ash that has been removed from floating and unsuitable materials and settled to the bottom to a subsequent classifier, and a cleaning water replenishment mechanism that replenishes the cleaning tank with cleaning water It is in that it is composed of devices.

  According to the above-described configuration, the wash water in the tank is pulsated by the vibration mechanism, so that the incinerated main ash that has been thrown in is effectively dispersed and washed in the wash water. Then, unburned materials such as paper and wood chips contained in the incinerated main ash are removed by the floating substance separation mechanism, and the main ash from which large-sized metals and glass are removed by the inappropriate material removal mechanism is further washed in the tank. As it is, it settles in the tank and is transported to the subsequent classifier by the transport mechanism. At this time, a part of the cleaning water is drained by the transport mechanism, and new cleaning water is replenished by the cleaning water replenishment mechanism, so that the concentration of chlorine in the cleaning tank is not saturated. As a result, the cleaning performance is maintained.

  In the fifth feature configuration, in addition to any one of the first to fourth feature configurations described above, the incinerator main ash charging portion formed in the cleaning device is a garbage incinerator. The incinerator main ash which is provided in the lower part of the ash chute and incinerated in the furnace and dropped from the ash chute is charged.

  According to the above-described configuration, the incineration main ash that is incinerated in the furnace and falls from the ash chute is sorted and cleaned on the spot, so even if the incineration ash treatment facility is far away, it is useless. This makes it possible to reduce the cost of transport. For example, the separated unburned material can be incinerated again on the spot, eliminating the need to transport large-diameter metals and glass to waste incineration ash processing equipment. Further, since the dechlorination treatment is performed before the chlorine content in the incinerated main ash forms Friedel's salt, the dechlorination treatment can be performed with less washing water or a shorter washing time.

  The characteristic configuration of the processing facility according to the present invention is a processing facility for cleaning a granular processing object mixed with a coarse material as described in claim 13, wherein the processing object is cleaned while the processing object is being cleaned. A cleaning device for sorting into powder particles and a classification device for classifying the powder particles separated and washed by the cleaning device are provided.

  As described above, according to the present invention, the processing cost for reusing as a cement raw material is reduced, and chlorine contained in incineration ash such as main ash and fly ash discharged from the incinerator is efficiently obtained. An incineration ash processing method and incineration ash processing equipment that can be removed, and a processing equipment for processing a granular processing object mixed with a coarse product can be provided.

  The incineration ash treatment facility attached to the garbage incineration facility will be described below. As shown in FIG. 1, the waste incineration facility includes a waste pit 1 for collecting collected garbage, a furnace body A for incinerating waste, an exhaust gas treatment equipment B for treating combustion exhaust gas generated in the furnace body A, and the like. It is configured with.

  The furnace main body A pushes and throws in the furnace the hopper 3 into which the trash held by the bucket 2A of the crane apparatus 2 installed on the ceiling portion of the trash pit 1 is put, and the trash put into the hopper 3 into the furnace. A pusher 4 and a stoker-type incineration treatment zone 16 that incinerates the introduced garbage while being conveyed are provided, and the incinerated residue is configured to fall from the ash chute 17.

  The exhaust gas treatment facility B includes a waste heat boiler 7 that recovers heat of exhaust gas generated in the furnace, a catalytic desulfurization device that renders sulfur oxides contained in the exhaust gas harmless, an activated carbon adsorption tower that adsorbs toxic components, dust, etc. The solid matter separated by the exhaust gas treatment mechanism 11 is collected as incineration fly ash. Furthermore, the generator 9 that generates power by the steam turbine 8 driven by the steam supplied from the waste heat boiler 7 and the water (condensate) sent from the steam turbine 8 are heated and returned to the waste heat boiler 7. The economizer 10 and the like sent to the flue are provided, and the exhaust gas purified by the exhaust gas treatment facility B is attracted by the induction blower 12 and exhausted from the chimney 13.

  As shown in FIG. 3, the incineration ash treatment equipment includes a jig sorting device 18 as a washing device for washing incineration main ash having a particle size of 200 mm or less while separating unsorted and unsuitable materials, and a washed incineration. First and second classifiers 24 and 40 for classifying incinerated main ash from the main ash in advance from the largest to the smallest based on the reference particle size set in multiple stages based on the chlorine content, and each classifier 24, First and second re-cleaning devices 41 and 42 for re-cleaning the incinerated main ash classified on the small-diameter side and the incinerated main ash re-washed by the second re-cleaning device 44 are rinsed water. The first dewatering device 45 that is rinsed and dewatered in the ash, the ash sedimentation tank 42 that settles the fine ash classified on the large diameter side by the second classifying device 40, and the incineration fly ash recovered from the exhaust gas treatment mechanism 11 A slurrying device 46 for mixing with washing water to form a slurry; And it is configured to Lee reduction has been incineration fly ash and the like second dewatering device 47 for dewatering.

  FIG. 4 is a value obtained by analyzing the content of chlorine after sieving the incinerated main ash with a mesh width of 4.75 mm, 2 mm, 1 mm, 0.3 mm, and 0.15 mm and sprinkling water. From the figure, in coarse ash with a particle size of 2 mm or more, chlorine is removed to 1000 mg / Kg or less that can be sufficiently used as a cement raw material only by simple cleaning treatment, and for fine ash with a particle size of 0.15 mm to 2 mm It is understood that the chlorine content is almost the same as 1600 to 2000 mg / Kg, the fine ash having a diameter smaller than 0.15 mm is 3000 mg / Kg, and the chlorine content is larger than the fine ash having a particle diameter of 0.15 mm to 2 mm. Is done. In addition, the distribution of the chlorine content with respect to the particle size of the main ash has some differences depending on the properties of the waste incinerated in the waste incinerator. In such a case, the chlorine content for each particle size is analyzed in advance. Therefore, it is necessary to adjust the classification size to a size suitable for desalting.

  As shown in FIG. 2, the jig sorting device 18 includes a cleaning tank 20 composed of a U-shaped tube filled with cleaning water, and a vibration mechanism 21 that pulsates the cleaning water filled in the cleaning tank 20. A floating substance separation mechanism 22 that separates floating substances from the incinerated main ash charged into the washing tank 20, and an inappropriate substance removal mechanism 23 that removes metals and glass larger than the maximum reference particle size as inappropriate substances. The bucket-type transport mechanism 25 that transports the incinerated main ash that has been removed from the floating and unsuitable materials and settled to the bottom together with the cleaning water to the first classifier 24, and the cleaning that has been reduced in the transport process by the transport mechanism 25 A washing water replenishing mechanism 26 for replenishing the washing tank 20 with water is provided, and a charging portion of the incinerated main ash to the washing tank 20 is provided below the ash chute 17 of the incinerator.

  The vibration mechanism 21 is disposed at one end of a U-shaped tube, and includes a motor 27, a rotating plate 28 connected to the motor 27, and a water vibrating plate 30 connected to the rotating plate 28 via a piston 29. It consists of When the rotating disk 28 is rotated by driving the motor 27, the water vibration plate 30 connected via the piston 29 is moved up and down to raise and lower the water surface at one end of the washing tank 20, thereby Pulsate 20 wash water. By pulsating the surface of the washing water, the floating ash and unsuitable substances are removed while performing a washing process in which the incinerated main ash containing the floating substances and unsuitable substances put into the washing tank 20 is dispersed and washed in the tank. Do.

  The floating substance separation mechanism 22 includes a floating substance discharge port 31 provided at the other end side of the cleaning tank 20 and unburned floating substances such as wood pieces and paper discharged from the floating substance discharge port 31. The floating substance is discharged from the floating substance discharge port 31 together with the overflow water by the washing water pulsated by the vibration mechanism 21 and is collected by the floating substance collecting part 32. . The suspended matter separated from the washing water in the floating matter collecting unit 32 is returned to the garbage pit 1 to be reprocessed in the incinerator, and the washing water is returned by the washing water collecting mechanism 19 having a pump 33 and a washing water pipe 34. It is collected in the cleaning tank 20.

  The inadequate material removal mechanism 23 is composed of a mesh conveyor mechanism 35 that is arranged so that a part thereof passes through the cleaning water of the cleaning tank 20, and is put into the cleaning tank 20 and incinerated main ash that settles on the mesh conveyor. Among them, the incinerated main ash having a particle size smaller than that of the mesh settles as it is, and unsuitable materials having a large particle size are conveyed and removed out of the tank by the mesh conveyor. The mesh conveyor mechanism 35 removes unsuitable materials such as metals and glass having a particle size of 10 mm or more, and the metal from which the metals have been removed by the metal recovery mechanism 36a is crushed by the crushing device 36b and incinerated main ash As shown in FIG.

  The transport mechanism 25 is composed of a bucket conveyor mechanism 38 in which a plurality of buckets 37 each having a plurality of small-diameter openings are arranged along an endless track, and an incinerator main body settled and deposited on the bottom of the cleaning tank 20. The ash is scraped out together with the washing water by the bucket 37 and conveyed to the first classifier 24. In addition, the amount of the wash water taken out and the amount of the wash water to be replenished are adjusted by setting the hole diameter and the aperture ratio of the opening to appropriate values.

  The first classifier 24 is composed of a vibration sieve device, and the incinerated main ash having a diameter smaller than 10 mm washed by the jig sorting device 18 is composed of coarse ash having a particle size of 2 mm or more and first fine ash having a particle size of less than 2 mm. Classify. After the classified coarse ash having a particle size of 2 mm or more is charged into the first watering device 39, free water in the ash is dehydrated by gravity in the storage facility and recovered as a cement raw material. The fine ash is put into the first re-cleaning device 41 and cleaned again.

  The chlorine concentration in the coarse ash satisfies the cement manufacturer's acceptance standard of 1000 mg / Kg or less, and even when washed, the chlorine content hardly changes, so washing is performed from the viewpoint of water and energy utilization efficiency. Is to end.

  The first re-cleaning device 41 includes a stirring device 41b including a stirring motor 41a, and an ash slurry transport pipe 41d that transports the cleaned incinerated main ash to the second classifying device 40 via a pump 41c. The re-washed first fine ash is further classified by the second classifier 40.

  The second classifier 40 is composed of a wet cyclone and classifies it into second fine ash having a particle size of 0.15 mm to 2 mm and third fine ash having a particle size of less than 0.15 mm. The classified second fine ash settles in the ash settling tank 42 and is discharged by the scraping device 43, and free water in the ash is dehydrated by gravity in the storage facility and collected as a cement raw material. Further, the classified third fine ash is supplied to the second re-cleaning device 44 and cleaned again. The concentration of chlorine contained in the third fine ash is about twice that of the second fine ash, and further cleaning of the third fine ash reduces the chlorine content and enables effective reuse as a cement raw material. .

  The second re-cleaning device 44 includes a stirring device 44b having a stirring motor 44a and a treated water transport pipe 44d for transporting the re-washed incinerated main ash to the first dehydrating device 45 through the pump 44c. The re-washed second fine ash is dehydrated by the first dehydrator 45 and then recovered as a cement raw material.

  The filtrate produced in the first dehydrator 45 is stored in a dehydrated filtrate tank 48, a part of which is used to replenish the washing water of the jig sorting device 18, and the remaining liquid is sent to the first water treatment device 49. Then, it is discharged after water purification treatment such as calcium removal, biological denitrification, coagulation sedimentation, sand filtration and activated carbon filtration. That is, the washing water replenishing mechanism 26 is constituted by the pump 48 c connected to the dehydrated filtrate tank 48 and the pipe line connected to the jig sorting device 18. Further, washing wastewater having a low chlorine concentration, such as the rinse water filtrate used in the first watering device 39, is returned to the jig sorting device 18 by the washing water replenishing mechanism 26 and reused.

  The fly ash collected from the exhaust gas treatment mechanism 11 is fed into the slurrying device 46 and washed, and then sent to the second dehydrating device 47. The slurried incineration fly ash is dehydrated by the second dehydrator 47 and recovered as a cement raw material. The filtrate from the second dehydrator 47 is stored in the treated water tank 50 and discharged after the second water treatment device 51 performs water removal treatment such as calcium removal, sand filtration, and activated carbon.

  As described above, a cleaning process for cleaning the incinerated main ash separated and recovered from the incinerated ash by the jig sorting apparatus 18 while separating unburned and unsuitable materials is performed, and chlorine is previously contained in the incinerated main ash after cleaning. A classifying step for classifying large-diameter incineration main ash based on the reference particle size set in a plurality of stages based on the rate is performed in the first and second classifiers 24 and 40, and the remaining small-diameter incineration main ash The re-washing process for re-washing is performed by the first and second re-washing devices 41 and 44, and the classification step and the re-washing are performed in order from the largest to the smallest particle size with respect to the incinerated main ash after washing. It is comprised so that a process may be repeated.

  Another embodiment of the present invention will be described below. In the above-described embodiment, an example in which the incineration ash treatment facility is provided in the waste incineration facility is shown so that the incineration main ash falling from the ash chute 17 of the incinerator can be directly input to the jig sorting device 18. Although what was comprised was demonstrated, you may comprise so that the incineration main ash which falls to the water-sealed conveyor from the ash chute | shoot 17 and was collect | recovered by the ash pit may be thrown into the jig | tool sorter 18. FIG. The incineration ash treatment facility may be constructed in an area separated from the site of the waste incineration facility.

  In the above-described embodiment, the incineration main ash, which is a granular processing object mixed with a coarse material, has been described as being directly input into the jig sorting apparatus. However, before being put into the jig sorting apparatus, the incineration main ash is coarse from the incinerated main ash. It may be configured to be put into a jig sorter after separating and removing the material, or after removing the coarse material, the metal mixed in the incinerated main ash may be collected using a magnetic separator. . This is because the incinerator main ash may be mixed with coarse items such as bicycles, pans, and kettles, and in such cases, it may be difficult to operate the jig sorting device smoothly.

  When separating and removing coarse materials, arrange steel bars on the frame in a posture that the downstream side is inclined at regular intervals along the direction of flow of the coarse materials, and the frame or steel bar is vibrated by a vibrator. A grizzly vibratory feeder can be used.

  In the above-described embodiment, an example in which a classification process is performed in a multi-stage classification process after the cleaning process of separating unburned and unsuitable substances from the incinerated main ash is performed using the jig sorting apparatus has been described. However, the method for treating incineration ash according to the present invention includes a first step of washing the incinerated main ash separated and recovered from the incineration ash while separating unburned and unsuitable materials, and the incineration separated and washed in the first step. What is necessary is just to have the 2nd process which classifies main ash, and the 2nd process is not restricted to what has a plurality of classification processes, and may have only one classification process. By such a processing method, unburned materials and unsuitable materials are not mixed in the second step, and the classification process can be smoothly performed.

  Moreover, the structure of the classification apparatus used for a one-stage classification process is not specifically limited, A well-known classification apparatus, such as a vibration sieve apparatus, a wet cyclone, a flowing water classifier, can be used suitably.

  In the embodiment described above, the incinerated main ash is classified into three according to the particle size, but is not limited to this, and depending on the incinerated main ash, it is classified into two or four or more, and a classification process and a re-cleaning process for each. It is also possible to perform.

  In the above-described embodiment, a jig sorting device is used as the cleaning device. However, the present invention is not limited to this, and a sorting device other than the jig sorting device may be used as long as it removes suspended matter and inappropriate materials from the incinerated main ash. It is also possible to use it.

  Below, the processing method and processing equipment of the incineration ash using the jig sorter whose composition differs from the jig sorter mentioned above are explained.

  As shown in FIG. 8, the granular material processing system 100 sorts the granular material into a coarse particle and a granular material while washing the incinerated ash that is the object to be processed, and the granular material from the fine particle and the fine particle. Wet-sorting means 200 for classifying medium grains having a large particle size, first re-washing means 400 for re-washing the fine particles classified by the wet-sorting means 200, and re-sorting the intermediate grains classified by the wet-sorting means 200 A second re-cleaning means 600 for cleaning is provided.

  Furthermore, the first waste water discharged from the first re-cleaning means 400 is returned to the wet sorting means 200, and the waste water discharged from the second re-cleaning means 600 is returned to the second re-cleaning means 200. A second circulation path 900 that returns to the cleaning means is provided, and the cleaning wastewater returned through each circulation path is reused as cleaning water.

  As shown in FIG. 5 to FIG. 7, the wet sorting means 200 includes a washing water tank 120 having a rectangular shape in plan view, filled with washing water and inclined at the bottom, and one upper opening communicating with the washing water tank 120, and the other opening. A U-shaped pulsating washing tank 121 provided with a pulsation generating device 130, one opening of the pulsating washing tank 121 and the inclined bottom of the washing water tank 120, are rotatably supported by pulleys 122a, 122b, 122c. A plurality of conveyor belts 122 having a mesh-like transport surface, and water jet nozzles 123a and 123b that are provided along the rotation direction of the conveyor belt 122 and that form a water flow in a direction opposite to the rotation direction of the conveyor belt 122. , 123c, and 123d.

  The pulsation generator 130 includes an eccentric sheave 133 connected to move the plunger 131 up and down through the bellows 137 and the rod 132 from the vicinity of the water surface of the other opening of the pulsation washing tank 121, and the rotational shaft of the eccentric sheave 133 is provided. A motor 134 that rotates is provided.

  The number of rotations of the motor 134 is adjusted by the inverter device, and the bellows 137 is expanded and contracted as the motor 134 rotates, so that the water in the cleaning water tank 120 pulsates in the vertical direction via the pulsating cleaning tank 121.

  The pulsation generator 130 includes a stroke length adjustment mechanism (not shown) that adjusts the stroke length of the plunger 131 that moves up and down, and can change the height of the pulsating liquid surface.

  As the stroke length adjusting mechanism, a mechanism for adjusting the mounting position of the plunger 131 in the vertical direction, a mechanism for adjusting the length of the rod 132, and a mechanism for adjusting the mounting position of the rod 132 on the eccentric sheave 133 in the diametrical direction are used. Can do.

  The pulsation washing tank 121 is divided into three along the extending direction of the conveyor belt 122, and eccentric sheaves 133 to which the rotation shafts 135 are attached at different eccentric positions are arranged, and pulsations with different phases are applied.

  The processing object conveyed to the wet sorting means 200 by the belt conveyor device 136 is put into the washing water tank 120 by the vibration feeder 124, dispersed by the vertical pulsation of the washing water by the pulsation washing tank 121, and mixed into the ash. Among the coarse materials, metals and glass having large specific gravity (such as stones and glass pieces) are discharged from the coarse material outlet 125 by the conveyor belt 122 after the ash adhering to the washing water is removed, and organic materials having a small specific gravity ( Rubber, plastic, paper, fiber, wood chips, etc.) float on the water surface and flow out from the overflow weir 126 to the drainage basin 127 according to the water flow by the water injection nozzles 123a, 123b, 123c, 123d.

  That is, in the wet sorting means 200, a specific gravity sorting step is performed in which the coarse product is sorted into a coarse product with a large specific gravity and a coarse product with a low specific gravity by the specific gravity difference.

  Further, the ash charged into the washing water tank 120 is dispersed by the vertical pulsation of the washing water in the pulsating washing tank 121, and the medium ash (coarse ash) that has a large sedimentation speed and settles against the upward pulsating flow. And fine ash) settles in the water tank, and the fine ash having a low sedimentation velocity floats in the washing water according to the water flow by the water injection nozzles 123a, 123b, 123c, 123d and flows out from the overflow weir 126 to the drainage basin 127.

  That is, in the wet sorting means 200, a classification step is performed in which the ash that is a granular material is classified into fine ash and medium ash having a larger particle size than the fine ash due to a difference in sedimentation speed.

  In the course of the specific gravity sorting step and the classification step, obstructive substances such as salt adhering to coarse substances and granular materials are washed away. That is, as shown to Fig.9 (a), a granular material processing system classifies a granular material into two or more groups while classifying into a coarse thing and a granular material, wash | cleaning a process target object. Further, as shown in FIG. 9B, the wet sorting means sorts the coarse product into a coarse product with a large specific gravity and a coarse product with a low specific gravity by the difference in specific gravity, and the fine particles and fine particles are separated by the difference in sedimentation speed. Classification into medium particles having a particle size larger than that of the particles.

  Metals and glass discharged from the bulk material outlet 125 are separated and collected by the metal recovery unit 110 such as a magnetic separator, and the overflow water flowing out to the drainage 127 is drained by a draining screen 128. After the organic material is removed, it is sent to the first re-cleaning means 400 together with the fine ash. At this time, the draining screen 128 may spray the cleaning water to clean the organic material.

  A plurality of buckets 129a having a plurality of small-diameter openings formed side by side or at the bottom are arranged side by side along an endless track in the middle ash that has settled from the opening formed at the bottom of the pulsating washing tank 121 to the bottom of the washing water tank 120. While being drained by the bucket conveyor mechanism 129, it is carried out of the tank and further cleaned by the second re-cleaning means 600.

  In the first re-cleaning means 400, the overflow water passing through the draining screen 128 is accumulated in the relay tank 140 provided as necessary, the concentration is uniformly stirred by the stirring pump, and the fine ash contained in the overflow water is discharged by the pump. It is sent to a thickener as the concentrating device 142 and concentrated. As the concentrating device 142, a known device such as a wet cyclone, a belt concentrator, or a centrifugal concentrator can be used. Further, a chemical agent 141 such as a flocculant such as a sulfuric acid band, a pH adjuster, or a chelating agent may be added to the relay tank 140.

  The concentrated fine ash is pulled out from the bottom of the thickener, sent to the relay tank 143 and stirred and washed with new washing water supplied from the water supply tank 101, and then dehydrated and washed by the dehydration washing apparatus 144. To be served. In addition, without providing the relay tank 143, the fine ash concentrated by the thickener may be sent directly to the dehydrating and cleaning apparatus 144 and dehydrated while injecting cleaning water. As such a dehydration washing apparatus 144, a filter press, a centrifugal dehydrator, a belt-type dehydrator, or the like can be used. The supply amount of the wash water is adjusted according to the salt concentration of the supernatant of the thickener. If the salt concentration is high, the supply amount of the wash water is increased.

  Note that the fine ash may be sent directly from the relay tank 140 to the dehydration washing device 144 without providing the concentration device 142.

  The washing waste water from the dehydrating and cleaning device 144 is drained into the relay tank 145 and finally stored in the storage tank 146.

  The storage tank 146 is divided into three chambers by two weirs with different heights, and the waste water overflowing the higher weir is stored in the final storage tank 147 and purified by the water treatment device and discharged outside the system. Is done.

  The cleaning wastewater separated by the concentrating device 142 and the dehydrating and cleaning device 144 and stored in the storage tank 146 is returned to the wet sorting means 200 via the first circulation path 800 by the pump, and the water injection nozzles 123a, 123b, 123c, and 123d. It is used as re-washing water in the washing water tank 120 via

  Moreover, since the washing waste water separated by the concentrating device 142 has a high concentration of obstacle substances, it is preferentially discharged out of the system, so it is sent to the storage tank 147 without passing through the storage tank 146, and only when the washing water is insufficient. It may be configured to be sent to the storage tank 146 and used as rewash water.

  In addition, the water injection provided in the lower part of the plunger 131 of the pulsation washing tank 121 separately from the route which supplies the rewash water supplied from the first circulation path 800 via the water injection nozzles 123a, 123b, 123c, and 123d. Routes supplied from the section 121a may be provided, and the supply ratio of rewash water through each route may be adjusted. By adjusting the ratio supplied from the water injection part 121a and adjusting the speed of the upward flow in the pulsation washing tank 121, the particle size to be classified can be set by controlling the sedimentation speed of the powder.

  The salt content of the fine ash is higher than the salt content of the midstream ash, and the salt content of the cleaning effluent from the first re-cleaning means 400 is higher than the cleaning effluent of the second re-cleaning means 600. The second re-cleaning means 600 is separated and returned to the wet sorting means 200.

  In this way, in the wet sorting means 200 and the first re-cleaning means 400, the cleaning process is performed with the cleaning wastewater having a high salt concentration, but a new cleaning is supplied to the dehydration cleaning apparatus 144 via the concentration apparatus 142. The amount of water (rinse water) can be suppressed very slightly.

  The second re-cleaning means 600 classifies the medium ash carried out of the tank by the bucket conveyor mechanism 129 into coarse ash and fine ash, and the fine particles classified by the classification device 161. A cleaning device 162 for re-cleaning is provided. The classifying device 161 is configured by a wet vibrating screen device, and is dropped from the bucket conveyor mechanism 129 via the chute 160. A screen device can be used as the classification device 161.

  The chute 160 and the classifier 161 are sprayed with cleaning wastewater having a low salinity concentration circulated and supplied via the second circulation path 900, and new cleaning water is supplied from the water supply tank 101 on the downstream side of the classifier 161. Is spray-fed and the classified coarse ash is drained as it is and used as a cement raw material. Coarse ash having a large particle size has a small amount of adhering salts, and therefore does not require much washing.

  The cleaning device 162 includes a relay tank 163 that stores fine particles and cleaning wastewater that have passed through the classification device 161, and a wet cyclone as a solid-liquid separator 164 that separates the fine ash that has been stirred and washed again in the relay tank 163 into a solid and liquid. And a washing tank 165 for washing the fine ash solid-liquid separated by the wet cyclone.

  Fine ash settled in the ash settling tank is rinsed with new washing water (rinse water) supplied from the water supply tank 101 while being carried out by the ash lifting conveyor 166, and then used as a cement material. . The overflow water in the cleaning tank 165 is circulated and supplied to the relay tank 163.

  The washing wastewater separated by the wet cyclone is circulated and supplied as washing water to the chute 160 and the classifier 161 described above, and after the excess washing wastewater is stored in the storage tank 102, it is supplied as washing water for the wet sorting means 200. The The washing waste water separated by the wet cyclone contains fine ash that has not been sufficiently separated by the wet sorting means 200, and such fine ash passes through the second circulation path 900 and again by the wet sorting means 200. Classified. The solid-liquid separator 164 is not limited to a wet cyclone, and may be configured to separate fine ash and washing wastewater using a known dehydrator, a sedimentation tank, or the like.

  The second circulation path 900 includes a circulation path 191 for returning the cleaning waste water from the cleaning tank 165 to the relay tank 163 and a circulation path 192 for returning the waste water of the solid-liquid separator 164 to the classifying device 161.

  That is, as shown in FIG. 9 (c), the granular material processing system includes a first re-cleaning unit for re-cleaning the fine particles, a second re-cleaning unit for re-cleaning the medium particles, A first circulation path for returning cleaning wastewater discharged from one recleaning means to the wet sorting means; and a second circulation path for returning cleaning wastewater discharged from the second recleaning means to the second recleaning means. A circulation path is provided, and the washing wastewater returned through each circulation path is reused as washing water.

  Further, as shown in FIG. 9 (d), the first re-cleaning means includes a concentrating device for concentrating the fine particles and a washing and dehydrating device for washing and dewatering the fine particles concentrated by the concentrating device. The separated separated liquid is returned to the wet sorting means through the first circulation path.

  Furthermore, as shown to Fig.10 (a), a 2nd re-washing means is a classifier which classifies a medium grain thing into a coarse grain thing and a fine grain thing, and a washing apparatus which re-washes the classified fine grain substance It has.

  Further, as shown in FIG. 10 (b), the cleaning device includes a relay tank for fine particles, a solid-liquid separator for solid-liquid separation of the re-washed fine particles, and a fine-particle material that has been subjected to solid-liquid separation. The second circulation path has a circulation path for returning the washing waste water from the washing tank to the relay tank, and a circulation path for returning the waste water of the solid-liquid separator to the classification device. .

  In the present embodiment, the case where the relay tank 163 and the solid-liquid separator 164 are configured in one stage is shown, but the relay tank 163 and the solid-liquid separator are arranged in a plurality of stages in two or more stages. In this case, as shown in FIG. 11, the second circulation path includes a circulation path for transferring the waste water of the subsequent solid-liquid separator to the relay tank immediately before the solid-liquid separator, and a washing tank. It is preferable to provide a circulation path for transferring the waste water to the relay tank immediately before the washing tank and a circulation path for returning the waste water of the first-stage solid-liquid separator to the classification device.

  As described above, in the processing system of the granular material, in order to clean the granular processing object mixed with coarse material and remove the obstacle substance mixed in the processing object, the processing object is processed by the wet sorting process. While the product is being washed, a coarse particle and a granular material are sorted and a granular material processing method is performed in which the granular material is classified into two or more groups, and the wet sorting process has a large specific gravity due to a difference in specific gravity. A specific gravity selection step of selecting a coarse product and a coarse product having a small specific gravity, and a classification step of classifying the granular material into a fine product and a medium product having a larger particle size than the fine product by a difference in settling speed are performed.

  In addition, the first re-cleaning step for re-washing the fine particles, the second re-washing step for re-washing the medium-sized particles, and the washing wastewater discharged in the first re-washing step are used as washing water for the wet sorting step In addition, the cleaning wastewater discharged in the second rewashing process is returned as cleaning water in the second rewashing process, and each cleaning wastewater is reused as cleaning water.

  A part of the rewash water in the second rewash process is returned to the wet sorting process, and is effectively used as the rewash water in the first rewash process. Therefore, while simplifying the equipment and reducing the amount of water to be washed, coarse substances mixed in the treatment object are washed and removed, and the circulation path of the washing wastewater is separated into two systems, so that water-soluble components are separated from the granular material. And obstructive substances such as heavy metals can be efficiently removed.

  Although the cleaning tank of the jig sorting device 18 and the wet sorting means 200 described above is configured in a U-shaped tube shape, the shape of the cleaning tank is not limited to the U-shaped tube shape, and the upper part branches into two. As long as the tube shape is connected to the lower portion, it may be V-shaped or Y-shaped.

  In the above-described embodiment, the powder processing system and the powder processing system have been described in which incinerated ash mixed with coarse materials such as metals, glass, and organic materials is treated. The object to be treated by the body treatment system and the particulate treatment system is not limited to incinerated ash, but is soil contaminated with heavy metals, such as landfilled soil illegally dumped. This method can also be applied to the case where the powdered soil particles are recycled as resources. In this case, heavy metal contaminants are washed away from the earth and sand.

  The specific configuration of each part described in the above-described embodiment is merely an example, and it is needless to say that the design can be appropriately changed within the scope of the effects of the present invention.

Explanatory drawing of the waste incinerator equipped with the incineration ash treatment facility according to the present invention Explanatory drawing of the washing | cleaning apparatus of the processing equipment of incineration ash by this invention Explanatory drawing of incineration ash processing equipment according to the present invention Explanatory drawing of chlorine concentration in incineration main ash Explanatory drawing of the wet-sorting means which shows another embodiment of this invention and is used for the processing system of a granular material Top view of the wet sorting means Explanatory drawing of the main part of the wet sorting means Explanatory drawing of processing system of granular material Block explanatory diagram of powder processing system Block explanatory diagram of powder processing system Block explanatory diagram of powder processing system

Explanation of symbols

1: garbage pit 2A: bucket 2: crane device 3: hopper 4: pusher 7: waste heat boiler 8: steam turbine 9: generator 10: economizer 11: exhaust gas treatment mechanism 12: induction blower 13: chimney 16: incineration treatment zone 17 : Ash chute 18: Jig sorting device 19: Washing water recovery mechanism 20: Washing tank 21: Shaking mechanism 22: Floating substance separation mechanism 23: Improper object removal mechanism 24: First classifier 25: Transport mechanism 26: Washing water replenishment Mechanism 27: Motor 28: Turntable 29: Piston 30: Water vibrating plate 31: Floating material discharge port 32: Floating material collecting unit 33: Pump 34: Washing water pipe 35: Mesh conveyor mechanism 36a: Metal collecting mechanism 36b: Crushing device 37 : Bucket 38: Bucket conveyor mechanism 39: First sprinkler 40: Second classifier 41: First recleaning device 42: Ash settling tank 43: Scraping device 44 Second re-cleaning device 45: first dewatering device 46: slurrying device 47: the second dewatering device 48: dehydration filtrate tank 49: first water treatment apparatus 50: treatment water tank 51: second water treatment apparatus

Claims (13)

An incineration ash treatment method for cleaning incineration ash,
Incineration ash comprising a first step of cleaning the incinerated main ash separated and recovered from the incinerated ash while separating unburned and unsuitable materials, and a second step of classifying the incinerated main ash separated and washed in the first step Processing method.   The incineration ash treatment method according to claim 1, wherein the incineration main ash separated and recovered from the incineration ash is put into the first step without being washed in advance.   In the first step, the incinerated main ash is put into a washing tank filled with washing water to remove unburned substances floating in the washing water, and unsuitable items that settle in the washing water are removed. The incinerated ash treatment method according to claim 1, further comprising: an unsuitable substance removing step; and a transporting step of transporting the incinerated main ash from which suspended matter and unsuitable materials have been removed to a subsequent classification step.   In the first step, while washing the incinerated main ash charged into the pulsation washing tank in which the filled washing water pulsates up and down, the unburned matter contained in the incinerated main ash is floated by the specific gravity difference, and the upper layer is washed Equipped with a floating substance separation process that carries out with water, an unsuitable substance removal process that accepts and discharges unsuitable substances that settle in the washing water due to the difference in specific gravity, and a transportation process that transports the incinerated main ash that settles to the bottom to the subsequent classification process The incineration ash processing method according to claim 1 or 2. An incineration ash treatment method for cleaning incineration ash,
The incineration main ash separated and recovered from the incineration ash is cleaned while separating unburned and unsuitable materials, and the incineration main ash after the cleaning process is classified based on a standard particle size set in multiple stages in advance. A classification step, and a re-washing step for re-washing the incineration main ash on the small diameter side after the classification step, the classification step and the above in order from the largest to the smallest particle size with respect to the incineration main ash after the washing step Incineration ash treatment method that repeats the re-cleaning process.   The cleaning step includes injecting the main incinerator ash into a cleaning tank filled with cleaning water to separate the floating unburned matter, the unsuitable matter removing step for removing the unsuitable matter that settles, and the floating step. 6. A method for treating incinerated ash according to claim 5, further comprising: a transporting step for transporting the incinerated main ash from which the waste and unsuitables have been removed to a subsequent classification step; .   The method for treating incinerated ash according to claim 6, wherein metal is removed from the unsuitable material removed in the unsuitable material removing step and then crushed, and the material to be crushed is put into the washing step. Incineration ash processing equipment for cleaning incineration ash,
Incineration ash processing equipment comprising a cleaning device that cleans incinerated main ash separated and recovered from incinerated ash while separating unburned and unsuitable materials, and a classification device that classifies the incinerated main ash after cleaning .   The cleaning device is filled with cleaning water, has a tubular pulsation cleaning tank in which the upper part is branched into two and the lower part is connected, a pulsation generator for pulsating the cleaning water in the pulsating cleaning tank, and the pulsating cleaning While washing the incinerator main ash that has been put into the tank, the unburned material contained in the incinerator main ash is floated due to the difference in specific gravity, and discharged with the upper cleaning water. The incineration ash processing equipment according to claim 8, further comprising: a conveyor device that receives and conveys the incinerator main ash that sinks to the bottom and conveys the incinerated main ash to a subsequent classification step. Incineration ash processing equipment for cleaning incineration ash,
A cleaning device that cleans the incinerated main ash separated and recovered from the incinerated ash while separating unburned and unsuitable materials, and the main size of the incinerated main ash after cleaning based on standard particle sizes set in multiple stages. A plurality of classifiers for classifying in that order, a plurality of rewashing devices installed at the subsequent stage of each classifying device to rewash the incinerated main ash classified on the small diameter side, and the incinerators rewashed by the recleaning device Incineration ash treatment equipment that is equipped with a dehydration device that dehydrates ash.   The cleaning device separates a floating tank filled with cleaning water, a vibration mechanism that pulsates the cleaning water filled in the cleaning tank, and unburned substances floating from the incinerated main ash charged into the cleaning tank. Floating substance separation mechanism, unsuitable substance removal mechanism that removes unsuitable sediments, a transport mechanism that removes suspended matter and unsuitable substances and settles the incinerated main ash that has settled to the bottom, to a subsequent classifier, and washing water The incineration ash treatment facility according to any one of claims 8 to 10, comprising a jig sorting device having a washing water replenishing mechanism for replenishing the washing tank.   The incinerator main ash input portion formed in the cleaning device is provided below the ash chute of the incinerator, and the incinerated main ash that has been incinerated in the furnace and dropped from the ash chute is input. Incineration ash processing equipment described in Crab. A processing facility for cleaning a granular processing object mixed with a coarse material,
A processing facility comprising a cleaning device that sorts a coarse object and a granular material while cleaning an object to be processed, and a classification device that classifies the granular material separated and washed by the cleaning device.

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