JP2008240121A - Ferritic stainless steel for exhaust system diameter-expanded member having excellent spinning workability - Google Patents
Ferritic stainless steel for exhaust system diameter-expanded member having excellent spinning workability Download PDFInfo
- Publication number
- JP2008240121A JP2008240121A JP2007085741A JP2007085741A JP2008240121A JP 2008240121 A JP2008240121 A JP 2008240121A JP 2007085741 A JP2007085741 A JP 2007085741A JP 2007085741 A JP2007085741 A JP 2007085741A JP 2008240121 A JP2008240121 A JP 2008240121A
- Authority
- JP
- Japan
- Prior art keywords
- less
- spinning
- stainless steel
- ferritic stainless
- exhaust system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000009987 spinning Methods 0.000 title claims abstract description 39
- 229910001220 stainless steel Inorganic materials 0.000 title claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims description 9
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910000831 Steel Inorganic materials 0.000 description 15
- 239000010959 steel Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 11
- 230000007797 corrosion Effects 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 238000012545 processing Methods 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000000137 annealing Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000001105 regulatory effect Effects 0.000 description 3
- 230000006872 improvement Effects 0.000 description 2
- 238000010409 ironing Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 238000003466 welding Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000005097 cold rolling Methods 0.000 description 1
- 238000009749 continuous casting Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000001953 recrystallisation Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000002436 steel type Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Images
Landscapes
- Shaping Metal By Deep-Drawing, Or The Like (AREA)
- Heat Treatment Of Sheet Steel (AREA)
Abstract
Description
本発明は、マフラーや触媒コンバータのハウジング等の、排気系膨径部材の素材として好適なフェライト系ステンレス鋼に関し、特にスピニング加工性の優れたフェライト系ステンレス鋼に関するものである。 The present invention relates to a ferritic stainless steel suitable as a material for an exhaust system expanding member such as a muffler and a housing of a catalytic converter, and more particularly to a ferritic stainless steel excellent in spinning workability.
自動車の排気系部材には、従来、加工性と耐食性に優れたSUS 409L、SUS429或いはSUS 436Lなどのフェライト系ステンレス鋼が多用されている。例えば、自動車のエンジンから排出された排気ガスを処理する、触媒コンバータのハウジングやマフラーがその一例である。 Conventionally, ferritic stainless steels such as SUS 409L, SUS429, and SUS 436L, which are excellent in workability and corrosion resistance, are frequently used as exhaust system members of automobiles. For example, a catalytic converter housing or a muffler that processes exhaust gas discharged from an automobile engine is an example.
上記したハウジングの一般的な形状を図1に示す。同図に示したとおり、触媒コンバータのハウジングは、触媒担体を収容する比較的大径の本体r1 とエキゾーストパイプに接続される比較的小径の接続部r3を有し、さらに本体r1 から接続部r3 に向かって漸次小径となるテーパ状のコーン部r2 とにより構成されている。 The general shape of the housing described above is shown in FIG. As shown in the drawing, the catalytic converter housing have a relatively small diameter of the connecting portion r 3, further from the body r 1 is connected to the larger diameter body r 1 and exhaust pipe for accommodating the catalyst carrier A tapered cone portion r 2 having a gradually decreasing diameter toward the connecting portion r 3 .
このような触媒コンバータのハウジングは、一般に、本体r1 とほぼ同じ径の素管をスピニング加工により成形して製造される場合が多い。例えば、特許文献1には、素管の一端を芯金上に固定し、素管の外周に案内ロールを備えたローラーを複数個対称的に配備して、しごき加工を行う方法が開示されている。また、特許文献2には、素管を3つのローラーで把持し、ローラーの傾斜角を規定して、素管を回転することにより、しごき加工を行う方法が開示されている。
In general, such a catalytic converter housing is generally manufactured by forming an element tube having the same diameter as that of the main body r 1 by spinning. For example,
このようなスピニング加工によってテーパを有する管材を成形する方法は、板材をプレスしてそれらを溶接にて接合して製造する方法に比べて、
1)材料の歩留りが良い、
2)一体成形が可能で溶接部の信頼性低下がない、
3)型が不要、
4)工数が少ない
等の利点があるが、一方で、プレスを利用する方法に比べるとスピニング加工時に特に溶接部での割れ(図2におけるw参照)発生確率が高くなるとの問題があった。
1) Good material yield,
2) Integrated molding is possible and there is no decrease in the reliability of the weld.
3) No need for mold,
4) Although there are advantages such as fewer man-hours, on the other hand, there is a problem that the probability of occurrence of cracks (see w in FIG. 2) in the welded portion is particularly high during spinning processing as compared with a method using a press.
すなわち、本発明は、管の端部などの溶接部にスピニング加工を施す際の割れの発生を抑制し得る、排気系膨径部材に供するフェライト系ステンレス鋼について提案することを目的とする。 That is, an object of the present invention is to propose a ferritic stainless steel for use in an exhaust system expansion member capable of suppressing the occurrence of cracks when spinning a welded portion such as an end of a pipe.
さて、発明者らは、スピニング加工の際の素管溶接部からの割れの確率が、同一鋼種を素材として用いた場合であっても、コイル毎に異なることから、鋼中の成分および鋼中の不純物成分がスピニング加工性に影響を及ぼしていると考え、これらの鋼中成分がスピニング加工性に及ぼす影響について、綿密な調査、検討を行った。その結果、鋼成分に関し、Al+TiおよびCr+6Siの各量を規制して、スピニング加工における割れの確率が飛躍的に低減されることの知見を得た。本発明は、上記の知見に立脚するものである。 Now, since the probabilities of cracks from the welded portion of the raw pipe during the spinning process are different for each coil even when the same steel type is used as the material, the components in the steel and the steel The effect of these impurities on the spinning processability was investigated, and the effects of these steel components on the spinning processability were investigated and examined. As a result, regarding the steel components, the amount of Al + Ti and Cr + 6Si was regulated to obtain the knowledge that the probability of cracking in spinning processing was drastically reduced. The present invention is based on the above findings.
すなわち、本発明の要旨構成は、次のとおりである。
1.質量%で、
C:0.02 %以下、
Si:2.0%以下、
Mn:2.0%以下、
Ni:0.6 %以下、
Nb:0.1〜1.0%、
P:0.040%以下、
S:0.01 %以下および
N:0.02%以下
を含み、さらにCrをCr +6Si:12.0〜22.0%の関係を満足する範囲において、またAlおよびTiをAl+Ti:0.010%以下の関係を満足する範囲において、それぞれ含有し、残部はFeおよび不可避的不純物の組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。
That is, the gist configuration of the present invention is as follows.
1. % By mass
C: 0.02% or less,
Si: 2.0% or less,
Mn: 2.0% or less,
Ni: 0.6% or less,
Nb: 0.1-1.0%
P: 0.040% or less,
S: 0.01% or less and N: 0.02% or less, and Cr in a range satisfying the relationship of Cr + 6Si: 12.0 to 22.0%, and Al and Ti in a range satisfying the relationship of Al + Ti: 0.010% or less And ferritic stainless steel for exhaust system expanded diameter members excellent in spinning workability, characterized in that each contains a balance of Fe and inevitable impurities.
2.前記1において、さらに、質量%で
V:0.01〜0.5 %、
Co:0.01〜0.25%および
W:0.001 〜0.05%
のうちから選んだ1種または2種以上を含有する組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。
2. In 1 above, V: 0.01 to 0.5% in mass%,
Co: 0.01 to 0.25% and W: 0.001 to 0.05%
A ferritic stainless steel for exhaust system expanded-diameter members excellent in spinning processability, wherein the composition contains one or more selected from the above.
3.前記1または2において、さらに、質量%で
Cu:3.0 %以下および
Mo:3.0 %以下
のうちから選んだ1種または2種を含有する組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。
3. In the above 1 or 2, further in mass%
Cu: 3.0% or less and
Mo: Ferritic stainless steel for exhaust system expanded-diameter members excellent in spinning processability, characterized by having a composition containing one or two selected from 3.0% or less.
4.前記1、2または3において、さらに、質量%で
B:0.0002〜0.0030%
を含有する組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。
4). In the above 1, 2 or 3, further, in mass% B: 0.0002 to 0.0030%
A ferritic stainless steel for exhaust system expanded-diameter members excellent in spinning workability, characterized in that it contains a composition comprising
かくして、本発明によれば、スピニング加工を施す場合の製品不良率を格段に低減することができ、特に加工速度を高速化した場合であっても良好なスピニング加工性を得ることもできる。従って、本発明のフェライト系ステンレス鋼を用いれば、排気系膨径部材用鋼材を有利に提供することができる。 Thus, according to the present invention, it is possible to remarkably reduce the product defect rate when performing the spinning process, and it is also possible to obtain a good spinning processability even when the processing speed is increased. Therefore, if the ferritic stainless steel of the present invention is used, the steel material for the exhaust system expanded member can be advantageously provided.
以下、本発明を具体的に説明する。まず、本発明において鋼の成分組成を上記の範囲に限定した理由について説明する。なお、成分に関する「%」表示は特に断らない限り質量%を意味するものとする。
C:0.02%以下
N:0.02%以下
CおよびNは、靱性を低下させるだけでなく、自動車の排気系部材に適用する場合に重要な特性である耐酸化性を低下させるので、含有量は低い程望ましい。そこで、本発明では、CおよびNの量は、それぞれ0.02%以下に限定した。
The present invention will be specifically described below. First, the reason why the composition of steel is limited to the above range in the present invention will be described. Unless otherwise specified, “%” in relation to ingredients means mass%.
C: 0.02% or less N: 0.02% or less C and N not only lower toughness but also lower oxidation resistance, which is an important characteristic when applied to automobile exhaust system members, so the content is low It is desirable. Therefore, in the present invention, the amounts of C and N are limited to 0.02% or less, respectively.
Si:2.0%以下
Siは、本発明における重要な元素である。すなわち、Siは、スピニング加工性および靱性を低下させるので、これらの面からは含有量を低減する方が望ましいことから、2.0%以下とした。一方で、耐酸化性を高める働きがあることから、下限を0.01%とすることが好ましい。
Si: 2.0% or less
Si is an important element in the present invention. That is, since Si reduces spinning workability and toughness, it is desirable to reduce the content from these aspects, so the content was made 2.0% or less. On the other hand, the lower limit is preferably set to 0.01% because it has a function of improving oxidation resistance.
Mn:2.0%以下
Mnは、強度並びにスケール剥離性の向上に有効な元素であり、好ましくは0.1%以上で含有させるが、多量に含有させると靱性を低下させるので、2.0%以下に限定した。
Mn: 2.0% or less
Mn is an element effective for improving strength and scale peelability, and is preferably contained in an amount of 0.1% or more. However, if contained in a large amount, Mn is limited to 2.0% or less.
Ni:0.6 %以下
Niは、靱性の向上に有利に寄与するため、好ましくは0.1%以上で含有させるが、含有量が 0.6%を超えると耐酸化性の劣化を招くため、Niは 0.6%以下に限定した。
Ni: 0.6% or less
Since Ni contributes advantageously to improving toughness, it is preferably contained at 0.1% or more. However, if the content exceeds 0.6%, the oxidation resistance is deteriorated, so Ni is limited to 0.6% or less.
Nb:0.1〜1.0%
Nbは、高温強度を高めるために有効な元素であり、その含有量が0.1%未満では実用的な強度向上は期待できない。一方、1.0%を超えると、靭性が低下するため、上限を1.0%とする。
Nb: 0.1-1.0%
Nb is an effective element for increasing the high-temperature strength, and if its content is less than 0.1%, practical strength improvement cannot be expected. On the other hand, if it exceeds 1.0%, the toughness decreases, so the upper limit is made 1.0%.
P:0.040%以下
Pも、強度を高めるのに有効な元素であるが、多量に含有させると靱性を低下させるので、0.040 %以下に限定した。なお、Pは低いほど好ましいが、0.01%未満の低減はコストの増加をまねくことから、0.01%以上の含有は許容することができる。
P: 0.040% or less P is also an element effective for increasing the strength. However, if contained in a large amount, the toughness is lowered, so the content is limited to 0.040% or less. In addition, although P is so preferable that it is low, since the reduction | decrease of less than 0.01% leads to the increase in cost, inclusion of 0.01% or more can be accept | permitted.
S:0.010 %以下
Sは、不可避的不純物として通常含有され、含有量が低いほど好ましいが、本発明においてはCr+6SiおよびAl+Tiの規制が最も重要であることから、これらの規制があればS含有量は0.01%以下に規制すればよい。好ましくは、0.001%以上0.006%以下である。
S: 0.010% or less S is usually contained as an unavoidable impurity, and the lower the content, the better. However, in the present invention, the regulation of Cr + 6Si and Al + Ti is the most important. May be regulated to 0.01% or less. Preferably, it is 0.001% or more and 0.006% or less.
Al+Ti:0.010%以下
AlおよびTiは、溶接部に介在物を生成しやすい元素であり、スピニング加工時の割れは、これらの介在物を起点として発生する場合が多いため、AlおよびTiの合計量を0.010%以下に規制する必要がある。好ましくは、AlおよびTiの合計量を0.008%以下、さらに好ましくはAl:0.005%以下およびTi:0.002%以下に制限する。
Al + Ti: 0.010% or less
Al and Ti are elements that easily generate inclusions in welds, and cracks during spinning often occur starting from these inclusions, so the total amount of Al and Ti should be 0.010% or less. It is necessary to regulate. Preferably, the total amount of Al and Ti is limited to 0.008% or less, more preferably Al: 0.005% or less and Ti: 0.002% or less.
Cr+6Si:12.0〜22.0%
CrおよびSiは、必要な耐食性および耐酸化性のレベルに応じて添加量が決まるが、スピニング加工性の観点からは、Cr+6Siを22.0%以下に抑制する必要がある。一方、Cr+6Siが12.0%未満では、耐酸化性が低下し排気系に使用することが難しくなる。ここに、Cr+6Siの上限を規制したことが、本発明の重要な点の1つである。すなわち、Al+Tiの規定によって介在物を減少させるだけでは不十分であり、Cr+6Siを22.0%以下にする必要がある。この理由は明確ではないが、スピニング加工温度(200〜400℃)での溶接部マトリックスの延性が重要であり、この延性を確保するのにCr+6Siを22.0%以下にすることが寄与しているものと考えられる。好ましくは17.0%以上21.0%以下である。
Cr + 6Si: 12.0-22.0%
The amount of Cr and Si added depends on the required level of corrosion resistance and oxidation resistance, but from the viewpoint of spinning workability, Cr + 6Si needs to be suppressed to 22.0% or less. On the other hand, if Cr + 6Si is less than 12.0%, the oxidation resistance is lowered and it is difficult to use it in the exhaust system. Here, regulating the upper limit of Cr + 6Si is one of the important points of the present invention. That is, it is not sufficient to reduce inclusions by the definition of Al + Ti, and Cr + 6Si needs to be 22.0% or less. The reason for this is not clear, but the ductility of the weld matrix at the spinning temperature (200-400 ° C) is important, and Cr + 6Si of 22.0% or less contributes to ensure this ductility. it is conceivable that. Preferably they are 17.0% or more and 21.0% or less.
以上、基本成分について説明したが、本発明ではその他にも、以下に述べる元素を適宜含有させることができる。
V:0.01〜0.5%
Co:0.01〜0.25%
W:0.001 〜0.05%
V、CoおよびWは、いずれも溶接熱影響部の溶接割れ感受性を改善するのに有用な元素であるが、それぞれ含有量が下限に満たないとその添加効果に乏しく、一方上限を超えると母材および溶接熱影響部の靱性の低下を招くので、それぞれ上記の範囲で含有させるものとした。より好ましい範囲は、V:0.05〜0.3 %、Co:0.02〜0.07%およびW:0.005 〜0.03%である。
The basic components have been described above. However, in the present invention, other elements described below can be appropriately contained.
V: 0.01-0.5%
Co: 0.01-0.25%
W: 0.001 to 0.05%
V, Co, and W are all useful elements for improving the weld cracking sensitivity of the heat affected zone, but if the content is less than the lower limit, the additive effect is poor. Since the toughness of the material and the weld heat affected zone is reduced, it is included in the above ranges. More preferable ranges are V: 0.05 to 0.3%, Co: 0.02 to 0.07%, and W: 0.005 to 0.03%.
さらに、Cu:3.0 %以下およびMo:3.0 %以下のうちから選んだ1種または2種を含有することができる。
Cu:3.0 %以下
Cuは、耐食性を向上させる元素であり、高い耐食性を必要とする場合に添加することが有効である。しかしながら、3.0 %を超えて添加すると、熱間圧延等における熱間割れのおそれが生じるため、Cuは 3.0%以下で含有させるものとした。なお、より好ましくは効果が顕著となる 0.1%を下限とし、2.0 %以下で含有させることが望ましい。
Furthermore, 1 type or 2 types selected from Cu: 3.0% or less and Mo: 3.0% or less can be contained.
Cu: 3.0% or less
Cu is an element that improves corrosion resistance, and it is effective to add Cu when high corrosion resistance is required. However, if added over 3.0%, there is a risk of hot cracking in hot rolling or the like, so Cu was contained at 3.0% or less. More preferably, the lower limit is 0.1% at which the effect is remarkable, and it is desirable to contain it at 2.0% or less.
Mo:3.0 %以下
Moも、Cu同様、耐食性の改善に有効な元素である。しかしながら、3.0 %を超えて添加すると、スピニング加工性が低下するだけでなく、特に溶接熱影響部のじん性が低下する。このため、Moは 3.0%以下で含有させるものとした。なお、スピニング加工性と耐食性の両立という観点からは 0.1〜1.6 %の範囲が好適である。
Mo: 3.0% or less
Mo, like Cu, is an element effective in improving corrosion resistance. However, if added over 3.0%, not only the spinning workability is lowered, but also the toughness of the heat affected zone is lowered. For this reason, Mo is contained at 3.0% or less. From the viewpoint of achieving both spinning workability and corrosion resistance, the range of 0.1 to 1.6% is preferable.
さらにまた、B:0.0002〜0.0030%を含有することができる。
Bは、焼入れ性の向上を通じて特に溶接熱影響部のじん性改善に効果がある。しかしながら、含有量が0.0002%未満ではその効果に乏しく、一方0.0030%を超える添加では、硬化が大きくなり、母材、溶接熱影響部とも、じん性および加工性が損なわれる。このため、Bは0.0002〜0.0030%の範囲で含有させるものとした。なお、より好ましくは0.0005〜0.0010%の範囲である。
Furthermore, B: 0.0002 to 0.0030% can be contained.
B is particularly effective for improving the toughness of the weld heat affected zone through the improvement of the hardenability. However, when the content is less than 0.0002%, the effect is poor. On the other hand, when the content exceeds 0.0030%, the hardening increases, and the toughness and workability of both the base material and the weld heat affected zone are impaired. Therefore, B is included in the range of 0.0002 to 0.0030%. In addition, More preferably, it is 0.0005 to 0.0010% of range.
次に、本発明鋼の好適製造方法について説明する。上記した好適成分組成の溶鋼を、転炉、電気炉、真空溶解炉等の公知の方法で溶製し、連続鋳造法あるいは造塊−分塊法により鋼素材(スラブ)とする。この鋼素材を、その後加熱するか、あるいは加熱することなく直接、熱間圧延して熱延板とする。熱延板には、通常、熱延板焼鈍が施されるが、用途によっては熱延板焼鈍を省略してもよい。ついで、酸洗後、冷間圧延により冷延板としたのち、再結晶焼鈍を施して、製品とする。 Next, the suitable manufacturing method of this invention steel is demonstrated. The molten steel having the above-mentioned preferred component composition is melted by a known method such as a converter, electric furnace, vacuum melting furnace or the like, and is made into a steel material (slab) by a continuous casting method or an ingot-bundling method. This steel material is then heated or directly hot-rolled without heating to form a hot-rolled sheet. The hot-rolled sheet is usually subjected to hot-rolled sheet annealing, but depending on the application, the hot-rolled sheet annealing may be omitted. Next, after pickling, the sheet is cold-rolled by cold rolling, and then subjected to recrystallization annealing to obtain a product.
以下、実施例に基づいて、本発明をさらに詳しく説明する。表1に示す成分組成になる鋼を、小型真空溶解炉で溶製し、100 kgの鋼塊とした。これらの鋼塊を、1050〜1250℃に加熱後、仕上げ温度:750 〜950 ℃、巻取り温度:650 〜850 ℃の条件で熱間圧延を施して 3.0mm厚の熱延板とした。ついで、これらの熱延板の一部に対しては 800〜1000℃の熱延板焼鈍を施したのち、酸洗してから、冷間圧延により板厚:1.2 mmの冷延板とした。上記のようにして得られた各鋼板から、試験片を採取し、スピニング加工性を次の試験方法に基づいて評価した。 Hereinafter, the present invention will be described in more detail based on examples. Steel having the composition shown in Table 1 was melted in a small vacuum melting furnace to obtain a 100 kg steel ingot. These steel ingots were heated to 1050 to 1250 ° C. and then hot-rolled under the conditions of finishing temperature: 750 to 950 ° C. and winding temperature: 650 to 850 ° C. to obtain hot rolled sheets having a thickness of 3.0 mm. Next, a part of these hot-rolled sheets was subjected to hot-rolled sheet annealing at 800 to 1000 ° C., pickled, and then cold-rolled to obtain cold-rolled sheets having a thickness of 1.2 mm. Test pieces were collected from each steel plate obtained as described above, and spinning workability was evaluated based on the following test methods.
<スピニング加工性>
試験片を、高周波溶接により、1.2 mmt×120 mmφ×500 mmLの電縫管とした。これらの電縫管に対し、図3に示すスピニング加工装置を用いて、回転速度:500 rpm、絞り込み量:2mm/回、成形ロールの相対平行移動速度:8000mm/minの条件で、図1に示すような、絞り部(図1のr3 部)径が60mmφ、長さが50mm、テーパ部(図1のr2 部)の長さが60mmとなるようなスピニング加工を施した。なお、締り込量みは、成形ロールが素管に対して相対的に往復運動するとき、この1往復当たりの成形ロール押し当て量の増大分を表す。
<Spinning workability>
The test piece was made into an electric resistance tube of 1.2 mmt × 120 mmφ × 500 mmL by high frequency welding. For these ERW pipes, the spinning machine shown in FIG. 3 is used, and the rotational speed is 500 rpm, the amount of squeezing is 2 mm / time, and the relative translation speed of the forming roll is 8000 mm / min. As shown in the drawing, spinning was performed so that the diameter of the narrowed portion (r 3 portion in FIG. 1) was 60 mmφ, the length was 50 mm, and the length of the tapered portion (r 2 portion in FIG. 1) was 60 mm. The tightening amount represents an increase in the pressing amount of the forming roll per reciprocation when the forming roll reciprocates relative to the raw tube.
図3のスピニング加工装置は、素管1を把持してその軸C−C回りに回転させる回転駆動手段と、素管1に所定の形状を付与すべく成形ローラ4を移動させる成形ローラ移動手段を備えている。回転駆動手段は、スピンドル2に設けられた素管を把持するためのチャック等の把持機構3と、スピンドル2を回転駆動するためのモータ(図示省略)とを備えてなるもので、素管1を把持してその軸C−C回りに回転させる。成形ローラ4の移動手段は、数値制御可能なサーボ機構(図示省略)からなるもので、素管1を所望の形状に成形すべく、設定入力されたデータに基づいて成形ローラ4と素管1とを相対的に軸C−C方向および径D方向に移動させるよう構成されている。成形ローラ4は、図中Aの矢印のように移動させられつつ素管1に押し当てられることによって、素管1は円錐部をもつ形状にスピニング絞り加工される。
The spinning apparatus of FIG. 3 includes a rotation driving unit that grips the
ここに、スピニング加工性は、上述した加工を300本の電縫管に対して施し、加工割れ発生数を調査した。その調査結果について、割れ発生数が1%以下を◎、1%超えを×として、表1に示す。 Here, spinning workability was determined by applying the above-described processing to 300 ERW pipes and examining the number of occurrences of processing cracks. The results of the investigation are shown in Table 1 where the number of cracks generated is 1% or less, and ◎ is greater than 1%.
表1に示したとおり、本発明に従い得られた鋼板はいずれも、比較例に比べて極めて優れたスピニング加工性が得られている。すなわち、比較例Bのように、Cr+6Siが発明範囲にあっても、Al+Tiの量が発明範囲から外れているとスピニング加工性に劣るものとなる。一方、Al+Tiの量が発明範囲であっても、比較例AおよびCのように、Cr+6Siが22をこえた場合はいずれも、スピニング加工性に劣るものとなる。以上の結果から、Al+TiおよびCr+6Siが重要であることがわかる。すなわち、Al+Ti量は介在物、Cr+6Si量はマトリックス靭性をあらわしており、この両者が所定範囲にあることが重要であることがわかる。 As shown in Table 1, all of the steel sheets obtained according to the present invention have extremely excellent spinning workability as compared with the comparative example. That is, as in Comparative Example B, even if Cr + 6Si is within the invention range, if the amount of Al + Ti is out of the invention range, the spinning processability is poor. On the other hand, even when the amount of Al + Ti is within the range of the invention, as in Comparative Examples A and C, when Cr + 6Si exceeds 22, both are inferior in spinning workability. From the above results, it can be seen that Al + Ti and Cr + 6Si are important. That is, the amount of Al + Ti represents inclusions, and the amount of Cr + 6Si represents matrix toughness, and it is important that both are within a predetermined range.
1 素管
2 スピンドル
3 把持機構
4、4′、4″ 成形ローラ
5 回転台
6 基台
7 把持機構
8 移動テーブル
9 モータケース
r1 ハウジングの本体部
r2 ハウジングのコーン部
r3 ハウジングの接続部
DESCRIPTION OF
Claims (4)
C:0.02%以下、
Si:2.0%以下、
Mn:2.0%以下、
Ni:0.6 %以下、
Nb:0.1〜1.0%、
P:0.040%以下、
S:0.01%以下および
N:0.02%以下
を含み、さらにCrをCr +6Si:12.0〜22.0%の関係を満足する範囲において、またAlおよびTiをAl+Ti:0.010%以下の関係を満足する範囲において、それぞれ含有し、残部はFeおよび不可避的不純物の組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。 % By mass
C: 0.02% or less,
Si: 2.0% or less,
Mn: 2.0% or less,
Ni: 0.6% or less,
Nb: 0.1-1.0%
P: 0.040% or less,
S: 0.01% or less and N: 0.02% or less, and Cr within a range satisfying the relationship of Cr + 6Si: 12.0 to 22.0%, and Al and Ti within a range satisfying the relationship of Al + Ti: 0.010% or less And ferritic stainless steel for exhaust system expanded diameter members excellent in spinning workability, characterized in that each contains a balance of Fe and inevitable impurities.
V:0.01〜0.5 %、
Co:0.01〜0.25%および
W:0.001 〜0.05%
のうちから選んだ1種または2種以上を含有する組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。 In Claim 1, Furthermore, by mass% V: 0.01-0.5%,
Co: 0.01 to 0.25% and W: 0.001 to 0.05%
A ferritic stainless steel for exhaust system expanded-diameter members excellent in spinning workability, characterized in that it comprises a composition containing one or more selected from among them.
Cu:3.0 %以下および
Mo:3.0 %以下
のうちから選んだ1種または2種を含有する組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。 3. The method according to claim 1, further comprising:
Cu: 3.0% or less and
Mo: Ferritic stainless steel for exhaust system expanded-diameter members excellent in spinning processability, characterized by having a composition containing one or two selected from 3.0% or less.
B:0.0002〜0.0030%
を含有する組成になることを特徴とするスピニング加工性に優れた排気系膨径部材用のフェライト系ステンレス鋼。 In Claim 1, 2, or 3, Furthermore, by mass% B: 0.0002-0.0030%
A ferritic stainless steel for exhaust system expanded-diameter members excellent in spinning workability, characterized in that it contains a composition comprising
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007085741A JP5194512B2 (en) | 2007-03-28 | 2007-03-28 | Ferritic stainless steel cold-rolled sheet for exhaust system expanded members with excellent spinning processability |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007085741A JP5194512B2 (en) | 2007-03-28 | 2007-03-28 | Ferritic stainless steel cold-rolled sheet for exhaust system expanded members with excellent spinning processability |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2008240121A true JP2008240121A (en) | 2008-10-09 |
JP5194512B2 JP5194512B2 (en) | 2013-05-08 |
Family
ID=39911800
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2007085741A Active JP5194512B2 (en) | 2007-03-28 | 2007-03-28 | Ferritic stainless steel cold-rolled sheet for exhaust system expanded members with excellent spinning processability |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP5194512B2 (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106799422A (en) * | 2016-12-30 | 2017-06-06 | 北京有色金属研究总院 | A kind of composite bimetal pipe material spinning preparation method |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH083698A (en) * | 1994-04-21 | 1996-01-09 | Kawasaki Steel Corp | Hot rolled ferritic steel for automobile exhaust material |
JPH10102208A (en) * | 1996-09-25 | 1998-04-21 | Kawasaki Steel Corp | Ferritic stainless steel for engine exhaust member, excellent in heat resistance, workability, and corrosion resistance in weld zone |
JPH11131191A (en) * | 1997-10-30 | 1999-05-18 | Kawasaki Steel Corp | Ferritic stainless steel excellent in ridging resistance |
JPH11236650A (en) * | 1998-02-20 | 1999-08-31 | Kawasaki Steel Corp | Ferritic stainless steel for engine exhaust member excellent in workability, intergranular corrosion resistance and high temperature strength |
JP2000073147A (en) * | 1998-08-27 | 2000-03-07 | Kawasaki Steel Corp | Chromium-containing steel excellent in high temperature strength workability and surface property |
JP2004243354A (en) * | 2003-02-13 | 2004-09-02 | Jfe Steel Kk | Ferritic stainless steel welded tube of excellent spinning workability |
JP2006291294A (en) * | 2005-04-11 | 2006-10-26 | Nisshin Steel Co Ltd | Ferritic stainless steel sheet superior in spinning formability, and spinning method |
-
2007
- 2007-03-28 JP JP2007085741A patent/JP5194512B2/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH083698A (en) * | 1994-04-21 | 1996-01-09 | Kawasaki Steel Corp | Hot rolled ferritic steel for automobile exhaust material |
JPH10102208A (en) * | 1996-09-25 | 1998-04-21 | Kawasaki Steel Corp | Ferritic stainless steel for engine exhaust member, excellent in heat resistance, workability, and corrosion resistance in weld zone |
JPH11131191A (en) * | 1997-10-30 | 1999-05-18 | Kawasaki Steel Corp | Ferritic stainless steel excellent in ridging resistance |
JPH11236650A (en) * | 1998-02-20 | 1999-08-31 | Kawasaki Steel Corp | Ferritic stainless steel for engine exhaust member excellent in workability, intergranular corrosion resistance and high temperature strength |
JP2000073147A (en) * | 1998-08-27 | 2000-03-07 | Kawasaki Steel Corp | Chromium-containing steel excellent in high temperature strength workability and surface property |
JP2004243354A (en) * | 2003-02-13 | 2004-09-02 | Jfe Steel Kk | Ferritic stainless steel welded tube of excellent spinning workability |
JP2006291294A (en) * | 2005-04-11 | 2006-10-26 | Nisshin Steel Co Ltd | Ferritic stainless steel sheet superior in spinning formability, and spinning method |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106799422A (en) * | 2016-12-30 | 2017-06-06 | 北京有色金属研究总院 | A kind of composite bimetal pipe material spinning preparation method |
CN106799422B (en) * | 2016-12-30 | 2018-06-15 | 北京有色金属研究总院 | A kind of composite bimetal pipe material spinning preparation method |
Also Published As
Publication number | Publication date |
---|---|
JP5194512B2 (en) | 2013-05-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4400058B2 (en) | Ferritic stainless steel welded pipe with excellent spinning processability | |
JP5682901B2 (en) | Ti-added ferritic stainless steel sheet excellent in spinning workability and manufacturing method thereof | |
TWI493057B (en) | Fat iron stainless steel | |
JP5142141B2 (en) | Hot-rolled steel sheets for hydroforming, steel pipes for hydroforming, and methods for producing them | |
TWI460292B (en) | Ferritic stainless steel | |
JP5707671B2 (en) | Nb-added ferritic stainless steel sheet excellent in workability and manufacturability and method for producing the same | |
WO2008105216A1 (en) | Electric resistance welded steel pipe prior to heat treatment and process for manufacturing the same | |
JP5560578B2 (en) | Ferritic stainless steel cold-rolled steel sheet excellent in workability and manufacturing method thereof | |
TWI553129B (en) | Ferrous iron-type stainless steel hot-rolled steel sheet, its manufacturing method and fat iron-based stainless steel cold-rolled steel plate | |
JP2009091654A (en) | Ferritic stainless steel having excellent weldability | |
CN109804092B (en) | Cold-rolled steel sheet for flux-cored wire and method for manufacturing same | |
JP2000104117A (en) | Production of seamless steel pipe for linepipe excellent in toughness and uniformity of strength | |
JP2003342694A (en) | Ferritic stainless steel excellent in spinning workability and used for diameter-enlarged member of gas exhaust system | |
JP5333074B2 (en) | Steel pipe manufacturing method for steel tower | |
JP5428129B2 (en) | Ferritic stainless steel weld metal with excellent penetration shape and workability | |
JP2001049400A (en) | Austenitic heat resisting steel excellent in hot workability | |
JP5194512B2 (en) | Ferritic stainless steel cold-rolled sheet for exhaust system expanded members with excellent spinning processability | |
JP6814678B2 (en) | Ferritic stainless steel pipes for thickening pipe ends and ferritic stainless steel pipes for automobile exhaust system parts | |
JP4241431B2 (en) | Ferritic stainless steel | |
JP4608818B2 (en) | Ferritic stainless steel with excellent secondary work brittleness resistance and high temperature fatigue properties of welds | |
JPH0567699B2 (en) | ||
JP2682335B2 (en) | Manufacturing method of ferritic stainless steel hot rolled strip | |
JP2004217992A (en) | Electric resistance welded tube and production method therefor | |
JPS6149365B2 (en) | ||
JP3951481B2 (en) | Steel pipe manufacturing method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20100222 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20120227 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120313 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20120511 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20120828 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20121019 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20130108 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20130121 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20160215 Year of fee payment: 3 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5194512 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |