JP2008111200A - Water-absorbing extensible composite yarn and fabric - Google Patents

Water-absorbing extensible composite yarn and fabric Download PDF

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JP2008111200A
JP2008111200A JP2006293517A JP2006293517A JP2008111200A JP 2008111200 A JP2008111200 A JP 2008111200A JP 2006293517 A JP2006293517 A JP 2006293517A JP 2006293517 A JP2006293517 A JP 2006293517A JP 2008111200 A JP2008111200 A JP 2008111200A
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composite yarn
fabric
yarn
fiber
knitted fabric
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JP5214131B2 (en
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Shoichi Akita
祥一 秋田
Ayumi Koyachi
亜由美 小谷地
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Asahi Kasei Corp
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Asahi Kasei Fibers Corp
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a composite yarn facilitating to produce a fabric which is comfortable when worn and gives no sense of stickiness or no sense of sweatiness when sweated. <P>SOLUTION: This composite yarn comprising polyester-based fibers and cellulose fibers is characterized by having a crimp extension rate of 5 to 20% and a water-absorbing extension rate equal to or more than 4%. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は吸水時伸長する複合糸に関し、より詳細には、着用発汗時に快適な布帛の製造に適した複合糸および布帛に関する。   The present invention relates to a composite yarn that elongates when water is absorbed, and more particularly, to a composite yarn and a fabric that are suitable for producing a fabric that is comfortable when worn and sweated.

従来の衣服は、スポーツなどの運動により発汗した際には布帛が吸汗し、肌と布帛が密着して、いわゆるべとつき感や蒸れ感を生じる。これを防止するために種々の布帛が開発されているが、布帛構造のみでは吸汗時の快適性に限界があり、これを解消するために使用する繊維の検討が進められ、吸汗時に伸長する繊維を使用した布帛が各種提案されている。例えば、特許文献1には、吸汗時に自己伸長する繊維を使用して、ニットループが吸水時に大きくなり、通気性が向上する生地が提案されているが、糸長比の制約があり、製法上複雑となる。また、特許文献2、3には、吸汗時に捲縮率が異なる繊維をサイドバイサイド型に接合した繊維を使用する布帛が開示されている。しかし、これらに用いる繊維は吸湿性がなく、身体の不感蒸泄による水分は吸収しないため、不快感があり、さらに、発汗時にもべとつき感や、蒸れ感が残るものであった。また、セルロース繊維を使用すれば吸湿性がよく、通常の着用時では快適であることが知られているが、運動などによる発汗時には吸汗量が不足して、べとつき感や蒸れ感を覚える。従って着用時、発汗時共に快適となる繊維は見当たらないのが現状である。
特開2005−36374公報 特開2006−112009公報 特開2005−23431公報
In conventional garments, when sweat is generated by exercise such as sports, the fabric absorbs sweat, and the skin and the fabric adhere to each other, so that a so-called stickiness or stuffiness is generated. Various fabrics have been developed to prevent this. However, there is a limit to the comfort during sweat absorption with the fabric structure alone. Various kinds of fabrics using the material have been proposed. For example, Patent Document 1 proposes a fabric that uses a fiber that self-extends when absorbing sweat and a knit loop becomes large when absorbing water, improving air permeability. It becomes complicated. Patent Documents 2 and 3 disclose fabrics using fibers obtained by bonding fibers having different crimping ratios in a side-by-side manner during sweat absorption. However, the fibers used for these have no hygroscopicity and do not absorb moisture due to insensitive digestion of the body, so there is an unpleasant feeling, and a sticky feeling and a feeling of stuffiness remain when sweating. In addition, it is known that if cellulose fibers are used, the hygroscopicity is good, and it is known that it is comfortable when worn normally. However, when sweating due to exercise or the like, the amount of absorbed sweat is insufficient, and a feeling of stickiness and stuffiness is felt. Therefore, there are currently no fibers that are comfortable when worn and when sweating.
JP 2005-36374 A JP 2006-112009 A JP 2005-23431 A

本発明の課題は、着用時快適で、かつ、発汗時にもべとつき感や蒸れ感のない布帛製造に適した複合糸、及び該複合糸により製造された布帛を提供することである。   An object of the present invention is to provide a composite yarn suitable for manufacturing a fabric that is comfortable when worn and does not feel sticky or damp even when sweating, and a fabric manufactured using the composite yarn.

本発明者は、上記課題を達成するため着用テストなどを含み鋭意検討した結果、吸汗時に自己伸長する画期的なセルロース繊維を含有する複合糸を使用した布帛により、上記課題が達成されることを見出した。   As a result of intensive studies including a wearing test in order to achieve the above-mentioned problems, the present inventor achieves the above-described problems with a fabric using a composite yarn containing an innovative cellulose fiber that self-extends during sweat absorption. I found.

すなわち本願で特許請求される発明は以下のとおりである。
(1)ポリエステル系繊維とセルロース繊維とからなる複合糸において、該複合糸の捲縮伸長率が5〜20%であり、吸水伸長率が4%以上であることを特徴とする複合糸。
(2)ポリエステル系繊維とセルロース繊維とを複合したのち、アルカリ水溶液20g/L以上、20℃以上、5分以上浸漬処理することを特徴とする(1)に記載の複合糸の製造方法。
(3)(1)に記載の複合糸により製造された布帛。
That is, the invention claimed in the present application is as follows.
(1) A composite yarn comprising polyester fiber and cellulose fiber, wherein the composite yarn has a crimp elongation of 5 to 20% and a water absorption elongation of 4% or more.
(2) The method for producing a composite yarn according to (1), wherein the polyester-based fiber and the cellulose fiber are combined and then immersed in an alkaline aqueous solution of 20 g / L or more, 20 ° C. or more, and 5 minutes or more.
(3) A fabric produced from the composite yarn according to (1).

本発明の複合糸を使用すれば、着用時快適で発汗時にもべとつき感や蒸れ感のない布帛が製造可能で、スポーツウェア、インナー、アウターなどの衣服に製造した時に、快適な着用感が得られる。   By using the composite yarn of the present invention, it is possible to produce a fabric that is comfortable when worn and does not feel sticky or stuffy when sweating, and when worn on clothes such as sportswear, inner and outerwear, a comfortable wearing feeling is obtained. It is done.

以下、本発明について詳細に説明する。
本発明によるポリエステル系繊維とは、ポリエチレンテレフタレート、ポリトリメチレンテレフタレート等のポリエステル系繊維をいい、断面形状については任意で、丸断面の他、W型断面、あるいは中空糸などの異型糸の使用が可能である。さらに、これらポリエステル系繊維の仮撚り加工糸、押し込み加工糸などの加工糸が使用でき、特に限定されないが、仮撚り加工糸の使用が好ましい。繊維の太さについては、11dt(デシテックス:以下、同じ記号を使用)〜400dt、特に40dtから170dtが扱いやすく好ましい。
Hereinafter, the present invention will be described in detail.
The polyester fiber according to the present invention refers to a polyester fiber such as polyethylene terephthalate or polytrimethylene terephthalate. The cross-sectional shape is arbitrary, and in addition to a round cross-section, a W-shaped cross-section or a modified yarn such as a hollow fiber can be used. Is possible. Furthermore, processed yarns such as false twisted yarns and indented yarns of these polyester fibers can be used, and although not particularly limited, use of false twisted yarns is preferable. The thickness of the fiber is preferably 11 dt (decitex: the same symbol is used hereinafter) to 400 dt, particularly 40 dt to 170 dt, which is easy to handle.

また、本発明によるセルロース繊維とは、キュプラ、レーヨン、竹繊維、綿などであり、特に再生セルロースが好ましい。また、複合糸とするためには、これらの長繊維の使用が好ましく、繊維の太さは11dt(デシテックス)〜400dt、特に40dtから170dtが扱いやすく好ましい。   The cellulose fiber according to the present invention includes cupra, rayon, bamboo fiber, cotton and the like, and particularly regenerated cellulose is preferable. In order to obtain a composite yarn, it is preferable to use these long fibers, and the thickness of the fibers is preferably 11 dt (decitex) to 400 dt, particularly preferably 40 dt to 170 dt.

本発明の複合糸におけるポリエステル系繊維とセルロース系繊維の混率は任意に設定可能であるが、好ましいセルロース繊維の混率は20〜80%、より好ましくは25〜75%である。   The mixing ratio of the polyester fiber and the cellulose fiber in the composite yarn of the present invention can be arbitrarily set, but the preferable mixing ratio of the cellulose fiber is 20 to 80%, more preferably 25 to 75%.

本発明の複合糸は、吸水伸長率が4%以上、好ましくは5%以上である。吸水伸長率が4%未満では、発汗時にべとつき感や蒸れ感が低減するのに必要な伸長性が得られない。セルロース繊維が吸水して伸長することにより吸水伸長率が4%以上の複合糸が得られる。この場合、通常のセルロース繊維とポリエステル系繊維との複合糸では、吸水伸長率が4%以上の複合糸が得られないが、本発明の複合糸をアルカリ水溶液中で処理することにより、セルロース繊維が吸水伸長する繊維となり、吸水伸長率が4%以上の複合糸とすることが出来る。   The composite yarn of the present invention has a water absorption elongation rate of 4% or more, preferably 5% or more. If the water absorption elongation rate is less than 4%, the extensibility necessary to reduce the feeling of stickiness and stuffiness during sweating cannot be obtained. A cellulose fiber absorbs water and stretches to obtain a composite yarn having a water absorption elongation rate of 4% or more. In this case, a composite yarn of ordinary cellulose fiber and polyester fiber cannot obtain a composite yarn having a water absorption elongation rate of 4% or more. However, by treating the composite yarn of the present invention in an alkaline aqueous solution, the cellulose fiber Becomes a fiber that absorbs and stretches water, and a composite yarn having a water absorption elongation rate of 4% or more can be obtained.

なお、セルロース繊維をアルカリ処理することは従来より知られており、例えばシルケット加工が最も一般的なものである。ところが本発明では、従来の常識を打ち破り、過酷なアルカリ処理により吸水時に伸長するセルロース繊維の製造に成功し、具体的には、例えばセルロース繊維を水酸化ナトリウムを20g/L(リットル)以上の水溶液で20℃以上の水中で、5分以上浸漬処理することにより吸水伸長する繊維が得られる。吸水伸長率の制御はこれら条件のコントロールにより可能で、アルカリ濃度、温度、時間など処理条件が弱いほど吸水伸長率は小さくなるが、処理条件を強くしすぎても、ある限度以上の吸水伸長率を有するセルロース繊維は得られない。またアルカリ処理剤としては公知のものが使用でき、例えば、水酸化ナトリウム、水酸化カリウムなどのアルカリ金属水酸化物の使用が可能である。   In addition, it is conventionally known to perform an alkali treatment on cellulose fibers, and for example, mercerization is the most common. However, in the present invention, the conventional common sense has been broken, and the cellulose fibers that have been elongated upon water absorption by a severe alkali treatment have been successfully produced. Specifically, for example, the cellulose fibers are made into an aqueous solution of 20 g / L (liter) or more of sodium hydroxide. The fiber which absorbs and expands water is obtained by immersing in water at 20 ° C. or higher for 5 minutes or longer. The water absorption elongation rate can be controlled by controlling these conditions. Although the water absorption elongation rate decreases as the processing conditions such as alkali concentration, temperature, and time are weak, the water absorption elongation rate exceeds a certain limit even if the processing conditions are too strong. Cellulose fibers having the following cannot be obtained. Moreover, a well-known thing can be used as an alkali processing agent, For example, alkali metal hydroxides, such as sodium hydroxide and potassium hydroxide, can be used.

アルカリ濃度としては20〜200g/L水溶液相当がより好ましく、処理温度、時間はそれぞれ20〜110℃で、5〜120分間処理することがより好ましい。また、アルカリ処理について、複合糸の状態で行う方法、布帛製造後に行う方法など任意であるが、布帛製造後に行うほうが容易である。   The alkali concentration is more preferably equivalent to a 20 to 200 g / L aqueous solution, and the treatment temperature and time are each 20 to 110 ° C., more preferably 5 to 120 minutes. In addition, the alkali treatment is optional such as a method performed in the state of a composite yarn, a method performed after the manufacture of the fabric, etc., but it is easier to perform after the manufacture of the fabric.

本発明において、複合糸の吸水伸長率の測定法は、20℃65%RH下の環境で、0.088cN/dtの荷重下で繊維長を測定(A)し、次いで、繊維を水に浸して2分後の長さを0.088cN/dtの荷重下で測定(B)し、下記式(2)により吸水伸長率を求める。尚、複合糸の吸水伸長率測定は、染色仕上げ後の布帛中より繊維を抜き出してから測定する。

吸水伸長率(%)=((B−A)/A)×100 (1)

本発明の複合糸は、捲縮伸長率が5〜20%、好ましくは、8〜18%である。捲縮伸長率が5%未満の場合には、吸汗時に十分な伸長性が得られず本発明の目的は達成されない。また20%を越える場合には、複合糸の捲縮性は十分であるが、捲縮が強すぎて吸汗時、セルロース繊維が伸張しても捲縮が伸びず、複合糸としては伸長性が十分に得られない。なお、複合糸の捲縮伸長率は、複合仮撚り後の複合糸を下記条件にて測定したものである。
In the present invention, the water absorption elongation rate of the composite yarn is measured by measuring the fiber length (A) under an environment of 20 ° C. and 65% RH under a load of 0.088 cN / dt, and then immersing the fiber in water. Then, the length after 2 minutes is measured (B) under a load of 0.088 cN / dt, and the water absorption elongation is obtained by the following formula (2). The water absorption elongation rate of the composite yarn is measured after the fibers are extracted from the fabric after dyeing finish.

Water absorption elongation (%) = ((B−A) / A) × 100 (1)

The composite yarn of the present invention has a crimp elongation of 5 to 20%, preferably 8 to 18%. When the crimp elongation rate is less than 5%, sufficient stretchability cannot be obtained at the time of sweat absorption, and the object of the present invention is not achieved. On the other hand, if it exceeds 20%, the crimping property of the composite yarn is sufficient, but the crimping is too strong, and the sweat does not stretch even if the cellulose fiber stretches during sweat absorption. Not enough. The crimp elongation of the composite yarn is a value obtained by measuring the composite yarn after composite false twisting under the following conditions.

20℃65%RH下の環境で24時間放置した複合糸を、張力0.088cN/dtで枠周1mの検尺機にて10周巻取り、小綛にし、小綛下端に0.26×10-3cN/dtの荷重をかけたまま乾燥機にて90℃×15分の乾熱処理を行う。処理終了後、0.26×10-3cN/dtの荷重を取り外し、20℃65%RH下の環境で24時間放置する。次いで、小綛の上端を固定し、小綛下端に1.77×10-3cN/dtの荷重をかけ、30秒後の長さ(A)を測定する。次いで、1.77×10-3cN/dtの荷重を取り外し、0.088cN/dtの荷重をかけ、30秒後の長さ(B)を測定し、下記式(2)により捲縮伸長率を求める。

捲縮伸長率(%)=((B−A)/A)×100 (2)

本発明における複合糸の製造方法としては、仮撚り機を使用して仮撚り加工と流体混繊加工を同時に行う方法や、別途用意した加工糸を流体混繊加工機を使用して複合する方法があげられる。前者の方法では、仮撚り加工前に流体混繊加工を行っても、仮撚加工後に流体混繊加工を行ってもよい。仮撚り加工方法としては一般に用いられているピンタイプ、ディスクフリクションタイプ、ニップベルトタイプ、エアー加撚タイプ等どの方法でもよい。また、ヒーターについては1ヒーター仮撚り法、2ヒーター仮撚り法のどちらでもよいが、複合糸の吸汗時の伸長性を阻害しないためには1ヒーター仮撚り法が好ましい。
The composite yarn left for 24 hours in an environment of 20 ° C. and 65% RH is wound up 10 turns with a measuring machine with a frame circumference of 1 m at a tension of 0.088 cN / dt, made into a small punch, and 0.26 × at the lower end of the small punch. While applying a load of 10 −3 cN / dt, dry heat treatment is performed in a dryer at 90 ° C. for 15 minutes. After the treatment is completed, the load of 0.26 × 10 −3 cN / dt is removed and the mixture is left for 24 hours in an environment at 20 ° C. and 65% RH. Next, the upper end of the gavel is fixed, a load of 1.77 × 10 −3 cN / dt is applied to the lower end of the gavel, and the length (A) after 30 seconds is measured. Next, the load of 1.77 × 10 −3 cN / dt was removed, the load of 0.088 cN / dt was applied, the length (B) after 30 seconds was measured, and the crimp elongation rate was obtained by the following formula (2) Ask for.

Crimp elongation (%) = ((B−A) / A) × 100 (2)

As a method for producing a composite yarn in the present invention, a method of simultaneously performing false twisting and fluid mixing using a false twisting machine, or a method of combining separately prepared processed yarn using a fluid mixing processing machine Can be given. In the former method, the fluid mixing process may be performed before the false twisting process, or the fluid mixing process may be performed after the false twisting process. The false twisting method may be any method such as a pin type, a disk friction type, a nip belt type, and an air twist type that are generally used. As for the heater, either the 1 heater false twisting method or the 2 heater false twisting method may be used, but the 1 heater false twisting method is preferable in order not to inhibit the extensibility of the composite yarn during sweat absorption.

本発明におけるポリエステル系繊維とセルロース繊維の複合方法としては、流体混繊加工や複合撚糸加工等があげられるが、吸水伸長性を阻害しない点から、例えばインターレースノズルや流体乱流ノズルを用いた、流体混繊加工が好ましい。   Examples of the composite method of the polyester fiber and cellulose fiber in the present invention include fluid blending processing and composite twisting processing, but from the point of not inhibiting the water absorption elongation, for example, using an interlace nozzle or a fluid turbulent flow nozzle, Fluid blending is preferred.

複合糸の流体混繊加工において、インターレースノズルを用いた流体混繊加工により得られる交絡数は50〜120個/mが好ましい。50個/m未満では布帛とした際にセルロースの目ムキが生じ易く、また120個/mより多いと、ポリエステル系繊維とセルロース繊維との絡みつきが多くなりすぎ、吸汗時の伸長性を阻害することがある。この時のポリエステル系繊維とセルロース繊維のフィード率は同率で良いが、フィード差を0〜5%程度で加工することも可能である。また、流体乱流ノズルを用いた流体混繊加工では、糸ずれしない交絡強度があり、且つ、解舒性に問題ない形態が得られるような混繊条件であればよく、例えば芯糸のフィード率が1〜5%、鞘糸のフィード率が5〜15%、芯糸と鞘糸のフィード率差が3〜10%程度が好ましい。   In the fluid mixing process of composite yarn, the number of entanglements obtained by the fluid mixing process using an interlace nozzle is preferably 50 to 120 / m. If it is less than 50 pieces / m, it is easy to cause unevenness of cellulose when it is made into a fabric, and if it is more than 120 pieces / m, the entanglement between the polyester fiber and the cellulose fiber becomes excessive, and the extensibility during sweat absorption is inhibited. Sometimes. At this time, the feed rate of the polyester fiber and the cellulose fiber may be the same, but it is also possible to process with a feed difference of about 0 to 5%. Further, in the fluid mixing process using the fluid turbulent nozzle, it is sufficient that the mixing condition is such that the entanglement strength does not cause the yarn misalignment and the form having no problem with the unwinding property can be obtained. The rate is preferably 1 to 5%, the feed rate of the sheath yarn is 5 to 15%, and the feed rate difference between the core yarn and the sheath yarn is preferably about 3 to 10%.

本発明における複合糸の仮撚り加工において、第1ヒーター温度は120〜230℃が好ましい。230℃より高いとポリエステル系繊維の融着や著しい強度低下、糸切れが発生し、120℃未満では吸汗時に伸長するのに必要な捲縮が得られない。仮撚り数においては一般に用いられる範囲でよく、下記式にて算出される。この場合、仮撚り数の係数Kの値が18500〜37000の範囲であることが好ましい。
仮撚り数(T/M)=K/(仮撚り糸の繊度(dtex))1/2
延伸倍率については、走行性や加工性に支障をきたさない範囲で、加撚張力として10〜30cNが好ましい。
In the false twisting of the composite yarn in the present invention, the first heater temperature is preferably 120 to 230 ° C. When the temperature is higher than 230 ° C., polyester fibers are fused, markedly reduced in strength, and thread breakage occurs. When the temperature is lower than 120 ° C., the crimp necessary for stretching during sweat absorption cannot be obtained. The number of false twists may be a generally used range, and is calculated by the following formula. In this case, the value of the false twist number coefficient K is preferably in the range of 18500-37000.
Number of false twists (T / M) = K / (Fineness of false twisted yarn (dtex)) 1/2
About a draw ratio, 10-30 cN is preferable as twisting tension in the range which does not cause trouble in runnability and workability.

また必要に応じて、第1ヒーターに第2ヒーターを併用し、2ヒーター仮撚り糸としても良い。この時の第2ヒーター温度は100〜200℃が好ましく、200℃より高いと捲縮性が低下し、吸汗時のセルロース繊維の伸長性が阻害され、100℃未満では捲縮性が高いため、同様に吸汗時のセルロース繊維の伸長性が阻害される。   If necessary, a second heater may be used in combination with the first heater to form a two-heater false twisted yarn. The second heater temperature at this time is preferably 100 to 200 ° C., and if it is higher than 200 ° C., the crimpability is lowered, the extensibility of cellulose fibers during sweat absorption is inhibited, and if it is less than 100 ° C., the crimp property is high. Similarly, the stretchability of the cellulose fiber during sweat absorption is inhibited.

本発明による布帛は、捲縮伸長率が5〜20%であり、吸水伸長率が4%以上である前記複合糸を使用して製造される。この布帛は、該複合糸100%使いでも良く、また、非吸水伸長繊維と交編、交織して布帛製造することも可能である。本発明の複合糸の布帛中の混率については、布帛設計により得られる本発明の効果を加味して任意に設定可能である。なお、上記非吸水伸長繊維とは、本発明による吸水伸長率測定法で測定した結果、吸水伸長率が4%未満の繊維をいい、ポリエステル、ポリトリメチレンテレフタレート等のポリエステル系繊維、ポリアミド系繊維、ポリウレタン系繊維、セルロース系繊維、アセテート、綿、ウールなど、任意の繊維の長繊維、あるいは短繊維であり、これらの断面形状も任意で、丸断面の他、W型断面、あるいは中空糸などの異型糸の使用が可能である。これら任意の繊維との交編、交織により、本発明の複合糸が吸汗した際、布帛を構成する編目や織糸が伸びて大きくなり、吸汗部分の密度が下がるように設計すれば、運動などの発汗時に蒸れ感を覚えない衣服製造が可能となる。この蒸れ感を覚えない衣服を製造する場合は、織物よりも編物の方が高い効果が得られる。   The fabric according to the present invention is manufactured using the composite yarn having a crimp elongation of 5 to 20% and a water absorption elongation of 4% or more. This fabric may be used with 100% of the composite yarn, and can also be produced by knitting and weaving with non-water-absorbing stretch fibers. The mixing ratio of the composite yarn of the present invention in the fabric can be arbitrarily set in consideration of the effect of the present invention obtained by the fabric design. The above-mentioned non-water-absorbing stretched fiber means a fiber having a water-absorbing elongation rate of less than 4% as measured by the method of measuring the water-absorbing elongation rate according to the present invention. Polyester fibers such as polyester and polytrimethylene terephthalate, polyamide fibers , Polyurethane fibers, cellulosic fibers, acetate, cotton, wool, etc., any long fibers or short fibers, and these cross-sectional shapes are also optional, in addition to round cross sections, W-shaped cross sections, hollow fibers, etc. Can be used. If the composite yarn of the present invention absorbs sweat by knitting or weaving with any of these fibers, the stitches and woven yarn constituting the fabric are stretched and enlarged, and the density of the sweat absorbing portion is reduced. It is possible to manufacture clothes that do not feel stuffy when sweating. In the case of producing a garment that does not feel stuffy, a knitted fabric is more effective than a woven fabric.

本発明による衣服は、着用発汗時には複合糸が伸長して吸汗部分の密度が低下し、蒸れ感を覚えないが、その機能を十分発揮するためには、吸汗時の通気性が10%以上増加するように布帛設計するのが好ましく、例えば、フライス組織で、非吸水伸長繊維と本発明の複合糸との構成を、1本交互や3本に1本の割合で配置するなどの設計が考慮される。   In the garment according to the present invention, when the sweat is worn, the composite yarn stretches and the density of the sweat-absorbing portion decreases, and the stuffiness is not felt. However, in order to fully demonstrate its function, the breathability during sweat absorption is increased by 10% or more. It is preferable to design the fabric so that, for example, in the milling structure, the configuration of the non-water-absorbing stretch fiber and the composite yarn of the present invention is alternately arranged or arranged at a ratio of one to three. Is done.

本発明の、複合糸を含む布帛の染色加工方法は、糸状態、布帛状態とも通常の染色仕上げ工程が使用でき、使用する染色機も複合糸状態での加工はチーズ染色機の使用、布帛状態での加工は液流染色機、ウインス染色機など任意な染色機の使用ができる。ただし、染色加工工程中にアルカリ処理が必要であり、本発明の場合は、染色機を使用し染色前にアルカリ処理を行い、その後、繊維素材に応じた染色条件による染色を行うのが好ましい。また、布帛状態での加工において、仕上げセットは布帛乾燥時に皺になったり、突っ張ったりしないように仕上げればよい。また、仕上げ剤として、吸水剤の付与を行うと、より吸汗性が向上し好ましい。   The dyeing method for a fabric containing a composite yarn of the present invention can use a normal dyeing finishing process for both the yarn state and the fabric state, and the dyeing machine to be used is also processed with a cheese dyeing machine, the fabric state. For the processing at, any dyeing machine such as a liquid dyeing machine or a wins dyeing machine can be used. However, alkali treatment is required during the dyeing process, and in the case of the present invention, it is preferable to use a dyeing machine to perform alkali treatment before dyeing, and then perform dyeing under dyeing conditions corresponding to the fiber material. Further, in the processing in the fabric state, the finishing set may be finished so as not to become wrinkles or stretch when the fabric is dried. In addition, it is preferable to apply a water absorbing agent as a finishing agent because sweat absorption is further improved.

以下、実施例により本発明を詳述する。無論、本発明はこれに限定されるものではない。
なお、実施例における評価は以下の方法により測定した。
(1)着用快適性
実施例による布帛で運動シャツを縫製し、発汗するまで運動して、着用快適性を10名
の被験者で官能評価し、その平均値を着用快適性とした。
実際に問題ないのは下記3以上である。
Hereinafter, the present invention will be described in detail by way of examples. Of course, the present invention is not limited to this.
The evaluation in the examples was measured by the following method.
(1) Wearing comfort An exercise shirt was sewed with the fabric according to the example and exercised until sweating, and the wearing comfort was subjected to sensory evaluation with 10 subjects, and the average value was defined as the wearing comfort.
There are actually 3 or more of the following.

5 : 発汗しても衣服のべとつき感や、蒸れ感がなく極めて快適
4 : 発汗時、べとつき感、蒸れ感を覚えない
3 : 発汗時、僅かに衣服がややべとつくが快適である
2 : 発汗時、べとつき感、蒸れ感を覚える
1 : 発汗時、かなりべとつき、蒸れ感も甚だしく不快である
5: Even if sweating, the clothes do not feel sticky or stuffy and extremely comfortable. 4: When sweating, do not feel sticky, stuffy. 3: When sweating, the clothes are slightly sticky but comfortable. 2: When sweating , I feel sticky and stuffy : When I sweat, I feel quite sticky and stuffy.

[実施例1]
キュプラ繊維(Cuと表記)56dt/30fとポリエステルW型断面糸56dt/30fとを、仮撚り加工前に阿波スピンドル社製インターレースノズルMK−2にて80個/mの交絡を入れた後に、TMTマシナリー社製マッハ33Hニップベルトタイプ仮撚り機にて加工速度300m/分、第1ヒーター温度200℃、ツイスターベルト角95°、延伸倍率0.984倍の条件で1ヒーター仮撚にて複合糸を試作した。この複合糸の捲縮伸長率は12.1%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維(PETと表記)の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ6.3%であった。
[Example 1]
After the cupra fiber (denoted as Cu) 56 dt / 30f and the polyester W-shaped cross-section yarn 56 dt / 30f were interlaced at 80 pieces / m with an interlace nozzle MK-2 manufactured by Awa Spindle Co., Ltd., TMT A composite yarn is formed by a single heater false twist under the conditions of a machining speed of 300 m / min, a first heater temperature of 200 ° C., a twister belt angle of 95 °, and a draw ratio of 0.984 times on a Mach 33H nip belt type false twister manufactured by Machinery. Prototype. The crimp elongation of this composite yarn was 12.1%. A milling knitted fabric knitted by alternately arranging two heater false twisted yarns of this composite yarn and non-water-absorbing fiber 84dt / 36f polyester fiber (indicated as PET) using a 28 gauge circular knitting machine is described below. The dyeing finish was performed under the conditions, the composite yarn was extracted from the fabric, and the water absorption elongation was measured to be 6.3%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で30℃×20分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment with sodium hydroxide at a concentration of 60 g / L at 30 ° C. for 20 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例2]
実施例1において、第1ヒーター温度を150℃とした以外は同じ糸種、同じ仮撚り条件で複合糸を試作した。この複合糸の捲縮伸長率は5.7%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ5.3%であった。
[Example 2]
In Example 1, a composite yarn was prototyped under the same yarn type and the same false twist conditions except that the first heater temperature was set to 150 ° C. The crimp elongation of this composite yarn was 5.7%. A milling knitted fabric in which this composite yarn and non-water absorbent fiber 84dt / 36f polyester fiber 2-heater false twisted yarn are alternately arranged using a 28 gauge circular knitting machine is dyed and finished under the following conditions. After processing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured and found to be 5.3%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で30℃×20分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment with sodium hydroxide at a concentration of 60 g / L at 30 ° C. for 20 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例3]
実施例1において、第1ヒーター温度を220℃、ツイスターベルト角を105°とした以外は同じ糸種、同じ仮撚り条件で複合糸を試作した。この複合糸の捲縮伸長率は18.8%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ5.0%であった。
[Example 3]
A composite yarn was prototyped under the same yarn type and the same false twist conditions except that the first heater temperature was 220 ° C. and the twister belt angle was 105 ° in Example 1. The crimp elongation of this composite yarn was 18.8%. A milling knitted fabric in which this composite yarn and non-water absorbent fiber 84dt / 36f polyester fiber 2-heater false twisted yarn are alternately arranged using a 28 gauge circular knitting machine is dyed and finished under the following conditions. After processing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured to be 5.0%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で30℃×20分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment with sodium hydroxide at a concentration of 60 g / L at 30 ° C. for 20 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例4]
キュプラ繊維56dt/30fとポリエステルW型断面糸56dt/30fとを、仮撚り加工前に阿波スピンドル社製インターレースノズルMK−2にて80個/mの交絡を入れた後に、TMTマシナリー社製マッハ33Hニップベルトタイプ仮撚り機にて加工速度300m/分、第1ヒーター温度200℃、ツイスターベルト角95°、延伸倍率0.984倍、第2ヒーター温度150℃、第2フィード率5.0%の条件で2ヒーター仮撚にて複合糸を試作した。この複合糸の捲縮伸長率は8.4%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ7.2%であった。
[Example 4]
The cupra fiber 56dt / 30f and the polyester W-shaped cross-section yarn 56dt / 30f are entangled at 80 pieces / m with an interlace nozzle MK-2 manufactured by Awa Spindle Co. before false twisting, and then Mach 33H manufactured by TMT Machinery Co., Ltd. With a nip belt type false twister, the processing speed is 300 m / min, the first heater temperature is 200 ° C., the twister belt angle is 95 °, the draw ratio is 0.984 times, the second heater temperature is 150 ° C., and the second feed rate is 5.0%. A composite yarn was prototyped by two-heater false twist under conditions. The crimp elongation of this composite yarn was 8.4%. A milling knitted fabric in which this composite yarn and non-water absorbent fiber 84dt / 36f polyester fiber 2-heater false twisted yarn are alternately arranged using a 28 gauge circular knitting machine is dyed and finished under the following conditions. After processing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured and found to be 7.2%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で30℃×20分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment with sodium hydroxide at a concentration of 60 g / L at 30 ° C. for 20 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例5]
実施例1において、ツイスターベルト角を105°とした以外は同じ糸種、同じ仮撚り条件で複合糸を試作した。この複合糸の捲縮伸長率は16.1%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ6.8%であった。
[Example 5]
A composite yarn was prototyped under the same yarn type and the same false twist conditions except that the twister belt angle was 105 ° in Example 1. The crimp elongation of this composite yarn was 16.1%. A milling knitted fabric in which this composite yarn and non-water absorbent fiber 84dt / 36f polyester fiber 2-heater false twisted yarn are alternately arranged using a 28 gauge circular knitting machine is dyed and finished under the following conditions. After processing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured and found to be 6.8%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で30℃×20分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment with sodium hydroxide at a concentration of 60 g / L at 30 ° C. for 20 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例6]
実施例1において、第1ヒーター温度を220℃とした以外は同じ糸種、同じ仮撚り条件で複合糸を試作した。この複合糸の捲縮伸長率は12.2%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ5.7%であった。
[Example 6]
In Example 1, a composite yarn was prototyped under the same yarn type and the same false twist conditions except that the first heater temperature was 220 ° C. The crimp elongation of this composite yarn was 12.2%. A milling knitted fabric in which this composite yarn and non-water absorbent fiber 84dt / 36f polyester fiber 2-heater false twisted yarn are alternately arranged using a 28 gauge circular knitting machine is dyed and finished under the following conditions. After processing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured and found to be 5.7%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で30℃×20分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment with sodium hydroxide at a concentration of 60 g / L at 30 ° C. for 20 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例7]
レーヨン繊維(Raと表記)84dt/31fと、ポリエステルW型断面糸84dt/30fとを、仮撚り加工前に阿波スピンドル社製インターレースノズルMK−2にて80個/mの交絡を入れた後に、TMTマシナリー社製マッハ33Hニップベルトタイプ仮撚り機にて加工速度300m/分、第1ヒーター温度200℃、ツイスターベルト角95°、延伸倍率0.984倍の条件で1ヒーター仮撚にて複合糸を試作した。この複合糸の捲縮伸長率は15.0%であった。この複合糸と非吸水繊維167dt/72fのポリエステル2ヒーター仮撚り加工糸を22ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ11.5%であった。
[Example 7]
After entanglement of 80 pcs / m of rayon fiber (expressed as Ra) 84dt / 31f and polyester W-shaped cross section yarn 84dt / 30f with an interlace nozzle MK-2 manufactured by Awa Spindle Co., Ltd. before false twisting, Composite yarn with 1 heater false twist under conditions of 300m / min processing speed, 200 ° C first heater temperature, 95 ° twister belt angle, 0.984 times draw ratio with Mach 33H nip belt type false twister manufactured by TMT Machinery Prototyped. The crimp elongation of this composite yarn was 15.0%. A milled knitted fabric in which this composite yarn and non-water-absorbing fiber 167 dt / 72f polyester 2 heater false twisted yarn are alternately arranged using a 22 gauge circular knitting machine is dyed and finished under the following conditions. The composite yarn was extracted from the fabric, and the water absorption elongation was measured and found to be 11.5%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で30℃×20分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment with sodium hydroxide at a concentration of 60 g / L at 30 ° C. for 20 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例8]
ポリエステルW型断面糸56dt/60fを、TMTマシナリー社製ATF−21ディスクフリクションタイプ仮撚り機にて加工速度400m/分、第1ヒーター温度180℃、ウレタンディスク枚数4枚、延伸倍率1.050倍の条件で仮撚り加工し得られた1ヒーター仮撚糸とキュプラ繊維56dt/30fとを仮撚り後にヘバライン社製インターレースノズルP−142にて70個/mの交絡を入れて複合糸とした。この複合糸の捲縮伸長率は12.1%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して2本置きになるよう配置して編成したスムース編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ4.5%であった。
[Example 8]
Polyester W-shaped cross section yarn 56dt / 60f processed by TMT Machinery ATF-21 disk friction type false twister 400m / min, 1st heater temperature 180 ° C, 4 urethane disks, draw ratio 1.050 times 1 heater false twisted yarn obtained by false twisting under the above conditions and cupra fiber 56 dt / 30f were false twisted and interlaced at 70 pieces / m by interlace nozzle P-142 manufactured by Hebaline Co. to obtain a composite yarn. The crimp elongation of this composite yarn was 12.1%. A smooth knitted fabric obtained by knitting the composite yarn and non-water-absorbing fiber 84dt / 36f polyester fiber 2-heater false-twisted yarn using a 28-gauge circular knitting machine arranged in two pieces under the following conditions After dyeing and finishing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured to be 4.5%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウム
50g/Lの濃度で40℃×30分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment at a concentration of 50 g / L of sodium hydroxide at 40 ° C. for 30 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[実施例9]
ポリエステル丸型断面糸56dt/36fを、TMTマシナリー社製ATF−21ディスクフリクションタイプ仮撚り機にて加工速度500m/分、第1ヒーター温度220℃、ウレタンディスク枚数4枚、延伸倍率1.050倍、第2ヒーター温度190℃、第2フィード率5.0%の条件で仮撚り加工し得られた2ヒーター仮撚糸とキュプラ繊維56dt/30fとを仮撚り後にヘバライン社製流体乱流ノズルT−311にてキュプラ繊維のフィード率4%、ポリエステル1ヒーター仮撚り糸のフィード率12%で交絡処理をし、複合糸とした。この複合糸の捲縮伸長率は16.1%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を22ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ4.2%であった。
[Example 9]
Polyester round cross-section yarn 56dt / 36f is processed by TMT Machinery ATF-21 disk friction type false twister, processing speed 500m / min, first heater temperature 220 ° C, 4 urethane disks, draw ratio 1.050 times , A two-heater false twisted yarn obtained by false twisting under conditions of a second heater temperature of 190 ° C. and a second feed rate of 5.0% and a cupra fiber 56 dt / 30f were false twisted, and then a fluid turbulent nozzle T- 311 was entangled with a feed rate of 4% for cupra fibers and a feed rate of 12% for polyester 1 heater false twisted yarn to obtain a composite yarn. The crimp elongation of this composite yarn was 16.1%. A milling knitted fabric knitted by alternately arranging two-heater false twisted yarn of this composite yarn and non-water-absorbing fiber 84dt / 36f polyester fiber using a 22 gauge circular knitting machine is dyed and finished under the following conditions: After processing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured to be 4.2%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で20℃×15分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then alkali-treated with sodium hydroxide at a concentration of 60 g / L at 20 ° C. for 15 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[比較例1]
ポリエステルW型断面糸56dt/30fを、TMTマシナリー社製ATF−21ディスクフリクションタイプ仮撚り機にて加工速度400m/分、第1ヒーター温度200℃、ウレタンディスク枚数5枚、延伸倍率1.050倍の条件で仮撚り加工し得られた1ヒーター仮撚糸とキュプラ繊維56dt/30fとを仮撚り後にヘバライン社製インターレースノズルP−142にて70個/mの交絡を入れて複合糸とした。この複合糸の捲縮伸長率は21.9%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して2本置きになるよう配置して編成したスムース編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ8.7%であった。
[Comparative Example 1]
Polyester W-shaped cross section yarn 56dt / 30f processed by TMT Machinery ATF-21 disk friction type false twister 400m / min, 1st heater temperature 200 ° C, 5 urethane disks, draw ratio 1.050 times 1 heater false twisted yarn obtained by false twisting under the above conditions and cupra fiber 56 dt / 30f were false twisted and interlaced at 70 pieces / m by interlace nozzle P-142 manufactured by Hebaline Co. to obtain a composite yarn. The crimp elongation of this composite yarn was 21.9%. A smooth knitted fabric obtained by knitting the composite yarn and non-water-absorbing fiber 84dt / 36f polyester fiber 2-heater false-twisted yarn using a 28-gauge circular knitting machine arranged in two pieces under the following conditions After dyeing and finishing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured. As a result, it was 8.7%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウム
50g/Lの濃度で40℃×30分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then subjected to alkali treatment at a concentration of 50 g / L of sodium hydroxide at 40 ° C. for 30 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[比較例2]
ポリエステルW型断面糸56dt/30fを、TMTマシナリー社製ATF−21ディスクフリクションタイプ仮撚り機にて加工速度500m/分、第1ヒーター温度220℃、ウレタンディスク枚数4枚、延伸倍率1.050倍、第2ヒーター温度190℃、第2フィード率5.0%の条件で仮撚り加工し得られた2ヒーター仮撚糸とキュプラ繊維56dt/30fとを仮撚り後にヘバライン社製インターレースノズルP−142にて70個/mの交絡を入れて複合糸とした。この複合糸の捲縮伸長率は3.0%であった。この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を22ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ1.1%であった。
[Comparative Example 2]
Polyester W-type cross section yarn 56dt / 30f processed by TMT Machinery ATF-21 disk friction type false twister, processing speed 500m / min, first heater temperature 220 ° C, 4 urethane disks, draw ratio 1.050 times The two heater false twisted yarn obtained by false twisting under the conditions of the second heater temperature of 190 ° C. and the second feed rate of 5.0% and the cupra fiber 56 dt / 30f were subjected to false twisting into an interlace nozzle P-142 made by Hebaline. 70 yarns / m was entangled into a composite yarn. The crimp elongation of this composite yarn was 3.0%. A milling knitted fabric knitted by alternately arranging two-heater false twisted yarn of this composite yarn and non-water-absorbing fiber 84dt / 36f polyester fiber using a 22 gauge circular knitting machine is dyed and finished under the following conditions: After processing, the composite yarn was extracted from the fabric, and the water absorption elongation was measured and found to be 1.1%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを60g/Lの濃度で20℃×15分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then alkali-treated with sodium hydroxide at a concentration of 60 g / L at 20 ° C. for 15 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[比較例3]
実施例1と同じ複合糸を使用し、この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ2.3%であった。
[Comparative Example 3]
Using the same composite yarn as in Example 1, two heater false twisted yarns of this composite yarn and non-water absorbing fiber 84dt / 36f polyester fiber are alternately arranged using a 28 gauge circular knitting machine. The milled knitted fabric was dyed and finished under the following conditions, and the composite yarn was extracted from the fabric and the water absorption elongation was measured to be 2.3%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、アルカリ処理をしないで130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine is put into a liquid dyeing machine, scoured at 80 ° C for 20 minutes, drained, and dyed only at the ester side at 130 ° C without alkali treatment, and the knitted fabric after dyeing is uneven. After drying using a short loop dryer, the knitted fabric was stretched with a pin tenter to the extent that wrinkles can be removed, and finished at 170 ° C. for 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

[比較例4]
実施例1と同じ複合糸を使用し、この複合糸と非吸水繊維84dt/36fのポリエステル繊維の2ヒーター仮撚り加工糸を28ゲージの丸編機を使用して交互になるよう配置して編成したフライス編地を下記条件にて染色仕上げ加工を行い、その布帛から複合糸を抜き出し吸水伸長率を測定したところ2.2%であった。
[Comparative Example 4]
Using the same composite yarn as in Example 1, two heater false twisted yarns of this composite yarn and non-water absorbing fiber 84dt / 36f polyester fiber are alternately arranged using a 28 gauge circular knitting machine. The milled knitted fabric was dyed and finished under the following conditions, and the composite yarn was extracted from the fabric and the water absorption elongation rate was measured to be 2.2%.

編成した生機を液流染色機に投入し、80℃×20分精練し排水後、水酸化ナトリウムを10g/Lの濃度で10℃×3分間アルカリ処理した。次いで、130℃でエステル側のみ染色を行い、染色上がりの編地は凹凸状となっているため、ショートループドライヤーを使用して乾燥後、ピンテンターにて編地のしわが取れる程度に伸長して170℃×60秒にて仕上げセットを行った。
得られた編地の運動発汗時の、快適性着用試験を行った。着用試験の結果を表1に示す。
The knitted raw machine was put into a liquid flow dyeing machine, scoured at 80 ° C. for 20 minutes, drained, and then alkali treated with sodium hydroxide at a concentration of 10 g / L for 10 ° C. for 3 minutes. Next, only the ester side is dyed at 130 ° C, and the dyed knitted fabric is uneven. After drying using a short loop dryer, the knitted fabric is stretched to the extent that wrinkles can be removed with a pin tenter. Finish setting was performed at 170 ° C. × 60 seconds.
A comfort wearing test was performed on the obtained knitted fabric during exercise sweating. The results of the wearing test are shown in Table 1.

Figure 2008111200
Figure 2008111200

本発明による複合糸を使用して布帛を製造すれば、着用時快適で、かつ、発汗時にもべとつき感や蒸れ感のない衣服が製造可能で、スポーツウェア、インナー、アウターなど衣服に於いて、快適な着用感が得られる。   If a fabric is produced using the composite yarn according to the present invention, it is possible to produce a garment that is comfortable when worn and does not feel sticky or stuffy when sweating. A comfortable wearing feeling is obtained.

Claims (3)

ポリエステル系繊維とセルロース繊維とからなる複合糸において、該複合糸の捲縮伸長率が5〜20%であり、吸水伸長率が4%以上であることを特徴とする複合糸。   A composite yarn comprising polyester fiber and cellulose fiber, wherein the composite yarn has a crimp elongation of 5 to 20% and a water absorption elongation of 4% or more. ポリエステル系繊維とセルロース繊維とを複合したのち、アルカリ水溶液20g/L以上、20℃以上、5分以上浸漬処理することを特徴とする請求項1に記載の複合糸の製造方法。   2. The method for producing a composite yarn according to claim 1, wherein after the polyester fiber and the cellulose fiber are combined, immersion treatment is performed at an alkaline aqueous solution of 20 g / L or more, 20 ° C. or more, and 5 minutes or more. 請求項1に記載の複合糸により製造された布帛。   A fabric produced from the composite yarn according to claim 1.
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JP2017101340A (en) * 2015-11-30 2017-06-08 旭化成株式会社 Cellulose-mixed circular knitted fabric

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KR101989744B1 (en) * 2018-06-02 2019-06-18 제원화섬 주식회사 Polyester complex yarn including bamboo filament having excellent refreshing touch effect and manufacturing process thereof
KR101989742B1 (en) * 2018-06-02 2019-06-18 제원화섬 주식회사 Interlace Textured yarn using bamboo fiber and Manufacturing process thereof

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JPH093740A (en) * 1995-06-16 1997-01-07 Asahi Chem Ind Co Ltd Composite textured yarn and fabric excellent in refreshingness
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WO2012049870A1 (en) * 2010-10-12 2012-04-19 旭化成せんい株式会社 Multilayered knitted fabric
CN103154344A (en) * 2010-10-12 2013-06-12 旭化成纤维株式会社 Multilayered knitted fabric
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