JP2008106169A5 - - Google Patents
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- Publication number
- JP2008106169A5 JP2008106169A5 JP2006291150A JP2006291150A JP2008106169A5 JP 2008106169 A5 JP2008106169 A5 JP 2008106169A5 JP 2006291150 A JP2006291150 A JP 2006291150A JP 2006291150 A JP2006291150 A JP 2006291150A JP 2008106169 A5 JP2008106169 A5 JP 2008106169A5
- Authority
- JP
- Japan
- Prior art keywords
- ethylenically unsaturated
- monomer
- unsaturated group
- meth
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000178 monomer Substances 0.000 claims description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 8
- 239000011347 resin Substances 0.000 claims description 8
- 229920005989 resin Polymers 0.000 claims description 8
- 239000011342 resin composition Substances 0.000 claims description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 238000010494 dissociation reaction Methods 0.000 claims description 4
- 230000005593 dissociations Effects 0.000 claims description 4
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- -1 phenoxyethyl Chemical group 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 150000002431 hydrogen Chemical class 0.000 claims 1
- 238000003775 Density Functional Theory Methods 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
Description
本発明者は、樹脂組成物中の炭素と水素との結合の解離エネルギーと理論活性水素量に着目し、特定の数値以下の炭素と水素との結合の解離エネルギーを有する理論活性水素の量が特定の数値範囲内にあれば、ＴＶＯＣの放散量が少なくなるという知見を得るに及んで、本発明を完成させるに至った。
すなわち本発明は、エチレン性不飽和基を含有する樹脂（１）及び一分子中にエチレン性不飽和基を１個有する単量体（２）を含んでなる硬化性樹脂組成物において、前記エチレン性不飽和基を含有する樹脂（１）が、ポリエステル（メタ）アクリレートであり、前記一分子中にエチレン性不飽和基を１個有する単量体（２）が、フェノキシエチル（メタ）アクリレート、ジシクロペンテニルオキシエチル（メタ）アクリレート、及び２−ヒドロキシエチル（メタ）アクリレートからなる群から選ばれる少なくとも１種であり、前記エチレン性不飽和基を含有する樹脂（１）及び／又は前記一分子中にエチレン性不飽和基を１個有する単量体中に炭素と水素との結合解離エネルギーが密度汎関数法に基づいて算出される値で８０ｋｃａｌ／ｍｏｌ以下の結合からなる活性水素を有し、前記活性水素の量が前記樹脂（１）と前記単量体（２）との合計１Ｋｇ中０．１〜２０ｍｏｌであることを特徴とする硬化性樹脂組成物に関する。
The inventor pays attention to the dissociation energy of the bond between carbon and hydrogen and the theoretically active hydrogen amount in the resin composition, and the amount of theoretically active hydrogen having the dissociation energy of the bond between carbon and hydrogen below a specific numerical value. As long as it is within a specific numerical range, the present inventors have completed the present invention in order to obtain the knowledge that the amount of TVOC emission is reduced.
That is, the present invention provides a ethylenically unsaturated group-containing resin-1 and curing resin composition comprising the monomer (2) having one ethylenically unsaturated group per molecule, the ethylene The resin (1) containing an ethylenically unsaturated group is a polyester (meth) acrylate, and the monomer (2) having one ethylenically unsaturated group in one molecule is a phenoxyethyl (meth) acrylate, Resin (1) and / or said one molecule which is at least one selected from the group consisting of dicyclopentenyloxyethyl (meth) acrylate and 2-hydroxyethyl (meth) acrylate, and contains said ethylenically unsaturated group 80 kcal / m as a value calculated based on the density functional theory of bond dissociation energy of carbon and hydrogen in a monomer having one ethylenically unsaturated group Curability characterized by having active hydrogen consisting of bonds of 1 or less, and the amount of the active hydrogen being 0.1-20 mol in a total of 1 kg of the resin (1) and the monomer (2) The present invention relates to a resin composition.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006291150A JP2008106169A (en) | 2006-10-26 | 2006-10-26 | Curable resin composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006291150A JP2008106169A (en) | 2006-10-26 | 2006-10-26 | Curable resin composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008106169A JP2008106169A (en) | 2008-05-08 |
| JP2008106169A5 true JP2008106169A5 (en) | 2009-12-10 |
Family
ID=39439798
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006291150A Pending JP2008106169A (en) | 2006-10-26 | 2006-10-26 | Curable resin composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2008106169A (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2010146912A1 (en) * | 2009-06-18 | 2010-12-23 | Dic株式会社 | Air-drying polyester (meth)acrylate resin composition, structure and method for providing same |
| KR101786778B1 (en) * | 2010-06-18 | 2017-10-18 | 디아이씨 가부시끼가이샤 | Urethane(meth)acrylate resin composition and coating material using same |
| JP5003854B2 (en) * | 2010-11-19 | 2012-08-15 | Ｄｉｃ株式会社 | Radical curable resin composition, coating material using the same, civil engineering building structure, and construction method thereof |
| JP5845935B2 (en) * | 2012-01-31 | 2016-01-20 | Dic株式会社 | Radical polymerizable resin composition |
| JP2014065873A (en) | 2012-09-27 | 2014-04-17 | Dic Corp | Radical-polymerizable compound |
| JP6212892B2 (en) * | 2013-03-25 | 2017-10-18 | Dic株式会社 | Radical curable composition and civil engineering building material |
| JP6394077B2 (en) * | 2014-06-04 | 2018-09-26 | Dic株式会社 | Radical polymerizable composition, concrete repair material and road primer |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002332316A (en) * | 2001-05-09 | 2002-11-22 | Dainippon Ink & Chem Inc | Unsaturated polyester resin composition, coating material and molded product |
| JP4151310B2 (en) * | 2001-05-22 | 2008-09-17 | Ｄｉｃ株式会社 | Curable unsaturated resin composition |
| JP4193490B2 (en) * | 2002-08-27 | 2008-12-10 | Ｄｉｃ株式会社 | Floor covering structure |
| JP5179696B2 (en) * | 2003-10-20 | 2013-04-10 | 昭和電工株式会社 | Low odor resin composition, coating material containing the same, and coating method using the same |
| JP2005154688A (en) * | 2003-11-28 | 2005-06-16 | Hitachi Chem Co Ltd | Thermosetting resin composition |
| JP2005255937A (en) * | 2004-03-15 | 2005-09-22 | Hitachi Chem Co Ltd | Unsaturated polyester resin composition and putty coating |
| JP4441868B2 (en) * | 2004-12-09 | 2010-03-31 | Ｄｉｃ株式会社 | Curable resin composition for civil engineering and building materials, civil engineering and building materials for application, and civil engineering buildings |
| JP4973914B2 (en) * | 2006-06-07 | 2012-07-11 | Ｄｉｃ株式会社 | Curable resin composition and waterproof material composition |
-
2006
- 2006-10-26 JP JP2006291150A patent/JP2008106169A/en active Pending
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