JP2008075036A - Lubricating composition for chuck sliding part - Google Patents

Lubricating composition for chuck sliding part Download PDF

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JP2008075036A
JP2008075036A JP2006258344A JP2006258344A JP2008075036A JP 2008075036 A JP2008075036 A JP 2008075036A JP 2006258344 A JP2006258344 A JP 2006258344A JP 2006258344 A JP2006258344 A JP 2006258344A JP 2008075036 A JP2008075036 A JP 2008075036A
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chuck
inorganic powder
grease
lubricating composition
sliding part
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JP5070783B2 (en
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Takuya Shinada
卓也 品田
Yuji Watanabe
祐史 渡辺
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Nok Klueber Co Ltd
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Nok Klueber Co Ltd
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Abstract

<P>PROBLEM TO BE SOLVED: To provide a lubricating composition for a chuck sliding part having improved frictional properties and durability which enable securing the improvement on the gripping force and the stability of a chuck. <P>SOLUTION: The lubricating composition for a chuck sliding part comprises a grease composed of a base oil and a thickening agent and an inorganic powder which accounts for 15-65 wt.% of the total amount of the grease and the inorganic powder. The inorganic powder which is used has a primary particle diameter or an average particle diameter of about 0.1-50 μm, preferably about 0.5-20 μm (provided that when the inorganic powder is silicon oxide, the average particle diameter is about 1-50 nm, preferably 5-40 nm). <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、チャック摺動部用潤滑組成物に関する。さらに詳しくは、チャックの把握力の向上や安定性を確保せしめる摩擦特性および耐久性を改善させたチャック摺動部用潤滑組成物に関する。   The present invention relates to a lubricating composition for a chuck sliding part. More specifically, the present invention relates to a lubricating composition for a sliding part of a chuck, which has improved friction characteristics and durability for ensuring improvement in chucking force and stability.

チャックは、チャッキング治具の一種であり、工作機械では最も一般的でかつ重要な構成部品の一つであるといえる。チャックの作動方式には、手動式、油圧式、空圧式、電動式などがあり、その開閉方式にはくさび形、カムレバー型、クランク型、ドローダウン型、スクロール型などがあり、一般的にはセルフロックが利き、内外径チャックもできることから、くさび形が多く使用されている。   The chuck is a kind of chucking jig and is one of the most common and important components in a machine tool. There are manual operation, hydraulic operation, pneumatic operation, electric operation, etc. as the chuck operation method, and there are wedge type, cam lever type, crank type, draw down type, scroll type, etc. A wedge shape is often used because of its self-locking and inner and outer diameter chucks.

従来から工作機械チャック摺動部にはグリースが使用されており、一般的にはチャック用グリースとして、基油として鉱油を、増稠剤としてリチウム系石けんを用いた汎用のグリースが使用されている。   Conventionally, grease has been used for machine tool chuck sliding parts. Generally, general-purpose grease using mineral oil as the base oil and lithium soap as the thickener is used as the grease for the chuck. .

また、キー付きチャック、キー無しチャック、すべての形式のコレット、迅速釈放チャック、タップ取付装置、鋸刃または研磨ディスクを駆動スピンドルに取り付けるナットおよびトルク増大装置、工具を駆動部材で取り付ける装置または機構などの工具保持装置の主要な摩擦係合構成部品に、好ましくはコーティングとして施された、固体薄膜潤滑剤が用いられており、固体潤滑剤は結合剤と顔料とからなり、結合剤に担持される粒子顔料として最も普通の組合せは、10%のグラファイトと90%の二硫化モリブデンであるとされている。
特表平11−506704公報
Also, chucks with keys, chucks without keys, all types of collets, quick release chucks, tap mounting devices, nuts and torque increasing devices for attaching saw blades or abrasive discs to drive spindles, devices or mechanisms for attaching tools with drive members, etc. A solid thin film lubricant, preferably applied as a coating, is used on the main frictional engagement components of the tool holding device of the present invention, which consists of a binder and a pigment and is carried by the binder The most common combination of particulate pigments is said to be 10% graphite and 90% molybdenum disulfide.
Japanese National Patent Publication No. 11-506704

これ迄は、冷却液や切削液に対する耐性のありグリースが必要特性として挙げられており、それらの特性を満足させるグリースが使用されてきたが、近年の加工速度の高速化や高精度加工化のため、ワークの強力把握や把握力の安定化が要求されており、このためチャックの把握力が重要な要素であるが、把握力の低下という問題でこうした要求に対応できないのが現状である。   Until now, grease with resistance to cooling fluid and cutting fluid has been listed as a necessary characteristic, and grease that satisfies those characteristics has been used. For this reason, there is a demand for powerful grasping of the workpiece and stabilization of the grasping force. For this reason, the grasping force of the chuck is an important factor, but the present situation is that it cannot respond to such a request due to the problem of a decrease in grasping force.

また、従来は、下記特許文献2〜3に示される如く、チャックのジョウ形状やジョウの軽量化に関する発明はみられるものの、把握力と塗布グリースとの関係についての検討はなされていない。
特許第2,646,076号公報 特許第2,579,750号公報
Conventionally, as shown in the following Patent Documents 2 to 3, although inventions relating to the shape of the chuck jaws and the weight reduction of the jaws have been seen, the relationship between the gripping force and the applied grease has not been studied.
Japanese Patent No. 2,646,076 Japanese Patent No. 2,579,750

グリースについてのチャックの把握は、マスタージョーとチャック本体との摺動によって起きており、摺動部の摩擦力が小さい程、より小さな力で把握することができる。しかしながら、従来の汎用グリースでは、摩擦力が大きいため、把握力の向上や安定性が望めないという問題がみられる。   The chuck grasps about the grease by sliding between the master jaw and the chuck body, and the smaller the frictional force of the sliding portion, the smaller the force can be grasped. However, the conventional general-purpose grease has a problem that improvement in grasping force and stability cannot be expected due to a large frictional force.

本発明の目的は、チャックの把握力の向上や安定性を確保せしめる摩擦特性および耐久性を改善させたチャック摺動部用潤滑組成物を提供することにある。   An object of the present invention is to provide a lubricating composition for a sliding part of a chuck that has improved friction characteristics and durability that can improve the gripping force and stability of the chuck.

かかる本発明の目的は、基油および増稠剤からなるグリースに、グリースとの合計量中15〜65重量%を占める割合で無機粉末を含有せしめたチャック摺動部用潤滑組成物によって達成される。無機粉末としては、一次粒径または平均粒径が約0.1〜50μm、好ましくは0.5〜20μm程度(ただし、酸化けい素にあっては平均粒径が約1〜50nm、好ましくは約5〜40nm程度)のものが用いられる。   The object of the present invention is achieved by a lubricating composition for a sliding part of a chuck, in which an inorganic powder is contained in a grease comprising a base oil and a thickener in a proportion of 15 to 65% by weight in the total amount of the grease. The The inorganic powder has a primary particle size or average particle size of about 0.1 to 50 μm, preferably about 0.5 to 20 μm (however, in the case of silicon oxide, the average particle size is about 1 to 50 nm, preferably about 5 to 40 nm. ) Is used.

本発明に係る潤滑組成物は、グリースに無機粉末を含有せしめることにより、これをチャック摺動部に適用したとき、摩擦係数によって示される摩擦特性および試験片ディスクの摩耗痕径によって示される耐久性を改善することができ、その結果前記の如き各種工作機械用チャックに大きな把握力を与えることができ、また把握力が一定となる、スティックスリップを起し難い、トライボ損傷を起し難い、冷却液や切削液に対する耐性が改善されるといった効果を奏する。   The lubricating composition according to the present invention includes an inorganic powder in grease, and when this is applied to a chuck sliding portion, the friction characteristic indicated by the friction coefficient and the durability indicated by the wear scar diameter of the test piece disk. As a result, a large gripping force can be given to the various machine tool chucks as described above, the gripping force is constant, stick-slip is difficult to occur, tribo damage is difficult to occur, cooling There is an effect that resistance to the fluid and the cutting fluid is improved.

基油としては、例えばパラフィン系、ナフテン系等の鉱物油、ポリ-α-オレフィン、エチレン・α-オレフィンコオリゴマー、ポリブデンまたはこれらの水素化物等の合成炭化水素油、ポリオールエステル、二塩基酸エステル、芳香族多価カルボン酸エステル、リン酸エステル、亜リン酸エステル、炭酸エステル等のエステル系合成油、アルキルジフェニルエーテル、ポリプロピレングリコール等のエーテル系合成油が挙げられる。   Base oils include, for example, paraffinic and naphthenic mineral oils, synthetic hydrocarbon oils such as poly-α-olefins, ethylene / α-olefin co-oligomers, polybutenes or their hydrides, polyol esters, dibasic acid esters And ester-based synthetic oils such as aromatic polycarboxylic acid esters, phosphoric acid esters, phosphite esters, and carbonic acid esters, and ether-based synthetic oils such as alkyl diphenyl ether and polypropylene glycol.

これらの各種基油の性状については特に制限がなく、使用条件に応じて適宜選択し得るが、一般にはその動粘度(40℃)が約2〜1000mm2/秒、好ましくは約5〜500mm2/秒のものが用いられる。これ以下の動粘度を有する基油を用いると、蒸発損失の増加や油膜強度の低下など寿命の低下や摩耗、焼付きの原因となる可能性があり、一方これ以上の動粘度のものを用いると、粘性抵抗の増加などトルクが大きくなる不具合を生ずる可能性がある。 The properties of these various base oils are not particularly limited and may be appropriately selected depending on the use conditions. In general, the kinematic viscosity (40 ° C.) is about 2 to 1000 mm 2 / sec, preferably about 5 to 500 mm 2. / Sec is used. Using a base oil with a kinematic viscosity lower than this may cause a decrease in life such as an increase in evaporation loss or a decrease in oil film strength, and may cause wear and seizure. And there is a possibility of causing a problem that the torque becomes large, such as an increase in viscous resistance.

増稠剤としては、リチウム系石けん、リチウム系複合石けん、カルシウム系石けん、カルシウム系複合石けん、バリウム系石けん、バリウム系複合石けん、アルミニウム系石けん、アルミニウム系複合石けん等の石けん類またはウレア系化合物が用いられる。   Thickeners include soaps such as lithium soaps, lithium complex soaps, calcium soaps, calcium complex soaps, barium soaps, barium complex soaps, aluminum soaps, aluminum complex soaps or urea compounds. Used.

無機粉末としては、窒化けい素、酸化けい素等のけい素化合物、リン酸カルシウム、リン酸亜鉛等のリン酸金属塩、酸化亜鉛、酸化マグネシウム等の金属酸化物などの粉末の少くとも一種が用いられる。これらの無機粉末は、一次粒径または平均粒径が約0.1〜50μm、好ましくは約0.5〜20μm程度のものが用いられ、ただし酸化けい素にあっては約1〜50nm、好ましくは約5〜40nmのものが用いられる。粒径がこれよりも小さい無機粉末を用いると耐久性に問題がみられ、一方これよりも大きい粒径の無機粉末を用いると、潤滑面に粉末粒子が円滑に供給されないため、所望の効果が得られない。   As the inorganic powder, at least one kind of powder such as a silicon compound such as silicon nitride and silicon oxide, a metal phosphate such as calcium phosphate and zinc phosphate, and a metal oxide such as zinc oxide and magnesium oxide is used. . These inorganic powders have a primary particle size or average particle size of about 0.1 to 50 μm, preferably about 0.5 to 20 μm. However, for silicon oxide, about 1 to 50 nm, preferably about 5 to The one with 40 nm is used. When using an inorganic powder having a particle size smaller than this, there is a problem in durability. On the other hand, if an inorganic powder having a particle size larger than this is used, the powder particles are not smoothly supplied to the lubricated surface, so that the desired effect is obtained. I can't get it.

これらの無機粉末は、基油および増稠剤からなるグリースとの合計量中約15〜65重量%、好ましくは約25〜55重量%を占める割合で用いられる。無機粉末の添加割合がこれ以下では、添加した無機粉末の能力が発揮されず、摩擦係数の低減が期待できず、一方これ以上の添加割合で無機粉末が用いられると、組成物が硬くなりすぎしかも離油が大きくなり、グリース化することができなくなる。   These inorganic powders are used in a ratio of about 15 to 65% by weight, preferably about 25 to 55% by weight, based on the total amount of the base oil and the thickener. If the addition ratio of the inorganic powder is less than this, the ability of the added inorganic powder is not exhibited, and a reduction in the friction coefficient cannot be expected. On the other hand, if the inorganic powder is used at an addition ratio higher than this, the composition becomes too hard. Moreover, the oil separation becomes large and it becomes impossible to make grease.

残りの約85〜35重量%、好ましくは約75〜45重量%を占めるグリースの内、基油は約99.9〜60重量%、好ましくは約95〜70重量%を、また増稠剤は約0.1〜40重量%、好ましくは約5〜30重量%を占めるような割合でそれぞれ用いられる。   Of the remaining grease of about 85-35%, preferably about 75-45%, the base oil is about 99.9-60%, preferably about 95-70%, and the thickener is about 0.1%. Each is used in a proportion of -40% by weight, preferably about 5-30% by weight.

組成物中には、さらに従来潤滑剤に添加されている酸化防止剤、防錆剤、腐食防止剤、極圧剤、油性剤、粘度指数向上剤等のその他の添加剤を必要に応じて添加することができる。酸化防止剤としては、例えば2,6-ジ第3ブチル-4-メチルフェノール、4,4′-メチレンビス(2,6-ジ第3ブチルフェノール)等のフェノール系の酸化防止剤、アルキルジフェニルアミン、トリフェニルアミン、フェニル-α-ナフチルアミン、フェノチアジン、アルキル化フェニル-α-ナフチルアミン、アルキル化フェノチアジン等のアミン系の酸化防止剤、さらにはリン酸系酸化防止剤、イオウ系酸化防止剤などが挙げられる。   In the composition, other additives such as antioxidants, rust inhibitors, corrosion inhibitors, extreme pressure agents, oiliness agents, viscosity index improvers, etc. that have been added to conventional lubricants are added as necessary. can do. Examples of the antioxidant include phenolic antioxidants such as 2,6-ditertiarybutyl-4-methylphenol and 4,4′-methylenebis (2,6-ditertiarybutylphenol), alkyldiphenylamine, Examples include amine-based antioxidants such as phenylamine, phenyl-α-naphthylamine, phenothiazine, alkylated phenyl-α-naphthylamine, and alkylated phenothiazine, and phosphoric acid-based antioxidants and sulfur-based antioxidants.

防錆剤としては、例えば脂肪酸、脂肪酸アミン、アルキルスルホン酸金属塩、アルキルスルホン酸アミン塩、酸化パラフィン、ポリオキシエチレンアルキルエーテル等が挙げられ、また腐食防止剤としては、例えばベンゾトリアゾール、ベンゾイミダゾール、チアジアゾール等が挙げられる。   Examples of the rust preventive agent include fatty acids, fatty acid amines, alkyl sulfonic acid metal salts, alkyl sulfonic acid amine salts, oxidized paraffins, polyoxyethylene alkyl ethers, and the like, and corrosion inhibitors include, for example, benzotriazole and benzimidazole. , Thiadiazole and the like.

極圧剤としては、例えばリン酸エステル、亜リン酸エステル、リン酸エステルアミン塩等のリン系化合物、スルフィド類、ジスルフィド類等のイオウ系化合物、ジアルキルジチオリン酸金属塩、ジアルキルジチオカルバミン酸金属塩等のイオウ系化合物金属塩、塩素化パラフィン、塩素化ジフェニル等の塩素系化合物などが挙げられる。   Examples of extreme pressure agents include phosphorous compounds such as phosphate esters, phosphite esters, and phosphate ester amine salts, sulfur compounds such as sulfides and disulfides, dialkyldithiophosphate metal salts, and dialkyldithiocarbamic acid metal salts. And sulfur-based compound metal salts, chlorinated paraffin, chlorinated diphenyl and other chlorinated compounds.

油性剤としては、例えば脂肪酸またはそのエステル、高級アルコール、多価アルコールまたはそのエステル、脂肪族アミン、脂肪酸モノグリセライド、モンタンワックス、アミド系ワックス等が挙げられる。また、他の固体潤滑剤としては、例えば二硫化モリブデン、グラファイト、窒化ホウ素、窒化シラン等が挙げられる。   Examples of the oily agent include fatty acids or esters thereof, higher alcohols, polyhydric alcohols or esters thereof, aliphatic amines, fatty acid monoglycerides, montan wax, amide waxes, and the like. Examples of other solid lubricants include molybdenum disulfide, graphite, boron nitride, and silane nitride.

粘度指数向上剤としては、ポリメタクリレート、エチレン-プロピレン共重合体、ポリイソブチレン、ポリアルキルスチレン、スチレン-イソプレン共重合体水素化物等が挙げられる。   Examples of the viscosity index improver include polymethacrylate, ethylene-propylene copolymer, polyisobutylene, polyalkylstyrene, styrene-isoprene copolymer hydride, and the like.

組成物の調製は、基油、増稠剤、無機粉末および他の必要な添加剤を所定量添加し、3本ロールまたは高圧ホモジナイザで十分に混練する方法等によって行われる。   The composition is prepared by a method of adding a predetermined amount of base oil, thickener, inorganic powder and other necessary additives and kneading sufficiently with a three-roll or high-pressure homogenizer.

次に、実施例について本発明の効果を説明する。   Next, effects of the present invention will be described with respect to examples.

実施例1〜6、比較例1〜6
基油A:鉱油(40℃動粘度30mm2/秒)
〃 B:ポリα-オレフィン油(40℃動粘度400mm2/秒)
〃 C:ポリアルキレングリコール油(40℃動粘度400mm2/秒)
増稠剤A:Li系石けん
〃 B:Li系複合石けん
〃 C:Ba系複合石けん
〃 D:Ca系複合石けん
無機粉末A:リン酸亜鉛(一次粒径3μm)
〃 B:酸化亜鉛(平均粒径2μm)
〃 C:酸化けい素(平均粒径14nm)
〃 D:MoS2(平均粒径10μm)
酸化防止剤:フェニルナフチルアミン
Examples 1-6, Comparative Examples 1-6
Base oil A: Mineral oil (40 ° C kinematic viscosity 30mm 2 / sec)
〃 B: Poly α-olefin oil (40 ° C kinematic viscosity 400mm 2 / sec)
〃 C: Polyalkylene glycol oil (40 ° C kinematic viscosity 400mm 2 / sec)
Thickener A: Li-based soap 〃 B: Li-based composite soap 〃 C: Ba-based composite soap 〃 D: Ca-based composite soap Inorganic powder A: Zinc phosphate (primary particle size 3μm)
〃 B: Zinc oxide (average particle size 2μm)
〃 C: Silicon oxide (average particle size 14nm)
〃 D: MoS 2 (average particle size 10μm)
Antioxidant: Phenylnaphthylamine

以上の基油、増稠剤、無機粉末および酸化防止剤(2重量部共通して使用)の各成分からなる潤滑組成物を、図1にその主要部品が示される装置(SRV試験機)のシリンダー1およびディスク2の間に供給し、次の試験条件下で、その間に発生する摩擦力から摩耗係数を測定すると共に、試験後のディスクの摩耗痕径を測定することにより耐久性を評価した。得られた測定結果は、次の表に示される。
(試験条件)
上部試験片:100CR6製シリンダー(15mm径、長さ22mm)
下部試験片:100CR6製ディスク(24mm径、長さ7.9mm)
試験荷重:200N
滑り距離:0.5mm
振動数:50Hz
試験温度:50℃
試験時間:60分間

基油 増稠剤 無機粉末 摩耗 摩耗
種類 重量部 種類 重量部 種類 重量部 係数 深さ(μm)
実施例1 A 65 A 5 A 28 0.19 0.5
〃 2 A 40 D 10 A 28 0.15 0.4
B 20
〃 3 A 35 C 15 A 20 0.15 0.4
B 28
〃 4 A 35 D 10 A 25 0.14 0.3
B 20
C 8
〃 5 B 50 C 20 B 28 0.18 0.5
〃 6 C 50 A 15 A 33 0.18 0.5
比較例1 A 83 A 15 − − >0.50 2.1
〃 2 A 78 A 10 D 10 0.38 1.2
〃 3 A 75 B 20 C 3 >0.50 2.2
〃 4 A 70 D 25 A 3 >0.50 1.9
〃 5 B 65 C 30 B 3 0.45 1.7
〃 6 C 66 C 28 A 4 0.43 1.8
Lubricating composition comprising the above base oil, thickener, inorganic powder and antioxidant (used in common by 2 parts by weight) is a component of the apparatus (SRV tester) whose main parts are shown in FIG. The durability was evaluated by measuring the wear coefficient from the friction force generated between the cylinder 1 and the disk 2 and measuring the friction coefficient generated during the test under the following test conditions. . The measurement results obtained are shown in the following table.
(Test conditions)
Upper test piece: 100CR6 cylinder (15mm diameter, 22mm length)
Lower specimen: 100CR6 disc (24mm diameter, 7.9mm length)
Test load: 200N
Sliding distance: 0.5mm
Frequency: 50Hz
Test temperature: 50 ℃
Test time: 60 minutes
table
Base oil thickener inorganic powder wear
Example Type Weight part type Weight part type Weight part coefficient Depth (μm)
Example 1 A 65 A 5 A 28 0.19 0.5
〃 2 A 40 D 10 A 28 0.15 0.4
B 20
3 3 A 35 C 15 A 20 0.15 0.4
B 28
4 4 A 35 D 10 A 25 0.14 0.3
B 20
C 8
5 5 B 50 C 20 B 28 0.18 0.5
C 6 C 50 A 15 A 33 0.18 0.5
Comparative Example 1 A 83 A 15 − −> 0.50 2.1
〃 2 A 78 A 10 D 10 0.38 1.2
〃 3 A 75 B 20 C 3> 0.50 2.2
4 4 A 70 D 25 A 3> 0.50 1.9
5 5 B 65 C 30 B 3 0.45 1.7
C 6 C 66 C 28 A 4 0.43 1.8

測定に用いられたSRV試験機の概略図である。It is the schematic of the SRV testing machine used for the measurement.

符号の説明Explanation of symbols

1 シリンダー
2 ディスク
1 cylinder 2 disc

Claims (3)

基油および増稠剤からなるグリースに、グリースとの合計量中15〜65重量%を占める割合で無機粉末を含有せしめてなるチャック摺動部用潤滑組成物。   A lubricant composition for a sliding part of a chuck, wherein inorganic grease is contained in a grease comprising a base oil and a thickener at a ratio of 15 to 65% by weight in the total amount of the grease. 無機粉末がけい素化合物、リン酸金属塩および金属酸化物の少くとも一種である請求項1記載のチャック摺動部用潤滑組成物。   The lubricating composition for a chuck sliding portion according to claim 1, wherein the inorganic powder is at least one of a silicon compound, a metal phosphate, and a metal oxide. 一次粒径または平均粒径が0.1〜50μmの無機粉末(ただし、酸素けい素にあっては1〜50nm)が用いられた請求項1または2記載のチャック摺動部用潤滑組成物。   The lubricating composition for a chuck sliding portion according to claim 1 or 2, wherein an inorganic powder having a primary particle size or an average particle size of 0.1 to 50 µm (however, 1 to 50 nm for silicon oxide) is used.
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Cited By (3)

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Publication number Priority date Publication date Assignee Title
CN107674737A (en) * 2017-09-20 2018-02-09 安徽劲派纺织服饰有限公司 Maintaining agent and preparation method thereof before a kind of metal slide fastener tooth dispatches from the factory
JP2021509423A (en) * 2017-12-21 2021-03-25 ディーディーピー スペシャルティ エレクトロニック マテリアルズ ユーエス 9 リミテッド ライアビリティ カンパニー Lubricating grease composition
US11781087B2 (en) 2017-12-21 2023-10-10 Ddp Specialty Electronic Materials Us9, Llc Lubricant composition for clamping devices

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JP2005255977A (en) * 2004-02-09 2005-09-22 Ntn Corp Grease composition and rolling bearing
JP2006124426A (en) * 2004-10-26 2006-05-18 Nsk Ltd Grease composition, rolling bearing and rolling bearing device for supporting wheel

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JPH08157859A (en) * 1994-12-02 1996-06-18 Showa Shell Sekiyu Kk Lubricating grease composition
JPH11217582A (en) * 1998-02-04 1999-08-10 Nippon Seiko Kk Grease for roller bearing
JP2003003186A (en) * 2001-06-20 2003-01-08 Dow Corning Asia Ltd POLY-alpha-OLEFIN GREASE COMPOSITION
JP2003301188A (en) * 2002-04-09 2003-10-21 Mitsubishi Heavy Ind Ltd Lubricating grease and bearing using the lubricating grease
JP2004256588A (en) * 2003-02-24 2004-09-16 Nsk Ltd Lubricating oil composition for traction and traction drive
JP2005255977A (en) * 2004-02-09 2005-09-22 Ntn Corp Grease composition and rolling bearing
JP2006124426A (en) * 2004-10-26 2006-05-18 Nsk Ltd Grease composition, rolling bearing and rolling bearing device for supporting wheel

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107674737A (en) * 2017-09-20 2018-02-09 安徽劲派纺织服饰有限公司 Maintaining agent and preparation method thereof before a kind of metal slide fastener tooth dispatches from the factory
JP2021509423A (en) * 2017-12-21 2021-03-25 ディーディーピー スペシャルティ エレクトロニック マテリアルズ ユーエス 9 リミテッド ライアビリティ カンパニー Lubricating grease composition
JP7230029B2 (en) 2017-12-21 2023-02-28 ディーディーピー スペシャルティ エレクトロニック マテリアルズ ユーエス 9 リミテッド ライアビリティ カンパニー lubricating grease composition
US11781087B2 (en) 2017-12-21 2023-10-10 Ddp Specialty Electronic Materials Us9, Llc Lubricant composition for clamping devices

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