JP2008074975A - Contamination-proof detergent composition for hard surface, washing material impregnated with the composition and washing method using those - Google Patents
Contamination-proof detergent composition for hard surface, washing material impregnated with the composition and washing method using those Download PDFInfo
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- JP2008074975A JP2008074975A JP2006256309A JP2006256309A JP2008074975A JP 2008074975 A JP2008074975 A JP 2008074975A JP 2006256309 A JP2006256309 A JP 2006256309A JP 2006256309 A JP2006256309 A JP 2006256309A JP 2008074975 A JP2008074975 A JP 2008074975A
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- Prior art keywords
- water
- ethylene oxide
- mass
- composition
- detergent composition
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- 239000000203 mixture Substances 0.000 title claims abstract description 79
- 239000003599 detergent Substances 0.000 title claims abstract description 34
- 238000000034 method Methods 0.000 title claims abstract description 17
- 239000000463 material Substances 0.000 title abstract description 26
- 238000005406 washing Methods 0.000 title abstract description 10
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 42
- 229920001577 copolymer Polymers 0.000 claims abstract description 40
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 35
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000004094 surface-active agent Substances 0.000 claims abstract description 21
- 239000002738 chelating agent Substances 0.000 claims abstract description 18
- 239000003021 water soluble solvent Substances 0.000 claims abstract description 18
- 230000003373 anti-fouling effect Effects 0.000 claims description 46
- 238000004140 cleaning Methods 0.000 claims description 31
- 239000011550 stock solution Substances 0.000 claims description 8
- 239000011538 cleaning material Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 claims description 4
- 238000005507 spraying Methods 0.000 claims description 4
- 238000001139 pH measurement Methods 0.000 claims description 3
- 238000007865 diluting Methods 0.000 claims description 2
- 229920003023 plastic Polymers 0.000 abstract description 15
- 239000004033 plastic Substances 0.000 abstract description 15
- 239000000344 soap Substances 0.000 abstract description 10
- 239000008233 hard water Substances 0.000 abstract description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 7
- 239000011777 magnesium Substances 0.000 abstract description 7
- 229910052749 magnesium Inorganic materials 0.000 abstract description 7
- 239000008399 tap water Substances 0.000 abstract description 7
- 235000020679 tap water Nutrition 0.000 abstract description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 abstract description 6
- 239000011575 calcium Substances 0.000 abstract description 6
- 229910052791 calcium Inorganic materials 0.000 abstract description 6
- 235000020681 well water Nutrition 0.000 abstract description 6
- 239000002349 well water Substances 0.000 abstract description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 4
- 239000011707 mineral Substances 0.000 abstract description 4
- 239000000356 contaminant Substances 0.000 abstract 3
- 230000008021 deposition Effects 0.000 abstract 1
- 230000002040 relaxant effect Effects 0.000 abstract 1
- -1 polyethylene Polymers 0.000 description 47
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 230000002378 acidificating effect Effects 0.000 description 11
- 229920000642 polymer Polymers 0.000 description 11
- 239000000126 substance Substances 0.000 description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 10
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 10
- 239000011976 maleic acid Substances 0.000 description 10
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 10
- 239000004698 Polyethylene Substances 0.000 description 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 9
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 9
- 229920000573 polyethylene Polymers 0.000 description 9
- 210000002374 sebum Anatomy 0.000 description 9
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 8
- 239000004480 active ingredient Substances 0.000 description 8
- 229920001155 polypropylene Polymers 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 8
- 239000000243 solution Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- 229910052783 alkali metal Inorganic materials 0.000 description 7
- 239000003093 cationic surfactant Substances 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 230000007935 neutral effect Effects 0.000 description 7
- 159000000000 sodium salts Chemical class 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000012459 cleaning agent Substances 0.000 description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 6
- 238000010979 pH adjustment Methods 0.000 description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229960005069 calcium Drugs 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 230000033001 locomotion Effects 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 238000010998 test method Methods 0.000 description 5
- RGHNJXZEOKUKBD-SQOUGZDYSA-N D-gluconic acid Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 235000015165 citric acid Nutrition 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 235000014113 dietary fatty acids Nutrition 0.000 description 4
- 239000000194 fatty acid Substances 0.000 description 4
- 229930195729 fatty acid Natural products 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 150000007524 organic acids Chemical class 0.000 description 4
- 235000005985 organic acids Nutrition 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 229920006395 saturated elastomer Polymers 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 4
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 3
- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000001630 malic acid Substances 0.000 description 3
- 235000011090 malic acid Nutrition 0.000 description 3
- 235000010755 mineral Nutrition 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 230000003472 neutralizing effect Effects 0.000 description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 3
- 229920001451 polypropylene glycol Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000005201 scrubbing Methods 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- 239000001124 (E)-prop-1-ene-1,2,3-tricarboxylic acid Substances 0.000 description 2
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical compound CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 229920002125 Sokalan® Polymers 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 2
- 229940091181 aconitic acid Drugs 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 description 2
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- 239000012298 atmosphere Substances 0.000 description 2
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- GTZCVFVGUGFEME-IWQZZHSRSA-N cis-aconitic acid Chemical compound OC(=O)C\C(C(O)=O)=C\C(O)=O GTZCVFVGUGFEME-IWQZZHSRSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
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- 239000000839 emulsion Substances 0.000 description 2
- 150000002169 ethanolamines Chemical class 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000000174 gluconic acid Substances 0.000 description 2
- 235000012208 gluconic acid Nutrition 0.000 description 2
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 2
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- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
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- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 description 2
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- QWOZZTWBWQMEPD-UHFFFAOYSA-N 1-(2-ethoxypropoxy)propan-2-ol Chemical compound CCOC(C)COCC(C)O QWOZZTWBWQMEPD-UHFFFAOYSA-N 0.000 description 1
- ZFPGARUNNKGOBB-UHFFFAOYSA-N 1-Ethyl-2-pyrrolidinone Chemical compound CCN1CCCC1=O ZFPGARUNNKGOBB-UHFFFAOYSA-N 0.000 description 1
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- XXXQFHALDVELNQ-UHFFFAOYSA-N 1-ethylpyrrolidin-3-one Chemical compound CCN1CCC(=O)C1 XXXQFHALDVELNQ-UHFFFAOYSA-N 0.000 description 1
- RERATEUBWLKDFE-UHFFFAOYSA-N 1-methoxy-2-[2-(2-methoxypropoxy)propoxy]propane Chemical compound COCC(C)OCC(C)OCC(C)OC RERATEUBWLKDFE-UHFFFAOYSA-N 0.000 description 1
- SLPUTJFVMJPMKV-UHFFFAOYSA-N 1-methylpyrrolidin-3-one Chemical compound CN1CCC(=O)C1 SLPUTJFVMJPMKV-UHFFFAOYSA-N 0.000 description 1
- IBLKWZIFZMJLFL-UHFFFAOYSA-N 1-phenoxypropan-2-ol Chemical compound CC(O)COC1=CC=CC=C1 IBLKWZIFZMJLFL-UHFFFAOYSA-N 0.000 description 1
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- HLCFGWHYROZGBI-JJKGCWMISA-M Potassium gluconate Chemical compound [K+].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O HLCFGWHYROZGBI-JJKGCWMISA-M 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
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- 229920000297 Rayon Polymers 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- QPFYNOGVFGQCTI-UHFFFAOYSA-N [F].CCOC(N)=O Chemical compound [F].CCOC(N)=O QPFYNOGVFGQCTI-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960000686 benzalkonium chloride Drugs 0.000 description 1
- 125000005501 benzalkonium group Chemical class 0.000 description 1
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 description 1
- 229940052299 calcium chloride dihydrate Drugs 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- NCEXYHBECQHGNR-UHFFFAOYSA-N chembl421 Chemical compound C1=C(O)C(C(=O)O)=CC(N=NC=2C=CC(=CC=2)S(=O)(=O)NC=2N=CC=CC=2)=C1 NCEXYHBECQHGNR-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- YXVFQADLFFNVDS-UHFFFAOYSA-N diammonium citrate Chemical compound [NH4+].[NH4+].[O-]C(=O)CC(O)(C(=O)O)CC([O-])=O YXVFQADLFFNVDS-UHFFFAOYSA-N 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- WPUMTJGUQUYPIV-JIZZDEOASA-L disodium (S)-malate Chemical compound [Na+].[Na+].[O-]C(=O)[C@@H](O)CC([O-])=O WPUMTJGUQUYPIV-JIZZDEOASA-L 0.000 description 1
- HQWKKEIVHQXCPI-UHFFFAOYSA-L disodium;phthalate Chemical compound [Na+].[Na+].[O-]C(=O)C1=CC=CC=C1C([O-])=O HQWKKEIVHQXCPI-UHFFFAOYSA-L 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011151 fibre-reinforced plastic Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- YVIVRJLWYJGJTJ-UHFFFAOYSA-N gamma-Valerolactam Chemical compound CC1CCC(=O)N1 YVIVRJLWYJGJTJ-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- WRUGWIBCXHJTDG-UHFFFAOYSA-L magnesium sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=O WRUGWIBCXHJTDG-UHFFFAOYSA-L 0.000 description 1
- 229940061634 magnesium sulfate heptahydrate Drugs 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- URLKBWYHVLBVBO-UHFFFAOYSA-N p-dimethylbenzene Natural products CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 239000001508 potassium citrate Substances 0.000 description 1
- 229960002635 potassium citrate Drugs 0.000 description 1
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 description 1
- 235000011082 potassium citrates Nutrition 0.000 description 1
- 239000004224 potassium gluconate Substances 0.000 description 1
- 235000013926 potassium gluconate Nutrition 0.000 description 1
- 229960003189 potassium gluconate Drugs 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- QGKLPGKXAVVPOJ-UHFFFAOYSA-N pyrrolidin-3-one Chemical compound O=C1CCNC1 QGKLPGKXAVVPOJ-UHFFFAOYSA-N 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000019265 sodium DL-malate Nutrition 0.000 description 1
- HELHAJAZNSDZJO-OLXYHTOASA-L sodium L-tartrate Chemical compound [Na+].[Na+].[O-]C(=O)[C@H](O)[C@@H](O)C([O-])=O HELHAJAZNSDZJO-OLXYHTOASA-L 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 235000011083 sodium citrates Nutrition 0.000 description 1
- 239000000176 sodium gluconate Substances 0.000 description 1
- 235000012207 sodium gluconate Nutrition 0.000 description 1
- 229940005574 sodium gluconate Drugs 0.000 description 1
- 239000001394 sodium malate Substances 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 229940074404 sodium succinate Drugs 0.000 description 1
- ZDQYSKICYIVCPN-UHFFFAOYSA-L sodium succinate (anhydrous) Chemical compound [Na+].[Na+].[O-]C(=O)CCC([O-])=O ZDQYSKICYIVCPN-UHFFFAOYSA-L 0.000 description 1
- 239000001433 sodium tartrate Substances 0.000 description 1
- 229960002167 sodium tartrate Drugs 0.000 description 1
- 235000011004 sodium tartrates Nutrition 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3707—Polyethers, e.g. polyalkyleneoxides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
- C11D3/3765—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2065—Polyhydric alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Abstract
Description
本発明は、特にポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材で構成される浴室や浴槽、さらには腰掛け、手おけ、およびスノコなどの浴室用具に用いることにより、これら被洗浄物の表面に酸化エチレン／酸化プロピレン／酸化エチレン共重合体が吸着し、親水性の単分子皮膜を形成させ、素材表面に防汚性を与え、せっけんかすや、皮脂、および水道水や井戸水の硬水成分であるカルシウムやマグネシウムなどの無機質分（スケール）等の汚れの付着を和らげ、これらの汚れが付着しても容易に洗浄、除去できる硬表面用防汚洗浄剤組成物に関するものである。
なお、ＦＲＰとは、Ｆｉｂｅｒ Ｒｅｉｎｆｏｒｃｅｄ Ｐｌａｓｔｉｃの略で、広義の意味として強化ガラス繊維プラスチックのことであり、代表的なものとして補強材にガラス繊維、マトリックスに不飽和ポリエステル樹脂、エポキシ樹脂、ビニルエステル樹脂などを使用したものが挙げられる。（「ＦＲＰ成形の実際」（株）高分子刊行会。）
The present invention is particularly useful for bathrooms and bathtubs made of plastic materials such as polyethylene, polypropylene, and FRP, as well as bathroom utensils such as stools, handles, and slats. Propylene oxide / ethylene oxide copolymer adsorbs, forms a hydrophilic monomolecular film, imparts antifouling properties to the material surface, soap and sebum, and hard water components of tap water and well water such as calcium and magnesium The present invention relates to an antifouling detergent composition for hard surfaces that can reduce the adhesion of dirt such as inorganic matter (scale) and the like, and can be easily washed and removed even if these dirt adheres.
In addition, FRP is an abbreviation for Fiber Reinforced Plastic, which means reinforced glass fiber plastic in a broad sense. Typical examples include glass fiber as a reinforcing material, unsaturated polyester resin, epoxy resin, vinyl ester resin as a matrix. Etc. are used. ("Practical FRP molding", Kobunshi Publishing Co., Ltd.)
ビジネスホテルやシティーホテル、ファッションホテル、および観光ホテルなどの浴室や浴槽、および洗面台の多くは、ＦＲＰを主体としたプラスチック素材で構成されている。
これらの箇所は、常時宿泊客に利用され、素材の表面は絶えず温水のシャワーやせっけん、シャンプー、リンス、ハンドソープ、化粧品などの使用に晒されている。その結果、素材の表面には、常時、上記の風呂汚れが付着してしまう。
これらの汚れに対して、施設を管理する作業者は従来から、浴室用中性洗剤、および酸性〜弱酸性の浴室用洗剤等を用いてきた。
Many bathrooms, bathtubs, and washstands at business hotels, city hotels, fashion hotels, and tourist hotels are made of plastic materials mainly composed of FRP.
These parts are always used by guests, and the surface of the material is constantly exposed to the use of hot water showers and soaps, shampoos, rinses, hand soaps and cosmetics. As a result, the bath dirt always adheres to the surface of the material.
For these stains, workers who manage facilities have conventionally used neutral bathroom detergents and acidic to weakly acidic bathroom detergents.
浴室用中性洗剤としては、例えば、特開昭６１−２８３７００号公報には、カチオン界面活性剤、非イオン界面活性剤、およびマレイン酸系の（共）重合体を含有する洗浄力に優れた浴室用中性洗浄剤組成物が開示されている。（特許文献１を参照。）また、特開平１−２２１４９７号公報には、カチオン界面活性剤、非イオン界面活性剤、アミノカルボン酸類を含有する洗浄力とケイ酸スケール付着防止性に優れた浴室用中性洗浄剤組成物が開示されている。（特許文献２を参照。）また、酸性〜弱酸性の洗浄剤としては、特開昭５１−７１３０２号公報および特開昭５２−７７１１１号公報に、有機酸、界面活性剤および水溶性溶剤を含有する洗浄剤組成物が開示されている。（特許文献３及び特許文献４を参照。）さらに、特開昭６４−３８４９８号公報には、界面活性剤、ヒドロキシ多価カルボン酸類、アクリル酸またはメタクリル酸類の重合体（共重合体）類および水溶性溶剤を含有し、組成物のｐＨが３〜６である浴室用洗浄剤組成物が開示されている。（特許文献５を参照。） As a neutral detergent for bathrooms, for example, Japanese Patent Application Laid-Open No. 61-283700 has an excellent detergency containing a cationic surfactant, a nonionic surfactant, and a maleic acid-based (co) polymer. A neutral detergent composition for bathrooms is disclosed. (See Patent Document 1) Japanese Patent Application Laid-Open No. 1-222197 discloses a bathroom having a cationic surfactant, a nonionic surfactant, an aminocarboxylic acid-containing detergency and excellent anti-silicate adhesion. A neutral detergent composition for use is disclosed. (See Patent Document 2.) Further, as acidic to weakly acidic detergents, Japanese Patent Application Laid-Open Nos. 51-71302 and 52-77111 describe organic acids, surfactants and water-soluble solvents. Disclosed cleaning compositions are disclosed. (See Patent Document 3 and Patent Document 4) Further, JP-A No. 64-38498 discloses surfactants, hydroxy polyvalent carboxylic acids, acrylic acid or methacrylic acid polymers (copolymers), and A bathroom cleaning composition containing a water-soluble solvent and having a pH of 3 to 6 is disclosed. (See Patent Document 5)
また、防汚性能を謳う先願特許としては、例えば、特開平３−１９７５９６号公報には、ジメチルシロキサンなどのシリコーンを主体とし、界面活性剤や水溶性溶剤、金属イオン封鎖剤等を含有した洗浄剤組成物が開示されている。（特許文献６を参照。）また、特開２０００−１９８９９９号公報には、第四級アンモニウム型カチオン界面活性剤、新水性シリコーンを含有する硬質表面防汚抗菌洗浄剤組成物が開示されている。（特許文献７を参照。）さらには、特開２００４−１６２０４１号公報には、ポリエーテルアミドアミノ変性シリコーンと界面活性剤、キレート剤等を含有した防汚洗浄剤組成物が開示されている。（特許文献８を参照。）
しかしながら、上記の中性、および酸性〜弱酸性の洗浄剤では、軽度な風呂汚れに対してはそれなりの洗浄力を発揮していたが、堆積した頑固な風呂汚れに対しては、充分に汚れを洗浄することができなかった。そのため、研磨材を含むクレンザーや硬質洗浄パッドなどを併用して、過度なこすり洗いを行い、浴槽等のプラスチック表面が傷つき荒れてしまったことで、かえって石鹸カスや皮脂汚れ等の汚れが付着し易くなるといった悪循環をまねいていた。このため、浴槽、浴室等を傷めず、簡便な浴室施設の維持管理や洗浄作業が求められていた。 However, the neutral and acidic to mildly acidic cleaning agents described above showed some detergency against mild bath stains, but they were sufficiently soiled against accumulated stubborn bath stains. Could not be washed. For this reason, excessive scrubbing with a cleanser or hard cleaning pad containing abrasives, and the plastic surface of the bathtub and the like has been damaged and roughened, so that dirt such as soap scum and sebum dirt will adhere. It was mimicking a vicious cycle of becoming easier. For this reason, the maintenance management and washing | cleaning operation | work of simple bathroom facilities were calculated | required, without damaging a bathtub, a bathroom, etc.
また、特に酸性〜弱酸性の洗浄剤では、塩素系洗浄剤・漂白剤との併用による塩素ガス中毒の恐れがあることや、金属、プラスチック等の被洗浄物を損傷しやすいこと、さらには、誤って皮膚に付着した場合には炎症を起こすおそれがある等の問題があった。
一方、防汚性能を有する洗浄剤組成物としては、主な防汚成分として、ジメチルポリシロキサンや親水性官能基型変性シリコーンを含有するものが提案されているが満足のいく防汚効果を有するものに至っていない。
In particular, with acidic to weakly acidic cleaning agents, there is a risk of chlorine gas poisoning due to the combined use with chlorine-based cleaning agents and bleaching agents, and it is easy to damage objects to be cleaned such as metals and plastics. There was a problem that it may cause inflammation if it accidentally adheres to the skin.
On the other hand, as a cleaning composition having antifouling performance, a composition containing dimethylpolysiloxane or hydrophilic functional group-modified silicone as a main antifouling component has been proposed, but has a satisfactory antifouling effect. It hasn't reached anything.
本発明は、このような事情に鑑みなされたもので、特にポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材で構成される浴室や浴槽、さらには腰掛け、手おけ、およびスノコなどの浴室用具に用いることにより、これらの対象面に酸化エチレン／酸化プロピレン／酸化エチレン共重合体が吸着し、親水性の単分子皮膜を形成させ、素材表面に防汚性を与え、せっけんかすや、皮脂、および水道水や井戸水の硬水成分であるカルシウムやマグネシウムなどの無機質分（スケール）等の汚れの付着を和らげ、これらの汚れが付着しても簡便に洗浄、除去できる硬表面用防汚洗浄剤組成物及び該組成物を含浸した洗浄材ならびにそれらを用いた洗浄方法の提供を目的とする。 The present invention has been made in view of such circumstances, and particularly by being used for bathrooms and bathtubs made of plastic materials such as polyethylene, polypropylene, and FRP, and also bathroom equipment such as stools, handbags, and slats. , Ethylene oxide / propylene oxide / ethylene oxide copolymer is adsorbed on these target surfaces, forming a hydrophilic monomolecular film, giving antifouling properties to the surface of the material, soap, sebum, tap water, Antifouling detergent composition for hard surface that can soften and remove dirt such as inorganic matter (scale) such as calcium and magnesium, which are hard water components of well water, and can be easily cleaned and removed even if these dirt adheres, and the composition It is an object of the present invention to provide a cleaning material impregnated with an object and a cleaning method using them.
上記の目的を達成するため、本発明は、（Ａ）下記の式で表される、酸化エチレン／酸化プロピレン／酸化エチレン共重合体０．５〜６０質量％、（Ｂ）界面活性剤０．１〜１５質量％、（Ｃ）キレート剤０．１〜１５質量％、（Ｄ）水溶性溶剤０．１〜１５質量％、及び（Ｅ）水を残質量％含有する硬表面用防汚洗浄剤組成物を第１の要旨とする。
ＨＯ−（Ｃ２Ｈ４Ｏ）ｎ−（Ｃ３Ｈ６Ｏ）ｍ−（Ｃ２Ｈ４Ｏ）ｎ−Ｈ （ただしｎは０でない整数）
In order to achieve the above object, the present invention provides: (A) 0.5 to 60% by mass of an ethylene oxide / propylene oxide / ethylene oxide copolymer represented by the following formula; 1-15% by mass, (C) 0.1-15% by mass of a chelating agent, (D) 0.1-15% by mass of a water-soluble solvent, and (E) antifouling cleaning for hard surfaces containing the remaining mass% of water The agent composition is the first gist.
HO- (C 2 H 4 O) n- (C 3 H 6 O) m- (C 2 H 4 O) n-H ( where n is not 0 integer)
また、本発明は上記（Ａ）成分の酸化エチレン／酸化プロピレン／酸化エチレン共重合体の平均分子量が４，０００以上、２５，０００以下である硬表面用防汚洗浄剤組成物を第２の要旨とする。 The present invention also provides a second antifouling detergent composition for hard surfaces, wherein the ethylene oxide / propylene oxide / ethylene oxide copolymer (A) has an average molecular weight of 4,000 or more and 25,000 or less. The gist.
さらに、本発明は、上記（Ａ）成分の酸化エチレン／酸化プロピレン／酸化エチレン共重合体の平均分子量中に占める酸化エチレンの割合が５０〜８５質量％である硬表面用防汚洗浄剤組成物を第３の要旨とする。 Furthermore, the present invention provides an antifouling detergent composition for hard surfaces, wherein the proportion of ethylene oxide in the average molecular weight of the ethylene oxide / propylene oxide / ethylene oxide copolymer of component (A) is 50 to 85% by mass. Is the third gist.
浴室用及び浴槽用の用途である硬表面用防汚洗浄剤組成物を第４の要旨とする。 The antifouling detergent composition for hard surfaces, which is used for bathrooms and bathtubs, is a fourth gist.
上記硬表面用防汚洗浄剤組成物の原液のｐＨ（ＪＩＳ Ｚ−８８０２：１９８４「ｐＨ測定法」による）は、２５℃で、６〜８に設定されている硬表面用防汚洗浄剤組成物を第５の要旨とする。 The pH of the stock solution of the antifouling detergent composition for hard surfaces (according to JIS Z-8802: 1984 “pH measurement method”) is 25 ° C. and set to 6-8. This is the fifth gist.
上記硬表面用防汚洗浄剤組成物を含浸させた洗浄材を第６の要旨とする。 A cleaning material impregnated with the hard surface antifouling cleaning composition is a sixth aspect.
上記の洗浄材を用いて、硬表面の汚れを拭き取る工程、該硬表面に残った洗浄剤組成物を、水を含ませたタオル又はダスターで拭き取る工程とを含む洗浄方法を第７の要旨とする。 A seventh gist is a cleaning method including a step of wiping off dirt on a hard surface using the cleaning material, and a step of wiping the cleaning composition remaining on the hard surface with a towel or duster soaked in water. To do.
上記の硬表面用防汚洗浄剤を水で２〜１０倍に希釈した洗浄液を、硬表面にスプレー、または塗布する工程と、水ですすぐ工程とを含む洗浄方法を第８の要旨とする。 An eighth aspect of the present invention is a cleaning method including a step of spraying or applying a cleaning liquid obtained by diluting the antifouling detergent for hard surfaces 2 to 10 times with water onto a hard surface and a step of rinsing with water.
ポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材からなる浴室、浴槽、腰掛け、手おけ、およびスノコなどの浴室用具に付着する風呂汚れに対して、防汚洗浄効果を発揮すると考えられる素材を鋭意検討した結果、種々のフッ素化合物や変性シリコーン化合物、およびアクリルポリマー系化合物等は、すべて所望の効果を得られなかったが、唯一、酸化エチレン／酸化プロピレン／酸化エチレン共重合体が満足のゆく結果を得、本発明に至った。 As a result of earnestly examining materials that are expected to exert antifouling cleaning effects against bathroom dirt that adheres to bathroom tools such as bathrooms, bathtubs, stools, handbags, and slats made of plastic materials such as polyethylene, polypropylene, and FRP Various fluorine compounds, modified silicone compounds, acrylic polymer compounds, etc. did not achieve the desired effect, but only ethylene oxide / propylene oxide / ethylene oxide copolymers obtained satisfactory results, The present invention has been reached.
すなわち、本発明の硬表面用防汚洗浄剤組成物は、特にポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材で構成される浴室や浴槽、さらには腰掛け、手おけ、およびスノコなどの浴室用具に用いる（以下これら用具をまとめて浴室用具ということがある。）ことにより、これら被洗浄物の表面に酸化エチレン／酸化プロピレン／酸化エチレン共重合体が吸着し親水性の単分子皮膜を形成させ、素材表面に防汚性を与え、せっけんかすや、皮脂、および水道水や井戸水の硬水成分であるカルシウムやマグネシウムなどの無機質分（スケール）等の汚れの付着を和らげ、これらの汚れが付着しても容易に洗浄、除去できることにより日常の作業員の洗浄負荷、労力を大幅に低減し作業効率の向上や、美観の向上、および衛生の維持に寄与することができる。 That is, the antifouling detergent composition for hard surfaces of the present invention is used in bathrooms and bathtubs composed of plastic materials such as polyethylene, polypropylene, and FRP, as well as bathroom tools such as stools, handbags, and slats ( Hereinafter, these tools may be collectively referred to as bathroom tools.) As a result, ethylene oxide / propylene oxide / ethylene oxide copolymer is adsorbed on the surface of the object to be cleaned to form a hydrophilic monomolecular film. Gives antifouling properties to soften soaps, sebum, and minerals (scales) such as calcium and magnesium, which are hard water components in tap water and well water. Can be cleaned and removed easily, greatly reducing the daily labor's cleaning load and labor, improving work efficiency, improving aesthetics, and hygiene. It can contribute to lifting.
以下、本発明を実施するための最良の形態について詳細に説明する。 Hereinafter, the best mode for carrying out the present invention will be described in detail.
まず、本発明の硬表面用防汚洗浄剤組成物（以下、「本組成物」ともいう。）は、（Ａ）酸化エチレン／酸化プロピレン／酸化エチレン共重合体、（Ｂ）界面活性剤、（Ｃ）キレート剤、（Ｄ）水溶性溶剤、及び（Ｅ）水を必須成分として含有する。 First, the antifouling detergent composition for hard surfaces of the present invention (hereinafter also referred to as “the present composition”) comprises (A) an ethylene oxide / propylene oxide / ethylene oxide copolymer, (B) a surfactant, (C) A chelating agent, (D) a water-soluble solvent, and (E) water are contained as essential components.
本発明に用いられる（Ａ）成分の酸化エチレン／酸化プロピレン／酸化エチレン共重合体は、特にポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材で構成される浴室や浴槽、さらには腰掛け、手おけ、およびスノコなどの浴室用具に用いることにより、これらの対象面に酸化エチレン／酸化プロピレン／酸化エチレン共重合体が吸着し親水性の単分子皮膜を形成させ、素材表面に防汚性を与え、せっけんかすや、皮脂、および水道水や井戸水の硬水成分であるカルシウムやマグネシウムなどの無機質分（スケール）等の汚れの付着を和らげ、これらの汚れが付着しても容易に洗浄、除去できることを目的として配合され、単独あるいは２種以上を併用して用いてもよい。 The ethylene oxide / propylene oxide / ethylene oxide copolymer of component (A) used in the present invention is a bathroom or bath tub made of a plastic material such as polyethylene, polypropylene, and FRP, as well as a stool, a handle, and a snowboard. When used in bathroom tools such as these, ethylene oxide / propylene oxide / ethylene oxide copolymer is adsorbed on these target surfaces to form a hydrophilic monomolecular film, giving antifouling properties to the surface of the material. It is formulated for the purpose of reducing the adhesion of dirt such as sebum, minerals such as calcium and magnesium, which are hard water components of tap water and well water, and easy cleaning and removal even if these dirt adheres. These may be used alone or in combination of two or more.
なお、酸化エチレン／酸化プロピレン／酸化エチレン共重合体製法としては、ブロック重合かランダム重合があるが、本発明の本組成物に用いられる（Ａ）成分の酸化エチレン／酸化プロピレン／酸化エチレン共重合体はブロック重合により合成され、詳しくは、高温高圧下の反応重合釜で、プロピレングリコールを出発原料とし、まず最初にプロピレンオキサイドガスを噴き込み反応させ、ポリプロピレングリコールを形成させ、エチレンオキサイドガスを噴き込んで反応させて生成する。製造された上記（Ａ）成分は、酸化プロピレンを中心とし、その両側に酸化エチレンが付加される The ethylene oxide / propylene oxide / ethylene oxide copolymer production method includes block polymerization or random polymerization, but the component (A) ethylene oxide / propylene oxide / ethylene oxide copolymer used in the present composition of the present invention. The coalescence is synthesized by block polymerization. Specifically, in a reaction polymerization kettle under high temperature and high pressure, propylene glycol is used as a starting material, propylene oxide gas is first injected and reacted to form polypropylene glycol, and ethylene oxide gas is injected. And reacts. The produced component (A) is mainly composed of propylene oxide, and ethylene oxide is added to both sides thereof.
上記（Ａ）成分の酸化エチレン／酸化プロピレン／酸化エチレン共重合体は、平均分子量が４，０００以上、２５，０００未満で、平均分子量中に占める酸化エチレンの割合が５０〜８５質量％であるものが好ましい。なかでも平均分子量が８，０００〜２３，０００で、酸化エチレンの付加率が６０〜８５質量％のものが好ましく、このうち、特に平均分子量が２０，０００で、酸化エチレンの付加率が８０質量％のものがより好ましい。 The ethylene oxide / propylene oxide / ethylene oxide copolymer of the component (A) has an average molecular weight of 4,000 or more and less than 25,000, and the proportion of ethylene oxide in the average molecular weight is 50 to 85% by mass. Those are preferred. Among them, those having an average molecular weight of 8,000 to 23,000 and an addition rate of ethylene oxide of 60 to 85% by mass are preferable, and among these, the average molecular weight is 20,000 and the addition rate of ethylene oxide is 80 masses. % Is more preferable.
酸化エチレン／酸化プロピレン／酸化エチレン共重合体の平均分子量が４，０００未満の場合は、プラスチック素材への吸着力が弱く親水性の単分子皮膜の形成が不充分であるために防汚性能に乏しく、平均分子量が２５，０００以上のものが市販のものでは見あたらないため、上記の平均分子量の上限を２５，０００未満と設定したが、平均分子量が２５，０００以上のものであっても本発明の要旨に沿い使用を妨げるものではない。
また、酸化エチレンの付加率が５０質量％未満のものでは、酸化エチレンの付加率が低く、酸化プロピレンの付加率が高くなるため、プラスチック素材への吸着力が弱く親水性の単分子膜の形成ができず防汚特性がない。また本洗浄剤組成物に泡立ちを与えることができず、可溶化力が低下するために、本洗浄剤組成物における所望の貯蔵安定性を得ることができない。
さらに、酸化エチレンの付加率が８５質量％を超えると親水性が高まりすぎるために、泡立ちの傾向が大きくなるため好ましくない。
When the average molecular weight of the ethylene oxide / propylene oxide / ethylene oxide copolymer is less than 4,000, the adsorption power to the plastic material is weak and the formation of a hydrophilic monomolecular film is insufficient. The upper limit of the above average molecular weight is set to less than 25,000 because the average molecular weight is 25,000 or less and is not found in commercially available products, but even if the average molecular weight is 25,000 or more It does not impede use according to the gist of the invention.
In addition, when the addition rate of ethylene oxide is less than 50% by mass, the addition rate of ethylene oxide is low and the addition rate of propylene oxide is high. Cannot be antifouling. In addition, foaming cannot be imparted to the present cleaning composition and solubilization power is reduced, so that desired storage stability in the present cleaning composition cannot be obtained.
Furthermore, when the addition rate of ethylene oxide exceeds 85% by mass, the hydrophilicity is excessively increased, and the tendency of foaming is increased, which is not preferable.
そして、上記に規定した酸化エチレン／酸化プロピレン／酸化エチレン共重合体は、本発明の本組成物全体に対し０．５〜６０質量％の範囲で配合される。
すなわち、０．５質量％未満の配合量では、特にポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材からなる浴室や浴槽、および浴室用具等の被洗浄物の表面への吸着量が不充分で単分子膜が形成されないため、素材表面の防汚性は発揮されず、風呂汚れの付着を和らげることができない。一方、６０質量％を超えると、汚れの付着緩和効果は飽和となり、却って表面にベタつきやムラ等が発生し、さらにはすすぎ性などが低下する。よって、酸化エチレン／酸化プロピレン／酸化エチレン共重合体は、本発明の本組成物全体に対し、上記範囲のなかでも１〜４０質量％の範囲で配合されることが好ましく、さらには、２〜２０質量％の範囲で配合されることがより好ましい。
And the ethylene oxide / propylene oxide / ethylene oxide copolymer prescribed | regulated above is mix | blended in 0.5-60 mass% with respect to the whole this composition of this invention.
That is, when the blending amount is less than 0.5% by mass, the amount of adsorption onto the surface of an object to be cleaned such as a bathroom or a bath made of a plastic material such as polyethylene, polypropylene, and FRP, and bathroom utensils is insufficient. Since no film is formed, the antifouling property of the material surface is not exhibited, and the adhesion of bath dirt cannot be relieved. On the other hand, if it exceeds 60% by mass, the effect of reducing the adhesion of dirt becomes saturated, and on the contrary, stickiness or unevenness occurs on the surface, and the rinsing properties and the like are further reduced. Therefore, the ethylene oxide / propylene oxide / ethylene oxide copolymer is preferably blended in the range of 1 to 40% by mass in the above range with respect to the entire composition of the present invention. More preferably, it is blended in the range of 20% by mass.
本発明に用いられる（Ｂ成分）の界面活性剤としては、非イオン界面活性剤、両性界面活性剤、陰イオン界面活性剤、および陽イオン界面活性剤を挙げることができる。上記（Ｂ）成分のうちの非イオン界面活性剤としては、ポリオキシアルキレンアルキルエーテル、ポリオキシアルキレンアルケニルエーテル、ポリオキシアルキレンアルキルフェニルエーテル、アルキルポリグルコシド、脂肪酸ポリグリセリンエステル、脂肪酸ショ糖エステル、脂肪酸アルカノールアミド等があげられる。
本発明においては、これらの非イオン界面活性剤のうち、ポリオキシアルキレンアルキルエーテル、アルキルポリグルコシド、脂肪酸アルカノールアミド等が好ましい。
Examples of the (B component) surfactant used in the present invention include nonionic surfactants, amphoteric surfactants, anionic surfactants, and cationic surfactants. Among the nonionic surfactants among the above component (B), polyoxyalkylene alkyl ether, polyoxyalkylene alkenyl ether, polyoxyalkylene alkyl phenyl ether, alkyl polyglucoside, fatty acid polyglycerin ester, fatty acid sucrose ester, fatty acid And alkanolamides.
In the present invention, among these nonionic surfactants, polyoxyalkylene alkyl ether, alkyl polyglucoside, fatty acid alkanolamide and the like are preferable.
両性界面活性剤としては、アルキルカルボキシベタイン、アルキルスルホベタイン、アルキルヒドロキシスルホベタイン、アルキルアミドベタイン、イミダゾリニウムベタイン、アルキルジアミノエチルグリシン、ジアルキルジアミノエチルグリシン、アルキルアミンオキサイド、アルキルエーテルアミンオキサイド、アミドアミンオキサイド等があげられる。
本発明においては、これらの両性界面活性剤のうち、アルキルアミドベタインやアルキルアミンオキサイドが好ましい。
Amphoteric surfactants include alkylcarboxybetaines, alkylsulfobetaines, alkylhydroxysulfobetaines, alkylamidobetaines, imidazolinium betaines, alkyldiaminoethylglycines, dialkyldiaminoethylglycines, alkylamine oxides, alkyl ether amine oxides, amidoamine oxides Etc.
In the present invention, among these amphoteric surfactants, alkylamide betaines and alkylamine oxides are preferable.
陰イオン界面活性剤としては、アルキル硫酸塩、アルキル硫酸エステル塩、アルキルベンゼン硫酸塩、アルファオレフィンスルホン酸塩、メタキシレンスルホン酸塩、パラキシレンスルホン酸塩、クメンスルフォン酸塩等があげられる。
これらの陰イオン界面活性剤の対イオンは、ナトリウム、マグネシウム、アンモニウム、エタノールアミン等である。本発明においては、これらの陰イオン界面活性剤のうち、ラウリル硫酸ナトリウム、ラウリル硫酸アンモニウム、ラウリル硫酸エステルナトリウム、ラウリル硫酸エステルアンモニウム等が好ましい。
Examples of the anionic surfactant include alkyl sulfates, alkyl sulfate esters, alkylbenzene sulfates, alpha olefin sulfonates, metaxylene sulfonates, paraxylene sulfonates, cumene sulfonates, and the like.
The counter ions of these anionic surfactants are sodium, magnesium, ammonium, ethanolamine and the like. In the present invention, among these anionic surfactants, sodium lauryl sulfate, ammonium lauryl sulfate, sodium lauryl sulfate ester, ammonium lauryl sulfate ester and the like are preferable.
陽イオン界面活性剤としては、アルキルトリメチルアンモニウム塩、ジアルキルジメチルアンモニウム塩、アルキルジメチルアンモニウムアジペート、ベンザルコニウム塩、ベンゼントニウム塩、ピリジニウム塩、イミダゾリニウム塩、ビグアニド化合物等があげられる。これらの陽イオン界面活性剤の対イオンは、ハロゲン等である。
本発明においては、これらの陽イオン界面活性剤のうち、塩化ベンザルコニウムやジアルキルジメチルアンモニウムクロライドが好ましい。
Examples of the cationic surfactant include alkyltrimethylammonium salt, dialkyldimethylammonium salt, alkyldimethylammonium adipate, benzalkonium salt, benzenetonium salt, pyridinium salt, imidazolinium salt, biguanide compound and the like. The counter ion of these cationic surfactants is halogen or the like.
In the present invention, among these cationic surfactants, benzalkonium chloride and dialkyldimethylammonium chloride are preferable.
上記（Ｂ）成分の界面活性剤を配合することにより、洗浄力と被洗浄面へのレベリング性、適度な起泡性の付与、良好なすすぎ性、および殺菌性などの性能を得ることができ、各性能の必要に応じて適宜、該界面活性剤から選択して用いることができる。これらの界面活性剤は、各々単独で用いても２種以上を併用してもよい。なお、「レベリング性」とは、「濡れ性」のことであり、組成物を被洗浄面に塗布、またはスプレーした際、液がはじいたりせず均一に濡れ広がることをいう。 By blending the surfactant as the component (B), it is possible to obtain performances such as detergency and leveling to the surface to be cleaned, imparting appropriate foaming properties, good rinsing properties, and bactericidal properties. These surfactants can be appropriately selected and used as required for each performance. These surfactants may be used alone or in combination of two or more. The “leveling property” means “wetting property”, and means that when the composition is applied or sprayed on the surface to be cleaned, the liquid does not repel and spreads uniformly.
この（Ｂ）成分の界面活性剤は、本発明の本組成物全体に対し０．１〜１５質量％の範囲で配合される。界面活性剤の配合量が０．１質量％未満では、洗浄力や被洗浄面へのレベリング性、起泡性、および殺菌性などに乏しく、また１５質量％を超えて配合しても、洗浄力等の上記の性能は飽和状態となり、また経済的にも不利となる。
上記界面活性剤の配合量は、性能の点から１〜１５質量％の範囲が好ましく、さらに経済性の点から１〜１０質量％の範囲がより好ましい。
This (B) component surfactant is mix | blended in the range of 0.1-15 mass% with respect to this whole composition of this invention. When the amount of the surfactant is less than 0.1% by mass, the cleaning power and leveling property to the surface to be cleaned, foaming property, and bactericidal property are poor, and even if the amount exceeds 15% by mass, cleaning is performed. The above-mentioned performance such as force becomes saturated and disadvantageous economically.
The blending amount of the surfactant is preferably in the range of 1 to 15% by mass from the viewpoint of performance, and more preferably in the range of 1 to 10% by mass from the viewpoint of economy.
また、本発明に用いられる（Ｃ）成分のキレート剤としては、アクリル酸、マレイン酸、メタクリル酸、アコニット酸等の少なくとも一種からなるカルボキシル基含有単量体の重合体、および共重合体、並びにその水溶性アルカリ金属塩や、クエン酸、リンゴ酸、酒石酸、コハク酸、グルコン酸、フタル酸等の有機酸、およびこれらのアルカリ金属塩が挙げられる。上記水溶性アルカリ金属塩としては、ナトリウム塩、カリウム塩、アンモニウム塩、エタノールアミン塩等が上げられるが、なかでもナトリウム塩、アンモニウム塩が好ましい。 In addition, as the chelating agent of the component (C) used in the present invention, a polymer of a carboxyl group-containing monomer composed of at least one of acrylic acid, maleic acid, methacrylic acid, aconitic acid, and a copolymer, and Examples thereof include water-soluble alkali metal salts, organic acids such as citric acid, malic acid, tartaric acid, succinic acid, gluconic acid, and phthalic acid, and alkali metal salts thereof. Examples of the water-soluble alkali metal salt include sodium salts, potassium salts, ammonium salts, ethanolamine salts, and the like, among which sodium salts and ammonium salts are preferable.
より詳しくは、アクリル酸、マレイン酸、メタクリル酸、アコニット酸等の少なくとも一種からなるカルボキシル基含有単量体の重合体、および共重合体、並びにその水溶性アルカリ金属塩としては、ポリアクリル酸ナトリウム、ポリマレイン酸ナトリウム、ポリメタクリル酸ナトリウム、ポリアコニット酸ナトリウム、アクリル酸−ビニル化合物共重合体、スチレン−マレイン酸共重合体、イソアミレン−無水マレイン酸共重合体、メチルビニルエーテル−マレイン酸共重合体、アクリル酸−マレイン酸共重合体、アクリル酸−ビニル化合物共重合体のナトリウム塩、スチレン−マレイン酸共重合体のナトリウム塩、イソアミレン−無水マレイン酸共重合体のナトリウム塩、メチルビニルエーテル−マレイン酸共重合体のナトリウム塩、アクリル酸−マレイン酸共重合体のナトリウム塩等が上げられる。
また、クエン酸、リンゴ酸、酒石酸、コハク酸、グルコン酸、フタル酸等の有機酸、およびこれらのアルカリ金属塩としては、クエン酸ナトリウム、リンゴ酸ナトリウム、酒石酸ナトリウム、コハク酸ナトリウム、グルコン酸ナトリウム、フタル酸ナトリウム、クエン酸カリウム、グルコン酸カリウム、クエン酸アンモニウム等が挙げられる。
これらのキレート剤は、各々単独で用いても２種以上を併用してもよい。
More specifically, a polymer and copolymer of a carboxyl group-containing monomer composed of at least one of acrylic acid, maleic acid, methacrylic acid, aconitic acid and the like, and water-soluble alkali metal salts thereof include sodium polyacrylate Sodium polymaleate, sodium polymethacrylate, sodium polyaconitate, acrylic acid-vinyl compound copolymer, styrene-maleic acid copolymer, isoamylene-maleic anhydride copolymer, methyl vinyl ether-maleic acid copolymer, Acrylic acid-maleic acid copolymer, sodium salt of acrylic acid-vinyl compound copolymer, sodium salt of styrene-maleic acid copolymer, sodium salt of isoamylene-maleic anhydride copolymer, methyl vinyl ether-maleic acid copolymer Polymer sodium salt, a Acrylic acid - sodium salt of maleic acid copolymers and the like.
In addition, organic acids such as citric acid, malic acid, tartaric acid, succinic acid, gluconic acid, phthalic acid, and alkali metal salts thereof include sodium citrate, sodium malate, sodium tartrate, sodium succinate, sodium gluconate. Sodium phthalate, potassium citrate, potassium gluconate, ammonium citrate and the like.
These chelating agents may be used alone or in combination of two or more.
上記（Ｃ）成分のキレート剤の中でも、マレイン酸、アクリル酸のうち少なくとも一方を単量体とする重合体または共重合体、並びにその水溶性アルカリ塩が好ましく、その例として、マレイン酸重合体、アクリル酸重合体、マレイン酸とアクリル酸との重合体、およびこれらの水溶性アルカリ金属塩が挙げられる。そして、特に好ましくは、ポリマレイン酸ナトリウム、ポリアクリル酸ナトリウム、アクリル酸とマレイン酸との共重合体のナトリウム塩が用いられる。さらにはクエン酸やリンゴ酸、並びにその水溶性アルカリ塩が好ましく用いられる。 Among the chelating agents of the component (C), a polymer or copolymer having at least one of maleic acid and acrylic acid as a monomer, and a water-soluble alkali salt thereof are preferable, and examples thereof include a maleic acid polymer. , Acrylic acid polymers, polymers of maleic acid and acrylic acid, and water-soluble alkali metal salts thereof. Particularly preferably, sodium polymaleate, sodium polyacrylate, or a sodium salt of a copolymer of acrylic acid and maleic acid is used. Furthermore, citric acid, malic acid, and water-soluble alkali salts thereof are preferably used.
そして、マレイン酸重合体、アクリル酸重合体、およびその水溶性アルカリ金属塩の平均分子量は、６００〜１５，０００のものが好適に用いられ、特に好ましくは１，０００〜１５，０００のものが用いられる。また、マレイン酸とアクリル酸の共重合体、および水溶性金属塩の平均分子量としては、１，０００〜１００，０００のものが好適に用いられ、特に好ましくは５０，０００〜８０，０００のものが用いられる。上記キレート剤は、ｐＨ調整され中和して用いることができるが、それ自体が酸性であるため、他の成分を中和するためのｐＨ調整機能を果たす場合もある。 The average molecular weight of the maleic acid polymer, the acrylic acid polymer, and the water-soluble alkali metal salt thereof is preferably 600 to 15,000, particularly preferably 1,000 to 15,000. Used. The average molecular weight of the copolymer of maleic acid and acrylic acid and the water-soluble metal salt is preferably 1,000 to 100,000, particularly preferably 50,000 to 80,000. Is used. The chelating agent can be used after pH adjustment and neutralization. However, since the chelating agent itself is acidic, it may sometimes perform a pH adjustment function for neutralizing other components.
上記（Ｃ）成分のキレート剤を配合することにより、硬水を軟化させる（硬水軟化性とも記す）とともに、浴室、浴槽に付着したせっけんかす汚れに対する洗浄性を向上させることができる。 By blending the chelating agent of the above component (C), hard water is softened (also referred to as hard water softening property), and at the same time, it is possible to improve the detergency against soapy dirt adhering to the bathroom and bathtub.
上記（Ｃ）成分のキレート剤は、本発明の本組成物全体に対し０．１〜１５質量％の範囲で配合される。この量が０．１質量％未満では、硬水軟化性や洗浄性に乏しく、また１５質量％を超えて配合しても、硬水軟化性等の向上は飽和状態となり、経済的にも不利となる。上記キレート剤の配合量は、性能の点から０．５〜１５質量％の範囲が好ましく、さらに経済性の点から０．５〜１０質量％の範囲がより好ましい。 The chelating agent of said (C) component is mix | blended in 0.1-15 mass% with respect to the whole this composition of this invention. If this amount is less than 0.1% by mass, the water softening property and detergency are poor, and even if it exceeds 15% by mass, the improvement of the water softening property becomes saturated, which is economically disadvantageous. . The amount of the chelating agent is preferably in the range of 0.5 to 15% by mass from the viewpoint of performance, and more preferably in the range of 0.5 to 10% by mass from the viewpoint of economy.
また、本発明に用いられる（Ｄ）成分の水溶性溶剤としては、（１）エタノール、プロパノール、イソプロパノール、ブタノール等の１価のアルコール、エチレングリコール、ジエチレングリコール、イソプレングリコール、プロピレングリコール等のアルキレングリコール、グリセリン、ポリグリセリン、１，３−ブタンジオール等の多価アルコール等のアルコール類、（２）エチレングリコールモノメチルエーテル、エチレングリコールジメチルエーテル、エチレングリコールモノエチルエーテル、エチレングリコールモノブチルエーテル、プロピレングリコールモノメチルエーテル、プロピレングリコールモノエチルエーテル、プロピレングリコールモノブチルエーテル、プロピレングリコールモノフェニルエーテル、ジエチレングリコールモノメチルエーテル、ジエチレングリコールモノエチルエーテル、ジエチレングリコールモノブチルエーテル、ジプロピレングリコールモノメチルエーテル、ジプロピレングリコールモノエチルエーテル、ジプロピレングリコールモノブチルエーテル、トリエチレングリコールモノブチルエーテル、トリプロピレングリコールジメチルエーテル等のアルキレングリコール（モノ、ジ）アルキルエーテル等のグリコールエーテル類、（３）また、２−ピロリドン、３−ピロリドン、Ｎ−メチル−２−ピロリドン、Ｎ−エチル−２−ピロリドン、Ｎ−プロピル−２−ピロリドン等のＮ−アルキル−２−ピロリドン、５−メチル−２−ピロリドン、５−エチル−２−ピロリドン、５−プロピル−２−ピロリドン等の５−アルキル−２−ピロリドン、Ｎ−ビニル−２−ピロリドン、Ｎ−メチル−３−ピロリドン、Ｎ−エチル−３−ピロリドン、Ｎ−プロピル−３−ピロリドン等のＮ−アルキル−３−ピロリドン等のピロリドン化合物があげられる。 Examples of the water-soluble solvent of component (D) used in the present invention include (1) monohydric alcohols such as ethanol, propanol, isopropanol and butanol, alkylene glycols such as ethylene glycol, diethylene glycol, isoprene glycol and propylene glycol, Alcohols such as glycerin, polyglycerin, polyhydric alcohols such as 1,3-butanediol, (2) ethylene glycol monomethyl ether, ethylene glycol dimethyl ether, ethylene glycol monoethyl ether, ethylene glycol monobutyl ether, propylene glycol monomethyl ether, propylene Glycol monoethyl ether, propylene glycol monobutyl ether, propylene glycol monophenyl ether, diethylene glycol Alkylene glycol (mono, dipropylene glycol monobutyl ether, diethylene glycol monobutyl ether, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, dipropylene glycol monobutyl ether, triethylene glycol monobutyl ether, tripropylene glycol dimethyl ether, etc.) Di) glycol ethers such as alkyl ethers; (3) and N-pyrrolidone, 3-pyrrolidone, N-methyl-2-pyrrolidone, N-ethyl-2-pyrrolidone, N-propyl-2-pyrrolidone, and the like. 5-alkyl-2-pyrrolidone such as alkyl-2-pyrrolidone, 5-methyl-2-pyrrolidone, 5-ethyl-2-pyrrolidone, 5-propyl-2-pyrrolidone Emissions, N- vinyl-2-pyrrolidone, N- methyl-3-pyrrolidone, N- ethyl-3-pyrrolidone, N- propyl-3-N-alkyl-3-pyrrolidone compound of pyrrolidone such as pyrrolidone.
本発明においては、これら（Ｄ）成分の水溶性溶剤のうち、エタノール、プロピレングリコールモノメチルエーテル、ジプロピレングリコールモノメチルエーテル、Ｎ−メチル−２−ピロリドンなどが好ましい。 In the present invention, among these water-soluble solvents of component (D), ethanol, propylene glycol monomethyl ether, dipropylene glycol monomethyl ether, N-methyl-2-pyrrolidone and the like are preferable.
上記（Ｄ）成分の水溶性溶剤を配合することにより、特に皮脂汚れなどに対する洗浄性を維持することができ、必要に応じて適宜、選択して用いることができる。これらの水溶性溶剤は、各々単独で用いても２種以上を併用してもよい。 By blending the water-soluble solvent of the above component (D), it is possible to maintain particularly cleanability against sebum stains and the like, and it can be appropriately selected and used as necessary. These water-soluble solvents may be used alone or in combination of two or more.
この（Ｄ）成分の水溶性溶剤の配合量は、本発明の本組成物全体に対し０．１〜１５質量％の範囲で配合される。この量が０．１質量％未満では、皮脂汚れに対する洗浄性や、本組成物の貯蔵安定性の維持などに乏しく、また１５質量％を超えて配合しても、効果は飽和状態となり、経済的に不利となる。上記水溶性溶剤の配合量は、性能の点から１〜１５質量％の範囲が好ましく、さらに経済性の点から１〜１０質量％の範囲がより好ましい。 The blending amount of the water-soluble solvent as the component (D) is blended in the range of 0.1 to 15% by mass with respect to the entire composition of the present invention. If this amount is less than 0.1% by mass, the cleaning properties against sebum stains and the storage stability of the present composition are poor, and even if it exceeds 15% by mass, the effect becomes saturated and the economy Disadvantageous. The blending amount of the water-soluble solvent is preferably in the range of 1 to 15% by mass from the viewpoint of performance, and more preferably in the range of 1 to 10% by mass from the viewpoint of economy.
また本発明に用いられる（Ｅ）成分の水としては、純水、イオン交換水、軟水、蒸留水、水道水等があげられる。これらは、各々単独で用いても２種以上を併用してもよい。なかでも、本組成物の貯蔵安定性の点から、イオン交換水が好ましく用いられる。なお、上記「水」は、本発明の本組成物を構成する各成分に由来する結晶水や水溶液の形で含まれる水と、外から加えられる水との総和であり、本組成物全体が１００％のバランスとなるよう配合される。 Examples of the water of component (E) used in the present invention include pure water, ion exchange water, soft water, distilled water, and tap water. These may be used alone or in combination of two or more. Of these, ion-exchanged water is preferably used from the viewpoint of the storage stability of the composition. The “water” is the sum of water contained in the form of crystal water or aqueous solution derived from each component constituting the composition of the present invention and water added from the outside, and the entire composition is Formulated to achieve 100% balance.
本発明の本組成物は、作業上や環境への安全性、および被洗浄物の材質等に悪影響を及ぼさないよう、原液のｐＨは中性の範囲に調整される。ｐＨ調整に用いられるアルカリ性を呈する物質としては、水酸化ナトリウム、水酸化カリウム等の水酸化アルカリ、炭酸ナトリウム、炭酸カリウム等の炭酸塩、ケイ酸ナトリウム、ケイ酸カリウム等のケイ酸塩、モノエタノールアミン、ジエタノールアミン等のアミン、アンモニア等が用いられ、また、ｐＨ調整に用いられる酸性を呈する物質としては、塩酸、硫酸等の無機酸、クエン酸、酢酸等の有機酸等が用いられるが、なかでも特にアンモニアが好ましく、上記ｐＨの範囲となるよう適量添加される。 In the composition of the present invention, the pH of the undiluted solution is adjusted to a neutral range so as not to adversely affect the safety to work and the environment and the material of the object to be cleaned. Examples of alkaline substances used for pH adjustment include alkali hydroxides such as sodium hydroxide and potassium hydroxide, carbonates such as sodium carbonate and potassium carbonate, silicates such as sodium silicate and potassium silicate, monoethanol Amines such as amine and diethanolamine, ammonia and the like are used, and as an acidic substance used for pH adjustment, inorganic acids such as hydrochloric acid and sulfuric acid, and organic acids such as citric acid and acetic acid are used. However, ammonia is particularly preferable, and an appropriate amount is added so as to be in the above pH range.
そして、本組成物の原液のｐＨ（ＪＩＳ Ｚ−８８０２：１９８４「ｐＨ測定法」による）は、２５℃で、６〜８に設定されていることを特徴とする。 The pH of the stock solution of the present composition (according to JIS Z-8802: 1984 “pH measurement method”) is set to 6 to 8 at 25 ° C.
なお、上記ｐＨ調整剤を用いてｐＨ調整を行う際には、（Ｃ）成分であるキレート剤の配合割合が、０．１〜１５質量％の範囲から外れないように配慮する必要がある。 In addition, when adjusting pH using the said pH adjuster, it is necessary to consider so that the mixture ratio of the chelating agent which is (C) component does not remove | deviate from the range of 0.1-15 mass%.
さらに本組成物には、本発明の目的を阻害しない範囲で、任意に香料、増粘剤、殺菌剤、防腐剤等を配合することができる。 Furthermore, a fragrance | flavor, a thickener, a disinfectant, a preservative, etc. can be arbitrarily mix | blended with this composition in the range which does not inhibit the objective of this invention.
また、洗浄材としては、麻、綿、セルロース、羊毛および絹等の天然動植物繊維、または、レーヨン、ポリオレフィン、ポリエステル、アクリル、ナイロンおよびポリウレタン等の合成繊維・発泡材等からなる織布、不織布、またはこれらのサンドイッチ状ないしは積層状シートやマット材、さらにはパルプ紙、合成紙またはその積層紙、あるいはスポンジ等が用いられる。 As cleaning materials, natural animal and vegetable fibers such as hemp, cotton, cellulose, wool and silk, or woven fabrics and nonwoven fabrics made of synthetic fibers and foams such as rayon, polyolefin, polyester, acrylic, nylon and polyurethane, etc. Alternatively, a sandwich or laminated sheet or mat material, pulp paper, synthetic paper or laminated paper thereof, or sponge is used.
これらの必須成分、および任意成分を用いて得られる本発明の硬表面用防汚洗浄剤組成物は、被洗浄物の材質を傷めることなく、特にポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材で構成される浴室や浴槽、さらには腰掛け、手おけ、およびスノコなどの浴室用具に用いることにより、これら被洗浄物の表面に酸化エチレン／酸化プロピレン／酸化エチレン共重合体が吸着し親水性の単分子皮膜を形成させ、素材表面に防汚性を与え、せっけんかすや、皮脂、および水道水や井戸水の硬水成分であるカルシウムやマグネシウムなどの無機質分（スケール）等の汚れの付着を和らげ、これらの汚れが付着しても容易に洗浄、除去できる。さらに、適度な洗浄力と、組成物の貯蔵安定性にも優れている。
また、皮膚に付着するようなことがあっても、その刺激性は従来の酸性洗浄剤、およびアルカリ性洗浄剤と比べ低いので、作業者はより安全に浴槽の洗浄が行えるという利点を有する。さらに、排出された洗浄液排水のｐＨは中性であるため環境負荷もより低い。
The antifouling detergent composition for hard surfaces of the present invention obtained by using these essential components and optional components is composed of a plastic material such as polyethylene, polypropylene, and FRP without damaging the material of the object to be cleaned. Used in bathrooms such as bathrooms and bathtubs, as well as bathrooms such as stools, handbags, and slats, so that the surface of these objects to be cleaned adsorbs ethylene oxide / propylene oxide / ethylene oxide copolymer and has a hydrophilic monomolecular film. It forms anti-fouling properties on the surface of the material, soothes dirt, such as soaps, sebum, and minerals (scales) such as calcium and magnesium, which are hard water components of tap water and well water. Even if it adheres, it can be easily washed and removed. Furthermore, it is excellent in moderate detergency and the storage stability of the composition.
Moreover, even if it adheres to skin, since the irritation is low compared with the conventional acidic cleaning agent and alkaline cleaning agent, it has the advantage that the operator can wash the bathtub more safely. Furthermore, since the pH of the discharged cleaning liquid wastewater is neutral, the environmental load is lower.
なお、本発明の本組成物は、硬表面の汚れの度合いに応じて、原液ないしは、水またはぬるま湯で２〜１０倍に希釈した洗浄液として用いられる。 The present composition of the present invention is used as a stock solution or a cleaning solution diluted 2 to 10 times with water or lukewarm water according to the degree of soiling on the hard surface.
また、本発明の本組成物の原液または希釈液を用いた硬表面の洗浄方法としては、例えば、
（１）本発明の本組成物の原液または希釈液を含浸させたスポンジ等で硬表面をこすり洗いした後、水ですすぐ方法、
（２） 被洗浄面に本発明の本組成物の原液または希釈液をスプレー、または塗布後、水ですすぐ方法、
（３） 不織布等に本発明の本組成物の原液または希釈液を含浸させ、硬表面の立面に貼り付けて、しばらく放置した後、水ですすぐ方法、
（４） 本発明の本組成物の原液または希釈液を含浸させた洗浄材で硬表面の汚れを拭き取った後、水を含ませたタオルで拭き取る方法、等があげられる。
なお、上記（２）においては、本組成物の原液または希釈液をスプレーまたは塗布後に直ちに水ですすいでもよいが、汚れの質や量に応じて、より洗浄性能を高めるために３０秒〜数分間、好ましくは１分程度放置した後に水ですすぐことが好ましく、これにより、高い防汚効果を得ることができる。
In addition, as a method for cleaning a hard surface using a stock solution or a diluted solution of the composition of the present invention, for example,
(1) A method of scrubbing a hard surface with a sponge or the like impregnated with a stock solution or a diluent of the present composition of the present invention, and then rinsing with water.
(2) A method of spraying or applying an undiluted or diluted solution of the composition of the present invention to the surface to be cleaned and rinsing with water
(3) A method in which a non-woven fabric or the like is impregnated with a stock solution or a diluted solution of the present composition of the present invention, attached to a vertical surface of a hard surface, left for a while, and then rinsed with water.
(4) A method of wiping off the dirt on the hard surface with a cleaning material impregnated with the undiluted or diluted solution of the present composition of the present invention and then wiping with a towel soaked with water, and the like.
In the above (2), the stock solution or diluted solution of this composition may be rinsed with water immediately after spraying or application, but depending on the quality and amount of dirt, it may take 30 seconds to several It is preferable to leave it for 1 minute, preferably about 1 minute, and then rinse with water, whereby a high antifouling effect can be obtained.
以下、本発明の硬表面用防汚洗浄剤組成物について、実施例と比較例により本発明を詳細に説明する。なお、本発明はこれらに限定されるものではない。 Hereinafter, the present invention will be described in detail with reference to examples and comparative examples of the antifouling detergent composition for hard surfaces of the present invention. The present invention is not limited to these.
後記の表１〜表８に示す実施例１〜１８及び比較例１〜２０の組成の硬表面用防汚洗浄剤組成物を調製し、貯蔵安定性、防汚性、洗浄性の３項目について評価した。その結果を後記の表１〜表８に併せて示す。なお、表中の組成は、アンモニア水を用いてキレート剤の成分の中和、および組成全体のｐＨ調整機能を果たし、ｐＨ値を６〜８に設定している。
成分（Ａ）〜（Ｅ）の総和は、全体で１００質量％となっている。
また、各項目の試験方法は、以下に示すとおりである。
Prepare antifouling detergent compositions for hard surfaces having the compositions of Examples 1 to 18 and Comparative Examples 1 to 20 shown in Tables 1 to 8 below, and about three items of storage stability, antifouling properties and detergency evaluated. The results are also shown in Tables 1 to 8 below. In addition, the composition in a table | surface performs neutralization of the component of a chelating agent using ammonia water, and the pH adjustment function of the whole composition, and sets pH value to 6-8.
The sum total of components (A) to (E) is 100% by mass as a whole.
The test method for each item is as follows.
（１）貯蔵安定性
〔試験方法〕
供試本組成物２００ｍＬを２５０ｍＬの透明ポリエチレン瓶に入れ、恒温槽（小林理化器械工業社製、形式：ＫＡＸ−７３４）により５０℃の雰囲気下に置くとともに、冷凍冷蔵庫（ホシザキ社製、形式：ＨＲＦ−９０Ｐ）により５℃の雰囲気下に置き、その状態で調製してから１ケ月間保管した。そして、その外観を目視により定期的に観察し、それぞれ下記の判定基準で貯蔵安定性を評価した。
〔判定基準〕
◎：１ケ月後、分離や沈殿、白濁等の外観変化は一切みられない。
○：２週間後、分離や沈殿、白濁等の外観変化がわずかにみられた。
△：１週間後、分離や沈殿、白濁等の外観変化がわずかにみられた。
×：１日以内に、分離や沈殿、白濁等の外観変化がみられた。
(1) Storage stability [Test method]
200 mL of the test sample composition was placed in a 250 mL transparent polyethylene bottle and placed in a constant temperature bath (manufactured by Kobayashi Rika Kikai Kogyo Co., Ltd., model: KAX-734) in an atmosphere of 50 ° C., and a freezer refrigerator (manufactured by Hoshizaki Co., Ltd., model: HRF-90P) was placed in an atmosphere at 5 ° C. and prepared in that state and stored for 1 month. And the external appearance was regularly observed visually and the storage stability was evaluated according to the following judgment criteria, respectively.
[Criteria]
◎ After 1 month, no change in appearance such as separation, precipitation or cloudiness is observed.
○: After 2 weeks, slight changes in appearance such as separation, precipitation, and cloudiness were observed.
Δ: After one week, slight changes in appearance such as separation, precipitation, and cloudiness were observed.
X: Appearance changes such as separation, precipitation and cloudiness were observed within 1 day.
（２）防汚性
〔試験方法〕
ユニットバスに多用されているプラスチック素材の試験片（ＦＲＰ片１５×７ｃｍ）を床用剥離洗浄剤（ジョンソン・プロフェッショナル社製、ゲットオフ５倍希釈液）を含ませたスポンジでよく洗浄、すすぎ、乾燥後、１ｍＬの供試本組成物を試験片に滴下して、ペーパークロスで均一に塗り広げて、室温下に１分間放置した後、温水（４０℃）で２〜３秒間すすいで、ペーパークロスでよく拭き上げた。
その後、該試験片をほぼ垂直に立て掛け、下記の２種類の人工汚垢を０．５〜１．０ｍＬの割合で試験片に吹き付け、そのまま一晩、室温下に放置した。
１）人工せっけんかす汚垢：
固形石鹸（０．４％）、セバム（０．０４％、ステアリン酸と油脂の混合物）、硬度１５０ｐｐｍの水（３３．５５％）、イオン交換水（６６．０１％）の混合液。
２）人工硬水汚垢（ＣａＣＯ３として、１５０ｍｇ／Ｌ）：
塩化カルシウム２水塩（１６３．５ｍｇ）、硫酸マグネシウム７水塩（９５．１ｍｇ）、炭酸水素ナトリウム（１８３．０ｍｇ）を蒸留水に溶解して１Ｌとした。
放置後、試験片に付着する上記の人工汚垢の多少を目視により確認し、下記の判定基準で防汚性を評価した。
〔判定基準〕
◎：人工汚垢は、試験片にほとんど付着していなかった。（付着率２５％未満）
○：人工汚垢は、試験片にある程度付着していた。（付着率２５％以上５０％未満）
△：人工汚垢は、試験片に多めに付着していた。（付着率５０％以上７５％未満）
×：人工汚垢は、試験片に非常に多く付着していた。（付着率７５％以上〜１００％）
（供試本組成物未処理の試験片の人工汚垢の付着率を１００％とした）
(2) Antifouling [Test method]
A plastic test specimen (FRP piece 15 x 7 cm) often used in the unit bath is thoroughly cleaned and rinsed with a sponge containing a floor peeling cleaner (manufactured by Johnson Professional Co., Ltd., get-off 5-fold diluted solution). After drying, 1 mL of the test composition is dropped onto a test piece, spread evenly with a paper cloth, left at room temperature for 1 minute, rinsed with warm water (40 ° C.) for 2 to 3 seconds, paper Wipe well with a cloth.
Thereafter, the test piece was leaned almost vertically, and the following two types of artificial dirt were sprayed on the test piece at a rate of 0.5 to 1.0 mL, and left as it was overnight at room temperature.
1) Artificial soap stains:
A mixture of solid soap (0.4%), sebum (0.04%, a mixture of stearic acid and oil), water with a hardness of 150 ppm (33.55%), and ion-exchanged water (66.01%).
2) artificial hard water Kitanaaka (as CaCO 3, 150mg / L):
Calcium chloride dihydrate (163.5 mg), magnesium sulfate heptahydrate (95.1 mg), and sodium bicarbonate (183.0 mg) were dissolved in distilled water to make 1 L.
After standing, the amount of the artificial dirt adhering to the test piece was visually confirmed, and the antifouling property was evaluated according to the following criteria.
[Criteria]
A: Artificial dirt hardly adhered to the test piece. (Adhesion rate less than 25%)
○: Artificial dirt adhered to the test piece to some extent. (Adhesion rate 25% or more and less than 50%)
Δ: Artificial dirt adhered to the test piece in a large amount. (Adhesion rate 50% or more and less than 75%)
X: Artificial dirt adhered to the test piece very much. (Adhesion rate 75% to 100%)
(Adhesion rate of artificial dirt of the test specimen untreated specimen is 100%)
（３）洗浄性
〔試験方法〕
上記（２）の防汚性試験方法に基き、得られた試験片を水平に静置し、試験片上に、ペーパークロスを貼り付けた分銅（荷重：３００ｇ）を置き、人工汚垢が完全に除去されるまで、分銅を動かし往復運動を繰り返し、こすり洗いを行った。（判定基準における「洗浄」とは人工汚垢が完全に除去された状態を示すものとする。）
分銅の往復運動回数（こすり洗い回数）を測定して、下記の判定基準で洗浄性を評価した。
〔判定基準〕
◎：試験片の人工汚垢は、５回以内の往復運動で洗浄できた。
○：試験片の人工汚垢は、６〜１０回の往復運動で洗浄できた。
△：試験片の人工汚垢の洗浄に、１１〜２０回の往復運動を要した。
×：試験片の人工汚垢は、２１回以上の往復運動をしても洗浄できなかった。
（供試本組成物未処理の試験片に付着する人工汚垢は、２５回以上、往復運動回数を繰り返しても洗浄できなかった）
(3) Detergency [Test method]
Based on the antifouling test method of (2) above, place the obtained test piece horizontally and place a weight (load: 300 g) with a paper cloth on the test piece. Until the weight was removed, the weight was moved and the reciprocating motion was repeated to rub. ("Washing" in the criteria indicates that the artificial dirt has been completely removed.)
The number of reciprocating motions of the weight (the number of scrubbing) was measured, and the cleaning property was evaluated according to the following criteria.
[Criteria]
(Double-circle): The artificial dirt of the test piece was washable by the reciprocating motion within 5 times.
(Circle): The artificial dirt of the test piece was washable by 6-10 reciprocating motions.
(Triangle | delta): The reciprocation of 11-20 times was required for washing | cleaning of the artificial dirt of a test piece.
X: The artificial dirt on the test piece could not be washed even after 21 reciprocations.
(The artificial dirt adhering to the test piece untreated with the test sample composition could not be cleaned even if the number of reciprocating motions was repeated 25 times or more.)
なお、後記の表１〜表８に示した実施例及び比較例の各種成分の詳細とその有効成分量（質量％、以下、「％」と略す。）は、下記の通りであり、表中の数値は、有り姿で示した。
〔Ａ成分〕
酸化エチレン／酸化プロピレン／酸化エチレン共重合体
・ポリオキシエチレンポリオキシプロピレングリコール１：
（分子量約４，１００、酸化エチレン付加重量率５０％）
商品名：ニューポールＰＥ−７５、三洋化成工業社製
・ポリオキシエチレンポリオキシプロピレングリコール２：
（分子量約８，７５０、酸化エチレン付加重量率８０％）
商品名：ニューポールＰＥ−６８、三洋化成工業社製
・ポリオキシエチレンポリオキシプロピレングリコール３：
（分子量約１０，２５０、酸化エチレン付加重量率８０％）
商品名：ニューポールＰＥ−７８、三洋化成工業社製
・ポリオキシエチレンポリオキシプロピレングリコール４：
（分子量約１６，２５０、酸化エチレン付加重量率８０％）
商品名：ニューポールＰＥ−１０８、三洋化成工業社製
・ポリオキシエチレンポリオキシプロピレングリコール５：
（分子量約２０，０００、酸化エチレン付加重量率８０％）
商品名：ニューポールＰＥ−１２８、三洋化成工業社製
In addition, the detail of the various components of the Examples and Comparative Examples shown in Tables 1 to 8 below and the amounts of the effective components (mass%, hereinafter abbreviated as “%”) are as follows. The numbers are shown as they are.
[Component A]
Ethylene oxide / propylene oxide / ethylene oxide copolymer / polyoxyethylene polyoxypropylene glycol 1:
(Molecular weight 4,100, ethylene oxide addition weight ratio 50%)
Product name: New Pole PE-75, manufactured by Sanyo Chemical Industries, Ltd., polyoxyethylene polyoxypropylene glycol 2:
(Molecular weight approximately 8,750, ethylene oxide addition weight ratio 80%)
Product name: New Pole PE-68, manufactured by Sanyo Chemical Industries, Ltd., polyoxyethylene polyoxypropylene glycol 3:
(Molecular weight approximately 10,250, ethylene oxide addition weight ratio 80%)
Product name: New Pole PE-78, manufactured by Sanyo Chemical Industries, Ltd., polyoxyethylene polyoxypropylene glycol 4:
(Molecular weight 16,250, ethylene oxide addition weight ratio 80%)
Product name: New Pole PE-108, manufactured by Sanyo Chemical Industries, Ltd., polyoxyethylene polyoxypropylene glycol 5:
(Molecular weight 20,000, ethylene oxide addition weight ratio 80%)
Product name: New Pole PE-128, manufactured by Sanyo Chemical Industries
〔Ｂ成分〕
界面活性剤
・界面活性剤１：
（炭素数Ｃ１０とＣ１４のアルキルジメチルアミンオキサイド）
商品名：ゲナミノックス１０１４、有効成分３２％、クラリアントジャパン社製
・界面活性剤２：
（炭素数Ｃ１０ゲルベアルコール、エチレンオキサイド・プロピレンオキサイド付加物）
商品名：ノイゲンＸＬ−８０、有効成分９９％以上、第一工業製薬社製
・界面活性剤３：
（炭素数Ｃ１０イソデシルアルコール、エチレンオキサイド７モル付加物）
商品名：ナロアクティーＩＤ−７０、有効成分９９％以上、三洋化成工業社製
・界面活性剤４：
（炭素数Ｃ９〜Ｃ１１のアルキルエーテル、エチレンオキサイド８モル付加物）
商品名：ネオドール９１−８Ｔ、有効成分９９％以上、シェル社製
・界面活性剤５：
（塩化アルキルジメチルベンジルアンモニウム）
商品名：カチオンＧ−５０、有効成分５１％、三洋化成工業社製
[B component]
Surfactant / Surfactant 1:
(C10 and C14 alkyldimethylamine oxide)
Product name: Genaminox 1014, active ingredient 32%, manufactured by Clariant Japan, Surfactant 2:
(C10 carbon gel gel alcohol, ethylene oxide / propylene oxide adduct)
Product name: Neugen XL-80, active ingredient 99% or more, manufactured by Daiichi Kogyo Seiyaku Co., Ltd., surfactant 3:
(C10 C10 isodecyl alcohol, ethylene oxide 7 mol adduct)
Product name: NAROACTY ID-70, active ingredient 99% or more, manufactured by Sanyo Chemical Industries, Ltd. Surfactant 4:
(C9-C11 alkyl ether, ethylene oxide 8-mol adduct)
Product name: Neodol 91-8T, active ingredient 99% or more, manufactured by Shell, surfactant 5:
(Alkyldimethylbenzylammonium chloride)
Product name: Cation G-50, active ingredient 51%, manufactured by Sanyo Chemical Industries
〔Ｃ成分〕
キレート剤
・キレート剤１：
ポリアクリル酸ナトリウム（平均分子量４，０００）
商品名：ソカランＰＡ−２５ＣＬ、有効成分４５％、ＢＡＳＦ社製
・キレート剤２：
クエン酸アンモニウム、
商品名：クエン酸二アンモニウム、含量９８％以上、磐田化学工業社製
[C component]
Chelating agent / chelating agent 1:
Sodium polyacrylate (average molecular weight 4,000)
Product name: Socaran PA-25CL, 45% active ingredient, manufactured by BASF, chelating agent 2:
Ammonium citrate,
Product name: Diammonium citrate, content 98% or more, manufactured by Iwata Chemical Industry Co., Ltd.
〔Ｄ成分〕
水溶性溶剤
・水溶性溶剤１：
プロピレングリコールモノメチルエーテル
商品名：ＭＦＧ、日本乳化剤社製
・水溶性溶剤２：
ジプロピレングリコールモノメチルエーテル
商品名：ＭＦＤＧ、日本乳化剤社製
・水溶性溶剤３：
Ｎ−メチル−２−ピロリドン（ＮＭＰ）
商品名：Ｍピロール、ＩＳＰ社製
[D component]
Water-soluble solvent / water-soluble solvent 1:
Propylene glycol monomethyl ether Product name: MFG, manufactured by Nippon Emulsifier Co., Ltd. Water-soluble solvent 2:
Dipropylene glycol monomethyl ether Product name: MFDG, manufactured by Nippon Emulsifier Co., Ltd. Water-soluble solvent 3:
N-methyl-2-pyrrolidone (NMP)
Product name: M pyrrole, made by ISP
〔任意成分〕
ｐＨ調整のための中和剤
・中和剤：
アンモニア
商品名：アンモニア水、有効成分２５％、高杉製薬社製
[Optional ingredients]
Neutralizing agent and neutralizing agent for pH adjustment:
Ammonia Product name: Ammonia water, active ingredient 25%, manufactured by Takasugi Pharmaceutical Co., Ltd.
〔比較成分〕
・リバース型、ポリオキシプロピレンポリオキシエチレングリコール１：
（分子量約２，５００、酸化エチレン付加重量率１０％）
商品名：プルロニック２５Ｒ−１、ＡＤＥＫＡ社製
・リバース型、ポリオキシプロピレンポリオキシエチレングリコール２：
（分子量約２，５００、酸化エチレン付加重量率２０％）
商品名：プルロニック２５Ｒ−２、ＡＤＥＫＡ社製
・ポリエチレンオキサイド付加重合物：
（平均分子量６００〜８，０００，０００）
商品名：ＰＥＯ−１８Ｚ、住友精化社製
・ポリエチレングリコール付加重合物：
（平均分子量２０，０００）
商品名：ＰＥＧ２００００、日本油脂社製
・変性シリコーン：
ポリエーテルアミノアミド変性オルガノポリシロキサン
商品名：ＢＹ１６−９０６、東レ・ダウコーニング・シリコーン社製
・フッ素系エマルジョン：
フッ素ウレタン樹脂系エマルジョン
商品名：ＡＧ−３００１、不揮発分：２０％、明成化学工業社製
・アクリルポリマー：
アクリル樹脂系ポリマー
商品名：ＳＵＲＦ Ｓ１００、有効成分濃度：２０％、ローディア社製
[Comparative ingredients]
・ Reverse type, polyoxypropylene polyoxyethylene glycol 1:
(Molecular weight 2,500, ethylene oxide addition weight ratio 10%)
Product name: Pluronic 25R-1, manufactured by ADEKA, reverse type, polyoxypropylene polyoxyethylene glycol 2:
(Molecular weight 2,500, ethylene oxide addition weight ratio 20%)
Product name: Pluronic 25R-2, manufactured by ADEKA, polyethylene oxide addition polymer:
(Average molecular weight 600-8,000,000)
Product name: PEO-18Z, manufactured by Sumitomo Seika Co., Ltd. Polyethylene glycol addition polymer:
(Average molecular weight 20,000)
Product name: PEG 20000, manufactured by NOF Corporation, modified silicone:
Polyetheraminoamide-modified organopolysiloxane Product name: BY16-906, manufactured by Toray Dow Corning Silicone Co., Ltd., fluorine emulsion:
Fluorine urethane resin emulsion Product name: AG-3001, nonvolatile content: 20%, Meisei Chemical Industry Co., Ltd. acrylic polymer:
Acrylic resin-based polymer Product name: SURF S100, active ingredient concentration: 20%, manufactured by Rhodia
上記の結果から、実施例１〜１８品は、貯蔵安定性、防汚性、洗浄性のいずれの試験項目においても、良好な性能を示すことがわかる。
以上のように、本発明の硬表面用防汚洗浄剤組成物は、特定、かつ所定量の酸化エチレン／酸化プロピレン／酸化エチレン共重合体（Ａ成分）、界面活性剤（Ｂ成分）、キレート剤（Ｃ成分）、水溶性溶剤（Ｄ成分）、および水（Ｅ成分）を組み合わせることにより、被洗浄面に対し優れた防汚効果と優れた洗浄効果を発揮することがわかる。
したがって、本発明の硬表面用防汚洗浄剤組成物は、特にポリエチレンやポリプロピレン、およびＦＲＰ等のプラスチック素材からなる浴室や浴槽。さらには腰掛け、手おけ、およびスノコなどの浴室用具等の硬表面に対する防汚洗浄剤として好適に用いることができる。
From the above results, it can be seen that the products of Examples 1 to 18 show good performance in any of the test items of storage stability, antifouling property, and detergency.
As described above, the antifouling detergent composition for hard surfaces of the present invention is a specific and predetermined amount of ethylene oxide / propylene oxide / ethylene oxide copolymer (component A), surfactant (component B), chelate. It can be seen that by combining an agent (C component), a water-soluble solvent (D component), and water (E component), an excellent antifouling effect and an excellent cleaning effect are exhibited on the surface to be cleaned.
Therefore, the antifouling detergent composition for hard surfaces of the present invention is a bathroom or bathtub made of a plastic material such as polyethylene, polypropylene, and FRP. Furthermore, it can be suitably used as an antifouling cleaning agent for hard surfaces of bathroom tools such as stools, handbags, and slats.
Claims (8)
ＨＯ−（Ｃ２Ｈ４Ｏ）ｎ−（Ｃ３Ｈ６Ｏ）ｍ−（Ｃ２Ｈ４Ｏ）ｎ−Ｈ （ただしｎとｍは０でない整数） (A) 0.5-60 mass% of ethylene oxide / propylene oxide / ethylene oxide copolymer represented by the following formula, (B) 0.1-15 mass% of surfactant, (C) chelating agent 0 1. An antifouling detergent composition for hard surfaces, comprising 1 to 15% by mass, (D) 0.1 to 15% by mass of a water-soluble solvent, and (E) remaining mass% of water.
HO- (C 2 H 4 O) n- (C 3 H 6 O) m- (C 2 H 4 O) n-H ( where n and m are not 0 integer)
Including a step of spraying or applying a cleaning liquid obtained by diluting the antifouling detergent for hard surfaces according to any one of claims 1 to 5 with water to a hard surface, and a step of rinsing with water. A characteristic cleaning method.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006256309A JP5079290B2 (en) | 2006-09-21 | 2006-09-21 | Antifouling detergent composition for bathrooms, cleaning composition impregnated with the composition, and cleaning method using them |
| PCT/US2007/078472 WO2008036559A2 (en) | 2006-09-21 | 2007-09-14 | Antifouling detergent composition for hard surface, washing mateiral impregnated with the composition, and washing method using same |
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|---|---|---|---|
| JP2006256309A JP5079290B2 (en) | 2006-09-21 | 2006-09-21 | Antifouling detergent composition for bathrooms, cleaning composition impregnated with the composition, and cleaning method using them |
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| JP2008074975A true JP2008074975A (en) | 2008-04-03 |
| JP5079290B2 JP5079290B2 (en) | 2012-11-21 |
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| WO (1) | WO2008036559A2 (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011516647A (en) * | 2008-04-04 | 2011-05-26 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Use of citrate as a cleaning aid for hard surfaces |
| JP2011522086A (en) * | 2008-05-30 | 2011-07-28 | アメリカン ステリライザー カンパニー | Biodegradable scale control composition for highly concentrated alkaline detergents |
| JP2014167135A (en) * | 2009-11-25 | 2014-09-11 | Basf Se | Cleaning composition |
| JP2014526586A (en) * | 2011-09-27 | 2014-10-06 | ダウ グローバル テクノロジーズ エルエルシー | Branched alkoxylate surfactant composition |
| WO2014192680A1 (en) * | 2013-05-29 | 2014-12-04 | 花王株式会社 | Hard surface detergent composition |
| JP2015512970A (en) * | 2012-02-17 | 2015-04-30 | エコラボ ユーエスエー インコーポレイティド | Neutral floor cleaner |
| JP5996822B1 (en) * | 2016-05-30 | 2016-09-21 | 株式会社ニイタカ | Cleaning composition for automatic cleaning machine |
| JP2020519746A (en) * | 2017-06-22 | 2020-07-02 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Cleaning products |
| WO2022123995A1 (en) * | 2020-12-10 | 2022-06-16 | 花王株式会社 | Hard surface treatment agent composition |
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| US20100062164A1 (en) | 2008-09-08 | 2010-03-11 | Lam Research | Methods and Solutions for Preventing the Formation of Metal Particulate Defect Matter Upon a Substrate After a Plating Process |
| EP3418360B1 (en) | 2017-06-22 | 2019-08-28 | The Procter & Gamble Company | Sprayable cleaning composition |
| US11932795B2 (en) | 2020-06-03 | 2024-03-19 | Ecolab Usa Inc. | Aromatic amine epoxide adducts for corrosion inhibition |
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| GB2336370B (en) * | 1998-04-14 | 2002-09-04 | Reckitt & Colman Inc | Improvements in or relating to organic compositions |
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| CA2567625A1 (en) * | 2004-06-07 | 2005-12-22 | The Procter & Gamble Company | Detergent composition |
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| JP2000096098A (en) * | 1998-09-22 | 2000-04-04 | Kao Corp | Aqueous liquid cleanser |
| JP2002256030A (en) * | 2001-03-05 | 2002-09-11 | Lion Corp | Tertiary amino group-containing high polymer compound, detergent composition, antifoulant composition and detergent antifoulant composition |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011516647A (en) * | 2008-04-04 | 2011-05-26 | ユニリーバー・ナームローゼ・ベンノートシヤープ | Use of citrate as a cleaning aid for hard surfaces |
| JP2011522086A (en) * | 2008-05-30 | 2011-07-28 | アメリカン ステリライザー カンパニー | Biodegradable scale control composition for highly concentrated alkaline detergents |
| JP2014167135A (en) * | 2009-11-25 | 2014-09-11 | Basf Se | Cleaning composition |
| JP2014526586A (en) * | 2011-09-27 | 2014-10-06 | ダウ グローバル テクノロジーズ エルエルシー | Branched alkoxylate surfactant composition |
| JP2015512970A (en) * | 2012-02-17 | 2015-04-30 | エコラボ ユーエスエー インコーポレイティド | Neutral floor cleaner |
| JP2015007221A (en) * | 2013-05-29 | 2015-01-15 | 花王株式会社 | Hard surface detergent composition |
| WO2014192680A1 (en) * | 2013-05-29 | 2014-12-04 | 花王株式会社 | Hard surface detergent composition |
| JP5996822B1 (en) * | 2016-05-30 | 2016-09-21 | 株式会社ニイタカ | Cleaning composition for automatic cleaning machine |
| JP2017214446A (en) * | 2016-05-30 | 2017-12-07 | 株式会社ニイタカ | Detergent composition for automatic washing machine |
| JP2020519746A (en) * | 2017-06-22 | 2020-07-02 | ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ | Cleaning products |
| JP2022078252A (en) * | 2017-06-22 | 2022-05-24 | ザ プロクター アンド ギャンブル カンパニー | Cleaning product |
| JP7405887B2 (en) | 2017-06-22 | 2023-12-26 | ザ プロクター アンド ギャンブル カンパニー | cleaning products |
| WO2022123995A1 (en) * | 2020-12-10 | 2022-06-16 | 花王株式会社 | Hard surface treatment agent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5079290B2 (en) | 2012-11-21 |
| WO2008036559A3 (en) | 2008-05-08 |
| WO2008036559A2 (en) | 2008-03-27 |
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