JP2008068633A - Injection molding mold - Google Patents

Injection molding mold Download PDF

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JP2008068633A
JP2008068633A JP2007316212A JP2007316212A JP2008068633A JP 2008068633 A JP2008068633 A JP 2008068633A JP 2007316212 A JP2007316212 A JP 2007316212A JP 2007316212 A JP2007316212 A JP 2007316212A JP 2008068633 A JP2008068633 A JP 2008068633A
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resin
sheet
mold
gate
picture
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Hiroyuki Atake
浩之 阿竹
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Dai Nippon Printing Co Ltd
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Dai Nippon Printing Co Ltd
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  • Injection Moulding Of Plastics Or The Like (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To prevent a sink mark from appearing on the gate of the product surface and a printing sheet from being damaged by the heat of an injected resin in molding a printed molding by an in-mold printing method. <P>SOLUTION: The in-mold printing method comprises feeding a printing sheet in the middle of the male and female molds for injection molding, clamping the molds, injecting a fluidized resin into the cavity and obtaining a printed mold. The gate through which the resin is injected into the cavity of the mold used is arranged at the rib behind the molding. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

本発明は、射出成形同時絵付方法に用いる射出成形型に関する。特に、ゲート部分の製品表面にヒケが生じるのを防げる射出成形型に関する。   The present invention relates to an injection mold used in an injection molding simultaneous painting method. In particular, the present invention relates to an injection mold that prevents the occurrence of sink marks on the product surface of the gate portion.

従来より、成形品の成形と同時にその外表面に模様等を設ける射出成形同時絵付方法が各種の態様で行われている。例えば、真空成形用の通気孔を設けた雌型を利用して熱可塑性樹脂よりなる絵付シートを真空成形した後、雌雄両型を型締めし、溶融樹脂を両型で形成されるキャビティに射出して、射出成形と同時に成形品の外表面に絵付シートを一体化させる方法が開示されている(たとえば、特許文献1参照)。この態様の射出成形同時絵付方法では真空成形と射出成形とを組合わせた方法であり、複雑な曲面形状に模様付けができる。なお、絵付シートには、ラミネートタイプと転写タイプとがあり、前者では絵付シート自体を成形品に積層させて絵付けし、後者では絵付シートの基材シートのみを剥離してその転写層を成形品に転写させて絵付けする。
特公昭50−19132号公報
2. Description of the Related Art Conventionally, an injection molding simultaneous painting method in which a pattern or the like is provided on the outer surface simultaneously with molding of a molded product has been performed in various modes. For example, after a vacuum-formed sheet made of thermoplastic resin is formed using a female mold provided with a vent for vacuum forming, both the male and female molds are clamped and the molten resin is injected into a cavity formed by both molds. And the method of integrating a picture sheet | seat with the outer surface of a molded article simultaneously with injection molding is disclosed (for example, refer patent document 1). The injection molding simultaneous painting method of this aspect is a method in which vacuum molding and injection molding are combined, and a pattern can be formed on a complicated curved surface shape. In addition, there are two types of picture sheets: a laminate type and a transfer type. In the former, the picture sheet itself is laminated on the molded product and painted, and in the latter, only the base sheet of the picture sheet is peeled off and the transfer layer is formed. I transfer it to the product and paint it.
Japanese Patent Publication No. 50-19132

ところで、射出樹脂はキャビティ内にはゲートから充填する事になるが、成形品の形状やゲート位置等によっては、ゲート部近傍の成形品表面が凹む、所謂ヒケが発生する事がある。また、射出成形同時絵付方法に於いては、成形品表側面を絵付シートで絵付けし、ゲートは通常成形品の裏側に設けて裏側から樹脂は射出する事になる為に、絵付シートの耐熱性が充分で無い場合、裏側のゲートからキャビティ内に充填された直後の溶融樹脂が、絵付シートの接着面となる裏面に触れて、絵付シートが熱溶融したり軟化して、絵付シートが破断したり流れたりする事がある。また、絵付シート裏面側に絵柄等を付与する為に印刷形成したインキ層の耐熱性が十分で無い場合でも、同様の理由から、インキ層が溶融乃至軟化して流れる事がある。インキ層が流れると絵柄が歪んだり消失する。特に、樹脂がゲートを通じてキャビティ内に充填されだす部分では、流路の断面積が小さい為に、樹脂の剪断発熱による影響もある。この為、図3に示す如く、ゲート3周囲の成形品裏面に円形状に肉厚部4を設けて、絵付シート或いはそのインキ層にかかる熱の影響を少なくする事もあるが、今度は肉厚部の肉厚が厚くなっている為に、ヒケがひどくなり、成形品の外観不良となる場合もある。この様に、射出成形同時絵付方法の場合は、絵付シートを使用する為に、その耐熱性や成形品形状などによっては、ヒケ防止や、射出樹脂の熱で絵付シートが損傷しない様な特別の工夫をする必要があった。   By the way, the injection resin is filled from the gate into the cavity. However, depending on the shape of the molded product, the gate position, and the like, a so-called sink may occur in which the surface of the molded product near the gate portion is recessed. In the injection molding simultaneous painting method, the front side of the molded product is painted with a painted sheet, and the gate is usually provided on the back side of the molded product, and the resin is injected from the back side. If the properties are not sufficient, the molten resin immediately after filling the cavity from the gate on the back side touches the back surface, which becomes the adhesive surface of the painted sheet, and the painted sheet melts and softens, causing the painted sheet to break There are times when it flows. Further, even when the heat resistance of the ink layer printed and formed for imparting a pattern or the like to the back side of the picture sheet is insufficient, the ink layer may flow after being melted or softened for the same reason. When the ink layer flows, the pattern is distorted or disappears. In particular, in the portion where the resin begins to fill into the cavity through the gate, the flow path has a small cross-sectional area, which is also affected by the shear heat generation of the resin. For this reason, as shown in FIG. 3, there is a case where a circular thick portion 4 is provided on the back surface of the molded product around the gate 3 to reduce the influence of heat applied to the picture sheet or its ink layer. Since the thickness of the thick part is thick, sink marks become severe, and the appearance of the molded product may be deteriorated. In this way, in the case of the injection molding simultaneous painting method, because the painting sheet is used, depending on its heat resistance and the shape of the molded product, special treatments such as prevention of sink marks and damage to the painting sheet due to the heat of the injection resin It was necessary to devise.

そこで、上記課題を解決すべく、本発明の射出成形型では、絵付シートを射出成形の雌雄両型間に供給した後、両型を型締めして、流動状態の樹脂を両型で形成されるキャビティに射出して、絵付け成形品を製造する射出成形同時絵付方法に使用する型において、樹脂のキャビティ内への注入孔であるゲートが、成形品裏側のリブに設けられている構成とした。この結果、ゲート位置に対応する成形品表側面にヒケが発生しなくなる。また、充填時に樹脂が剪断発熱する部分から絵付シートが遠いので、絵付シートのインキ層が流れる等の絵付シート損傷も防げる。   Therefore, in order to solve the above-described problems, in the injection mold of the present invention, after supplying the sheet with a picture between both the male and female molds of injection molding, both molds are clamped to form a fluid resin in both molds. In the mold used in the injection molding simultaneous painting method for producing a painted product by injecting into a cavity, a gate as an injection hole into the resin cavity is provided on the rib on the back side of the molded product. did. As a result, no sink marks are generated on the side surface of the molded product corresponding to the gate position. In addition, since the picture sheet is far from the portion where the resin shears and generates heat during filling, damage to the picture sheet such as the flow of the ink layer of the picture sheet can be prevented.

本発明の射出成形型によれば、射出成形同時絵付けによって絵付け成形品を得るに当たって、ゲート位置に対応する成形品表側面にヒケが発生しない。また、樹脂がキャビティ内に充填される際に、ゲート或いはゲート近傍の剪断発熱し易い部分に、絵付シートが存在しない為に、インキ層が流れる等の絵付シート損傷が起きない。元々有るリブを利用すれば製品設計を変更せずに、ヒケや絵付シート損傷を防げる。また、絵付シートの損傷を防げるから、元々は絵付シートによる絵付け無しの成形品に対して、絵付シート使用時特有の肉厚部を設ける等の設計変更をせずに、絵付シートで絵付けできる。更に、リブにゲートを設けるので、リブに於けるショートショット等が発生しにくい。   According to the injection mold of the present invention, when obtaining a painted product by simultaneous injection molding, there is no sink on the side surface of the molded product corresponding to the gate position. In addition, when the resin is filled in the cavity, the painting sheet does not exist in the gate or in the vicinity of the gate where the heat is easily generated. Therefore, the painting sheet is not damaged such as the ink layer flowing. By using the original ribs, it is possible to prevent sink marks and damaged sheets with pictures without changing the product design. In addition, to prevent damage to the painted sheet, the painted sheet is originally painted with a painted sheet without any design changes, such as providing a thick part specific to the use of the painted sheet. it can. Further, since the rib is provided with a gate, short shots and the like are unlikely to occur on the rib.

以下、図面を参照しながら本発明の射出成形型について、実施の形態を説明する。図1は射出成形型が本発明による場合と、従来の場合とを比較説明する説明図である。なお、図では、型に充填される樹脂を基準として、すなわち成形品の断面図で描いてある。   Embodiments of an injection mold according to the present invention will be described below with reference to the drawings. FIG. 1 is an explanatory view for comparing and explaining the case where the injection mold is according to the present invention and the conventional case. In the figure, the resin filled in the mold is used as a reference, that is, in a sectional view of the molded product.

従来の射出成形型は、例えば、サブマリンゲートの場合には、図1(A)の如く、成形品1の裏面に設けたボス6にゲート3を設けたりする構造であった。なお、このボス6は樹脂充填専用に設ける以外に、他の目的と兼用で設ける場合もある。これに対して、本発明の射出成形型では、図1(B)にその一形態で例示する如く、成形品1の裏面に設けられているリブ7を活用して、リブ7にゲート3を設ける。なお、図1(B)はリブ7の先端にピンポイントゲートを設けた例である。図1(A)の様に、成形品1が裏面にリブ7を有する場合には、リブにゲートを設ければ、ヒケは防げる。流動状態の樹脂は、スプルー(不図示)からランナー2を通過してゲート3からリブ7を有するキャビティ内に充填される。   For example, in the case of a submarine gate, a conventional injection mold has a structure in which a gate 3 is provided on a boss 6 provided on the back surface of a molded product 1 as shown in FIG. The boss 6 may be provided for other purposes in addition to being provided exclusively for resin filling. On the other hand, in the injection mold of the present invention, as exemplified in FIG. 1B, the rib 7 provided on the back surface of the molded product 1 is utilized to provide the gate 3 with the rib 7. Provide. FIG. 1B shows an example in which a pinpoint gate is provided at the tip of the rib 7. As shown in FIG. 1A, when the molded product 1 has ribs 7 on the back surface, sink marks can be prevented by providing gates on the ribs. The resin in a fluid state passes through the runner 2 from a sprue (not shown) and is filled into a cavity having ribs 7 from the gate 3.

また、図1(A)及び(B)は成形品1の裏面にリブが有る場合であったが、成形品1の裏面にはリブが無い場合でも、図1(C)の如くリブ7が成形品の裏側として成形品外周に有る場合には、そのリブ7を活用すれば良い。すなわち、図1(D)の如く、成形品外周に後方に張り出したリブ7にゲート3を設ければ良い。なお、図1(C)及び(D)に例示するゲート3は、サブマリンゲート(トンネルゲート)による場合であるが、もちろん、この場合、サブマリンゲートに限定されるものでは無い。   1 (A) and 1 (B) show the case where the ribs are provided on the back surface of the molded product 1, but the ribs 7 are not formed on the back surface of the molded product 1 as shown in FIG. When it is on the outer periphery of the molded product as the back side of the molded product, the rib 7 may be used. That is, as shown in FIG. 1D, the gate 3 may be provided on the rib 7 projecting rearward on the outer periphery of the molded product. Note that the gate 3 illustrated in FIGS. 1C and 1D is a submarine gate (tunnel gate), but of course, in this case, the gate 3 is not limited to the submarine gate.

以上の様に、本発明の射出成形型では、ゲートをリブに設けるので、ヒケが発生しない。また、絵付シートも、充填時に樹脂が剪断発熱する部分から遠いので、絵付シートのインキ層が流れる等の絵付シート損傷も起き難い。なお、ゲートを設けるリブは元々設けてあるリブを利用しても良いが、成形品の使用上、支障が無ければ、ゲート用にリブを新設しても良い。また、ゲートの種類は、上記説明ではピンポイントゲートとサブマリンゲートで説明したが、これに限定される事はなく、その他の公知の各種ゲートでも良い。また、射出成形型の型材は特に限定されず、例えば、S50C、S55C、SCM3、SCM4等の金型材として従来公知の各種鋼材の他に、銅等の他の金属及び金属合金、或いはセラミックス等の非金属材料等でも良く、適宜選択使用すれば良い。   As described above, in the injection mold according to the present invention, since the gate is provided on the rib, sink does not occur. In addition, the picture sheet is also far from the portion where the resin shears and generates heat during filling, so that the picture sheet is less likely to be damaged, such as the ink layer of the picture sheet flowing. In addition, although the rib which originally provided may be utilized for the rib which provides a gate, if there is no trouble on use of a molded article, you may newly provide a rib for gates. Moreover, although the kind of gate demonstrated in the said description by the pinpoint gate and the submarine gate, it is not limited to this, Other well-known various gates may be sufficient. In addition, the mold material of the injection mold is not particularly limited. For example, other metal materials such as copper, other metal materials such as copper, metal alloys, ceramics, and the like are conventionally known as mold materials such as S50C, S55C, SCM3, and SCM4. A non-metallic material or the like may be used and may be appropriately selected and used.

〔射出成形同時絵付方法〕本発明の射出成形型が使用され得る射出成形同時絵付方法について、ここで説明しておく。射出成形同時絵付方法とは、特公昭50−19132号公報、特公昭43−27488号公報、特開平6−315950号公報、特公平2−42080号公報等に記載されるように、絵付シートを射出成形の雌雄両金型間に供給した後、流動状態の樹脂を両型で形成されるキャビティ内に射出充填し、樹脂成型物の成形と同時にその表面に絵付シートを積層して、ラミネ−ト又は転写で絵付けした絵付け成形品を製造する方法である。   [Injection molding simultaneous painting method] The injection molding simultaneous painting method in which the injection mold of the present invention can be used will be described here. The method of simultaneous painting with injection molding is as follows: Japanese Patent Publication No. 50-19132, Japanese Patent Publication No. 43-27488, Japanese Patent Laid-Open No. 6-315950, Japanese Patent Publication No. 2-4080, etc. After being supplied between both male and female molds for injection molding, a resin in a fluid state is injected and filled into a cavity formed by both molds, and simultaneously with the molding of the resin molded product, a picture sheet is laminated on the surface, This is a method for manufacturing a painted product that has been painted by transfer or transfer.

射出成形同時絵付方法は各種形態があり、それら各種形態に対して、本発明の射出成形型が使用される得る。射出成形同時絵付方法の各種形態としては、例えば、絵付シートの予備成形を行う形態でも行わない形態でも、いずれでも良い。また、絵付シートの予熱を行っても良く、行わなくても良い。なお、予備成形時には通常は絵付シートは予熱する。もちろん、絵付シートの絞りが大きい場合は、予備成形を行うのが好ましい。一方、絵付シートの絞りが少ない場合は、射出される流動状態の樹脂の樹脂圧で絵付シートを成形できる。この際、絞りが浅ければ、予備成形無しで樹脂射出と同時に型内に充填される流動状態の樹脂の樹脂圧のみで絵付シートを成形する事もある。また、樹脂圧で絵付シートを成形する場合でも、絵付シートは予熱せずに射出樹脂の熱を利用する事もある。また、絵付シートの予備成形は、通常は、射出成形型を真空成形型と兼用するが、型間に絵付シートを供給する前に、型外部で別の真空成形型で絵付シートを真空成形する様な予備成形でも良い。なお、真空成形とは真空圧空成形も包含する。   The injection molding simultaneous painting method has various forms, and the injection mold of the present invention can be used for these various forms. Various forms of the injection molding simultaneous painting method may be, for example, a form in which a picture sheet is preformed or not. In addition, the picture sheet may or may not be preheated. In the pre-molding, the picture sheet is usually preheated. Of course, when the drawing sheet has a large aperture, it is preferable to perform preforming. On the other hand, when the drawing sheet has a small aperture, the drawing sheet can be formed by the resin pressure of the injected resin in a fluid state. At this time, if the drawing is shallow, the picture sheet may be formed only with the resin pressure of the resin in a fluid state filled in the mold at the same time as the resin injection without pre-molding. Even when a picture sheet is molded by resin pressure, the picture sheet may be preheated and use the heat of the injection resin. In addition, the pre-molding of a picture sheet is usually performed by using an injection mold as a vacuum mold, but before supplying the picture sheet between the molds, the picture sheet is vacuum-formed by another vacuum mold outside the mold. Various preforms may be used. The vacuum forming includes vacuum / pressure forming.

図2の概念図によって、射出成形同時絵付方法を、その或る一形態で説明する。なお、ここで説明する形態は、型締めする前に、絵付シートを型間で加熱し軟化させて射出成形型で真空成形により予備成形した後に、型締めして樹脂を射出する形態である。また、この概念図は、射出成形同時絵付方法それ自体の説明の為の図であるので、ゲートの位置を敢えて特定せず、簡略して図示したが、もちろん、本発明に於いては、図1(B)、(D)の如く、ゲートを成形品裏側のリブの所に設けるようにする。   With reference to the conceptual diagram of FIG. 2, the injection molding simultaneous painting method will be described in one form. In addition, the form demonstrated here is a form which heats and softens a picture sheet between molds, pre-molds it with an injection molding die by vacuum molding, and injects resin after mold clamping. Further, this conceptual diagram is a diagram for explaining the injection molding simultaneous painting method itself, and therefore, the position of the gate is not specified intentionally, but is simply illustrated. As shown in 1 (B) and (D), the gate is provided at the rib on the back side of the molded product.

先ず、図2(A)の如く、射出成形型としては、射出ノズルと連通するランナー及びゲートを有する型Maと、型面に吸引孔41を有しシートの予備成形型を兼用する型Mbの一対の成形型を用いる。これらの型は鉄等の金属、或いはセラミックスからなる。型開き
状態に於いて両型Ma、Mb間に絵付シートSを供給し、型Mbに絵付シートSを枠状のシートクランプ42で押圧する等して固定する。この際、絵付シートの接着面側は、図面右側の射出樹脂側となる様にする事はもちろんである。次いで、適宜、両型間に挿入したヒータで絵付シートを加熱軟化させる。加熱は例えば非接触の輻射加熱とするが、接触加熱でも良い。そして、吸引孔から吸引して真空成形して、絵付シートを型Mbのキャビティ面に沿わせ予備成形する。なお、真空成形は圧空も併用する真空圧空成形でも良く、これも包含する。次いで、ヒータを両型間から退避させ、図2(B)の如く両型を型締めし、両型で形成さるキャビティに加熱熔融状態等の流動状態の樹脂を充填する。そして、樹脂が冷却等により固化した後、型開きして成形物を取り出す。絵付シートがラミネ−トシートの場合は、絵付シートの不要部分があれば適宜トリミングすれば、樹脂成形物に絵付シートが積層され絵付けされた絵付け成形品が得られる。また、絵付シートが転写シートの場合は、その基材シートを型Mb側に残した状態で成形物を取り出すか、或いは、絵付シート全体が積層された状態で成形物を取り出し後、基材シートを剥離して、転写層のみが積層されて絵付けされた絵付け成形品を得る。
First, as shown in FIG. 2A, the injection mold includes a mold Ma having a runner and a gate communicating with the injection nozzle, and a mold Mb having a suction hole 41 on the mold surface and also serving as a sheet preforming mold. A pair of molds is used. These molds are made of metal such as iron or ceramics. In the mold open state, a picture sheet S is supplied between both molds Ma and Mb, and the picture sheet S is fixed to the mold Mb by pressing it with a frame-shaped sheet clamp 42. In this case, it goes without saying that the adhesive surface side of the picture sheet is the injection resin side on the right side of the drawing. Next, the picture sheet is softened by heating with a heater inserted between both molds as appropriate. The heating is, for example, non-contact radiation heating, but may be contact heating. Then, vacuum suction is performed through the suction holes, and the picture sheet is preformed along the cavity surface of the mold Mb. Note that the vacuum forming may be vacuum / pressure forming using pressure air together, and includes this. Next, the heater is retracted from between both molds, both molds are clamped as shown in FIG. 2B, and a resin formed in a fluid state such as a heat-melted state is filled in a cavity formed by both molds. And after resin solidifies by cooling etc., a mold is opened and a molding is taken out. In the case where the picture sheet is a laminate sheet, if there is an unnecessary portion of the picture sheet, trimming is appropriately performed to obtain a picture-molded article in which the picture sheets are laminated on the resin molded product. When the picture sheet is a transfer sheet, the molded product is taken out with the base sheet left on the mold Mb side, or the molded sheet is taken out with the whole picture sheet laminated, and then the base sheet Is peeled off to obtain a painted product in which only the transfer layer is laminated and painted.

なお、本発明の射出成形型を用いて射出成形同時絵付けする際に、射出成形する樹脂としては、射出成形同時絵付方法に於ける従来公知のものが使用でき特に制限はない。射出成形樹脂は、製品の要求物性やコスト等に応じて選定される。例えば、熱可塑性樹脂であ
れば、ABS(アクリロニトリル−ブタジエン−スチレン共重合体)樹脂、AS(アクリロニトリル−スチレン共重合体)樹脂、スチレン樹脂、塩化ビニル樹脂、アクリル樹脂、ポリカーボネート樹脂、或いはポリエチレン、ポリプロピレン、ポリブテン、ポリメチルペンテン、エチレン−プロピレン共重合体、エチレン−プロピレン−ブテン共重合体、オレフィン系熱可塑性エラストマー等のポリオレフィン系樹脂等である。また、硬化性樹脂であれば、2液硬化型の樹脂、例えば、ウレタン樹脂、不飽和ポリエステル樹脂、エポキシ樹脂等の未硬化樹脂液等の射出成形同時絵付用として従来より知られている材料を使用できる。熱可塑性樹脂は加熱熔融して流動状態で射出し、また硬化性樹脂は室温又は適宜加熱して流動状態で射出する。但し、本発明の射出成形型の利点が、特に活かされる樹脂は加熱して射出する樹脂であり、特に加熱溶融によって流動状態で射出する熱可塑性樹脂である。
In addition, when performing the injection molding simultaneous painting using the injection mold of the present invention, as the resin to be injection molded, those conventionally known in the injection molding simultaneous painting method can be used and there is no particular limitation. The injection molding resin is selected according to the required physical properties and cost of the product. For example, if it is a thermoplastic resin, ABS (acrylonitrile-butadiene-styrene copolymer) resin, AS (acrylonitrile-styrene copolymer) resin, styrene resin, vinyl chloride resin, acrylic resin, polycarbonate resin, polyethylene, polypropylene , Polyolefin resins such as polybutene, polymethylpentene, ethylene-propylene copolymer, ethylene-propylene-butene copolymer, and olefin-based thermoplastic elastomer. Moreover, if it is curable resin, the material conventionally known for injection molding simultaneous painting of uncured resin liquids, such as two-component curable resin, for example, urethane resin, unsaturated polyester resin, epoxy resin, etc. Can be used. The thermoplastic resin is melted by heating and injected in a fluid state, and the curable resin is injected in a fluid state at room temperature or appropriately heated. However, the advantage of the injection mold of the present invention is that the resin that is particularly utilized is a resin that is heated and injected, and in particular, a thermoplastic resin that is injected in a fluidized state by heating and melting.

〔絵付シート〕上述の様な射出成形型を用いて射出成形同時絵付けする際に用い得る絵付シートは、転写タイプ或いはラミネートタイプとして従来公知の絵付シートを用いる事ができ、特に限定されるものでは無い。但し、本発明の射出成形型では、ゲート部の熱の影響が軽減している為に、従来よりも耐熱性が弱い絵付シートでも使用できる。そこで、絵付シートについても一応説明しておく。   [Painted sheet] A sheet with a picture that can be used for simultaneous painting by injection molding using an injection mold as described above can be a transfer type or a laminate type, and a conventionally known sheet with a picture can be used. Not. However, in the injection mold according to the present invention, since the influence of the heat of the gate portion is reduced, it is possible to use a sheet with a picture having a lower heat resistance than before. Therefore, I will explain the sheets with pictures.

転写タイプの絵付シート(転写シート)は、基材シートに剥離性のシートを用い、基材シート上に転写層が積層された構成である。転写層は例えば装飾層や接着剤層等からなる。また、転写層の基材シート側には剥離層を転写層の構成要素として適宜設けた構成等もある。ラミネートタイプの絵付シート(ラミネートシート)は、例えば基材シート上に装飾層と接着剤層とを順次積層した構成である。なお、転写タイプ、ラミネートタイプ共に接着剤層は省略することもある。   A transfer-type picture sheet (transfer sheet) has a configuration in which a peelable sheet is used as a base sheet, and a transfer layer is laminated on the base sheet. The transfer layer is made of, for example, a decoration layer or an adhesive layer. There is also a configuration in which a release layer is appropriately provided as a component of the transfer layer on the base sheet side of the transfer layer. A laminate-type picture sheet (laminate sheet) has a configuration in which, for example, a decorative layer and an adhesive layer are sequentially laminated on a base sheet. Note that the adhesive layer may be omitted for both the transfer type and the laminate type.

(基材シート)基材シートとしては、成形性の有る樹脂シートが代表的には用いられる。該樹脂シートとしては、例えば、ポリエチレン、ポリプロピレン、エチレン−プロピレン共重合体、エチレン−プロピレン−ブテン共重合体、オレフィン系熱可塑性エラストマー等のオレフィン系樹脂、ポリブチレンテレフタレート、エチレンテレフタレートイソフタレート共重合体等のポリエステル樹脂、塩化ビニル樹脂、アクリル樹脂、ABS(アクリロニトリル−ブタジエン−スチレン共重合体)樹脂、AS(アクリロニトリル−スチレン共重合体)樹脂、ポリアミド樹脂、ウレタン系等のその他の熱可塑性エラストマー、等の熱可塑性樹脂のシートの単層又は異種材料の2層以上の積層体が用いられる。また、成形性を満足すれば、不織布や織布等の布等に対して樹脂を含浸させたシートや、これに前記樹脂シートを積層した積層体等も用いられる。なお、転写タイプでは、必要に応じ、基材シートの転写層側に、転写層との剥離性を向上させる為、離型層を設けた構成の基材シートとする。離型層は基材シート剥離時に基材シートと共に転写層から分離し剥離除去される。離型層には、例えば、シリコーン樹脂、メラミン樹脂、ポリアミド樹脂、ウレタ
ン樹脂、ポリオレフィン樹脂、ワックス等の単体又は2種以上の混合物が用いられる。また、ラミネートタイプでは、基材シート樹脂中に顔料等の着色剤を練り込んで、基材シートを着色透明又は着色不透明、或いは無色透明又は無色不透明等とする装飾処理を施す事もある。この場合、基材シート自体が装飾層を成し基材シートのみの構成の絵付シートとなる場合もある。
(Substrate sheet) As the substrate sheet, a resin sheet having moldability is typically used. Examples of the resin sheet include polyethylene, polypropylene, ethylene-propylene copolymer, ethylene-propylene-butene copolymer, olefin resins such as olefin thermoplastic elastomer, polybutylene terephthalate, ethylene terephthalate isophthalate copolymer. Polyester resins such as vinyl chloride resin, acrylic resin, ABS (acrylonitrile-butadiene-styrene copolymer) resin, AS (acrylonitrile-styrene copolymer) resin, polyamide resin, urethane-based other thermoplastic elastomers, etc. A single layer of a thermoplastic resin sheet or a laminate of two or more layers of different materials is used. Moreover, if the moldability is satisfied, a sheet obtained by impregnating a resin into a cloth such as a nonwoven fabric or a woven fabric, or a laminate in which the resin sheet is laminated on the sheet is used. In addition, in a transfer type, in order to improve the peelability from the transfer layer on the transfer layer side of the base sheet, a base sheet having a release layer is provided as necessary. The release layer is separated and removed from the transfer layer together with the base sheet when the base sheet is peeled off. For the release layer, for example, a single substance or a mixture of two or more of a silicone resin, a melamine resin, a polyamide resin, a urethane resin, a polyolefin resin, a wax, or the like is used. In the laminate type, a coloring agent such as a pigment is kneaded in the base sheet resin, and the base sheet may be subjected to a decoration treatment such as colored transparent or colored opaque or colorless transparent or colorless opaque. In this case, the base sheet itself may form a decorative layer and become a picture-attached sheet having only the base sheet.

(装飾層)装飾層は、グラビア印刷、シルクスクリーン印刷、オフセット印刷等の従来公知の方法、材料で絵柄等を印刷した絵柄層(インキ層)、アルミニウム、クロム等の金属を公知の蒸着法等で部分又は全面に形成した金属薄膜層等である。絵柄は、板目や柾目等の木目模様、大理石や御影石等の石目模様、タイル調模様、煉瓦調模様、布目模様、文字、幾何学模様、全面ベタなど任意である。絵柄層用インキは、バインダー等からなるビヒクル、顔料や染料等の着色剤、これに適宜加える各種添加剤からなる。バインダーには、塩素化ポリエチレン、塩素化ポリプロピレン等の塩素化ポリオレフィン、ポリエステル樹脂、熱可塑性ウレタン樹脂、アクリル樹脂、酢酸ビニル樹脂、塩化ビニル−酢酸ビニル共重合体、セルロース系樹脂等の熱可塑性樹脂、熱硬化性ウレタン樹脂、エポキシ樹脂等の熱硬化性樹脂等を、これら樹脂の単体又は混合物として用いる。顔料又は染料等の着色剤としては、チタン白、カーボンブラック、弁柄、コバルトブルー、黄鉛、フタロシアニンブルー、イソインドリノン、キナクリドン、アルミニウム粉等の金属顔料、真珠光沢(パール)顔料等が用いられる。   (Decoration layer) The decoration layer is a conventionally known method such as gravure printing, silk screen printing, offset printing, a pattern layer (ink layer) obtained by printing a pattern or the like with a material, a known vapor deposition method using a metal such as aluminum or chromium, etc. The metal thin film layer etc. which were formed in the part or the whole. The pattern may be any pattern such as a wood grain pattern such as a grain or a grain, a stone pattern such as marble or granite, a tile-like pattern, a brick-like pattern, a texture pattern, a character, a geometric pattern, or a solid pattern. The pattern layer ink is composed of a vehicle composed of a binder, a colorant such as a pigment or a dye, and various additives appropriately added thereto. The binder includes chlorinated polyolefins such as chlorinated polyethylene and chlorinated polypropylene, polyester resins, thermoplastic urethane resins, acrylic resins, vinyl acetate resins, vinyl chloride-vinyl acetate copolymers, cellulose resins and other thermoplastic resins, A thermosetting resin such as a thermosetting urethane resin or an epoxy resin is used as a single substance or a mixture of these resins. As colorants such as pigments or dyes, titanium white, carbon black, petal, cobalt blue, chrome lead, phthalocyanine blue, isoindolinone, quinacridone, aluminum powder and other metallic pigments, pearlescent (pearl) pigments, etc. are used. It is done.

(接着剤層)絵付シートの裏面には、射出樹脂との接着性向上のため、コロナ放電処理、公知の各種プライマー塗工等の易接着処理や感熱型等の接着剤層を施すことがある。接着剤層には、熱可塑性樹脂、熱硬化性樹脂等の公知の樹脂が用いられる。例えば、熱可塑性樹脂では、ポリスチレン、ポリα−メチルスチレン等のスチレン樹脂又はスチレン共重合体、ポリ(メタ)アクリル酸メチル、ポリ(メタ)アクリル酸エチル、ポリ(メタ)アクリル酸ブチル等のアクリル樹脂、塩素化ポリプロピレン等の塩素化ポリオレフィン樹脂、塩化ビニル樹脂、酢酸ビニル樹脂、塩化ビニル−酢酸ビニル共重合体、ポリビニルブチラール等のビニル重合体、ポリイソプレンゴム、ポリイソブチルゴム、スチレンブタジエンゴム、ブタジエンアクリロニトリルゴム等のゴム系樹脂、ポリアミド樹脂等の熱可塑性樹脂等の1種又は2種以上の混合物が用いられる。また、熱硬化性樹脂では、ウレタン樹脂、エポキシ樹脂等が用いられる。   (Adhesive layer) In order to improve the adhesion to the injection resin, an adhesive layer such as a corona discharge treatment or various known primer coatings or a heat-sensitive adhesive layer may be applied to the back surface of the sheet with a picture. . For the adhesive layer, a known resin such as a thermoplastic resin or a thermosetting resin is used. For example, for thermoplastic resins, styrene resins or styrene copolymers such as polystyrene and poly-α-methylstyrene, acrylics such as poly (meth) methyl acrylate, poly (meth) ethyl acrylate, poly (meth) butyl acrylate, etc. Resin, chlorinated polyolefin resin such as chlorinated polypropylene, vinyl chloride resin, vinyl acetate resin, vinyl chloride-vinyl acetate copolymer, vinyl polymer such as polyvinyl butyral, polyisoprene rubber, polyisobutyl rubber, styrene butadiene rubber, butadiene One type or a mixture of two or more types such as a rubber-based resin such as acrylonitrile rubber and a thermoplastic resin such as polyamide resin is used. In the thermosetting resin, a urethane resin, an epoxy resin, or the like is used.

〔その他〕なお、本発明でいう「絵付け」とは、単に絵柄や文字、図形等の目視可能な模様を成形品に付与する以外に、目視不可能な模様、あるいは硬質塗膜、導電性等の機能性層を付与することも包含する。目視可能な模様としては、印刷等により形成した絵柄層、真空蒸着等により形成した金属薄膜層など公知のものが、目視不可能な模様の例としては可視光に対しては透明で紫外線照射で蛍光を発する蛍光インクの絵柄が用いられる。   [Others] “Painting” as used in the present invention refers to an invisible pattern, a hard coating film, or a conductive film, other than simply providing a visible pattern such as a pattern, character, or figure to a molded product. It also includes providing a functional layer such as. As a visible pattern, known patterns such as a pattern layer formed by printing, a metal thin film layer formed by vacuum deposition, etc. are examples of patterns that are not visible. A fluorescent ink pattern that emits fluorescence is used.

次に、実施例及び比較例により本発明を更に詳述する。   Next, the present invention will be described in more detail with reference to examples and comparative examples.

本発明の射出成形型として、自動車のコンソールボックス用の成形品を成形する金型を用意した。絵付け成形品の寸法は、正面が横200mm、縦500mmの長方形で、肉厚は平均3mm、絵付シートの絞り深さが最大40mmである。ゲートは、図1(B)の如く、成形品1の裏面に有るリブ7の先端にゲード3を設けた。リブ7の幅は0.7mmで、ゲートは直径2.5mmのピンポイントゲートとした。   As the injection mold of the present invention, a mold for molding a molded product for a console box of an automobile was prepared. The size of the picture-molded product is a rectangle with a front of 200 mm in width and a length of 500 mm, an average thickness of 3 mm, and a drawing sheet with a maximum drawing depth of 40 mm. As shown in FIG. 1B, the gate is provided with a gade 3 at the tip of the rib 7 on the back surface of the molded product 1. The rib 7 had a width of 0.7 mm and the gate was a pinpoint gate having a diameter of 2.5 mm.

一方、絵付シートには、厚み125μmの透明なアクリル樹脂フィルムからなる基材シートの裏側となる面(成形品側)に、アクリル樹脂と塩化ビニル−酢酸ビニル共重合体との混合樹脂系をバインダーの樹脂とし、弁柄を主体とする着色顔料が添加されている着色インキを用いて、木目柄の意匠の絵柄層をグラビア印刷の三色刷りで形成した上に、更に、塩化ビニル−酢酸ビニル共重合体からなる接着剤層(4μm厚)をグラビアコートによる2層コートで形成して、用意した。   On the other hand, for a sheet with a picture, a mixed resin system of an acrylic resin and a vinyl chloride-vinyl acetate copolymer is bonded to the back surface (molded product side) of a base sheet made of a transparent acrylic resin film having a thickness of 125 μm. The pattern layer of the wood grain design is formed by gravure printing using a colored ink containing a colored pigment mainly composed of a petal, and further combined with vinyl chloride-vinyl acetate. An adhesive layer (4 μm thick) made of a polymer was formed by two-layer coating by gravure coating and prepared.

そして、上記絵付シートを用いて、図2の概念図で説明した様にして射出成形同時絵付けを行い、絵付シートがラミネ−トされた絵付け成形品を製造してみた。先ず、絵付シートをその絵柄層が雄金型のゲート側を向く様にして、型開き状態の雌雄両金型間に供給した後、表面温度350℃に加熱した赤外線輻射加熱方式の熱盤を型間に挿入して、絵付シートを非接触で3秒間加熱した後、雌型を真空成形型として、真空引きを開始して真空成形による絵付シートの予備成形を行い、軟化した絵付シートを雌型のキャビティ面に沿う形状に成形した。その後、真空引き開始5秒後に、熱盤を型外の退避位置に退避させて、両型を型締めした。次いで、耐熱ABS樹脂を、樹脂温度240℃、金型温度60℃の条件で、両型で形成されるキャビティ内に射出した。そして、樹脂が冷却し固化後、型開きして、絵付け成形品を得た。   Then, by using the above-mentioned picture sheet, simultaneous injection painting was performed as described in the conceptual diagram of FIG. 2, and a picture-molded article in which the picture sheet was laminated was manufactured. First, after supplying the sheet with a picture between the male and female molds with the pattern layer facing the gate side of the male mold, an infrared radiation heating type heating plate heated to a surface temperature of 350 ° C. Insert between the molds and heat the picture sheet for 3 seconds without contact, then use the female mold as a vacuum mold and start vacuuming to pre-form the picture sheet by vacuum forming. Molded into a shape along the cavity surface of the mold. Thereafter, 5 seconds after the start of evacuation, the hot platen was retracted to the retracted position outside the mold, and both molds were clamped. Next, the heat-resistant ABS resin was injected into a cavity formed by both molds under the conditions of a resin temperature of 240 ° C. and a mold temperature of 60 ° C. Then, after the resin was cooled and solidified, the mold was opened to obtain a painted product.

その結果、成形品の表側には、ヒケ発生は認められなかった。また、絵付シートは射出時の樹脂の熱にも耐え、基材シート、絵柄層ともに、破断、流動、を生じ無かった。また、リブにゲートがある為に、射出樹脂圧が低くても、(リブに樹脂が充填されない)ショートショットにならない為に、バリが発生しない安定した射出成形同時絵付けが出来た。   As a result, no sink marks were observed on the front side of the molded product. Further, the picture sheet withstood the heat of the resin at the time of injection, and neither the base sheet nor the pattern layer was broken or flowed. In addition, since there is a gate on the rib, even if the injection resin pressure is low, a short shot (not filled with resin in the rib) does not result in a short shot, so that stable injection molding simultaneous painting with no burr has been achieved.

[比較例]
実施例において用いた金型に対して、ゲートの位置は、図3の如く、成形品1の裏面に直接、ゲード3を設けた。ゲートは直径2.5mmのピンポイントゲートとした。但し、成形品の裏面のゲート3の周囲は、直径10mmの円形状に肉厚を3mmから4mmに1mm増やした肉厚部4を設けた。この他は、実施例同様にして、射出成形同時絵付けして、絵付け成形品を得た。
[Comparative example]
With respect to the mold used in the example, the gate is provided with the gad 3 directly on the back surface of the molded product 1 as shown in FIG. The gate was a pinpoint gate with a diameter of 2.5 mm. However, the periphery of the gate 3 on the back surface of the molded product was provided with a thick portion 4 having a circular shape with a diameter of 10 mm and a thickness increased from 3 mm to 4 mm by 1 mm. Other than this, in the same manner as in the example, painting by injection molding was performed to obtain a painted product.

その結果、絵付シートは射出時の樹脂の熱にも耐えたが、図3に示す如く、成形品1の表側には、ゲート3の部分にヒケ5が発生していた。そして、ヒケを直す為に、射出樹脂圧を上げて成形し直してみたが、成形品周囲にバリが発生してしまった。   As a result, the picture sheet withstood the heat of the resin at the time of injection, but as shown in FIG. 3, sink marks 5 occurred in the gate 3 portion on the front side of the molded product 1. Then, in order to correct the sink, the injection resin pressure was increased and re-molding was performed, but burr was generated around the molded product.

本発明の射出成形型と従来の射出成形型を成形品形状で概念的に説明する説明図。Explanatory drawing which illustrates notionally the injection mold of this invention and the conventional injection mold by the shape of a molded article. 射出成形同時絵付方法を或る一例で説明する概念図。The conceptual diagram explaining the injection molding simultaneous painting method by a certain example. 従来の射出成形型の他の例を成形品形状で概念的に説明する説明図。Explanatory drawing which illustrates notionally other examples of the conventional injection molding die by a molded article shape.

符号の説明Explanation of symbols

1 成形品
2 ランナー
3 ゲート
4 肉厚部
5 ヒケ
6 ボス
7 リブ
41 吸引孔
42 シートクランプ
Ma 射出成形型(雄型)
Mb 射出成形型(雌型)
PL パーティングライン
S 絵付シート
DESCRIPTION OF SYMBOLS 1 Molded product 2 Runner 3 Gate 4 Thick part 5 Sinking 6 Boss 7 Rib 41 Suction hole 42 Sheet clamp Ma Injection mold (male mold)
Mb injection mold (female)
PL parting line S sheet with picture

Claims (1)

絵付シートを射出成形の雌雄両型間に供給した後、両型を型締めして、流動状態の樹脂を両型で形成されるキャビティに射出して、絵付け成形品を製造する射出成形同時絵付方法に使用する型において、樹脂のキャビティ内への注入孔であるゲートが、成形品裏側のリブに設けられている射出成形型。 At the same time of injection molding, a picture sheet is supplied between both male and female molds for injection molding, and then both molds are clamped to inject a fluid resin into a cavity formed by both molds. An injection mold in which a gate, which is an injection hole into a resin cavity, is provided on a rib on the back side of a molded product in a mold used for a painting method.
JP2007316212A 2007-12-06 2007-12-06 Injection molding mold Pending JP2008068633A (en)

Priority Applications (1)

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Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2007316212A JP2008068633A (en) 2007-12-06 2007-12-06 Injection molding mold

Related Parent Applications (1)

Application Number Title Priority Date Filing Date
JP28904398A Division JP4139487B2 (en) 1998-10-12 1998-10-12 Manufacturing method of painted products

Publications (1)

Publication Number Publication Date
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Application Number Title Priority Date Filing Date
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Country Link
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009285893A (en) * 2008-05-27 2009-12-10 Suzuki Motor Corp Injection molding method and injection molding die
JP2011005743A (en) * 2009-06-25 2011-01-13 Suzuki Motor Corp Injection mold and method of producing injection molding
JP2013155881A (en) * 2013-05-20 2013-08-15 Ntn Corp Sensor cap for wheel bearing device with rotating speed detection device, wheel bearing device with rotating speed detection device having the same, and method of manufacturing sensor cap for wheel bearing device with rotating speed detection device

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04316814A (en) * 1991-04-16 1992-11-09 Dainippon Printing Co Ltd Simultaneously injecting and foil-decorating device and method thereof
JPH04344213A (en) * 1991-05-22 1992-11-30 Dainippon Printing Co Ltd In-mold injection patterning apparatus
JPH0577271A (en) * 1991-04-16 1993-03-30 Dainippon Printing Co Ltd In-mold injecton simultaneous decorating device and injection simultaneous decorating method
JP2000043097A (en) * 1998-07-30 2000-02-15 Nissha Printing Co Ltd Manufacture of overlaid in-mold molding

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04316814A (en) * 1991-04-16 1992-11-09 Dainippon Printing Co Ltd Simultaneously injecting and foil-decorating device and method thereof
JPH0577271A (en) * 1991-04-16 1993-03-30 Dainippon Printing Co Ltd In-mold injecton simultaneous decorating device and injection simultaneous decorating method
JPH04344213A (en) * 1991-05-22 1992-11-30 Dainippon Printing Co Ltd In-mold injection patterning apparatus
JP2000043097A (en) * 1998-07-30 2000-02-15 Nissha Printing Co Ltd Manufacture of overlaid in-mold molding

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009285893A (en) * 2008-05-27 2009-12-10 Suzuki Motor Corp Injection molding method and injection molding die
JP2011005743A (en) * 2009-06-25 2011-01-13 Suzuki Motor Corp Injection mold and method of producing injection molding
JP2013155881A (en) * 2013-05-20 2013-08-15 Ntn Corp Sensor cap for wheel bearing device with rotating speed detection device, wheel bearing device with rotating speed detection device having the same, and method of manufacturing sensor cap for wheel bearing device with rotating speed detection device

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