JP2000117782A - Mold for foil decorating simultaneously with injection molding - Google Patents

Mold for foil decorating simultaneously with injection molding

Info

Publication number
JP2000117782A
JP2000117782A JP29629998A JP29629998A JP2000117782A JP 2000117782 A JP2000117782 A JP 2000117782A JP 29629998 A JP29629998 A JP 29629998A JP 29629998 A JP29629998 A JP 29629998A JP 2000117782 A JP2000117782 A JP 2000117782A
Authority
JP
Japan
Prior art keywords
mold
resin
sheet
porous material
painting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29629998A
Other languages
Japanese (ja)
Inventor
Hiroyuki Atake
浩之 阿竹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dai Nippon Printing Co Ltd
Original Assignee
Dai Nippon Printing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dai Nippon Printing Co Ltd filed Critical Dai Nippon Printing Co Ltd
Priority to JP29629998A priority Critical patent/JP2000117782A/en
Publication of JP2000117782A publication Critical patent/JP2000117782A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/14Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor incorporating preformed parts or layers, e.g. injection moulding around inserts or for coating articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C45/00Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
    • B29C45/17Component parts, details or accessories; Auxiliary operations
    • B29C45/26Moulds
    • B29C45/34Moulds having venting means
    • B29C45/345Moulds having venting means using a porous mould wall or a part thereof, e.g. made of sintered metal

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Injection Moulding Of Plastics Or The Like (AREA)
  • Moulds For Moulding Plastics Or The Like (AREA)

Abstract

PROBLEM TO BE SOLVED: To easily escape a gas by forming the entirety or a part of the cavity face of the side opposite to the side with which a decorated sheet comes into contact, of a porous material, on the cavity face. SOLUTION: The half, corresponding to the first surface, of a mold is a female half Mb with a recessed part, and a decorated sheet S is a mold on the side where a decorated sheet S comes into contact with a cavity face 1. On the other hand, another half on the opposite side, of the mold is a male half Ma with a projecting part, and a part of the cavity face 1 is formed of a porous material 2. This part is a part including a final resin filling position and the porous material 2 is embedded in the male half Ma in such a manner that a part of the material 2 forms the cavity face 1. In addition, when the resin is injected through a gate G, a gas inside the cavity is allowed to escape to the outside through the porous material 2. The area and depth of the cavity face 1 formed with the porous material 2 are properly decided. Thus it is possible to allow an easy escape of the gas from the cavity during injecting the resin and prevent the imperfect gas escape from occurring.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、射出成形同時絵付
用型に関する。特に、射出時にキャビティ内のガスを逃
がし易い型に関する。
The present invention relates to a mold for simultaneous painting with injection molding. In particular, the present invention relates to a mold in which gas in a cavity is easily released at the time of injection.

【0002】[0002]

【従来の技術】従来より、射出成形同時絵付方法によっ
て、成形と同時に樹脂成形物の表面に装飾等が施された
絵付シートを一体化して、絵付け成形品とする事が各種
の態様で行われている。例えば、特公昭50−1913
2号公報では、真空成形用の通気孔を設けた雌型を利用
して熱可塑性樹脂よりなる絵付シートを真空成形した
後、雌雄両型を型締めし、溶融樹脂を両型で形成される
キャビティに射出して、射出成形と同時に樹脂成形物の
外表面に絵付シートを一体化させる方法が開示されてい
る。この態様の射出成形同時絵付方法では真空成形と射
出成形とを組合わせた方法であり、複雑な曲面形状に模
様付けができる。なお、絵付シートには、ラミネートタ
イプと転写タイプとがあり、前者では絵付シート自体を
樹脂成形物に積層させて絵付けし、後者では絵付シート
の基材シートのみを剥離してその転写層を樹脂成形物に
転写させて絵付けする。
2. Description of the Related Art Conventionally, in accordance with an injection molding simultaneous painting method, a painting sheet having a decoration or the like applied to the surface of a resin molded product is integrally formed at the same time as molding to form a painting molded product in various forms. Have been done. For example, Japanese Patent Publication No. 50-1913
In Japanese Patent Application Publication No. 2 (1993) -1995, a painted sheet made of a thermoplastic resin is vacuum-formed using a female mold provided with air holes for vacuum molding, and then the male and female molds are clamped to form a molten resin in both molds. There is disclosed a method of injecting into a cavity and integrating a painting sheet with the outer surface of a resin molded product simultaneously with injection molding. The simultaneous injection molding painting method of this aspect is a method in which vacuum molding and injection molding are combined, and a complicated curved surface can be patterned. Note that there are two types of painted sheets: a laminate type and a transfer type.In the former, the painted sheet itself is laminated on a resin molded product and painted, and in the latter, only the base sheet of the painted sheet is peeled off and the transfer layer is formed. It is transferred to a resin molding and painted.

【0003】そして、絵付シートを使用しない通常の射
出成形型では、キャビティ内のガスは、絵付け成形品裏
側面に対応するキャビティ面に設けたエジェクターピン
周囲の隙間等から逃がしたり、ガスが残り易い位置にイ
ンサートブロックを設けて、その周囲隙間から逃がした
りする様に、エアベントを設ける位置を工夫している。
しかし、射出成形同時絵付用型の場合は、通常の射出成
形同時絵付方法の形態では、雌型・雄型間に供給された
絵付シートは、射出成形同時絵付用型を真空成形型と兼
用して真空成形して、一方の型(通常は雌型)のキャビ
ティ面に沿った状態で、射出成形する事になる。この
為、絵付シートを沿わせ接触させる側のキャビティ面に
ついては、ガスを逃がす為のエアベントを設けることが
できない。そこで、射出成形同時絵付用型の場合は、絵
付シートを接触させないキャビティ面を有する他方の型
(通常は雄型)や、パーティング面をエアベントに利用
する等の工夫をしてきた。また、型温を雌型よりも雄型
の方を高めに設定して樹脂の流れを制御し、パーティン
グ面からガスが逃げきる時間的余裕を持たせる様にする
場合もあった。
[0003] In a normal injection molding die that does not use a painting sheet, gas in the cavity escapes from a gap around an ejector pin provided on the cavity surface corresponding to the back side surface of the painting product, and gas remains. The position of the air vent is devised so that the insert block is provided at an easy position and escapes from the surrounding gap.
However, in the case of the injection molding simultaneous painting mold, in the form of the normal injection molding simultaneous painting method, the painting sheet supplied between the female mold and the male mold uses the injection molding simultaneous painting mold as the vacuum molding mold. And then injection-molded along the cavity surface of one mold (usually a female mold). For this reason, it is not possible to provide an air vent for allowing gas to escape on the cavity surface on the side along which the painted sheet is brought into contact. Therefore, in the case of the mold for simultaneous painting with injection molding, the other mold (usually a male mold) having a cavity surface which does not allow the painting sheet to come into contact, and the use of a parting surface as an air vent have been devised. In some cases, the mold temperature is set higher in the male mold than in the female mold to control the flow of the resin so as to allow time for the gas to escape from the parting surface.

【0004】図2は、従来の射出成形同時絵付用型に於
いて、エアベントが不完全の場合に発生し易いガス溜ま
り3を、概念的に示す断面図である。そして、図3はガ
ス溜まり3の部分の要部拡大断面図である。図3は、ガ
ス溜まり3が絵付シートSに接した位置に発生した場合
である。この様な場合、ガス溜まりによって起きる樹脂
の未充填で、図4の断面図に示す如く、得られる絵付け
成形品Pに於いては、射出され固化した樹脂成形物5の
一部に欠損部4が生じる。この為、欠損部4の部分で
は、絵付シートが樹脂成形物5にラミネートされ一体化
するラミネートシートの場合では、絵付シートSが樹脂
成形物5に密着していない、密着不良が発生する。ま
た、絵付シートが転写シートの場合では、樹脂成形物に
転写移行する転写層が、欠損部4で樹脂成形物に密着し
ていない為、密着不良に起因する転写不良が発生する事
になる。密着不良部分では、加熱軟化した絵付シート
が、空洞(欠損部4)側に膨らんだり、樹脂の流れによ
って位置ずれして皺が寄ったりする事もある。これらの
結果、絵付け不良となる。
FIG. 2 is a cross-sectional view conceptually showing a gas reservoir 3 which is likely to be generated when the air vent is incomplete in a conventional injection molding and simultaneous painting mold. FIG. 3 is an enlarged sectional view of a main part of the gas reservoir 3. FIG. 3 shows a case where the gas reservoir 3 is generated at a position in contact with the painting sheet S. In such a case, as shown in the cross-sectional view of FIG. 4, in the unpainted resin P caused by the gas pool, in the obtained painted molded product P, a defective portion is formed in a part of the injected and solidified resin molded product 5. 4 results. For this reason, in the case of the laminated sheet in which the painted sheet is laminated and integrated with the resin molded product 5 in the defective portion 4, the painted sheet S does not adhere to the resin molded product 5, and poor adhesion occurs. Further, when the painting sheet is a transfer sheet, the transfer layer that transfers to the resin molded product is not in close contact with the resin molded product at the defective portion 4, so that a transfer failure due to poor adhesion occurs. In the poor adhesion portion, the heat-softened painting sheet may swell toward the cavity (deficient portion 4), or may be displaced and wrinkled by the flow of the resin. As a result, poor painting results.

【0005】[0005]

【発明が解決しようとする課題】以上の様に、射出成形
同時絵付用型の場合では通常の射出成形型に比べてエア
ベントは工夫する必要があった。そして、パーティング
面をエアベントに利用する場合でも、絵付シートは通常
パーティング面に対して固定する為に、(型よりは柔軟
な)絵付シートとパーティング面が接する事によって、
パーティング面からガスを逃がす事も、通常の射出成形
型に比べると容易ではなかった。そこで、型締め力を下
げて当たりを少し弱くしたり、最終充填位置近くのパー
ティング面を他の部分に比べて10〜50μm程度削っ
たりして、ガスを逃がし易くする事もできるが、今度は
樹脂のバリが発生し易くなるという問題があった。一
方、雌雄両型の型温度差で樹脂の流れを制御する方法で
は、安定的に制御する事が非常に難しかった。
As described above, in the case of the mold for simultaneous painting with injection molding, it is necessary to devise an air vent in comparison with a normal injection molding die. And even if the parting surface is used for air venting, the painted sheet is usually fixed to the parting surface.
It was not easy to release gas from the parting surface as compared with a normal injection mold. Therefore, it is possible to lower the mold clamping force to slightly reduce the contact, or to cut the parting surface near the final filling position by about 10 to 50 μm compared to other parts to make it easier for gas to escape. Has a problem that resin burrs are easily generated. On the other hand, it is very difficult to stably control the resin flow by controlling the flow of the resin based on the temperature difference between the male and female molds.

【0006】そこで、本発明の目的は、通常の射出成形
型に比べて、ガスを逃がし難い射出成形同時絵付用型に
於いて、ガスを逃がし易くした型を提供する事である。
Accordingly, an object of the present invention is to provide a mold for simultaneous injection molding and painting, in which gas is less likely to escape than a normal injection molding die, in which gas is easily escaped.

【0007】[0007]

【課題を解決するための手段】そこで、上記課題を解決
すべく、本発明の射出成形同時絵付用型では、絵付シー
トを一対の型の間に挿入した後、両型を型締めし、両型
で形成されるキャビティに流動状態の樹脂を射出し、成
形と同時に絵付シートと樹脂成形物とを一体化させて、
絵付け成形品を得る射出成形同時絵付方法に使用する型
において、キャビティ面に絵付シートが接する側の型と
は反対側の型のキャビティ面が、その全面又は一部が多
孔質材で形成されている構成の型とした。その結果、多
孔質材によって、樹脂射出時のキャビティ内のガスが逃
がし易くなってるので、ガス逃げ不良を防げる。従っ
て、ガス溜りが発生せず、樹脂成形物の欠損部発生や、
ガス溜まり部分で絵付シートが樹脂成形物に密着しない
為に起きる、絵付シートの密着不良(ラミネートシート
の場合)や、転写層の密着(転写)不良(転写シートの
場合)等の絵付けが一部で成されない絵付け不良による
製品欠陥を防げる。
Therefore, in order to solve the above problems, in the injection molding simultaneous painting mold of the present invention, after inserting a painting sheet between a pair of molds, both molds are clamped, and both molds are clamped. Inject the resin in the fluid state into the cavity formed by the mold, and integrate the painted sheet and the resin molding at the same time as molding,
In the mold used for the simultaneous injection molding and painting method for obtaining a painted molded product, the cavity surface of the mold opposite to the mold on which the painting sheet is in contact with the cavity surface is entirely or partially formed of a porous material. Type of configuration. As a result, the gas in the cavity at the time of resin injection is easily released by the porous material, so that a defective gas escape can be prevented. Therefore, gas accumulation does not occur, generation of a defective portion of the resin molded product,
Painting, such as poor adhesion of the painted sheet (in the case of a laminate sheet) or poor adhesion (transfer) of the transfer layer (in the case of a transfer sheet), which occurs because the painted sheet does not adhere to the resin molded product in the gas reservoir part. Prevents product defects due to poor painting that is not achieved in the department.

【0008】なお、キャビティ面内に於いて多孔質材が
形成されている位置は、樹脂の最終充填位置、ウェルド
ラインの発生位置のいずれか片方、又は両方とすると良
い。この様にすると、効率的にキャビティ内のガスを逃
がせる。それは、これらの部分がキャビティ内での樹脂
の流れの下流側に相当するからである。
The position where the porous material is formed in the cavity surface may be one or both of the final filling position of the resin and the position where the weld line is generated. This allows the gas in the cavity to escape efficiently. This is because these portions correspond to the downstream side of the flow of the resin in the cavity.

【0009】[0009]

【発明の実施の形態】以下、図面を参照しながら本発明
の実施の形態を説明する。
Embodiments of the present invention will be described below with reference to the drawings.

【0010】〔射出成形同時絵付用型〕先ず、一般的
に、射出成形同時絵付用型は、通常の形態の射出成形同
時絵付方法の形態に於いて使用する型の場合には、絵付
け成形品の絵付けされた面が表側面となり、該表側面に
対応する方の型が凹部を有する雌型(キャビティ型)
で、該雌型が絵付シートがキャビティ面に接する側の型
であり、その反対側の型は凸部を有する雄型(コア型)
となる。そして、通常は雄型側から樹脂を射出する。但
し、逆に、絵付け成形品の表側面に対応する方が、凸を
有する雄型の場合もあり得る。従って、絵付シートがキ
ャビティ面に接する側の型は、必ずしも雌型とは限らな
い。しかし、以下の説明では、便宜上その型が雌型であ
ると仮定して説明する。
[Injection Mold Simultaneous Painting Mold] First, in general, the injection molding simultaneous painting mold is a mold used in the normal injection molding simultaneous painting method. The painted side of the product is the front side, and the mold corresponding to the front side has a recessed female mold (cavity mold)
The female mold is a mold on the side where the painted sheet is in contact with the cavity surface, and the mold on the opposite side is a male mold (core mold) having a convex portion.
Becomes Then, the resin is usually injected from the male mold side. However, conversely, there may be a case where the side corresponding to the front side of the painted molded product is a male type having a protrusion. Therefore, the mold on the side where the painted sheet contacts the cavity surface is not necessarily a female mold. However, in the following description, it is assumed for convenience that the type is a female type.

【0011】先ず、図1(A)は、或る絵付け成形品P
の外形形状とゲートGとの関係を示す平面図である。そ
して、図1(B)は、図1(A)の絵付け成形品Pに対
して、多孔質材でキャビティ面が形成されている位置を
含むX−X線を切断線とした時の、樹脂充填完了後に於
ける断面図である。そして、図1(B)の場合では、型
Ma(雄型に相当)のキャビティ面1の一部が多孔質材
2で形成してある。多孔質材2で形成されているキャビ
ティ面の部分は、樹脂の最終充填位置を含む部分であ
る。多孔質材2は型Maにその一部がキャビティ面を成
す様に埋め込んである。一方、型Mb(雌型に相当)は
絵付シートSがキャビティ面に沿う様に接する側の型で
ある。この様に多孔質材2で絵付シートSがキャビティ
面に接しない側の型の該キャビティ面1を形成すれば、
ゲートGから樹脂が射出される時に、キャビティ内のガ
スは、多孔質材2を通して、外部に逃がす事ができる
(図面の多孔質材2内の矢印参照)。
First, FIG. 1A shows a certain painted molded product P.
FIG. 4 is a plan view showing the relationship between the external shape of the device and the gate G. FIG. 1B shows a case where the X-X line including the position where the cavity surface is formed by the porous material is taken as a cutting line with respect to the decorative molded product P of FIG. 1A. It is sectional drawing after completion of resin filling. In the case of FIG. 1B, a part of the cavity surface 1 of the mold Ma (corresponding to a male mold) is formed of the porous material 2. The portion of the cavity surface formed of the porous material 2 is a portion including the final filling position of the resin. The porous material 2 is embedded in a mold Ma so that a part thereof forms a cavity surface. On the other hand, the mold Mb (corresponding to a female mold) is a mold on the side where the painted sheet S contacts along the cavity surface. In this way, if the cavity surface 1 of the mold on the side where the painting sheet S does not contact the cavity surface is formed by the porous material 2,
When the resin is injected from the gate G, the gas in the cavity can escape to the outside through the porous material 2 (see the arrow in the porous material 2 in the drawing).

【0012】多孔質材が成すキャビティ面の広さ、及び
多孔質材のキャビティ面からの深さは、適宜決めれは良
い。図1は概念図であり、その大きさ(広さ、深さ)は
あくまでも概念的に描いてある。また、図1(B)の如
く、多孔質材が成す面をキャビティ面からパーティング
面にまで延長しておいても良い。この様にすれば、多孔
質材で形成する位置を、樹脂の最終充填位置に厳密に位
置合わせする必要が無く、型の設計が容易となる。
The width of the cavity surface formed by the porous material and the depth of the porous material from the cavity surface may be appropriately determined. FIG. 1 is a conceptual diagram, and the size (width, depth) is conceptually drawn to the last. Further, as shown in FIG. 1B, the surface formed by the porous material may be extended from the cavity surface to the parting surface. In this case, it is not necessary to precisely align the position formed of the porous material with the final filling position of the resin, and the design of the mold is facilitated.

【0013】また、通常は、キャビティ面のうち多孔質
材で形成する部分は、樹脂の最終充填位置を含む部分に
設けるのが好ましい。従って、多孔質材の位置は、図1
(A)で示す略楕円形状の絵付け成形品Mに対して、そ
の中央にゲートGが1点有る場合では、成形品の外周部
分のうち、楕円の長軸方向となるX−X線と交わる部分
が最終充填位置となるので、少なくともその部分を含む
様な位置に設ければ良い。また、多孔質材で形成するキ
ャビティ面の位置は、通常は、図1(B)の如く、雄型
となる側の型Mbでガスが溜まり易い型Ma及び型Mb
の両型が接するパーティングライン付近に設ける。ま
た、多孔質材の位置は、ウェルドラインの発生位置とす
るのも好ましい。ウェルドラインは、キャビティを流れ
る樹脂の合流点である為に、該樹脂で押しやられたガス
が集まって来る部分であり、そこで円滑に逃がしながら
樹脂を充填して行く事が完全にできれば、最終充填位置
ではもはや溜まり得るガスを無くする事もできるからで
ある。もちろん、最後に多少ガスが残るならば、ウェル
ドランイと共に最終充填位置も多孔質材でキャビティ面
を形成するが好ましい。なお、もちろんだが、雄型のキ
ャビティ面全面を多孔質材で形成しても良い。但し、キ
ャビティ面の一部分に設ける事で所望のエアベント性能
を満足すれば、それで十分である。
Usually, it is preferable to provide the portion of the cavity surface formed of the porous material in a portion including the final filling position of the resin. Therefore, the position of the porous material is shown in FIG.
In the case where there is one gate G at the center of the substantially elliptical shaped molded product M shown in (A), in the outer peripheral portion of the molded product, there is an X-X line that is in the major axis direction of the ellipse. Since the intersecting portion is the final filling position, it may be provided at a position including at least that portion. The position of the cavity surface formed of the porous material is usually determined by the mold Ma and the mold Mb in which gas easily accumulates in the mold Mb on the male mold side as shown in FIG.
It is provided near the parting line where both types contact. It is also preferable that the position of the porous material is a position where a weld line is generated. Since the weld line is the junction of the resin flowing through the cavity, the gas that has been pushed away by the resin comes together.If it is possible to completely fill the resin while allowing it to escape smoothly, the final filling This is because it is possible to eliminate gas that can accumulate at the position. Of course, if some gas remains at the end, it is preferable to form the cavity surface with a porous material at the final filling position together with the weld run. Of course, the entire cavity surface of the male mold may be formed of a porous material. However, it is sufficient if the desired air vent performance is satisfied by providing a part of the cavity surface.

【0014】なお、多孔質材のキャビティ面を成す面か
ら多孔質材の内部に入ったガスは、多孔質材の側面や底
面から型外部に逃がせば良い。この為には、多孔質材の
側面や底面は、型の側面や底面にまで延長して露出させ
ても良いが、型の機械的強度等の点では、必要部のみに
多孔質材を使用した方が良い。この為には、埋め込まれ
た多孔質材の側面や底面に、型外に通じる通路をエアベ
ントとして接続すれば良い(不図示)。但し、このエア
ベントは射出樹脂が接触する訳では無い為、間隙は広く
ても良い。或いは、更にエアベントに真空ポンプを接続
して、強制的にガスを排気するようにしても良い。
The gas that has entered the inside of the porous material from the surface forming the cavity surface of the porous material may escape from the side or bottom surface of the porous material to the outside of the mold. For this purpose, the side and bottom of the porous material may be extended to the side and bottom of the mold and exposed, but in terms of the mechanical strength of the mold, etc., the porous material is used only for the necessary parts. It is better to do. For this purpose, a passage leading to the outside of the mold may be connected to the side or bottom surface of the embedded porous material as an air vent (not shown). However, since the air vent does not come into contact with the injection resin, the gap may be wide. Alternatively, a vacuum pump may be further connected to the air vent to forcibly exhaust the gas.

【0015】多孔質材としては、通気性、機械的強度、
耐熱性等を備えた材料であれば、特に限定はない。ま
た、そのキャビティ面を成す面は、射出樹脂が内部まで
に進入し固化しない程度の大きさの通気孔が開口する面
であれば良い。多孔質材に接した樹脂成形物に多孔質の
跡が粗面として賦形される場合が生じるが、通常その部
分は、目に触れないか、或いは目に触れても意匠上問題
が無い部分であることが殆どなので、支障は来さない。
この様な多孔質材は、例えば鉄、ニッケル等からなる。
多孔質材は、それら金属から多孔質電鋳法、粉体焼結法
等の公知の方法で多孔質化した物で良い。或いは、多孔
質セラミックス等でも良い。
As the porous material, air permeability, mechanical strength,
There is no particular limitation as long as the material has heat resistance and the like. In addition, the surface forming the cavity surface may be any surface as long as a vent hole large enough to prevent the injected resin from entering the interior and solidifying is opened. In some cases, a mark of the porous material is formed as a rough surface on the resin molded product in contact with the porous material, but the portion is usually invisible or has no problem in design even if touched. This is almost no problem, so there is no problem.
Such a porous material is made of, for example, iron, nickel, or the like.
The porous material may be a material obtained by making the metal porous by a known method such as a porous electroforming method or a powder sintering method. Alternatively, porous ceramics or the like may be used.

【0016】例えば、多孔質電鋳法は、特開昭60−1
52692号公報等に開示の如く、メッキ皮膜を多孔質
層として得る方法である。ちなみに、特開昭60−15
2692号公報で開示する方法は、通常の電鋳法が、メ
ッキ皮膜中にピンホールが生じるのを防止する目的で、
メッキ液中にラウリル硫酸ナトリウム等の界面活性剤を
添加するのに対して、界面活性剤を添加せずにメッキす
る事でピンホールを積極的に発生させて、メッキ皮膜を
多孔質とする方法である。
For example, a porous electroforming method is disclosed in
This is a method of obtaining a plating film as a porous layer as disclosed in Japanese Patent No. 52692. Incidentally, JP-A-60-15
No. 2692 discloses a method disclosed in Japanese Patent Application Laid-Open No. HEI 6-92, for the purpose of preventing the occurrence of pinholes in a plating film by a normal electroforming method.
A method of adding a surfactant such as sodium lauryl sulfate to the plating solution, while positively generating pinholes by plating without adding a surfactant to make the plating film porous. It is.

【0017】また、多孔質セラミックスとしは、好まし
くは、特公平7−102588号公報の如く、孔径が5
0〜150μmの範囲に分布し、透気度で3〜25m3
/cm2 ・sである物が良い。この様な多孔質セラミッ
クスとしては、例えば、セラミックスの粉末に対して金
属の粉末及び繊維、またはこれらの一方を混合して焼結
した物等を使用できる。具体的には、新東工業株式会社
から販売されている商品名「ポーセラックス」等が使用
できる。透気度は大きくなるとガスの通りは良くなるが
機械的強度が低下し、また透気度が小さくなると機械的
強度は良くなるが、ガスの通りが悪くなる。また、孔径
は、成形物の要求される表面(通常は成形品の裏面を成
す面となるが)品質にもよるが、大きくなると射出樹脂
が多孔質材内部まで進入し、小さすぎるとガスの通りが
悪くなる。
The porous ceramic preferably has a pore size of 5 as disclosed in JP-B-7-102588.
It is distributed in the range of 0 to 150 μm and has an air permeability of 3 to 25 m 3.
/ Cm 2 · s is good. As such a porous ceramic, for example, a metal powder and a fiber with respect to a ceramic powder, or a material obtained by mixing and sintering one of them can be used. Specifically, a product name “Porcelax” sold by Shinto Kogyo Co., Ltd. can be used. The higher the air permeability, the better the gas flow, but the lower the mechanical strength. The lower the air permeability, the better the mechanical strength, but the worse the gas flow. The pore size depends on the quality of the surface required of the molded product (usually the surface that forms the back surface of the molded product). The street gets worse.

【0018】なお、射出成形同時絵付用型の多孔質材以
外の部分の材料は、従来公知の材料で良い。例えば、鉄
や鉄合金等の金属又は金属合金、或いはセラミックス等
の非金属材料でも良い。
The material of the part other than the porous material of the mold for simultaneous painting with injection molding may be a conventionally known material. For example, a metal or metal alloy such as iron or iron alloy, or a non-metallic material such as ceramics may be used.

【0019】なお、本発明の射出成形同時絵付用型で
は、エアベントとして多孔質材でキャビティ面の少なく
とも一部を形成した構造とするが、従来公知のその他の
エアベント手段が併設された構造であっても良い。ま
た、従来公知の型同様に、雌型や雄型等はそれぞれ複数
の部分に分割した型を用いることもある。また、図1に
例示した絵付け成形品の形状及びゲート位置の場合、多
孔質材の位置として選んだ樹脂の最終充填位置は、該最
終充填位置が絵付け成形品の外周部分であった。しか
し、もちろんの事、多孔質材の位置を最終充填位置とし
て選んだ場合でも、その最終充填位置は成形品形状次第
では成形品の外周部分とは限らない。
The mold for simultaneous painting with injection molding of the present invention has a structure in which at least a part of the cavity surface is formed of a porous material as an air vent, but has a structure in which other conventionally known air vent means are provided. May be. Further, similarly to the conventionally known molds, a mold divided into a plurality of parts may be used for each of the female mold and the male mold. In the case of the shape and the gate position of the painted product illustrated in FIG. 1, the final filling position of the resin selected as the position of the porous material was the outer peripheral portion of the painted product. However, needless to say, even when the position of the porous material is selected as the final filling position, the final filling position is not necessarily the outer peripheral portion of the molded product depending on the shape of the molded product.

【0020】〔射出成形同時絵付方法〕本発明の射出成
形同時絵付用型が使用され得る射出成形同時絵付方法に
ついて、ここで説明しておく。射出成形同時絵付方法と
は、特公昭50−19132号公報、特公昭43−27
488号公報、特開平6−315950号公報、特公平
2−42080号公報等に記載される様に、絵付シート
を型開き状態にある一対の型の間に挿入した後、両型を
型締めし、両型で形成されるキャビティに流動状態の樹
脂を射出し、成形と同時に絵付シートと樹脂成形物とを
一体化させて、絵付け成形品を製造する方法である。
[Injection Simultaneous Painting Method] A simultaneous injection molding simultaneous painting method in which the injection molding simultaneous painting mold of the present invention can be used will be described here. Injection molding simultaneous painting method is described in JP-B-50-19132, JP-B-43-27.
No. 488, JP-A-6-315950, JP-B-2-42080, etc., after inserting a sheet with a picture between a pair of molds in a mold open state, the molds are clamped. In this method, a resin in a flowing state is injected into a cavity formed by both molds, and simultaneously with molding, the painted sheet and the resin molded product are integrated to produce a painted molded product.

【0021】射出成形同時絵付方法は各種形態があり、
それら各種形態に対して、本発明の射出成形同時絵付用
型が使用される得る。射出成形同時絵付方法の各種形態
としては、例えば、絵付シートの予備成形を行う形態で
も行わない形態でも、いずれでも良い。また、絵付シー
トの予熱を行っても良く、行わなくても良い。なお、予
備成形時には通常は絵付シートは予熱する。もちろん、
絵付シートの絞りが大きい場合は、予備成形を行うのが
好ましい。一方、絵付シートの絞りが小さい場合は、射
出される流動状態の樹脂の樹脂圧で絵付シートを成形で
きる。この際、絞りが小さければ、予備成形無しで樹脂
射出と同時に型内に充填される流動状態の樹脂の樹脂圧
のみで絵付シートを成形する事もある。また、樹脂圧で
絵付シートを成形する場合でも、絵付シートは予熱せず
に射出樹脂の熱を利用する事もある。また、絵付シート
の予備成形は、通常は、射出成形同時絵付用型を真空成
形型と兼用するが、型間に絵付シートを供給する前に、
型外部で別の真空成形型で絵付シートを真空成形する様
な予備成形でも良い。なお、真空成形とは真空圧空成形
も包含する。
There are various types of simultaneous injection molding painting methods.
For these various forms, the injection molding simultaneous painting mold of the present invention can be used. As various forms of the simultaneous injection molding painting method, for example, either a form in which pre-forming of a painted sheet is not performed or a form in which pre-forming is not performed may be used. Also, the prepainted sheet may or may not be preheated. Note that the prepainted sheet is usually preheated during preforming. of course,
When the drawing sheet has a large drawing, it is preferable to perform preforming. On the other hand, when the drawing sheet has a small aperture, the drawing sheet can be formed by the resin pressure of the resin in the flowing state to be injected. At this time, if the drawing is small, the painted sheet may be formed only by the resin pressure of the resin in the flowing state filled into the mold at the same time as the resin injection without the preliminary molding. Further, even when the painted sheet is formed by the resin pressure, the painted sheet may utilize the heat of the injection resin without preheating. In addition, the preforming of the painted sheet is usually performed by simultaneously using the injection molding simultaneous painting mold and the vacuum forming mold, but before supplying the painted sheet between the molds,
Preforming such as vacuum forming the picture sheet with another vacuum forming die outside the die may be used. In addition, the vacuum forming includes vacuum pressure forming.

【0022】図5の概念図によって、射出成形同時絵付
方法を、その或る一形態で説明する。なお、ここで説明
する形態は、型締めする前に、絵付シートを型間で加熱
し軟化させて射出成形同時絵付用型で真空成形により予
備成形した後に、型締めして樹脂を射出する形態であ
る。
Referring to the conceptual diagram of FIG. 5, the simultaneous injection molding painting method will be described in one form. In addition, the form described here is a form in which the painted sheet is heated and softened between the molds, pre-molded by vacuum molding with a simultaneous injection molding painting mold before clamping, and then the resin is injected by clamping. It is.

【0023】先ず、図5(A)の如く、射出成形同時絵
付用型としては、射出ノズルと連通するランナー及びゲ
ートを有する型Maと、キャビティ面に吸引孔41を有
しシートの予備成形型を兼用する型Mbの一対の成形型
を用いる。これらの型は鉄等の金属、或いはセラミック
スからなる。もろちん、図面の煩雑さを避ける為、便宜
上、図5では図示は略すが、本発明の射出成形同時絵付
用型に於いては、そのキャビティ面の要所に多孔質材が
使われている。そして、型開き状態に於いて両型Ma、
Mb間に射出成形同時絵付シートSを供給し、型Mbに
絵付シートSを枠状のシートクランプ42で押圧する等
して固定する。この際、絵付シートの接着面側は、図面
右側の射出樹脂側となる様にする事はもちろんである。
次いで、適宜、両型間に挿入したヒータ(図示略)で絵
付シートを加熱軟化させる。加熱は例えば非接触の輻射
加熱とするが、接触加熱でも良い。そして、吸引孔から
吸引して真空成形して、絵付シートを型Mbのキャビテ
ィ面に沿わせ予備成形する。なお、真空成形は圧空も併
用する真空圧空成形でも良く、これも包含する。次い
で、ヒータを両型間から退避させ、図5(B)の如く両
型を型締めし、両型で形成さるキャビティに加熱熔融状
態等の流動状態の樹脂を充填する。そして、樹脂が冷却
により固化した後、型開きして成形物を取り出す。射出
成形同時絵付シートがラミネ−トシートの場合は、絵付
シートの不要部分があれば適宜トリミングすれば、樹脂
成形物に絵付シートが積層され絵付けされた絵付け成形
品が得られる。また、絵付シートが転写シートの場合
は、その基材シートを型Mb側に残した状態で成形物を
取り出すか、或いは、絵付シート全体が積層された状態
で成形物を取り出し後、基材シートを剥離して、転写層
のみが積層されて絵付けされた絵付け成形品を得る。
First, as shown in FIG. 5 (A), as a mold for simultaneous painting with injection molding, a mold Ma having a runner and a gate communicating with an injection nozzle, and a preforming mold for a sheet having a suction hole 41 on a cavity surface. Are used as a pair of molds of the mold Mb. These molds are made of metal such as iron or ceramics. Of course, in order to avoid complication of the drawing, for the sake of convenience, it is not shown in FIG. 5, but in the injection molding simultaneous painting mold of the present invention, a porous material is used at important points on the cavity surface. . Then, in the mold open state, both molds Ma,
The injection-molded simultaneous painting sheet S is supplied between Mb, and the painting sheet S is fixed to the mold Mb by pressing with a frame-shaped sheet clamp 42 or the like. At this time, it goes without saying that the adhesive surface side of the painted sheet is on the injection resin side on the right side of the drawing.
Next, the painted sheet is appropriately heated and softened by a heater (not shown) inserted between both molds. The heating is, for example, non-contact radiation heating, but may be contact heating. Then, the sheet is sucked from the suction hole and vacuum formed, and the prepainted sheet is preformed along the cavity surface of the mold Mb. In addition, vacuum forming may be vacuum press forming using both pressure and air, and this is also included. Next, the heater is retracted from between the two dies, the two dies are clamped as shown in FIG. 5B, and a cavity formed by the two dies is filled with a resin in a flowing state such as a heated and molten state. After the resin is solidified by cooling, the mold is opened and the molded product is taken out. In the case where the simultaneously painted sheet with the injection molding is a laminate sheet, if there is an unnecessary portion of the painted sheet, the painted sheet is laminated on the resin molded product and a painted molded article is obtained. When the painted sheet is a transfer sheet, the molded article is taken out with the base sheet left on the mold Mb side, or the molded article is taken out with the whole painted sheet laminated, and then the base sheet is taken out. Is removed to obtain a painted molded article in which only the transfer layer is laminated and painted.

【0024】〔絵付シート〕上述の様な射出成形同時絵
付用型を用いて射出成形同時絵付けする際に用い得る絵
付シートは、転写タイプ或いはラミネートタイプとして
従来公知の絵付シートを用いる事ができ、特に限定され
るものでは無い。そこで、絵付シートについても一応説
明しておく。
[Painting sheet] The painting sheet that can be used for simultaneous painting by injection molding using the above-described mold for simultaneous painting by injection molding can be a conventionally known painting sheet as a transfer type or a laminate type. It is not particularly limited. Therefore, the painting sheet will be briefly described.

【0025】転写タイプの絵付シート(転写シート)
は、基材シートに剥離性のシートを用い、基材シート上
に転写層が積層された構成である。転写層は例えば装飾
層や接着剤層等からなる。また、転写層の基材シート側
には剥離層を転写層の構成要素として適宜設けた構成等
もある。ラミネートタイプの絵付シート(ラミネートシ
ート)は、例えば基材シート上に装飾層と接着剤層とを
順次積層した構成である。なお、転写タイプ、ラミネー
トタイプ共に接着剤層は省略することもある。
Transfer type painting sheet (transfer sheet)
Has a configuration in which a releasable sheet is used as a base sheet and a transfer layer is laminated on the base sheet. The transfer layer includes, for example, a decorative layer, an adhesive layer, and the like. In addition, there is a configuration in which a release layer is appropriately provided as a component of the transfer layer on the base sheet side of the transfer layer. The laminate type painting sheet (laminated sheet) has a configuration in which, for example, a decorative layer and an adhesive layer are sequentially laminated on a base material sheet. The adhesive layer may be omitted in both the transfer type and the laminate type.

【0026】基材シートとしては、成形性の有る樹脂シ
ートが代表的には用いられる。該樹脂シートとしては、
例えば、ポリエチレン、ポリプロピレン、オレフィン系
熱可塑性エラストマー等のオレフィン系樹脂、ポリブチ
レンテレフタレート、エチレンテレフタレートイソフタ
レート共重合体等のポリエステル樹脂、塩化ビニル樹
脂、アクリル樹脂、ABS(アクリロニトリル−ブタジ
エン−スチレン共重合体)樹脂、ポリアミド樹脂、ウレ
タン系等のその他の熱可塑性エラストマー、等の熱可塑
性樹脂のシートの単層又は異種材料の2層以上の積層体
が用いられる。また、成形性を満足すれば、不織布や織
布等の布等に対して樹脂を含浸させたシートや、前記樹
脂シートを積層した積層体等も用いられる。なお、転写
タイプでは、必要に応じ、基材シートの転写層側に、転
写層との剥離性を向上させる為、離型層を設けた構成の
基材シートとする。離型層は基材シート剥離時に基材シ
ートと共に転写層から分離し剥離除去される。離型層に
は、例えば、シリコーン樹脂、メラミン樹脂、ポリアミ
ド樹脂、ウレタン樹脂、ポリオレフィン樹脂、ワックス
等の単体又は2種以上の混合物が用いられる。また、ラ
ミネートタイプでは、基材シート樹脂中に顔料等の着色
剤を練り込んで、基材シートを着色透明又は着色不透明
等とする装飾処理を施す事もある。この場合、基材シー
ト自体が装飾層を成し基材シートのみの構成の絵付シー
トとなる場合もある。
As the base sheet, a resin sheet having moldability is typically used. As the resin sheet,
For example, olefin resins such as polyethylene, polypropylene and olefin thermoplastic elastomer, polyester resins such as polybutylene terephthalate and ethylene terephthalate isophthalate copolymer, vinyl chloride resin, acrylic resin, ABS (acrylonitrile-butadiene-styrene copolymer) A single layer of a sheet of a thermoplastic resin such as a resin, a polyamide resin, another thermoplastic elastomer such as a urethane-based elastomer, or a laminate of two or more layers of different materials is used. If the formability is satisfied, a sheet in which a resin such as a nonwoven fabric or a woven fabric is impregnated with a resin, a laminate in which the resin sheet is laminated, or the like is used. In the transfer type, a base sheet having a release layer is provided on the transfer layer side of the base sheet, if necessary, in order to improve the releasability from the transfer layer. The release layer is separated from the transfer layer together with the base sheet when the base sheet is peeled, and is removed. For the release layer, for example, a single substance or a mixture of two or more of silicone resin, melamine resin, polyamide resin, urethane resin, polyolefin resin, wax and the like are used. Further, in the case of a laminate type, a coloring agent such as a pigment is kneaded into a base sheet resin to perform a decoration treatment for making the base sheet colored transparent or colored opaque. In this case, the base sheet itself may form a decorative layer, and may be a picture sheet having a configuration of only the base sheet.

【0027】装飾層は、グラビア印刷、シルクスクリー
ン印刷、オフセット印刷等の従来公知の方法、材料で絵
柄等を印刷した絵柄層、アルミニウム、クロム等の金属
を公知の蒸着法等で部分又は全面に形成した金属薄膜層
等である。絵柄は、板目や柾目等の木目模様、大理石や
御影石等の石目模様、タイル調模様、煉瓦調模様、布目
模様、文字、幾何学模様、全面ベタなど任意である。絵
柄層用インキは、バインダー等からなるビヒクル、顔料
や染料等の着色剤、これに適宜加える各種添加剤からな
る。バインダーには、塩素化ポリエチレン、塩素化ポリ
プロピレン等の塩素化ポリオレフィン、ポリエステル樹
脂、ウレタン樹脂、アクリル樹脂、酢酸ビニル樹脂、塩
化ビニル−酢酸ビニル共重合体、セルロース系樹脂等の
熱可塑性樹脂、ウレタン樹脂、エポキシ樹脂等の熱硬化
性樹脂等を、これら樹脂の単体又は混合物として用い
る。顔料又は染料等の着色剤としては、チタン白、カー
ボンブラック、弁柄、コバルトブルー、黄鉛、フタロシ
アニンブルー、イソインドリノン、キナクリドン、アル
ミニウム粉等の金属顔料、真珠光沢(パール)顔料等が
用いられる。
The decorative layer is formed on a part or the whole surface by a conventionally known method such as gravure printing, silk screen printing or offset printing, a pattern layer on which a pattern is printed with a material, or a metal such as aluminum or chrome by a known vapor deposition method. It is a formed metal thin film layer or the like. The pattern is arbitrary, such as a grain pattern such as a plate grain or a straight grain, a grain pattern such as marble or granite, a tile pattern, a brick pattern, a cloth pattern, a character, a geometric pattern, and a solid surface. The picture layer ink comprises a vehicle such as a binder, a coloring agent such as a pigment or a dye, and various additives appropriately added thereto. Binders include chlorinated polyolefins such as chlorinated polyethylene and chlorinated polypropylene, polyester resins, urethane resins, acrylic resins, vinyl acetate resins, vinyl chloride-vinyl acetate copolymers, thermoplastic resins such as cellulose resins, and urethane resins. Or a thermosetting resin such as an epoxy resin is used alone or as a mixture of these resins. As a coloring agent such as a pigment or a dye, metal pigments such as titanium white, carbon black, red iron oxide, cobalt blue, graphite, phthalocyanine blue, isoindolinone, quinacridone, and aluminum powder, and pearlescent (pearl) pigments are used. Can be

【0028】絵付シートの裏面には、射出樹脂との接着
性向上のため、コロナ放電処理、公知の各種プライマー
塗工等の易接着処理や感熱型等の接着剤層を施すことが
ある。接着剤層には、熱可塑性樹脂、熱硬化性樹脂等の
公知の樹脂が用いられる。例えば、熱可塑性樹脂では、
ポリスチレン、ポリα−メチルスチレン等のスチレン樹
脂又はスチレン共重合体、ポリ(メタ)アクリル酸メチ
ル、ポリ(メタ)アクリル酸エチル、ポリ(メタ)アク
リル酸ブチル等のアクリル樹脂、塩素化ポリプロピレン
等の塩素化ポリオレフィン樹脂、塩化ビニル樹脂、酢酸
ビニル樹脂、塩化ビニル−酢酸ビニル共重合体、ポリビ
ニルブチラール等のビニル重合体、ポリイソプレンゴ
ム、ポリイソブチルゴム、スチレンブタジエンゴム、ブ
タジエンアクリロニトリルゴム等のゴム系樹脂、ポリア
ミド樹脂等の熱可塑性樹脂等の1種又は2種以上の混合
物が用いられる。また、熱硬化性樹脂では、ウレタン樹
脂、エポキシ樹脂等が用いられる。なお、接着剤層が形
成された絵付シートでは、接着剤層が射出時に射出樹脂
と接して接着剤層中の残留溶剤が揮発する事によるガス
が余計に発生し易い。ところが、本発明の射出成形同時
絵付用型では、エアベント性能が良いので、絵付シート
の密着不良や転写層の転写不良等の製品欠陥が発生し難
い。
In order to improve the adhesiveness to the injection resin, an easy-adhesion treatment such as corona discharge treatment and various known primer coatings, or a heat-sensitive adhesive layer may be applied to the back surface of the painted sheet. Known resins such as a thermoplastic resin and a thermosetting resin are used for the adhesive layer. For example, in thermoplastic resin,
Styrene resins or styrene copolymers such as polystyrene and poly-α-methylstyrene, acrylic resins such as poly (methyl) acrylate, ethyl poly (meth) acrylate and butyl poly (meth) acrylate, chlorinated polypropylene and the like Vinyl polymers such as chlorinated polyolefin resin, vinyl chloride resin, vinyl acetate resin, vinyl chloride-vinyl acetate copolymer, polyvinyl butyral, and rubber resins such as polyisoprene rubber, polyisobutyl rubber, styrene butadiene rubber, butadiene acrylonitrile rubber And one or a mixture of two or more thermoplastic resins such as polyamide resins. As the thermosetting resin, a urethane resin, an epoxy resin, or the like is used. In addition, in the painted sheet on which the adhesive layer is formed, the adhesive layer comes into contact with the injection resin at the time of injection, and a gas is more easily generated due to the volatilization of the residual solvent in the adhesive layer. However, the mold for simultaneous painting with injection molding of the present invention has good air vent performance, so that product defects such as poor adhesion of the painting sheet and poor transfer of the transfer layer hardly occur.

【0029】〔射出樹脂〕なお、本発明の射出成形同時
絵付用型を用いて射出成形同時絵付けする際に、射出成
形する樹脂としては、射出成形同時絵付方法に於ける従
来公知のものが使用でき特に制限はない。射出樹脂は、
製品の要求物性やコスト等に応じて選定される。例え
ば、熱可塑性樹脂であれば、ABS(アクリロニトリル
−ブタジエン−スチレン共重合体)樹脂、AS(アクリ
ロニトリル−スチレン共重合体)樹脂、スチレン樹脂、
塩化ビニル樹脂、アクリル樹脂、ポリカーボネート樹
脂、或いはポリエチレン、ポリプロピレン、ポリブテ
ン、ポリメチルペンテン、エチレン−プロピレン共重合
体、エチレン−プロピレン−ブテン共重合体、オレフィ
ン系熱可塑性エラストマー等のポリオレフィン系樹脂等
である。また、硬化性樹脂であれば、2液硬化型の樹
脂、例えば、ウレタン樹脂、不飽和ポリエステル樹脂、
エポキシ樹脂等の未硬化樹脂液等である。熱可塑性樹脂
は加熱熔融して流動状態で射出し、また硬化性樹脂は室
温又は適宜加熱して流動状態で射出する。なかでも、本
発明ではガス溜まりが原因となる、絵付シートの密着不
良や転写層の転写不良等による絵付け不良等の製品欠陥
発生を防げるので、射出樹脂の流れが早くガスが溜まり
易い樹脂、例えばポリプロピレン等のポリオレフィン樹
脂等の場合では、特に効果的である。
[Injection Resin] The resin to be injection-molded at the time of simultaneous injection-molding and painting using the injection-molding and simultaneous painting mold of the present invention may be any of those conventionally known in the simultaneous injection-molding and painting method. It can be used without any particular restrictions. Injection resin is
It is selected according to the required physical properties and cost of the product. For example, in the case of a thermoplastic resin, an ABS (acrylonitrile-butadiene-styrene copolymer) resin, an AS (acrylonitrile-styrene copolymer) resin, a styrene resin,
Polyvinyl chloride resin, acrylic resin, polycarbonate resin, or polyolefin resin such as polyethylene, polypropylene, polybutene, polymethylpentene, ethylene-propylene copolymer, ethylene-propylene-butene copolymer, olefin-based thermoplastic elastomer, etc. . In the case of a curable resin, a two-component curable resin, for example, a urethane resin, an unsaturated polyester resin,
An uncured resin liquid such as an epoxy resin. The thermoplastic resin is melted by heating and injected in a fluid state, and the curable resin is injected at room temperature or appropriately heated and flowed. Above all, in the present invention, due to gas accumulation, it is possible to prevent the occurrence of product defects such as poor painting due to poor adhesion of the painted sheet or poor transfer of the transfer layer, etc. For example, it is particularly effective in the case of a polyolefin resin such as polypropylene.

【0030】〔その他〕なお、本発明でいう「絵付け」
とは、単に絵柄や文字、図形等の目視可能な模様を成形
品に付与する以外に、目視不可能な模様、あるいは硬質
塗膜、導電性等の機能性層を付与することも包含する。
目視可能な模様としては、印刷等により形成した絵柄
層、真空蒸着等により形成した金属薄膜層など公知のも
のが、目視不可能な模様の例としては可視光に対しては
透明で紫外線照射で蛍光を発する蛍光インキで印刷した
絵柄等が、用いられる。最も単純な絵付シートは、何も
印刷されていない無着色の(透明又は不透明の)単なる
樹脂シートのみのシートである。なお、該樹脂シート
は、表面強度向上等の表面物性の付与、塗装感の付与等
に使用される。
[Others] In the present invention, "painting"
The expression includes not only providing a visible pattern such as a pattern, a character, or a figure to a molded product, but also providing a pattern that is not visible or a functional layer such as a hard coating film or conductivity.
Known patterns such as a pattern layer formed by printing or the like and a metal thin film layer formed by vacuum evaporation or the like are examples of the pattern that can be visually observed. A pattern printed with fluorescent ink that emits fluorescence is used. The simplest painted sheet is an uncolored (transparent or opaque) mere resin sheet without any printing. In addition, the resin sheet is used for imparting surface physical properties such as improvement of surface strength and imparting a feeling of painting.

【0031】[0031]

【実施例】次に、実施例及び比較例により本発明を更に
詳述する。
Next, the present invention will be described in more detail with reference to Examples and Comparative Examples.

【0032】〔実施例及び比較例〕試験する絵付け成形
品は、図1(A)の如き形状で、幅40mm、長さ40
0mmの概略楕円形で、図1(B)の如く、絵付け面と
なる表面側に凸を成す断面が概略台形形状の車両内装用
のパネルとした。
[Examples and Comparative Examples] The painted molded article to be tested has a shape as shown in FIG. 1A, a width of 40 mm and a length of 40 mm.
As shown in FIG. 1 (B), the panel for vehicle interiors has a substantially trapezoidal cross section which has a substantially elliptical shape of 0 mm and which is convex on the surface side serving as a painting surface.

【0033】一方、絵付シートとしては、メチルメタク
リレート−ブチルメタクリレート共重合体からなる12
5μm厚のアクリル樹脂フィルムの裏側(射出樹脂側)
となる面に、バインダーの樹脂がアクリル樹脂と塩化ビ
ニル−酢酸ビニル共重合体との1対1重量比混合物で、
顔料がチタン白、フタロシアニンブルー、ポリアゾレッ
ド、及びポリアゾイエローからなるインキで木目柄をグ
ラビア印刷の多色刷りで形成した上に、更に、塩素化ポ
リプロピレン樹脂からなる厚さ4μmの接着剤層をグラ
ビア印刷の2回刷りで形成したシートを用意した。
On the other hand, a sheet with a picture is made of methyl methacrylate-butyl methacrylate copolymer.
Back side of 5 μm thick acrylic resin film (injection resin side)
On the surface to become, the resin of the binder is a 1: 1 weight ratio mixture of acrylic resin and vinyl chloride-vinyl acetate copolymer,
The grain pattern is formed by multicolor printing of gravure printing using an ink composed of titanium white, phthalocyanine blue, polyazo red, and polyazo yellow. The sheet formed by the second printing was prepared.

【0034】そして、射出成形同時絵付用型として用い
た金型は、図1(B)の如く、多孔質材2を樹脂の最終
充填位置となる成形品外周の一部を含む、図面左右両端
の雄型のキャビティ面部分の2箇所に、それぞれブロツ
ク状の多孔質材2を入れ子状に埋め込んだ構造とした。
なお、ゲートGの位置は、成形品裏側面(雄型側)のほ
ぼ中央に1箇所とした。多孔質材には多孔質金属(株式
会社神戸製鋼所製、商品名「ピポラス」)を用いた。ま
た、多孔質材以外の部分の型は、雌雄両型とも炭素鋼で
形成した。
As shown in FIG. 1 (B), the mold used as the mold for simultaneous painting with injection molding has a porous material 2 that includes a part of the outer periphery of the molded product at the final filling position of the resin. The block-shaped porous material 2 was nested at two locations on the male mold cavity surface.
The position of the gate G was set at one position substantially at the center of the back surface (male side) of the molded product. As the porous material, a porous metal ("Piporus", manufactured by Kobe Steel Ltd.) was used. The molds other than the porous material were both formed of carbon steel.

【0035】そして、前記上記絵付シートと上記射出成
形同時絵付用型を用いて、図5の概念図で説明した様に
して射出成形同時絵付けを行い、絵付シートがラミネ−
トされた絵付け成形品を製造した。絵付シートは、先
ず、型開き状態の雌雄両型間に供給した後、赤外線輻射
加熱方式の熱盤を更に型間に挿入して、絵付シートを非
接触で加熱した後、雌型を真空成形型とした真空成形で
絵付シートの予備成形を行い、軟化させた絵付シートを
雌型のキャビティ面に沿う形状に成形した。その後、熱
盤を型外の退避位置に退避させて、両型を型締めした。
次いで、ポリプロピレン系樹脂を、樹脂温度220℃、
金型温度50℃(雌型及び雄型の両方とも)、射出時間
2秒の条件で、両型で形成されるキャビティ内に射出し
た。そして、樹脂が冷却し固化後、型開きして、絵付け
成形品を得た。
Then, simultaneous painting by injection molding is performed using the above-mentioned painting sheet and the above-mentioned mold for simultaneous painting by injection molding as described with reference to the conceptual diagram of FIG.
The painted molded article was manufactured. The painted sheet is first supplied between the male and female molds in the mold open state, then a hot plate of infrared radiation heating method is further inserted between the molds, the painted sheet is heated in a non-contact manner, and the female mold is vacuum formed. The painting sheet was preformed by vacuum molding as a mold, and the softened painting sheet was molded into a shape along the cavity surface of the female mold. Thereafter, the hot plate was retracted to a retracted position outside the mold, and both molds were clamped.
Next, a polypropylene-based resin was used at a resin temperature of 220 ° C.
The mold was injected into the cavity formed by both molds under the conditions of a mold temperature of 50 ° C. (both the female mold and the male mold) and an injection time of 2 seconds. After the resin was cooled and solidified, the mold was opened to obtain a painted molded product.

【0036】その結果、多孔質材使用の射出成形同時絵
付用型による実施例では、エアベントは良好で、ガス溜
まりが発生せず、良好な製品となった。絵付シートは成
形品外周部の端まで樹脂成形物に密着し、絵付シートが
端で浮き上がる事も無く、良好であった。
[0036] As a result, in the embodiment using the mold for simultaneous painting with injection molding using a porous material, the air vent was good, and no gas accumulation occurred, and a good product was obtained. The painted sheet was in close contact with the resin molded product up to the edge of the outer peripheral portion of the molded article, and the painted sheet was good without being lifted at the end.

【0037】しかし、比較例として、図6の断面図で示
す如き、多孔質材の代わりに炭素鋼からなる無垢材(通
気孔無し)6を埋め込んだ通常の射出成形同時絵付用型
では(エアベントはパーティング面に一応設けてあ
る)、ガス逃げが不十分で、成形品末端部分にガス溜ま
りが出来てしまった。その為、ガス溜まり部分では樹脂
の充填不足、及び絵付シートが樹脂成形物5と密着せず
に、浮き上がってしまった。
However, as a comparative example, as shown in the cross-sectional view of FIG. 6, a conventional injection molding simultaneous painting mold in which a solid material (without air holes) 6 made of carbon steel is embedded instead of a porous material (air vent) Is temporarily provided on the parting surface), the gas escape was insufficient, and gas accumulation occurred at the end of the molded product. For this reason, in the gas accumulation portion, the resin was insufficiently filled, and the painted sheet floated up without adhering to the resin molded product 5.

【0038】[0038]

【発明の効果】本発明によれば、キャビティ面の一部を
多孔質材で形成することによって、樹脂射出時のキャビ
ティ内のガスが逃がし易くなっているので、ガス逃げ不
良を防げる。従って、ガス溜りが発生しにくく、樹脂成
形物の欠損部発生や、ガス溜まり部分で絵付シートが樹
脂成形物に密着しない為に起きる、絵付シートの密着不
良(ラミネートシートの場合)や、転写層の密着不良
(転写シートの場合)等の絵付けが一部で成されない絵
付け不良による製品欠陥を防げる。また、多孔質材を設
ける位置を、樹脂の最終充填位置、ウェルドラインの発
生位置のいずれか片方、又は両方とすれば、効率的にキ
ャビティ内のガスを逃がせる。
According to the present invention, by forming a part of the cavity surface with a porous material, the gas in the cavity at the time of resin injection can be easily escaped, so that a gas escape defect can be prevented. Therefore, gas accumulation is unlikely to occur, and the defective portion of the painted sheet (in the case of a laminated sheet), which occurs due to the occurrence of a defective portion of the resin molded product or the fact that the painted sheet does not adhere to the resin molded product at the gas accumulation portion, or the transfer layer This prevents product defects due to poor painting, such as poor adhesion (in the case of a transfer sheet), which is not partially achieved. Further, if the position where the porous material is provided is one or both of the final filling position of the resin and the position where the weld line is generated, the gas in the cavity can be efficiently released.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の射出成形同時絵付用型を概念的に説明
する断面図。
FIG. 1 is a cross-sectional view conceptually illustrating a mold for simultaneous painting with injection molding of the present invention.

【図2】従来の射出成形同時絵付用型の場合でエアベン
ト不足で起き得るガス溜まりを概念的に説明する断面
図。
FIG. 2 is a cross-sectional view conceptually illustrating a gas reservoir that can occur due to an insufficient air vent in the case of a conventional injection molding simultaneous painting mold.

【図3】図2のガス溜まり部分の要部拡大断面図。FIG. 3 is an enlarged cross-sectional view of a main part of a gas reservoir part of FIG. 2;

【図4】図3に対応した、絵付け成形品での欠陥を説明
する断面図。
FIG. 4 is a cross-sectional view corresponding to FIG. 3 for explaining a defect in a painted molded product.

【図5】射出成形同時絵付方法を或る一例で説明する概
念図。
FIG. 5 is a conceptual diagram illustrating an example of a simultaneous injection molding painting method.

【図6】比較例で用いた射出成形同時絵付用型の構造を
概念的に説明する断面図。
FIG. 6 is a sectional view conceptually illustrating the structure of a mold for simultaneous painting with injection molding used in a comparative example.

【符号の説明】[Explanation of symbols]

1 キャビティ面 2 多孔質材 3 ガス溜まり 4 欠損部 5 樹脂成形物 6 無垢材 41 吸引孔 42 シートクランプ Ma 射出成形同時絵付用型(雄型) Mb 射出成形同時絵付用型(雌型) G ゲート P 絵付け成形品 S 絵付シート DESCRIPTION OF SYMBOLS 1 Cavity surface 2 Porous material 3 Gas reservoir 4 Defective part 5 Resin molding 6 Solid material 41 Suction hole 42 Sheet clamp Ma Injection molding simultaneous painting mold (male mold) Mb Injection molding simultaneous painting mold (female mold) G Gate P Painted product S Painted sheet

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 絵付シートを一対の型の間に挿入した
後、両型を型締めし、両型で形成されるキャビティに流
動状態の樹脂を射出し、成形と同時に絵付シートと樹脂
成形物とを一体化させて、絵付け成形品を得る射出成形
同時絵付方法に使用する型において、 キャビティ面に絵付シートが接する側の型とは反対側の
型のキャビティ面が、その全面又は一部が多孔質材で形
成されている射出成形同時絵付用型。
1. After inserting a painted sheet between a pair of molds, both molds are clamped, and a resin in a flowing state is injected into a cavity formed by both molds. And a mold used in the simultaneous painting method for injection molding to obtain a painted molded product, wherein the cavity surface of the mold on the side opposite to the side where the painted sheet is in contact with the cavity surface is the whole or part thereof Is a mold for simultaneous painting with injection molding, which is formed of a porous material.
【請求項2】 多孔質材で形成されている位置が、樹脂
の最終充填位置、ウェルドラインの発生位置のいずれか
片方、又は両方である、請求項1記載の射出成形同時絵
付用型。
2. The mold for simultaneous injection molding and painting according to claim 1, wherein the position formed by the porous material is one or both of a final filling position of the resin and a position where a weld line is generated.
JP29629998A 1998-10-19 1998-10-19 Mold for foil decorating simultaneously with injection molding Pending JP2000117782A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29629998A JP2000117782A (en) 1998-10-19 1998-10-19 Mold for foil decorating simultaneously with injection molding

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29629998A JP2000117782A (en) 1998-10-19 1998-10-19 Mold for foil decorating simultaneously with injection molding

Publications (1)

Publication Number Publication Date
JP2000117782A true JP2000117782A (en) 2000-04-25

Family

ID=17831764

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29629998A Pending JP2000117782A (en) 1998-10-19 1998-10-19 Mold for foil decorating simultaneously with injection molding

Country Status (1)

Country Link
JP (1) JP2000117782A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002103387A (en) * 2000-09-29 2002-04-09 Dainippon Printing Co Ltd Apparatus for in-mold decorating synchronized with injection molding and laminated product
CN110216851A (en) * 2018-03-02 2019-09-10 彰洋材料股份有限公司 Transformation projects mould, projects footwear material and its manufacturing method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2002103387A (en) * 2000-09-29 2002-04-09 Dainippon Printing Co Ltd Apparatus for in-mold decorating synchronized with injection molding and laminated product
CN110216851A (en) * 2018-03-02 2019-09-10 彰洋材料股份有限公司 Transformation projects mould, projects footwear material and its manufacturing method
CN110216851B (en) * 2018-03-02 2021-12-31 彰洋材料股份有限公司 Variable-pressure injection mold, injection shoe material and manufacturing method thereof

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