JP2008038123A - Rust preventing wax composition - Google Patents
Rust preventing wax composition Download PDFInfo
- Publication number
- JP2008038123A JP2008038123A JP2006261153A JP2006261153A JP2008038123A JP 2008038123 A JP2008038123 A JP 2008038123A JP 2006261153 A JP2006261153 A JP 2006261153A JP 2006261153 A JP2006261153 A JP 2006261153A JP 2008038123 A JP2008038123 A JP 2008038123A
- Authority
- JP
- Japan
- Prior art keywords
- wax
- rust preventing
- weight
- rust preventive
- rust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/06—Waxes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/008—Temporary coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
本発明は防錆ワックス組成物に関し、更に詳しくは、ナフテン系鉱油ワックス、防錆添加剤、アルキド樹脂、および添加剤を含有する防錆ワックス組成物において、酸化石油ワックスとマイクロスタリンワックスが最適比で混合されたワックスを使用し、防錆添加剤として石油スルホン酸カルシウムとジノニルナフタレンスルホン酸バリウムを混合することで防錆性が向上し、また、作業時に揮発有機成分が減少するため自動車車体部位用ワックスとして適用できる優れた防錆ワックス組成物に関するものである。 The present invention relates to a rust preventive wax composition, and more particularly, in a rust preventive wax composition containing a naphthenic mineral oil wax, a rust preventive additive, an alkyd resin, and an additive, an oxidized petroleum wax and a microstalline wax are in an optimum ratio. By using the wax mixed in the above and mixing calcium sulfonate and barium dinonylnaphthalene sulfonate as anti-corrosive additives, the anti-rust property is improved and the volatile organic components are reduced during the work. The present invention relates to an excellent rust preventive wax composition that can be applied as a wax for parts.
最近、自動車産業では自動車の室内だけでなく自動車製造作業場も有害物質を遮断しようとする努力がなされている。特に自動車製造過程で車体溶接部位の防錆目的に使用されている既存の防錆ワックスは、溶剤にワックスおよび添加剤などを希釈して塗布され、その後、溶剤の揮発により車体にワックスと添加剤のみ残されて防錆がなされる。したがって、このような防錆ワックスは塗布後、工場内では別途換風機などを利用し、乾燥時に揮発する溶剤を作業場内から除去する必要があった。 Recently, efforts have been made in the automobile industry to block harmful substances not only in automobile interiors but also in automobile manufacturing workshops. In particular, existing rust-preventing wax used for rust prevention of car body welded parts in the automobile manufacturing process is applied by diluting the solvent with wax and additives, and then the wax and additives are applied to the car body by volatilization of the solvent. Only left behind is rust prevention. Therefore, after applying such a rust preventive wax, it is necessary to remove a solvent which volatilizes at the time of drying from the work place by using a separate air conditioner or the like in the factory.
このように防錆目的で使用されるワックスの有害揮発性有機化合物を低減するために大韓民国公開特許第１０−２００６−００２１１９８号のようにイオン交換水を組成物に添加した水溶性防錆ワックスのような技術もあるが、このような技術は防錆ワックスに含まれた水を蒸発させるために高い温度で乾燥しなければならない短所があった。
したがって、自動車用防錆ワックスとして、揮発成分を排出せず、且つ別途の加熱乾燥装備を必要としない既存ワックスと同等の性能を有する防錆性能のワックスの開発が切実に求められている。
Therefore, there is an urgent need to develop a rust-preventing wax having the same performance as that of an existing wax that does not emit volatile components and does not require a separate heating and drying equipment, as a rust-preventing wax for automobiles.
本発明者は揮発成分を有する溶剤の代わりにナフテン系鉱油を使用し、塗布後に前記ナフテン系鉱油が流れ落ちる問題を解決するため、アルキド樹脂を組成物に塗布して流れ落ちるのを防止することで、作業時に有害揮発性有機物の発生がなく、且つ別途の高温乾燥装置を必要としない、防錆性能が溶剤形防錆ワックスと同等のワックス組成物を開発した。 The present inventor uses a naphthenic mineral oil instead of a solvent having a volatile component, and solves the problem of the naphthenic mineral oil flowing down after coating, in order to prevent the alkyd resin from flowing down by applying to the composition, We have developed a wax composition that does not generate harmful volatile organic substances during work and that does not require a separate high-temperature drying device, and that has the same antirust performance as solvent-type antirust wax.
本発明の目的は有害揮発性有機物の発生がなく、塗布後に流れ落ちない防錆ワックス組成物を提供することである。 An object of the present invention is to provide a rust preventive wax composition which does not generate harmful volatile organic substances and does not flow down after application.
本発明は、ナフテン系鉱油１０〜２０重量％、酸化石油ワックスとマイクロスタリンワックスが１０：５〜１５：１０重量比で混合されたワックス１５〜２５重量％、石油スルホン酸カルシウムとジノニルナフタレンスルホン酸バリウムが１０：３５〜２０：４５重量比で混合された防錆添加剤４５〜６５重量％、アルキド樹脂１０〜３０重量％、および、その他の添加剤０．５〜２重量％、を含有することを特徴とする。 The present invention includes 10 to 20% by weight of a naphthenic mineral oil, 15 to 25% by weight of a wax in which oxidized petroleum wax and microstalline wax are mixed in a ratio of 10: 5 to 15:10, calcium petroleum sulfonate and dinonylnaphthalene sulfone. Contains 45-65 wt% rust preventive additive, 10-30 wt% alkyd resin mixed with 10: 35-20: 45 wt% of barium acid, and 0.5-2 wt% other additive It is characterized by doing.
本発明の防錆ワックス組成物は有害揮発性有機成分の排出が改善され、２次流動性、塗膜、ゴムに対する影響が既存の防錆ワックスと同等であり、作業環境も改善され、自動車などの防錆ワックスとして適用が可能である。 The rust preventive wax composition of the present invention has improved emission of harmful volatile organic components, has the same effect on secondary fluidity, coating film and rubber as the existing rust preventive wax, improved working environment, automobiles, etc. It can be applied as a rust preventive wax.
以下、本発明の防錆ワックス組成物についてより具体的に説明する。
本発明はナフテン系鉱油、ワックス、防錆添加剤、アルキド樹脂、および添加剤を含有した防錆ワックス組成物に関し、酸化石油ワックスとマイクロスチレンワックスが最適比で混合されたワックスを使用し、防錆添加剤として石油スルホン酸カルシウムとジノニルナフタレンスルホン酸バリウムを混合し、その他の添加剤を含有する防錆ワックス組成物であり、作業時に有害揮発性有機物が発生するという問題点を改善し、防錆性が向上された防錆ワックス組成物に関するものである。
Hereinafter, the rust preventive wax composition of the present invention will be described more specifically.
The present invention relates to a rust preventive wax composition containing a naphthenic mineral oil, a wax, a rust preventive additive, an alkyd resin, and an additive, using a wax in which an oxidized petroleum wax and a microstyrene wax are mixed in an optimum ratio, It is a rust preventive wax composition that contains calcium sulfonate and barium dinonylnaphthalene sulfonate as rust additives and contains other additives, which improves the problem of generating harmful volatile organic substances during work. The present invention relates to a rust preventive wax composition having improved rust preventive properties.
本発明では、オイルにワックス、防錆添加剤、アルキド樹脂、および添加剤を溶解させる。これは、防錆ワックスの噴霧を容易に行うために使用するもので、炭化水素が主成分であり、原油の常圧蒸留の残渣油を減圧蒸留して流出した油を分離して得る。オイルは引火点によって区分されるが、一般的なオイルの場合、芳香族成分が含まれているため精製方法によっては発癌性物質が含まれることもある。 In the present invention, wax, rust preventive additive, alkyd resin, and additive are dissolved in oil. This is used for easily spraying the rust-preventing wax, which is mainly composed of hydrocarbons, and is obtained by separating the oil that has flowed out by distilling the residual oil of the crude oil at atmospheric pressure under reduced pressure. Oils are classified according to their flash points. However, in the case of general oils, carcinogens may be included depending on the purification method because aromatic components are included.
従って、本発明では一般的なオイルを使用せずに高度に精製されたナフテン系鉱油を使用し、オイルの粘度は１００℃を基準に３ｃＳｔ、引火点は１００℃以上であり、その含量は１０〜２０重量％のものを使用する。前記含量が１０重量％未満の場合、粘度が過度に高いため噴霧ができず、２０重量％を超過する場合、乾燥時間が過度に長くなるため噴霧後に前記ナフテン系鉱油が流れ落ちてしまうという問題点が発生する。 Therefore, in the present invention, a highly refined naphthenic mineral oil is used without using a general oil, the viscosity of the oil is 3 cSt based on 100 ° C., the flash point is 100 ° C. or more, and the content is 10 Use ˜20% by weight. When the content is less than 10% by weight, the spray cannot be sprayed because the viscosity is excessively high. When the content exceeds 20% by weight, the drying time becomes excessively long, and thus the naphthenic mineral oil flows down after spraying. Occurs.
本発明で使用するワックスは飽和炭化水素を主成分としたもので、被膜形成物質として適用し、防錆性も付与する。前記ワックスは被膜形成時、水分通過を遮断する障壁の役割を有する。前記ワックスは融点が高いほど撥水性が良くなり、温度に対する感応性が高くなる。ワックスは飽和炭化水素であるため温度に対する反応性が高く、低温で粘度が急激に増加する現象が起きるため、本発明では１種類のみ使用せず、酸化石油ワックスとマイクロスタリンワックスを１０：５〜１５：１０重量比で混合して使用する。
前記重量比が１０：５未満である場合、塗布後にワックスが容易に流れ落ちて車体に錆が発生し、１５：１０重量比を超過する場合、防錆性は良好であるが乾燥時間が長くなる問題点が発生する。
The wax used in the present invention is mainly composed of a saturated hydrocarbon, and is applied as a film-forming substance and imparts rust prevention properties. The wax has a role of a barrier that blocks moisture passage during film formation. The higher the melting point of the wax, the better the water repellency and the higher the sensitivity to temperature. Since the wax is a saturated hydrocarbon, it has a high reactivity with respect to temperature, and a phenomenon in which the viscosity rapidly increases at a low temperature occurs. Therefore, in the present invention, not only one type is used, but oxidized petroleum wax and microstalline wax are used at 10: 5 to 5. Used in a 15:10 weight ratio.
When the weight ratio is less than 10: 5, the wax easily flows down after application and rust is generated on the vehicle body. When the weight ratio exceeds 15:10 weight ratio, the rust prevention is good but the drying time is long. Problems arise.
前記酸化石油ワックス（Ｏｘｉｄｉｚｅｄ Ｐｅｔｒｏｌｅｕｍ Ｗａｘ）は融点が８０℃、全酸価１７．５ｍｇＫＯＨ／ｇを特徴とするワックスである。またマイクロスタリンワックス（一般的にマイクロワックスと呼ぶ）は高粘度潤滑蒸留分（Ｌｕｄｅ ｄｉｓｔｉｌｌａｔｅ）と脱アスファルト残渣油（Ｄｅａｓｐｈａｌｔｅｄ ｏｉｌ ｆｒｏｍ ｒｅｓｉｄｕｅ）などから溶剤抽出法により脱ろうされたワックスであり、初期には無定形ワックス（Ａｍｏｒｐｈｏｕｓ ｗａｘ）とも呼ばれ、側鎖型飽和炭化水素が主成分の針状形で接着性のある白色または黄色のワックスである。 Oxidized petroleum wax is a wax characterized by a melting point of 80 ° C. and a total acid value of 17.5 mg KOH / g. Microstalline wax (generally referred to as microwax) is a wax that has been dewaxed by a solvent extraction method from a high-viscosity lubricated distillate and a deasphalted oil from residual oil. Is also called an amorphous wax, and is a white or yellow wax having a needle-like shape mainly composed of a side chain type saturated hydrocarbon and having adhesiveness.
油分との親和力が大きいため油分からの分離が簡単でなく、パラフィンワックスに比べて油分含量が高い方である。前記マイクロワックスは別の種類のワックス（鉱物性、植物性ワックス）と調和されて融点および硬度を高めるのに使用される。マイクロワックスは側鎖型飽和炭化水素を有しており、温度による粘度変化が相対的に少ないため最初に使用した酸化石油ワックスの温度による粘度変化の弱点を補完する役割も有する。 Separation from oil is not easy because of its high affinity with oil, and the oil content is higher than that of paraffin wax. The microwax is used in combination with another type of wax (mineral or vegetable wax) to increase the melting point and hardness. Microwax has side chain type saturated hydrocarbons and has a relatively small change in viscosity due to temperature. Therefore, the microwax also has a role of complementing the weak point of change in viscosity due to temperature of the oxidized petroleum wax used first.
このようなマイクロワックスは融点が７０℃で、全酸価が１．５ｍｇＫＯＨ／ｇであることが特徴である。ワックスの含量は、１５〜２５重量％の範囲で使用し、１５重量％未満の場合、防錆性が低下して防錆ワックスの機能を果たすことができず、粘度が過度に低くなり塗布後に流れ落ちてしまう。
また、２５重量％を超過する場合、防錆性は良好であるが乾燥時間が長くなるという問題が発生する。
Such micro waxes are characterized by a melting point of 70 ° C. and a total acid value of 1.5 mg KOH / g. The wax content is in the range of 15 to 25% by weight, and if it is less than 15% by weight, the rust prevention property is lowered and the function of the rust prevention wax cannot be achieved, and the viscosity becomes excessively low after coating. It will flow down.
On the other hand, if it exceeds 25% by weight, the problem is that the rust prevention is good but the drying time is long.
本発明で使用する防錆添加剤は石油スルホン酸カルシウムとジノニルナフタレンスルホン酸バリウムを１０：３５〜２０：４５重量比で使用し、１０：３５重量比未満の場合、防錆性が低くなり、２０：４５重量比を超過する場合、２次流動性が悪くなる問題が発生する。 The rust preventive additive used in the present invention uses petroleum calcium sulfonate and barium dinonylnaphthalene sulfonate in a weight ratio of 10:35 to 20:45. When the weight ratio exceeds 20:45, there is a problem that the secondary fluidity is deteriorated.
金属塩のスルホン酸は世界的に最も多く適用されている防錆添加剤で、アルキル基の種類によって防錆性に違いの発生することが知られている。酸素原子の二重結合からなる金属塩スルホン酸が金属と化学的に吸着を行うため、錆の原因となる水分と酸素の金属表面への付着を遮断する効果がある。また、スルホン酸は金属イオンを付着させて石鹸を作るが、この金属イオンの種類による差異はスルホン酸の性質を左右させる。一般的にバリウムが最も高い防錆性を示し、カルシウムイオンを付着したものは耐熱性が優れている。 The metal salt sulfonic acid is the most commonly applied rust preventive additive in the world, and it is known that the rust preventive property varies depending on the type of alkyl group. Since the metal salt sulfonic acid composed of a double bond of oxygen atoms chemically adsorbs to the metal, it has an effect of blocking the adhesion of moisture and oxygen that cause rust to the metal surface. In addition, sulfonic acid attaches metal ions to make soap, but the difference depending on the type of metal ions affects the properties of sulfonic acid. In general, barium exhibits the highest rust-preventing property, and those to which calcium ions are attached have excellent heat resistance.
このようなスルホン酸はただ防錆性のみを付与するのではなく、溶液システムに添加するワックスを安定化させる効果もあり、流動性を付与する。本発明に使用される石油スルホン酸カルシウムは融点が１８２℃であり、全酸価が４５ｍｇＫＯＨ／ｇであるものを使用し、ジノニルナフタレンスルホン酸バリウムは液状で絶対粘度が１００００ｃＰのものを使用し、含量が４５〜６５重量％の範囲で使用する。４５重量％より少ない場合、防錆性能が落ち、６５重量％を超過する場合、２次流動性が悪くなる。 Such a sulfonic acid not only imparts rust prevention properties but also has an effect of stabilizing the wax added to the solution system and imparts fluidity. Petroleum calcium sulfonate used in the present invention has a melting point of 182 ° C. and a total acid value of 45 mg KOH / g, and dinonyl naphthalene sulfonate barium is liquid and has an absolute viscosity of 10,000 cP. The content is in the range of 45 to 65% by weight. When it is less than 45% by weight, the rust prevention performance is lowered, and when it exceeds 65% by weight, the secondary fluidity is deteriorated.
本発明で使用するアルキド樹脂は多塩基酸と多価アルコールを反応させたエステルを基本とし、再び脂肪酸または油を反応させて得られる成分で、不揮発分１００％の樹脂である。前記アルキド樹脂は４０℃での動粘度が３１ｃＳｔ、全酸価が２２ｍｇＫＯＨ／ｇであるものを使用し、含量は１０〜３０重量％が適当である。１０重量％未満の場合、防錆ワックスが流れ落ちる問題が発生し、３０重量％を超過する場合、貯蔵安定性が低くなる。 The alkyd resin used in the present invention is based on an ester obtained by reacting a polybasic acid and a polyhydric alcohol, and is a component obtained by reacting a fatty acid or oil again, and is a resin having a nonvolatile content of 100%. The alkyd resin has a kinematic viscosity at 40 ° C. of 31 cSt and a total acid value of 22 mgKOH / g, and the content is suitably 10 to 30% by weight. When the amount is less than 10% by weight, a problem occurs that the rust preventive wax flows down, and when it exceeds 30% by weight, the storage stability is lowered.
本発明で使用するその他の添加剤は防錆ワックスの気泡生成を抑制する抑泡剤、車体表面に付いている水分を塗布時に効果的に防錆ワックスに吸収させる界面活性剤、アルキド樹脂を酸化させる乾燥剤、保管時に露出表面の早期硬化を防止するスキン防止剤などの中から選択された少なくとも１種の混合物を使用し、その使用量は０．５〜２重量％である。０．５重量％未満の場合、アルキド樹脂が乾燥しないため容易に流れ落ち、２重量％を超過する場合、すぐに乾燥するため噴霧ができないという問題が発生する。前記抑泡剤はアクリルポリマー、界面活性剤は脂肪酸エステル、乾燥剤はコバルト触媒、表面スキン防止剤はオキシム化合物を使用する。
本発明の防錆ワックス組成物の製造方法は特別に限定しない。
Other additives used in the present invention are a foam inhibitor that suppresses the formation of bubbles in the rust preventive wax, a surfactant that effectively absorbs moisture attached to the surface of the vehicle body into the rust preventive wax, and oxidizes the alkyd resin. At least one mixture selected from a desiccant to be used and a skin inhibitor to prevent premature curing of the exposed surface during storage is used, and the amount used is 0.5 to 2% by weight. When the amount is less than 0.5% by weight, the alkyd resin does not dry, so it easily flows down. The foam inhibitor is an acrylic polymer, the surfactant is a fatty acid ester, the desiccant is a cobalt catalyst, and the surface skin inhibitor is an oxime compound.
The manufacturing method of the rust preventive wax composition of the present invention is not particularly limited.
以下、本発明を下記実施例１〜３によって更に具体的に説明するが、これらは本発明を例示するためのものであり、本発明の範囲を制限しない。 Hereinafter, the present invention will be described more specifically with reference to the following Examples 1 to 3, but these are for illustrating the present invention and do not limit the scope of the present invention.
表１に表す通り、各成分を常温で攪拌器によって混合した後、防錆ワックス組成物を製造し、下記試験を行ってその結果を表２に表した。 As shown in Table 1, after mixing each component with a stirrer at room temperature, an antirust wax composition was produced, the following test was performed, and the results are shown in Table 2.
（比較例１）
実施例１と同様に実施するが、ワックスはソルベント・ナフサの含量が５５％のものを除外し、その他は同様の組成物で下記試験方法を行ない結果を表２に表した。
(Comparative Example 1)
The procedure was the same as in Example 1, except that the wax had a solvent naphtha content of 55%. Other than that, the following test method was carried out with the same composition, and the results are shown in Table 2.
（比較例２）
大韓民国公開特許第１０−２００６−００２１１９８号の実施例１で製造した水溶性防錆ワックス。
A water-soluble rust preventive wax produced in Example 1 of Korean Patent No. 10-2006-0021198.
＜試験方法＞
（１）不揮発分：不揮発分は試料約２ｇを平底容器に採取し、その重さを計り、１０５〜１１０℃に調節された強制換気乾燥機の中で３時間加熱した後、デシケーター中で冷却した後、重さを測定し、下記の式によって算出した。
不揮発分（重量％）＝不揮発分（ｇ）／試料採取量（ｇ）×１００
（２）塩水噴霧試験：ＫＳＭ２１０９によって実施した。
（３）粘度：ブルックフィールド粘度計を使用して評価した。
<Test method>
(1) Non-volatile content: About 2 g of non-volatile content was collected in a flat bottom container, weighed, heated for 3 hours in a forced-air dryer controlled at 105-110 ° C, and then cooled in a desiccator. Then, the weight was measured and calculated by the following formula.
Nonvolatile content (% by weight) = Nonvolatile content (g) / Sample collection amount (g) × 100
(2) Salt spray test: Conducted by KSM2109.
(3) Viscosity: Evaluated using a Brookfield viscometer.
（４）２次流動性：溶剤で洗浄した０．８ｔ×７０×１５０ｍｍの鋼板（ＳＰＣＣ）に防錆剤を１００μになるように塗布し、２４時間放置した後、８０±５℃の雰囲気の中で垂直に２４時間ぶら下げた後、流動長さ（ｍｍ）を測定した。
（５）塗膜に対する影響：ＫＳＭ５４００（塗料一般の試験方法）に凖して評価した。
（６）ゴムに対する影響：ＫＳＭ５４００（塗料一般の試験方法）に凖して評価した。
(4) Secondary fluidity: A 0.8 t × 70 × 150 mm steel plate (SPCC) washed with a solvent was coated with a rust inhibitor to a thickness of 100 μm, allowed to stand for 24 hours, and then in an atmosphere of 80 ± 5 ° C. After hanging vertically for 24 hours, the flow length (mm) was measured.
(5) Influence on coating film: Evaluated according to KSM5400 (test method for paints in general).
(6) Influence on rubber: Evaluated according to KSM5400 (coating test method in general).
以上の結果によると、実施例１〜３は比較例１〜２より不揮発分が多く、作業時に排出される有害揮発性有機成分が大きく改善され、粘度も優れている。
According to the above result, Examples 1-3 have more non-volatile content than Comparative Examples 1-2, the harmful volatile organic component discharged | emitted at the time of a work is improved significantly, and the viscosity is also excellent.
Claims (5)
酸化石油ワックスとマイクロスタリンワックスが１０：５〜１５：１０重量比で混合されたワックス１５〜２５重量％、
石油スルホン酸カルシウムとジノニルナフタレンスルホン酸バリウムが１０：３５〜２０：４５重量比で混合された防錆添加剤４５〜６５重量％、
アルキド樹脂が１０〜３０重量％、および
抑泡剤、乾燥剤、界面活性剤および表面スキン防止剤の中から選択された少なくとも１種の混合物であるその他の添加剤０．５〜２重量％、
を含有することを特徴とする防錆ワックス組成物。 10-20% by weight of naphthenic mineral oil,
15 to 25% by weight of a wax in which an oxidized petroleum wax and a microstalline wax are mixed at a weight ratio of 10: 5 to 15:10
Rust preventive additive 45-65% by weight in which petroleum calcium sulfonate and dinonylnaphthalene sulfonate barium are mixed in a weight ratio of 10: 35-20: 45,
10 to 30% by weight of an alkyd resin, and 0.5 to 2% by weight of other additives that are at least one mixture selected from a defoaming agent, a desiccant, a surfactant, and a surface skin inhibitor.
An anticorrosive wax composition comprising:
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| KR1020060075231A KR100820408B1 (en) | 2006-08-09 | 2006-08-09 | The composition for anticorrosion Wax |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2008038123A true JP2008038123A (en) | 2008-02-21 |
Family
ID=38922196
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006261153A Pending JP2008038123A (en) | 2006-08-09 | 2006-09-26 | Rust preventing wax composition |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20080035881A1 (en) |
| JP (1) | JP2008038123A (en) |
| KR (1) | KR100820408B1 (en) |
| CN (1) | CN101121863A (en) |
| DE (1) | DE102006056688A1 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017002885A1 (en) * | 2015-07-01 | 2017-01-05 | 日本ペイントホールディングス株式会社 | Surface layer-peelable composite coating film, coating composition for forming composite coating film, and method |
| CN106752948A (en) * | 2016-12-07 | 2017-05-31 | 江苏聚冠新材料科技有限公司 | A kind of timber floor edge sealing agent and preparation method thereof |
| WO2017094868A1 (en) * | 2015-12-04 | 2017-06-08 | 日東電工株式会社 | Anti-corrosion paste, anti-corrosion structure and method for producing anti-corrosion structure |
| KR20170078300A (en) * | 2015-12-29 | 2017-07-07 | 김재환 | Waterproofing sheet using PVA film and constructing method thereof |
| US10538676B2 (en) | 2015-07-01 | 2020-01-21 | Nippon Paint Holdings Co., Ltd. | Surface layer-peelable composite coating film, coating composition for forming composite coating film, and method |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| RU2465014C2 (en) * | 2007-05-01 | 2012-10-27 | Блю Лагун Перлс Пти Лтд | Water treatment composition |
| DE202009008205U1 (en) * | 2009-06-09 | 2010-02-11 | Eftec Aftermarket Gmbh | Use of a waxy composition as a coating of surfaces to improve its cleanability |
| KR101150679B1 (en) * | 2010-03-19 | 2012-05-25 | 현대하이스코 주식회사 | Rust preventive oil with excellent anti oil stain property at high temperature |
| DE102011011388A1 (en) | 2011-02-17 | 2011-12-01 | Daimler Ag | Corrosion proof motor car hollow body i.e. motor car door, has opening including edge that is designed as collar projecting into cavity, where height of collar corresponds to predetermined level of corrosion protection material |
| DE102011011389A1 (en) | 2011-02-17 | 2011-12-01 | Daimler Ag | Passage stopper for corrosion proof motor car hollow body i.e. door, fillable with e.g. corrosion protection wax, has head portion whose external dimensions are larger than external dimensions of foot portion |
| KR101338757B1 (en) * | 2012-10-12 | 2013-12-06 | 현대하이스코 주식회사 | Rust preventive oil for galvannealed steel sheet with excellent long time rust prevention |
| EP2865723B1 (en) | 2013-10-23 | 2016-09-14 | Fuchs Europe Schmierstoffe GmbH | Corrosion protection agent for cold application |
| NO342205B1 (en) * | 2014-11-26 | 2018-04-16 | Yara Int Asa | Conditioning agent for a particulate fertilizer to reduce hygroscopicity and dust formation |
| US20160369108A1 (en) * | 2015-06-19 | 2016-12-22 | Hyundai Motor Company | Anticorrosion wax composition containing plate zinc flake |
| CN105038420B (en) * | 2015-07-30 | 2017-12-12 | 苏州金枪新材料股份有限公司 | A kind of preservative and its protective system and anti-corrosion method |
| CN105542660B (en) * | 2016-02-03 | 2017-12-19 | 江苏泰尔新材料股份有限公司 | A kind of heat molten type protective wax composite |
| CN106867321B (en) * | 2016-12-15 | 2019-03-08 | 沈阳帕卡濑精有限总公司 | A kind of low VOC total solids part cavity flooding Wax composition |
| ES2870526T3 (en) * | 2018-12-18 | 2021-10-27 | Fuchs Petrolub Se | Corrosion inhibitor for cavity sealing and use |
| CN112647082B (en) * | 2020-12-11 | 2022-10-28 | 中国航发北京航空材料研究院 | Electronic equipment corrosion inhibitor and preparation method thereof |
| CN116042095B (en) * | 2022-10-18 | 2023-08-29 | 青岛迪恩特尚核新材料科技有限公司 | Modified petrolatum anti-corrosion paste and preparation method thereof |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3671012A (en) * | 1970-03-16 | 1972-06-20 | Continental Oil Co | Grease compositions containing polymers |
| US3746643A (en) * | 1970-10-21 | 1973-07-17 | Continental Oil Co | Grease and rust inhibitor compositions |
| JPS5682843A (en) * | 1979-12-08 | 1981-07-06 | Nippon Oil Co Ltd | Wax emulsion |
| US4629753A (en) * | 1981-11-18 | 1986-12-16 | The Lubrizol Corporation | Water dispersed rust inhibitive coating compositions |
| US4729791A (en) * | 1985-02-25 | 1988-03-08 | Witco Corporation | Corrosion-inhibiting coating compositions for metals |
| US4728578A (en) * | 1986-08-13 | 1988-03-01 | The Lubrizol Corporation | Compositions containing basic metal salts and/or non-Newtonian colloidal disperse systems and vinyl aromatic containing polymers |
| JPS63189475A (en) * | 1987-01-30 | 1988-08-05 | Nissan Motor Co Ltd | Rust preventive coating agent |
| JPH05195261A (en) * | 1992-01-23 | 1993-08-03 | Yushiro Chem Ind Co Ltd | Rust preventive composition for underfloor of automobile |
| JPH0762568A (en) * | 1993-08-26 | 1995-03-07 | Yushiro Chem Ind Co Ltd | Water-in-oil type rust inhibitor |
| US5455075A (en) * | 1994-03-10 | 1995-10-03 | Daubert Chemical Company, Inc. | Hot melt corrosion inhibiting coating composition |
| US5888281A (en) * | 1997-08-22 | 1999-03-30 | Daubert Chemical Company, Inc. | Corrosion inhibiting composition |
| KR100246141B1 (en) | 1997-12-22 | 2000-04-01 | 정몽규 | Composition of wax for vehicle with anticorrosion and cold resistance |
| JP4351945B2 (en) | 2004-03-31 | 2009-10-28 | 新日本石油株式会社 | Rust preventive composition |
| US7820076B2 (en) * | 2005-10-27 | 2010-10-26 | The United States Of America As Represented By The Secretary Of The Navy | Oleaginous corrosion and mildew-inhibiting composition |
-
2006
- 2006-08-09 KR KR1020060075231A patent/KR100820408B1/en not_active IP Right Cessation
- 2006-09-26 JP JP2006261153A patent/JP2008038123A/en active Pending
- 2006-11-08 US US11/595,402 patent/US20080035881A1/en not_active Abandoned
- 2006-11-30 CN CNA2006101633064A patent/CN101121863A/en active Pending
- 2006-11-30 DE DE102006056688A patent/DE102006056688A1/en not_active Withdrawn
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017002885A1 (en) * | 2015-07-01 | 2017-01-05 | 日本ペイントホールディングス株式会社 | Surface layer-peelable composite coating film, coating composition for forming composite coating film, and method |
| US10538676B2 (en) | 2015-07-01 | 2020-01-21 | Nippon Paint Holdings Co., Ltd. | Surface layer-peelable composite coating film, coating composition for forming composite coating film, and method |
| WO2017094868A1 (en) * | 2015-12-04 | 2017-06-08 | 日東電工株式会社 | Anti-corrosion paste, anti-corrosion structure and method for producing anti-corrosion structure |
| KR20170078300A (en) * | 2015-12-29 | 2017-07-07 | 김재환 | Waterproofing sheet using PVA film and constructing method thereof |
| KR101898444B1 (en) * | 2015-12-29 | 2018-09-13 | 김재환 | Waterproofing sheet using PVA film and constructing method thereof |
| CN106752948A (en) * | 2016-12-07 | 2017-05-31 | 江苏聚冠新材料科技有限公司 | A kind of timber floor edge sealing agent and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR100820408B1 (en) | 2008-04-10 |
| US20080035881A1 (en) | 2008-02-14 |
| CN101121863A (en) | 2008-02-13 |
| KR20080013551A (en) | 2008-02-13 |
| DE102006056688A1 (en) | 2008-02-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2008038123A (en) | Rust preventing wax composition | |
| JP5550492B2 (en) | Rust prevention oil composition | |
| JP2008050518A (en) | Lubrication oil for press processing and method for press processing metallic material using the same | |
| US2382699A (en) | Slushing oil compositions | |
| JPWO2019188809A1 (en) | Rust-preventive oil composition and its manufacturing method | |
| JP4276141B2 (en) | Rust prevention composition | |
| WO2018088013A1 (en) | Rust preventive oil composition for iron products coated with iron oxide | |
| JP5228213B2 (en) | Liquid lubricant composition | |
| JP2007153962A (en) | Rust preventive oil composition also serving as machining fluid | |
| JP7169909B2 (en) | Rust preventive oil composition and method for producing the same | |
| KR101150679B1 (en) | Rust preventive oil with excellent anti oil stain property at high temperature | |
| JP2020143358A (en) | Rust-proof oil composition and its manufacturing method | |
| JP4575232B2 (en) | Rust prevention method for steel | |
| JP5502848B2 (en) | Anti-rust oil composition for processing | |
| JP7014931B2 (en) | Cavity protection anticorrosive and its use | |
| JPH09183992A (en) | Cleaning and rust preventive oil composition for plastic forming | |
| JP6133660B2 (en) | Rust prevention composition | |
| JP3639876B2 (en) | Rust preventive lubricant composition for plastic working | |
| KR102387026B1 (en) | Hydrogenated natural oils in rust preventive coatings | |
| JP3103859B2 (en) | Anti-rust oil composition for bearings | |
| JP2002339086A (en) | Raw material for rust preventive for steel tube and composition thereof | |
| SE461984B (en) | PROTECTIVE AND LUBRICATION COMPOSITION FOR METAL PLATES | |
| CN113416488A (en) | All-solid automobile chassis anti-corrosion wax composition | |
| JP2004124192A (en) | Water base rust preventive composition | |
| CN115786020A (en) | High-performance soft film anti-rust oil |