JP2008037837A5 - - Google Patents

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Publication number
JP2008037837A5
JP2008037837A5 JP2006217700A JP2006217700A JP2008037837A5 JP 2008037837 A5 JP2008037837 A5 JP 2008037837A5 JP 2006217700 A JP2006217700 A JP 2006217700A JP 2006217700 A JP2006217700 A JP 2006217700A JP 2008037837 A5 JP2008037837 A5 JP 2008037837A5
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JP
Japan
Prior art keywords
carboxylic acid
producing
polyhydric alcohol
esterification reaction
dehydration esterification
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Pending
Application number
JP2006217700A
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Japanese (ja)
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JP2008037837A (en
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Priority to JP2006217700A priority Critical patent/JP2008037837A/en
Priority claimed from JP2006217700A external-priority patent/JP2008037837A/en
Publication of JP2008037837A publication Critical patent/JP2008037837A/en
Publication of JP2008037837A5 publication Critical patent/JP2008037837A5/ja
Pending legal-status Critical Current

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Claims (3)

ゲル型の酸性イオン交換樹脂の存在下で多価アルコールとカルボン酸とを脱水エステル化反応させてカルボン酸モノエステルを製造する方法。  A method for producing a carboxylic acid monoester by dehydrating a polyhydric alcohol and a carboxylic acid in the presence of a gel-type acidic ion exchange resin. 平均細孔径が２００Å以下の固体酸触媒の存在下で多価アルコールとカルボン酸とを脱水エステル化反応させてカルボン酸モノエステルを製造する方法。   A method for producing a carboxylic acid monoester by subjecting a polyhydric alcohol and a carboxylic acid to a dehydration esterification reaction in the presence of a solid acid catalyst having an average pore diameter of 200 mm or less. 前記脱水エステル化反応の際に、固体酸触媒の乾燥質量に対し７０質量％〜１０００質量％の水を反応系内に存在させることを特徴とする請求項１または２に記載の方法。 Wherein upon the dehydration esterification reaction, a method according to claim 1 or 2, characterized in that the presence of 70 wt% to 1000% by weight of water with respect to the dry weight of the solid acid catalyst in the reaction system.
JP2006217700A 2006-08-10 2006-08-10 Method for producing monoester Pending JP2008037837A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006217700A JP2008037837A (en) 2006-08-10 2006-08-10 Method for producing monoester

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006217700A JP2008037837A (en) 2006-08-10 2006-08-10 Method for producing monoester

Publications (2)

Publication Number Publication Date
JP2008037837A JP2008037837A (en) 2008-02-21
JP2008037837A5 true JP2008037837A5 (en) 2009-09-03

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ID=39173271

Family Applications (1)

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JP2006217700A Pending JP2008037837A (en) 2006-08-10 2006-08-10 Method for producing monoester

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JP (1) JP2008037837A (en)

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008174483A (en) * 2007-01-18 2008-07-31 Gifu Univ Method for producing carboxylic acid polyhydric alcohol ester
JP5147759B2 (en) * 2009-03-02 2013-02-20 株式会社日本触媒 Method for producing ethylene glycol (meth) acrylate
WO2020032271A1 (en) * 2018-08-10 2020-02-13 国立大学法人東北大学 Production method for polyvalent alcohol ester compounds
CN114515597B (en) * 2020-11-19 2023-05-09 中国石油化工股份有限公司 Esterification catalyst, preparation method thereof and application thereof in esterification synthesis reaction of acetic acid and alcohol

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB782480A (en) * 1954-10-26 1957-09-04 Olin Mathieson Method of producing mono-esters of monocarboxylic acids with di- or tri-hydric alcohols
CS154962B1 (en) * 1971-08-19 1974-04-30
JP3246958B2 (en) * 1992-09-22 2002-01-15 広栄化学工業株式会社 Method for producing polyhydric alcohol (meth) acrylate monoester
JPH0959280A (en) * 1995-08-24 1997-03-04 Toyota Central Res & Dev Lab Inc Catalyst for synthesizing porphyrin
JPH09267042A (en) * 1996-01-29 1997-10-14 Showa Denko Kk Acid catalyst consisting of acid salt of heteropoly-acid
JPH11193262A (en) * 1997-11-06 1999-07-21 Mitsubishi Rayon Co Ltd Production of hydroxyalkyl mono (meth) acrylate
JP2002088019A (en) * 2000-09-08 2002-03-27 Nippon Shokubai Co Ltd Method for producing (meth)acrylic acid ester
JP2003334441A (en) * 2002-03-13 2003-11-25 Kyoeisha Chem Co Ltd Solid acid catalyst for esterifying carboxylic acid
JP2005336110A (en) * 2004-05-27 2005-12-08 Mitsubishi Chemicals Corp Method for producing (meth)acrylic acid and (meth)acrylic acid ester

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