JP2008007737A - Waste plastic-pyrolyzed oil production system - Google Patents

Waste plastic-pyrolyzed oil production system Download PDF

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JP2008007737A
JP2008007737A JP2006202538A JP2006202538A JP2008007737A JP 2008007737 A JP2008007737 A JP 2008007737A JP 2006202538 A JP2006202538 A JP 2006202538A JP 2006202538 A JP2006202538 A JP 2006202538A JP 2008007737 A JP2008007737 A JP 2008007737A
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pyrolysis
chamber
pyrolysis chamber
waste plastic
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Jiro Oikawa
二郎 及川
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GS KK
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/62Plastics recycling; Rubber recycling

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Abstract

<P>PROBLEM TO BE SOLVED: To provide a polymeric waste plastic pyrolysis system designed not to entrain the outside air in charging feedstock( waste plastics ) thereinto and continuously discharging char therefrom. <P>SOLUTION: The polymeric waste plastic pyrolysis system comprises a multi-tiered pyrolysis chamber 10 including conveying screws 11, a heating chamber 20 for heating the pyrolysis chamber 10, a reduced-pressure charging section 50 equipped with a reduced-pressure pipe 55 connected to a charging port 13 so as to charge feedstock into the pyrolysis chamber 10 while blocking entraining the outside air, a gas collection chamber 100 designed to collect pyrolyzed gas via an exhaust pipe 14 and feed to a refining facility to liquefy the pyrolyzed gas by heat exchanging effect, a reduced-pressure discharge section 60 equipped with a pressure-reducing section 62 so as to discharge treated waste plastics via the exit 15 of the pyrolysis chamber while blocking entraining the outside air, and a vacuum pump 70 equipped for the pressure reduction of the pyrolysis chamber through being connected to the exit 15. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

この考案はビニール,ゴム,合成樹脂などの高分子類の廃棄物を低酸素状態から高熱による熱分解過程に分解過程から出てくる油化ガスをリサイクルできるようにした高分子類廃棄物の熱分解焼却装置に関したことである。  This device is designed to recycle the waste of polymer waste such as vinyl, rubber, and synthetic resin from low oxygen state to pyrolysis process by high heat. It is about decomposition incinerator.

一般的な合成樹脂など高分子類の処理方法はリサイクルする事ができるものを分類して再生源料で利用されているが、その比率はきわめて微々で大体に埋めたてや焼却によって処理されているので、資源浪費だけでなく深刻な大気及び環境汚染を誘発しているのが現実である。
中間部に減圧移送部(12)を持ったスクリューコンベア(10)と、
下方の一つの軸に高熱を供給するバ−ナ−(50)を装備して上段に熱路(61)を形成した加熱線(60)と、
上記加熱室(60)に複数個を横熱に装備してジグザグに移送スクリュー(73)が内在された連結通路(75)を通して連動されるように設置され、入口(71)をスクリューコンベヤー(10)と投入口(80)に連結した多段の熱分解室(70)と
上記の三段の熱分解室(70)の入口の出口に各々設置されるロータリーバルブ(R)と、
上記の三段の熱分解室(70)で熱分解ガスを各排気管(74)に通して砲集して熱交換作用によって液化させる精製設備に送るようにしたガス砲集室(90)に構成されている。
上記の先出願では多重の熱分解室内部に外部空気の流入を制御して低酸素の状態を持つようにするためにスクリューコンベアー(10)に減圧装置を設置してまた三段の熱分解室の出入り口にそれぞれのロータリーバルブを設置している。
しかし熱分解装置は長時間の運転が行われるところで、このような作動の中には真空吸入装置を継続的に作動させて熱分解室の内部に空気の流入を遮断されるようにするので運転中には真空ポンプなどが一緒に継続的に作動されなければならないことによって真空ポンプが長時間の運転時には相当な負荷を耐えられなく、故障が発生されて長時間の運転が出来ない問題点があった。
また熱分解室の出入り口にそれぞれロータリーバルブが設置されて内部に空気の流入を制御できるようにしていたが、ビニールを投入するときビニールの特性でロータリーバルブにひっかかる現象のために原料の投入が正常に行われない場合が発生されてるし,また連結構成が複雑で別途の駆動手段が要求されて製作単価を上昇させる等の問題点があった。
General synthetic resin and other polymer processing methods are classified into those that can be recycled and are used as recycling raw materials. However, the ratio is extremely small and is roughly buried or incinerated. Therefore, it is a reality that it induces not only resource waste but also serious air and environmental pollution.
A screw conveyor (10) having a vacuum transfer section (12) in the middle;
A heating line (60) equipped with a burner (50) for supplying high heat to one lower shaft and forming a heat path (61) in the upper stage;
A plurality of the heating chambers (60) are installed in the transverse heat, and are installed in a zigzag manner so as to be linked through a connecting passage (75) in which a transfer screw (73) is incorporated, and the inlet (71) is connected to the screw conveyor (10 ) And a multistage pyrolysis chamber (70) connected to the input port (80), and rotary valves (R) installed at the outlets of the inlets of the three-stage pyrolysis chamber (70),
In the above-mentioned three-stage pyrolysis chamber (70), the pyrolysis gas is passed through each exhaust pipe (74) and collected into a gas gun collection chamber (90) where it is sent to a purification facility that liquefies by heat exchange. It is configured.
In the above-mentioned prior application, a decompression device is installed in the screw conveyor (10) in order to control the inflow of external air into the multiple pyrolysis chambers so as to have a low oxygen state, and a three-stage pyrolysis chamber. Each rotary valve is installed at the entrance.
However, the pyrolysis device is operated for a long time, and in such an operation, the vacuum suction device is continuously operated so that the inflow of air into the pyrolysis chamber is blocked. There is a problem that the vacuum pump, etc. must be continuously operated together, so that the vacuum pump cannot withstand a considerable load when operating for a long time, and a failure occurs and it cannot be operated for a long time. there were.
In addition, rotary valves were installed at the entrances and exits of the pyrolysis chamber to control the inflow of air inside. However, when vinyl was introduced, the raw material was normally input due to the phenomenon of vinyl being caught in the rotary valve. In some cases, there is a problem that the connection structure is complicated and the connection structure is complicated and a separate driving means is required, which increases the production unit cost.

上記の従来の問題点を解決するために提案されたこの考案は
原料(廃棄物)の投入時、スクリューコンベヤーによって原料が自体の圧縮を遂行されるようにして廃プラスチックの形状や破砕程度に影響されなくても空気流入の遮断する効果を極大化させたし、排出口またスクリューコンベヤーの下端に圧縮部をおいて、生産物である炭(char)の連続排出時、外部空気の引入を防止するようにした高分子類の廃棄物の熱分解焼却装置を提供することである。
また搬入される廃棄物に人為的に隔膜を置いて真空ポンプを通して持続的に空気を除去した既存工程に比べてこの考案では熱分解工程1回に限って空気除去装置を使用すれば、持続的な低酸素の雰囲気が維持されるので、空気除去装置の寿命を延長する事ができるし、熱分解室を三段に構成して熱分解の過程が十分に行われながら効率性を高めることができる。
This device, proposed to solve the above-mentioned conventional problems, has an effect on the shape and degree of crushing of waste plastic by allowing the raw material (waste) to be compressed by the screw conveyor when it is charged. Even if it is not done, the effect of blocking the air inflow is maximized, and a compression part is placed at the lower end of the discharge port or screw conveyor to prevent the introduction of external air during continuous discharge of the product char. An object of the present invention is to provide a thermal decomposition incineration apparatus for polymer wastes.
In addition, compared with the existing process in which air is continuously removed through a vacuum pump by manually placing a diaphragm on the waste to be carried in, this device can be sustained if the air removal device is used only once in the thermal decomposition process. A low-oxygen atmosphere is maintained, so the life of the air removal device can be extended, and the thermal decomposition chamber can be configured in three stages to increase efficiency while the thermal decomposition process is sufficiently performed. it can.

以下,貼付した図面によってこの考案の望ましい実施例を詳細に説明すればつぎになる。
図1はこの考案の全体構成を現したことであり、図2はこの考案での減圧投入部を表せた拡大図であり、図3は図2のA−A線の断面図であり,図4はこの考案での減圧排出部を現したところ、
一つの軸にバーナー(40)を装備して上段に煙道(30)を形成して可燃室(20)に横熱をジグザグに形成して、連結通路(12)として連動されながら駆動手段(82)によって回動される移送スクリュー(11)がそれぞれ内在された多段の熱分解室(10)と、
上記の熱分解室(10)の投入口(13)につながっているようにしながら、ピッチを漸進的に減らして圧力を高める移送スクリュー(51)の羽が駆動手段(81)によって回動されるようにした減圧投入部(50)と、
上記の熱分解室(10)で熱分解ガスを各排気管(14)を通して砲集して熱交換作用によって液化させて精製設備に送るようにしたガス砲集室(100)と、
上記の熱分解室(10)の出口に設置されて移送スクリュー(61)が駆動手段(83)によって回動されるようにして減圧排出部(60)と、上記出口(15)に連結されて熱分解室(10)を減圧させるように具備した真空ポンプ(70)に構成する。
上記の減圧投入部(50)は前方にスクリュー軸と(52)を支持するように支持体(53)を装備して後方に移送される原料が圧縮されて投入口(13)に連結される減圧管(55)を具備する。
上記の減圧投入部(50)でスクリュー管(54)の内面に長さと方向でビニールの移送能力を高めるために突起を適正間隔を置いて形成させる移送ガイド(57)を付着して、またスクリュー管(54)に減圧管(55)をフランジ連結と連結して保守及び設置が容易であるように構成する。
上記の減圧排出部(60)は外側部に処理される廃棄物が集められてきたものが詰められるようにして、外部空気の流入を遮断するように減圧部(62)を具備する。
上記で駆動手段(81,82,83)はモーターの駆動が移送スクリュー(11,51,61)に軸線されたスプロケットにチェーンをかけて動力が伝達されるようにしたのである。
図面の符号56はホッパで、90は熱分解装置を支持する機台だ。
これのように構成したこの考案に対する作用を説明すれば、
とりあえずこの考案を作動させるときには減圧排出部(60)の減圧部(62)を外部から人為的に臨時遮断させた後、この考案を作動させるところ、
ゴム,合成樹などの高分子類の廃プラスチックを適正な大きさに破砕して、ビニールなど廃プラスチックの直接減圧移送部(50)の外軸に装備したホッパ(56)に投入すれば駆動手段(81)によって回動される移送スクリュー(51)によって廃棄物が移送される過程で破砕されながら移送スクリュー(51)のピッチがますます小さくなって廃プラスチックの移送速度が遅滞され、移送スクリュー(51)内の空間に廃プラスチックが密集される状態に減圧管(55)に送られる。
ここでスクリュー管(54)の内面に適正な間隔で移送ガイド(57)が形成されていて廃プラスチックの中ビニール種類は移送の途中に移送ガイド(57)の間の溝にひっかかることもあるので、移送スクリュー(51)に巻きつかなく移送がスムーズになるし,このような過程で減圧観(55)に廃棄物が集められてきたものが詰められるようになって、徐々に滞って投入口(13)を通して熱分解室(10)に供給されるので、この過程から減圧管(55)に廃プラスチックが圧縮で満たされて外部の空気が投入口(13)を通じて熱分解室(10)に流入することが制御される機能を遂行することになる。
このように減圧投入口(50)に空気流入が遮断されて、減圧排出部(60)も臨時的に遮断されることによって、出口(15)に連結されて作動される真空ポンプ(70)によって熱分解室(10)の内部を減圧させて低酸所状態を維持させることによって、正常的な熱分解作用ができることである。
そして三段の熱分解室(10)に投入された廃プラスチックは駆動手段(82)によって回動される移送スクリュー(11)によって移送されて連結通路(13)を通して2,3次の熱分解室(10)にそれぞれの段階的に移送されて、移送される過程からバーナー(40)によって高熱が供給される加熱室(20)の高熱によって熱分解作用が行われて,下段の熱分解室(10)を経て出てくる処理された廃棄物が出口(15)と連結された減圧排出口(60)の移送スクリュー(61)によって減圧部(62)に送られれば、減圧部(62)に処理された灰形態の廃棄物が集められてきたものが詰められるようになって、徐々に滞りながら外部に排出するようになって,この過程から減圧部(62)に処理された廃プラスチックが満たされることによって、外部の空気が出口(51)を通じて熱分解室(10)に流入することを制御する機能を遂行するので、人為的に臨時的に遮断したことを除去されると,真空ポンプ(70)は熱分解室(10)に適正な圧力からマイナスになればオフさせればよい。
上記の過程によって熱分解室(10)の内に低酸素状態で高熱によって、段階的に移送される廃プラスチックが熱分解作用が行われて、この過程から発生される油化ガスなどの分解ガスは各熱分解室(10)の側断に形成された各排気管(14)を通じてガス砲集室(100)に流入され,砲集されたガスは別途の熱交換作用で液化させる精製設備によって燃料で使われることができる液化燃料を得ることができるようで、熱分解作用を経て残存するアスファルトコンクリートなどの残存物は徐々に外部へ押されながら排出するようになることである。
Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the attached drawings.
FIG. 1 shows the overall configuration of the present invention, FIG. 2 is an enlarged view showing a decompression input portion in the present invention, and FIG. 3 is a cross-sectional view taken along the line AA of FIG. 4 shows the decompression discharge part in this device.
Equipped with a burner (40) on one shaft, forming a flue (30) in the upper stage, forming lateral heat in the combustible chamber (20) in a zigzag, and driving means ( 82) multistage pyrolysis chambers (10) each containing a transfer screw (11) rotated by
While being connected to the inlet (13) of the above-described pyrolysis chamber (10), the blades of the transfer screw (51) that gradually reduces the pitch and increases the pressure are rotated by the drive means (81). A reduced pressure charging section (50),
A gas gun collection chamber (100) in which pyrolysis gas is collected through each exhaust pipe (14) in the above pyrolysis chamber (10), liquefied by heat exchange action, and sent to a purification facility;
Installed at the outlet of the pyrolysis chamber (10), the transfer screw (61) is rotated by the drive means (83) and is connected to the vacuum discharge part (60) and the outlet (15). The pyrolysis chamber (10) is configured as a vacuum pump (70) provided to reduce the pressure.
The decompression charging part (50) is equipped with a support (53) so as to support the screw shaft and (52) in the front, and the raw material transferred rearward is compressed and connected to the charging port (13). A pressure reducing tube (55) is provided.
A transfer guide (57) is formed on the inner surface of the screw pipe (54) to increase the vinyl transfer capability in the length and direction, and the screw guide (57) is formed at an appropriate interval. The pressure reducing pipe (55) is connected to the pipe (54) with a flange connection so that maintenance and installation are easy.
The decompression discharge part (60) includes a decompression part (62) so as to block the inflow of external air so that wastes to be treated are collected on the outer side.
In the above, the drive means (81, 82, 83) is configured such that the power is transmitted by applying a chain to the sprocket whose axis is driven by the transfer screw (11, 51, 61).
Reference numeral 56 in the drawing is a hopper, and 90 is a machine base for supporting the thermal decomposition apparatus.
If we explain the action for this device configured like this,
For the time being, when this device is operated, the pressure-reducing part (62) of the pressure-reducing discharge part (60) is artificially shut off temporarily from the outside, and then this device is operated.
Driving means by crushing polymer waste plastics such as rubber and synthetic trees into an appropriate size and putting them in a hopper (56) mounted on the outer shaft of a waste plastic plastic (50) direct decompression transfer unit (50) While the waste is being crushed by the transfer screw (51) rotated by (81), the pitch of the transfer screw (51) becomes smaller and smaller while the waste plastic is being crushed, and the transfer speed of the waste plastic is delayed. 51) is sent to the pressure reducing pipe (55) so that the waste plastic is densely packed in the space inside.
Here, the transfer guide (57) is formed at an appropriate interval on the inner surface of the screw tube (54), and the middle vinyl type of waste plastic may get caught in the groove between the transfer guide (57) during the transfer. The transfer screw (51) does not wrap around and the transfer becomes smooth, and in this process, the waste collected in the decompression view (55) is packed, gradually lagging in the input port. Since it is supplied to the thermal decomposition chamber (10) through (13), waste plastic is filled in the decompression pipe (55) by compression from this process, and external air enters the thermal decomposition chamber (10) through the inlet (13). Inflow will perform the function controlled.
In this way, the air inflow is blocked at the pressure reducing inlet (50) and the pressure reducing discharge part (60) is also temporarily blocked by the vacuum pump (70) connected to the outlet (15) and operated. By depressurizing the inside of the pyrolysis chamber (10) and maintaining the low acidity state, a normal pyrolysis action can be performed.
The waste plastic put into the three-stage pyrolysis chamber (10) is transferred by the transfer screw (11) rotated by the driving means (82) and passes through the connecting passage (13) to obtain the second and third pyrolysis chambers. In step (10), the pyrolysis action is carried out by the high heat of the heating chamber (20) to which high heat is supplied by the burner (40) from the transferred process, and the lower pyrolysis chamber ( 10) If the treated waste coming out via 10) is sent to the decompression section (62) by the transfer screw (61) of the decompression discharge port (60) connected to the outlet (15), the decompression section (62) As a result, the waste collected in the form of treated ash is packed and gradually discharged to the outside, and the waste plastic treated in the decompression unit (62) is discharged from this process. Filled Therefore, the function of controlling the outside air flowing into the pyrolysis chamber (10) through the outlet (51) is performed. 70) may be turned off if the pressure in the pyrolysis chamber (10) becomes negative from the appropriate pressure.
Through the above process, the waste plastic transferred in stages in the pyrolysis chamber (10) in a low oxygen state with high heat undergoes a pyrolysis action, and a cracked gas such as oily gas generated from this process. Is introduced into the gas gun collection chamber (100) through the exhaust pipes (14) formed on the side of each pyrolysis chamber (10), and the collected gas is liquefied by a separate heat exchange action. It is possible to obtain a liquefied fuel that can be used as a fuel. Residues such as asphalt concrete remaining through a thermal decomposition action are gradually pushed out and discharged.

以上のようでこの考案は廃プラスチックを熱分解室に投入前に機械的の分離及び減圧ではなく、廃プラスチック自体の工程の減圧を行うようにすることによって、熱分解作用を安全に遂行することができるようにする効果があって、また作動中に中止されても熱分解室に外部空気の流入が制御され、安全性を確保することができるだけでなく構造が簡単で製作単価を大幅に減らすことができることは勿論、維持・保守が容易な効果がある。  As described above, this device can perform the pyrolysis action safely by reducing the pressure of the waste plastic itself rather than mechanically separating and reducing the pressure before putting the waste plastic into the pyrolysis chamber. In addition, it can control the flow of external air into the thermal decomposition chamber even if it is stopped during operation, ensuring safety and simplifying the structure, greatly reducing the manufacturing cost. Of course, there is an effect that maintenance and maintenance are easy.

はこの発明の構成を表す全体の構成図Is an overall configuration diagram showing the configuration of the present invention はこの発明において減圧投入部を表す拡大図Is an enlarged view showing a pressure reducing charging portion in the present invention は図2のA−A線の断面図Is a sectional view taken along line AA in FIG. はこの発明において減圧排出部を表す拡大図Is an enlarged view showing a vacuum discharge part in the present invention

符号の説明Explanation of symbols

10:熱分解室 11,51,61:移送スクリュ−類
12:連結通路 13:投入口
14:排気管
20:加熱室 40:バーナー
50:減圧投入部 53:支持体
54:スクリュー管 55:減圧管
60:減圧排出部 62:減圧部
81,82,83:駆動手段 100:ガス砲集室
DESCRIPTION OF SYMBOLS 10: Pyrolysis chamber 11, 51, 61: Transfer screw 12: Connection channel 13: Input port 14: Exhaust pipe 20: Heating chamber 40: Burner 50: Depressurization introduction part 53: Support body 54: Screw pipe 55: Decompression Tube 60: Depressurization discharge part 62: Decompression part 81, 82, 83: Driving means 100: Gas gun collection chamber

Claims (3)

バーナー(40)に熱源を提供する加熱室(20)に横熱ジグザグで形成して連結通路(12)に連動しながら、駆動手段(82)によって同動される移送スクリュー(11)がそれぞれ内在され、多重の熱分解室(10);
駆動手段(81)によって同動される移送スクリュー(51)により、移送される原料が満たされ、外部空気の流入を遮断されながら、熱分解室(10)の投入口(13)に連結される減圧管(55)を装備した減圧投入部(50);
上記の熱分解室(10)で、熱分解ガスは各排気管(14)を通して砲集して、熱交換作用によって液化させる精製設備に送るようにするガス砲集室(100);
上記の熱分解室(10)の出口(15)で輩出される処理された廃プラスチックを駆動手段(83)に因って回動される移送スクリュー(61)として移送させて廃プラスチックが詰められるようにして、外部空気の流入を遮断するように減圧部(62)を装備した減圧排出部(60);
上記の出口(15)に連結されて熱分解室(10)を減圧させるために装備した真空ポンプ(70);で構成していることが特徴であることと高分子類の廃棄物の熱分解加熱装置。
In the heating chamber (20) that provides a heat source to the burner (40), a transfer screw (11) that is moved by the driving means (82) while being interlocked with the connecting passage (12) is formed in the heating chamber (20). A multiple pyrolysis chamber (10);
The transfer screw (51) driven by the driving means (81) is connected to the inlet (13) of the pyrolysis chamber (10) while the material to be transferred is filled and the inflow of external air is blocked. A pressure reducing inlet (50) equipped with a pressure reducing tube (55);
In the above pyrolysis chamber (10), the pyrolysis gas is collected through each exhaust pipe (14) and sent to a purification facility to be liquefied by heat exchange action (100);
The treated waste plastic produced at the outlet (15) of the pyrolysis chamber (10) is transferred as a transfer screw (61) rotated by the driving means (83), and the waste plastic is packed. Thus, the reduced pressure discharge part (60) equipped with the reduced pressure part (62) so as to block the inflow of external air;
It is characterized by comprising a vacuum pump (70) connected to the outlet (15) and equipped to depressurize the pyrolysis chamber (10), and pyrolysis of polymer wastes Heating device.
第1項において、
上記の減圧投入部(50)でスクリュー管(54)の内面に長さと方向に適正な間隔を置いて形成させる移送ガイドを(57)を付着した高分子類の廃棄物の熱分解加熱装置。
In item 1,
A polymer waste pyrolysis heating apparatus in which (57) is attached to a transfer guide which is formed on the inner surface of the screw tube (54) at an appropriate interval in the length and direction by the reduced pressure input section (50).
代表図
図1
熱分解加熱装置,熱分解室,減圧投入,減圧管
Figure 1
Pyrolysis heating device, pyrolysis chamber, reduced pressure input, pressure reducing tube
JP2006202538A 2006-06-28 2006-06-28 Waste plastic-pyrolyzed oil production system Pending JP2008007737A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2458690A (en) * 2008-03-28 2009-09-30 Dyfodol Energy Ltd Treatment of waste plastics material
KR100941964B1 (en) 2008-04-14 2010-02-11 김기석 The Refined Oil Manufacturing Device for Coking Prevention
CN103589445A (en) * 2013-11-26 2014-02-19 杨金国 Harmless continuous pyrolyzing device for waste tire powder
KR101490414B1 (en) 2012-12-07 2015-02-04 주식회사 재원에너지 Fever disassemble pipe of variable pitch type and oil extraction apparatus using the same
JP2016508161A (en) * 2012-12-17 2016-03-17 グローバル ヴェロシティー ホールディング リミテッド Tire refining method and equipment

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2458690A (en) * 2008-03-28 2009-09-30 Dyfodol Energy Ltd Treatment of waste plastics material
GB2458690B (en) * 2008-03-28 2012-10-03 Dyfodol Energy Ltd Treatment of waste plastics material
KR100941964B1 (en) 2008-04-14 2010-02-11 김기석 The Refined Oil Manufacturing Device for Coking Prevention
KR101490414B1 (en) 2012-12-07 2015-02-04 주식회사 재원에너지 Fever disassemble pipe of variable pitch type and oil extraction apparatus using the same
JP2016508161A (en) * 2012-12-17 2016-03-17 グローバル ヴェロシティー ホールディング リミテッド Tire refining method and equipment
CN103589445A (en) * 2013-11-26 2014-02-19 杨金国 Harmless continuous pyrolyzing device for waste tire powder
CN103589445B (en) * 2013-11-26 2015-12-02 杨金国 The innoxious continuous pyrolysis device of a kind of scrap tire powder

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