JP2007517975A5 - - Google Patents
Download PDFInfo
- Publication number
- JP2007517975A5 JP2007517975A5 JP2006549685A JP2006549685A JP2007517975A5 JP 2007517975 A5 JP2007517975 A5 JP 2007517975A5 JP 2006549685 A JP2006549685 A JP 2006549685A JP 2006549685 A JP2006549685 A JP 2006549685A JP 2007517975 A5 JP2007517975 A5 JP 2007517975A5
- Authority
- JP
- Japan
- Prior art keywords
- weight percent
- composition
- difluoro
- group
- trifluoro
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 claims description 45
- XRKOOHTZZDPJNE-UHFFFAOYSA-N 1,1,1-trifluorohexane Chemical compound CCCCCC(F)(F)F XRKOOHTZZDPJNE-UHFFFAOYSA-N 0.000 claims description 10
- GQSMEOJGQJMOHA-UHFFFAOYSA-N 1,1,3-trifluoropropane Chemical compound FCCC(F)F GQSMEOJGQJMOHA-UHFFFAOYSA-N 0.000 claims description 10
- JKYLNUHIUDXCMN-UHFFFAOYSA-N 1,2-difluoropentane Chemical compound CCCC(F)CF JKYLNUHIUDXCMN-UHFFFAOYSA-N 0.000 claims description 10
- CXHPKSYTQFAXIN-UHFFFAOYSA-N 1,4-difluorobutane Chemical compound FCCCCF CXHPKSYTQFAXIN-UHFFFAOYSA-N 0.000 claims description 10
- 239000003507 refrigerant Substances 0.000 claims description 9
- 238000005057 refrigeration Methods 0.000 claims description 9
- OLURRGJWZJYRIM-UHFFFAOYSA-N 1,3-difluoro-2-methylpropane Chemical compound FCC(C)CF OLURRGJWZJYRIM-UHFFFAOYSA-N 0.000 claims description 8
- 239000012530 fluid Substances 0.000 claims description 8
- 238000004378 air conditioning Methods 0.000 claims description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-Hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims 4
- 125000001931 aliphatic group Chemical group 0.000 description 11
- 125000004432 carbon atoms Chemical group C* 0.000 description 11
- 125000002723 alicyclic group Chemical group 0.000 description 6
- 150000002430 hydrocarbons Chemical class 0.000 description 6
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000002904 solvent Substances 0.000 description 5
- GVEUEBXMTMZVSD-UHFFFAOYSA-N 3,3,4,4,5,5,6,6,6-nonafluorohex-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C=C GVEUEBXMTMZVSD-UHFFFAOYSA-N 0.000 description 4
- ZYGHJZDHTFUPRJ-UHFFFAOYSA-N Coumarin Chemical compound C1=CC=C2OC(=O)C=CC2=C1 ZYGHJZDHTFUPRJ-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 239000007850 fluorescent dye Substances 0.000 description 4
- 238000007906 compression Methods 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichloro-1,2,2-trifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N Anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- VWCLQNINSPFHFV-UHFFFAOYSA-N C1=CC=C2C3=CC=C4OC5=CC=CC=C5CC4=C3C=CC2=C1 Chemical compound C1=CC=C2C3=CC=C4OC5=CC=CC=C5CC4=C3C=CC2=C1 VWCLQNINSPFHFV-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- YNPNZTXNASCQKK-UHFFFAOYSA-N Phenanthrene Chemical compound C1=CC=C2C3=CC=CC=C3C=CC2=C1 YNPNZTXNASCQKK-UHFFFAOYSA-N 0.000 description 2
- PQJUJGAVDBINPI-UHFFFAOYSA-N Thioxanthene Chemical compound C1=CC=C2CC3=CC=CC=C3SC2=C1 PQJUJGAVDBINPI-UHFFFAOYSA-N 0.000 description 2
- GJCOSYZMQJWQCA-UHFFFAOYSA-N Xanthene Chemical compound C1=CC=C2CC3=CC=CC=C3OC2=C1 GJCOSYZMQJWQCA-UHFFFAOYSA-N 0.000 description 2
- 150000001408 amides Chemical class 0.000 description 2
- 125000004429 atoms Chemical group 0.000 description 2
- XJHABGPPCLHLLV-UHFFFAOYSA-N benzo[de]isoquinoline-1,3-dione Chemical compound C1=CC(C(=O)NC2=O)=C3C2=CC=CC3=C1 XJHABGPPCLHLLV-UHFFFAOYSA-N 0.000 description 2
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 2
- 229960000956 coumarin Drugs 0.000 description 2
- 235000001671 coumarin Nutrition 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 125000000743 hydrocarbylene group Chemical group 0.000 description 2
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 150000002596 lactones Chemical class 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- LYGJENNIWJXYER-UHFFFAOYSA-N Nitromethane Chemical group C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 125000002619 bicyclic group Chemical group 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- -1 carbon atoms Aryl ethers Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- 125000001183 hydrocarbyl group Chemical group 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000873 masking Effects 0.000 description 1
- 201000002674 obstructive nephropathy Diseases 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
Description
データは、本発明の組成物がＣＦＣ−１１３に類似のエバポレーターおよび凝縮器圧力を有することを示す。幾つかの組成物はまた、ＣＦＣ−１１３より高いキャパシティまたはエネルギー効率（ＣＯＰ）を有する。
本発明は、以下の態様を含む。
（態様１）
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，１，３−トリフルオロプロパン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，４−ジフルオロブタン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，３−ジフルオロ−２−メチルプロパン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，２−ジフルオロペンタン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，１，１−トリフルオロヘキサン、ならびに
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする冷媒または伝熱流体組成物。
（態様２）
遠心圧縮機を用いる冷凍またはエアコン機器で使用するための冷媒または伝熱流体組成物であって、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，１，３−トリフルオロプロパン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，４−ジフルオロブタン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，３−ジフルオロ−２−メチルプロパン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，２−ジフルオロペンタン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，１，１−トリフルオロヘキサン、ならびに
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする組成物。
（態様３）
（ｉ）多段遠心圧縮機、（ｉｉ）シングルスラブ／ワンパス熱交換器を用いる冷凍またはエアコン機器で使用するための冷媒または伝熱流体組成物であって、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，１，３−トリフルオロプロパン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，４−ジフルオロブタン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，３−ジフルオロ−２−メチルプロパン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，２−ジフルオロペンタン、
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および１，１，１−トリフルオロヘキサン、ならびに
Ｃ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする組成物。
（態様４）
約１〜約６３重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および約９９〜約３７重量パーセントの１，１，３−トリフルオロプロパン、
約１〜約９９重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および約９９〜約１重量パーセントの１，３−ジフルオロ−２−メチルプロパン、
約１〜約９９重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および約９９〜約１重量パーセントの重量パーセントの１，４−ジフルオロブタン、
約１〜約９９重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および約９９〜約１重量パーセントの１，２−ジフルオロペンタン、
約１〜約９９重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および約９９〜約１重量パーセントの１，１，１−トリフルオロヘキサン、ならびに
約１〜約９９重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および約９９〜約１重量パーセントの３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする共沸または擬共沸組成物。
（態様５）
約４４．２℃の温度で約１４．７ｐｓｉａ（１０１ｋＰａ）の蒸気圧を有する２１．４重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および７８．６重量パーセントの１，１，３−トリフルオロプロパン、
約７４．２℃の温度で約１４．７ｐｓｉａ（１０１ｋＰａ）の蒸気圧を有する７７．４重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および２２．６重量パーセントの１，４−ジフルオロブタン、
約７２．５℃の温度で約１４．７ｐｓｉａ（１０１ｋＰａ）の蒸気圧を有する６１．４重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および３８．６重量パーセントの１，２−ジフルオロペンタン、ならびに
約７２．２℃の温度で約１４．７ｐｓｉａ（１０１ｋＰａ）の蒸気圧を有する５６．６重量パーセントのＣ ４ Ｆ ９ ＯＣ ２ Ｈ ５ および４３．４重量パーセントの１，１，１−トリフルオロヘキサン
よりなる群から選択されることを特徴とする共沸組成物。
（態様６）
冷却される物体の近傍で上記態様１〜４のいずれか一つに記載の組成物を蒸発させ、その後前記組成物を凝縮させる工程を含むことを特徴とする冷却をもたらすための方法。
（態様７）
加熱される物体の近傍で上記態様１〜４のいずれか一つに記載の組成物を凝縮させ、その後前記組成物を蒸発させる工程を含むことを特徴とする熱をもたらすための方法。
（態様８）
前記組成物を熱源からヒートシンクへ移す工程を含むことを特徴とする伝熱のための上記態様１〜４のいずれか一つに記載の組成物の使用方法。
（態様９）
ナフタルイミド、ペリレン、クマリン、アントラセン、フェナントレン、キサンテン、チオキサンテン、ナフトキサンテン、フルオレセイン、前記染料の誘導体、およびそれらの組合せよりなる群から選択された少なくとも１つの紫外線蛍光染料をさらに含むことを特徴とする上記態様１に記載の組成物。
（態様１０）
ナフタルイミド、ペリレン、クマリン、アントラセン、フェナントレン、キサンテン、チオキサンテン、ナフトキサンテン、フルオレセイン、前記染料の誘導体およびそれらの組合せよりなる群から選択された少なくとも１つの紫外線蛍光染料をさらに含むことを特徴とする上記態様２〜４のいずれか一つに記載の組成物。
（態様１１）
炭化水素、ジメチルエーテル、ポリオキシアルキレングリコールエーテル、アミド、ケトン、ニトリル、クロロカーボン、エステル、ラクトン、アリールエーテル、ヒドロフルオロエーテル、および１，１，１−トリフルオロアルカンよりなる群から選択された少なくとも１つの可溶化剤をさらに含み、冷媒および可溶化剤が同じ化合物ではないことを特徴とする上記態様９に記載の組成物。
（態様１２）
前記可溶化剤が、
ａ）式Ｒ １ ［（ＯＲ ２ ） ｘ ＯＲ ３ ］ ｙ （式中、ｘが１〜３の整数であり、ｙが１〜４の整数であり、Ｒ １ が水素および１〜６個の炭素原子とｙ個の結合部位とを有する脂肪族炭化水素基から選択され、Ｒ ２ が２〜４個の炭素原子を有する脂肪族ヒドロカルビレン基から選択され、Ｒ ３ が水素、ならびに１〜６個の炭素原子を有する脂肪族および脂環式炭化水素基から選択され、Ｒ １ およびＲ ３ の少なくとも１つが前記炭化水素基から選択される）で表され、約１００〜約３００原子質量単位の分子量を有するポリオキシアルキレングリコールエーテル、
ｂ）式Ｒ １ ＣＯＮＲ ２ Ｒ ３ およびシクロ−［Ｒ ４ ＣＯＮ（Ｒ ５ ）−］（式中、Ｒ １ 、Ｒ ２ 、Ｒ ３ およびＲ ５ が独立して１〜１２個の炭素原子を有する脂肪族および脂環式炭化水素基、ならびに６〜１２個の炭素原子を有する多くても１つの芳香族基から選択され、Ｒ ４ が３〜１２個の炭素原子を有する脂肪族ヒドロカルビレン基から選択される）で表され、約１００〜約３００原子質量単位の分子量を有するアミド、
ｃ）式Ｒ １ ＣＯＲ ２ （式中、Ｒ １ およびＲ ２ が独立して１〜１２個の炭素原子を有する脂肪族、脂環式およびアリール炭化水素基から選択される）で表され、約７０〜約３００原子質量単位の分子量を有するケトン、
ｄ）式Ｒ １ ＣＮ（式中、Ｒ １ が５〜１２個の炭素原子を有する脂肪族、脂環式またはアリール炭化水素基から選択される）で表され、約９０〜約２００原子質量単位の分子量を有するニトリル、
ｅ）式ＲＣｌ ｘ （式中、ｘが整数１または２から選択され、Ｒが１〜１２個の炭素原子を有する脂肪族および脂環式炭化水素基から選択される）で表され、約１００〜約２００原子質量単位の分子量を有するクロロカーボン、
ｆ）式Ｒ １ ＯＲ ２ （式中、Ｒ １ が６〜１２個の炭素原子を有するアリール炭化水素基から選択され、Ｒ ２ が１〜４個の炭素原子を有する脂肪族炭化水素基から選択される）で表され、約１００〜約１５０原子質量単位の分子量を有するアリールエーテル、
ｇ）式ＣＦ ３ Ｒ １ （式中、Ｒ １ が約５〜約１５個の炭素原子を有する脂肪族および脂環式炭化水素基から選択される）で表される１，１，１−トリフルオロアルカン、
ｉ）式Ｒ １ ＯＣＦ ２ ＣＦ ２ Ｈ（式中、Ｒ １ が約５〜約１５個の炭素原子を有する脂肪族および脂環式炭化水素基から選択される）で表されるヒドロフルオロエーテル、および
ｊ）構造［Ｂ］、［Ｃ］、および［Ｄ］
ｋ）一般式Ｒ １ ＣＯ ２ Ｒ ２ （式中、Ｒ １ およびＲ ２ が独立して線状および環式の、飽和および不飽和の、アルキルおよびアリール基から選択される）で表され、約８０〜約５５０原子質量単位の分子量を有するエステル、
よりなる群から選択されることを特徴とする上記態様１１に記載の組成物。
（態様１３）
（ｉ）紫外線蛍光染料を可溶化剤の存在下で伝熱流体の冷媒組成物に溶解させ、該組合せを前記圧縮冷凍もしくはエアコン機器へ導入すること、または（ｉｉ）可溶化剤とＵＶ蛍光染料とを組み合わせ、前記組合せを冷媒および／または伝熱流体を含有する冷凍もしくはエアコン機器へ導入することによって組成物を圧縮冷凍またはエアコン機器へ導入する工程を含むことを特徴とする上記態様９または１１に記載の組成物の使用方法。
（態様１４）
前記組成物を前記機器に提供する工程と、前記機器の漏洩ポイントでまたは近傍で前記組成物を検出するための好適な手段を提供する工程とを含むことを特徴とする圧縮冷凍またはエアコン機器での上記態様９または１１に記載の組成物の使用方法。
（態様１５）
（ｉ）冷却される物体の近傍で前記組成物を蒸発させ、その後前記組成物を凝縮させることによって冷却をもたらす工程、または
（ｉｉ）加熱される物体の近傍で前記組成物を凝縮させ、その後前記組成物を蒸発させることによって熱をもたらす工程
を含むことを特徴とする上記態様９または１１に記載の組成物の使用方法。
（態様１６）
熱安定剤または臭気を帯びたマスキング剤をさらに含むことを特徴とする上記態様１〜４のいずれか一つに記載の組成物。
（態様１７）
前記熱安定剤がニトロメタンであることを特徴とする上記態様１６に記載の組成物。
（態様１８）
多段遠心圧縮機を用いる冷凍またはエアコン機器で熱または冷却をもたらすことを含むことを特徴とする上記態様３に記載の組成物の使用方法。
（態様１９）
前記多段遠心圧縮機が２段遠心圧縮機であることを特徴とする上記態様１８に記載の方法。
The data show that the composition of the present invention has an evaporator and condenser pressure similar to CFC-113. Some compositions also have higher capacity or energy efficiency (COP) than CFC-113.
The present invention includes the following aspects.
(Aspect 1)
C 4 F 9 OC 2 H 5 and 1,1,3-trifluoro-propane,
C 4 F 9 OC 2 H 5 and 1,4-difluorobutane,
C 4 F 9 OC 2 H 5 and 1,3-difluoro-2-methylpropane,
C 4 F 9 OC 2 H 5 and 1,2-difluoro-pentane,
C 4 F 9 OC 2 H 5 and 1,1,1-trifluoro-hexane, and
C 4 F 9 OC 2 H 5 and 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene
A refrigerant or heat transfer fluid composition characterized by being selected from the group consisting of:
(Aspect 2)
A refrigerant or heat transfer fluid composition for use in refrigeration or air conditioning equipment using a centrifugal compressor,
C 4 F 9 OC 2 H 5 and 1,1,3-trifluoro-propane,
C 4 F 9 OC 2 H 5 and 1,4-difluorobutane,
C 4 F 9 OC 2 H 5 and 1,3-difluoro-2-methylpropane,
C 4 F 9 OC 2 H 5 and 1,2-difluoro-pentane,
C 4 F 9 OC 2 H 5 and 1,1,1-trifluoro-hexane, and
C 4 F 9 OC 2 H 5 and 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene
A composition selected from the group consisting of:
(Aspect 3)
(I) a multi-stage centrifugal compressor, (ii) a refrigerant or heat transfer fluid composition for use in refrigeration or air conditioning equipment using a single slab / one-pass heat exchanger,
C 4 F 9 OC 2 H 5 and 1,1,3-trifluoro-propane,
C 4 F 9 OC 2 H 5 and 1,4-difluorobutane,
C 4 F 9 OC 2 H 5 and 1,3-difluoro-2-methylpropane,
C 4 F 9 OC 2 H 5 and 1,2-difluoro-pentane,
C 4 F 9 OC 2 H 5 and 1,1,1-trifluoro-hexane, and
C 4 F 9 OC 2 H 5 and 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene
A composition selected from the group consisting of:
(Aspect 4)
About 1 to about 63 weight percent C 4 F 9 OC 2 H 5 and about 99 to about 37 weight percent 1,1,3-trifluoropropane;
From about 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and from about 99 to about 1 weight percent 1,3-difluoro-2-methylpropane;
From about 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and from about 99 to about 1 weight percent weight percent 1,4-difluorobutane;
From about 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and from about 99 to about 1 weight percent 1,2-difluoropentane;
About 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and about 99 to about 1 weight percent 1,1,1-trifluorohexane, and
About 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and about 99 to about 1 weight percent 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene
An azeotropic or pseudoazeotropic composition, characterized in that it is selected from the group consisting of:
(Aspect 5)
21.4 weight percent C 4 F 9 OC 2 H 5 and 78.6 weight percent 1,1,3-trifluoropropane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 44.2 ° C. ,
77.4 weight percent C 4 F 9 OC 2 H 5 and 22.6 weight percent 1,4-difluorobutane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 74.2 ° C . ;
61.4 weight percent C 4 F 9 OC 2 H 5 and 38.6 weight percent 1,2-difluoropentane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 72.5 ° C. , and
56.6 weight percent C 4 F 9 OC 2 H 5 and 43.4 weight percent 1,1,1-trifluorohexane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 72.2 ° C.
An azeotropic composition characterized in that it is selected from the group consisting of:
(Aspect 6)
A method for providing cooling comprising the steps of: evaporating a composition according to any one of the above aspects 1-4 in the vicinity of an object to be cooled and then condensing the composition.
(Aspect 7)
A method for producing heat, comprising the step of condensing the composition according to any one of the above aspects 1 to 4 in the vicinity of an object to be heated and subsequently evaporating the composition.
(Aspect 8)
The method of using the composition according to any one of the above aspects 1 to 4 for heat transfer, comprising a step of transferring the composition from a heat source to a heat sink.
(Aspect 9)
And further comprising at least one ultraviolet fluorescent dye selected from the group consisting of naphthalimide, perylene, coumarin, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, derivatives of the dye, and combinations thereof. The composition according to aspect 1 above.
(Aspect 10)
It further comprises at least one ultraviolet fluorescent dye selected from the group consisting of naphthalimide, perylene, coumarin, anthracene, phenanthrene, xanthene, thioxanthene, naphthoxanthene, fluorescein, derivatives of the dyes, and combinations thereof. The composition according to any one of the above aspects 2 to 4.
(Aspect 11)
At least one selected from the group consisting of hydrocarbon, dimethyl ether, polyoxyalkylene glycol ether, amide, ketone, nitrile, chlorocarbon, ester, lactone, aryl ether, hydrofluoroether, and 1,1,1-trifluoroalkane The composition according to embodiment 9, wherein the composition further comprises two solubilizers, and the refrigerant and the solubilizer are not the same compound.
(Aspect 12)
The solubilizer is
a) Formula R 1 [(OR 2 ) x OR 3 ] y (wherein x is an integer of 1 to 3, y is an integer of 1 to 4, R 1 is hydrogen and 1 to 6 carbons) Selected from an aliphatic hydrocarbon group having an atom and y binding sites, R 2 is selected from an aliphatic hydrocarbylene group having 2 to 4 carbon atoms, R 3 is hydrogen, and 1-6 Selected from aliphatic and cycloaliphatic hydrocarbon groups having 1 carbon atom, wherein at least one of R 1 and R 3 is selected from said hydrocarbon group), about 100 to about 300 atomic mass units Polyoxyalkylene glycol ether having a molecular weight,
b) Formula R 1 CONR 2 R 3 and cyclo- [R 4 CON (R 5 )-], wherein R 1 , R 2 , R 3 and R 5 independently have 1 to 12 carbon atoms. Aliphatic and alicyclic hydrocarbon groups and aliphatic hydrocarbylene groups selected from at most one aromatic group having 6 to 12 carbon atoms and R 4 having 3 to 12 carbon atoms An amide having a molecular weight of from about 100 to about 300 atomic mass units
c) represented by the formula R 1 COR 2 , wherein R 1 and R 2 are independently selected from aliphatic, alicyclic and aryl hydrocarbon groups having 1 to 12 carbon atoms, A ketone having a molecular weight of 70 to about 300 atomic mass units;
d) represented by the formula R 1 CN, wherein R 1 is selected from an aliphatic, alicyclic or aryl hydrocarbon group having 5 to 12 carbon atoms, and about 90 to about 200 atomic mass units A nitrile having a molecular weight of
e) represented by the formula RCl x , wherein x is selected from the integers 1 or 2 and R is selected from aliphatic and alicyclic hydrocarbon groups having 1 to 12 carbon atoms, and about 100 A chlorocarbon having a molecular weight of about 200 atomic mass units;
f) Formula R 1 OR 2 , wherein R 1 is selected from an aryl hydrocarbon group having 6 to 12 carbon atoms, and R 2 is selected from an aliphatic hydrocarbon group having 1 to 4 carbon atoms Aryl ethers having a molecular weight of from about 100 to about 150 atomic mass units,
g) 1,1,1-tri represented by the formula CF 3 R 1 , wherein R 1 is selected from aliphatic and alicyclic hydrocarbon groups having from about 5 to about 15 carbon atoms. Fluoroalkane,
i) a hydrofluoroether represented by the formula R 1 OCF 2 CF 2 H, wherein R 1 is selected from aliphatic and alicyclic hydrocarbon groups having from about 5 to about 15 carbon atoms; and
j) Structures [B], [C], and [D]
k) represented by the general formula R 1 CO 2 R 2 , wherein R 1 and R 2 are independently selected from linear and cyclic, saturated and unsaturated, alkyl and aryl groups; An ester having a molecular weight of 80 to about 550 atomic mass units;
The composition according to the above aspect 11, which is selected from the group consisting of:
(Aspect 13)
(I) dissolving an ultraviolet fluorescent dye in a refrigerant composition of a heat transfer fluid in the presence of a solubilizer and introducing the combination into the compression refrigeration or air conditioner equipment; or (ii) a solubilizer and a UV fluorescent dye. And introducing the composition into a refrigeration or air-conditioning equipment containing a refrigerant and / or a heat transfer fluid, thereby introducing the composition into a compression refrigeration or air-conditioning equipment. Use of the composition described in 1.
(Aspect 14)
A compression refrigeration or air conditioner device comprising: providing the composition to the device; and providing a suitable means for detecting the composition at or near a leakage point of the device. The use method of the composition as described in the said aspect 9 or 11.
(Aspect 15)
(I) providing cooling by evaporating the composition in the vicinity of the object to be cooled and then condensing the composition;
(Ii) providing the heat by condensing the composition in the vicinity of the object to be heated and then evaporating the composition;
A method of using the composition according to the above aspect 9 or 11, characterized by comprising:
(Aspect 16)
5. The composition according to any one of the above aspects 1 to 4, further comprising a heat stabilizer or an odorous masking agent.
(Aspect 17)
The composition according to Aspect 16, wherein the heat stabilizer is nitromethane.
(Aspect 18)
4. Use of the composition according to aspect 3 above, comprising providing heat or cooling in refrigeration or air conditioning equipment using a multi-stage centrifugal compressor.
(Aspect 19)
The method according to aspect 18, wherein the multistage centrifugal compressor is a two-stage centrifugal compressor.
Claims (5)
Ｃ４Ｆ９ＯＣ２Ｈ５および１，４−ジフルオロブタン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，３−ジフルオロ−２−メチルプロパン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，２−ジフルオロペンタン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，１，１−トリフルオロヘキサン、ならびに
Ｃ４Ｆ９ＯＣ２Ｈ５および３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする冷媒または伝熱流体組成物。 C 4 F 9 OC 2 H 5 and 1,1,3-trifluoro-propane,
C 4 F 9 OC 2 H 5 and 1,4-difluorobutane,
C 4 F 9 OC 2 H 5 and 1,3-difluoro-2-methylpropane,
C 4 F 9 OC 2 H 5 and 1,2-difluoro-pentane,
C 4 F 9 OC 2 H 5 and 1,1,1-trifluoro-hexane, and C 4 F 9 OC 2 H 5 and 3,3,4,4,5,5,6,6,6-nonafluoro -1 A refrigerant or heat transfer fluid composition, characterized in that it is selected from the group consisting of hexene.
Ｃ４Ｆ９ＯＣ２Ｈ５および１，１，３−トリフルオロプロパン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，４−ジフルオロブタン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，３−ジフルオロ−２−メチルプロパン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，２−ジフルオロペンタン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，１，１−トリフルオロヘキサン、ならびに
Ｃ４Ｆ９ＯＣ２Ｈ５および３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする組成物。 A refrigerant or heat transfer fluid composition for use in refrigeration or air conditioning equipment using a centrifugal compressor,
C 4 F 9 OC 2 H 5 and 1,1,3-trifluoro-propane,
C 4 F 9 OC 2 H 5 and 1,4-difluorobutane,
C 4 F 9 OC 2 H 5 and 1,3-difluoro-2-methylpropane,
C 4 F 9 OC 2 H 5 and 1,2-difluoro-pentane,
C 4 F 9 OC 2 H 5 and 1,1,1-trifluoro-hexane, and C 4 F 9 OC 2 H 5 and 3,3,4,4,5,5,6,6,6-nonafluoro -1 A composition characterized in that it is selected from the group consisting of hexene.
Ｃ４Ｆ９ＯＣ２Ｈ５および１，１，３−トリフルオロプロパン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，４−ジフルオロブタン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，３−ジフルオロ−２−メチルプロパン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，２−ジフルオロペンタン、
Ｃ４Ｆ９ＯＣ２Ｈ５および１，１，１−トリフルオロヘキサン、ならびに
Ｃ４Ｆ９ＯＣ２Ｈ５および３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする組成物。 (I) a multi-stage centrifugal compressor, (ii) a refrigerant or heat transfer fluid composition for use in refrigeration or air conditioning equipment using a single slab / one-pass heat exchanger,
C 4 F 9 OC 2 H 5 and 1,1,3-trifluoro-propane,
C 4 F 9 OC 2 H 5 and 1,4-difluorobutane,
C 4 F 9 OC 2 H 5 and 1,3-difluoro-2-methylpropane,
C 4 F 9 OC 2 H 5 and 1,2-difluoro-pentane,
C 4 F 9 OC 2 H 5 and 1,1,1-trifluoro-hexane, and C 4 F 9 OC 2 H 5 and 3,3,4,4,5,5,6,6,6-nonafluoro -1 A composition characterized in that it is selected from the group consisting of hexene.
約１〜約９９重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および約９９〜約１重量パーセントの１，３−ジフルオロ−２−メチルプロパン、
約１〜約９９重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および約９９〜約１重量パーセントの重量パーセントの１，４−ジフルオロブタン、
約１〜約９９重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および約９９〜約１重量パーセントの１，２−ジフルオロペンタン、
約１〜約９９重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および約９９〜約１重量パーセントの１，１，１−トリフルオロヘキサン、ならびに
約１〜約９９重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および約９９〜約１重量パーセントの３，３，４，４，５，５，６，６，６−ノナフルオロ−１−ヘキセン
よりなる群から選択されることを特徴とする共沸または擬共沸組成物。 About 1 to about 63 weight percent C 4 F 9 OC 2 H 5 and about 99 to about 37 weight percent 1,1,3-trifluoropropane;
From about 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and from about 99 to about 1 weight percent 1,3-difluoro-2-methylpropane;
About 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and about 99 to about 1 weight percent weight percent 1,4-difluorobutane;
From about 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and from about 99 to about 1 weight percent 1,2-difluoropentane;
About 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and about 99 to about 1 weight percent 1,1,1-trifluorohexane, and about 1 to about 99 weight percent C 4 F 9 OC 2 H 5 and about 99 to about 1 weight percent of 3,3,4,4,5,5,6,6,6-nonafluoro-1-azeotropic or pseudo, characterized in that it is selected from the group consisting of hexene Azeotropic composition.
約７４．２℃の温度で約１４．７ｐｓｉａ（１０１ｋＰａ）の蒸気圧を有する７７．４重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および２２．６重量パーセントの１，４−ジフルオロブタン、
約７２．５℃の温度で約１４．７ｐｓｉａ（１０１ｋＰａ）の蒸気圧を有する６１．４重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および３８．６重量パーセントの１，２−ジフルオロペンタン、ならびに
約７２．２℃の温度で約１４．７ｐｓｉａ（１０１ｋＰａ）の蒸気圧を有する５６．６重量パーセントのＣ４Ｆ９ＯＣ２Ｈ５および４３．４重量パーセントの１，１，１−トリフルオロヘキサン
よりなる群から選択されることを特徴とする共沸組成物。 21.4 weight percent C 4 F 9 OC 2 H 5 and 78.6 weight percent 1,1,3-trifluoropropane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 44.2 ° C. ,
77.4 weight percent C 4 F 9 OC 2 H 5 and 22.6 weight percent 1,4-difluorobutane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 74.2 ° C .;
61.4 weight percent C 4 F 9 OC 2 H 5 and 38.6 weight percent 1,2-difluoropentane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of about 72.5 ° C., and about From 56.6 weight percent C 4 F 9 OC 2 H 5 and 43.4 weight percent 1,1,1-trifluorohexane having a vapor pressure of about 14.7 psia (101 kPa) at a temperature of 72.2 ° C. An azeotropic composition characterized by being selected from the group consisting of:
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US53681904P | 2004-01-14 | 2004-01-14 | |
| US11/013,901 US7208099B2 (en) | 2004-01-14 | 2004-12-16 | Refrigerant compositions comprising 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane and a hydrofluorocarbon and uses thereof |
| PCT/US2005/001509 WO2005067558A2 (en) | 2004-01-14 | 2005-01-12 | Refrigerant compositions comprising 1-ethoxy-1,1,2,2,3,3,4,4-nonafluorobutane and a hydrofluorocarbon and uses thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2007517975A JP2007517975A (en) | 2007-07-05 |
| JP2007517975A5 true JP2007517975A5 (en) | 2008-02-28 |
Family
ID=34797978
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006549685A Pending JP2007517975A (en) | 2004-01-14 | 2005-01-12 | Refrigerant composition comprising 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane and hydrofluorocarbon and use thereof |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP1711576A2 (en) |
| JP (1) | JP2007517975A (en) |
| KR (1) | KR20060123531A (en) |
| AR (1) | AR049614A1 (en) |
| AU (1) | AU2005204955A1 (en) |
| BR (1) | BRPI0506522A (en) |
| CA (1) | CA2553276A1 (en) |
| NO (1) | NO20063644L (en) |
| RU (1) | RU2006129298A (en) |
| WO (1) | WO2005067558A2 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7413676B2 (en) | 2005-04-26 | 2008-08-19 | E.I. Du Pont De Nemours And Company | Heat transfer and refrigerant compositions comprising 3,3,4,4,5,5,6,6,6-nonafluoro-1-hexene and a fluoroether |
| CA2922197A1 (en) * | 2005-11-01 | 2007-05-10 | E. I. Du Pont De Nemours And Company | Compositions comprising fluoroolefins and uses thereof |
| US7708903B2 (en) | 2005-11-01 | 2010-05-04 | E.I. Du Pont De Nemours And Company | Compositions comprising fluoroolefins and uses thereof |
| EP1951838B1 (en) * | 2005-11-01 | 2013-07-17 | E.I. Du Pont De Nemours And Company | Compositions comprising fluoroolefins and uses thereof |
| KR20080114757A (en) | 2006-02-28 | 2008-12-31 | 이 아이 듀폰 디 네모아 앤드 캄파니 | Azeotropic compositions comprising fluorinated compounds for cleaning applications |
| GB201002625D0 (en) * | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
| JP2010185048A (en) * | 2009-02-13 | 2010-08-26 | Daikin Ind Ltd | Heat transfer apparatus and heat transfer method, and heat transfer fluid used for the same |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5417871A (en) * | 1994-03-11 | 1995-05-23 | E. I. Du Pont De Nemours And Company | Hydrofluorocarbon compositions |
| US5580906A (en) * | 1995-05-19 | 1996-12-03 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions |
| JP4348510B2 (en) * | 2002-04-25 | 2009-10-21 | ダイキン工業株式会社 | Method for producing synthetic resin foam |
-
2005
- 2005-01-12 CA CA002553276A patent/CA2553276A1/en not_active Abandoned
- 2005-01-12 AU AU2005204955A patent/AU2005204955A1/en not_active Abandoned
- 2005-01-12 WO PCT/US2005/001509 patent/WO2005067558A2/en not_active Application Discontinuation
- 2005-01-12 JP JP2006549685A patent/JP2007517975A/en active Pending
- 2005-01-12 RU RU2006129298/04A patent/RU2006129298A/en not_active Application Discontinuation
- 2005-01-12 EP EP05711559A patent/EP1711576A2/en not_active Withdrawn
- 2005-01-12 KR KR1020067016240A patent/KR20060123531A/en not_active Application Discontinuation
- 2005-01-12 BR BRPI0506522-4A patent/BRPI0506522A/en not_active Application Discontinuation
- 2005-01-14 AR ARP050100138A patent/AR049614A1/en unknown
-
2006
- 2006-08-11 NO NO20063644A patent/NO20063644L/en not_active Application Discontinuation
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2007517975A5 (en) | ||
| JP2007526384A5 (en) | ||
| ES2645091T3 (en) | Trans-chloro-3,3,3-trifluoropropene for use in chiller applications | |
| JPWO2019124409A1 (en) | Refrigeration cycle equipment | |
| JP2008539312A5 (en) | ||
| JPWO2020017522A1 (en) | Refrigeration cycle equipment | |
| JP2016196642A (en) | Heat-transfer fluids and use thereof in countercurrent heat exchangers | |
| JP2007511645A5 (en) | ||
| JP6980771B2 (en) | Compositions based on 1-chloro-3,3,3-trifluoropropene | |
| RU2007103162A (en) | COMPOSITIONS OF REFRIGERATING AGENTS CONTAINING ORGANIC COMPOUNDS WITH FUNCTIONAL GROUPS AND THEIR APPLICATION | |
| JP2008505212A5 (en) | ||
| JP2008539311A5 (en) | ||
| JP6777260B1 (en) | A composition containing a refrigerant, its use, a refrigerator having it, a method of operating the refrigerator, and a refrigerating cycle device having it. | |
| RU2006134980A (en) | COMPOSITIONS OF HALOGENKETONE REFRIGERANTS AND THEIR APPLICATION | |
| WO2021065944A1 (en) | Air conditioning apparatus | |
| WO2020256119A1 (en) | Refrigerant-containing composition, use thereof, refrigerator having same, operation method for said refrigerator, and refrigeration cycle device equipped with said refrigerator | |
| RU2007103173A (en) | COMPOSITIONS OF REFRIGERANTS BASED ON 1-ETOXY-1,1,2,2,3,3,4,4,4-NONAFTORBUTANE CONTAINING ORGANIC COMPOUNDS WITH VARIOUS FUNCTIONAL GROUPS AND THEIR USE | |
| RU2006129298A (en) | REFRIGERANT COMPOSITIONS, INCLUDING 1-ETOXY-1, 1, 2, 2, 3, 3, 4, 4, 4-NONAFTORBUTANE AND HYDROGEN AND HYDROCARBON, AND APPLICATION OF THE INDICATED COMPOSITIONS | |
| JP2007517974A5 (en) | ||
| JP2007517970A5 (en) | ||
| JP2008505211A5 (en) | ||
| JP2005535755A5 (en) | ||
| JP2007517971A5 (en) | ||
| RU2007103192A (en) | REFRIGERANT COMPOSITIONS BASED ON 1,1,1,2,2,3,3,4,4-NONAFTOR-4-METHOXIBUTANE CONTAINING FUNCTIONALIZED ORGANIC COMPOUNDS, AND THEIR APPLICATION | |
| RU2007103186A (en) | 1-ethoxy-1,1,2,2,3,3,4,4,4-nonafluorobutane REFRIGERANT COMPOSITIONS CONTAINING A HYDROCARBON AND THEIR APPLICATION |