JP2007331336A - Fiberboard and its manufacturing method - Google Patents
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本発明は一般住宅の壁、床、天井等に施工される内装材、特に、断熱材としても使用できる繊維板に関する。 The present invention relates to an interior material applied to a wall, floor, ceiling or the like of a general house, and more particularly to a fiberboard that can also be used as a heat insulating material.
従来、防蟻性,防火性および物理的強度に優れた建築用繊維板が提案されている。例えば、鉱物質繊維、有機繊維を主成分とする水性スラリーを抄造してウェットマットを成形した後、前記ウェットマットに、熱水に溶解した硼素化合物を塗布,含浸させて製造される建築用繊維板がある(特許文献1参照)。
しかしながら、前述の製造方法では、硼素化合物を熱水に溶解させる工程が必要であるだけでなく、溶解液をウェットマットに塗布,含浸させる必要があるので、製造作業に手間がかかる。また、硼素化合物を溶解させた溶解液をウェットマットに塗布,含浸させているので、建築用繊維板全体、特に、各繊維表面に均一に硼素化合物を付着させることが困難であった。さらに、硼素化合物を塗布,含浸させるために溶解液を使用するので、繊維表面に付着させる硼素化合物の歩留まりを高めようとすると、硼素化合物の濃度を高めるか、溶解液の液量を増大させる必要があり、生産コストが高い。そして、高濃度の溶解液を使用した場合には、その廃液処理のための処理施設が必要であり、生産コストがより一層高くなるという問題点がある。 However, the above-described production method requires not only a step of dissolving the boron compound in hot water, but also a need for applying and impregnating the solution to the wet mat, which requires labor. Further, since the solution obtained by dissolving the boron compound is applied and impregnated on the wet mat, it is difficult to uniformly adhere the boron compound to the entire fiberboard for construction, particularly to each fiber surface. Furthermore, since the solution is used to apply and impregnate the boron compound, it is necessary to increase the concentration of the boron compound or increase the amount of the solution to increase the yield of the boron compound adhered to the fiber surface. Production costs are high. When a high-concentration solution is used, a treatment facility for treating the waste liquid is required, and there is a problem that the production cost is further increased.
本発明は、前記問題点に鑑み、通常の湿式抄造方法で製造できるとともに、繊維板の各繊維の表面に硼素化合物を均一、かつ、効率的に付着させることにより、高い防蟻性・防腐性を有する繊維板およびその製造方法を提供することを課題とする。 In view of the above problems, the present invention can be manufactured by a normal wet papermaking method, and by uniformly and efficiently depositing a boron compound on the surface of each fiber of the fiberboard, it has high antifungal and antiseptic properties. It is an object of the present invention to provide a fiberboard having the above and a manufacturing method thereof.
本発明者らは、前記問題点を解決すべく、鋭意研究の結果、溶解度の低いホウ素化合物を使用すれば、各繊維の表面に前記ホウ素化合物を均一、かつ、効率的に付着させることができ、防蟻性等が向上することを知見し、この知見に基づいて本願発明を完成した。 As a result of intensive studies to solve the above problems, the present inventors can uniformly and efficiently adhere the boron compound to the surface of each fiber by using a boron compound having low solubility. Based on this finding, the present invention has been completed.
本発明にかかる繊維板は、前記課題を解決すべく、木質繊維と、前記木質繊維の添加量の5重量%以上、50重量%以下で添加される無機質繊維と、温度20℃の溶解度0.01重量%以上、2重量%未満のホウ素化合物と、結合剤と、からなるスラリーを湿式抄造して成形した比重0.2以上、0.3以下としてある。 In order to solve the above problems, the fiberboard according to the present invention has a wood fiber, an inorganic fiber added in an amount of 5% by weight to 50% by weight of the added amount of the wood fiber, and a solubility of 0. A specific gravity of 0.2 or more and 0.3 or less formed by wet papermaking of a slurry comprising 01% by weight or more and less than 2% by weight of a boron compound and a binder.
本発明の繊維板は、溶解度の低いホウ素化合物を添加したスラリーを抄造して製造されるので、木質繊維および無機繊維の各繊維表面に前記ホウ素化合物が均一、かつ、効率的に付着する。このため、従来例のように別工程を必要とせず、生産性が高いだけでなく、防蟻性,防腐性の高い繊維板が得られる。特に、無機繊維が添加されているので、木質繊維だけからなる繊維板よりも優れた防火性をも有する繊維板が得られる。 Since the fiberboard of the present invention is produced by making a slurry to which a boron compound having low solubility is added, the boron compound adheres uniformly and efficiently to the fiber surfaces of the wood fiber and the inorganic fiber. For this reason, a separate process is not required as in the conventional example, and not only the productivity is high, but also a fiberboard having high antproofing and antiseptic properties is obtained. In particular, since an inorganic fiber is added, a fiberboard having a fire resistance superior to a fiberboard made of only wood fibers can be obtained.
本発明にかかる実施形態としては、無機繊維が繊維長さ125μm以上、500μm以下であってもよい。
本実施形態によれば、無機繊維をスラリー中に均一に分散させやすいとともに、強度の大きい繊維板が得られる。
In an embodiment according to the present invention, the inorganic fiber may have a fiber length of 125 μm or more and 500 μm or less.
According to this embodiment, it is easy to disperse the inorganic fibers uniformly in the slurry, and a fiberboard with high strength is obtained.
本発明にかかる他の実施形態としては、前述の繊維板を複数枚、積層一体化して得た積層板の外周に本実加工を施しておいてもよい。
本実施形態によれば、物理的強度が高く、組付作業が容易で組付精度の高い繊維板が得られる。
As other embodiment concerning this invention, you may give this actual process to the outer periphery of the laminated board obtained by carrying out lamination | stacking integration of the above-mentioned several fiber board.
According to this embodiment, a fiberboard having high physical strength, easy assembling work, and high assembling accuracy can be obtained.
本発明にかかる繊維板の製造方法は、木質繊維、前記木質繊維の添加量の5重量%以上、50重量%以下で添加される無機質繊維、温度20℃で溶解度0.01重量%以上、2重量%未満のホウ素化合物、および、結合剤を水中で混合分散させてスラリーを得る工程と、前記スラリーからウェットマットを湿式抄造する工程と、前記ウェットマットをプレスして水分を搾り出し、厚さを整える工程と、搾った前記ウェットマットを加熱,乾燥させて結合剤を硬化させる工程と、からなるものである。 The fiberboard manufacturing method according to the present invention comprises a wood fiber, an inorganic fiber added at 5% by weight or more and 50% by weight or less of the added amount of the wood fiber, a solubility of 0.01% by weight or more at 20 ° C., 2 A step of obtaining a slurry by mixing and dispersing less than% by weight of a boron compound and a binder in water, a step of wet-making a wet mat from the slurry, pressing the wet mat to squeeze moisture, And a step of heating and drying the squeezed wet mat to cure the binder.
本発明の繊維板は、溶解度の低いホウ素化合物を添加したスラリーを抄造して製造されるので、木質繊維および無機繊維の各繊維表面に前記ホウ素化合物が均一、かつ、効率的に付着する。このため、従来例のように別工程を必要とせず、生産性が高いとともに、防蟻性,防腐性の高い繊維板が得られる。特に、無機繊維が添加されているので、木質繊維だけからなる繊維板よりも優れた防火性をも有する繊維板が得られるという効果がある。 Since the fiberboard of the present invention is produced by making a slurry to which a boron compound having low solubility is added, the boron compound adheres uniformly and efficiently to the fiber surfaces of the wood fiber and the inorganic fiber. For this reason, a separate process is not required as in the conventional example, and a fiberboard having high productivity and high antproofing and antiseptic properties can be obtained. In particular, since inorganic fiber is added, there is an effect that a fiberboard having fire resistance superior to that of a fiberboard made of only wood fibers can be obtained.
本発明にかかる繊維板の実施形態としては、木質繊維と、前記木質繊維の添加量の5重量%以上、50重量%以下で添加される無機質繊維と、温度20℃の溶解度0.01重量%以上、2重量%未満のホウ素化合物と、結合剤と、からなるスラリーを湿式抄造して成形した比重0.2以上、0.3以下であることを特徴とする繊維板が挙げられる。 As an embodiment of the fiberboard according to the present invention, a wood fiber, an inorganic fiber added at 5 wt% or more and 50 wt% or less of the addition amount of the wood fiber, and a solubility of 0.01 wt% at a temperature of 20 ° C. As mentioned above, there is a fiberboard characterized by a specific gravity of 0.2 or more and 0.3 or less formed by wet-making a slurry comprising less than 2% by weight of a boron compound and a binder.
木質繊維としては、その樹種を限定するものではなく、針葉樹、広葉樹であってもよく、また、建築廃材、パレット用廃材から得たものでもよく、麻、亜麻等の植物繊維であってもよい。
さらに、木質繊維の添加量は、全固形成分の50重量%〜90重量%が好ましい。50重量%未満であると、木質の特性である吸放湿性が低下し、壁体等に結露が発生しやすくなるからである。また、90重量%を越えると、無機繊維が相対的に少なくなり、必要な防火性能が得られないからである。
The wood fiber is not limited to its tree species, and may be a conifer or a broad-leaved tree, may be obtained from building waste or pallet waste, or may be plant fiber such as hemp or flax. .
Furthermore, the amount of wood fiber added is preferably 50% to 90% by weight of the total solid components. This is because if it is less than 50% by weight, the moisture absorption / release property, which is a characteristic of wood, is lowered, and condensation is likely to occur on the wall body. On the other hand, if it exceeds 90% by weight, the amount of inorganic fibers becomes relatively small and the necessary fireproof performance cannot be obtained.
無機質繊維としては、ロックウール、グラスウール、ミネラネウールおよびガラス繊維などが挙げられ、これらを単独あるいは2種以上組み合わせて使用できる。
また、前記無機質繊維は繊維長が125μm〜500μmであるものが好ましい。125μm未満であると、無機質繊維は粉状体であり、木質繊維間に偏って入り込んだり、あるいは、いわゆるダマになったりし、密度にバラツキが生じて断熱性能にバラツキが生じるからである。一方、500μmを越えると、均一な混合が困難となり、偏在しやすくなり、断熱性能にバラツキが生じるからである。
さらに、前記無機質繊維の添加量は、木質繊維の添加量の5重量%以上、50重量%以下であることが好ましい。5重量%未満であると、難燃効果が乏しくなるからであり、50重量%を越えると、均一に混練しにくくなり、生産性が低下するからである。
Examples of the inorganic fibers include rock wool, glass wool, mineralane wool, and glass fiber, and these can be used alone or in combination of two or more.
The inorganic fiber preferably has a fiber length of 125 μm to 500 μm. If the thickness is less than 125 μm, the inorganic fibers are in a powdery state, and the fibers are unevenly inserted between wood fibers or become so-called lumps, resulting in variations in density and variations in heat insulation performance. On the other hand, when the thickness exceeds 500 μm, uniform mixing becomes difficult, it tends to be unevenly distributed, and the heat insulation performance varies.
Furthermore, it is preferable that the addition amount of the said inorganic fiber is 5 to 50 weight% of the addition amount of a wood fiber. This is because if it is less than 5% by weight, the flame retardant effect becomes poor, and if it exceeds 50% by weight, it becomes difficult to uniformly knead and productivity is lowered.
ホウ素化合物は防蟻性,防腐性を高めるために添加されるものであり、ホウ砂、ホウ酸カルシウム、ホウ酸亜鉛等が挙げられる。
使用するホウ素化合物は、20℃での溶解度が0.01重量%以上、2重量%未満のものが好ましい。0.01重量%未満であると、溶解度が低すぎるため、前記ホウ素化合物を蟻が食べても、その体内で溶解せず、所望の防蟻性は得られないからである。一方、溶解度が2重量%以上であると、溶解しやすいので、ホウ素化合物が繊維の表面に付着しにくくなり、付着効率が低くなるからである。さらに、溶解度が高いと、廃水処理のために高度な廃水処理施設が必要になるからである。
また、ホウ素化合物の粒度は、10〜100μmであることが好ましい。粒度が10μm未満であると、繊維に付着しにくくなり、歩留まりが悪いからであり、100μmを越えると、ホウ素化合物の付着箇所(分散点)が少なくなり、防蟻効果が相対的に低下するからである。
さらに、スラリー作成のために添加するホウ素化合物の添加量は、全固形成分の2重量%以上、10重量%以下であることが好ましい。2重量%未満であると、所望の防蟻性が得られないからであり、10重量%を越えると、防蟻性能の向上が望めないからである。
Boron compounds are added to enhance the antifungal and antiseptic properties, and examples thereof include borax, calcium borate, and zinc borate.
The boron compound used preferably has a solubility at 20 ° C. of 0.01% by weight or more and less than 2% by weight. If the content is less than 0.01% by weight, the solubility is too low, so even if an ant eats the boron compound, it does not dissolve in the body and the desired ant protection cannot be obtained. On the other hand, when the solubility is 2% by weight or more, it is easy to dissolve, so that the boron compound is difficult to adhere to the surface of the fiber, and the adhesion efficiency is lowered. Furthermore, if the solubility is high, an advanced wastewater treatment facility is required for wastewater treatment.
Moreover, it is preferable that the particle size of a boron compound is 10-100 micrometers. If the particle size is less than 10 μm, it will be difficult to adhere to the fiber and the yield will be poor, and if it exceeds 100 μm, the number of boron compound adhesion points (dispersion points) will decrease and the ant-proof effect will be relatively lowered. It is.
Furthermore, it is preferable that the addition amount of the boron compound added for slurry preparation is 2 wt% or more and 10 wt% or less of the total solid components. This is because if it is less than 2% by weight, the desired ant-repellent property cannot be obtained, and if it exceeds 10% by weight, improvement in the ant-repellent performance cannot be expected.
結合剤は、前記木質繊維および前記無機質繊維を結合一体化するためのものであり、例えば、フェノール樹脂、ポバール樹脂、エポキシ樹脂、スターチ等を用いることができ、また、これらを単独あるいは2種類以上組み合わせて使用できる。
そして、前記結合剤の添加量は、全固形成分の1重量%〜10重量%が好ましい。1重量%未満であると、所望の接着力が得られず、板強度が低下するからであり、10重量%を越えると、接着力の増大がなくなり、生産コストだけが上昇するからである。
The binder is for binding and integrating the wood fiber and the inorganic fiber, and for example, phenol resin, poval resin, epoxy resin, starch, etc. can be used, and these can be used alone or in combination of two or more. Can be used in combination.
And the addition amount of the said binder has preferable 1 to 10 weight% of a total solid component. This is because if the amount is less than 1% by weight, the desired adhesive strength cannot be obtained and the plate strength decreases, and if it exceeds 10% by weight, the increase in the adhesive strength is lost and only the production cost increases.
また、必要に応じ、前記スラリーに抄造用添加剤として、ワックス,ロジン,ロジンワックス等の耐水剤、硫酸バンド,ポリ塩化アルミニウム等の凝集剤、または、消泡剤等を適宜添加してもよい。 Further, if necessary, a water-resistant agent such as wax, rosin and rosin wax, a flocculant such as sulfate band and polyaluminum chloride, or an antifoaming agent may be appropriately added to the slurry as a papermaking additive. .
(実施例)
木質繊維としては松および杉の混合材80重量%、無機質繊維としてロックウール12.5重量%、ホウ素化合物として平均粒度20μm、20℃の水における溶解度0.08重量%のホウ酸カルシウム3重量%、結合剤としてスターチ3重量%を清水に投入するとともに、その他、耐水剤、凝集剤、消泡剤等1.5重量%を水中に投入し、攪拌して固形成分2%のスラリーを得た。そして、前記スラリーを抄造してウェットマットを得、これをプレスして水分を搾り出しつつ、厚さを整えた。ついで、前記ウェットマットを乾燥炉で加熱,乾燥して結合剤を硬化させることにより、厚さ20mmの繊維板を得た。この繊維板から長さ20mm、巾20mmの正方形のサンプルを切り出し、このサンプルに対してJIS−K−1571に準じた防蟻性試験を行った。
(Example)
The wood fiber is 80% by weight of pine and cedar mixed material, the inorganic fiber is 12.5% by weight of rock wool, the boron compound is an average particle size of 20 μm, and the solubility in water at 20 ° C. is 3% by weight of calcium borate. In addition, 3% by weight of starch as a binder was added to fresh water, and 1.5% by weight of other water-resistant agents, flocculants, antifoaming agents, etc. were added to water and stirred to obtain a slurry having a solid content of 2%. . Then, the slurry was made to obtain a wet mat, which was pressed to squeeze out moisture and adjust the thickness. Subsequently, the wet mat was heated and dried in a drying furnace to cure the binder, thereby obtaining a fiber board having a thickness of 20 mm. A square sample having a length of 20 mm and a width of 20 mm was cut out from the fiber plate, and an anti-antaliency test according to JIS-K-1571 was performed on the sample.
また、得られた2枚の前記繊維板を接着剤で貼り合わせて厚さ40mmの繊維板とし、さらに、前記繊維板の外周にテノーナー加工を施すことにより、図1に示すような雄実10a,雌実10bを有するサンプル10を得た。そして、前記サンプル10を図2および図3に示すような外断熱工法の断熱材として施工した。
Further, the obtained two fiber boards are bonded to each other with an adhesive to form a fiber board having a thickness of 40 mm, and further, tenoner processing is performed on the outer periphery of the fiber board, whereby a male 10a as shown in FIG.
すなわち、柱11間に所定のピッチで間柱12を配設するとともに、ころび止め13で連結する。さらに、前記柱11,間柱12の間に断熱材14を充填するとともに、前記柱11,間柱12に内装材15および構造用面材16取り付ける。ついで、前記構造用面材16の外向面に前記サンプル10を突き合わせて張り付けるとともに、前記サンプル10の表面に防水紙17を張り付ける。そして、通気用胴縁18を介して外装材19を固定し、目地部分をシールした。なお、20は胴差、21は基礎、22は土台である。
That is, the inter-columns 12 are disposed between the
(比較例)
市販のA級インシュレーションボード(厚さ20mm)から長さ20mm、巾20mmの正方形のサンプルを切り出し、実施例と同様、JIS−K−1571に準じた防蟻性試験を行った。
(Comparative example)
A square sample having a length of 20 mm and a width of 20 mm was cut out from a commercially available class A insulation board (
前述のJIS−K−1571に準じた防蟻性試験の結果、実施例の質量減少率は9%であったのに対し、比較例の質量減少率は19%であった。したがって、市販のA級インシュレーションボードよりも本願発明に係る繊維板の方が高い防蟻性を有することが判った。 As a result of the ant protection test according to the above-mentioned JIS-K-1571, the mass reduction rate of the example was 9%, while the mass reduction rate of the comparative example was 19%. Therefore, it was found that the fiberboard according to the present invention has higher ant protection than the commercially available Class A insulation board.
実施例にかかる繊維板を断熱材として外断熱工法で施工することにより、通常の施工が可能であることを確認できた。 It was confirmed that normal construction was possible by constructing the fiberboard according to the example as a heat insulating material by the outer heat insulation method.
なお、前記A級インシュレーションボードには無機繊維が添加されていないので、本願発明に係る繊維板の方が優れた難燃性,防火性を有することは明かである。 In addition, since the inorganic fiber is not added to the said A class insulation board, it is clear that the fiber board which concerns on this invention has the flame retardance and fireproofing which were excellent.
本願発明に係る繊維板は、前述の内装材,断熱材に限らず、他の建築資材としても使用できるものである。 The fiberboard according to the present invention is not limited to the interior material and the heat insulating material described above, but can be used as other building materials.
10:繊維板
10a:雄実
10b:雌実
10:
Claims (4)
A wood fiber, an inorganic fiber added in an amount of 5% by weight or more and 50% by weight or less of the amount of the wood fiber, a boron compound having a solubility of 0.01% by weight or more and less than 2% by weight at a temperature of 20 ° C., and , A step of mixing and dispersing the binder in water to obtain a slurry, a step of wet-making a wet mat from the slurry, a step of pressing the wet mat to squeeze moisture, and adjusting the thickness, A method of manufacturing a fiberboard, comprising: heating and drying the wet mat to cure the binder.
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JP2006168789A Pending JP2007331336A (en) | 2006-06-19 | 2006-06-19 | Fiberboard and its manufacturing method |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107030807A (en) * | 2017-03-21 | 2017-08-11 | 郭宝龙 | The preparation method of environment-friendly type shaving board |
CN110126056A (en) * | 2019-04-29 | 2019-08-16 | 李珂 | A kind of manufacture craft of fireproof medium-density fiberboard |
CN114311214A (en) * | 2021-12-10 | 2022-04-12 | 大亚人造板集团有限公司 | Manufacturing process of artificial board containing inorganic fiber |
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JPS63135599A (en) * | 1986-11-27 | 1988-06-07 | 王子製紙株式会社 | Paper containing boron compound |
JPH04209900A (en) * | 1990-12-10 | 1992-07-31 | Kuraray Co Ltd | Production of inorganic fiberboard |
JPH0532573U (en) * | 1991-09-27 | 1993-04-27 | 株式会社ノダ | Building board |
JPH0647826A (en) * | 1992-07-29 | 1994-02-22 | Nitto Boseki Co Ltd | Manufacture of fiber plate for building |
JPH0835200A (en) * | 1994-07-22 | 1996-02-06 | Daiken Trade & Ind Co Ltd | Production of fiber board |
JP2005280030A (en) * | 2004-03-29 | 2005-10-13 | Daiken Trade & Ind Co Ltd | Method for producing hard fiberboard |
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JPS63135599A (en) * | 1986-11-27 | 1988-06-07 | 王子製紙株式会社 | Paper containing boron compound |
JPH04209900A (en) * | 1990-12-10 | 1992-07-31 | Kuraray Co Ltd | Production of inorganic fiberboard |
JPH0532573U (en) * | 1991-09-27 | 1993-04-27 | 株式会社ノダ | Building board |
JPH0647826A (en) * | 1992-07-29 | 1994-02-22 | Nitto Boseki Co Ltd | Manufacture of fiber plate for building |
JPH0835200A (en) * | 1994-07-22 | 1996-02-06 | Daiken Trade & Ind Co Ltd | Production of fiber board |
JP2005280030A (en) * | 2004-03-29 | 2005-10-13 | Daiken Trade & Ind Co Ltd | Method for producing hard fiberboard |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107030807A (en) * | 2017-03-21 | 2017-08-11 | 郭宝龙 | The preparation method of environment-friendly type shaving board |
CN107030807B (en) * | 2017-03-21 | 2019-03-12 | 郭宝龙 | The preparation method of environment-friendly type shaving board |
CN110126056A (en) * | 2019-04-29 | 2019-08-16 | 李珂 | A kind of manufacture craft of fireproof medium-density fiberboard |
CN114311214A (en) * | 2021-12-10 | 2022-04-12 | 大亚人造板集团有限公司 | Manufacturing process of artificial board containing inorganic fiber |
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