JP2007302965A - Method for operating apparatus for treating aluminum chip - Google Patents

Method for operating apparatus for treating aluminum chip Download PDF

Info

Publication number
JP2007302965A
JP2007302965A JP2006133750A JP2006133750A JP2007302965A JP 2007302965 A JP2007302965 A JP 2007302965A JP 2006133750 A JP2006133750 A JP 2006133750A JP 2006133750 A JP2006133750 A JP 2006133750A JP 2007302965 A JP2007302965 A JP 2007302965A
Authority
JP
Japan
Prior art keywords
gas
pyrolysis
aluminum chips
pyrolysis furnace
aluminum
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2006133750A
Other languages
Japanese (ja)
Other versions
JP4685702B2 (en
Inventor
Sakae Okayama
栄 岡山
Takeshi Hori
多奎志 堀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fuji Electric Co Ltd
Miyamoto Kogyosho Co Ltd
Original Assignee
Fuji Electric Systems Co Ltd
Miyamoto Kogyosho Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuji Electric Systems Co Ltd, Miyamoto Kogyosho Co Ltd filed Critical Fuji Electric Systems Co Ltd
Priority to JP2006133750A priority Critical patent/JP4685702B2/en
Publication of JP2007302965A publication Critical patent/JP2007302965A/en
Application granted granted Critical
Publication of JP4685702B2 publication Critical patent/JP4685702B2/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Landscapes

  • Processing Of Solid Wastes (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for operating an apparatus for treating aluminum chips containing water and oil, which inhibits white smoke from flowing out to the outside of the apparatus, and prevents the emanation of pyrolysis gases that are harmful to human bodies and have a danger of inflammation. <P>SOLUTION: A pyrolysis furnace receives a raw material such as aluminum chips containing water and oil, heats the raw material, transports it, and discharges the pyrolysis gases containing water vapor, oil vapor and hydrocarbon gases, and the heat-treated aluminum chips; and comprises a kiln 33 and an induction heating coil 34. A treated-substance-discharging means discharges the aluminum chips after having been heat-treated, sucks the pyrolysis gases, liquidizes some of the gases or dissolves some of the gases into water, and discharges them; and comprises a discharge screw 37, a paddle screw 41 and a storage hopper 42. The thermal decomposition method comprises the steps of: introducing nitrogen gas into a kiln; and controlling a gauge pressure in the kiln so as to be approximately equal to or lower than the atmospheric pressure by a gas suction force of a blower 56. <P>COPYRIGHT: (C)2008,JPO&INPIT

Description

この発明は、アルミニウム切粉等の処理装置の運転方法、特にアルミニウム切粉等の原料を連続的に熱処理して不純物を除去しアルミニウムを再利用可能に回収する処理装置の運転方法に関する。この発明において、アルミニウム切粉等とは、アルミニウム製品の製造時に発生するアルミニウム屑、切削屑、シュレッダー屑のほか、使用済のアルミ缶等アルミ製品の使用済屑等のアルミニウム含有物を含む。なお、この発明の運転方法は、この発明の技術思想の範囲内において、アルミニウム以外の金属切粉等にも適用できる。   The present invention relates to a method for operating a processing apparatus such as aluminum chips, and more particularly to a method for operating a processing apparatus that continuously heat-treats raw materials such as aluminum chips to remove impurities and recover aluminum in a reusable manner. In this invention, aluminum chips and the like include aluminum-containing materials such as used scraps of aluminum products such as used aluminum cans in addition to aluminum scraps, cutting scraps and shredder scraps generated during the manufacture of aluminum products. The operating method of the present invention can also be applied to metal chips other than aluminum within the scope of the technical idea of the present invention.

上記アルミニウム切粉等は、溶解炉で溶融再生されアルミニウム資源として回収され、再利用される。しかしながら、アルミニウム切粉等の熱処理前のアルミニウム原料には、一般に、水分と油分とを含むので、これらの不純物を除去するために、溶解炉で溶融処理に先立って加熱処理する方法が行われている。   The aluminum chips and the like are melted and regenerated in a melting furnace, recovered as aluminum resources, and reused. However, since the aluminum raw material before heat treatment such as aluminum chips generally contains moisture and oil, a method of performing a heat treatment prior to the melting treatment in a melting furnace is performed in order to remove these impurities. Yes.

従来、アルミニウム切粉等のリサイクルを目的とした処理装置や処理方法としては、種々の特許出願がなされているが、大別して、処理対象がアルミニウム切粉等に限定されたもの(例えば、特許文献1および2参照。)と、アルミニウム切粉等がその他の廃棄物と混在したもの(例えば、特許文献3および4参照。)とに分類される。さらに、関連する処理技術として、処理対象がアルミニウム切粉等を含まない(もしくは少量含む)一般廃棄物を処理する廃棄物処理装置(例えば、特許文献5参照。)もある。   Conventionally, various patent applications have been filed as processing apparatuses and processing methods for the purpose of recycling aluminum chips and the like, but broadly classified, the processing object is limited to aluminum chips (for example, patent documents) 1 and 2) and those in which aluminum chips and the like are mixed with other wastes (see, for example, Patent Documents 3 and 4). Further, as a related processing technique, there is a waste processing apparatus (for example, refer to Patent Document 5) that processes general waste whose processing target does not include (or includes a small amount of) aluminum chips.

ここでは、本願発明の背景技術として、本願発明の一部の構成に比較的近い技術を開示する特許文献1および特許文献5について、その概要を以下に述べる。   Here, as a background art of the present invention, an outline of Patent Document 1 and Patent Document 5 that disclose a technique relatively close to a part of the configuration of the present invention will be described below.

まず、特許文献1について述べる。図4は、特許文献1に開示されたアルミニウム切削屑等の処理方法に係る装置の概略システム系統図を示す。特許文献1は、その請求項の記載を引用すると、「炉枠は固定式とし、炉両端に軸受けを持った回転軸に設けた撹拌部材からなる内部撹拌装置を備え、密閉した乾留炉内に、可燃物の付着したアルミニウムの切削屑等を供給し、撹拌しながら、付着した可燃物を酸素濃度を制御し温度を300〜500℃に維持して部分燃焼させ、且つ低酸素条件下で加熱乾留処理することを特徴とする可燃物の付着したアルミニウム切削屑等を密閉した乾留炉を用いて連続処理する方法。」を開示する。   First, Patent Document 1 will be described. FIG. 4 is a schematic system diagram of an apparatus related to a method for processing aluminum cutting waste and the like disclosed in Patent Document 1. Patent document 1 quotes the description of the claim. “The furnace frame is fixed, and an internal stirring device comprising a stirring member provided on a rotating shaft having bearings at both ends of the furnace is provided. Supplied with combustible materials, such as aluminum scraps, and while stirring, the combustible materials were partially burned while controlling the oxygen concentration and maintaining the temperature at 300 to 500 ° C, and heated under low oxygen conditions. Disclosed is a method of continuously treating a combustible material-attached aluminum cutting waste or the like using a dry distillation furnace, which is characterized by performing a carbonization process.

図4において、1は原料ホッパ、3は乾留炉、5は乾留炉内に設けた攪拌羽根、12は熱分解ガスを燃焼させる再燃炉、25は溶解炉、26はアルミニウムを回収し再利用に資する製品を示す。図4のシステムの場合、乾留炉3において発生したガスの大部分は、ガス排出口10から再燃炉12に導入され、一方、供給口14から燃料及び空気が供給され、800〜1000℃程度の温度で発生ガスを完全燃焼させて油分をCO2とH2O等に酸化させ、併せて脱臭も行うように構成されている(詳細は、特許文献1参照)。 In FIG. 4, 1 is a raw material hopper, 3 is a dry distillation furnace, 5 is a stirring blade provided in the dry distillation furnace, 12 is a reburning furnace for burning pyrolysis gas, 25 is a melting furnace, and 26 is aluminum recovered and reused. Indicates a product that contributes. In the case of the system of FIG. 4, most of the gas generated in the carbonization furnace 3 is introduced into the reburning furnace 12 from the gas discharge port 10, while fuel and air are supplied from the supply port 14, and about 800 to 1000 ° C. The generated gas is completely combusted at a temperature to oxidize the oil to CO 2 and H 2 O or the like, and at the same time, deodorization is also performed (for details, refer to Patent Document 1).

次に、特許文献5について述べる。特許文献5の発明は、塩化ビニール、ポリエチレン等の塩素化合物を含む廃棄物をダイオキシンが発生しないようにして処理する廃棄物処理装置に関するもので、その請求項の記載を引用すると、「長手方向の両端部に配備した円筒形のタイヤの下部を駆動装置のローラで回転可能に支持し、前後段に配備する機器により内部を密閉するようにした中空の円筒体から構成し、前段から搬入された塩素化合物を含む廃棄物原料を内部で所定の温度に加熱保持しながら搬送して熱分解ガスおよび不揮発性残渣を生成するキルン本体と、該キルン本体の前段に配備して、前記廃棄物を前記キルン本体に搬送するスクリューフィーダーを有する廃棄物原料投入装置と、該キルン本体を外周側から誘導加熱する誘導加熱コイルと、前記キルン本体の後段に配備して不揮発性残渣を回収するとともに、熱分解ガスを収集して後段のガス処理装置へ排出する残渣回収室とを備えたことを特徴とする廃棄物処理装置。」を開示する。   Next, Patent Document 5 will be described. The invention of Patent Document 5 relates to a waste treatment apparatus that treats waste containing chlorine compounds such as vinyl chloride and polyethylene so that dioxins are not generated. The lower part of the cylindrical tire deployed at both ends is rotatably supported by the roller of the drive unit, and it is composed of a hollow cylindrical body that is sealed inside by the equipment deployed at the front and rear stages, and is carried from the front stage A kiln main body that generates a pyrolysis gas and a non-volatile residue by conveying a waste raw material containing a chlorine compound while being heated and held at a predetermined temperature, and disposed in a front stage of the kiln main body, Waste material input device having a screw feeder for conveying to the kiln main body, an induction heating coil for induction heating the kiln main body from the outer peripheral side, and a subsequent stage of the kiln main body With deployed to recover the non-volatile residue, and collect the pyrolysis gases, characterized in that a residue recovery chamber for discharging to a subsequent gas treatment device waste disposal device. "Discloses.

また、特許文献5は、廃棄物が加熱、保温されているゾーンでは酸素濃度を減少させ、熱分解ガスに含まれる塩素ガスなどから有害ガスが生成するのを未然に防止することを目的として、「キルン本体に不活性ガスを導入する不活性ガス導入手段を設けた構成」も開示する。   Patent Document 5 aims to reduce the oxygen concentration in a zone where waste is heated and kept warm, and to prevent generation of harmful gas from chlorine gas contained in the pyrolysis gas. Also disclosed is “a configuration in which an inert gas introduction means for introducing an inert gas into the kiln body” is provided.

ところで、本願発明者等は、従来装置に比べて装置の簡素化を図り、火災の危険性をできる限り低減する観点から、油分を出来る限り燃焼性のガスに分解せずに液状で回収し、さらに熱分解炉に不活性ガスを導入して熱処理を行う方式のアルミニウム切粉等の処理装置を開発した。その第一次開発装置の概略システム系統図を図3に示す。以下にこの装置について述べる。   By the way, the inventors of the present application aim to simplify the apparatus as compared with the conventional apparatus, and collect the oil in a liquid form without decomposing it into a combustible gas as much as possible from the viewpoint of reducing the risk of fire as much as possible. In addition, we have developed a processing equipment for aluminum chips and the like that uses an inert gas in the pyrolysis furnace and performs heat treatment. A schematic system diagram of the primary development apparatus is shown in FIG. This apparatus will be described below.

図3に示す装置は、中空円筒体の内部に、水分と油分とを含むアルミニウム切粉等の原料を投入して所定の温度に加熱しながら搬送し、熱分解により生成した水蒸気と油蒸気と炭化水素系ガスとを含む熱分解気体および熱処理されたアルミニウム切粉を排出する熱分解炉と、この熱分解炉の前段に配設され前記アルミニウム切粉等を搬送して投入する原料搬送投入手段と、前記熱分解炉の後段に配設され前記熱分解気体および熱処理されたアルミニウム切粉を排出する処理物排出手段と、前記熱分解炉に不活性ガスを導入する不活性ガス導入手段とを備える。   In the apparatus shown in FIG. 3, the raw material such as aluminum chips containing moisture and oil is introduced into the hollow cylindrical body and conveyed while being heated to a predetermined temperature. A pyrolysis furnace for discharging a pyrolysis gas containing a hydrocarbon-based gas and heat-treated aluminum chips, and a raw material conveyance input means for conveying the aluminum chips and the like disposed before the pyrolysis furnace And a treated product discharging means for discharging the pyrolyzed gas and heat-treated aluminum chips disposed downstream of the pyrolysis furnace, and an inert gas introducing means for introducing an inert gas into the pyrolysis furnace. Prepare.

前記熱分解炉は、キルン33、IH電源を有する誘導加熱コイル34、冷却ブロア35、キルン駆動手段36、冷却ケーシング38、マンホール39を備える。また、前記原料搬送投入手段は、投入スクリュウ(1)31および投入スクリュウ(2)32を備え、30で示す投入口には、前処理工程としての遠心分離工程により、アルミニウム切粉等に含まれる油分および水分を減少させた遠心分離後の切粉が投入される。なお、キルン33の円筒内部には、例えば、複数個の掻き揚げ板が設けられ、アルミニウム切粉を掻き揚げて均等に加熱すると共に、切粉がキルンの排出口方向へ移動できるように構成されている。   The pyrolysis furnace includes a kiln 33, an induction heating coil 34 having an IH power source, a cooling blower 35, a kiln driving means 36, a cooling casing 38, and a manhole 39. Further, the raw material conveying and charging means includes a charging screw (1) 31 and a charging screw (2) 32, and the charging port indicated by 30 is included in aluminum chips or the like by a centrifugal separation process as a pretreatment process. Chips after centrifugation with reduced oil and moisture are added. Note that, for example, a plurality of scraping plates are provided inside the cylinder of the kiln 33 so that the aluminum chips can be scraped up and heated evenly, and the chips can be moved toward the discharge port of the kiln. ing.

また、前記処理物排出手段は、キルン33の出口部に設けた排出スクリュウ37および冷却ケーシング38における凝縮部の後段の全ての機器からなり、詳細は熱分解動作等の説明と共に後述する。さらに、前記不活性ガス導入手段は、例えば、高圧の工場エヤー61を高分子分離膜により酸素と窒素とに分離して窒素ガスを得る窒素ガス発生器62から、N2ガスをキルン33に供給する構成を備える。 Moreover, the said processed material discharge | emission means consists of all the apparatus of the back | latter stage of the condensing part in the discharge | emission screw 37 provided in the exit part of the kiln 33, and the cooling casing 38, and it mentions later with description of thermal decomposition operation | movement etc. for details. Further, the inert gas introduction means supplies, for example, N 2 gas to the kiln 33 from a nitrogen gas generator 62 that obtains nitrogen gas by separating the high-pressure factory air 61 into oxygen and nitrogen by a polymer separation membrane. The structure to be provided is provided.

次に、熱分解動作等について述べる。水分と油分とを含むアルミニウム切粉等の原料とN2ガスをキルン33に供給して、300〜500℃の範囲の所定の温度(例えば、400℃弱)に加熱しながら搬送する。キルン33の出口部における符号Aは処理された乾燥切粉を示し、符号Bは熱分解により生成した水蒸気と油蒸気と炭化水素系ガスを含む熱分解気体ならびにN2ガスを示し、それぞれ、キルン33の下方から分離して排出される。前記炭化水素系ガスとしては、処理温度によっても異なるが、ヘキサン、ブタン、トルエン、キシレン、ベンゼン、プロピレン、プロパン、アセチレン等のガスを含む。さらに、炭化水素系ガス以外に、COガスも含まれる。 Next, the thermal decomposition operation and the like will be described. A raw material such as aluminum chips containing moisture and oil and N 2 gas are supplied to the kiln 33 and conveyed while heating to a predetermined temperature in the range of 300 to 500 ° C. (for example, less than 400 ° C.). Reference sign A at the outlet of the kiln 33 indicates the processed dry chips, reference sign B indicates pyrolysis gas including steam, oil vapor, and hydrocarbon-based gas generated by pyrolysis, and N 2 gas. Separated from below 33 and discharged. The hydrocarbon-based gas includes gases such as hexane, butane, toluene, xylene, benzene, propylene, propane, and acetylene, although depending on the processing temperature. Further, in addition to the hydrocarbon-based gas, CO gas is also included.

乾燥切粉Aは、切粉搬送用コンベア40により、後工程のために搬送される。一方、符号Bで示す気体は、冷却されて水蒸気と油蒸気の一部が凝縮し、符号Wで示すラインにより、後段の凝縮器51に導入される。残りの気体は符号Gで示すラインにより凝縮器51の上方に導入されるが、凝縮器に付設され、凝縮した液体を用いて冷却する冷却水シャワー53により、気体内の凝縮性成分が液化すると共に水溶性の気体が溶解する。さらに残った気体は、ポンプ57を有する冷却水シャワー58により再度冷却され一部が液化または溶解する。この冷却水シャワー58には、さらに、符号Cで示す気体(イ)(ロ)が合流して導入される。符号Cの気体は主に、切粉搬送用コンベア40において、乾燥切粉Aから発生する水蒸気、油蒸気、残留する炭化水素系ガス等を含む気体(ロ)である。なお、キルン33の出口部に示す符号Cの(イ)のラインは、キルンに万一漏れが発生した場合に、漏れ気体を誘導するラインを示す。   The dried swarf A is transported for subsequent processes by the swarf transporting conveyor 40. On the other hand, the gas indicated by the symbol B is cooled to condense part of the water vapor and the oil vapor, and is introduced into the subsequent condenser 51 through the line indicated by the symbol W. The remaining gas is introduced above the condenser 51 by a line indicated by reference numeral G, but the condensable component in the gas is liquefied by the cooling water shower 53 attached to the condenser and cooled by using the condensed liquid. At the same time, water-soluble gas dissolves. Further, the remaining gas is cooled again by a cooling water shower 58 having a pump 57, and a part thereof is liquefied or dissolved. The cooling water shower 58 is further introduced with the gas (A) and (B) indicated by reference numeral C joined together. The gas of the code | symbol C is mainly gas (b) containing the water vapor | steam which generate | occur | produces from the dry chip A, the oil vapor, the residual hydrocarbon gas, etc. in the conveyor 40 for chip conveyance. In addition, the line | wire of (C) of the code | symbol C shown in the exit part of the kiln 33 shows the line which induces | leads a leak gas, when a leak generate | occur | produces in a kiln.

凝縮器51の他に示された2つのタンク55a,55bは、バブリングタンクであり、ブロア56により、バブリングタンク55a上部の気体を吸引してバブリングを行い気体中の凝縮成分を出来る限り液化すると共に水溶解成分を溶解し、凝縮液はポンプ52を介して、部番59の部分から図示しない廃液槽へ排出される。一方、残りの無害化されたクリーンな気体は屋外へ排気される。なお、凝縮器51と2つのバブリングタンク55a,55bおよび冷却ケーシング38における凝縮液の液面は、全て、実質的に同一レベルである。
特公平6−17520号公報 特開平10−176227号公報 特開平10−226830号公報 特開平11−100621号公報 特開平11−226542号公報
The two tanks 55a and 55b shown in addition to the condenser 51 are bubbling tanks. The blower 56 sucks the gas above the bubbling tank 55a and performs bubbling to liquefy the condensed components in the gas as much as possible. The water-soluble component is dissolved, and the condensate is discharged from the portion 59 to a waste liquid tank (not shown) via the pump 52. On the other hand, the remaining detoxified clean gas is exhausted outdoors. Note that the liquid levels of the condensate in the condenser 51, the two bubbling tanks 55a and 55b, and the cooling casing 38 are all at substantially the same level.
Japanese Patent Publication No. 6-17520 Japanese Patent Laid-Open No. 10-176227 Japanese Patent Laid-Open No. 10-226830 Japanese Patent Laid-Open No. 11-100611 JP-A-11-226542

ところで、上記図3に示すアルミニウム切粉等の処理装置によれば、油分を出来る限り燃焼性のガスに分解せずに液状で回収可能であって、さらに熱分解炉に不活性ガスを導入して熱処理を行うので、装置を比較的簡素化することができ、さらに火災発生の危険性をかなり低減できるが、通常の運転方法を行った場合、即ち、キルン33内を大気圧より高くした状態で運転した場合には、下記のような問題があることが判明した。   By the way, according to the processing apparatus such as aluminum chips shown in FIG. 3, the oil can be recovered in a liquid state without being decomposed into combustible gas as much as possible, and an inert gas is further introduced into the pyrolysis furnace. Since the heat treatment is performed, the apparatus can be relatively simplified, and further, the risk of fire occurrence can be considerably reduced. However, when the normal operation method is performed, that is, the inside of the kiln 33 is made higher than the atmospheric pressure. The following problems were found when driving at:

図3において、冷却ケーシング38内を含むキルン内部および排出スクリュウ37内部の圧力が大気圧より高い場合には、前述のような水蒸気、油蒸気、炭化水素系ガスおよびCOガスを含む白煙が、排出スクリュウ37の出口部で発生し、かつ切粉搬送用コンベア40により搬送される乾燥切粉Aからも白煙が発生し易い状態となる。また、装置に漏れが生じた場合には、前述のように、図3のCで示す部分に白煙が発生する。   In FIG. 3, when the pressure inside the kiln including the inside of the cooling casing 38 and the inside of the discharge screw 37 is higher than the atmospheric pressure, white smoke containing water vapor, oil vapor, hydrocarbon-based gas, and CO gas as described above, White smoke is also likely to be generated from the dry chips A generated at the outlet of the discharge screw 37 and conveyed by the chip conveying conveyor 40. Further, when a leak occurs in the apparatus, as described above, white smoke is generated in the portion indicated by C in FIG.

この白煙は前述のように、水蒸気、油蒸気、炭化水素系ガスおよびCOガスを含むので、条件次第では、発火の危険性がある。前記炭化水素系ガスの内、発火点が最も低いガスはヘキサンの260℃であるが、油蒸気の発火点は約162℃であり、排出される切粉の温度が約200℃程度であるので、発火のトラブルが発生し易い。さらに、この白煙は、人体に有害である。   As described above, the white smoke contains water vapor, oil vapor, hydrocarbon-based gas, and CO gas, so that there is a risk of ignition depending on conditions. Among the hydrocarbon gases, the gas having the lowest ignition point is 260 ° C of hexane, but the ignition point of oil vapor is about 162 ° C, and the temperature of the discharged chips is about 200 ° C. , Ignition troubles are likely to occur. Furthermore, this white smoke is harmful to the human body.

この発明は、上記のような問題点に鑑みてなされたもので、この発明の課題は、油分を出来る限り燃焼性のガスに分解せずに液状で回収を行うアルミニウム切粉等の処理装置の運転方法において、装置外部に対する白煙の発生を、乾燥切粉からの微量発生を除いて抑止し、人体に有害かつ発火の危険性を有する熱分解気体の発散を防止することにある。   The present invention has been made in view of the above-described problems, and an object of the present invention is to provide a processing apparatus such as aluminum chips that recovers oil in a liquid state without decomposing the oil into a combustible gas as much as possible. In the operation method, the generation of white smoke to the outside of the apparatus is suppressed except for a small amount from dry chips, and the emission of pyrolysis gas which is harmful to human body and has a risk of ignition is prevented.

前述の課題を解決するため、この発明は、水分と油分とを含むアルミニウム切粉等の原料を投入して所定の温度に加熱しながら搬送し、熱分解により生成した水蒸気と油蒸気と炭化水素系ガスとを含む熱分解気体および熱処理されたアルミニウム切粉を排出する熱分解炉と、この熱分解炉の前段に配設され前記アルミニウム切粉等を搬送して投入する原料搬送投入手段と、前記熱分解炉の後段に配設され熱処理されたアルミニウム切粉を排出しかつ前記熱分解気体をブロアにより吸引しその一部を液化および水溶解処理して排出する処理物排出手段とを備えたアルミニウム切粉等の処理装置の運転方法において、前記熱分解処理の際、熱分解炉に不活性ガスを導入し、かつ前記ブロアの気体吸引力により、前記熱分解炉内のゲージ圧力を略大気圧もしくは大気圧より小とすることを特徴とする(請求項1)。   In order to solve the above-mentioned problems, the present invention introduces a raw material such as aluminum chips containing moisture and oil, transports it while heating it to a predetermined temperature, and generates steam, oil vapor and hydrocarbons generated by thermal decomposition. A pyrolysis furnace that discharges the pyrolysis gas containing the system gas and the heat-treated aluminum chips, and a raw material transport and input means that is disposed in a front stage of the pyrolysis furnace and that transports and inputs the aluminum chips and the like, And a treated product discharging means for discharging the heat-treated aluminum chips disposed at the subsequent stage of the pyrolysis furnace and sucking the pyrolysis gas by a blower and liquefying and partially dissolving the pyrolyzed gas. In the operation method of the processing apparatus such as aluminum chips, an inert gas is introduced into the pyrolysis furnace during the pyrolysis process, and the gauge pressure in the pyrolysis furnace is substantially increased by the gas suction force of the blower. Characterized by a less than pressure or atmospheric pressure (claim 1).

この発明によれば、装置外部に対する白煙の発生を、乾燥切粉からの発生を除いて抑止し、人体に有害かつ発火の危険性を有する熱分解気体の発散を防止することができる。基本的には、熱分解炉内のゲージ圧力は大気圧より小とすることが好ましいが、気体が発散する抵抗を考慮すると、実際上は、略大気圧でも問題はなく、熱分解炉内のゲージ圧力は、+5〜−20Paの範囲とする(請求項2)。   According to this invention, the generation of white smoke to the outside of the apparatus can be suppressed except for the generation from dry chips, and the emission of pyrolysis gas that is harmful to human bodies and has a risk of ignition can be prevented. Basically, it is preferable to set the gauge pressure in the pyrolysis furnace to be lower than the atmospheric pressure. However, in consideration of the resistance of gas to escape, in practice, there is no problem even at substantially atmospheric pressure. The gauge pressure is in the range of +5 to -20 Pa (Claim 2).

また、上記発明の実施態様としては、下記請求項3ないし6の発明が好ましい。即ち、前記請求項1または2に記載のアルミニウム切粉等の処理装置の運転方法において、前記圧力は、前記熱分解炉に設けた圧力センサの測定値に基づき、前記ブロアの回転数を制御して調節する(請求項3)。さらに、前記請求項1に記載のアルミニウム切粉等の処理装置の運転方法において、前記不活性ガスは、空気から分離した窒素とする(請求項4)。   As embodiments of the above invention, the inventions of claims 3 to 6 below are preferable. That is, in the method of operating a processing apparatus for aluminum chips or the like according to claim 1 or 2, the pressure controls the rotational speed of the blower based on a measured value of a pressure sensor provided in the pyrolysis furnace. (Claim 3). Furthermore, in the method for operating a processing apparatus for aluminum chips or the like according to claim 1, the inert gas is nitrogen separated from air (claim 4).

また、前記請求項1ないし4のいずれか1項に記載のアルミニウム切粉等の処理装置の運転方法において、前記処理物排出手段は、前記熱分解気体中の水蒸気と油蒸気とを冷却して凝縮させ、この凝縮液を廃液槽へ排出する手段を有する凝縮器と、前記熱分解気体中の未凝縮気体または水溶性気体を、凝縮した液体を用いた冷却用シャワーおよび/または液中へのバブリングにより再凝縮または水溶解させる手段とを備えることを特徴とする(請求項5)。   Further, in the method of operating a processing apparatus for aluminum chips or the like according to any one of claims 1 to 4, the processed material discharge means cools water vapor and oil vapor in the pyrolysis gas. A condenser having means for condensing and discharging the condensate to a waste liquid tank, and a non-condensable gas or a water-soluble gas in the pyrolysis gas into a cooling shower and / or liquid using the condensed liquid. And a means for recondensing or dissolving in water by bubbling (Claim 5).

さらに、前記請求項1に記載のアルミニウム切粉等の処理装置の運転方法において、アルミニウム切粉等の原料投入前の熱分解炉起動時には、熱処理されたアルミニウム切粉の排出口を閉鎖した状態で前記ブロアを起動して、前記熱分解炉内および熱分解炉後段の熱分解気体流路内の空気を排出し、空気排出後もしくは空気排出と並行して熱分解炉に不活性ガスを供給し、その後アルミニウム切粉等を投入して熱分解処理運転に移行することを特徴とする(請求項6)。   Furthermore, in the operation method of the processing apparatus for aluminum chips and the like according to claim 1, the heat treatment aluminum chip discharge port is closed at the time of starting the pyrolysis furnace before charging the raw materials such as aluminum chips. Start up the blower, exhaust air in the pyrolysis furnace and in the pyrolysis gas flow path after the pyrolysis furnace, and supply inert gas to the pyrolysis furnace after the air discharge or in parallel with the air discharge Then, aluminum chips and the like are introduced to shift to the thermal decomposition treatment operation (Claim 6).

この発明によれば、油分を出来る限り燃焼性のガスに分解せずに液状で回収を行うアルミニウム切粉等の処理装置の運転方法において、装置外部に対する白煙の発生を、乾燥切粉からの微量発生を除いて抑止し、人体に有害かつ発火の危険性を有する熱分解気体の発散を防止することができる。   According to the present invention, in the method of operating a processing apparatus such as aluminum chips that recovers oil in liquid form without breaking it into combustible gas as much as possible, the generation of white smoke from outside the apparatus Suppressing except for a small amount of generation, it is possible to prevent the emission of pyrolysis gas which is harmful to human body and has a risk of ignition.

本発明の実施例について、まず図3に基づいて述べ、さらに図3を改良した装置の実施例について、図1および図2に基づき以下に述べる。なお、本発明はこれらの実施例によって限定されるものではない。   An embodiment of the present invention will be first described with reference to FIG. 3, and an embodiment of the apparatus improved from FIG. 3 will be described below with reference to FIGS. In addition, this invention is not limited by these Examples.

図3の装置のシステム構成の詳細は前述のとおりであるので重複説明は省略するが、図3の場合、熱分解処理の際、キルン33にN2ガスを導入し、かつブロア56の気体吸引力により、キルン33内のゲージ圧力を略大気圧もしくは大気圧より小となる+5〜−20Pa、より好ましくは、0〜−20Paとする。 The details of the system configuration of the apparatus shown in FIG. 3 are as described above, and thus a duplicate description is omitted. In the case of FIG. 3, N 2 gas is introduced into the kiln 33 and gas is sucked into the blower 56 in the pyrolysis process. By force, the gauge pressure in the kiln 33 is set to +5 to −20 Pa, more preferably 0 to −20 Pa, which is approximately atmospheric pressure or lower than atmospheric pressure.

また、図3において、アルミニウム切粉等の原料投入前のキルン起動時には、以下のようにする。即ち、排出スクリュウ37におけるアルミニウム切粉の排出口を閉鎖した状態で、ブロア56を起動して、キルン33内およびキルン後段の冷却ケーシング38内、経路G、凝縮器51上部、バブリングタンク55aおよび55b上部等の熱分解気体流路内の空気を排出し、空気排出後もしくは空気排出と並行してキルン33内にN2ガスを導入し、その後アルミニウム切粉等を部番30の位置から投入して熱分解処理運転に移行する。 Moreover, in FIG. 3, at the time of kiln starting before raw material injection | throwing-in, such as aluminum chip, it is as follows. That is, the blower 56 is started in a state where the discharge port of the aluminum chips in the discharge screw 37 is closed, and the inside of the kiln 33 and the cooling casing 38 at the downstream of the kiln, the path G, the condenser 51 upper portion, the bubbling tanks 55a and 55b The air in the pyrolysis gas flow path such as the upper part is discharged, N 2 gas is introduced into the kiln 33 after the air discharge or in parallel with the air discharge, and then aluminum chips and the like are introduced from the position of the part number 30. Shift to thermal decomposition operation.

次に、図1および図2の実施例について述べる。図1は、図3の装置を、主に乾燥切粉から発生する白煙による火災発生の危険性を抑止するために改良した実施例に係る概略システム系統図であり、乾燥切粉の排出経路に、強制冷却手段と不活性ガス導入手段とを備えることを特徴とする。   Next, the embodiment of FIGS. 1 and 2 will be described. FIG. 1 is a schematic system diagram according to an embodiment in which the apparatus of FIG. 3 is improved in order to suppress the risk of a fire due to white smoke generated mainly from dry chips, and the discharge route of dry chips. And a forced cooling means and an inert gas introduction means.

図1において、図3に示した部材と同一もしくは機能が同一の部材には同一符号を付し、それらの詳細説明は省略する。図1と図3との実質的な相違点は、主として処理物排出手段、特に図3における排出スクリュウ37の後段の装置構成にある。また、図3におけるバブリングタンク周りの装置構成も一部相違するが、基本的機能は実質的に同一である。詳細は後述する。   1, members that are the same as or have the same functions as those shown in FIG. 3 are given the same reference numerals, and detailed descriptions thereof are omitted. The substantial difference between FIG. 1 and FIG. 3 lies mainly in the apparatus configuration of the processed material discharge means, particularly the latter stage of the discharge screw 37 in FIG. Moreover, although the apparatus structure around the bubbling tank in FIG. 3 is also partially different, the basic functions are substantially the same. Details will be described later.

図1において、図3と異なる部材番号について示すと以下のとおりである。41はパドルスクリュウ、41a,42aは冷却ジャケット、42は貯留ホッパー、43,44はスクリュウ、46は装置の起動時の用いるシール蓋、48は捕集器、55はバブリングタンクに代わるスクラバー、56a,56bはブロア、63,64,65,66,67,68は窒素ガス供給ライン、69は大気導入弁、71,72は酸素センサ、74は切粉レベルセンサである。なお、T1〜T5は温度センサ(例えば、熱電対)、Pは圧力センサ、M1〜M7は駆動モータ、FMは流量計、LSはレベルセンサを示す。   1, the member numbers different from those in FIG. 3 are as follows. 41 is a paddle screw, 41a and 42a are cooling jackets, 42 is a storage hopper, 43 and 44 are screws, 46 is a seal lid used when starting the apparatus, 48 is a collector, 55 is a scrubber instead of a bubbling tank, 56a, 56b is a blower, 63, 64, 65, 66, 67 and 68 are nitrogen gas supply lines, 69 is an air introduction valve, 71 and 72 are oxygen sensors, and 74 is a chip level sensor. T1 to T5 are temperature sensors (for example, thermocouples), P is a pressure sensor, M1 to M7 are drive motors, FM is a flow meter, and LS is a level sensor.

図1の装置の処理物排出手段においては、キルン33のアルミニウム切粉排出部に接続して順に、切粉排出用の排出スクリュウ37と、パドルスクリュウ41と、切粉を一旦貯留する貯留ホッパー42と、この貯留ホッパー42から切粉を後工程に搬送する搬送用スクリュウ43および44とが設けられ、乾燥切粉Aは、キルン33から前記各スクリュウを経由して、部番45で示す位置に到達し、ここから、バケットコンベアにより次工程に搬送される。なお、パドルスクリュウ41と排出スクリュウ37との間の、部番を付さない板状部材は、スクリュウ駆動用回転シャフトの軸受部を示す。   In the processed product discharge means of the apparatus of FIG. 1, a discharge screw 37 for discharging chips, a paddle screw 41, and a storage hopper 42 for temporarily storing chips are sequentially connected to the aluminum chip discharge unit of the kiln 33. And conveying screws 43 and 44 for conveying the chips from the storage hopper 42 to the subsequent process, and the dried chips A are passed from the kiln 33 to the position indicated by the part number 45 via the screws. From here, it is conveyed to the next process by a bucket conveyor. In addition, the plate-shaped member which does not attach | subject the part number between the paddle screw 41 and the discharge | emission screw 37 shows the bearing part of the rotating shaft for screw drive.

上記パドルスクリュウ41は、断面U字状の中空チャンバを有し、その軸方向内部に設けたスクリュウの各先端部には切粉の掻き揚げ板が設けられた公知の構成を有するもので、U字状チャンバー下方の半円筒部の外周部には、チャンバ軸方向に沿って水冷ジャケット41aが設けられ、チャンバ内の切粉が強制水冷されるように構成されている。なお、水冷ジャケットは、42aで示すように、貯留ホッパー42の外周部にも設けることが好ましい。上記により、貯留ホッパー42内のアルミニウム切粉の温度は100℃以下とする。   The paddle screw 41 has a known configuration in which a hollow chamber having a U-shaped cross section is provided, and a tip of the screw provided inside the axial direction is provided with a scraping plate for chips. A water cooling jacket 41a is provided along the chamber axial direction on the outer periphery of the semi-cylindrical portion below the letter-shaped chamber so that chips in the chamber are forcibly water cooled. The water cooling jacket is also preferably provided on the outer periphery of the storage hopper 42 as indicated by 42a. As described above, the temperature of the aluminum chips in the storage hopper 42 is set to 100 ° C. or less.

また、パドルスクリュウ41には、窒素ガス供給ライン65および67が接続され、窒素ガス供給ライン64を介して、窒素ガス発生器62から、窒素ガスが導入される。さらに、部番66や68で示すように、貯留ホッパー42の内部や切粉レベルセンサ74の貫通部にも、窒素ガスを導入することが好ましい。なお、窒素ガスの代わりにアルゴン等の他の不活性ガスを用いることもできる。また、強制冷却は、水冷に代えて空冷や他の冷却媒体を用いることもできる。   Further, nitrogen gas supply lines 65 and 67 are connected to the paddle screw 41, and nitrogen gas is introduced from the nitrogen gas generator 62 through the nitrogen gas supply line 64. Furthermore, as indicated by part numbers 66 and 68, it is preferable to introduce nitrogen gas also into the inside of the storage hopper 42 and the penetration part of the chip level sensor 74. Other inert gas such as argon can be used instead of nitrogen gas. For forced cooling, air cooling or another cooling medium can be used instead of water cooling.

上記処理物排出手段の構成によれば、アルミニウム切粉が強制冷却されて温度が低下し、かつ、切粉の周りには窒素ガスが導入されて酸素濃度が低減するので、発火の危険性が抑止される。また、前述のように、排出スクリュウ37の前段部と貯留ホッパー42内に溜まったアルミニウム切粉は、パドルスクリュウ41および排出スクリュウ後段部を塞いでガスの流通を妨げるので、パドルスクリュウ部に供給された窒素ガスが流出し難くなり、火災抑止効果がより向上する。   According to the configuration of the treated product discharge means, the aluminum chips are forcibly cooled to lower the temperature, and nitrogen gas is introduced around the chips to reduce the oxygen concentration, so there is a risk of ignition. Deterred. Further, as described above, the aluminum chips accumulated in the front stage portion of the discharge screw 37 and the storage hopper 42 block the paddle screw 41 and the rear stage portion of the discharge screw and prevent the gas from flowing, and thus are supplied to the paddle screw portion. Nitrogen gas is difficult to flow out and the fire suppression effect is further improved.

上記構成において、乾燥切粉Aから発生する水蒸気、油蒸気、残留する炭化水素系ガス等を含む気体Cは、スクリュウ44の終端部上方から、捕集器48を介して、冷却水シャワー58へと運ばれる。前記捕集器48は、固形状粉塵を重力沈降させて捕集するもので、必要に応じて設ける。   In the above configuration, the gas C containing water vapor, oil vapor, residual hydrocarbon gas, etc. generated from the dry swarf A is passed from the upper end of the screw 44 to the cooling water shower 58 via the collector 48. It is carried. The collector 48 collects solid dust by gravity sedimentation, and is provided as necessary.

次に、符号Bで示す気体は、図3の場合と同様に、冷却されて水蒸気と油蒸気の一部が凝縮し、符号Wで示すラインにより、後段の凝縮器51に導入される。残りの気体は符号Gで示すラインにより凝縮器51の上方に導入され、冷却水シャワー53により、気体内の凝縮性成分が液化すると共に水溶性の気体が溶解する。図1の場合、図3で示した2つのバブリングタンクに代えて、1つのスクラバー55を設け、気体による攪拌やバブリングにより、気体の溶解や清浄化を行うようにしており、その基本的な機能は図3の場合と同様である。   Next, similarly to the case of FIG. 3, the gas indicated by the symbol B is cooled to condense a part of the water vapor and the oil vapor, and is introduced into the subsequent condenser 51 through the line indicated by the symbol W. The remaining gas is introduced to the upper side of the condenser 51 through a line denoted by reference numeral G, and the condensable component in the gas is liquefied and the water-soluble gas is dissolved by the cooling water shower 53. In the case of FIG. 1, instead of the two bubbling tanks shown in FIG. 3, one scrubber 55 is provided to dissolve and clean the gas by stirring and bubbling with the gas. Is the same as in FIG.

次に、図1の装置の運転方法や異常監視等について以下に述べる。アルミニウム切粉等の熱分解処理運転において、キルン33内のゲージ圧は0〜−20Pa程度の圧力で運転することが好ましい。装置運転中は、キルン33の前後がアルミニウム切粉等により塞がれた状態となるので、スクラバー55の上方に設けたブロア56aの回転数制御により吸引量を調節して、前記0〜−20Paの圧力とすることができる。アルミニウム切粉投入前の装置の起動時には、大気導入弁69およびシール蓋46を閉じて、スクラバー55の上方に設けたブロア56aを起動する。これにより、装置内部の空気が排出される。その後、窒素ガスの導入とアルミニウム切粉等の投入により、キルン内の圧力センサーの測定値に基づき、ブロア56aの回転数制御を行って、運転モードに移行する。   Next, the operation method and abnormality monitoring of the apparatus of FIG. 1 will be described below. In the thermal decomposition treatment operation of aluminum chips or the like, the gauge pressure in the kiln 33 is preferably operated at a pressure of about 0 to −20 Pa. During operation of the apparatus, the front and rear of the kiln 33 are closed with aluminum chips or the like, so the suction amount is adjusted by controlling the rotational speed of the blower 56a provided above the scrubber 55, and the above-mentioned 0 to -20 Pa. Pressure. At the start of the apparatus before the aluminum chips are charged, the air introduction valve 69 and the seal lid 46 are closed, and the blower 56a provided above the scrubber 55 is started. Thereby, the air inside the apparatus is discharged. Thereafter, by introducing nitrogen gas and introducing aluminum chips, the rotational speed of the blower 56a is controlled based on the measured value of the pressure sensor in the kiln, and the operation mode is shifted.

次に、異常監視について述べる。装置に漏れが生じた場合や、何らかの原因で装置内の酸素濃度が異常となった場合には、装置を緊急停止する。そのために酸素センサ71および72を設けて監視を行う。また、切粉レベルセンサ74を設け、レベルが上限に到達した際にはキルンの駆動を停止する。この場合、誘導加熱コイルは停止せずに加熱状態を維持することが好ましい。さらに、凝縮器51へ向う気体の流路G内がタール分等で詰また場合にも装置を緊急停止する。そのために温度センサT2を設け、この測定値が、所定温度(例えば、70℃)以下となった場合に、加熱気体が正常に流れていないと判断して装置を緊急停止する。   Next, abnormality monitoring will be described. If a leak occurs in the device, or if the oxygen concentration in the device becomes abnormal for some reason, the device is stopped urgently. For this purpose, oxygen sensors 71 and 72 are provided for monitoring. Moreover, the chip level sensor 74 is provided, and when the level reaches the upper limit, the driving of the kiln is stopped. In this case, it is preferable to maintain the heating state without stopping the induction heating coil. Further, when the gas flow path G toward the condenser 51 is clogged with tar or the like, the apparatus is urgently stopped. For this purpose, a temperature sensor T2 is provided, and when the measured value is equal to or lower than a predetermined temperature (for example, 70 ° C.), it is determined that the heated gas is not flowing normally, and the apparatus is stopped urgently.

次に、本発明の運転結果の一例を図2に基づいて述べる。図2は、図1における各部温度(T1,T3,T4,T5)の時間推移を示す。図2の運転条件としては、キルン内温度を設定値385±5℃とし、アルミニウム切粉等の処理量は500kg/Hとした。なお、この切粉等は、前工程としての遠心分離工程により、水分15kg,油分1kgを含むものとした。また、投入スクリュウ(1)31および投入スクリュウ(2)32のモータ周波数は7.4Hzとした。   Next, an example of the operation result of the present invention will be described with reference to FIG. FIG. 2 shows a time transition of each part temperature (T1, T3, T4, T5) in FIG. As operating conditions in FIG. 2, the kiln temperature was set to a set value 385 ± 5 ° C., and the processing amount of aluminum chips and the like was 500 kg / H. In addition, this chip etc. shall contain water 15kg and oil 1kg by the centrifugation process as a pre-process. The motor frequency of the charging screw (1) 31 and the charging screw (2) 32 was set to 7.4 Hz.

図2において、T1はキルン温度であり、定常運転状態において、設定値385±5℃に近い値を示している。T3はシュート温度(図1の排出スクリュウ37の切粉入口上部温度)であり、300℃前後の値を示している。T4はスクリュウ排ガス温度(図1のスクリュウ44の終端上部の排ガスCの温度)であり、70℃前後の値を示している。T5は貯留ホッパー42内の切粉温度であり、70℃弱の値を示しており、目標とする切粉温度より低いことが確認された。さらに、運転中、装置外部に対する白煙の発生がなく、人体に有害かつ発火の危険性を有する熱分解気体の発散を防止して、安全に運転できることが確認された。なお、この改良された図1の実施例によれば、乾燥切粉からの白煙の微量発生をも抑制することができる。   In FIG. 2, T1 is the kiln temperature, and shows a value close to the set value 385 ± 5 ° C. in the steady operation state. T3 is the chute temperature (the chip inlet upper temperature of the discharge screw 37 in FIG. 1), and shows a value around 300 ° C. T4 is the screw exhaust gas temperature (the temperature of the exhaust gas C at the upper end of the screw 44 in FIG. 1), and shows a value around 70 ° C. T5 is the chip temperature in the storage hopper 42, showing a value of less than 70 ° C., and was confirmed to be lower than the target chip temperature. Furthermore, during operation, it was confirmed that there was no generation of white smoke outside the device, and it was possible to operate safely by preventing the release of pyrolysis gas which is harmful to human body and has a risk of ignition. In addition, according to this improved embodiment of FIG. 1, generation | occurrence | production of the trace amount of white smoke from dry chips can also be suppressed.

本発明のアルミニウム切粉等の処理装置の改良された実施例に係る概略システム系統図。1 is a schematic system diagram according to an improved embodiment of a processing apparatus for aluminum chips and the like according to the present invention. 図1の装置の運転結果の一例として各部温度の時間推移を示す図。The figure which shows the time transition of each part temperature as an example of the operation result of the apparatus of FIG. 本発明に係るアルミニウム切粉等の処理装置の第一次開発装置の概略システム系統図。1 is a schematic system diagram of a primary development apparatus for a processing apparatus for aluminum chips and the like according to the present invention. 特許文献1に開示されたアルミニウム切削屑等の処理方法に係る装置の概略システム系統図。FIG. 2 is a schematic system diagram of an apparatus according to a method for processing aluminum cutting waste and the like disclosed in Patent Document 1.

符号の説明Explanation of symbols

31:投入スクリュウ(1)、32:投入スクリュウ(2)、33:キルン、34:誘導加熱コイル、35:冷却ブロア、36:キルン駆動手段、37:排出スクリュウ、38:冷却ケーシング、39:マンホール、40:切粉搬送用コンベア、41:パドルスクリュウ、41a,42a:水冷ジャケット、42:貯留ホッパー、43,44:スクリュウ、46:シール蓋、48:捕集器、51:凝縮器、52:ポンプ、53,58:冷却水シャワー、55:スクラバー、55a,55b:バブリングタンク、56,56a,56b:ブロア、57:シャワリングポンプ、61:工場エヤー、62:窒素ガス発生器、63,64,65,66,67,68:窒素ガス供給ライン、69:大気導入弁、71,72:酸素センサ、74:切粉レベルセンサ。

31: Input screw (1), 32: Input screw (2), 33: Kiln, 34: Induction heating coil, 35: Cooling blower, 36: Kiln driving means, 37: Discharge screw, 38: Cooling casing, 39: Manhole , 40: Chip conveying conveyor, 41: Paddle screw, 41a, 42a: Water-cooled jacket, 42: Storage hopper, 43, 44: Screw, 46: Seal lid, 48: Collector, 51: Condenser, 52: Pump, 53, 58: Cooling water shower, 55: Scrubber, 55a, 55b: Bubbling tank, 56, 56a, 56b: Blower, 57: Showering pump, 61: Factory air, 62: Nitrogen gas generator, 63, 64 , 65, 66, 67, 68: Nitrogen gas supply line, 69: Air introduction valve, 71, 72: Oxygen sensor, 74: Chip level Sensor.

Claims (6)

水分と油分とを含むアルミニウム切粉等の原料を投入して所定の温度に加熱しながら搬送し、熱分解により生成した水蒸気と油蒸気と炭化水素系ガスとを含む熱分解気体および熱処理されたアルミニウム切粉を排出する熱分解炉と、この熱分解炉の前段に配設され前記アルミニウム切粉等を搬送して投入する原料搬送投入手段と、前記熱分解炉の後段に配設され熱処理されたアルミニウム切粉を排出しかつ前記熱分解気体をブロアにより吸引しその一部を液化および水溶解処理して排出する処理物排出手段とを備えたアルミニウム切粉等の処理装置の運転方法において、
前記熱分解処理の際、熱分解炉に不活性ガスを導入し、かつ前記ブロアの気体吸引力により、前記熱分解炉内のゲージ圧力を略大気圧もしくは大気圧より小とすることを特徴とするアルミニウム切粉等の処理装置の運転方法。
Raw materials such as aluminum chips containing moisture and oil were introduced and conveyed while heating to a predetermined temperature, and pyrolyzed gas containing water vapor, oil vapor and hydrocarbon-based gas generated by pyrolysis and heat-treated A pyrolysis furnace that discharges aluminum chips, a raw material transport and input means that is disposed in the front stage of the pyrolysis furnace and transports and feeds the aluminum chips and the like, and is disposed in the rear stage of the pyrolysis furnace and is heat-treated. In a method for operating a processing apparatus such as aluminum chips, which includes a processed material discharge means for discharging the aluminum chips and sucking the pyrolysis gas with a blower and liquefying and partially dissolving the pyrolysis gas with water,
In the pyrolysis treatment, an inert gas is introduced into the pyrolysis furnace, and the gauge pressure in the pyrolysis furnace is set to approximately atmospheric pressure or lower than atmospheric pressure by the gas suction force of the blower. Method of processing equipment such as aluminum chips.
請求項1に記載の運転方法において、前記熱分解炉内のゲージ圧力は、+5〜−20Paとすることを特徴とするアルミニウム切粉等の処理装置の運転方法。 The operating method according to claim 1, wherein the gauge pressure in the pyrolysis furnace is set to +5 to −20 Pa. 請求項1または2に記載の運転方法において、前記圧力は、前記熱分解炉に設けた圧力センサの測定値に基づき、前記ブロアの回転数を制御して調節することを特徴とするアルミニウム切粉等の処理装置の運転方法。 3. The operation method according to claim 1, wherein the pressure is adjusted by controlling the number of revolutions of the blower based on a measurement value of a pressure sensor provided in the pyrolysis furnace. A method of operating a processing apparatus such as 請求項1に記載の運転方法において、前記不活性ガスは、空気から分離した窒素とすることを特徴とするアルミニウム切粉等の処理装置の運転方法。 2. The operation method according to claim 1, wherein the inert gas is nitrogen separated from air. 請求項1ないし4のいずれか1項に記載の運転方法において、前記処理物排出手段は、前記熱分解気体中の水蒸気と油蒸気とを冷却して凝縮させ、この凝縮液を廃液槽へ排出する手段を有する凝縮器と、前記熱分解気体中の未凝縮気体または水溶性気体を、凝縮した液体を用いた冷却用シャワーおよび/または液中へのバブリングにより再凝縮または水溶解させる手段とを備えることを特徴とするアルミニウム切粉等の処理装置の運転方法。 5. The operation method according to claim 1, wherein the treatment product discharging means cools and condenses water vapor and oil vapor in the pyrolysis gas, and discharges the condensate to a waste liquid tank. And a means for recondensing or dissolving the uncondensed gas or water-soluble gas in the pyrolysis gas by a cooling shower using condensed liquid and / or bubbling into the liquid. A method of operating a processing apparatus for aluminum chips or the like, comprising: 請求項1に記載の運転方法において、アルミニウム切粉等の原料投入前の熱分解炉起動時には、熱処理されたアルミニウム切粉の排出口を閉鎖した状態で前記ブロアを起動して、前記熱分解炉内および熱分解炉後段の熱分解気体流路内の空気を排出し、空気排出後もしくは空気排出と並行して熱分解炉に不活性ガスを供給し、その後アルミニウム切粉等を投入して熱分解処理運転に移行することを特徴とするアルミニウム切粉等の処理装置の運転方法。

2. The operation method according to claim 1, wherein at the time of starting the pyrolysis furnace before charging raw materials such as aluminum chips, the blower is started in a state where a discharge port of the heat-treated aluminum chips is closed, and the pyrolysis furnace The air in the pyrolysis gas flow path inside and after the pyrolysis furnace is discharged, and after the air discharge or in parallel with the air discharge, an inert gas is supplied to the pyrolysis furnace, and then aluminum chips etc. are added to heat A method for operating a processing apparatus for processing aluminum chips or the like, characterized in that the operation shifts to a decomposition processing operation.

JP2006133750A 2006-05-12 2006-05-12 Operation method of processing equipment such as aluminum chips Expired - Fee Related JP4685702B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2006133750A JP4685702B2 (en) 2006-05-12 2006-05-12 Operation method of processing equipment such as aluminum chips

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2006133750A JP4685702B2 (en) 2006-05-12 2006-05-12 Operation method of processing equipment such as aluminum chips

Publications (2)

Publication Number Publication Date
JP2007302965A true JP2007302965A (en) 2007-11-22
JP4685702B2 JP4685702B2 (en) 2011-05-18

Family

ID=38837141

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2006133750A Expired - Fee Related JP4685702B2 (en) 2006-05-12 2006-05-12 Operation method of processing equipment such as aluminum chips

Country Status (1)

Country Link
JP (1) JP4685702B2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015067871A (en) * 2013-09-30 2015-04-13 Jx日鉱日石金属株式会社 Pretreatment method for recycle material

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07126761A (en) * 1993-10-29 1995-05-16 Nisshin Steel Co Ltd Method for removing oil-component from stainless steel scrap and device therefor
JPH09217128A (en) * 1996-02-09 1997-08-19 Nisshin Steel Co Ltd Equipment for removing oil-component and moisture of metallic scrap and method therefor
JP2001201215A (en) * 1999-11-12 2001-07-27 Toho Gas Co Ltd Method and apparatus for removing refrigerating machine oil
JP2002284923A (en) * 2001-03-22 2002-10-03 Nippon Steel Corp Method for recycling waste of composite aluminum sash and equipment therefor
JP2003260433A (en) * 2002-03-08 2003-09-16 Daido Steel Co Ltd Method for removing recycled insulating oil
JP2003334528A (en) * 2002-05-17 2003-11-25 Hitachi Ltd Pyrolytic method for waste and pyrolytic gasifying apparatus

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07126761A (en) * 1993-10-29 1995-05-16 Nisshin Steel Co Ltd Method for removing oil-component from stainless steel scrap and device therefor
JPH09217128A (en) * 1996-02-09 1997-08-19 Nisshin Steel Co Ltd Equipment for removing oil-component and moisture of metallic scrap and method therefor
JP2001201215A (en) * 1999-11-12 2001-07-27 Toho Gas Co Ltd Method and apparatus for removing refrigerating machine oil
JP2002284923A (en) * 2001-03-22 2002-10-03 Nippon Steel Corp Method for recycling waste of composite aluminum sash and equipment therefor
JP2003260433A (en) * 2002-03-08 2003-09-16 Daido Steel Co Ltd Method for removing recycled insulating oil
JP2003334528A (en) * 2002-05-17 2003-11-25 Hitachi Ltd Pyrolytic method for waste and pyrolytic gasifying apparatus

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2015067871A (en) * 2013-09-30 2015-04-13 Jx日鉱日石金属株式会社 Pretreatment method for recycle material

Also Published As

Publication number Publication date
JP4685702B2 (en) 2011-05-18

Similar Documents

Publication Publication Date Title
JP2004507359A (en) Removal device for removing hydrocarbon contained in sludge from oil storage tank and / or treatment device for treating residue containing hydrocarbon and plasma process
JP4908914B2 (en) Processing equipment such as aluminum chips
JP2008194618A (en) Method of continuously recovering valuable metal from waste integrated circuit board
JP4685702B2 (en) Operation method of processing equipment such as aluminum chips
JP2006349224A (en) Scrap tire recycling device
JP2008094694A (en) Nanocarbon production apparatus
KR102399586B1 (en) High organic concurrent decoating kiln
JP2009203474A (en) Heat treatment device and pyrolytic method
JP2003334528A (en) Pyrolytic method for waste and pyrolytic gasifying apparatus
JP4745623B2 (en) Extraction processing method
JP6105900B2 (en) Method for recovering aluminum from packaging material containing aluminum layer and aluminum recovery apparatus using the same
JP4235654B2 (en) Carbide manufacturing method and carbide manufacturing apparatus
JP2004225935A (en) Horizontal type rotary heating device for heat treatment of metal waste
JP3840208B2 (en) Soil treatment apparatus and treatment method
JP3586451B2 (en) Device for dechlorination of collected fly ash and its dechlorination method
WO2008053571A1 (en) Method of pyrolyzing waste containing organic matter, apparatus therefor and pyrolytic gasification system
JP2011236313A (en) Apparatus and method for treating waste
JP2004298800A (en) Treatment method and apparatus for soil
JP2002284923A (en) Method for recycling waste of composite aluminum sash and equipment therefor
JP2006035218A (en) Soil treating apparatus
JP2005082778A (en) Method and apparatus for thermal decomposition treatment
JP2003262314A (en) Heat treatment method and facility for water containing organic matter
JP2005257182A (en) Operating method for pyrolizing facility and pyrolizing facility
JP2003343820A (en) Waste melting treatment equipment
JP5550932B2 (en) Heat treatment method for contaminated soil

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20080424

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20101118

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20101130

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20110117

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20110208

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20110210

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140218

Year of fee payment: 3

R150 Certificate of patent or registration of utility model

Free format text: JAPANESE INTERMEDIATE CODE: R150

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140218

Year of fee payment: 3

S111 Request for change of ownership or part of ownership

Free format text: JAPANESE INTERMEDIATE CODE: R313115

R350 Written notification of registration of transfer

Free format text: JAPANESE INTERMEDIATE CODE: R350

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20140218

Year of fee payment: 3

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

LAPS Cancellation because of no payment of annual fees